GB1354989A - Compositions for stabilizing solutions of peroxy compounds - Google Patents

Compositions for stabilizing solutions of peroxy compounds

Info

Publication number
GB1354989A
GB1354989A GB2594172A GB2594172A GB1354989A GB 1354989 A GB1354989 A GB 1354989A GB 2594172 A GB2594172 A GB 2594172A GB 2594172 A GB2594172 A GB 2594172A GB 1354989 A GB1354989 A GB 1354989A
Authority
GB
United Kingdom
Prior art keywords
acid
peroxide
silicate
salt
stabiliser
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2594172A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1354989A publication Critical patent/GB1354989A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3902Organic or inorganic per-compounds combined with specific additives
    • C11D3/3937Stabilising agents
    • C11D3/394Organic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/12Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

1354989 Stabilised bleaching compositions for organic materials MONSANTO CO 2 June 1972 [3 June 1971 (3)] 25941/72 Heading D1P A stabilising agent for reducing the decomposition of a peroxy compound comprises (a) 1-hydroxy ethylidene-1, I diphosphonic acid or water-soluble salt thereof, (b) nitrilotriacetic acid or a water-soluble salt thereof and (c) a water soluble salt which is a magnesium salt or a calcium salt. Preferably the mole ratio (a) to (b) to (c) is from 1:1:1 to 1:5:3. Alternatively the calcium or magnesium salt may be of acid (a) or acid (b). The agent is used at a concentration of 0.001 to 5% by weight to stabilise aqueous solutions containing 0.01 to 5% by weight of hydrogen peroxide, sodium peroxide, potassium peroxide, urea percompounds, perborates, persulphates, persulphuric acid, peracetic acid, peroxy monophosphoric acid or the sodium, potassium, ammonium or organic amine salts of the above peracids. The solutions also contain sodium silicate and are used to bleach textile materials at a temperature of 20‹C to 300‹F for 20 seconds to 36 hours at a pH of 7.5 to 12.5. Fluorescent brighteners and surfactants / wetting agents may also be included. A dry mixture of perborate and stabiliser is conveniently stored. It is suggested that metal ions such as ferrous which would decompose the peroxide are trapped by a magnesium and or calcium silicate complex. The function of the first two components of the stabiliser is to prevent precipitation of the silicate. The textile material may comprise fibres of cotton, hemp, jute, linen, viscose rayon, nylon, polyester or blends thereof. The stabilisation of the peroxide against metal ion catalysed decomposition to oxygen protects cellulose fibres against attack by oxygen in the alkaline media. The treatment of the textile may involve the steps of singeing, de-sizing, scouring, bleaching with an alkaline aqueous solution containing an alkali metal silicate and the stabiliser, scouring, mercerizing and dyeing or printing.
GB2594172A 1971-06-03 1972-06-02 Compositions for stabilizing solutions of peroxy compounds Expired GB1354989A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14985671A 1971-06-03 1971-06-03
US14985471A 1971-06-03 1971-06-03
US14985571A 1971-06-03 1971-06-03

Publications (1)

Publication Number Publication Date
GB1354989A true GB1354989A (en) 1974-06-05

Family

ID=27386881

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2594172A Expired GB1354989A (en) 1971-06-03 1972-06-02 Compositions for stabilizing solutions of peroxy compounds

Country Status (7)

Country Link
US (3) US3740187A (en)
JP (1) JPS5652080B1 (en)
DE (1) DE2226784C3 (en)
ES (1) ES403436A1 (en)
FR (1) FR2140213B1 (en)
GB (1) GB1354989A (en)
IT (1) IT956067B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2617182A1 (en) * 1987-06-26 1988-12-30 Sandoz Sa CONCENTRATED COMPOSITIONS AND THEIR USE AS STABILIZERS FOR ALKALINE PEROXIDE BATHS

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE795085A (en) * 1972-03-10 1973-05-29 Benckiser Knapsack Gmbh PROCESS FOR BLEACHING CELLULOSIC FIBERS SINGLE OR IN MIXTURE WITH SYNTHETIC FIBERS
US3951594A (en) * 1972-11-27 1976-04-20 Pennwalt Corporation Hydrogen peroxide bleaching solutions and process
JPS5313198B2 (en) * 1973-04-26 1978-05-08
US3951838A (en) * 1973-10-10 1976-04-20 E. I. Du Pont De Nemours And Company Silica sol stabilizers for improving the stability of sodium percarbonate in solid bleaches and detergents
FR2253823B1 (en) * 1973-12-11 1977-06-10 Colgate Palmolive Co
DE2506799B2 (en) * 1975-02-18 1977-03-31 Basf Ag, 6700 Ludwigshafen PROCESS FOR STABILIZING PEROXIDE STABILIZERS CONTAINING PEROXIDE BLEACHING FLATS CONTAINING ALKALINE, SILICATE AND EARTH ALKALIMETAL
LU74434A1 (en) * 1976-02-25 1977-09-12
CA1088726A (en) * 1976-06-09 1980-11-04 Carl L. Wright Carbonate leaching of uranium
US4302429A (en) * 1976-11-08 1981-11-24 E. I. Du Pont De Nemours And Company Process for solution mining of uranium ores
AT352241B (en) * 1977-04-22 1979-09-10 Henkel Kgaa POWDERED, PHOSPHATE-FREE TEXTILE DETERGENT
US4316879A (en) * 1977-06-17 1982-02-23 Fmc Corporation Stabilized sodium carbonate peroxide preparation method
US4497725A (en) * 1980-04-01 1985-02-05 Interox Chemicals Ltd. Aqueous bleach compositions
FR2493294A1 (en) * 1980-11-04 1982-05-07 Air Liquide STABILIZING COMPOSITIONS FOR PEROXIDE PRODUCTS
FR2503746A1 (en) * 1981-04-09 1982-10-15 Air Liquide ACTIVE BINDERING COMPOSITION USING PEROXIDE PRODUCTS
US4496472A (en) * 1981-12-23 1985-01-29 Ciba-Geigy Corporation Process for bleaching cellulosic fibre materials using oligomers of phosphonic acid esters as stabilizers in alkaline, peroxide-containing bleaching liquors
US4470919A (en) * 1982-02-03 1984-09-11 The Procter & Gamble Company Oxygen-bleach-containing liquid detergent compositions
US4529534A (en) * 1982-08-19 1985-07-16 The Procter & Gamble Company Peroxyacid bleach compositions
US4515597A (en) * 1982-12-10 1985-05-07 Ciba Geigy Corporation Magnesium complexes of oligomeric phosphonic acid esters, a process for their preparation and their use as stabilizers in alkaline, peroxide-containing bleach liquors
DE3338260C1 (en) * 1983-10-21 1985-07-25 Benckiser-Knapsack Gmbh, 6802 Ladenburg Process and means for bleaching groundwood
US4623356A (en) * 1984-11-06 1986-11-18 Spring Industries, Inc. Oxidative afterwash treatment for non-formaldehyde durable press finishing process
FR2573452B1 (en) * 1984-11-21 1987-03-06 Atochem HOUSEHOLD LAUNDRY LAUNDRY PROCESS IN A HOUSEHOLD WASHING CYCLE
US4623357A (en) * 1985-04-02 1986-11-18 Lever Brothers Company Bleach compositions
US4725281A (en) * 1985-07-19 1988-02-16 Ciba-Geigy Corporation Aqueous alkaline, silicate-containing composition and the use thereof for bleaching cellulosic fiber materials in the presence of per compounds
US4772290A (en) * 1986-03-10 1988-09-20 Clorox Company Liquid hydrogen peroxide/peracid precursor bleach: acidic aqueous medium containing solid peracid precursor activator
FR2598727B1 (en) * 1986-05-15 1990-02-02 Atochem METHOD AND COMPOSITION FOR THE BLEACHING OF DOMESTIC LAUNDRY
DE3720806C2 (en) * 1986-07-03 1997-08-21 Clariant Finance Bvi Ltd Use of a stabilizer in peroxide bleaching processes
US4900469A (en) * 1986-10-21 1990-02-13 The Clorox Company Thickened peracid precursor compositions
US4963157A (en) * 1987-04-17 1990-10-16 Nippon Peroxide Co., Ltd. Method for bleaching cellulosic fiber material with hydrogen peroxide
DE3720277A1 (en) * 1987-06-19 1988-12-29 Degussa METHOD FOR REDUCING THE TENSION TO BAKING UP PARTICULATE ACTIVE OXYGEN COMPOUNDS
DE3737890A1 (en) * 1987-11-07 1989-05-18 Basf Ag METHOD FOR PRE-TREATING TEXTILE MATERIALS
US5019289A (en) * 1988-11-25 1991-05-28 The Clorox Company Stable liquid detergent containing insoluble oxidant
US4915785A (en) * 1988-12-23 1990-04-10 C-I-L Inc. Single stage process for bleaching of pulp with an aqueous hydrogen peroxide bleaching composition containing magnesium sulphate and sodium silicate
GB8904007D0 (en) * 1989-02-22 1989-04-05 Procter & Gamble Stabilized,bleach containing,liquid detergent compositions
GB8925376D0 (en) * 1989-11-09 1989-12-28 Interox Chemicals Ltd Stabilisation of concentrated hydrogen peroxide solutions
DE4203797A1 (en) * 1992-02-10 1993-08-12 Bayer Ag BLEACH REGULATOR COMPOSITIONS AND BLEACHING METHOD THEREFOR
US5482516A (en) * 1993-05-24 1996-01-09 Surry Chemicals, Inc. Process for bleaching textiles
US5464563A (en) * 1993-08-25 1995-11-07 Burlington Chemical Co., Inc. Bleaching composition
US5616280A (en) * 1993-08-25 1997-04-01 Burlington Chemical Co., Inc. Bleaching composition
WO1996002624A1 (en) * 1994-07-13 1996-02-01 So-Safe Specialty Products Pty. Ltd. A cleaning kit and a cleaning composition and methods of use
EP0905226A1 (en) * 1997-09-19 1999-03-31 The Procter & Gamble Company The use of phosphonate compounds in hypochlorite bleaching compositions for treating textiles, for fabric whiteness and safety
DK1903081T3 (en) * 2006-09-19 2015-03-23 Poligrat Gmbh Stabilizer for acidic, metal-containing polishes
US8034759B2 (en) * 2008-10-31 2011-10-11 Ecolab Usa Inc. Enhanced stability peracid compositions
US9052289B2 (en) * 2010-12-13 2015-06-09 Schlumberger Technology Corporation Hydrogen sulfide (H2S) detection using functionalized nanoparticles
US8557178B2 (en) 2010-12-21 2013-10-15 Ecolab Usa Inc. Corrosion inhibition of hypochlorite solutions in saturated wipes
US8114344B1 (en) 2010-12-21 2012-02-14 Ecolab Usa Inc. Corrosion inhibition of hypochlorite solutions using sugar acids and Ca
US8603392B2 (en) 2010-12-21 2013-12-10 Ecolab Usa Inc. Electrolyzed water system
CN109868659A (en) * 2018-11-13 2019-06-11 江苏豪申家纺布艺科技有限公司 A kind of dyeing and finishing processing method promoting grey colour system activity dyeing fabric colour fastness to perspiration
US11905498B2 (en) 2020-02-12 2024-02-20 Ecolab Usa Inc. Use of urea or a urea/chelator combination to chemically stabilize peroxycarboxylic acid and peroxide formulations

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL60878C (en) * 1913-07-07
NL112774C (en) * 1953-03-12
DE1113931B (en) * 1958-02-17 1961-09-21 Prod Chim Et De Synthese Soc D Process for stabilizing bleaching solutions containing hydrogen peroxide
NL252116A (en) * 1959-06-03
US3356613A (en) * 1966-09-27 1967-12-05 Procter & Gamble Built detergent compositions containing a synergistic mixture of stp, nta, and sodium silicate
US3392121A (en) * 1962-11-05 1968-07-09 Procter & Gamble Built detergent compositions
US3234140A (en) * 1964-06-05 1966-02-08 Monsanto Co Stabilization of peroxy solutions
US3368978A (en) * 1964-12-28 1968-02-13 Monsanto Co Builder compositions and detergent compositions using same
US3384596A (en) * 1965-12-30 1968-05-21 Dow Chemical Co Peroxy acid bleaching systems
FR1526014A (en) * 1966-03-21 1968-05-24 Monsanto Co Laundry or laundry compositions containing oxygen releasing compounds
GB1209486A (en) * 1966-12-16 1970-10-21 Monsanto Co Phosporus-containing organic compounds
DE1594864A1 (en) * 1967-07-29 1971-05-13 Henkel & Cie Gmbh Process for bleaching and optionally washing textiles and means for carrying out the process
US3558497A (en) * 1967-08-03 1971-01-26 Du Pont Laundry detergent compositions containing a perborate and a peroxymonopersulfate
NL136358C (en) * 1967-12-20
DE1812382A1 (en) * 1968-12-03 1970-12-10 Henkel & Cie Gmbh Abrasives with a bleaching and disinfecting effect
DE1816347A1 (en) * 1968-12-21 1970-06-25 Henkel & Cie Gmbh Detergent for textiles made from synthetic fibers
US3579287A (en) * 1969-06-11 1971-05-18 Monsanto Co Bleaching process
DK132506A (en) * 1969-10-02

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2617182A1 (en) * 1987-06-26 1988-12-30 Sandoz Sa CONCENTRATED COMPOSITIONS AND THEIR USE AS STABILIZERS FOR ALKALINE PEROXIDE BATHS
GB2206903A (en) * 1987-06-26 1989-01-18 Sandoz Ltd Stabilisers for peroxide-containing bleaching liquors
GB2206903B (en) * 1987-06-26 1991-03-20 Sandoz Ltd Concentrated compositions and their use as stabilizers for peroxide-containing alkaline liquors

Also Published As

Publication number Publication date
US3740187A (en) 1973-06-19
ES403436A1 (en) 1975-12-01
DE2226784C3 (en) 1986-04-17
FR2140213A1 (en) 1973-01-12
IT956067B (en) 1973-10-10
DE2226784B2 (en) 1978-08-10
JPS5652080B1 (en) 1981-12-09
US3766078A (en) 1973-10-16
DE2226784A1 (en) 1972-12-14
FR2140213B1 (en) 1977-12-23
US3795625A (en) 1974-03-05

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee