FR2715841A1 - Hair cosmetic compsns. - Google Patents
Hair cosmetic compsns. Download PDFInfo
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- FR2715841A1 FR2715841A1 FR9401342A FR9401342A FR2715841A1 FR 2715841 A1 FR2715841 A1 FR 2715841A1 FR 9401342 A FR9401342 A FR 9401342A FR 9401342 A FR9401342 A FR 9401342A FR 2715841 A1 FR2715841 A1 FR 2715841A1
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- caprolactam
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
Composition cosmétique capillaire contenant un poly N-vinyl caprolactame et un
copolymère de N-vinyl pyrrolidone et de N-vinyl imidazolium et utillisations.Cosmetic hair composition containing a poly N-vinyl caprolactam and a
copolymer of N-vinylpyrrolidone and N-vinylimidazolium and uses.
Parmi les nombreux polymères utilisés de façon conventionnelle en cosmétique et en particulier dans des compositions pour le maintien de la coiffure, on peut citer les poly N-vinyl caprolactames. De telles compositions sont notamment décrites dans la demande DE-A4 013 872. Ces polymères sont particulièrement intéressants pour les produits de coiffage car ils apportent de la brillance aux cheveux et les films obtenus présentent un bon toucher. Cependant, de tels films sont très friables, ce qui signifie que ces polymères ont un faible pouvoir laquant.Among the many polymers conventionally used in cosmetics and in particular in compositions for maintaining the hairstyle, mention may be made of poly N-vinyl caprolactams. Such compositions are described in particular in application DE-A4 013 872. These polymers are particularly interesting for hair styling products because they provide shine to the hair and the films obtained have a good feel. However, such films are very friable, which means that these polymers have low lacquering power.
Par ailleurs, il est connu d'une manière générale d'améliorer le pouvoir laquant d'un polymère en plastifiant celuici à l'aide d'un agent plastifiant tel que ceux décrits dans la demande de brevet WO 93/09757. Toutefois, dans le cas particulier des poly N-vinyl caprolactames, lorsque l'on utilise un agent plastifiant classique dans des concentrations normales, c'est à dire à des concentrations comprises entre 1 et 10 % en poids par rapport au poids de polymère, on obtient des résultats au niveau du pouvoir laquant relativement faibles. En outre, si on augmente la concentration en agent plastifiant, le film de polymère obtenu après séchage devient poisseux.Furthermore, it is generally known to improve the lacquering power of a polymer by plasticizing it with a plasticizer such as those described in the patent application WO 93/09757. However, in the particular case of poly N-vinyl caprolactams, when a conventional plasticizer is used in normal concentrations, that is to say at concentrations of between 1 and 10% by weight relative to the weight of polymer, relatively low lacquer results are obtained. In addition, if the concentration of plasticizer is increased, the polymer film obtained after drying becomes sticky.
Or, la demanderesse a maintenant découvert, de façon inattendue et surprenante, que l'on peut améliorer de manière substantielle le pouvoir laquant des poly N-vinyl caprolactames, et ceci sans rencontrer les inconvénients de poissage susmentionnés, en associant auxdits poly N-vinyl caprolactames des copolymè-res de N-vinyl pyrrolidone et de N-vinyl imidazolium.However, the Applicant has now discovered, unexpectedly and surprisingly, that we can substantially improve the lacquering power of poly N-vinyl caprolactam, and this without encountering the aforementioned disadvantages of tack, by associating with said poly N-vinyl caprolactams copolymers of N-vinyl pyrrolidone and N-vinyl imidazolium.
La présente invention a donc pour objet une composition cosmétique capillaire contenant, dans un milieu cosmétiquement acceptable, un poly N-vinyl caprolactame et un copolymère de N-vinyl pyrrolidone et de N-vinyl imidazolium.The present invention therefore relates to a hair cosmetic composition containing, in a cosmetically acceptable medium, a poly N-vinyl caprolactam and a copolymer of N-vinylpyrrolidone and N-vinylimidazolium.
On entend par N-vinyl imidazolium tous les composés partiellement ou totalement quaternisés du N-vinyl imidazole et plus particulièrement le chlorure de méthyle
N-vinyl imidazolium ou le sulfate de diméthyle N-vinyl imidazolium.By N-vinylimidazolium is meant all the partially or totally quaternized compounds of N-vinylimidazole and more particularly methyl chloride.
N-vinyl imidazolium or dimethyl sulfate N-vinyl imidazolium.
