EP1399312A1 - Robust highly reflective optical construction - Google Patents
Robust highly reflective optical constructionInfo
- Publication number
- EP1399312A1 EP1399312A1 EP02706051A EP02706051A EP1399312A1 EP 1399312 A1 EP1399312 A1 EP 1399312A1 EP 02706051 A EP02706051 A EP 02706051A EP 02706051 A EP02706051 A EP 02706051A EP 1399312 A1 EP1399312 A1 EP 1399312A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- parylene
- layer
- optical construction
- silver
- optically transmissive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/02033—Core or cladding made from organic material, e.g. polymeric material
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/10—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
- G02B6/12—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type of the integrated circuit kind
- G02B6/122—Basic optical elements, e.g. light-guiding paths
- G02B6/1221—Basic optical elements, e.g. light-guiding paths made from organic materials
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/10—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
- G02B6/12—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type of the integrated circuit kind
- G02B6/13—Integrated optical circuits characterised by the manufacturing method
- G02B6/132—Integrated optical circuits characterised by the manufacturing method by deposition of thin films
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/10—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
- G02B6/12—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type of the integrated circuit kind
- G02B2006/12166—Manufacturing methods
- G02B2006/12169—Annealing
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/02395—Glass optical fibre with a protective coating, e.g. two layer polymer coating deposited directly on a silica cladding surface during fibre manufacture
Definitions
- the present invention relates to optical constructions, and more
- Optical components such as waveguides are generally designed to confine
- fiber optic is composed of a thin strand of concentric layers of optically
- optical medium i.e., the cladding
- Light is channeled through the core. During transmission, the light often travels to
- total internal reflection is not total, as some
- a reflective layer can be applied over the surface of the
- the reflective layer significantly reduces the thickness of the reflective layer.
- the reflective layer used in optical components should possess a
- Silver is one metal known to possess a high
- Silver has a reflectance of about 98% over the entire visible
- the present invention is generally directed to an optical construction for
- optical components such as hollow and solid waveguides, solid and hollow light
- optical construction of the present invention is designed to maintain high optical
- optical construction of the present invention is especially useful in
- optical components where a highly reflective surface composed of a metal such as
- the optical construction is further adapted to provide favorable
- optical component
- the optical construction generally comprises
- an optically transmissive substrate adapted for efficiently channeling light
- the parylene polymer protective layer as used in the present invention is the parylene polymer protective layer as used in the present invention
- optical construction of the present invention can further comprise
- adhesion-promoting layer promotes uniformity and consistency in reflective
- a waveguide structure such as a
- fiber optic comprising an optically transmissive glass or polymer material
- a silver reflective layer is applied in contact with the adhesion-
- a protective layer of a parylene polymer film is applied over the
- Figure 1 is a cross sectional view of an optical construction having a
- Figure 2 depicts a schematic diagram of a parylene vacuum evaporation
- Figure 3 is a cross sectional view of an optical construction having a
- Figure 4 is a cross sectional view of an optical construction having a
- Figure 5 is a cross sectional view of a fiber optic waveguide comprising
- Figure 6 is a graph plotting the silver corrosions rates for various samples
- Figure 7 is a graph plotting the silver corrosion rates for various samples
- the present invention is generally directed to an optical construction and a
- present invention includes a substrate, a highly reflective layer, an optional
- a protective layer comprising a parylene polymer film overlaying the
- optical construction of the present invention provides
- the substrate material can be selected from the group consisting of
- the parylene polymer film useful as a protective
- polymer coating may be exemplified in three forms or variations, with each
- the optical construction 10 generally comprises an optically transmissive
- reflective layer 14 preferably composed of a highly reflective metal such as silver
- the protective layer 16 preferably composed of a parylene polymer film.
- the surface of the substrate 12 is optically- smooth and substantially free from
- the substrate 12 can be optionally treated to promote adhesion with the reflective
- layer 14 including, but not limited to, plasma treatment as described in U.S. Pat.
- optically transmissive substrate used for fabricating optical
- components such as fiber optic waveguides can be selected from a range of
- optically transmissive substrate 12 can be composed of glass or polymer material.
- the polymer materials can include organic polymers such as polyhydrocarbons,
- polyoxyhydrocarbons polysulfohydrocarbons, and fluorocarbon and
- organic polymers include
- polyesters such as poly(ethyleneterephthalate) and poly(butyleneterephthalate),
- polyacrylates and methacrylates such as poly(metl ⁇ ylmethacrylate) (PMMA),
- poly(methacrylate), and poly(ethylacrylate), copolymers such as
- the polymer material is PMMA.
