EP1909971A2 - Substrate comprising at least one entire surface or partial surface macrostructured layer, method for the production thereof and its use - Google Patents
Substrate comprising at least one entire surface or partial surface macrostructured layer, method for the production thereof and its useInfo
- Publication number
- EP1909971A2 EP1909971A2 EP06776219A EP06776219A EP1909971A2 EP 1909971 A2 EP1909971 A2 EP 1909971A2 EP 06776219 A EP06776219 A EP 06776219A EP 06776219 A EP06776219 A EP 06776219A EP 1909971 A2 EP1909971 A2 EP 1909971A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- sol
- layer
- substrate
- gel
- gel solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 104
- 238000000034 method Methods 0.000 title claims abstract description 98
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 238000000576 coating method Methods 0.000 claims abstract description 32
- 239000011248 coating agent Substances 0.000 claims abstract description 22
- 238000001035 drying Methods 0.000 claims abstract description 16
- 239000010410 layer Substances 0.000 claims description 160
- 230000008569 process Effects 0.000 claims description 35
- 239000011521 glass Substances 0.000 claims description 33
- 239000002904 solvent Substances 0.000 claims description 33
- 238000007639 printing Methods 0.000 claims description 31
- 239000002241 glass-ceramic Substances 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 238000009835 boiling Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 15
- 239000000654 additive Substances 0.000 claims description 14
- 239000000049 pigment Substances 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 229910044991 metal oxide Inorganic materials 0.000 claims description 10
- 150000004706 metal oxides Chemical class 0.000 claims description 10
- 239000003973 paint Substances 0.000 claims description 10
- -1 enamel Substances 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 238000010411 cooking Methods 0.000 claims description 8
- 239000002346 layers by function Substances 0.000 claims description 8
- 230000000873 masking effect Effects 0.000 claims description 8
- 229920002120 photoresistant polymer Polymers 0.000 claims description 8
- 239000000975 dye Substances 0.000 claims description 7
- 238000007650 screen-printing Methods 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 210000003298 dental enamel Anatomy 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 239000004033 plastic Substances 0.000 claims description 6
- 229920003023 plastic Polymers 0.000 claims description 6
- 230000001680 brushing effect Effects 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 5
- 238000004132 cross linking Methods 0.000 claims description 5
- 230000035622 drinking Effects 0.000 claims description 5
- 238000009434 installation Methods 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 230000009974 thixotropic effect Effects 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 239000005328 architectural glass Substances 0.000 claims description 4
- 239000000314 lubricant Substances 0.000 claims description 4
- 239000003607 modifier Substances 0.000 claims description 4
- 238000007649 pad printing Methods 0.000 claims description 4
- 230000001699 photocatalysis Effects 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- 239000002023 wood Substances 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 230000000845 anti-microbial effect Effects 0.000 claims description 3
- 230000002155 anti-virotic effect Effects 0.000 claims description 3
- 229910052810 boron oxide Inorganic materials 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 238000005034 decoration Methods 0.000 claims description 3
- 238000007646 gravure printing Methods 0.000 claims description 3
- 239000012702 metal oxide precursor Substances 0.000 claims description 3
- 238000000059 patterning Methods 0.000 claims description 3
- 229910001392 phosphorus oxide Inorganic materials 0.000 claims description 3
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 claims description 3
- 229910001887 tin oxide Inorganic materials 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 2
- 230000003666 anti-fingerprint Effects 0.000 claims description 2
- 238000007645 offset printing Methods 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 229910010293 ceramic material Inorganic materials 0.000 claims 2
- 238000007641 inkjet printing Methods 0.000 claims 2
- 229910001220 stainless steel Inorganic materials 0.000 claims 2
- 239000010935 stainless steel Substances 0.000 claims 2
- 230000000996 additive effect Effects 0.000 claims 1
- 239000006103 coloring component Substances 0.000 claims 1
- 230000000295 complement effect Effects 0.000 claims 1
- 239000000417 fungicide Substances 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 15
- 239000002966 varnish Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 49
- 239000007788 liquid Substances 0.000 description 9
- 229910004298 SiO 2 Inorganic materials 0.000 description 8
- 239000004922 lacquer Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 229910010413 TiO 2 Inorganic materials 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 5
- 238000007598 dipping method Methods 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 238000003384 imaging method Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 238000003980 solgel method Methods 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 230000008719 thickening Effects 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910000502 Li-aluminosilicate Inorganic materials 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000001532 anti-fungicidal effect Effects 0.000 description 2
- 239000006117 anti-reflective coating Substances 0.000 description 2
- 230000003667 anti-reflective effect Effects 0.000 description 2
- 239000003125 aqueous solvent Substances 0.000 description 2
- 239000005352 borofloat Substances 0.000 description 2
- 239000005388 borosilicate glass Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000006119 easy-to-clean coating Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000005329 float glass Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 239000006128 CERAN Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910008556 Li2O—Al2O3—SiO2 Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000006094 Zerodur Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000005354 aluminosilicate glass Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000006116 anti-fingerprint coating Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000000010 aprotic solvent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- BGTFCAQCKWKTRL-YDEUACAXSA-N chembl1095986 Chemical compound C1[C@@H](N)[C@@H](O)[C@H](C)O[C@H]1O[C@@H]([C@H]1C(N[C@H](C2=CC(O)=CC(O[C@@H]3[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O3)O)=C2C=2C(O)=CC=C(C=2)[C@@H](NC(=O)[C@@H]2NC(=O)[C@@H]3C=4C=C(C(=C(O)C=4)C)OC=4C(O)=CC=C(C=4)[C@@H](N)C(=O)N[C@@H](C(=O)N3)[C@H](O)C=3C=CC(O4)=CC=3)C(=O)N1)C(O)=O)=O)C(C=C1)=CC=C1OC1=C(O[C@@H]3[C@H]([C@H](O)[C@@H](O)[C@H](CO[C@@H]5[C@H]([C@@H](O)[C@H](O)[C@@H](C)O5)O)O3)O[C@@H]3[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O3)O[C@@H]3[C@H]([C@H](O)[C@@H](CO)O3)O)C4=CC2=C1 BGTFCAQCKWKTRL-YDEUACAXSA-N 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000005293 duran Substances 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000005292 fiolax Substances 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 230000009975 flexible effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 108010025899 gelatin film Proteins 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000005304 optical glass Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000002444 silanisation Methods 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000010934 sterling silver Substances 0.000 description 1
- 229910000898 sterling silver Inorganic materials 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/32—Processes for applying liquids or other fluent materials using means for protecting parts of a surface not to be coated, e.g. using stencils, resists
- B05D1/322—Removable films used as masks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/02—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a matt or rough surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/40—Distributing applied liquids or other fluent materials by members moving relatively to surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0254—After-treatment
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C15/00—Details
- F24C15/02—Doors specially adapted for stoves or ranges
- F24C15/04—Doors specially adapted for stoves or ranges with transparent panels
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
Definitions
- Substrate comprising at least one fully or partially macrostructured layer, process for their preparation and their use
- the invention relates to a substrate comprising at least one fully or partially macrostructured layer, processes for their preparation and their use.
