GB1354989A - Compositions for stabilizing solutions of peroxy compounds - Google Patents
Compositions for stabilizing solutions of peroxy compoundsInfo
- Publication number
- GB1354989A GB1354989A GB2594172A GB2594172A GB1354989A GB 1354989 A GB1354989 A GB 1354989A GB 2594172 A GB2594172 A GB 2594172A GB 2594172 A GB2594172 A GB 2594172A GB 1354989 A GB1354989 A GB 1354989A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- peroxide
- silicate
- salt
- stabiliser
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3937—Stabilising agents
- C11D3/394—Organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
1354989 Stabilised bleaching compositions for organic materials MONSANTO CO 2 June 1972 [3 June 1971 (3)] 25941/72 Heading D1P A stabilising agent for reducing the decomposition of a peroxy compound comprises (a) 1-hydroxy ethylidene-1, I diphosphonic acid or water-soluble salt thereof, (b) nitrilotriacetic acid or a water-soluble salt thereof and (c) a water soluble salt which is a magnesium salt or a calcium salt. Preferably the mole ratio (a) to (b) to (c) is from 1:1:1 to 1:5:3. Alternatively the calcium or magnesium salt may be of acid (a) or acid (b). The agent is used at a concentration of 0.001 to 5% by weight to stabilise aqueous solutions containing 0.01 to 5% by weight of hydrogen peroxide, sodium peroxide, potassium peroxide, urea percompounds, perborates, persulphates, persulphuric acid, peracetic acid, peroxy monophosphoric acid or the sodium, potassium, ammonium or organic amine salts of the above peracids. The solutions also contain sodium silicate and are used to bleach textile materials at a temperature of 20C to 300F for 20 seconds to 36 hours at a pH of 7.5 to 12.5. Fluorescent brighteners and surfactants / wetting agents may also be included. A dry mixture of perborate and stabiliser is conveniently stored. It is suggested that metal ions such as ferrous which would decompose the peroxide are trapped by a magnesium and or calcium silicate complex. The function of the first two components of the stabiliser is to prevent precipitation of the silicate. The textile material may comprise fibres of cotton, hemp, jute, linen, viscose rayon, nylon, polyester or blends thereof. The stabilisation of the peroxide against metal ion catalysed decomposition to oxygen protects cellulose fibres against attack by oxygen in the alkaline media. The treatment of the textile may involve the steps of singeing, de-sizing, scouring, bleaching with an alkaline aqueous solution containing an alkali metal silicate and the stabiliser, scouring, mercerizing and dyeing or printing.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14985671A | 1971-06-03 | 1971-06-03 | |
US14985471A | 1971-06-03 | 1971-06-03 | |
US14985571A | 1971-06-03 | 1971-06-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1354989A true GB1354989A (en) | 1974-06-05 |
Family
ID=27386881
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2594172A Expired GB1354989A (en) | 1971-06-03 | 1972-06-02 | Compositions for stabilizing solutions of peroxy compounds |
Country Status (7)
Country | Link |
---|---|
US (3) | US3740187A (en) |
JP (1) | JPS5652080B1 (en) |
DE (1) | DE2226784C3 (en) |
ES (1) | ES403436A1 (en) |
FR (1) | FR2140213B1 (en) |
GB (1) | GB1354989A (en) |
IT (1) | IT956067B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2617182A1 (en) * | 1987-06-26 | 1988-12-30 | Sandoz Sa | CONCENTRATED COMPOSITIONS AND THEIR USE AS STABILIZERS FOR ALKALINE PEROXIDE BATHS |
Families Citing this family (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE795085A (en) * | 1972-03-10 | 1973-05-29 | Benckiser Knapsack Gmbh | PROCESS FOR BLEACHING CELLULOSIC FIBERS SINGLE OR IN MIXTURE WITH SYNTHETIC FIBERS |
US3951594A (en) * | 1972-11-27 | 1976-04-20 | Pennwalt Corporation | Hydrogen peroxide bleaching solutions and process |
JPS5313198B2 (en) * | 1973-04-26 | 1978-05-08 | ||
US3951838A (en) * | 1973-10-10 | 1976-04-20 | E. I. Du Pont De Nemours And Company | Silica sol stabilizers for improving the stability of sodium percarbonate in solid bleaches and detergents |
FR2253823B1 (en) * | 1973-12-11 | 1977-06-10 | Colgate Palmolive Co | |
DE2506799B2 (en) * | 1975-02-18 | 1977-03-31 | Basf Ag, 6700 Ludwigshafen | PROCESS FOR STABILIZING PEROXIDE STABILIZERS CONTAINING PEROXIDE BLEACHING FLATS CONTAINING ALKALINE, SILICATE AND EARTH ALKALIMETAL |
LU74434A1 (en) * | 1976-02-25 | 1977-09-12 | ||
CA1088726A (en) * | 1976-06-09 | 1980-11-04 | Carl L. Wright | Carbonate leaching of uranium |
US4302429A (en) * | 1976-11-08 | 1981-11-24 | E. I. Du Pont De Nemours And Company | Process for solution mining of uranium ores |
AT352241B (en) * | 1977-04-22 | 1979-09-10 | Henkel Kgaa | POWDERED, PHOSPHATE-FREE TEXTILE DETERGENT |
US4316879A (en) * | 1977-06-17 | 1982-02-23 | Fmc Corporation | Stabilized sodium carbonate peroxide preparation method |
US4497725A (en) * | 1980-04-01 | 1985-02-05 | Interox Chemicals Ltd. | Aqueous bleach compositions |
FR2493294A1 (en) * | 1980-11-04 | 1982-05-07 | Air Liquide | STABILIZING COMPOSITIONS FOR PEROXIDE PRODUCTS |
FR2503746A1 (en) * | 1981-04-09 | 1982-10-15 | Air Liquide | ACTIVE BINDERING COMPOSITION USING PEROXIDE PRODUCTS |
US4496472A (en) * | 1981-12-23 | 1985-01-29 | Ciba-Geigy Corporation | Process for bleaching cellulosic fibre materials using oligomers of phosphonic acid esters as stabilizers in alkaline, peroxide-containing bleaching liquors |
US4470919A (en) * | 1982-02-03 | 1984-09-11 | The Procter & Gamble Company | Oxygen-bleach-containing liquid detergent compositions |
US4529534A (en) * | 1982-08-19 | 1985-07-16 | The Procter & Gamble Company | Peroxyacid bleach compositions |
US4515597A (en) * | 1982-12-10 | 1985-05-07 | Ciba Geigy Corporation | Magnesium complexes of oligomeric phosphonic acid esters, a process for their preparation and their use as stabilizers in alkaline, peroxide-containing bleach liquors |
DE3338260C1 (en) * | 1983-10-21 | 1985-07-25 | Benckiser-Knapsack Gmbh, 6802 Ladenburg | Process and means for bleaching groundwood |
US4623356A (en) * | 1984-11-06 | 1986-11-18 | Spring Industries, Inc. | Oxidative afterwash treatment for non-formaldehyde durable press finishing process |
FR2573452B1 (en) * | 1984-11-21 | 1987-03-06 | Atochem | HOUSEHOLD LAUNDRY LAUNDRY PROCESS IN A HOUSEHOLD WASHING CYCLE |
US4623357A (en) * | 1985-04-02 | 1986-11-18 | Lever Brothers Company | Bleach compositions |
US4725281A (en) * | 1985-07-19 | 1988-02-16 | Ciba-Geigy Corporation | Aqueous alkaline, silicate-containing composition and the use thereof for bleaching cellulosic fiber materials in the presence of per compounds |
US4772290A (en) * | 1986-03-10 | 1988-09-20 | Clorox Company | Liquid hydrogen peroxide/peracid precursor bleach: acidic aqueous medium containing solid peracid precursor activator |
FR2598727B1 (en) * | 1986-05-15 | 1990-02-02 | Atochem | METHOD AND COMPOSITION FOR THE BLEACHING OF DOMESTIC LAUNDRY |
DE3720806C2 (en) * | 1986-07-03 | 1997-08-21 | Clariant Finance Bvi Ltd | Use of a stabilizer in peroxide bleaching processes |
US4900469A (en) * | 1986-10-21 | 1990-02-13 | The Clorox Company | Thickened peracid precursor compositions |
US4963157A (en) * | 1987-04-17 | 1990-10-16 | Nippon Peroxide Co., Ltd. | Method for bleaching cellulosic fiber material with hydrogen peroxide |
DE3720277A1 (en) * | 1987-06-19 | 1988-12-29 | Degussa | METHOD FOR REDUCING THE TENSION TO BAKING UP PARTICULATE ACTIVE OXYGEN COMPOUNDS |
DE3737890A1 (en) * | 1987-11-07 | 1989-05-18 | Basf Ag | METHOD FOR PRE-TREATING TEXTILE MATERIALS |
US5019289A (en) * | 1988-11-25 | 1991-05-28 | The Clorox Company | Stable liquid detergent containing insoluble oxidant |
US4915785A (en) * | 1988-12-23 | 1990-04-10 | C-I-L Inc. | Single stage process for bleaching of pulp with an aqueous hydrogen peroxide bleaching composition containing magnesium sulphate and sodium silicate |
GB8904007D0 (en) * | 1989-02-22 | 1989-04-05 | Procter & Gamble | Stabilized,bleach containing,liquid detergent compositions |
GB8925376D0 (en) * | 1989-11-09 | 1989-12-28 | Interox Chemicals Ltd | Stabilisation of concentrated hydrogen peroxide solutions |
DE4203797A1 (en) * | 1992-02-10 | 1993-08-12 | Bayer Ag | BLEACH REGULATOR COMPOSITIONS AND BLEACHING METHOD THEREFOR |
US5482516A (en) * | 1993-05-24 | 1996-01-09 | Surry Chemicals, Inc. | Process for bleaching textiles |
US5464563A (en) * | 1993-08-25 | 1995-11-07 | Burlington Chemical Co., Inc. | Bleaching composition |
US5616280A (en) * | 1993-08-25 | 1997-04-01 | Burlington Chemical Co., Inc. | Bleaching composition |
WO1996002624A1 (en) * | 1994-07-13 | 1996-02-01 | So-Safe Specialty Products Pty. Ltd. | A cleaning kit and a cleaning composition and methods of use |
EP0905226A1 (en) * | 1997-09-19 | 1999-03-31 | The Procter & Gamble Company | The use of phosphonate compounds in hypochlorite bleaching compositions for treating textiles, for fabric whiteness and safety |
DK1903081T3 (en) * | 2006-09-19 | 2015-03-23 | Poligrat Gmbh | Stabilizer for acidic, metal-containing polishes |
US8034759B2 (en) * | 2008-10-31 | 2011-10-11 | Ecolab Usa Inc. | Enhanced stability peracid compositions |
US9052289B2 (en) * | 2010-12-13 | 2015-06-09 | Schlumberger Technology Corporation | Hydrogen sulfide (H2S) detection using functionalized nanoparticles |
US8557178B2 (en) | 2010-12-21 | 2013-10-15 | Ecolab Usa Inc. | Corrosion inhibition of hypochlorite solutions in saturated wipes |
US8114344B1 (en) | 2010-12-21 | 2012-02-14 | Ecolab Usa Inc. | Corrosion inhibition of hypochlorite solutions using sugar acids and Ca |
US8603392B2 (en) | 2010-12-21 | 2013-12-10 | Ecolab Usa Inc. | Electrolyzed water system |
CN109868659A (en) * | 2018-11-13 | 2019-06-11 | 江苏豪申家纺布艺科技有限公司 | A kind of dyeing and finishing processing method promoting grey colour system activity dyeing fabric colour fastness to perspiration |
US11905498B2 (en) | 2020-02-12 | 2024-02-20 | Ecolab Usa Inc. | Use of urea or a urea/chelator combination to chemically stabilize peroxycarboxylic acid and peroxide formulations |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL60878C (en) * | 1913-07-07 | |||
NL112774C (en) * | 1953-03-12 | |||
DE1113931B (en) * | 1958-02-17 | 1961-09-21 | Prod Chim Et De Synthese Soc D | Process for stabilizing bleaching solutions containing hydrogen peroxide |
NL252116A (en) * | 1959-06-03 | |||
US3356613A (en) * | 1966-09-27 | 1967-12-05 | Procter & Gamble | Built detergent compositions containing a synergistic mixture of stp, nta, and sodium silicate |
US3392121A (en) * | 1962-11-05 | 1968-07-09 | Procter & Gamble | Built detergent compositions |
US3234140A (en) * | 1964-06-05 | 1966-02-08 | Monsanto Co | Stabilization of peroxy solutions |
US3368978A (en) * | 1964-12-28 | 1968-02-13 | Monsanto Co | Builder compositions and detergent compositions using same |
US3384596A (en) * | 1965-12-30 | 1968-05-21 | Dow Chemical Co | Peroxy acid bleaching systems |
FR1526014A (en) * | 1966-03-21 | 1968-05-24 | Monsanto Co | Laundry or laundry compositions containing oxygen releasing compounds |
GB1209486A (en) * | 1966-12-16 | 1970-10-21 | Monsanto Co | Phosporus-containing organic compounds |
DE1594864A1 (en) * | 1967-07-29 | 1971-05-13 | Henkel & Cie Gmbh | Process for bleaching and optionally washing textiles and means for carrying out the process |
US3558497A (en) * | 1967-08-03 | 1971-01-26 | Du Pont | Laundry detergent compositions containing a perborate and a peroxymonopersulfate |
NL136358C (en) * | 1967-12-20 | |||
DE1812382A1 (en) * | 1968-12-03 | 1970-12-10 | Henkel & Cie Gmbh | Abrasives with a bleaching and disinfecting effect |
DE1816347A1 (en) * | 1968-12-21 | 1970-06-25 | Henkel & Cie Gmbh | Detergent for textiles made from synthetic fibers |
US3579287A (en) * | 1969-06-11 | 1971-05-18 | Monsanto Co | Bleaching process |
DK132506A (en) * | 1969-10-02 |
-
1971
- 1971-06-03 US US00149856A patent/US3740187A/en not_active Expired - Lifetime
- 1971-06-03 US US00149855A patent/US3795625A/en not_active Expired - Lifetime
- 1971-06-03 US US00149854A patent/US3766078A/en not_active Expired - Lifetime
-
1972
- 1972-05-31 IT IT25149/72A patent/IT956067B/en active
- 1972-06-02 JP JP5439872A patent/JPS5652080B1/ja active Pending
- 1972-06-02 ES ES403436A patent/ES403436A1/en not_active Expired
- 1972-06-02 DE DE2226784A patent/DE2226784C3/en not_active Expired
- 1972-06-02 FR FR7219960A patent/FR2140213B1/fr not_active Expired
- 1972-06-02 GB GB2594172A patent/GB1354989A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2617182A1 (en) * | 1987-06-26 | 1988-12-30 | Sandoz Sa | CONCENTRATED COMPOSITIONS AND THEIR USE AS STABILIZERS FOR ALKALINE PEROXIDE BATHS |
GB2206903A (en) * | 1987-06-26 | 1989-01-18 | Sandoz Ltd | Stabilisers for peroxide-containing bleaching liquors |
GB2206903B (en) * | 1987-06-26 | 1991-03-20 | Sandoz Ltd | Concentrated compositions and their use as stabilizers for peroxide-containing alkaline liquors |
Also Published As
Publication number | Publication date |
---|---|
US3740187A (en) | 1973-06-19 |
ES403436A1 (en) | 1975-12-01 |
DE2226784C3 (en) | 1986-04-17 |
FR2140213A1 (en) | 1973-01-12 |
IT956067B (en) | 1973-10-10 |
DE2226784B2 (en) | 1978-08-10 |
JPS5652080B1 (en) | 1981-12-09 |
US3766078A (en) | 1973-10-16 |
DE2226784A1 (en) | 1972-12-14 |
FR2140213B1 (en) | 1977-12-23 |
US3795625A (en) | 1974-03-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |