GB1172002A - Low Temperature Process for Halogenation of Hydrocarbons - Google Patents
Low Temperature Process for Halogenation of HydrocarbonsInfo
- Publication number
- GB1172002A GB1172002A GB1929867A GB1929867A GB1172002A GB 1172002 A GB1172002 A GB 1172002A GB 1929867 A GB1929867 A GB 1929867A GB 1929867 A GB1929867 A GB 1929867A GB 1172002 A GB1172002 A GB 1172002A
- Authority
- GB
- United Kingdom
- Prior art keywords
- halogenation
- feed
- hydrocarbons
- april
- hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
Abstract
1,172,002. Halogenating hydrocarbons- MARATHON OIL CO. 26 April, 1967 [28 April, 1966], No. 19298/67. Heading C2C. A process for halogenating hydrocarbons comprises mixing a hydrocarbon and chlorine and/or bromine to form a feed and contacting said feed with a zeolite catalyst at a temperature of from 50‹ to 250‹ C. The reaction is preferably carried out in the vapour phase on a continuous basis, and the amount of halogenation attained is controlled by varying the ratio of hydrocarbon to halogen in the feed. Preferred zeolites are the Y-type molecular sieves, which may when desired be partially or totally ionexchanged with cationic substituents, e.g. mercury, silver, nickel, manganese and copper. Examples describe the halogenation of propane and ethane.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US55110266A | 1966-04-28 | 1966-04-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1172002A true GB1172002A (en) | 1969-11-26 |
Family
ID=24199867
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1929867A Expired GB1172002A (en) | 1966-04-28 | 1967-04-26 | Low Temperature Process for Halogenation of Hydrocarbons |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE1618686B1 (en) |
FR (1) | FR1561081A (en) |
GB (1) | GB1172002A (en) |
Cited By (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5200376A (en) * | 1990-04-27 | 1993-04-06 | Gaz De France | Catalysts for oxyhydrochlorination of methane |
US7674941B2 (en) | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
US7847139B2 (en) | 2003-07-15 | 2010-12-07 | Grt, Inc. | Hydrocarbon synthesis |
US7880041B2 (en) | 2004-04-16 | 2011-02-01 | Marathon Gtf Technology, Ltd. | Process for converting gaseous alkanes to liquid hydrocarbons |
US7883568B2 (en) | 2006-02-03 | 2011-02-08 | Grt, Inc. | Separation of light gases from halogens |
US7964764B2 (en) | 2003-07-15 | 2011-06-21 | Grt, Inc. | Hydrocarbon synthesis |
US7998438B2 (en) | 2007-05-24 | 2011-08-16 | Grt, Inc. | Zone reactor incorporating reversible hydrogen halide capture and release |
US8008535B2 (en) | 2004-04-16 | 2011-08-30 | Marathon Gtf Technology, Ltd. | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
US8053616B2 (en) | 2006-02-03 | 2011-11-08 | Grt, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8273929B2 (en) | 2008-07-18 | 2012-09-25 | Grt, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
US9206093B2 (en) | 2004-04-16 | 2015-12-08 | Gtc Technology Us, Llc | Process for converting gaseous alkanes to liquid hydrocarbons |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NZ200032A (en) * | 1981-03-19 | 1985-07-12 | Ici Plc | Production of chlorinated hydrocarbons from alkanes |
AU8164382A (en) * | 1981-03-19 | 1982-09-23 | Imperial Chemical Industries Plc | Production of methylene chloride |
AU8164582A (en) * | 1981-03-19 | 1982-09-23 | Imperial Chemical Industries Plc | Production of chloroackanes |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL248810A (en) * | 1959-03-27 | |||
US2956084A (en) * | 1959-03-27 | 1960-10-11 | Exxon Research Engineering Co | Process for chlorinating hydrocarbons using chlorine adsorbed on zeolite |
-
1967
- 1967-04-24 DE DE1967M0073723 patent/DE1618686B1/en active Pending
- 1967-04-26 GB GB1929867A patent/GB1172002A/en not_active Expired
- 1967-04-27 FR FR1561081D patent/FR1561081A/fr not_active Expired
Cited By (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5200376A (en) * | 1990-04-27 | 1993-04-06 | Gaz De France | Catalysts for oxyhydrochlorination of methane |
US8415512B2 (en) | 2001-06-20 | 2013-04-09 | Grt, Inc. | Hydrocarbon conversion process improvements |
US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
US7964764B2 (en) | 2003-07-15 | 2011-06-21 | Grt, Inc. | Hydrocarbon synthesis |
US7847139B2 (en) | 2003-07-15 | 2010-12-07 | Grt, Inc. | Hydrocarbon synthesis |
US8232441B2 (en) | 2004-04-16 | 2012-07-31 | Marathon Gtf Technology, Ltd. | Process for converting gaseous alkanes to liquid hydrocarbons |
US9206093B2 (en) | 2004-04-16 | 2015-12-08 | Gtc Technology Us, Llc | Process for converting gaseous alkanes to liquid hydrocarbons |
US7674941B2 (en) | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US8008535B2 (en) | 2004-04-16 | 2011-08-30 | Marathon Gtf Technology, Ltd. | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US7880041B2 (en) | 2004-04-16 | 2011-02-01 | Marathon Gtf Technology, Ltd. | Process for converting gaseous alkanes to liquid hydrocarbons |
US7883568B2 (en) | 2006-02-03 | 2011-02-08 | Grt, Inc. | Separation of light gases from halogens |
US8053616B2 (en) | 2006-02-03 | 2011-11-08 | Grt, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
US8921625B2 (en) | 2007-02-05 | 2014-12-30 | Reaction35, LLC | Continuous process for converting natural gas to liquid hydrocarbons |
US7998438B2 (en) | 2007-05-24 | 2011-08-16 | Grt, Inc. | Zone reactor incorporating reversible hydrogen halide capture and release |
US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
US8273929B2 (en) | 2008-07-18 | 2012-09-25 | Grt, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
US8415517B2 (en) | 2008-07-18 | 2013-04-09 | Grt, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US9133078B2 (en) | 2010-03-02 | 2015-09-15 | Gtc Technology Us, Llc | Processes and systems for the staged synthesis of alkyl bromides |
US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
Also Published As
Publication number | Publication date |
---|---|
DE1618686B1 (en) | 1971-08-26 |
FR1561081A (en) | 1969-03-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PLNP | Patent lapsed through nonpayment of renewal fees |