GB1326435A - Aqueous emulsion epoxy resin systems - Google Patents

Aqueous emulsion epoxy resin systems

Info

Publication number
GB1326435A
GB1326435A GB5232370A GB5232370A GB1326435A GB 1326435 A GB1326435 A GB 1326435A GB 5232370 A GB5232370 A GB 5232370A GB 5232370 A GB5232370 A GB 5232370A GB 1326435 A GB1326435 A GB 1326435A
Authority
GB
United Kingdom
Prior art keywords
radical
substituted
aminoethyl
unsubstituted
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5232370A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resyn Corp
Original Assignee
Resyn Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Resyn Corp filed Critical Resyn Corp
Publication of GB1326435A publication Critical patent/GB1326435A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C08G59/64—Amino alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/182—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents
    • C08G59/184—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

1326435 Epoxy resin emulsions RESYN CORP 3 Nov 1970 [3 Nov 1969 7 July 1970] 52323/70 Heading C2C [Also in Division C3] A compound, useful as an emulsifying agent and curing agent for epoxy resins has either the Formula (A) in which each of the groups R, which may be the same or different, is an unsubstituted or amino- or hydroxy-substituted C 2-10 hydrocarbon radical, an unsubstituted or alkyl-, cycloalkyl- or acetyl-substituted amino radical in which the (cyclo)alkyl radicals contain up to C 10 , or an aliphatic radical substituted by a heterocyclic radical with 5 to 8 ring atoms; each R<SP>1</SP>, which may be the same or different is H or an unsubstituted or amino- or hydroxy-substituted C 1-6 alkyl radical; each is Cl, Br or I; Y is the residue of a saturated or unsaturated diol in which the OH groups are attached to aliphatic carbon atoms; each n or n<SP>1</SP> is 0-12; with a proviso that at least two of R and R<SP>1</SP> are H or contain H bonded to N. Alternatively the compound may have the formula (B) which is a compound I in which one or more of the hydrogen atoms directly linked to a carbon atom is replaced by a C 1-6 alkyl radical or a C 5-7 aryl or cycloaliphatic radical or a heterocyclic radical having 5-8 ring atoms. I may be prepared by reacting a diglycidyl ether (X, Y, n and n<SP>1</SP> are as previously defined) with an amine HNRR<SP>1</SP> (R and R<SP>1</SP> are as previously defined) using a molar ratio of amine to diglycidyl ether of at least 2 : 1. R may be hydroxyethyl, aminoethyl, aminopropyl, aminobutyl, aminohexyl, acetylamino, polyaminoethyl, polypropylamino, ethyl, propyl, niso- or tert-butyl, pentyl, isopropyl, hexyl, heptyl, octyl, nonyl, decyl, aminoethyl or piperazino. R<SP>1</SP> may be methyl, ethyl, hydroxyethyl, aminoethyl, propyl, hydroxypropyl, aminopropyl, n- or sec-butyl, pentyl or hexyl. Y may be the residue of propylene glycol, di- or poly-propylene glycol, 1,4-butane diol, di- or polyethylene glycol or 1,6-hexane diol. The amine may be diethylenetriamine, triethylenetetramine, tetraethylenepentamine, ethylene diamine or 1,6-hexanediamine.
GB5232370A 1969-11-03 1970-11-03 Aqueous emulsion epoxy resin systems Expired GB1326435A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US87350169A 1969-11-03 1969-11-03
US5301070A 1970-07-07 1970-07-07

Publications (1)

Publication Number Publication Date
GB1326435A true GB1326435A (en) 1973-08-15

Family

ID=26731347

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5232370A Expired GB1326435A (en) 1969-11-03 1970-11-03 Aqueous emulsion epoxy resin systems

Country Status (8)

Country Link
JP (1) JPS5490297A (en)
AT (1) AT331520B (en)
BE (1) BE758385A (en)
CA (1) CA977757A (en)
DE (1) DE2053359A1 (en)
FR (1) FR2068390A5 (en)
GB (1) GB1326435A (en)
SE (1) SE379772B (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4089826A (en) 1974-11-06 1978-05-16 Ciba-Geigy Corporation New curing agents for epoxide resins
US4246148A (en) * 1979-08-27 1981-01-20 Celanese Corporation Two component aqueous coating composition based on an epoxy-polyamine adduct and a polyepoxide
US4304700A (en) 1979-08-27 1981-12-08 Celanese Corporation Two component aqueous based coating composition
US5489630A (en) * 1994-11-28 1996-02-06 Air Products And Chemicals, Inc. Self-emulsifying epoxy curing agent
US5527839A (en) * 1994-12-13 1996-06-18 Air Products And Chemicals, Inc. Self-emulsifying epoxy curing agent based on the reaction product of epoxy resin and polyether polyol
US5576416A (en) * 1994-12-13 1996-11-19 Air Products And Chemicals, Inc. Amide-containing self-emulsifying epoxy curing agent
WO2009094235A1 (en) * 2008-01-23 2009-07-30 Dow Global Technologies Inc. Epoxy resin hardener compositions and epoxy resin compositions containing such hardener compositions

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4197389A (en) * 1977-07-18 1980-04-08 Hoechst Aktiengesellschaft Hardening agent for aqueous epoxy resin compositions
US4748167A (en) * 1984-08-01 1988-05-31 Ppg Industries, Inc. Water-based coating compositions comprising epoxy-containing acrylic polymers an polyfunctional water-soluble amines
IT1248370B (en) * 1991-04-29 1995-01-11 Sir Ind Spa Aqueous emulsions of epoxyphenolic resins
DE4206392A1 (en) * 1992-02-29 1993-09-02 Hoechst Ag CURING AGENT FOR EPOXY RESINS

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4089826A (en) 1974-11-06 1978-05-16 Ciba-Geigy Corporation New curing agents for epoxide resins
US4246148A (en) * 1979-08-27 1981-01-20 Celanese Corporation Two component aqueous coating composition based on an epoxy-polyamine adduct and a polyepoxide
US4304700A (en) 1979-08-27 1981-12-08 Celanese Corporation Two component aqueous based coating composition
US5489630A (en) * 1994-11-28 1996-02-06 Air Products And Chemicals, Inc. Self-emulsifying epoxy curing agent
US5599855A (en) * 1994-11-28 1997-02-04 Air Products And Chemicals, Inc. Self-emulsifying epoxy curing agent
US5596030A (en) * 1994-12-13 1997-01-21 Air Products And Chemicals, Inc. Amide-containing self-emulsifying epoxy curing agent
US5576416A (en) * 1994-12-13 1996-11-19 Air Products And Chemicals, Inc. Amide-containing self-emulsifying epoxy curing agent
US5527839A (en) * 1994-12-13 1996-06-18 Air Products And Chemicals, Inc. Self-emulsifying epoxy curing agent based on the reaction product of epoxy resin and polyether polyol
WO2009094235A1 (en) * 2008-01-23 2009-07-30 Dow Global Technologies Inc. Epoxy resin hardener compositions and epoxy resin compositions containing such hardener compositions
CN101925627A (en) * 2008-01-23 2010-12-22 陶氏环球技术公司 Epoxy resin hardener composition and contain the composition epoxy resin of such hardener composition
US8389652B2 (en) 2008-01-23 2013-03-05 Dow Global Technologies Llc Epoxy resin hardener compositions and epoxy resin compositions containing such hardener compositions
US8927663B2 (en) 2008-01-23 2015-01-06 Dow Global Technologies Llc Epoxy resin hardener compositions and epoxy resin compositions containing such hardener compositions
KR101512623B1 (en) 2008-01-23 2015-04-21 다우 글로벌 테크놀로지스 엘엘씨 Epoxy resin hardener compositions and epoxy resin compositions containing such hardener compositions
US9133301B2 (en) 2008-01-23 2015-09-15 Dow Global Technologies Llc Epoxy resin hardener compositions and epoxy resin compositions containing such hardener compositions
US9371415B2 (en) 2008-01-23 2016-06-21 Blue Cube Ip Llc Epoxy resin hardener compositions and epoxy resin compositions containing such hardener compositions

Also Published As

Publication number Publication date
AT331520B (en) 1976-08-25
SE379772B (en) 1975-10-20
FR2068390A5 (en) 1971-08-20
ATA990270A (en) 1975-11-15
BE758385A (en) 1971-04-16
CA977757A (en) 1975-11-11
JPS5490297A (en) 1979-07-17
DE2053359A1 (en) 1972-01-13

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee