GB1344557A - Process for preparing 1,4-butanediol - Google Patents

Process for preparing 1,4-butanediol

Info

Publication number
GB1344557A
GB1344557A GB1344557DA GB1344557A GB 1344557 A GB1344557 A GB 1344557A GB 1344557D A GB1344557D A GB 1344557DA GB 1344557 A GB1344557 A GB 1344557A
Authority
GB
United Kingdom
Prior art keywords
copper
oxide
butanediol
preparing
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Petrochemical Co Ltd
Original Assignee
Mitsubishi Petrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Petrochemical Co Ltd filed Critical Mitsubishi Petrochemical Co Ltd
Publication of GB1344557A publication Critical patent/GB1344557A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium

Abstract

1344557 Hydrogenation catalysts MITSUBISHI PETROCHEMICAL CO Ltd 23 July 1972 29688/72 Heading B1E [Also in Division C2] A copper oxide-chromium, oxide catalyst comprises as an additional component at least one compound of K, Na, Rb, Al, Ti, Fe, Co or Ni or mixtures thereof. The catalyst is made by mixing a salt (e.g. a nitrate or carbonate) of the additional metal or titanium dioxide with a copper chromate cake and then drying the mixture, decomposing it in air at 230-270‹C and calcining it at 350‹C. The preferred atomic ratio of the added metal to copper is 0.005-0.2:1.
GB1344557D 1972-06-23 1972-06-23 Process for preparing 1,4-butanediol Expired GB1344557A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2968872 1972-06-23

Publications (1)

Publication Number Publication Date
GB1344557A true GB1344557A (en) 1974-01-23

Family

ID=10295517

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1344557D Expired GB1344557A (en) 1972-06-23 1972-06-23 Process for preparing 1,4-butanediol

Country Status (1)

Country Link
GB (1) GB1344557A (en)

Cited By (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4652685A (en) * 1985-11-15 1987-03-24 General Electric Company Hydrogenation of lactones to glycols
EP0318129A1 (en) * 1987-11-27 1989-05-31 Isp Investments Inc. Hydrogenation catalyst
US5030609A (en) * 1987-07-29 1991-07-09 Davy Mckee (London) Limited Process for producing a hydrogenation catalyst of copper chromite
US7154011B2 (en) 2002-06-11 2006-12-26 Basf Aktiengesellschaft Method for the production of 1,4- butanediol
US7169958B2 (en) 2002-06-11 2007-01-30 Basf Aktiengesellschaft Method for the production of 1,4- butane-diol by combined gas-phase and liquid-phase hydrogenation
US7271299B2 (en) 2002-06-11 2007-09-18 Basf Aktiengesellschaft Two-stage method for producing butanediol with intermediated separation of succinic anhydride
WO2010030711A2 (en) 2008-09-10 2010-03-18 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol
US7799545B2 (en) 2008-03-27 2010-09-21 Genomatica, Inc. Microorganisms for the production of adipic acid and other compounds
US7803589B2 (en) 2008-01-22 2010-09-28 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
WO2010141920A2 (en) 2009-06-04 2010-12-09 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol and related methods
US7947483B2 (en) 2007-08-10 2011-05-24 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
US7977084B2 (en) 2008-03-05 2011-07-12 Genomatica, Inc. Primary alcohol producing organisms
US8026386B2 (en) 2007-08-10 2011-09-27 Genomatica, Inc. Methods for the synthesis of olefins and derivatives
US8048661B2 (en) 2010-02-23 2011-11-01 Genomatica, Inc. Microbial organisms comprising exogenous nucleic acids encoding reductive TCA pathway enzymes
US8067214B2 (en) 2007-03-16 2011-11-29 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
US8129155B2 (en) 2008-12-16 2012-03-06 Genomatica, Inc. Microorganisms and methods for conversion of syngas and other carbon sources to useful products
US8129154B2 (en) 2008-06-17 2012-03-06 Genomatica, Inc. Microorganisms and methods for the biosynthesis of fumarate, malate, and acrylate
US8241877B2 (en) 2008-05-01 2012-08-14 Genomatica, Inc. Microorganisms for the production of methacrylic acid
US8377680B2 (en) 2009-05-07 2013-02-19 Genomatica, Inc. Microorganisms and methods for the biosynthesis of adipate, hexamethylenediamine and 6-aminocaproic acid
US8377666B2 (en) 2009-10-13 2013-02-19 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol, 4-hydroxybutanal, 4-hydroxybutyryl-coa, putrescine and related compounds, and methods related thereto
US8420375B2 (en) 2009-06-10 2013-04-16 Genomatica, Inc. Microorganisms and methods for carbon-efficient biosynthesis of MEK and 2-butanol
US8445244B2 (en) 2010-02-23 2013-05-21 Genomatica, Inc. Methods for increasing product yields
US8530210B2 (en) 2009-11-25 2013-09-10 Genomatica, Inc. Microorganisms and methods for the coproduction 1,4-butanediol and gamma-butyrolactone
US8580543B2 (en) 2010-05-05 2013-11-12 Genomatica, Inc. Microorganisms and methods for the biosynthesis of butadiene
US8597918B2 (en) 2009-06-04 2013-12-03 Genomatica, Inc. Process of separating components of a fermentation broth
WO2013184602A2 (en) 2012-06-04 2013-12-12 Genomatica, Inc. Microorganisms and methods for production of 4-hydroxybutyrate, 1,4-butanediol and related compounds
US8663957B2 (en) 2009-05-15 2014-03-04 Genomatica, Inc. Organisms for the production of cyclohexanone
US8673601B2 (en) 2007-01-22 2014-03-18 Genomatica, Inc. Methods and organisms for growth-coupled production of 3-hydroxypropionic acid
US8715957B2 (en) 2010-07-26 2014-05-06 Genomatica, Inc. Microorganisms and methods for the biosynthesis of aromatics, 2,4-pentadienoate and 1,3-butadiene
US8715971B2 (en) 2009-09-09 2014-05-06 Genomatica, Inc. Microorganisms and methods for the co-production of isopropanol and 1,4-butanediol
WO2014176514A2 (en) 2013-04-26 2014-10-30 Genomatica, Inc. Microorganisms and methods for production of 4-hydroxybutyrate, 1,4-butanediol and related compounds
US8993285B2 (en) 2009-04-30 2015-03-31 Genomatica, Inc. Organisms for the production of isopropanol, n-butanol, and isobutanol
US9017983B2 (en) 2009-04-30 2015-04-28 Genomatica, Inc. Organisms for the production of 1,3-butanediol
US9023636B2 (en) 2010-04-30 2015-05-05 Genomatica, Inc. Microorganisms and methods for the biosynthesis of propylene
US9562241B2 (en) 2009-08-05 2017-02-07 Genomatica, Inc. Semi-synthetic terephthalic acid via microorganisms that produce muconic acid
US10167477B2 (en) 2009-10-23 2019-01-01 Genomatica, Inc. Microorganisms and methods for the production of aniline
US10385344B2 (en) 2010-01-29 2019-08-20 Genomatica, Inc. Microorganisms and methods for the biosynthesis of (2-hydroxy-3methyl-4-oxobutoxy) phosphonate

Cited By (86)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4652685A (en) * 1985-11-15 1987-03-24 General Electric Company Hydrogenation of lactones to glycols
EP0222398A1 (en) * 1985-11-15 1987-05-20 General Electric Company Hydrogenation of lactones to glycols
US5030609A (en) * 1987-07-29 1991-07-09 Davy Mckee (London) Limited Process for producing a hydrogenation catalyst of copper chromite
EP0318129A1 (en) * 1987-11-27 1989-05-31 Isp Investments Inc. Hydrogenation catalyst
US7154011B2 (en) 2002-06-11 2006-12-26 Basf Aktiengesellschaft Method for the production of 1,4- butanediol
US7169958B2 (en) 2002-06-11 2007-01-30 Basf Aktiengesellschaft Method for the production of 1,4- butane-diol by combined gas-phase and liquid-phase hydrogenation
US7271299B2 (en) 2002-06-11 2007-09-18 Basf Aktiengesellschaft Two-stage method for producing butanediol with intermediated separation of succinic anhydride
US8673601B2 (en) 2007-01-22 2014-03-18 Genomatica, Inc. Methods and organisms for growth-coupled production of 3-hydroxypropionic acid
US8889399B2 (en) 2007-03-16 2014-11-18 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
US8357520B2 (en) 2007-03-16 2013-01-22 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
EP3800262A1 (en) 2007-03-16 2021-04-07 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
EP3214179A1 (en) 2007-03-16 2017-09-06 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
US11371046B2 (en) 2007-03-16 2022-06-28 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
US9487803B2 (en) 2007-03-16 2016-11-08 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
US8067214B2 (en) 2007-03-16 2011-11-29 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
US8969054B2 (en) 2007-03-16 2015-03-03 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
EP2821494A1 (en) 2007-03-16 2015-01-07 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
US8026386B2 (en) 2007-08-10 2011-09-27 Genomatica, Inc. Methods for the synthesis of olefins and derivatives
EP3447133A1 (en) 2007-08-10 2019-02-27 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
US7947483B2 (en) 2007-08-10 2011-05-24 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
EP2679684A1 (en) 2007-08-10 2014-01-01 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
EP2679685A1 (en) 2007-08-10 2014-01-01 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
EP2679676A1 (en) 2007-08-10 2014-01-01 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
US8470582B2 (en) 2007-08-10 2013-06-25 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
US9885064B2 (en) 2008-01-22 2018-02-06 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
US7803589B2 (en) 2008-01-22 2010-09-28 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
US8697421B2 (en) 2008-01-22 2014-04-15 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
US9051552B2 (en) 2008-01-22 2015-06-09 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
US8691553B2 (en) 2008-01-22 2014-04-08 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
US10550411B2 (en) 2008-01-22 2020-02-04 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
US8323950B2 (en) 2008-01-22 2012-12-04 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
US9260729B2 (en) 2008-03-05 2016-02-16 Genomatica, Inc. Primary alcohol producing organisms
US10208320B2 (en) 2008-03-05 2019-02-19 Genomatica, Inc. Primary alcohol producing organisms
US7977084B2 (en) 2008-03-05 2011-07-12 Genomatica, Inc. Primary alcohol producing organisms
US11613767B2 (en) 2008-03-05 2023-03-28 Genomatica, Inc. Primary alcohol producing organisms
US7799545B2 (en) 2008-03-27 2010-09-21 Genomatica, Inc. Microorganisms for the production of adipic acid and other compounds
US8062871B2 (en) 2008-03-27 2011-11-22 Genomatica, Inc. Microorganisms for the production of adipic acid and other compounds
US8088607B2 (en) 2008-03-27 2012-01-03 Genomatica, Inc. Microorganisms for the production of adipic acid and other compounds
US8241877B2 (en) 2008-05-01 2012-08-14 Genomatica, Inc. Microorganisms for the production of methacrylic acid
US8129154B2 (en) 2008-06-17 2012-03-06 Genomatica, Inc. Microorganisms and methods for the biosynthesis of fumarate, malate, and acrylate
EP3514242A2 (en) 2008-09-10 2019-07-24 Genomatica, Inc. Microrganisms for the production of 1,4-butanediol
WO2010030711A2 (en) 2008-09-10 2010-03-18 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol
US8178327B2 (en) 2008-09-10 2012-05-15 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol
US7858350B2 (en) 2008-09-10 2010-12-28 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol
US8129156B2 (en) 2008-09-10 2012-03-06 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol
US9175297B2 (en) 2008-09-10 2015-11-03 Genomatica, Inc. Microorganisms for the production of 1,4-Butanediol
US8129155B2 (en) 2008-12-16 2012-03-06 Genomatica, Inc. Microorganisms and methods for conversion of syngas and other carbon sources to useful products
US8993285B2 (en) 2009-04-30 2015-03-31 Genomatica, Inc. Organisms for the production of isopropanol, n-butanol, and isobutanol
US9017983B2 (en) 2009-04-30 2015-04-28 Genomatica, Inc. Organisms for the production of 1,3-butanediol
US8377680B2 (en) 2009-05-07 2013-02-19 Genomatica, Inc. Microorganisms and methods for the biosynthesis of adipate, hexamethylenediamine and 6-aminocaproic acid
US8663957B2 (en) 2009-05-15 2014-03-04 Genomatica, Inc. Organisms for the production of cyclohexanone
WO2010141920A2 (en) 2009-06-04 2010-12-09 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol and related methods
US10273508B2 (en) 2009-06-04 2019-04-30 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol and related methods
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US8597918B2 (en) 2009-06-04 2013-12-03 Genomatica, Inc. Process of separating components of a fermentation broth
US11401534B2 (en) 2009-06-04 2022-08-02 Genomatica, Inc. Microorganisms for the production of 1,4- butanediol and related methods
US8129169B2 (en) 2009-06-04 2012-03-06 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol and related methods
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US9434964B2 (en) 2009-06-04 2016-09-06 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol and related methods
US8420375B2 (en) 2009-06-10 2013-04-16 Genomatica, Inc. Microorganisms and methods for carbon-efficient biosynthesis of MEK and 2-butanol
US9562241B2 (en) 2009-08-05 2017-02-07 Genomatica, Inc. Semi-synthetic terephthalic acid via microorganisms that produce muconic acid
US10415063B2 (en) 2009-08-05 2019-09-17 Genomatica, Inc. Semi-synthetic terephthalic acid via microorganisms that produce muconic acid
US10041093B2 (en) 2009-08-05 2018-08-07 Genomatica, Inc. Semi-synthetic terephthalic acid via microorganisms that produce muconic acid
US8715971B2 (en) 2009-09-09 2014-05-06 Genomatica, Inc. Microorganisms and methods for the co-production of isopropanol and 1,4-butanediol
US8377667B2 (en) 2009-10-13 2013-02-19 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol, 4-hydroxybutanal, 4-hydroxybutyryl-CoA, putrescine and related compounds, and methods related thereto
US8377666B2 (en) 2009-10-13 2013-02-19 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol, 4-hydroxybutanal, 4-hydroxybutyryl-coa, putrescine and related compounds, and methods related thereto
US10612029B2 (en) 2009-10-23 2020-04-07 Genomatica, Inc. Microorganisms and methods for the production of aniline
US10167477B2 (en) 2009-10-23 2019-01-01 Genomatica, Inc. Microorganisms and methods for the production of aniline
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US10385344B2 (en) 2010-01-29 2019-08-20 Genomatica, Inc. Microorganisms and methods for the biosynthesis of (2-hydroxy-3methyl-4-oxobutoxy) phosphonate
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US8048661B2 (en) 2010-02-23 2011-11-01 Genomatica, Inc. Microbial organisms comprising exogenous nucleic acids encoding reductive TCA pathway enzymes
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