- sol-GeI sol-gel layers
- the sol-gel solutions used have different viscosities. Often, however, this is in the order of magnitude of aqueous solutions and is therefore very low.
- the application of the layers takes place over the entire surface using common Application methods, such as dipping, flooding, spraying, spraying, pouring, brushing, rolling or spinning. As a rule, the layers are cured by a subsequent tempering step.
- a method for producing a sintered structure on a substrate wherein a particle-containing liquid, such as a sol-gel solution, applied by an inkjet printer to a substrate and evaporated the liquid applied by means of a laser pulse and so layered a sintered structure is built.
- a particle-containing liquid such as a sol-gel solution
- WO 02/17347 A1 discloses a method for solidifying and structuring a sol-gel composition on a surface of a substrate, wherein a layer of a sol-gel composition is deposited on a surface of a substrate, an electron beam is irradiated onto selected areas of the substrate. GeI film is set to cure the SoI-GeI-FiIm and the non-cured areas are removed with a solvent again.
- EP 0 329 026 A1 relates to an ink-jet ink and printing method, wherein the ink comprises 90 to 99.9% by weight of an aqueous sol-gel medium, preferably a mixture of carrageenan and water, and 0.1 to 10% by weight of a coloring agent, and the ink represents a thermally reversibly convertible sol-gel ink which is a gel at ambient temperature and at temperatures between about 40 0 C and 100 0 C represents a sol.
- the ink is applied to the substrate as a sol, where it forms a gel upon cooling.
- the substrate used is almost exclusively paper into which the ink penetrates.
- US Pat. No. 5,970,873 relates to an imaging process comprising imagewise applying a mixture of a sol precursor and a liquid as a thin layer to a substrate and removing the liquid from the thin layer to imagewise form an insoluble, crosslinked, polymeric solubilizer.
- an imaging element made by the process such as a lithographic printing plate, will also be described.
- the image area created in the sol-gel matrix therefore serves as a "negative" to which ink is applied, which is then transferred to a suitable receptor material to reproduce the image.
- WO 99/33760 discloses a method of providing an article with visually-visible patterns wherein first at least a surface area of a substrate is masked, then at least one thin layer is applied to the masked and unmasked areas of the surface and the mask is removed to remove the mask to create desired patterns.
- the article produced therewith has at least a first portion carrying a generally transparent thin film selected from metal-containing, semi-metal-containing coatings and combinations thereof, which when viewed under reflected light exhibits a first color and exhibits a second color under light passing therethrough , as well as a second section, visibly different in contrast to the first.
- the SoI-GeI technology is mentioned, but no explanation is given how this can be done.
- DE 100 19 822 A1 describes a lift-off method for microstructuring thin layers, wherein a mask is applied to a substrate is applied, which contains recesses at the points to be coated, a SoI is applied over the entire surface of the substrate covered with the mask, the SoI-FiIm cured, the mask removed together with the present on the mask surface hardened SoI and the hardened SoI-FiIm by Supplying energy is converted to the desired solid state.
- a micro-frosted thin film device manufactured by this method such as a semiconductor device.
- the present invention is based on the object, in a development of the prior art, to provide a flexible, non-expensive and cost-effective method by means of which structures can be produced on a substrate in a simple manner. In particular, it should be possible to provide any substrate with a desired structure.
- a substrate comprising at least one fully or partially macrostructured layer obtainable by a method (a):
- the invention also provides 3 process variants for the production of the substrate according to the invention, which according to variant (a) has the following steps: ,
- process according to the invention according to process variant (b1) comprises the following steps:
- the process variant (b2) according to the invention has the following steps:
- Sol-gel layer (2) applying a resist to the sol-gel layer, either already in structured form or creating a structure in the resist after application;
- step (1) Optional stoving of the patterned, dried sol-gel layer to give a cured sol-gel layer unless already done in step (1).
- the present invention accordingly comprises substrates having a structured
- a sol-gel solution is used.
- structure is to be construed as broad as possible according to the invention and includes, for example, a pattern, logo, image (s), words, a mark, hatching, marking, inscriptions, in one or more defined optical manifestations, functionalities or the like be provided over the entire surface or only part of a surface on a substrate.
- sol-gel system i. a sol which forms a thin, preferably transparent, gel film after drying, which preferably hardens by baking / tempering.
- sol-gel layer in the present invention is intended to represent a layer prepared by a sol-gel method.
- nanosols can be used.
- the average particle diameter of such sols is in the range ⁇ 800 nm, preferably ⁇ 200 nm, particularly preferably ⁇ 100 nm. 06856
- the sol-gel layer is based on one or more metal oxides and is preferably selected from at least one titanium, zirconium, silicon, aluminum, tin, boron or phosphorus oxide or mixtures thereof. Particular preference is given to containing silicon oxide, but other or further ones may also be used
- Metal oxides are present.
- metal also the semimetals, such as silicon and germanium, understood.
- sol-gel solutions for example, so-called classic sol-gel solutions are used according to the invention in addition to a suitable amount of desired additives, a metal oxide precursor, a solvent, a minor amount of water for precondensation and a catalyst (acid or base).
- colloidal metal oxide solutions solutions of nanoscale metal oxide powders in water or other solvents are used, in some cases, classical sol-gel solutions are additionally mixed with nanoscale metal oxide powders an aqueous / organic solvent, such as, for example, ethanol or acetone
- Sol-gel solutions which are long-term stable can also be stored in purely organic solvents
- These sols are clear and stable solutions with solids contents generally in the range from about 1 to about 30% by weight. %. The metal oxide contents but can also be significantly higher.
- the sol-gel matrix can also be modified chemically in any manner by co-hydrolysis or co-condensation. These modifications are the
- sol-gel coating can be carried out directly in structured form according to process variant (a) according to the invention using various printing techniques.
- digital, tampon and gravure printing are to be mentioned, since they are particularly well suited for the processing of low-viscosity liquids.
- the sol-gel solution which is converted to the sol-gel layer can be applied directly in structured form:
- Structured liquid coatings can generally be applied to the substrate using known printing technologies, but so far this has not been known for sol-gel solutions used to make functional layers.
- Conventional sol-gel solutions dry very quickly, which can cause great difficulties in printing techniques. Without a modification of the solution, especially the solvents, many methods are unusable because the coating reacts on the transfer medium or in the printing nozzles. It is important that no / hardly any condensation reactions take place during the printing process.
- the present invention now provides ways in which - in contrast to the prior art - known printing technologies can be used, whereby the above problems are minimized or completely avoided.
- sol-gel solutions tailor-made for the special printing technology, which includes, for example, a modification of the viscosity of the solution and / or a suitable choice of the solvent, makes it the first time hitherto unavailable printing technologies accessible.
- a highly viscous sol-gel solution can be used for screen printing. In digital printing, however, it is desirable if the solution is low viscosity.
- sol-gel solutions generally have a comparatively low viscosity
- the digital, tampon and intaglio printing are suitable for the production of structured coated articles.
- the application of the sol-gel solution in already structured form according to the process (a) according to the invention is therefore carried out on the substrate, preferably with a low-viscosity sol-gel solution using a known printing process.
- low viscosity is meant in the present invention, a viscosity in the range of about 0.1 to about 10 4 mPa s.
- the airbrush (resolution 42 dpi) and the ink-jet technology (resolution around 1400 dpi) prove to be particularly suitable.
- the piezoelectric technique is preferred, since the sol-gel solutions are exposed here in contrast to the bubble variant no temperature stresses that can lead to the curing of the sol.
- only one sol-gel solution is generally required according to the invention for the production of functional layers.
- structured layers in particular substrates with structured layers, for example decorative color layers, are to be produced on a sol-gel basis, preferably also pigment-filled layers are used
- Color formulations which contain a sol-gel solution, for example as a binder.
- a sol-gel solution for example as a binder.
- thickening additives are, for example, cellulose, cellulose ethers, starch, aerosils (pyrogenic silicas), bentones, hydrophobically modified polyoxyethylenes, acrylates, polyurethanes, polyamides, polyolefins, Castor oil and basic sulphonates.
- thickening additives are added and a highly viscous, sufficiently thixotropic sol-gel solution is obtained, the application of the structured coating is also possible by means of screen printing or other printing techniques, such as offset, pad and pad printing.
- a "high-viscosity”, “sufficiently thixotropic” sol-gel solution is understood here to mean that the viscosity-in the absence of shear forces-is above a limit of about 10 3 mPa s, in particular about 10 4 to 10 6 mPa s.
- Thixotropy refers to the property of a non-Newtonian fluid to exhibit a lower viscosity after shearing and to rebuild at rest.
- the sol-gel layer can be applied over the entire surface of the substrate and subsequently structured in further working steps:
- these can be applied directly to the substrate as positive coatings at the points of the layer to be structured (process variant (b1) according to the invention).
- a printable topcoats used.
- the application of the Abdecklacks can already be done preferably in a structured form.
- a photoresist is used.
- the structuring can also take place after a full-area application of the photoresist in a second step with the aid of an exposure step and subsequent removal of the areas not to be lacquered. Subsequently, the full surface coating of the prepared substrate is carried out using the sol-gel solution.
- (screen) printable paints is preferred over that of photo-resists because they are significantly less expensive and their application is associated with a significantly lower cost.
- solvent or dispersant or solvent mixture suitable for such a process can be used as solvent or dispersant for the sol-gel solution of all processes according to the invention.
- examples are water and alcohols, for example ethanol, or alcohol-water mixtures.
- alcohols for example, alcohols, but also aprotic solvents, such as dioxane, or aqueous solvents can be used.
- the sol-gel layers applied according to the invention which are used in process variants (b1) and (b2) according to the invention, preferably have layer thicknesses in the range from 1 nm to 100 .mu.m, preferably 1 nm to 1 .mu.m, in particular 1 to 200 nm.
- the (preferred) layer thicknesses vary greatly. If only a few monolayers are deposited on the substrate in the case of an easy-to-clean layer, ie the layer thickness moves here in the nm range, then it may be preferred if pigment-filled, decorative sol-gel layers are opaque. This is achieved, for example, with layer thicknesses of at least 10 ⁇ m or significantly higher.
- a fully or partially coated layer is to be applied, it is preferably applied by a spraying or dipping method, wherein all other methods known to the person skilled in the art can also be used, for example spinning, roll coating (rolling), brushing, casting or knife coating ,
- drying according to process variant (b1) is preferably carried out in a temperature range from room temperature (25 ° C.) to 300 ° C. until substantially all the solvent has been removed, the solvent of the sol-gel solution being water, alcohol, all known to the person skilled in the art , in particular common, preferably halogen-free, low (boiling point: up to 120 0 C) and high-boiling solvents (boiling point: 120 to 250 0 C) and mixtures thereof are preferred.
- the drying time is generally in the range of a few minutes to 1 or more days.
- the quality of the layers formed in this way is sufficient, so that no further production step is required for baking. It is not possible to specify preferred drying times since these can be very different depending on the application.
- a "burn-in" means that the dried sol-gel layer is converted into its final form by chemical reaction, sintering and / or excitation of diffusion processes Layer for a period of 10 minutes to 3 hours a temperature in the range between room temperature and 800 0 C, preferably between 250 and 800 0 C. exposed.
- Coating lacquers generally can not be exposed to the temperatures necessary for curing the sol-gel layers, so that they are removed before stoving.
- Baking has the advantage that the mechanical and chemical resistance of the layer increases drastically. In some cases, the layer only gets its actually desired function by the burn-in. The coated article in these cases can be used only after the baking step in the respective application.
- Burning in can also specifically influence certain properties of the layer.
- the optical antireflection depends on SiO 2 -Ti ⁇ 2 -Wechsel Anlagensystemen (anti-reflection) but also on the refractive indices of the respective, present in the layer packet from individual layers. This in turn is structurally dependent.
- the chemical structure varies depending on the choice of baking conditions.
- the anti-reflection effect of such coating systems depends crucially on the conditions during the penetration of the layers.
- the sol-gel layer is preferably already converted into its final form, so that further post-treatment steps are not necessary.
- microstructures are produced in the present invention that can be used, for example, in semiconductor components, and become visible to the naked eye, for example, only under a microscope.
- macrostructured regions for example coarse-structured, optionally large-area regions, are produced. This means that structures in the order of up to a minimum of about 50 to 100 microns (corresponding to about the width of a hair) can be made, so that always visible to the eye structures are produced.
- a transfer of such Microstructures on macrostructures would not be considered by a person skilled in the art due to the well-known special status of semiconductor technology.
- the masking resist as a negative resist to a substrate which is already provided with the sol-gel layer over its entire area (inventive ' process variant (b2)).
- the evaporation of the solvent or drying according to process variant (b2) is preferably carried out in a temperature range from room temperature to max. 200 0 C until essentially all of the solvent has been removed, being used as the solvent of the sol-gel solution, water, alcohol, all known in the art, especially common, preferably halogen-free, low (boiling point: up to 120 0 C) and high-boiling solvent (Boiling point: 120 to 250 ° C) and mixtures thereof are preferred.
- the drying time is generally in the range of a few minutes to 1 or more days. Because of the diversity of the layers to be produced, the above information is only exemplary.
- the patterning of the resist can advantageously be effected by means of suitable (screen) printing methods, i. Applying the resist in structured form, or photolithographically, i. after application, done.
- the sol-gel layer is then removed at the exposed locations, for example with a suitable chemical etching solution.
- a suitable chemical etching solution may be, for example, an aqueous NaOH solution or an aqueous HF solution.
- the covering is again mechanically, chemically or pyrolytically - as already described - removed.
- the Abdecklack which is applied either in a structured form or structured after the order is not baked.
- any known in the art paint can be used.
- paint classes such as: topcoats, Peel-off lacquers, photostructurable lacquers (liquid resists, dry resists).
- Usable commercially available products are, for example: covering lacquer 80 2039 (from Ferro), Wepelan covering lacquer SD 2154 E (Peters), stripping lacquer SD 2962 P (Peters), liquid resist AZ 9260 (from Clariant), liquid resist AZ nLOF 2070 (Clariant), dry resist EtchMaster ES-102 (DuPont) and dry resist Riston 220 (DuPont).
- the sol-gel solution used according to the invention preferably contains further constituents selected from the group consisting of inorganic and / or organic dyes, pigments and / or additives, such as thickeners, dispersants, defoamers, anti-settling agents,
- Additives can be used, for example, for the specific introduction of specific functionalities.
- organic and / or inorganic dyes or pigments for example, additional color effects can be produced.
- pigments are able to introduce further functionalities, such as IR or UV reflection, into the layer.
- sol-gel solution which comprises or consists of the following components:
- metal oxide from about 1 to about 80% by weight of metal oxide, metal oxide precursors or metals such as SiO 2 , alkoxysilanes, alkylalkoxysilanes, fluorinated alkylalkoxysilanes, TiO 2 , titanium alkoxides, colloidal silver or colloidal silver compounds,
- solvents such as water, alcohols and all known in the art, especially common, preferably halogen-free, low (boiling point: up to 120 X) and high-boiling solvent (boiling point: 120 to 250 0 C);
- catalyst such as concentrated hydrochloric, sulfuric or nitric acid or alkali such as sodium or potassium hydroxide
- colorant component such as organic or inorganic colored pigments or organic dyes
- additives such as thickeners, dispersants, processing aids, defoamers, deaerators, anti-settling agents, surface tension modifiers, lubricants and leveling agents, crosslinking additives, primers, etc.
- the total amount of all components of the sol-gel solution naturally complements 100% by weight.
- the substrate in the above method provided with one or more structures is not particularly limited in the present invention. Any type of material may be used, such as, for example, plastic, metal, wood, enamel, glass, ceramics, in particular glass-ceramic, preference being given to glass and glass-ceramic substrates.
- alkali-containing float glasses such as borosilicate glasses (eg Borofloat 33, Borofloat 40, Duran from Schott AG, Mainz), as well as alkali-free glasses (eg AF 37, AF 45 from Schott AG, Mainz), aluminosilicate glasses (eg Fiolax, Illax from Schott AG, Mainz), alkaline earth glasses (eg B 270, BK 7 from Schott AG, Mainz), Li 2 O-Al 2 O 3 -SiO 2 -FlOaIgIaS, discolored float glass with an iron concentration below 700 ppm, preferably below 200 ppm , and in a more specific application soda-lime glasses, especially the latter being preferred.
- display glasses such as D263 from Schott-DESAG, Grünenplan. In principle, all known technical and optical glasses can be used.
- Typical glass ceramics which are used as alkali-containing glass-ceramics such as lithium aluminosilicate (LAS) glass-ceramics, such as CERAN ®, ® or ROBAX ZERODUR ® (all brands of Schott AG, Mainz), but also alkali-free glass ceramics, such as magnesium aluminosilicates (MAS) can be used.
- LAS lithium aluminosilicate
- CERAN ® ®
- ROBAX ZERODUR ® all brands of Schott AG, Mainz
- MAS magnesium aluminosilicates
- the substrate is not particularly limited in the invention not only in terms of the material but also in terms of shape, so that, for example, flat, round, rounded large and small objects can be used. Preference is given to objects made of or with glass and / or glass ceramics of any shape, such as glass tubes, glass lenses, ampoules, carpets, bottles, cans, disks, plates or any shaped parts.
- an optionally surface-treated substrate as well as a substrate already provided with a layer, for example a surface-treated or already coated glass.
- the substrate is provided at least on a part of its surface with a macrostructure according to the present invention.
- the entire surface may also be structured or the structure may be present on multiple parts of one or more surfaces.
- the structure can be applied, for example, on one or both sides, according to the shape of a substrate also on several sides.
- substrates tiles, enamel parts, panes, in particular viewing panes, plates, panels, glazings of all kinds, shower enclosures, covers, work and cooking surfaces, as part of refrigerators or freezers, dining or drinking utensils, containers, Fire protection windows, fireplace panes, oven panes as a glass cover for solar energy systems, medical glass, especially a Med ikamentenf tabs, windows or covers for displays, a component of hi-fi or computing or telecommunications equipment and the like. It goes without saying that in addition to single layers and multi-layer systems can be used to produce a desired macrostructure.
- the invention also relates to the partially or completely macro-structured layers produced according to the invention.
- These can be used, for example, in the form of functional layers, i. the partial or full-surface structured layer has one or more specific functions or properties.
- functional layers structured according to the invention are anti-reflection layers, color layers, decorative layers, photocatalytic layers, antimicrobial layers, anti-virus layers, anti-mold layers, anti-fungicidal layers, anti-algae layers, anti-fogging layers, Cleaning layers, odor neutralization layers, anti-fingerprint layers, air cleaning layers, or combinations thereof.
- substrates according to the invention comprising a fully or partially macrostructured layer
- examples include:
- Tiles such as ceramic, enamel or glass tiles; - Enamel parts, especially in oven muffles;
- Glazings of all kinds especially windows, for example
- Insulating glass doors for cabinets - Picture Frame
- Covers for example for displays
- Pool linings such as swimming pool coverings, fish breeding ponds
- Mirrors for example retro-reflective traffic mirrors
- - Walls in particular outer walls, for example of trains
- Discs such as viewing windows, in particular oven panes, chimney and microwave viewing panes
- Store window such as Boards, such as billboards
- - Kitchen utensils such as cutting boards, for example made of glass, ceramic, plastic or wood
- Shelves for example of glass, ceramic, plastic or metal; Cooking surfaces, for example glass ceramic cooking surfaces; Containers, such as baking cups; - Eating or drinking utensils, such as drinking glasses, and
- Furnishings of ovens, dishwashers or refrigerators and freezers such as refrigerator shelves, compartments or drawers.
- Household appliance a glass cover for solar energy systems, as a window of a dishwasher or a cookware, such as a steamer, as a fire or medical glass, such as drug bottles, for containers or pipes, such as coated container or pipe for dairy, as a window or cover for displays, part of hi-fi, computing or telecommunications equipment, for eating or drinking utensils, baby bottles, windows, optical lenses, laboratory glasses, in particular borosilicate glasses.
- low-cost anti-reflective layers These can be made, for example, from a colloidal SiO 2 -SoI by dipping. The structuring of the layers takes place primarily in the
- Glass reflections for the visible spectral range are, for example, AMIRAN or MIROGARD antireflective coatings from Schott AG. These are, for example, interference filters made of, for example, three layers
- a 3- or 5-layer structure of low-refractive SiO 2 and high-index TiO 2 layers is preferably alternating.
- Is preferably prepared from Si and Ti-containing sols by dipping.
- Flat glass with these coatings is used, for example, as architectural glass or as glazing in picture frames.
- the structuring of the layer system is preferably used for decorative purposes, such. B. the application of a logo.
- the desired optical effect can be achieved by
- Structuring of one or more layers of the system preferably the last layer of the system or by applying an additional layer in a structured form.
- Another application example is a colored underside coating on a transparent glass ceramic: it is preferably produced starting from a pigment-filled sol-gel color.
- the color is in principle adjustable with different viscosities, so that in addition to the methods already described for the application of low-viscosity sol-gel solutions, in particular spraying and casting, in suitable cases, the
- Bottom-coated glass ceramics are used, for example, as cooking surfaces.
- the structuring of the layers in this case serves the display capability as well as decorative purposes.
- photocatalytic coatings are also possible: Examples are TiO 2 layers (anatase), made from a colloidal TiO 2 -SoI by dipping or spinning.
- the layers have self-cleaning properties and therefore have a very wide range of applications: anti-bacterial, anti-virus, anti-mold, anti-fungicidal, anti-algae, anti-fogging, anti-fingerprint coating, odor neutralization,
- Air purification, etc. are provided with photocatalytic layers floor tiles, fish tanks, reflecting traffic levels, outer walls of trains, architectural glass, etc.
- the structuring of the layers in these contexts primarily to facilitate the installation of the coated
- Anti-microbial coatings can also be provided according to the invention: These are preferably prepared from an Ag-containing, colloidal sol by immersion. Such coated components can be used in refrigerators. The structuring takes place here primarily at the edges and can facilitate the installation of the components into the system or be a necessary condition for this. In addition, the amount of the very expensive coating can be limited to the relevant areas.
- easy-to-clean coatings For this purpose, surfaces of glasses and glass ceramics are modified, for example in a silanization reaction with longer, perfluorinated carbon chains. As a result, the surface acquires a hydrophobic character and is very easily cleaned by lowering the surface energy.
- Components with easy-to-clean coatings are used mainly in "White goods” area and there primarily in ,, Warmest "applications (permanent load up to 300 0 C) are used. Concrete examples are: oven panes, baking dishes, cooking surfaces, etc.
- the structuring of the layers has the purpose here, for example, the installation (for example
- Gluing of the substrate / the components in the overall system to facilitate or even allow.
- the advantages of the present invention are manifold:
- the present invention provides a substrate and method for the same
- Preparation taking advantage of the sol-gel technology, i. it can be wet-chemically provided at low cost and low cost structured coated substrates.
- the substrates are not particularly limited, particularly preferred are glass and glass ceramics.
- the sol-gel technology can be used in unexpected ways to produce almost arbitrarily structured substrates, although low-viscosity solutions can be used. Nevertheless, sharp and non-running structures are preserved.
- the viscosity of the sol-gel solution can be adjusted in the desired manner, so that it is possible to work with low-viscosity as well as highly viscous sol-gel solutions, whereby the best results are achieved for the respective application.
- sol-gel solution For structured application of the sol-gel solution can be known
- the sol-gel method allows economic structuring of large areas, which can be used, inter alia, on aqueous systems, so that the applied structures release no toxic solvents, are completely inert and used safely indoors can be.
- a suitable variant can be selected, whereby a high degree of flexibility is possible.
- sol-gel fabricated structures are also the frequently obtained good mechanical thermal and photochemical stability, room temperature capability and, if desired, high spectral transparency.
- Another advantage of such sol-gel layers in most cases is that they are not a food source for
- the inorganic sol-gel structure to be produced in the cured state is a structure which is free of impurities. This is therefore also suitable for uses with food contact.
- sol-gel method used according to the invention it is possible to produce thin, glassy, optionally colored, functional layers in great variety and structure. It is possible to create tailor-made structures related to specific applications.
- Embodiment 1 is a diagrammatic representation of Embodiment 1:
- Cooking surface made of a transparent glass ceramic with a displayable, colored underside coating A displayable underside coating has recesses in those areas of the hob where electronic display panels and LEDs are located. The electronic display elements are thus better recognizable on the cooking surface.
- the structuring of the coating is realized by first masking the hob at the desired locations with a resist.
- a sufficiently viscous and thixotropic lacquer eg Wepelan Abdecklack SD 2154 E from Peters, Abziehlack SD 2962 P from Peters or Abziehlack 80 2039 from Ferro
- TEOS tetraethoxysilane
- Aerosil OX ⁇ O Pigments and fillers are stirred into the binder by means of a stirrer with dissolver disk.
- the color is mixed with a further 43.0 g of n-propanol as the solvent.
- pigment-filled sol-gel color is applied over the entire surface, for example by means of the spraying or casting process on the substrate and dried for sufficient time in the air.
- Embodiment 2 is a diagrammatic representation of Embodiment 1:
Abstract
Description
Claims
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DE102005036427A DE102005036427A1 (en) | 2005-08-03 | 2005-08-03 | Substrate, comprising at least one fully or partially macrostructured layer, process for their preparation and their use |
PCT/EP2006/006856 WO2007014631A2 (en) | 2005-08-03 | 2006-07-13 | Substrate comprising at least one entire surface or partial surface macrostructured layer, method for the production thereof and its use |
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US (1) | US20080145625A1 (en) |
EP (1) | EP1909971B1 (en) |
JP (1) | JP2009502490A (en) |
CN (1) | CN101232952B (en) |
AT (1) | ATE483531T1 (en) |
DE (2) | DE102005036427A1 (en) |
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DE102009055992A1 (en) * | 2009-11-26 | 2011-06-01 | Robert Bosch Gmbh | Coating with cell structure |
DE102010026490A1 (en) * | 2010-07-07 | 2012-01-12 | Basf Se | Process for the production of finely structured surfaces |
DE102010031866A1 (en) * | 2010-07-21 | 2012-01-26 | Schott Ag | Silicone coating as a sealing layer for a decorative coating |
WO2012112993A2 (en) * | 2011-02-18 | 2012-08-23 | Bates Aaron P | Method and system for forming a reflective surface |
DE102011076756A1 (en) * | 2011-05-31 | 2012-12-06 | Schott Ag | Substrate element for the coating with an easy-to-clean coating |
DE102011111629B4 (en) | 2011-08-25 | 2013-06-27 | Helmholtz-Zentrum Berlin Für Materialien Und Energie Gmbh | Process for producing periodic crystalline silicon nanostructures |
ES2860931T3 (en) | 2011-11-16 | 2021-10-05 | Tronox Llc | Method for preparing a transparent, stable and neutral photocatalytic titanium dioxide sol |
WO2013130140A1 (en) * | 2011-12-01 | 2013-09-06 | University Of Utah Research Foundation | Photonic devices on planar and curved substrates and methods for fabrication thereof |
DE102011121106A1 (en) * | 2011-12-15 | 2013-06-20 | Robert Bosch Gmbh | Device for heating |
DE102012219571A1 (en) * | 2012-10-25 | 2014-04-30 | Solarworld Innovations Gmbh | Photovoltaic module for use with mark e.g. logo, on glass covering during manufacturing contention products, has solar cell arranged between two coverings in buried layer, and stable mark provided in first covering region over solar cell |
US20140161980A1 (en) * | 2012-12-10 | 2014-06-12 | Corning Incorporated | Methods and formulations for spray coating sol-gel thin films on substrates |
US20140178203A1 (en) * | 2012-12-21 | 2014-06-26 | Solar Turbines Incorporated | Coating fixtures for gas turbine engine compressor disks |
ES2480791B8 (en) * | 2012-12-27 | 2015-10-19 | Abengoa Solar New Technologies, S.A. | PROCEDURE FOR OBTAINING ANTI-REFLECTIVE COATING FOR OPTICAL AND THERMOELECTRIC DEVICES |
DE102014013528B4 (en) | 2014-09-12 | 2022-06-23 | Schott Ag | Coated glass or glass-ceramic substrate with stable multifunctional surface properties, method for its production and its use |
DE102014013527A1 (en) | 2014-09-12 | 2016-03-17 | Schott Ag | Process for producing a coated, chemically tempered glass substrate with anti-fingerprint properties and the glass substrate produced |
FR3031027B1 (en) * | 2014-12-30 | 2017-06-09 | Seb Sa | PROCESS FOR DECORATING A CULINARY ARTICLE BY MECHANICAL TREATMENT |
CN107922257A (en) | 2015-09-02 | 2018-04-17 | 康宁股份有限公司 | Antimicrobial antireflective article and its manufacture method |
RU2015143535A (en) * | 2015-10-12 | 2017-04-18 | федеральное государственное автономное образовательное учреждение высшего образования "Санкт-Петербургский национальный исследовательский университет информационных технологий, механики и оптики" (Университет ИТМО) | Sol-gel ink for color interference inkjet printing |
US10163632B2 (en) * | 2016-12-15 | 2018-12-25 | Taiwan Semiconductor Manufacturing Co., Ltd. | Material composition and process for substrate modification |
WO2018226991A1 (en) | 2017-06-07 | 2018-12-13 | Shifamed Holdings, Llc | Intravascular fluid movement devices, systems, and methods of use |
CN107738523A (en) * | 2017-09-30 | 2018-02-27 | 张东井 | A kind of method to printed matter cast protective layer and the article made of this method |
US11511103B2 (en) | 2017-11-13 | 2022-11-29 | Shifamed Holdings, Llc | Intravascular fluid movement devices, systems, and methods of use |
US11409176B2 (en) * | 2017-12-26 | 2022-08-09 | Heliotrope Europe S.L. | Gel electrolyte precursor compositions, electrochromic devices including gel electrolytes, and manufacturing methods thereof |
US10722631B2 (en) | 2018-02-01 | 2020-07-28 | Shifamed Holdings, Llc | Intravascular blood pumps and methods of use and manufacture |
EP3564197A1 (en) | 2018-05-04 | 2019-11-06 | Merck Patent GmbH | Ceramic colours |
DE102018210982A1 (en) * | 2018-07-04 | 2020-01-09 | Bayerische Motoren Werke Aktiengesellschaft | Method for coating a vehicle component |
CN109270696B (en) * | 2018-11-08 | 2021-02-09 | 宁波维真显示科技股份有限公司 | Preparation method of 3D film |
JP2022540616A (en) | 2019-07-12 | 2022-09-16 | シファメド・ホールディングス・エルエルシー | Intravascular blood pump and methods of manufacture and use |
US11654275B2 (en) | 2019-07-22 | 2023-05-23 | Shifamed Holdings, Llc | Intravascular blood pumps with struts and methods of use and manufacture |
WO2021062265A1 (en) | 2019-09-25 | 2021-04-01 | Shifamed Holdings, Llc | Intravascular blood pump systems and methods of use and control thereof |
US20210387902A1 (en) * | 2020-06-11 | 2021-12-16 | Hony Glass Technology Co., Ltd. | Beam splitter with photocatalytic coating and fabrication method thereof |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5021802A (en) * | 1988-02-19 | 1991-06-04 | Dataproducts Corporation | Thermally reversible sol-gel phase change ink or bubble jet ink |
JPH0780691B2 (en) * | 1989-12-26 | 1995-08-30 | 旭硝子株式会社 | Glass with anti-reflection film with excellent durability |
JPH055922A (en) * | 1991-06-26 | 1993-01-14 | Ricoh Co Ltd | Optical integrated optical system integrated with flat plate type optical element and production thereof |
JP2771105B2 (en) * | 1993-12-20 | 1998-07-02 | セントラル硝子株式会社 | Ink for thin film formation |
JP4346684B2 (en) * | 1996-04-17 | 2009-10-21 | コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ | Method for manufacturing sintered body on substrate |
JP3599903B2 (en) * | 1996-06-28 | 2004-12-08 | セントラル硝子株式会社 | Method for forming oxide film using ink for forming functional thin film |
FR2775914B1 (en) * | 1998-03-13 | 2000-04-21 | Saint Gobain Vitrage | METHOD FOR DEPOSITING LAYERS BASED ON METAL OXIDE (S) |
US5970873A (en) * | 1998-04-27 | 1999-10-26 | Eastman Kodak Company | Imaging and printing methods to form imaging member by formation of insoluble crosslinked polymeric sol-gel matrix |
DE19946712A1 (en) * | 1999-09-29 | 2001-04-05 | Inst Neue Mat Gemein Gmbh | Methods and compositions for printing substrates |
KR20020039681A (en) * | 1999-10-12 | 2002-05-27 | 추후 | Photocatalytic device for disk drive contamination reduction |
AU7917000A (en) * | 1999-11-03 | 2001-05-14 | Ciba Specialty Chemicals Holding Inc. | Pigmented vitreous material its precursor glass items coated therewith and method of its preparation |
DE10014373C2 (en) * | 2000-03-23 | 2003-12-11 | Schott Glas | hob |
DE10019822A1 (en) * | 2000-04-20 | 2001-10-25 | Iwt Stiftung Inst Fuer Werksto | Process for structuring thin layers used for corrosion protection layers comprises applying a thin film as sol to substrate, hardening, removing hardened film, and converting into the required solid body state by introducing energy |
JP2002060651A (en) * | 2000-08-23 | 2002-02-26 | Hitachi Chem Co Ltd | Metal oxide aqueous sol composition, method for forming membrane by using the same and member |
DE10044216A1 (en) * | 2000-09-07 | 2002-05-02 | Fraunhofer Ges Forschung | Coating material for multifunctional, superphobic layers |
US20030078552A1 (en) * | 2001-06-01 | 2003-04-24 | The Procter & Gamble Company | Odor-controlling disposal container |
WO2003087790A1 (en) * | 2002-03-28 | 2003-10-23 | Takai Tofu & Soymilk Equipment Company Limited | Evaluation method and device for gel state or sol-gel state change of object |
US20030194545A1 (en) * | 2002-04-11 | 2003-10-16 | Zesch James Charles | Systems and methods for filling voids and improving properties of porous thin films |
WO2004022338A2 (en) * | 2002-09-09 | 2004-03-18 | International Business Machines Corporation | Printing method using rubber stamp |
JP4429631B2 (en) * | 2003-05-22 | 2010-03-10 | 大日本印刷株式会社 | Curing shrinkable pattern forming material, pattern forming method, and color filter |
DE10355160B4 (en) * | 2003-11-26 | 2008-04-03 | Schott Ag | Coated glass ceramic plate, method for its production and hob with such a glass ceramic plate |
JP4453361B2 (en) * | 2003-12-25 | 2010-04-21 | 富士ゼロックス株式会社 | Raw material solution for nonlinear optical material production, nonlinear optical material, and nonlinear optical element |
US7288469B2 (en) * | 2004-12-03 | 2007-10-30 | Eastman Kodak Company | Methods and apparatuses for forming an article |
KR20070102717A (en) * | 2005-01-24 | 2007-10-19 | 신벤션 아게 | Metal containing composite materials |
-
2005
- 2005-08-03 DE DE102005036427A patent/DE102005036427A1/en not_active Ceased
-
2006
- 2006-07-13 WO PCT/EP2006/006856 patent/WO2007014631A2/en active Application Filing
- 2006-07-13 AT AT06776219T patent/ATE483531T1/en active
- 2006-07-13 ES ES06776219T patent/ES2349659T3/en active Active
- 2006-07-13 CN CN2006800275972A patent/CN101232952B/en active Active
- 2006-07-13 DE DE200650008031 patent/DE502006008031D1/en active Active
- 2006-07-13 JP JP2008524388A patent/JP2009502490A/en active Pending
- 2006-07-13 EP EP20060776219 patent/EP1909971B1/en active Active
-
2008
- 2008-01-30 US US12/022,293 patent/US20080145625A1/en not_active Abandoned
Non-Patent Citations (1)
Title |
---|
See references of WO2007014631A3 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7694887B2 (en) | 2001-12-24 | 2010-04-13 | L-1 Secure Credentialing, Inc. | Optically variable personalized indicia for identification documents |
US7798413B2 (en) | 2001-12-24 | 2010-09-21 | L-1 Secure Credentialing, Inc. | Covert variable information on ID documents and methods of making same |
US7980596B2 (en) | 2001-12-24 | 2011-07-19 | L-1 Secure Credentialing, Inc. | Increasing thermal conductivity of host polymer used with laser engraving methods and compositions |
US8083152B2 (en) | 2001-12-24 | 2011-12-27 | L-1 Secure Credentialing, Inc. | Laser etched security features for identification documents and methods of making same |
US7804982B2 (en) | 2002-11-26 | 2010-09-28 | L-1 Secure Credentialing, Inc. | Systems and methods for managing and detecting fraud in image databases used with identification documents |
US7728048B2 (en) | 2002-12-20 | 2010-06-01 | L-1 Secure Credentialing, Inc. | Increasing thermal conductivity of host polymer used with laser engraving methods and compositions |
US7789311B2 (en) | 2003-04-16 | 2010-09-07 | L-1 Secure Credentialing, Inc. | Three dimensional data storage |
Also Published As
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WO2007014631A2 (en) | 2007-02-08 |
CN101232952A (en) | 2008-07-30 |
WO2007014631A3 (en) | 2008-03-13 |
CN101232952B (en) | 2010-11-10 |
ES2349659T3 (en) | 2011-01-10 |
US20080145625A1 (en) | 2008-06-19 |
DE102005036427A1 (en) | 2007-02-08 |
DE502006008031D1 (en) | 2010-11-18 |
EP1909971B1 (en) | 2010-10-06 |
JP2009502490A (en) | 2009-01-29 |
ATE483531T1 (en) | 2010-10-15 |
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