FR1290837A - New reducto-oxidizable anthraquinone polymers, their preparation processes and their application to the manufacture of hydrogen peroxide - Google Patents

New reducto-oxidizable anthraquinone polymers, their preparation processes and their application to the manufacture of hydrogen peroxide

Info

Publication number
FR1290837A
FR1290837A FR847848A FR847848A FR1290837A FR 1290837 A FR1290837 A FR 1290837A FR 847848 A FR847848 A FR 847848A FR 847848 A FR847848 A FR 847848A FR 1290837 A FR1290837 A FR 1290837A
Authority
FR
France
Prior art keywords
hydrogen peroxide
resin
polymer
aqueous
oxidizable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR847848A
Other languages
French (fr)
Inventor
Andre Etienne
Georges Izoret
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Priority to FR847848A priority Critical patent/FR1290837A/en
Priority to GB4607061A priority patent/GB965676A/en
Priority to GB4607261A priority patent/GB965678A/en
Priority to GB4607161A priority patent/GB965677A/en
Application granted granted Critical
Publication of FR1290837A publication Critical patent/FR1290837A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/676—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01—Hydrogen peroxide
    • C01B15/022—Preparation from organic compounds
    • C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/36—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by a ketonic radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C08G63/54—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Hydrogen peroxide is produced from a reducible-oxidizable polymer having anthraquinone groups by cyclically reducing and then oxidizing the polymer by means of air or oxygen in the presence of a solvent for hydrogen peroxide. Specified polymers are polyvinyl anthraquinones, polyanthraquinonyl - methylene-malonates of linear polyalcohols having alcohol groups at each end, and acetals of formyl-2-anthraquinones and polyvinyl alcohols or acetates (see Specifications 965,676 and 965,677). They are preferably in the form of spheres, plates or strips and are reduced catalytically, e.g. palladium on alumina, or by aqueous reducing agents, e.g. titanium trichloride in hydrochloric acid, and sodium hydrosulphite. The re-oxidation may be achieved in the presence of a hydrogen peroxide stabilizer, e.g. sodium metaphosphate. An apparatus is described in which the polymer is held in a vertical tube through the top of which is introduced, in an inert atmosphere, the aqueous reducing agent. The resin is washed in an ascending current of water and air or oxygen is then blown up through the tube. The hydrogen peroxide is recovered as an aqueous solution by washing the resin. The reactions may also be effected on the polymers dissolved in a solvent, e.g. dimethyl formamide for catalytic hydrogenation, either alone or with aqueous alkali. After oxidation, the resin precipitates on dilution with water.
FR847848A 1960-12-23 1960-12-23 New reducto-oxidizable anthraquinone polymers, their preparation processes and their application to the manufacture of hydrogen peroxide Expired FR1290837A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR847848A FR1290837A (en) 1960-12-23 1960-12-23 New reducto-oxidizable anthraquinone polymers, their preparation processes and their application to the manufacture of hydrogen peroxide
GB4607061A GB965676A (en) 1960-12-23 1961-12-22 Polyesters
GB4607261A GB965678A (en) 1960-12-23 1961-12-22 A process for the production of hydrogen peroxide
GB4607161A GB965677A (en) 1960-12-23 1961-12-22 New reducible oxidisable polymers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR847848A FR1290837A (en) 1960-12-23 1960-12-23 New reducto-oxidizable anthraquinone polymers, their preparation processes and their application to the manufacture of hydrogen peroxide

Publications (1)

Publication Number Publication Date
FR1290837A true FR1290837A (en) 1962-04-20

Family

ID=8745400

Family Applications (1)

Application Number Title Priority Date Filing Date
FR847848A Expired FR1290837A (en) 1960-12-23 1960-12-23 New reducto-oxidizable anthraquinone polymers, their preparation processes and their application to the manufacture of hydrogen peroxide

Country Status (2)

Country Link
FR (1) FR1290837A (en)
GB (3) GB965678A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995010480A1 (en) * 1993-10-14 1995-04-20 Guillet James E Production of hydrogen peroxide

Families Citing this family (24)

* Cited by examiner, † Cited by third party
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US5624543A (en) * 1995-08-01 1997-04-29 Peroxco Incorporated Aqueous phase production of hydrogen peroxide and catalysts for use therein
WO2000003303A1 (en) * 1998-07-10 2000-01-20 Clariant International Ltd. Composition for bottom reflection preventive film and novel polymeric dye for use in the same
US10414839B2 (en) 2010-10-20 2019-09-17 Sirrus, Inc. Polymers including a methylene beta-ketoester and products formed therefrom
US9279022B1 (en) 2014-09-08 2016-03-08 Sirrus, Inc. Solution polymers including one or more 1,1-disubstituted alkene compounds, solution polymerization methods, and polymer compositions
US9249265B1 (en) 2014-09-08 2016-02-02 Sirrus, Inc. Emulsion polymers including one or more 1,1-disubstituted alkene compounds, emulsion methods, and polymer compositions
US9828324B2 (en) 2010-10-20 2017-11-28 Sirrus, Inc. Methylene beta-diketone monomers, methods for making methylene beta-diketone monomers, polymerizable compositions and products formed therefrom
MX370256B (en) 2011-10-19 2019-12-09 Sirrus Inc Multifunctional monomers, methods for making multifunctional monomers, polymerizable compositions and products formed therefrom.
JP6553505B2 (en) 2012-03-30 2019-07-31 シラス・インコーポレイテッド Composite and laminate articles and polymerization systems for making them
CA2869115A1 (en) 2012-03-30 2013-10-03 Bioformix Inc. Ink and coating formulations and polymerizable systems for producing the same
WO2013181600A2 (en) 2012-06-01 2013-12-05 Bioformix Inc. Optical material and articles formed therefrom
WO2014078689A1 (en) 2012-11-16 2014-05-22 Bioformix Inc. Plastics bonding systems and methods
WO2014085570A1 (en) 2012-11-30 2014-06-05 Bioformix, Inc. Composite compositions for electronics applications
CN105008321A (en) 2013-01-11 2015-10-28 瑟拉斯公司 Method to obtain methylene malonate via bis(hydroxymethyl) malonate pathway
US9315597B2 (en) 2014-09-08 2016-04-19 Sirrus, Inc. Compositions containing 1,1-disubstituted alkene compounds for preparing polymers having enhanced glass transition temperatures
US9416091B1 (en) 2015-02-04 2016-08-16 Sirrus, Inc. Catalytic transesterification of ester compounds with groups reactive under transesterification conditions
US10501400B2 (en) 2015-02-04 2019-12-10 Sirrus, Inc. Heterogeneous catalytic transesterification of ester compounds with groups reactive under transesterification conditions
US9334430B1 (en) 2015-05-29 2016-05-10 Sirrus, Inc. Encapsulated polymerization initiators, polymerization systems and methods using the same
US9217098B1 (en) 2015-06-01 2015-12-22 Sirrus, Inc. Electroinitiated polymerization of compositions having a 1,1-disubstituted alkene compound
US9518001B1 (en) 2016-05-13 2016-12-13 Sirrus, Inc. High purity 1,1-dicarbonyl substituted-1-alkenes and methods for their preparation
US10196481B2 (en) 2016-06-03 2019-02-05 Sirrus, Inc. Polymer and other compounds functionalized with terminal 1,1-disubstituted alkene monomer(s) and methods thereof
US9617377B1 (en) 2016-06-03 2017-04-11 Sirrus, Inc. Polyester macromers containing 1,1-dicarbonyl-substituted 1 alkenes
US9567475B1 (en) 2016-06-03 2017-02-14 Sirrus, Inc. Coatings containing polyester macromers containing 1,1-dicarbonyl-substituted 1 alkenes
US10428177B2 (en) 2016-06-03 2019-10-01 Sirrus, Inc. Water absorbing or water soluble polymers, intermediate compounds, and methods thereof
US20210363008A1 (en) * 2018-08-02 2021-11-25 Evonik Corporation Process for preparing a stabilized aqueous hydrogen peroxide solution

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995010480A1 (en) * 1993-10-14 1995-04-20 Guillet James E Production of hydrogen peroxide

Also Published As

Publication number Publication date
GB965678A (en) 1964-08-06
GB965676A (en) 1964-08-06
GB965677A (en) 1964-08-06

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