GB2030766A - Laser treatment of semiconductor material - Google Patents

Laser treatment of semiconductor material Download PDF

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Publication number
GB2030766A
GB2030766A GB7930141A GB7930141A GB2030766A GB 2030766 A GB2030766 A GB 2030766A GB 7930141 A GB7930141 A GB 7930141A GB 7930141 A GB7930141 A GB 7930141A GB 2030766 A GB2030766 A GB 2030766A
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GB
United Kingdom
Prior art keywords
amorphous
layers
layer
amorphous material
treating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB7930141A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Plessey Co Ltd
Original Assignee
Plessey Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Plessey Co Ltd filed Critical Plessey Co Ltd
Priority to GB7930141A priority Critical patent/GB2030766A/en
Publication of GB2030766A publication Critical patent/GB2030766A/en
Priority to DE19803032158 priority patent/DE3032158A1/en
Priority to JP11899680A priority patent/JPS5664476A/en
Priority to FR8018761A priority patent/FR2464565A1/en
Withdrawn legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/20Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof such devices or parts thereof comprising amorphous semiconductor materials
    • H01L31/208Particular post-treatment of the devices, e.g. annealing, short-circuit elimination
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C26/00Coating not provided for in groups C23C2/00 - C23C24/00
    • C23C26/02Coating not provided for in groups C23C2/00 - C23C24/00 applying molten material to the substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/26Bombardment with radiation
    • H01L21/263Bombardment with radiation with high-energy radiation
    • H01L21/268Bombardment with radiation with high-energy radiation using electromagnetic radiation, e.g. laser radiation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/06Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers
    • H01L31/075Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers the potential barriers being only of the PIN type, e.g. amorphous silicon PIN solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/186Particular post-treatment for the devices, e.g. annealing, impurity gettering, short-circuit elimination, recrystallisation
    • H01L31/1872Recrystallisation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005Processes
    • H01L33/0095Post-treatment of devices, e.g. annealing, recrystallisation or short-circuit elimination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/548Amorphous silicon PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • Manufacturing & Machinery (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Optics & Photonics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Recrystallisation Techniques (AREA)

Abstract

A layer or layers of amorphous material deposited on a non-crystalline amorphous substrate are subjected to treatment by exposure to a laser beam. The treatment may either recrystallise or anneal the amorphous material depending on the laser power and improves its suitability for such devices as solar cells by improving the life times and diffusion lengths within the material as compared to the untreated material. The use of P type SiC or polycrystalline silicon on superposed i and n type amorphous silicon layers to improve the transmissivity of the outer layers of solar cells, and the use of varying composition SiC layers for visible light emission devices are also disclosed.

Description

SPECIFICATION Improvements in or relating to solar cells and other devices.
The present invention relates to method of treatment of amorphous material layers to make them more suitable for the production of solar cells and other similar devices and to the solar cells and or other devices produced using the treated materials.
The possible use of thin film amorphous materials for solar cells, (or other devices such as p-n junctions, Schottky diodes, zener diodes) integrated into large area systems such as displays is extremely attractive due to the relatively low cost in terms of materials and energy. A disadvantage however, is that device performance has previously been severely limited by the short life times and diffusion lengths typical of amorphous materials. For example, the present state of the art A.M.I.
efficiencies for polycrystalline silicon solar cells is about 10% which is a factor of 2 higher than the best cell produced with amorophous material.
It is an object of the present invention to produce a treated layer of amorphous material which is substantially superior to that known at present and thus to be able to combine the advantages in terms of the low cost and large area capability of amorphous thin film with the superior device performance of the polycrystalline material.
According to the present invention there is provided a method of treating one or more layers of amorphous material deposited on a non-crystalline substrate, to improve the suitability of the material for use in solar cells or similar devices as hereinbefore defined, by subjecting the layer of amorphous material to exposure by a laser.
The present invention also provides an amorphous silicon solar cell comprising an upper layer of p type SixCi -x an intermediate layer of i,-Si and a lower layer of n Si on a suitable substrate.
The invention also provides an amorphous silicon solar cell comprising an upper layer of p type polycrystalline silicon an intermediate layer of i -Si and a lower layer of n Si on a suitable substrate.
In a preferred embodiment the amorphous material is silicon.
Embodiments of the present invention will now be described, by way of example with reference to the accompanying drawings, in which: Figure 1 shows a conventional schottky barrier cell, Figure 2 shows a conventional P-i-n barrier cell, Figure 3 shows a first solar cell heterostructure according to the present invention and, Figure 4 shows a second solar cell structure according to the present invention.
An amorphous silicon layer or multi-layer amorphous structure of 6,000A was grown on an amorphous non-crystalline substrate e.g. glass, metallised glass or stainless steel by known methods, for example the glow discharge decomposition of SiH4 or by sputtering. The amorphous layer or layers are then subjected to exposure by a suitable laser. The effect of the exposure to the laser is either to crystallise a controlled thickness of the amorphous structure when a high power is used to anneal the amorphous layer when a lower power is used.
The recrystallised layer possesses optical and electronic properties which make it more suitable as part of a solar cell, p-n junction or other devices.
In the case of the annealed, non-recystallised layer the properties will tend to reduce the density of the defect states in the gap.
Referring now to the drawings current practise when using amorphous-silicon (a- Si) for solar cells is to use p-i-n or Schottky barrier I - i - n structures, as shown in Figs. 1 and 2. These approaches limit the attainable solar conversion efficiency, for any quality i-Si, because of the p layer or metal Schottky barrier prevents a large proportion of the incident light from reaching the depleted i region. If these surface layers could be replaced by a relatively optically transparent material, which still forms an electrically active junction, then the device efficiency would be improved.
This invention replaces the pa -Si or metal Schottky barrier with an amorphous layer of 'p' type SixCi -x in which 0 x 1 as shown in Fig. 3. Amorphous S1 xCi -x forms a continuous series of solid solutions with a bandgap that increases as x decreases, thus a larger fraction of the incident light reaches the junction depletion than with conventional structures. This application therfore provides a heterojunction a-SiC/Si structure.
Further uses of this concept includes SixC, ~ x/SiyC, ~y/SixC1 ~ x/glass/metal or plastic substrate structures for visible light emission which would have applications for flat panel displays.
Referring now to Fig. 4 a second preferred solar cell according to the present invention is shown. Current amorphous silicon solar cells are limited in efficiency because of absorption or reflection of light by the top pa-Si or metal Schottky barrier layer. The solar cell shown in Fig. 4 reduces the wastage of input photons by forming a p-n junction between p-type polycrystalline silicon and the conventional i-na-Si layers as shown in Figs. 1 and 2. The cell is therefore more efficient than previously known solar cells.
In the above shown solar cells suitable front and rear contact metallisations are applied to realise a working structure.

Claims (9)

1. A method of treating one or more layers of amorphous material deposited on a non-crystalline substrate, to improve the suitability of the material for use in solar cells or similar devices as hereinbefore defined by subjecting the layer of amorphous material to exposure by a laser.
2. A method of treating one or more layers of amorphous material as claimed in claim 1 in which the amorphous material is silicon, or hydrogenated amorphous silicon or silicon carbide or gallium arsenide or gallium phosphide.
3. A method of treating one or more layers of amorphous material as claimed in claim 2 in which the amorphous silicon or hydrogenated amorphous silicon is deposited on the amorphous substrate using the glow discharge decomposition of Six4.
4. A method of treating one or more layers of amorphous material as claimed in any one of the preceding claims in which the exposure is at a low enough level so that the material is not recrystallised but is annealed so as to reduce the number of defect states in the gap with a consequent improvement in lifetime and diffusion lengths.
5. A method of treating one or more layers of amorphous material as claimed in any one of the preceding claims in which the exposure is at a level high enough to recrystallise at least one layer of the amorphous material.
6. A method of treating one or more layers of amorphous material substantially as described.
7. An amorphous silicon solar cell comprising an upper layer of p type SixC,-x and intermediate layer of ia-Si and a lower layer of naSi mounted on a suitable substrate.
8. An amorphous silicon solar cell comprising an upper layer of p type polycrystalline silicon an intermediate layer of ia-Si and a lower layer of naSi mounted on a suitable substrate.
9. An amorphous silicon solar cell substantially as described with reference to Fig. 3 or 4 of the accompanying drawings.
GB7930141A 1978-09-02 1979-08-30 Laser treatment of semiconductor material Withdrawn GB2030766A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB7930141A GB2030766A (en) 1978-09-02 1979-08-30 Laser treatment of semiconductor material
DE19803032158 DE3032158A1 (en) 1979-08-30 1980-08-26 SOLAR CELL
JP11899680A JPS5664476A (en) 1979-08-30 1980-08-28 Armophous silicon solar battery
FR8018761A FR2464565A1 (en) 1979-08-30 1980-08-29 Laser treatment of semiconductor material - uses low and high power dosages to crystallise or anneal controlled thickness of amorphous structure, grown on non-crystalline substrate

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB7835406 1978-09-02
GB7930141A GB2030766A (en) 1978-09-02 1979-08-30 Laser treatment of semiconductor material

Publications (1)

Publication Number Publication Date
GB2030766A true GB2030766A (en) 1980-04-10

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GB7930141A Withdrawn GB2030766A (en) 1978-09-02 1979-08-30 Laser treatment of semiconductor material

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Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0025872A2 (en) * 1979-09-21 1981-04-01 Messerschmitt-Bölkow-Blohm Gesellschaft mit beschränkter Haftung Semiconductor component part for the conversion of solar rays into electrical energy
EP0042868A1 (en) * 1979-12-26 1982-01-06 GIBBONS, James F. Amorphous solar cells and method
FR2525819A1 (en) * 1982-04-27 1983-10-28 Rca Corp SEMICONDUCTOR PHOTOELECTRIC CELL
FR2582455A1 (en) * 1985-05-21 1986-11-28 Menigaux Louis METHOD FOR MANUFACTURING A RIBBON AND LASER GEOMETRY SEMICONDUCTOR LASER OBTAINED BY THIS PROCESS
FR2588123A1 (en) * 1985-09-27 1987-04-03 Sanyo Electric Co PHOTOVOLTAIC DEVICE
EP0361481A2 (en) * 1988-09-30 1990-04-04 Kanegafuchi Chemical Industry Co., Ltd. Method of stabilizing amorphous semiconductors
WO1996017388A1 (en) * 1994-12-02 1996-06-06 Pacific Solar Pty. Limited Method of manufacturing a multilayer solar cell
EP0989102A1 (en) * 1998-09-21 2000-03-29 Central Glass Company, Limited Process for producing amorphous material containing single-crystal or polycrystal regions and material produced
EP1265297A1 (en) * 2000-03-13 2002-12-11 Sony Corporation Optical energy transducer
US8058615B2 (en) 2008-02-29 2011-11-15 Sionyx, Inc. Wide spectral range hybrid image detector
US8679959B2 (en) 2008-09-03 2014-03-25 Sionyx, Inc. High sensitivity photodetectors, imaging arrays, and high efficiency photovoltaic devices produced using ion implantation and femtosecond laser irradiation
US8680591B2 (en) 2009-09-17 2014-03-25 Sionyx, Inc. Photosensitive imaging devices and associated methods
US8698272B2 (en) 2010-12-21 2014-04-15 Sionyx, Inc. Semiconductor devices having reduced substrate damage and associated methods
US8698084B2 (en) 2011-03-10 2014-04-15 Sionyx, Inc. Three dimensional sensors, systems, and associated methods
US8802549B2 (en) 2009-04-28 2014-08-12 Sionyx, Inc. Semiconductor surface modification
US8865507B2 (en) 2011-09-16 2014-10-21 Sionyx, Inc. Integrated visible and infrared imager devices and associated methods
US9064764B2 (en) 2012-03-22 2015-06-23 Sionyx, Inc. Pixel isolation elements, devices, and associated methods
US9209345B2 (en) 2013-06-29 2015-12-08 Sionyx, Inc. Shallow trench textured regions and associated methods
US9496308B2 (en) 2011-06-09 2016-11-15 Sionyx, Llc Process module for increasing the response of backside illuminated photosensitive imagers and associated methods
US9673243B2 (en) 2009-09-17 2017-06-06 Sionyx, Llc Photosensitive imaging devices and associated methods
US9741761B2 (en) 2010-04-21 2017-08-22 Sionyx, Llc Photosensitive imaging devices and associated methods
US9761739B2 (en) 2010-06-18 2017-09-12 Sionyx, Llc High speed photosensitive devices and associated methods
US9762830B2 (en) 2013-02-15 2017-09-12 Sionyx, Llc High dynamic range CMOS image sensor having anti-blooming properties and associated methods
US9911781B2 (en) 2009-09-17 2018-03-06 Sionyx, Llc Photosensitive imaging devices and associated methods
US9939251B2 (en) 2013-03-15 2018-04-10 Sionyx, Llc Three dimensional imaging utilizing stacked imager devices and associated methods
US10244188B2 (en) 2011-07-13 2019-03-26 Sionyx, Llc Biometric imaging devices and associated methods
US10361083B2 (en) 2004-09-24 2019-07-23 President And Fellows Of Harvard College Femtosecond laser-induced formation of submicrometer spikes on a semiconductor substrate
US10374109B2 (en) 2001-05-25 2019-08-06 President And Fellows Of Harvard College Silicon-based visible and near-infrared optoelectric devices

Cited By (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0025872A2 (en) * 1979-09-21 1981-04-01 Messerschmitt-Bölkow-Blohm Gesellschaft mit beschränkter Haftung Semiconductor component part for the conversion of solar rays into electrical energy
EP0025872A3 (en) * 1979-09-21 1982-02-10 Messerschmitt-Bolkow-Blohm Gesellschaft Mit Beschrankter Haftung Semiconductor component part for the conversion of light into electrical energy
EP0042868A1 (en) * 1979-12-26 1982-01-06 GIBBONS, James F. Amorphous solar cells and method
EP0042868A4 (en) * 1979-12-26 1982-02-05 James F Gibbons Amorphous solar cells and method.
FR2525819A1 (en) * 1982-04-27 1983-10-28 Rca Corp SEMICONDUCTOR PHOTOELECTRIC CELL
FR2582455A1 (en) * 1985-05-21 1986-11-28 Menigaux Louis METHOD FOR MANUFACTURING A RIBBON AND LASER GEOMETRY SEMICONDUCTOR LASER OBTAINED BY THIS PROCESS
EP0203848A1 (en) * 1985-05-21 1986-12-03 Louis Menigaux Method of making a semiconductor laser with a stripe-shaped geometry and laser obtained by this method
US4742013A (en) * 1985-05-21 1988-05-03 Louis Menigaux Process for the production of a semiconductor laser with tape geometry and laser obtained by this process
FR2588123A1 (en) * 1985-09-27 1987-04-03 Sanyo Electric Co PHOTOVOLTAIC DEVICE
EP0361481A3 (en) * 1988-09-30 1990-11-14 Kanegafuchi Chemical Industry Co., Ltd. Method of stabilizing amorphous semiconductors, thus-stabilized amorphous semiconductors and devices using such semiconductors
EP0361481A2 (en) * 1988-09-30 1990-04-04 Kanegafuchi Chemical Industry Co., Ltd. Method of stabilizing amorphous semiconductors
WO1996017388A1 (en) * 1994-12-02 1996-06-06 Pacific Solar Pty. Limited Method of manufacturing a multilayer solar cell
US5942050A (en) * 1994-12-02 1999-08-24 Pacific Solar Pty Ltd. Method of manufacturing a multilayer solar cell
EP0989102A1 (en) * 1998-09-21 2000-03-29 Central Glass Company, Limited Process for producing amorphous material containing single-crystal or polycrystal regions and material produced
US6261420B1 (en) 1998-09-21 2001-07-17 Central Glass Company, Limited Process for producing amorphous material containing single crystal or polycrystal and material produced
EP1265297A1 (en) * 2000-03-13 2002-12-11 Sony Corporation Optical energy transducer
EP1265297A4 (en) * 2000-03-13 2003-07-02 Sony Corp Optical energy transducer
US7199303B2 (en) 2000-03-13 2007-04-03 Sony Corporation Optical energy conversion apparatus
US10374109B2 (en) 2001-05-25 2019-08-06 President And Fellows Of Harvard College Silicon-based visible and near-infrared optoelectric devices
US10361083B2 (en) 2004-09-24 2019-07-23 President And Fellows Of Harvard College Femtosecond laser-induced formation of submicrometer spikes on a semiconductor substrate
US10741399B2 (en) 2004-09-24 2020-08-11 President And Fellows Of Harvard College Femtosecond laser-induced formation of submicrometer spikes on a semiconductor substrate
US8058615B2 (en) 2008-02-29 2011-11-15 Sionyx, Inc. Wide spectral range hybrid image detector
US8679959B2 (en) 2008-09-03 2014-03-25 Sionyx, Inc. High sensitivity photodetectors, imaging arrays, and high efficiency photovoltaic devices produced using ion implantation and femtosecond laser irradiation
US8802549B2 (en) 2009-04-28 2014-08-12 Sionyx, Inc. Semiconductor surface modification
US9911781B2 (en) 2009-09-17 2018-03-06 Sionyx, Llc Photosensitive imaging devices and associated methods
US8680591B2 (en) 2009-09-17 2014-03-25 Sionyx, Inc. Photosensitive imaging devices and associated methods
US10361232B2 (en) 2009-09-17 2019-07-23 Sionyx, Llc Photosensitive imaging devices and associated methods
US9673243B2 (en) 2009-09-17 2017-06-06 Sionyx, Llc Photosensitive imaging devices and associated methods
US10229951B2 (en) 2010-04-21 2019-03-12 Sionyx, Llc Photosensitive imaging devices and associated methods
US9741761B2 (en) 2010-04-21 2017-08-22 Sionyx, Llc Photosensitive imaging devices and associated methods
US9761739B2 (en) 2010-06-18 2017-09-12 Sionyx, Llc High speed photosensitive devices and associated methods
US10505054B2 (en) 2010-06-18 2019-12-10 Sionyx, Llc High speed photosensitive devices and associated methods
US8698272B2 (en) 2010-12-21 2014-04-15 Sionyx, Inc. Semiconductor devices having reduced substrate damage and associated methods
US8698084B2 (en) 2011-03-10 2014-04-15 Sionyx, Inc. Three dimensional sensors, systems, and associated methods
US9666636B2 (en) 2011-06-09 2017-05-30 Sionyx, Llc Process module for increasing the response of backside illuminated photosensitive imagers and associated methods
US9496308B2 (en) 2011-06-09 2016-11-15 Sionyx, Llc Process module for increasing the response of backside illuminated photosensitive imagers and associated methods
US10269861B2 (en) 2011-06-09 2019-04-23 Sionyx, Llc Process module for increasing the response of backside illuminated photosensitive imagers and associated methods
US10244188B2 (en) 2011-07-13 2019-03-26 Sionyx, Llc Biometric imaging devices and associated methods
US8865507B2 (en) 2011-09-16 2014-10-21 Sionyx, Inc. Integrated visible and infrared imager devices and associated methods
US10224359B2 (en) 2012-03-22 2019-03-05 Sionyx, Llc Pixel isolation elements, devices and associated methods
US9905599B2 (en) 2012-03-22 2018-02-27 Sionyx, Llc Pixel isolation elements, devices and associated methods
US9064764B2 (en) 2012-03-22 2015-06-23 Sionyx, Inc. Pixel isolation elements, devices, and associated methods
US9762830B2 (en) 2013-02-15 2017-09-12 Sionyx, Llc High dynamic range CMOS image sensor having anti-blooming properties and associated methods
US9939251B2 (en) 2013-03-15 2018-04-10 Sionyx, Llc Three dimensional imaging utilizing stacked imager devices and associated methods
US10347682B2 (en) 2013-06-29 2019-07-09 Sionyx, Llc Shallow trench textured regions and associated methods
US9673250B2 (en) 2013-06-29 2017-06-06 Sionyx, Llc Shallow trench textured regions and associated methods
US9209345B2 (en) 2013-06-29 2015-12-08 Sionyx, Inc. Shallow trench textured regions and associated methods
US11069737B2 (en) 2013-06-29 2021-07-20 Sionyx, Llc Shallow trench textured regions and associated methods

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WAP Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1)