GB1470250A - Aluminosilicate ion-exchange materials as detergent builder compositions - Google Patents

Aluminosilicate ion-exchange materials as detergent builder compositions

Info

Publication number
GB1470250A
GB1470250A GB3123874A GB3123874A GB1470250A GB 1470250 A GB1470250 A GB 1470250A GB 3123874 A GB3123874 A GB 3123874A GB 3123874 A GB3123874 A GB 3123874A GB 1470250 A GB1470250 A GB 1470250A
Authority
GB
United Kingdom
Prior art keywords
weight
detergent composition
water
builder
detergent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3123874A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of GB1470250A publication Critical patent/GB1470250A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/09—Inorganic material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28—Base exchange silicates, e.g. zeolites
    • C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/46—Amorphous silicates, e.g. so-called "amorphous zeolites"

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Detergent Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

1470250 Aluminosilicate detergency builder PROCTER & GAMBLE CO 15 July 1974 [16 July 1973 (3)] 31238/74 Heading C5D [Also in Division C1] A detergent composition capable of rapidly reducing the free polyvalent metal ion content of an aqueous solution comprises 5-95% by weight of an amorphous, water-insoluble, hydrated aluminosilicate ion-exchange builder material, Na x (xAlO 2 .SiO 2 ) where x=1-1À2, having a Mg<SP>++</SP> exchange capacity of at least 50 mg, e.g. CaCO 3 /g. (anhydrous basis) and having a Ca<SP>++</SP> exchange capacity of at least 200 mg, e.g. CaCO 3 /g. (anhydrous basis) and 95-5% by weight of a water-soluble organic detergent of one or more anionic, non-ionic, ampholytic or zwitterionic detergents. The detergent composition may also contain 5-50% by weight of an auxiliary water-soluble detergency builder (preferably Na or K tripolyphosphate or P-free builder, e.g. inorganic carbonate, bicarbonate, silicate or organic polyacetates, carboxylates, polycarboxylates or polyhydroxysulphonates). The detergent composition may also contain 0À1-3% by weight of a polyethylene glycol of M.wt. 400-8000. A detergent composition is also based on the mixed amorphous-crystalline aluminosilicate (see Division C1) together with 5-95% of a water-soluble organic detergent as above.
GB3123874A 1973-07-16 1974-07-15 Aluminosilicate ion-exchange materials as detergent builder compositions Expired GB1470250A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US37988173A 1973-07-16 1973-07-16
US37988273A 1973-07-16 1973-07-16
US37988373A 1973-07-16 1973-07-16

Publications (1)

Publication Number Publication Date
GB1470250A true GB1470250A (en) 1977-04-14

Family

ID=27409473

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3123874A Expired GB1470250A (en) 1973-07-16 1974-07-15 Aluminosilicate ion-exchange materials as detergent builder compositions

Country Status (5)

Country Link
JP (1) JPS6052192B2 (en)
DE (1) DE2433485A1 (en)
FR (1) FR2237839B1 (en)
GB (1) GB1470250A (en)
IE (1) IE39618B1 (en)

Cited By (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4405483A (en) * 1982-04-27 1983-09-20 The Procter & Gamble Company Stable liquid detergents containing aluminosilicate ion exchange material
US4929380A (en) * 1986-06-27 1990-05-29 Henkel Kommanditgesellschaft Aug Aktien Process for the preparation of a storage-stable liquid detergent composition
EP0684303A2 (en) 1994-05-27 1995-11-29 Unilever Plc Detergent compositions
US5536432A (en) * 1993-11-02 1996-07-16 Lever Brothers Company, Division Of Conopco, Inc. Process for the production of a detergent composition
EP0779358A2 (en) 1995-12-16 1997-06-18 Unilever Plc Detergent composition
US5641741A (en) * 1994-08-26 1997-06-24 Lever Brothers Company, Division Of Conopco, Inc. Production of anionic surfactant granules by in situ neutralization
US5646107A (en) * 1994-08-26 1997-07-08 Lever Brothers Company, Division Of Conopco, Inc. Production of anionic surfactant granules
EP0786515A2 (en) 1996-01-25 1997-07-30 Unilever N.V. Prewash stain remover composition with siloxane based surfactant
EP0786516A2 (en) 1996-01-25 1997-07-30 Unilever N.V. Liquid detergent
US5789367A (en) * 1995-11-30 1998-08-04 Lever Brothers Company, Division Of Conopco, Inc. Detergent compositions containing soil release polymers
US5789366A (en) * 1995-11-30 1998-08-04 Lever Brothers Company, Division Of Conopco, Inc. Detergent compositions containing soil release polymers
US5789365A (en) * 1995-11-30 1998-08-04 Lever Brothers Division Of Conopco Inc. Detergent compositions containing soil release polymers
US5856294A (en) * 1996-02-26 1999-01-05 Lever Brothers Company, Division Of Conopco, Inc. Production of anionic detergent particles
US5976397A (en) * 1996-09-26 1999-11-02 Lever Brothers Company Photofading inhibitor derivatives and their use in fabric treatment compositions
USRE36593E (en) * 1996-02-26 2000-02-29 Lever Brothers Company Production of anionic detergent particles
US6051541A (en) * 1998-12-16 2000-04-18 Unilever Home & Personal Care, Division Of Conopco, Inc. Process for preparing pourable, transparent/translucent liquid detergent with continuous suspending system
US6056905A (en) * 1997-06-16 2000-05-02 Lever Brothers Company Division Of Conopco, Inc. Production of detergent granulates
US6069124A (en) * 1997-05-30 2000-05-30 Lever Brothers Company Division Of Conopco, Inc. Granular detergent compositions and their production
US6133223A (en) * 1997-06-27 2000-10-17 Lever Brothers Company, Division Of Conopco, Inc. Production of detergent granulates
US6159918A (en) * 1998-12-16 2000-12-12 Unilever Home & Personal Care U.S.A., Division Of Conopco, Inc. Transparent/translucent liquid enzyme compositions in clear bottles comprising UV absorber
US6191095B1 (en) 1997-05-30 2001-02-20 Lever Brothers Company, A Division Of Conopco, Inc. Detergent compositions
US6221831B1 (en) 1997-05-30 2001-04-24 Lever Brothers Company, Division Of Conopco, Inc. Free flowing detergent composition containing high levels of surfactant
US6258771B1 (en) 1998-12-16 2001-07-10 Unilever Home & Personal Care, Usa Division Of Conopco Process for preparing pourable, transparent/translucent liquid detergent with non-continuous suspending system
US6274544B1 (en) 1997-06-16 2001-08-14 Lever Brothers Company, Division Of Conopco, Inc. Production of detergent granulates
US6303558B1 (en) 1997-05-30 2001-10-16 Lever Brothers Co., Division Of Conopco Detergent composition containing at least two granular components
US6362156B1 (en) 1998-12-16 2002-03-26 Unilever Home & Personal Care, Usa, Division Of Conopco, Inc. Pourable transparent/translucent liquid detergent composition with suspended particles
US6630437B1 (en) 1998-12-16 2003-10-07 Unilever Home & Personal Care Usa , Division Of Conopco, Inc. Transparent/translucent liquid compositions in clear bottles comprising colorant and fluorescent dye or UV absorber
US6716807B2 (en) 2000-12-29 2004-04-06 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Detergent compositions
US6730649B2 (en) 2000-12-29 2004-05-04 Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. Detergent compositions
EP1702975A1 (en) 2005-03-15 2006-09-20 Unilever N.V. Laundry detergent with polyamine mono-anionic surfactant
WO2010105922A1 (en) 2009-03-19 2010-09-23 Unilever Plc Improvements relating to benefit agent delivery
US7867970B2 (en) 2003-06-16 2011-01-11 The Sun Products Corporation Detergent composition comprising lauric soap
EP2319910A2 (en) 2005-12-02 2011-05-11 Unilever PLC Improvements relating to fabric treatment compositions
EP2330178A2 (en) 2001-11-09 2011-06-08 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Polymers for laundry applications
WO2011072968A1 (en) 2009-12-14 2011-06-23 Unilever Plc Measured dosing cap assembly
WO2012007438A1 (en) 2010-07-15 2012-01-19 Unilever Plc Benefit delivery particle, process for preparing said particle, compositions comprising said particles and a method for treating substrates
WO2012084426A1 (en) 2010-12-22 2012-06-28 Unilever Nv Enzymatic laundry detergent composition for the promotion of hygiene and the prevention of malodour
WO2013087549A1 (en) 2011-12-16 2013-06-20 Unilever Plc Improvements relating to fabric treatment compositions
EP2650353A2 (en) 2002-12-23 2013-10-16 Basf Se Laundry care products containing hydrophobically modified polymers as additives
WO2014075956A1 (en) 2012-11-19 2014-05-22 Unilever Plc Improvements relating to encapsulated benefit agents
WO2016057623A1 (en) 2014-10-07 2016-04-14 The Procter & Gamble Company Method of pre-treating articles to be washed in a dishwashing machine
WO2016106167A1 (en) 2014-12-23 2016-06-30 Lubrizol Advanced Materials, Inc. Laundry detergent compositions
WO2016106168A1 (en) 2014-12-23 2016-06-30 Lubrizol Advanced Materials, Inc. Laundry detergent compositions stabilized with an amphiphilic rheology modifier crosslinked with an amphiphilic crosslinker
WO2018204812A1 (en) 2017-05-04 2018-11-08 Lubrizol Advanced Materials, Inc. Dual activated microgel
WO2021102080A1 (en) 2019-11-19 2021-05-27 Lubrizol Advanced Materials, Inc. Redeposition inhibiting polymers and detergent compositions containing same
WO2021115724A1 (en) 2019-12-11 2021-06-17 Unilever Ip Holdings B.V. Detergent composition
WO2021115705A1 (en) 2019-12-11 2021-06-17 Unilever Ip Holdings B.V. Detergent composition
WO2021126714A1 (en) 2019-12-20 2021-06-24 Advansix Resins & Chemicals Llc Surfactants for cleaning products
WO2021126986A1 (en) 2019-12-19 2021-06-24 Lubrizol Advanced Materials, Inc. Redeposition inhibiting polymers and detergent compositions containing same
WO2021183557A1 (en) 2020-03-11 2021-09-16 Advansix Resins & Chemicals Llc Surfactants for cleaning products
WO2022015606A1 (en) 2020-07-13 2022-01-20 Advansix Resins & Chemicals Llc Branched amino acid surfactants for cleaning products
US11427760B2 (en) 2020-02-05 2022-08-30 Advansix Resins & Chemicals Llc Surfactants for electronics
WO2022243283A1 (en) 2021-05-19 2022-11-24 Unilever Ip Holdings B.V. Process for preparing a spray dried detergent particle
WO2022243276A1 (en) 2021-05-19 2022-11-24 Unilever Ip Holdings B.V. Process for preparing a spray dried detergent particle
WO2022243265A1 (en) 2021-05-19 2022-11-24 Unilever Ip Holdings B.V. Process for preparing a spray dried detergent particle
WO2022243264A1 (en) 2021-05-19 2022-11-24 Unilever Ip Holdings B.V. Process for preparing a spray dried detergent particle
US11542428B2 (en) 2019-12-31 2023-01-03 Advansix Resins & Chemicals Llc Surfactants for oil and gas production
US11571377B2 (en) 2019-12-19 2023-02-07 Advansix Resins & Chemicals Llc Surfactants for use in personal care and cosmetic products
US11633481B2 (en) 2019-12-20 2023-04-25 Advansix Resins & Chemicals Llc Surfactants for use in healthcare products
US11905304B2 (en) 2019-12-19 2024-02-20 Advansix Resins & Chemicals Llc Surfactants for agricultural products
US11952394B2 (en) 2019-08-22 2024-04-09 Advansix Resins & Chemicals Llc Siloxane derivatives of amino acids having surface-active properties

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AT330930B (en) * 1973-04-13 1976-07-26 Henkel & Cie Gmbh PROCESS FOR THE PRODUCTION OF SOLID, SPILLABLE DETERGENTS OR CLEANING AGENTS WITH A CONTENT OF CALCIUM BINDING SUBSTANCES
AR208392A1 (en) * 1973-05-07 1976-12-27 Henkel & Cie Gmbh COMPOSITION TO WASH, WHITE OR CLEAN RESISTANT MATERIALS, ESPECIALLY TEXTILES ADDITIONAL TO PATENT NO 201687 ADDITIONAL TO NO 253286
US4136051A (en) * 1974-02-25 1979-01-23 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Pourable washing compositions containing a luminosilicates and non-ionics and method for their preparation
AT335590B (en) * 1974-08-29 1977-03-25 Henkel & Cie Gmbh LIQUID TO PASTE DETERGENT AND CLEANING AGENT CONCENTRATE AND METHOD OF MANUFACTURING
US4427410A (en) 1974-09-06 1984-01-24 Colgate-Palmolive Company Fabric softening composition containing molecular sieve zeolite
CA1058040A (en) * 1974-09-06 1979-07-10 Colgate-Palmolive Company Molecular sieve zeolite-built detergent paste
US4019998A (en) * 1974-09-27 1977-04-26 The Procter & Gamble Company Process for preparing a pyrophosphate-silicate detergent product
US4184975A (en) * 1974-10-03 1980-01-22 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Pourable agglomerated aluminosilicate builder compositions for washing and cleansing agents
US4000080A (en) * 1974-10-11 1976-12-28 The Procter & Gamble Company Low phosphate content detergent composition
AR205228A1 (en) * 1974-11-08 1976-04-12 Huber Corp J M PROCEDURE TO PRODUCE AN AMORPHOUS ALKALINE METAL ALUMINOSILICATE PIGMENT WITH ION EXCHANGE CAPACITY
US4007124A (en) * 1975-02-14 1977-02-08 The Procter & Gamble Company Process for preparing a silicate-pyrophosphate detergent composition
DE2510676C3 (en) * 1975-03-12 1982-04-22 Degussa Ag, 6000 Frankfurt Process for the production of a crystalline, ion-exchanging alkali aluminum silicate with a hydrophilic surface
DE2510675C3 (en) * 1975-03-12 1983-12-15 Degussa Ag, 6000 Frankfurt Process for the production of a crystalline, ion-exchanging alkali aluminum silicate with a hydrophilic surface and its use
US4019999A (en) * 1975-07-23 1977-04-26 The Procter & Gamble Co. Spray-dried granular detergent containing aluminosilicate, silicate, and pyrophosphate
US4041135A (en) * 1975-07-25 1977-08-09 J. M. Huber Corporation Production of high capacity inorganic crystalline base exchange materials
JPS5851992B2 (en) * 1975-11-27 1983-11-19 ミズサワカガクコウギヨウ カブシキガイシヤ Senzai Builder Oyobi Sono Seihou
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JPS5347408A (en) * 1976-10-13 1978-04-27 Mizusawa Industrial Chem Detergent builder and preparation thereof
ZA767282B (en) * 1975-12-15 1978-07-26 Colgate Palmolive Co Laundry detergent composition and use
US4096081A (en) * 1976-02-06 1978-06-20 The Procter & Gamble Company Detergent compositions containing aluminosilicate agglomerates
CA1102653A (en) * 1976-03-25 1981-06-09 Tom H. Ohren Detergent composition
DE2651437A1 (en) * 1976-11-11 1978-05-18 Degussa TYPE A VI CRYSTALLINE ZEOLITE POWDER
DE2651420A1 (en) * 1976-11-11 1978-05-18 Degussa TYPE A V CRYSTALLINE ZEOLITE POWDER
DE2651436A1 (en) * 1976-11-11 1978-05-18 Degussa TYPE A III CRYSTALLINE ZEOLITE POWDER
DE2651445A1 (en) * 1976-11-11 1978-05-18 Degussa TYPE A II CRYSTALLINE ZEOLITE POWDER
DE2651419A1 (en) * 1976-11-11 1978-05-18 Degussa TYPE A IV CRYSTALLINE ZEOLITE POWDER
US4409136A (en) * 1977-01-31 1983-10-11 Colgate Palmolive Company Molecular sieve zeolite-built detergent paste
JPS53141308A (en) * 1977-05-17 1978-12-09 Mizusawa Industrial Chem Detergent compositions appropriate to wash water containing magnesium as hardness component
US4094778A (en) * 1977-06-27 1978-06-13 Union Carbide Corporation Sequestering of CA++ and MG++ in aqueous media using zeolite mixtures
US4180485A (en) * 1977-11-02 1979-12-25 The Procter & Gamble Company Spray-dried detergent compositions
US4303556A (en) * 1977-11-02 1981-12-01 The Procter & Gamble Company Spray-dried detergent compositions
US4213874A (en) * 1978-01-27 1980-07-22 J. M. Huber Corporation Synthetic amorphous sodium aluminosilicate base exchange materials
US4261941A (en) * 1979-06-26 1981-04-14 Union Carbide Corporation Process for preparing zeolite-containing detergent agglomerates
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Cited By (66)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4405483A (en) * 1982-04-27 1983-09-20 The Procter & Gamble Company Stable liquid detergents containing aluminosilicate ion exchange material
US4929380A (en) * 1986-06-27 1990-05-29 Henkel Kommanditgesellschaft Aug Aktien Process for the preparation of a storage-stable liquid detergent composition
US5536432A (en) * 1993-11-02 1996-07-16 Lever Brothers Company, Division Of Conopco, Inc. Process for the production of a detergent composition
EP0684303A2 (en) 1994-05-27 1995-11-29 Unilever Plc Detergent compositions
US5641741A (en) * 1994-08-26 1997-06-24 Lever Brothers Company, Division Of Conopco, Inc. Production of anionic surfactant granules by in situ neutralization
US5646107A (en) * 1994-08-26 1997-07-08 Lever Brothers Company, Division Of Conopco, Inc. Production of anionic surfactant granules
USRE37949E1 (en) 1994-08-26 2002-12-31 Lever Brothers Company, Division Of Conopco, Inc. Production of anionic surfactant granules by in situ neutralization
US5789365A (en) * 1995-11-30 1998-08-04 Lever Brothers Division Of Conopco Inc. Detergent compositions containing soil release polymers
US5789367A (en) * 1995-11-30 1998-08-04 Lever Brothers Company, Division Of Conopco, Inc. Detergent compositions containing soil release polymers
US5789366A (en) * 1995-11-30 1998-08-04 Lever Brothers Company, Division Of Conopco, Inc. Detergent compositions containing soil release polymers
EP0779358A2 (en) 1995-12-16 1997-06-18 Unilever Plc Detergent composition
EP0786516A2 (en) 1996-01-25 1997-07-30 Unilever N.V. Liquid detergent
EP0786515A2 (en) 1996-01-25 1997-07-30 Unilever N.V. Prewash stain remover composition with siloxane based surfactant
US5856294A (en) * 1996-02-26 1999-01-05 Lever Brothers Company, Division Of Conopco, Inc. Production of anionic detergent particles
USRE36593E (en) * 1996-02-26 2000-02-29 Lever Brothers Company Production of anionic detergent particles
US5976397A (en) * 1996-09-26 1999-11-02 Lever Brothers Company Photofading inhibitor derivatives and their use in fabric treatment compositions
US6303558B1 (en) 1997-05-30 2001-10-16 Lever Brothers Co., Division Of Conopco Detergent composition containing at least two granular components
US6069124A (en) * 1997-05-30 2000-05-30 Lever Brothers Company Division Of Conopco, Inc. Granular detergent compositions and their production
US6191095B1 (en) 1997-05-30 2001-02-20 Lever Brothers Company, A Division Of Conopco, Inc. Detergent compositions
US6221831B1 (en) 1997-05-30 2001-04-24 Lever Brothers Company, Division Of Conopco, Inc. Free flowing detergent composition containing high levels of surfactant
US6056905A (en) * 1997-06-16 2000-05-02 Lever Brothers Company Division Of Conopco, Inc. Production of detergent granulates
US6429184B1 (en) 1997-06-16 2002-08-06 Lever & Brothers Company, Division Of Conopco, Inc. Production of detergent granulates
US6274544B1 (en) 1997-06-16 2001-08-14 Lever Brothers Company, Division Of Conopco, Inc. Production of detergent granulates
US6133223A (en) * 1997-06-27 2000-10-17 Lever Brothers Company, Division Of Conopco, Inc. Production of detergent granulates
US6362156B1 (en) 1998-12-16 2002-03-26 Unilever Home & Personal Care, Usa, Division Of Conopco, Inc. Pourable transparent/translucent liquid detergent composition with suspended particles
US6369018B1 (en) 1998-12-16 2002-04-09 Unilever Home & Personal Care, Usa, Division Of Conopco, Inc. Process for preparing pourable, transparent/translucent liquid detergent with non-continuous suspending system
US6258771B1 (en) 1998-12-16 2001-07-10 Unilever Home & Personal Care, Usa Division Of Conopco Process for preparing pourable, transparent/translucent liquid detergent with non-continuous suspending system
US6159918A (en) * 1998-12-16 2000-12-12 Unilever Home & Personal Care U.S.A., Division Of Conopco, Inc. Transparent/translucent liquid enzyme compositions in clear bottles comprising UV absorber
US6630437B1 (en) 1998-12-16 2003-10-07 Unilever Home & Personal Care Usa , Division Of Conopco, Inc. Transparent/translucent liquid compositions in clear bottles comprising colorant and fluorescent dye or UV absorber
US6051541A (en) * 1998-12-16 2000-04-18 Unilever Home & Personal Care, Division Of Conopco, Inc. Process for preparing pourable, transparent/translucent liquid detergent with continuous suspending system
US6716807B2 (en) 2000-12-29 2004-04-06 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Detergent compositions
US6730649B2 (en) 2000-12-29 2004-05-04 Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. Detergent compositions
EP2330178A2 (en) 2001-11-09 2011-06-08 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Polymers for laundry applications
EP2650353A2 (en) 2002-12-23 2013-10-16 Basf Se Laundry care products containing hydrophobically modified polymers as additives
US7867970B2 (en) 2003-06-16 2011-01-11 The Sun Products Corporation Detergent composition comprising lauric soap
EP1702975A1 (en) 2005-03-15 2006-09-20 Unilever N.V. Laundry detergent with polyamine mono-anionic surfactant
EP2319910A2 (en) 2005-12-02 2011-05-11 Unilever PLC Improvements relating to fabric treatment compositions
WO2010105922A1 (en) 2009-03-19 2010-09-23 Unilever Plc Improvements relating to benefit agent delivery
WO2011072968A1 (en) 2009-12-14 2011-06-23 Unilever Plc Measured dosing cap assembly
WO2012007438A1 (en) 2010-07-15 2012-01-19 Unilever Plc Benefit delivery particle, process for preparing said particle, compositions comprising said particles and a method for treating substrates
WO2012084426A1 (en) 2010-12-22 2012-06-28 Unilever Nv Enzymatic laundry detergent composition for the promotion of hygiene and the prevention of malodour
WO2013087549A1 (en) 2011-12-16 2013-06-20 Unilever Plc Improvements relating to fabric treatment compositions
WO2014075956A1 (en) 2012-11-19 2014-05-22 Unilever Plc Improvements relating to encapsulated benefit agents
WO2016057623A1 (en) 2014-10-07 2016-04-14 The Procter & Gamble Company Method of pre-treating articles to be washed in a dishwashing machine
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AU7128874A (en) 1976-01-22
FR2237839B1 (en) 1977-10-07
IE39618B1 (en) 1978-11-22
IE39618L (en) 1975-01-16
JPS6052192B2 (en) 1985-11-18
JPS5070409A (en) 1975-06-11
DE2433485A1 (en) 1975-02-06
FR2237839A1 (en) 1975-02-14

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