GB1354357A - Chromatographic packing with chemically bonded organic stationary phases - Google Patents

Chromatographic packing with chemically bonded organic stationary phases

Info

Publication number
GB1354357A
GB1354357A GB1669871A GB1669871A GB1354357A GB 1354357 A GB1354357 A GB 1354357A GB 1669871 A GB1669871 A GB 1669871A GB 1669871 A GB1669871 A GB 1669871A GB 1354357 A GB1354357 A GB 1354357A
Authority
GB
United Kingdom
Prior art keywords
substrate
chemically bonded
monomer
packing
stationary phase
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1669871A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB1354357A publication Critical patent/GB1354357A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/282—Porous sorbents
    • B01J20/283—Porous sorbents based on silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/286—Phases chemically bonded to a substrate, e.g. to silica or to polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3214—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating
    • B01J20/3217—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond
    • B01J20/3219—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond involving a particular spacer or linking group, e.g. for attaching an active group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
    • B01J20/3261—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such comprising a cyclic structure not containing any of the heteroatoms nitrogen, oxygen or sulfur, e.g. aromatic structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3268—Macromolecular compounds
    • B01J20/3272—Polymers obtained by reactions otherwise than involving only carbon to carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3268—Macromolecular compounds
    • B01J20/3276—Copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/22—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
    • C08G83/001—Macromolecular compounds containing organic and inorganic sequences, e.g. organic polymers grafted onto silica

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

1354357 Silanes hydrolysed on to or with an inorganic substrate E I DU PONT DE NEMOURS & CO 24 May 1971 [22 May 1970] 16698/71 Heading C3T [Also in Division B1] A chromatographic packing comprises an organosilicon polymeric (or mixtures thereof to vary the degree of cross-linking) stationary phase chemically bonded to a polyvalent metal or metalloid containing substrate. The polymer has repeating units of the formula where A is -O-, hydroxy, or, as R may be as well, a monovalent aliphatic or aromatic hydrocarbon group or substituted derivative thereof and is chemically bonded to the substrate by an linkage where M is the polyvalent metal or metalloid and is part of one of the repeating units. The stationary phase has an average thickness of from 30-10,000Š and the polymer comprises 5 to 80 per cent of the volume of the stationary phase. The packing is made by contacting the substrate with a solution in an organic solvent, of (i) the monomer where R 3 is OH or R, or (ii) the hydrolysable compound where R 1 and R 2 are alkoxy and R<SP>1</SP> 3 is alkoxy or R 3 other than hydroxy. The solution is heated to cause polymerization and chemical bonding. The heating is carried out in the presence of less water than 100 times the equivalent of the monomer when the solution contains -the hydrolysable compound in order to form the monomer. The substrate may be silica gel, a glass, sand, a diatomaceous earth, quartz, an aluminosilicate, porous silica beads, a clay, a non-alkaline metal oxide or metal having an oxide skin, alumina, thoria, titania, zircona, or the column wall itself. It may be in the form of rings, polyhedra, spheres, saddles, platelets, fibres, hollow tubes, rods or cylinders. The packing may be used in gas, liquid partition or ion-exchange chromatography.
GB1669871A 1970-05-22 1971-05-24 Chromatographic packing with chemically bonded organic stationary phases Expired GB1354357A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US3966570A 1970-05-22 1970-05-22

Publications (1)

Publication Number Publication Date
GB1354357A true GB1354357A (en) 1974-06-05

Family

ID=21906710

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1669871A Expired GB1354357A (en) 1970-05-22 1971-05-24 Chromatographic packing with chemically bonded organic stationary phases

Country Status (8)

Country Link
US (1) US3722181A (en)
JP (2) JPS5217078B1 (en)
CH (1) CH578732A5 (en)
DE (1) DE2125428C2 (en)
FR (1) FR2093601A5 (en)
GB (1) GB1354357A (en)
NL (1) NL7107016A (en)
SE (1) SE399647B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1986004063A1 (en) * 1984-12-28 1986-07-17 Ksv-Chemicals Oy Surface treatment agents and polymers
CN113000028A (en) * 2021-04-27 2021-06-22 临沂海普新材料科技有限公司 Preparation method of adsorbent for recovering phosphoric acid in waste acid

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US3984349A (en) * 1971-07-26 1976-10-05 Societe Rhone-Progil Modified porous bodies
DE2225973C2 (en) * 1972-05-27 1974-07-04 Merck Patent Gmbh, 6100 Darmstadt Process for coating non-porous material with a porous silicon dioxide layer
US3878092A (en) * 1973-03-12 1975-04-15 Phillips Petroleum Co Chromatographic colums
US3983299A (en) * 1974-03-04 1976-09-28 Purdue Research Foundation Bonded carbohydrate stationary phases for chromatography
JPS5247355B2 (en) * 1974-10-15 1977-12-01
GB1527598A (en) * 1974-11-12 1978-10-04 Dow Corning Ltd Catalysts and carriers therefor
US3987058A (en) * 1975-02-27 1976-10-19 The United States Of America As Represented By The Secretary Of Agriculture Preparation and uses of stable, bound stationary phases
US4029583A (en) * 1975-02-28 1977-06-14 Purdue Research Foundation Chromatographic supports and methods and apparatus for preparing the same
US4169790A (en) * 1975-05-02 1979-10-02 South African Inventions Development Corporation Solid surface texture suitable for a stationary phase for chromatography
US4140653A (en) * 1975-09-30 1979-02-20 Toyo Soda Manufacturing Co., Ltd. Solid support for liquid chromatography
US4118316A (en) * 1976-10-13 1978-10-03 Calgon Corporation Quaternized siliceous supports for gel permeation chromatography
JPS5489691A (en) * 1977-12-24 1979-07-16 Nippon Bunko Kogyo Kk Open tube type capillary column for micro rapid liquid chromatography and production thereof
US4199330A (en) * 1978-02-13 1980-04-22 The Dow Chemical Company Bonded organo-pellicular packings for chromatographic columns
US4243753A (en) * 1978-02-27 1981-01-06 Purdue Research Foundation Apparatus for enzyme detection
US4209554A (en) * 1979-02-22 1980-06-24 Scm Corporation Polydentate metal salts used in the process for the deactivation of glass surfaces and capillary columns therewith
US4242227A (en) * 1979-07-31 1980-12-30 The Dow Chemical Company Chromatographic column packing having a bonded organosiloxane coating
US4324689A (en) * 1980-02-26 1982-04-13 Shah Ramesh M High carbon content chromatographic packing and method for making same
US4737316A (en) * 1982-11-24 1988-04-12 Pedro B. Macedo Purification of contaminated liquid
US4591455A (en) * 1982-11-24 1986-05-27 Pedro B. Macedo Purification of contaminated liquid
US4648975A (en) * 1983-08-17 1987-03-10 Pedro B. Macedo Process of using improved silica-based chromatographic supports containing additives
US4540486A (en) * 1983-11-25 1985-09-10 J. T. Baker Chemical Company Polyethylenimine bound chromatographic packing
DE3427923A1 (en) * 1984-07-28 1986-01-30 Merck Patent Gmbh, 6100 Darmstadt SEPARATING MATERIAL FOR THICK LAYER CHROMATOGRAPHY
US4755294A (en) * 1984-11-06 1988-07-05 Societe Anonyme Dite Compagnie Francaise De Raffinage Stationary phase, preparation thereof and chromatographic column containing same
JPS61210956A (en) * 1985-03-15 1986-09-19 Cosmo Co Ltd Thin layer bar for chromatography
US4551245A (en) * 1985-04-22 1985-11-05 J. T. Baker Chemical Co. Acylated polyethylenimine bound chromatographic packing
US4743377A (en) * 1985-07-02 1988-05-10 Shiseido Company Ltd. Packing material for liquid chromatography
US5032266A (en) * 1985-11-01 1991-07-16 E. I. Du Pont De Nemours And Company Porous silica microspheres having silanol-enriched and silanized surfaces
US4874518A (en) * 1985-11-01 1989-10-17 E. I. Du Pont De Nemours And Company Porous silica microspheres having a silanol enriched surface
US5108595A (en) * 1985-11-01 1992-04-28 E. I. Du Pont De Nemours And Company Porous silica microspheres having silanol-enriched and silanized surfaces
GB8618322D0 (en) * 1986-07-28 1986-09-03 3I Res Expl Ltd Bonded chromotographic stationary phase
US4705725A (en) * 1986-11-28 1987-11-10 E. I. Du Pont De Nemours And Company Substrates with sterically-protected, stable, covalently-bonded organo-silane films
US4746572A (en) * 1986-11-28 1988-05-24 E. I. Dupont De Nemours And Company Structures surface modified with bidentate silanes
US5055194A (en) * 1989-07-28 1991-10-08 University Of Pennsylvania Support for high performance liquid chromatography in a magnetically stabilized fluidized bed
US5087597A (en) * 1990-07-19 1992-02-11 Armada De La Republica De Venezuela Carbon dioxide adsorbent and method for producing the adsorbent
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US20040129141A1 (en) * 2002-03-08 2004-07-08 Abdul Malik High efficiency sol-gel gas chromatography column
US20060005877A1 (en) * 2004-07-06 2006-01-12 General Electric Company Passivated, dye-sensitized oxide semiconductor electrode, solar cell using same, and method
JP5021479B2 (en) 2004-10-01 2012-09-05 フェノメネクス インコーポレイテッド PH stable chromatographic media using templated multilayer organic / inorganic graffiti
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US10086584B2 (en) 2012-12-13 2018-10-02 Corning Incorporated Glass articles and methods for controlled bonding of glass sheets with carriers
TWI617437B (en) 2012-12-13 2018-03-11 康寧公司 Facilitated processing for controlling bonding between sheet and carrier
US10014177B2 (en) 2012-12-13 2018-07-03 Corning Incorporated Methods for processing electronic devices
US9340443B2 (en) 2012-12-13 2016-05-17 Corning Incorporated Bulk annealing of glass sheets
US10510576B2 (en) 2013-10-14 2019-12-17 Corning Incorporated Carrier-bonding methods and articles for semiconductor and interposer processing
JP6770432B2 (en) 2014-01-27 2020-10-14 コーニング インコーポレイテッド Articles and methods for controlled binding of thin sheets to carriers
KR20160145062A (en) 2014-04-09 2016-12-19 코닝 인코포레이티드 Device modified substrate article and methods for making
JP2018524201A (en) 2015-05-19 2018-08-30 コーニング インコーポレイテッド Articles and methods for bonding sheets with carriers
JP7106276B2 (en) 2015-06-26 2022-07-26 コーニング インコーポレイテッド Articles and methods with sheets and carriers
TW201825623A (en) 2016-08-30 2018-07-16 美商康寧公司 Siloxane plasma polymers for sheet bonding
TWI810161B (en) 2016-08-31 2023-08-01 美商康寧公司 Articles of controllably bonded sheets and methods for making same
CN111615567B (en) 2017-12-15 2023-04-14 康宁股份有限公司 Method for treating substrate and method for producing article including adhesive sheet

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US3500616A (en) * 1968-05-08 1970-03-17 Mine Safety Appliances Co Adsorbent for gas-solid chromatography
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1986004063A1 (en) * 1984-12-28 1986-07-17 Ksv-Chemicals Oy Surface treatment agents and polymers
US4756971A (en) * 1984-12-28 1988-07-12 Ksv-Chemicals Oy Surface treatment agents and polymers comprising substituted phenyl silanes and siloxanes
CN113000028A (en) * 2021-04-27 2021-06-22 临沂海普新材料科技有限公司 Preparation method of adsorbent for recovering phosphoric acid in waste acid

Also Published As

Publication number Publication date
FR2093601A5 (en) 1972-01-28
DE2125428A1 (en) 1971-12-02
CH578732A5 (en) 1976-08-13
NL7107016A (en) 1971-11-24
DE2125428C2 (en) 1984-05-30
US3722181A (en) 1973-03-27
SE399647B (en) 1978-02-27
JPS5217078B1 (en) 1977-05-13
JPS49125098A (en) 1974-11-29

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years