L'invention a également pour objet l'utilisation d'une telle composition pour le coiffage des cheveux, ainsi que l'utilisation d'une telle composition comme, ou pour la fabrication de, produit de coiffage.The invention also relates to the use of such a composition for styling hair, as well as the use of such a composition as, or for the manufacture of, styling product.
Les copolymères de N-vinyl pyrrolidone et de N-vinyl imidazolium ont de préférence un poids moléculaire moyen compris entre 5 000 et 700 000.The copolymers of N-vinylpyrrolidone and N-vinylimidazolium preferably have an average molecular weight of between 5,000 and 700,000.
Parmi les copolymères de N-vinyl pyrrolidone et de N-vinyl imidazolium, on peut notamment citer ceux vendus sous les dénominations "LUVIQUAT FC 905", "LUVIQUAT FC 550", "LUVIQUAT FC 370", "LUVIQUAT HM 372", "LUVIQUAT
HM 552", "LUVIQUAT HM 8155" par la société BASF.Among the copolymers of N-vinylpyrrolidone and N-vinylimidazolium, there may be mentioned those sold under the names "Luviquat FC 905", "Luviquat FC 550", "Luviquat FC 370", "Luviquat HM 372", "Luviquat
HM 552 "," LUVIQUAT HM 8155 "by the company BASF.
Les poly N-vinyl caprolactames ont de préférence un poids moléculaire moyen compris entre 1 000 et 1 000 000. The poly N-vinyl caprolactams preferably have an average molecular weight of between 1,000 and 1,000,000.
Les compositions selon l'invention peuvent constituer des produits de coiffage intéressants et présentant de bonnes propriétés cosmétiques: les films de polymères déposés sur les cheveux sont brillants, présentent un bon toucher ainsi qu'un bon pouvoir laquant. Ils confèrent une bonne tenue de la coiffure.The compositions according to the invention can constitute interesting styling products and having good cosmetic properties: the polymer films deposited on the hair are shiny, have a good feel and good lacquering power. They confer a good behavior of the hairstyle.
Dans les compositions selon l'invention, le poly N-vinyl caprolactame est généralement présent à une concentration comprise entre 0,5 et 20 % en poids, et de préférence entre 1 et 10 % en poids par rapport au poids total de la composition.In the compositions according to the invention, the poly N-vinyl caprolactam is generally present in a concentration of between 0.5 and 20% by weight, and preferably between 1 and 10% by weight relative to the total weight of the composition.
Les copolymères de N-vinyl pyrrolidone et de N-vinyl imidazolium sont généralement présents à une concentration comprise entre 15 et 40 % en poids, et de préférence entre 20 et 30 % en poids par rapport au poids de poly N-vinyl caprolactame.The copolymers of N-vinylpyrrolidone and N-vinylimidazolium are generally present at a concentration of between 15 and 40% by weight, and preferably between 20 and 30% by weight relative to the weight of poly N-vinyl caprolactam.
Les compositions selon l'invention peuvent se présenter sous forme de lotion ou de gel aqueux ou hydroalcoolique, I'alcool étant choisi parmi les alcools inférieurs et notamment ceux ayant de 2 à 4 atomes de carbones tels que l'éthanol, I'isopropanol, le butanol. Les compositions sont alors sous forme de lotion de fixation pour pulvérisation manuelle, de lotion de mise en plis, de gel de coiffage.The compositions according to the invention may be in the form of an aqueous or hydroalcoholic lotion or gel, the alcohol being chosen from lower alcohols and in particular those having from 2 to 4 carbon atoms such as ethanol and isopropanol, butanol. The compositions are then in the form of fixing lotion for manual spraying, styling lotion, styling gel.
Les compositions peuvent être également pressurisées à l'aide d'un agent propulseur.The compositions may also be pressurized with a propellant.
Parmi les agents propulseurs utilisables, on peut citer le butane, le propane, I'isobutane, le pentane, les hydrocarbures fluorés etlou chlorés, l'azote, I'air comprimé, le protoxyde d'azote et le diméthyléther.Among the propellants that can be used include butane, propane, isobutane, pentane, fluorinated and / or chlorinated hydrocarbons, nitrogen, compressed air, nitrous oxide and dimethyl ether.
Les compositions pressurisées se présentent alors sous forme de laque aérosol ou de mousse de coiffage.The pressurized compositions are then in the form of aerosol lacquer or styling mousse.
II est par ailleurs possible d'introduire dans la composition selon l'invention un agent plastifiant classique dans le but de renforcer l'effet de plastification obtenu avec les copolymères de N-vinyl pyrrolidone et de N-vinyl imidazolium. L'agent plastifiant peut être choisi dans le groupe comprenant: - les Carbitols de la société Union Carbide à savoir le Carbitol ou diéthylène glycol éthyléther, le méthyl Carbitol ou diéthylène glycol méthyléther, le butyl
Carbitol ou diéthylène glycol butyléther ou encore l'hexyl Carbitol ou diéthylène glycol hexyléther, - les Cellosolves de la société Union Carbide à savoir le Cellosolve ou éthylène glycol éthyléther, le butyl Cellosolve ou éthylène glycol buthyléther, I'hexyl
Cellosolve ou éthylène glycol hexyléther, - les dérivés de propylène glycol et en particulier le propylène glycol phényléther, le propylène glycol diacétate, le dipropylène glycol butyléther, le tripropylène glycol butyléther, ainsi que les Dowanols de la société Dow Chemical à savoir le
Dowanol PM ou propylène glycol méthyléther, le Dowanol DPM ou dipropylène glycol méthyléther et le Dowanol TPM ou tripropylène glycol méthyléther.It is also possible to introduce into the composition according to the invention a conventional plasticizer in order to enhance the plasticizing effect obtained with the copolymers of N-vinylpyrrolidone and N-vinylimidazolium. The plasticizing agent may be chosen from the group comprising: Carbitols from Union Carbide, namely Carbitol or diethylene glycol ethyl ether, methyl carbitol or diethylene glycol methyl ether, butyl
Carbitol or diethylene glycol butyl ether or else hexyl Carbitol or diethylene glycol hexyl ether, Cellosolves from Union Carbide namely Cellosolve or ethylene glycol ethyl ether, butyl Cellosolve or ethylene glycol butyl ether, hexyl
Cellosolve or ethylene glycol hexyl ether, propylene glycol derivatives and in particular propylene glycol phenyl ether, propylene glycol diacetate, dipropylene glycol butyl ether, tripropylene glycol butyl ether, and Dowanols from Dow Chemical, namely the
Dowanol PM or propylene glycol methyl ether, Dowanol DPM or dipropylene glycol methyl ether and Dowanol TPM or tripropylene glycol methyl ether.
On peut encore citer: - le diéthylène glycol méthyléther ou Dowanol DM de la société Dow Chemical, - I'huile de ricin oxyéthylénée à 40 moles d'oxyde d'éthylène telle que celle vendue par la société Rhône Poulenc sous la dénomination de "Mulgofen EL719", - I'alcool benzylique, - le citrate de triéthyle vendu sous par la société Pfizer sous la dénomination de "Citroflex-2", - le 1,3-butylène glycol, - les phtalates et adipates de diéthyle, de dibutyle et de diisopropyle, - les tartrates de diéthyle et de dibutyle, - les phosphates de diéthyle, de dibutyle et de diéthyl-2 hexyle, et - les esters de glycérol tels que le diacétate de glycérol (diacétine) et le triacétate de glycérol (triacétine).Mention may also be made of: - diethylene glycol methyl ether or Dowanol DM from Dow Chemical, - castor oil oxyethylenated with 40 moles of ethylene oxide, such as that sold by Rhône Poulenc under the name "Mulgofen" EL719 ", - benzyl alcohol, - triethyl citrate sold under the name Pfizer under the name" Citroflex-2 ", - 1,3-butylene glycol, - phthalates and adipates of diethyl, dibutyl and diisopropyl, - diethyl and dibutyl tartrates, - diethyl, dibutyl and diethyl-2 hexyl phosphates, and - glycerol esters such as glycerol diacetate (diacetin) and glycerol triacetate (triacetin) .
L'agent plastifiant complémentaire est alors généralement utilisé à une concentration comprise entre 0,1 et 15 % en poids par rapport au poids de poly
N-vinyl caprolactame.The complementary plasticizing agent is then generally used at a concentration of between 0.1 and 15% by weight relative to the weight of poly
N-vinyl caprolactam.
La composition peut contenir également divers additifs cosmétiques tels que des filtres solaires, des silicones, des polymères, des agents épaississants, des agents moussants, des protéines, des conservateurs, des parfums, des antioxydants, des agents anti-mousse, des colorants.The composition may also contain various cosmetic additives such as sunscreens, silicones, polymers, thickeners, foaming agents, proteins, preservatives, fragrances, antioxidants, defoamers, dyes.
On va maitenant donner des exemples concrets illustrant la présente invention sans toutefois la limiter.We will now give concrete examples illustrating the present invention without limiting it.
Exemple 1:
On a évalué le pouvoir laquant et les propriétés de poissage de cinq formulations de laques aérosol de compositions suivantes:
Formulation A: - poly N-vinyl caprolactame 8 g (comparatif) - eau qsp 100 g
Formulation B: - poly N-vinyl caprolactame 8 g (comparatif) - monométhyl éther de tripropylèneglycol 0,8 g
- eau qsp 100g
Formulation C: - poly N-vinyl caprolactame 8 g (comparatif) - monométhyl éther de tripropylèneglycol 2,4 g
- eau qsp 100g
Formulation D: - poly N-vinyl caprolactame 8 g (comparatif) - phosphate de triéthyle 3,2 g
-eau qsp 100g
Formulation E: - poly N-vinyl caprolactame 8 g (invention) - Luviquat FC 550 2 g
- eau qsp 100g
Luviquat FC 550: copolymère de N-vinyl pyrrolidone et de chlorure de méthyle
N-vinyl imidazolium (50/50)
poids moléculaire moyen: 80 000
Dans la formulation A, le poly N-vinyl caprolactame n'est pas plastifié. Dans les formulations B, C, et D le poly N-vinyl caprolactame est plastifié à l'aide de plastifiants classiques à un taux respectif de 10, 30, et 40 % en poids par rapport au poids de la résine. Dans la formulation E selon l'invention, le poly N-vinyl caprolactame est plastifié à un taux de 25 % en poids par rapport au poids de la résine.Example 1
The lacquering and the tack properties of five aerosol lacquer formulations of the following compositions were evaluated:
Formulation A: poly N-vinyl caprolactam 8 g (comparative) - water qs 100 g
Formulation B: - poly N-vinyl caprolactam 8 g (comparative) - tripropylene glycol monomethyl ether 0.8 g
- water qs 100g
Formulation C: - poly N-vinyl caprolactam 8 g (comparative) - tripropylene glycol monomethyl ether 2.4 g
- water qs 100g
Formulation D: - poly N-vinyl caprolactam 8 g (comparative) - triethyl phosphate 3.2 g
water qs 100g
Formulation E: Poly N-vinyl caprolactam 8 g (invention) - Luviquat FC 550 2 g
- water qs 100g
Luviquat FC 550: copolymer of N-vinyl pyrrolidone and methyl chloride
N-vinyl imidazolium (50/50)
average molecular weight: 80,000
In formulation A, the poly N-vinyl caprolactam is not plasticized. In formulations B, C, and D, the poly N-vinyl caprolactam is plasticized using conventional plasticizers at a respective level of 10, 30, and 40% by weight relative to the weight of the resin. In the formulation E according to the invention, the poly N-vinyl caprolactam is plasticized at a level of 25% by weight relative to the weight of the resin.
70 g de chaque formulation ont été conditionnés dans un récipient aérosol approprié et on a ajouté 309 de diméthyléther. On a procédé ensuite à la fixation de la valve et à la fermeture hermétique du récipient.70 g of each formulation was packaged in a suitable aerosol container and 309 dimethyl ether was added. The valve was then fixed and the container was sealed.
On a vaporisé pendant 10 secondes la laque sur des cheveux naturels. Après séchage à l'air libre, on a noté le pouvoir laquant et le poissage. La notation varie de 0 à 5, 0 représentant une absence de pouvoir laquant ou un fort poissage, 5 représentant au contraire un fort pouvoir laquant ou une absence de poissage.The lacquer was sprayed for 10 seconds on natural hair. After drying in the open air, lacquering and tackiness were noted. The notation varies from 0 to 5, 0 representing an absence of lacquering power or a strong tack, 5 on the contrary representing a high lacquering power or an absence of tackiness.
On a ainsi obtenu les résultats suivants:
<tb> Formulation <SEP> A <SEP> B <SEP> C <SEP> D <SEP> E <SEP>
<tb> Pouvoir <SEP> 0,5 <SEP> 0,5 <SEP> 0,7 <SEP> I <SEP> 1,5
<tb> laquant
<tb> Poissage <SEP> 5 <SEP> 5 <SEP> 3 <SEP> 4,2 <SEP> 5
<tb>
On constate que la formulation A contenant le polymère non plastifié n'apporte pas de pouvoir laquant. La formulation B contenant le polymère plastifié à 10 % avec un agent plastifiant classique n'apporte également pas de pouvoir laquant.<tb> Formulation <SEP> A <SEP> B <SEP> C <SEP> D <SEP> E <SEP>
<tb> Ability <SEP> 0.5 <SEP> 0.5 <SEP> 0.7 <SEP> I <SEP> 1.5
<tb> lacquering
<tb> Poissage <SEP> 5 <SEP> 5 <SEP> 3 <SEP> 4,2 <SEP> 5
<Tb>
It is found that the formulation A containing the unplasticized polymer does not provide lacquering power. Formulation B containing the 10% plasticized polymer with a conventional plasticizer also does not provide lacquering power.
Si l'on augmente le taux de plastification à 30 % (formulation C), le pouvoir laquant est peu amélioré et un poissage apparait. Pour atteindre un pouvoir laquant satisfaisant avec un agent plastifiant classique, il faut utiliser un taux de plastification de 40 % (formulation D) mais on observe également un défaut de poissage. Seule la formulation E conforme à l'invention permet d'obtenir à la fois un bon pouvoir laquant et une absence de poissage à un taux de plastification réduit (25%).If one increases the rate of plasticization to 30% (formulation C), the lacquering power is little improved and a tack appears. To achieve satisfactory lacquering with a conventional plasticizer, it is necessary to use a plasticization rate of 40% (formulation D) but there is also a tackiness defect. Only the formulation E according to the invention makes it possible to obtain both a good lacquering power and an absence of tack at a reduced plasticization rate (25%).
Exemple 2:
On a préparé une laque aérosol pour cheveux en conditionnant, dans un récipient aérosol approprié, 5,6 g de poly N-vinyl caprolactame vendu sous la référence 24743/86/2 par la société BASF, 1,4 g de "Luviquat FC 550" vendu par la société BASF et la quantité suffisante d'eau pour compléter à 70 g. Example 2
An aerosol hair spray was prepared by conditioning, in a suitable aerosol container, 5.6 g of poly N-vinyl caprolactam sold under the reference 24743/86/2 by the company BASF, 1.4 g of "Luviquat FC 550 "sold by the company BASF and the sufficient amount of water to supplement to 70 g.
On a introduit ensuite selon les techniques conventionnelles, 30 g de diméthyléther et on a procédé à la fixation de la valve et à la fermeture hermétique du récipient.30 g of dimethyl ether were then introduced according to conventional techniques and the valve was fastened and the container was sealed.
La valve peut être du type prise de gaz additionnelle en vue d'obtenir une pulvérisation plus fine.The valve may be of the additional gas intake type in order to obtain a finer spray.
Par application de la laque sur des cheveux naturels, on a constaté qu'elle a un excellent pouvoir laquant et ne provoque aucun effet de poissage lors de l'application et après séchage.By applying the lacquer to natural hair, it has been found that it has excellent lacquering power and does not cause any staining effect during application and after drying.
Exemple 3:
On a préparé une mousse de coiffage aérosol ayant la composition suivante: - Poly N-vinyl caprolactame vendu sous la référence 2473/86/2
par la société BASF 4 9 MA - Copolymère "Luviquat HM 552" de la société BASF 0,8 g MA - Alcool polyvinylique vendu sous la dénomination "Mowiol 4088"
par la société HOECHST 1g - Ethanol 8,6 g - Parfum, colorant, conservateur q.s.Example 3
An aerosol styling foam was prepared having the following composition: Poly N-vinyl caprolactam sold under the reference 2473/86/2
by BASF 4 9 MA - Copolymer "Luviquat HM 552" from BASF 0.8 g MA - Polyvinyl alcohol sold under the name "Mowiol 4088"
by the company HOECHST 1g - Ethanol 8.6 g - Fragrance, dye, preservative qs
- Eau qsp 100g
Luviquat HM 552: copolymère de N-vinyl pyrrolidone et de chlorure de méthyle
N-vinyl imidazolium (50/50)
poids moléculaire moyen: 500 000
On a introduit 90 g de la composition ainsi obtenue dans un boîtier aérosol sans tube plongeur. On a procédé à la fixation de la valve et à la fermeture hermétique du récipient, puis on a introduit 10 g d'un mélange de propulseur butaneliso butane/propane (3,2 105 Pa).- Water qs 100g
Luviquat HM 552: copolymer of N-vinyl pyrrolidone and methyl chloride
N-vinyl imidazolium (50/50)
average molecular weight: 500,000
90 g of the composition thus obtained were introduced into an aerosol casing without a dip tube. The valve was fastened and the container was sealed, and then 10 g of a butanelisobutane propane propellant mixture (3.2 × 10 5 Pa) was introduced.
Par pulvérisation, on a obtenu une mousse rigide et ferme qui apporte un bon pouvoir de fixation ainsi que de bonnes propriétés cosmétiques sans effet de polissage. By spraying, a rigid and firm foam was obtained which provides good fixing power as well as good cosmetic properties without polishing effect.
Claims (15)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9401342A FR2715841B1 (en) | 1994-02-07 | 1994-02-07 | Cosmetic hair composition containing a poly N-vinyl caprolactam and a copolymer of N-vinyl pyrrolidone and N-vinyl imidazolium and uses. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9401342A FR2715841B1 (en) | 1994-02-07 | 1994-02-07 | Cosmetic hair composition containing a poly N-vinyl caprolactam and a copolymer of N-vinyl pyrrolidone and N-vinyl imidazolium and uses. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2715841A1 true FR2715841A1 (en) | 1995-08-11 |
| FR2715841B1 FR2715841B1 (en) | 1996-03-29 |
Family
ID=9459842
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR9401342A Expired - Fee Related FR2715841B1 (en) | 1994-02-07 | 1994-02-07 | Cosmetic hair composition containing a poly N-vinyl caprolactam and a copolymer of N-vinyl pyrrolidone and N-vinyl imidazolium and uses. |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2715841B1 (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0715843A1 (en) * | 1994-12-07 | 1996-06-12 | Basf Aktiengesellschaft | Quaternized copolymers as agents in cosmetic preparations for hair styling aid |
| FR2771925A1 (en) * | 1997-12-04 | 1999-06-11 | Oreal | AEROSOL DEVICE COMPRISING AN AQUEOUS FIXING HAIR COMPOSITION PROPELLED BY DIMETHYLETHER, BASED ON A POLYMER WITH VINYL LACTAME PATTERNS |
| EP1435226A1 (en) * | 2003-01-02 | 2004-07-07 | L'oreal | Aerosol spraying device containing an aqueous hairstyling composition comprising a copolymer of N-vinyl pyrrolidone and N-vinyl imidazole |
| FR2990131A1 (en) * | 2012-05-07 | 2013-11-08 | Oreal | AEROSOL DEVICE BASED ON CALCIUM SALT AND FIXING POLYMER |
| US10449140B2 (en) | 2014-10-29 | 2019-10-22 | L'oreal | Composition based on styling powder and/or sebum-absorbing powder and an aluminium salt |
| US10532880B2 (en) | 2015-01-08 | 2020-01-14 | L'oreal | Aerosol device for hair shaping and/or style retention |
| US10710791B2 (en) | 2015-01-08 | 2020-07-14 | L'oreal | Hair treatment process that provides sheen using an aerosol device |
| US11071698B2 (en) | 2014-10-29 | 2021-07-27 | L'oreal | Composition comprising styling powder and/or sebum-absorbing powder and a zinc salt |
| US11135140B2 (en) | 2013-04-30 | 2021-10-05 | L'oreal | Aerosol device based on sebum-absorbing powder and calcium carbonate |
| US11154466B2 (en) | 2014-06-30 | 2021-10-26 | L'oreal | Aerosol device based on a calcium salt, on a fixing polymer, on a surfactant and on water |
| US11253438B2 (en) | 2017-03-09 | 2022-02-22 | L'oreal | Aerosol device for dry-washing and treating the hair |
| FR3113592A1 (en) * | 2020-09-01 | 2022-03-04 | L'oreal | FIXING FOAM FOR MAKEUP |
| US11370601B2 (en) | 2017-03-09 | 2022-06-28 | L'oreal | Aerosol device for hair shaping and/or hairstyle hold |
| US11641917B2 (en) | 2013-04-30 | 2023-05-09 | L'oreal | Multi-diffusion-orifice aerosol device for dry-washing the hair |
| US11667462B2 (en) | 2013-04-30 | 2023-06-06 | L'oreal | Aerosol device with multi-aperture diffusion for hair shaping and/or style holding |
| US11911490B2 (en) | 2017-03-09 | 2024-02-27 | L'oreal | Aerosol device for hair shaping and/or hairstyle hold |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB747806A (en) * | 1953-03-27 | 1956-04-11 | Gen Aniline & Film Corp | Hair waving and setting composition |
| EP0455081A1 (en) * | 1990-04-30 | 1991-11-06 | BASF Aktiengesellschaft | Hair fixing and hair care composition |
-
1994
- 1994-02-07 FR FR9401342A patent/FR2715841B1/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB747806A (en) * | 1953-03-27 | 1956-04-11 | Gen Aniline & Film Corp | Hair waving and setting composition |
| EP0455081A1 (en) * | 1990-04-30 | 1991-11-06 | BASF Aktiengesellschaft | Hair fixing and hair care composition |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0715843A1 (en) * | 1994-12-07 | 1996-06-12 | Basf Aktiengesellschaft | Quaternized copolymers as agents in cosmetic preparations for hair styling aid |
| FR2771925A1 (en) * | 1997-12-04 | 1999-06-11 | Oreal | AEROSOL DEVICE COMPRISING AN AQUEOUS FIXING HAIR COMPOSITION PROPELLED BY DIMETHYLETHER, BASED ON A POLYMER WITH VINYL LACTAME PATTERNS |
| EP1435226A1 (en) * | 2003-01-02 | 2004-07-07 | L'oreal | Aerosol spraying device containing an aqueous hairstyling composition comprising a copolymer of N-vinyl pyrrolidone and N-vinyl imidazole |
| FR2849593A1 (en) * | 2003-01-02 | 2004-07-09 | Oreal | AEROSOL DEVICE COMPRISING A HAIR CAPILLARY COMPOSITION IN AQUEOUS MEDIUM PROPELLED BY DIMETHYL ETHER BASED ON AT LEAST ONE COPOLYMER OF N-VINYL PYRROLIDONE AND N-VINYL IMIDAZOLE |
| FR2990131A1 (en) * | 2012-05-07 | 2013-11-08 | Oreal | AEROSOL DEVICE BASED ON CALCIUM SALT AND FIXING POLYMER |
| WO2013167530A3 (en) * | 2012-05-07 | 2014-08-07 | L'oreal | Aerosol device based on a calcium salt and a fixing polymer |
| CN104271106A (en) * | 2012-05-07 | 2015-01-07 | 欧莱雅 | Aerosol device based on a calcium salt and a fixing polymer |
| US11135140B2 (en) | 2013-04-30 | 2021-10-05 | L'oreal | Aerosol device based on sebum-absorbing powder and calcium carbonate |
| US11667462B2 (en) | 2013-04-30 | 2023-06-06 | L'oreal | Aerosol device with multi-aperture diffusion for hair shaping and/or style holding |
| US11641917B2 (en) | 2013-04-30 | 2023-05-09 | L'oreal | Multi-diffusion-orifice aerosol device for dry-washing the hair |
| US11154466B2 (en) | 2014-06-30 | 2021-10-26 | L'oreal | Aerosol device based on a calcium salt, on a fixing polymer, on a surfactant and on water |
| US11071698B2 (en) | 2014-10-29 | 2021-07-27 | L'oreal | Composition comprising styling powder and/or sebum-absorbing powder and a zinc salt |
| US10449140B2 (en) | 2014-10-29 | 2019-10-22 | L'oreal | Composition based on styling powder and/or sebum-absorbing powder and an aluminium salt |
| US10710791B2 (en) | 2015-01-08 | 2020-07-14 | L'oreal | Hair treatment process that provides sheen using an aerosol device |
| US10532880B2 (en) | 2015-01-08 | 2020-01-14 | L'oreal | Aerosol device for hair shaping and/or style retention |
| US11253438B2 (en) | 2017-03-09 | 2022-02-22 | L'oreal | Aerosol device for dry-washing and treating the hair |
| US11370601B2 (en) | 2017-03-09 | 2022-06-28 | L'oreal | Aerosol device for hair shaping and/or hairstyle hold |
| US11911490B2 (en) | 2017-03-09 | 2024-02-27 | L'oreal | Aerosol device for hair shaping and/or hairstyle hold |
| FR3113592A1 (en) * | 2020-09-01 | 2022-03-04 | L'oreal | FIXING FOAM FOR MAKEUP |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2715841B1 (en) | 1996-03-29 |
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