GB1017153A - Treatment of synthetic hydrophobic fibres - Google Patents

Treatment of synthetic hydrophobic fibres

Info

Publication number
GB1017153A
GB1017153A GB3754162A GB3754162A GB1017153A GB 1017153 A GB1017153 A GB 1017153A GB 3754162 A GB3754162 A GB 3754162A GB 3754162 A GB3754162 A GB 3754162A GB 1017153 A GB1017153 A GB 1017153A
Authority
GB
United Kingdom
Prior art keywords
dimethylol
magnesium chloride
acrolein
vinyl
fabrics
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3754162A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Publication of GB1017153A publication Critical patent/GB1017153A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/347—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D06M2101/08—Esters or ethers of cellulose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
    • D06M2101/28—Acrylonitrile; Methacrylonitrile
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/04—Polyester fibers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/21—Nylon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2279—Coating or impregnation improves soil repellency, soil release, or anti- soil redeposition qualities of fabric

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Vinyl polymers containing hydroxyl and aldehyde groups in the molecule which are suitable for the treatment of synthetic polyester, polyacrylonitrile or partially acetylated cellulose fibre fabrics, are produced by the reaction of vinyl acetate with acrolein or acrolein diacetate in the presence of a ,a 1-azobisisobutyronitrile or benzoyl peroxide and saponification of the polymer produced with caustic soda. The vinyl polymers may be applied to the fabrics as aqueous solutions containing an aminoplast resin, e.g. dimethylolurea, dimethylol ethylene urea, dimethylolurane, dimethylol glyoxal monourein, tetramethylolacetylene diurea, dimethylol triazone and their alkylated compounds, and magnesium chloride as catalyst.ALSO:Fabrics comprising synthetic polyester, polyacrylonitrile or partially acetylated cellulose fibres alone or in admixture with natural cellulosic or animal fibres are given an improved dirt-preventing effect and hardness by soaking them in a resin bath containing an aqueous solution of a vinyl polymer containing hydroxyl and aldehyde groups in the molecule which is obtained by saponification of a copolymer of vinyl acetate with acrolein or acrolein diacetate, and magnesium chloride as catalyst. The vinyl polymers used may have molecular weights of more than 20,000 and less than 1,000,000 and the structure <FORM:1017153/D1-D2/1> in which x and y are whole numbers and the ratio x : y is 5-20 : 95-80. The magnesium chloride is preferably added in an amount of more than 15% by weight of an aqueous 30% by weight magnesium chloride solution to a 15% by weight paste of the vinyl polymer. The treating solution may also contain an aminoplast resin, e.g. dimethylolurea, dimethylol ethyleneurea, dimethylolurane dimethylol glyosal monourein, tetramethylolacetylene diurea, dimethylol triazone and their alkylated compounds.
GB3754162A 1961-10-10 1962-10-04 Treatment of synthetic hydrophobic fibres Expired GB1017153A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3674761 1961-10-10

Publications (1)

Publication Number Publication Date
GB1017153A true GB1017153A (en) 1966-01-19

Family

ID=12478307

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3754162A Expired GB1017153A (en) 1961-10-10 1962-10-04 Treatment of synthetic hydrophobic fibres

Country Status (5)

Country Link
US (1) US3238166A (en)
CH (1) CH383916A (en)
DE (1) DE1444122A1 (en)
FR (1) FR1342361A (en)
GB (1) GB1017153A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5407728A (en) 1992-01-30 1995-04-18 Reeves Brothers, Inc. Fabric containing graft polymer thereon
US5486210A (en) 1992-01-30 1996-01-23 Reeves Brothers, Inc. Air bag fabric containing graft polymer thereon

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3659375A (en) * 1970-05-04 1972-05-02 Kohner Bros Inc Toy with pseudo automobile controls and pseudo automobile windshield and windshield wiper mechanism
US4314805A (en) * 1979-10-29 1982-02-09 Mcknight Eugene A Laundry process and method for treating textiles

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2485239A (en) * 1945-03-06 1949-10-18 Du Pont Polymers containing recurring aldehyde groups and derivatives thereof and process for preparing same
US2569932A (en) * 1945-11-21 1951-10-02 Du Pont Cross-linked hydrolyzed interpolymer of vinyl acetate and allylidene diacetate and process
US2950553A (en) * 1957-01-16 1960-08-30 Rohm & Haas Method of producing wrinkle resistant garments and other manufactured articles of cotton-containing fabrics
CH399407A (en) * 1960-09-22 1965-09-30 Pfersee Chem Fab Agent for high-end finishing, in particular for making textiles made from cellulose and / or regenerated cellulose fibers crease-proof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5407728A (en) 1992-01-30 1995-04-18 Reeves Brothers, Inc. Fabric containing graft polymer thereon
US5486210A (en) 1992-01-30 1996-01-23 Reeves Brothers, Inc. Air bag fabric containing graft polymer thereon
US5552472A (en) 1992-01-30 1996-09-03 Reeves Brothers, Inc. Fabric containing graft polymer thereon

Also Published As

Publication number Publication date
US3238166A (en) 1966-03-01
CH383916A (en) 1965-01-29
DE1444122A1 (en) 1968-11-07
CH1179962A4 (en) 1964-07-31
FR1342361A (en) 1963-11-08

Similar Documents

Publication Publication Date Title
US3046079A (en) Process of reacting partially swollen cotton textiles with aqueous solutions of specific aldehydes containing acid catalysts to produce wet and dry crease resistance
US2243765A (en) Treatment of cellulosic textile materials
Baugh et al. ESR study of post‐irradiation reactions of cellulose and acrylonitrile
CN102877287A (en) Preparation method of halamine-containing antibacterial cellulose fabric
GB1498856A (en) Durable press process
GB745638A (en) Improvements relating to the protection of cellulosic fibrous materials having a lowswelling capacity from attack by micro-organisms
US3080207A (en) Preparation of polyvinyl alcohol bodies having improved knot strength
GB1017153A (en) Treatment of synthetic hydrophobic fibres
Hurwitz et al. Dialdehydes as Cotton Cellulose Cross-Linkers1
GB971207A (en) Treatment of animal fibre
US3050419A (en) Process for fixing aminoplasts in the wet state on cellulosic fibrous materials
US2724633A (en) Process of making cellulose fibers containing ether groups and beta-propiolactone substitutents
GB877582A (en) Improvements in or relating to a method of finishing textile materials
US3926550A (en) Cotton-tung oil durable-press textiles with high flex abrasion resistance
GB1190538A (en) Process for improving Fabrics containing Cellulosic Fibres
GB1068832A (en) Improvements in the treatment of polyester shaped articles
US2842541A (en) Cyanoethyl ethers
GB720016A (en) Improvements in or relating to imparting durable to water finishes to fabrics
US2375124A (en) Process for modifying the dyeing and other properties of cellulosic textile materials
US3677692A (en) High energy radiation stabilization of cellulose obtained by esterifying with furoyl chloride
GB1161539A (en) Process for Improving Cellulose Textile Material by Alkaline Treatment
GB1107468A (en) Improvements in reactive dressings intended to render cellulose fabrics uncreasable
GB928326A (en) Agents for increasing the wet shape retention of fibrous materials containing or consisting of cellulose and a process using the same
GB1024497A (en) Oleophobic and hydrophobic fibres
SU494477A1 (en) Composition for fire retardant and crushable finishing of cellulosic textile materials