GB1515963A - Crosslinked collagen-mucopolysaccharide composite materials - Google Patents

Crosslinked collagen-mucopolysaccharide composite materials

Info

Publication number
GB1515963A
GB1515963A GB2835976A GB2835976A GB1515963A GB 1515963 A GB1515963 A GB 1515963A GB 2835976 A GB2835976 A GB 2835976A GB 2835976 A GB2835976 A GB 2835976A GB 1515963 A GB1515963 A GB 1515963A
Authority
GB
United Kingdom
Prior art keywords
mucopolysaccharide
cross
collagen
sulphate
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2835976A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Massachusetts Institute of Technology
Original Assignee
Massachusetts Institute of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Massachusetts Institute of Technology filed Critical Massachusetts Institute of Technology
Publication of GB1515963A publication Critical patent/GB1515963A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
    • C08H1/00—Macromolecular products derived from proteins
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L17/00—Materials for surgical sutures or for ligaturing blood vessels ; Materials for prostheses or catheters
    • A61L17/06—At least partially resorbable materials
    • A61L17/10—At least partially resorbable materials containing macromolecular materials
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L27/00—Materials for grafts or prostheses or for coating grafts or prostheses
    • A61L27/14—Macromolecular materials
    • A61L27/22—Polypeptides or derivatives thereof, e.g. degradation products
    • A61L27/24—Collagen
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L33/00—Antithrombogenic treatment of surgical articles, e.g. sutures, catheters, prostheses, or of articles for the manipulation or conditioning of blood; Materials for such treatment
    • A61L33/0005—Use of materials characterised by their function or physical properties
    • A61L33/0011—Anticoagulant, e.g. heparin, platelet aggregation inhibitor, fibrinolytic agent, other than enzymes, attached to the substrate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L33/00—Antithrombogenic treatment of surgical articles, e.g. sutures, catheters, prostheses, or of articles for the manipulation or conditioning of blood; Materials for such treatment
    • A61L33/06—Use of macromolecular materials
    • A61L33/062—Mixtures of macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
    • C08B37/006—Heteroglycans, i.e. polysaccharides having more than one sugar residue in the main chain in either alternating or less regular sequence; Gellans; Succinoglycans; Arabinogalactans; Tragacanth or gum tragacanth or traganth from Astragalus; Gum Karaya from Sterculia urens; Gum Ghatti from Anogeissus latifolia; Derivatives thereof
    • C08B37/0063—Glycosaminoglycans or mucopolysaccharides, e.g. keratan sulfate; Derivatives thereof, e.g. fucoidan
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F2310/00—Prostheses classified in A61F2/28 or A61F2/30 - A61F2/44 being constructed from or coated with a particular material
    • A61F2310/00005—The prosthesis being constructed from a particular material
    • A61F2310/00365—Proteins; Polypeptides; Degradation products thereof

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Surgery (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biochemistry (AREA)
  • Hematology (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Transplantation (AREA)
  • Dermatology (AREA)
  • Biophysics (AREA)
  • Vascular Medicine (AREA)
  • Molecular Biology (AREA)
  • Materials For Medical Uses (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
  • Laminated Bodies (AREA)
  • Sealing Material Composition (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

1515963 Cross-linked polymer of collagen and a mucopolysaccharide MASSACHUSETTS INSTITUTE OF TECHNOLOGY 8 July 1976 [15 July 1975] 28359/76 Heading C3H A cross-linked polymer of collagen and a mucopolysaccharide obtained by reacting collagen with the mucopolysaccharide and cross-linking the product is characterized in that the polymer is cross-linked to an Mc value of 800-60,000 and contains at least 0À5% by weight of said mucopolysaccharide irreversibly bound to said collagen. The polymer may be produced by dipping fibres, sheets, films and tubes made of collagen into a solution of mucopolysaccharide. The cross-linking may be achieved with a chemical cross-linking agent, e.g. glutaraldehyde, dehydrothermal crosslinking, or by radiation. The mucopolysaccharide is preferably chondroilin 6-sulphate, chondroitin 4-sulphate, heparin, keratan sulphate, heparan sulphate, dermatan sulphate or hyduronic acid. The cross-linked polymer may be formed into a suture or prosthesis.
GB2835976A 1975-07-15 1976-07-08 Crosslinked collagen-mucopolysaccharide composite materials Expired GB1515963A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US59611175A 1975-07-15 1975-07-15

Publications (1)

Publication Number Publication Date
GB1515963A true GB1515963A (en) 1978-06-28

Family

ID=24386022

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2835976A Expired GB1515963A (en) 1975-07-15 1976-07-08 Crosslinked collagen-mucopolysaccharide composite materials

Country Status (5)

Country Link
JP (1) JPS5230885A (en)
CA (1) CA1087610A (en)
DE (1) DE2631908A1 (en)
FR (1) FR2318189A1 (en)
GB (1) GB1515963A (en)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4378017A (en) 1980-03-21 1983-03-29 Kureha Kagaku Kogyo Kabushiki Kaisha Composite material of de-N-acetylated chitin and fibrous collagen
GB2148901A (en) * 1983-10-04 1985-06-05 Johnson & Johnson Protein/polysaccharide complexes
US4526714A (en) * 1982-12-13 1985-07-02 Cordis Europa N.V. Conjugates of anticoagulant and protein
US4634762A (en) * 1981-12-15 1987-01-06 Sentron V.O.F. Conjugates of anticoagulant and protein
US4678671A (en) * 1981-12-15 1987-07-07 Cordis Europa N.V. Conjugates of anticoagulant and protein
WO1989000413A1 (en) * 1987-07-20 1989-01-26 Stone Kevin R Prosthetic meniscus
WO1990009769A1 (en) * 1989-03-02 1990-09-07 Regen Corporation Prosthetic meniscus
WO1991018558A1 (en) * 1990-05-29 1991-12-12 Creative Biomolecules, Inc. Synthetic bone matrix
US5108438A (en) * 1989-03-02 1992-04-28 Regen Corporation Prosthetic intervertebral disc
US5263984A (en) * 1987-07-20 1993-11-23 Regen Biologics, Inc. Prosthetic ligaments
US5306311A (en) * 1987-07-20 1994-04-26 Regen Corporation Prosthetic articular cartilage
US5681353A (en) * 1987-07-20 1997-10-28 Regen Biologics, Inc. Meniscal augmentation device
US5735902A (en) * 1987-07-20 1998-04-07 Regen Biologics, Inc. Hand implant device
EP1337266A1 (en) * 2000-10-31 2003-08-27 Orquest, Inc. Mineralized collagen-polysaccharide matrix for bone and cartilage repair
WO2006111347A1 (en) 2005-04-18 2006-10-26 Lohmann & Rauscher Gmbh & Co Kg. Self-sterilized, antiseptic collagen preparations, their use and method for producing them
US7309359B2 (en) 2003-08-21 2007-12-18 Warsaw Orthopedic, Inc. Allogenic/xenogenic implants and methods for augmenting or repairing intervertebral discs
CN100457989C (en) * 2006-11-04 2009-02-04 青岛大学 Method for preparing high-strength alginic acid/gelatin cross-blend fiber and its use
US8118779B2 (en) 2006-06-30 2012-02-21 Warsaw Orthopedic, Inc. Collagen delivery device
US8399619B2 (en) 2006-06-30 2013-03-19 Warsaw Orthopedic, Inc. Injectable collagen material
CN112704768A (en) * 2020-11-30 2021-04-27 山东大学 Chondroitin sulfate modified collagen/polycaprolactone vascular repair stent and preparation method and application thereof
CN117298327A (en) * 2023-11-15 2023-12-29 北京帝康医药投资管理有限公司 Hemostatic microsphere particles and preparation method and application thereof

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1085524B (en) * 1977-03-22 1985-05-28 Snam Progetti BIOCOMPATIBLE POROUS MATERIALS AND FIBERS ABLE TO ENGLISH SUBSTANCES OF BIOLOGICAL INTEREST AND METHODS FOR OBTAINING THEM
FR2517315B1 (en) * 1981-11-30 1985-12-20 Tech Cuir Centre PROCESS FOR THE PREPARATION OF NEW FORMS OF COLLAGEN, NATIVE OR DERETICULATED, WITH PRESERVED HELICOIDAL STRUCTURE, ASSOCIATED WITH MUCOPOLYSACCHARIDES AND THEIR APPLICATIONS IN PARTICULAR IN THE COSMETOLOGICAL, PHARMACEUTICAL, ANALYTICAL AND OTHER FIELDS
CA1213520A (en) * 1982-03-17 1986-11-04 Abe Widra Hydrophilic biopolymeric copolyelectrolytes, and biodegradable dressings comprising same
JPS58180162A (en) * 1982-04-19 1983-10-21 株式会社高研 Anti-thrombosis medical material
US4487865A (en) * 1983-12-15 1984-12-11 Biomatrix, Inc. Polymeric articles modified with hyaluronate
US4500676A (en) * 1983-12-15 1985-02-19 Biomatrix, Inc. Hyaluronate modified polymeric articles
JPS60130601A (en) * 1983-12-15 1985-07-12 バイオマトリツクス，インコ−ポレイテツド Manufacture of hyaluronic acid water-insoluble composition
CA1238043A (en) * 1983-12-15 1988-06-14 Endre A. Balazs Water insoluble preparations of hyaluronic acid and processes therefor
US4745098A (en) * 1984-02-24 1988-05-17 The Regents Of The University Of California Compositions and method for improving wound healing
SE442820B (en) * 1984-06-08 1986-02-03 Pharmacia Ab GEL OF THE CROSS-BOND HYALURONIC ACID FOR USE AS A GLASS BODY SUBSTITUTE
SE456346B (en) * 1984-07-23 1988-09-26 Pharmacia Ab GEL TO PREVENT ADHESION BETWEEN BODY TISSUE AND SET FOR ITS PREPARATION
US4582865A (en) * 1984-12-06 1986-04-15 Biomatrix, Inc. Cross-linked gels of hyaluronic acid and products containing such gels
FR2585576B1 (en) * 1985-07-30 1992-01-03 Bioetica Sa BONE MATRIX REPLACEMENT PROMOTING OSTEOGENESIS
EP0246638A3 (en) * 1986-05-23 1989-03-15 Cordis Corporation Biologically modified synthetic grafts
JPH01124465A (en) * 1987-11-10 1989-05-17 Kanegafuchi Chem Ind Co Ltd Composition for artificial basement membrane and implantation device with artificial basement membrane
JPH0622579B2 (en) * 1988-03-09 1994-03-30 テルモ株式会社 Cell invasive medical materials
US5292362A (en) * 1990-07-27 1994-03-08 The Trustees Of Columbia University In The City Of New York Tissue bonding and sealing composition and method of using the same
US5990096A (en) * 1990-09-18 1999-11-23 Hyal Pharmaceutical Corporation Formulations containing hyaluronic acid
US5824658A (en) * 1990-09-18 1998-10-20 Hyal Pharmaceutical Corporation Topical composition containing hyaluronic acid and NSAIDS
US5910489A (en) * 1990-09-18 1999-06-08 Hyal Pharmaceutical Corporation Topical composition containing hyaluronic acid and NSAIDS
CA2061703C (en) * 1992-02-20 2002-07-02 Rudolf E. Falk Formulations containing hyaluronic acid
US5977088A (en) * 1991-07-03 1999-11-02 Hyal Pharmaceutical Corporation Formulations containing hyaluronic acid
US6103704A (en) * 1991-07-03 2000-08-15 Hyal Pharmaceutical Corporation Therapeutic methods using hyaluronic acid
US5792753A (en) * 1991-07-03 1998-08-11 Hyal Pharmaceutical Corporation Compositions comprising hyaluronic acid and prostaglandin-synthesis-inhibiting drugs
US6218373B1 (en) 1992-02-20 2001-04-17 Hyal Pharmaceutical Corporation Formulations containing hyaluronic acid
US5767106A (en) * 1992-02-21 1998-06-16 Hyal Pharmaceutical Corporation Treatment of disease and conditions associated with macrophage infiltration
DE4425776C2 (en) * 1994-07-13 2002-08-29 Britta Hofmann Process for the preparation of an improved collagen graft with a loosened structure
AU700584C (en) * 1994-08-12 2002-03-28 Meadox Medicals, Inc. Vascular graft impregnated with a heparin-containing collagen sealant
DE19630879A1 (en) * 1996-07-31 1998-02-05 Hanno Lutz Prof Dr Baumann Production of blood-compatible material, for implants, containers etc.
ATE435668T1 (en) 2004-04-15 2009-07-15 Nexilis Ag OSTEOGENIC MATRIX COMPOSITE, METHOD FOR THE PRODUCTION THEREOF AND IMPLANT AND SCAFFOLD FOR TISSUE ENGINEERING WITH A COATING MADE OF AN OSTEOGENIC MATRIX COMPOSITE
CN103301510B (en) * 2013-06-20 2014-12-24 孙文善 Acupuncture implantation material

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1491218C3 (en) * 1963-06-15 1973-01-04 Spofa Sdruzheni Podniku Pro Zdravotnickou Vyrobu, Prag Blood vessel prosthesis and method for making the same
US3527225A (en) * 1964-09-29 1970-09-08 David F Smith Resorbable surgical sutures from fibrous proteins
FR2236539A1 (en) * 1973-07-13 1975-02-07 Ladialas Robert Biological polymeric membrane prepn. - by depolymerising elastin and then, copolymerising the peptides with gelatin, collagen etc.

Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4378017A (en) 1980-03-21 1983-03-29 Kureha Kagaku Kogyo Kabushiki Kaisha Composite material of de-N-acetylated chitin and fibrous collagen
US4634762A (en) * 1981-12-15 1987-01-06 Sentron V.O.F. Conjugates of anticoagulant and protein
US4678671A (en) * 1981-12-15 1987-07-07 Cordis Europa N.V. Conjugates of anticoagulant and protein
US4526714A (en) * 1982-12-13 1985-07-02 Cordis Europa N.V. Conjugates of anticoagulant and protein
GB2148901A (en) * 1983-10-04 1985-06-05 Johnson & Johnson Protein/polysaccharide complexes
US4880429A (en) * 1987-07-20 1989-11-14 Stone Kevin R Prosthetic meniscus
US5735902A (en) * 1987-07-20 1998-04-07 Regen Biologics, Inc. Hand implant device
WO1989000413A1 (en) * 1987-07-20 1989-01-26 Stone Kevin R Prosthetic meniscus
US5007934A (en) * 1987-07-20 1991-04-16 Regen Corporation Prosthetic meniscus
US6042610A (en) * 1987-07-20 2000-03-28 Regen Biologics, Inc. Meniscal augmentation device
US5735903A (en) * 1987-07-20 1998-04-07 Li; Shu-Tung Meniscal augmentation device
US5263984A (en) * 1987-07-20 1993-11-23 Regen Biologics, Inc. Prosthetic ligaments
US5306311A (en) * 1987-07-20 1994-04-26 Regen Corporation Prosthetic articular cartilage
US5624463A (en) * 1987-07-20 1997-04-29 Regen Biologics, Inc. Prosthetic articular cartilage
US5681353A (en) * 1987-07-20 1997-10-28 Regen Biologics, Inc. Meniscal augmentation device
WO1990009769A1 (en) * 1989-03-02 1990-09-07 Regen Corporation Prosthetic meniscus
US5108438A (en) * 1989-03-02 1992-04-28 Regen Corporation Prosthetic intervertebral disc
WO1991018558A1 (en) * 1990-05-29 1991-12-12 Creative Biomolecules, Inc. Synthetic bone matrix
US6468308B1 (en) 1990-05-29 2002-10-22 Stryker Corporation Synthetic bone matrix
US6605117B2 (en) 1990-05-29 2003-08-12 Stryker Corporation Synthetic bone matrix
EP1337266A4 (en) * 2000-10-31 2006-11-02 Depuy Spine Inc Mineralized collagen-polysaccharide matrix for bone and cartilage repair
EP1337266A1 (en) * 2000-10-31 2003-08-27 Orquest, Inc. Mineralized collagen-polysaccharide matrix for bone and cartilage repair
US7309359B2 (en) 2003-08-21 2007-12-18 Warsaw Orthopedic, Inc. Allogenic/xenogenic implants and methods for augmenting or repairing intervertebral discs
US9011543B2 (en) 2003-08-21 2015-04-21 Warsaw Orthopedic, Inc. Methods for augmenting or repairing intervertebral discs with allogenic/xenogenic implants
WO2006111347A1 (en) 2005-04-18 2006-10-26 Lohmann & Rauscher Gmbh & Co Kg. Self-sterilized, antiseptic collagen preparations, their use and method for producing them
US7956094B2 (en) 2005-04-18 2011-06-07 Lohmann & Rauscher Gmbh & Co. Kg Self-sterilized, antiseptic collagen preparations, their use and methods for producing them
US8118779B2 (en) 2006-06-30 2012-02-21 Warsaw Orthopedic, Inc. Collagen delivery device
US8399619B2 (en) 2006-06-30 2013-03-19 Warsaw Orthopedic, Inc. Injectable collagen material
CN100457989C (en) * 2006-11-04 2009-02-04 青岛大学 Method for preparing high-strength alginic acid/gelatin cross-blend fiber and its use
CN112704768A (en) * 2020-11-30 2021-04-27 山东大学 Chondroitin sulfate modified collagen/polycaprolactone vascular repair stent and preparation method and application thereof
CN117298327A (en) * 2023-11-15 2023-12-29 北京帝康医药投资管理有限公司 Hemostatic microsphere particles and preparation method and application thereof

Also Published As

Publication number Publication date
FR2318189A1 (en) 1977-02-11
JPS543779B2 (en) 1979-02-27
FR2318189B1 (en) 1980-08-01
DE2631908A1 (en) 1977-02-10
DE2631908C2 (en) 1988-10-20
JPS5230885A (en) 1977-03-08
CA1087610A (en) 1980-10-14

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Legal Events

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PS Patent sealed
PE20 Patent expired after termination of 20 years

Effective date: 19960707