- Other polymers can be used as optically transmissive substrate materials,
- MAKROLON DPI -1265 polycarbonate resin marketed by Bayer Corporation of
- polymer material can be clear, transparent, and optically transmissive. When used
- optically transmissive means a plastic or polymer that, in its configuration of
- the polymer substrates can be formed into solid bodies, sheets, films, or coatings applied or laminated onto nonpolymeric surfaces such as metal
- the reflective layer 14 of the optical construction 10 shown in Figure 1 is
- silver is the most preferred metal for the visible range
- the reflective layer 14 comprising a metal or an alloy of metals, can be
- the reflective layer 14 of the present invention is the reflective layer 14 of the present invention.
- the optical construction 10 is enclosed and sealed from ambient by the protective
- the protective layer 16 for optimal protection against corrosion and tarnishing.
- layer 16 in the form of a parylene polymer film, is vapor deposited on the surface
- the parylene polymer protective layer 16 forms a continuously uniform
- the parylene polymer film of the protective layer 16 can be composed of
- parylene N parylene N, parylene C, parylene D, or combinations or mixtures thereof.
- parylene polymer film can be composed of an interpolymer of monomers of
- parylene variants of varying mixture ratios The thickness of the parylene
- polymer film of the protective layer 16 is preferably at least 0.0001", more
- protective layer can be adjusted according to the application, requirements, the
- the parylene polymer film can be optionally processed using suitable
- treating refers to any processes for treating a substance or material
- the parylene polymer film is
- present invention can utilize any suitable commercially available method for
- parylene polymer on a surface as known by one skilled in the art.
- parylene vacuum evaporation deposition reactor system 40 for carrying out the
- system 40 provides an illustration of the process that may be used for coating a
- the system 40 can be constructed using
- the system 40 comprises a vaporization
- the vacuum pump 48 operates to evacuate the air from the interior of the
- the vaporization chamber 42 is adapted to heat a sample of the di-p-
- the vaporized dimer radiates in all directions
- the vaporized dimer proceeds to the cracking chamber 44 where the
- dimmer is heated to a temperature of less than 700°C, preferably between 450°C
- the parylene diradical monomer proceeds to the deposition chamber 46
- vacuum pump 48 is connected to the system 40 to ensure that the process is
- the first is that the room temperature deposition
- the second is the formation of a highly conforming and uniformly continuous
- the third is the capability to form
- the construction is formed by vapor
- optically transmissive substrate 12 The reflective metal-coated optically transmissive substrate 12.
- transmissive substrate is placed into the deposition chamber 46 of the reactor 40,
- polymer protective layer 16 can be determined while in the deposition chamber 46
- thickness of the parylene polymer protective layer 16 can be determined after the
- parylene N parylene C
- parylene D parylene D
- the deposition chamber 46 is sealed from ambient air and the atmosphere of the
- chamber 46 is evacuated with the vacuum pump 48. Alternatively, the atmosphere
- in the deposition chamber 46 can be substituted at ambient pressure with an inert
- gas such as helium, argon or nitrogen.
- the annealing temperature can be
- At least 120°C, preferably from about 120°C to 220°C and the annealing time may
- the annealing process can be carried out
- the annealing conditions can be varied as
- parylene polymer film can be annealed immediately after the
- the annealing process is
- annealing conditions may differ slightly between each variant of the parylene
- parylene polymer protective layer individually as applied during the vapor
- an optical construction 20 which is not drawn to scale, comprising an
- optically transmissive substrate 12 as described above and a thin adhesion-
- promoting layer 18 comprising the oxide form of at least one metal or metalloid
- the adliesion-promoting layer 18 is applied to the substrate 12 prior to
- the reflective layer 14 comprising a highly reflective metal such as silver
- a protective layer 16 comprising a parylene polymer film preferably using the
- the adhesion-promoting layer 18 preferably comprises the
- the thickness of the adhesion-promoting layer 18 can be any thickness of the adhesion-promoting layer 18.
- metal oxides as adhesion promoting materials between a metal and a metal
- polymer substrate is further described in U.S. Pat. Nos. 5,589,280 and 5,902,634,
- the adhesion-promoting layer in one embodiment of the present invention, the adhesion-promoting layer
- reflective layer 14 is composed of the oxide form of one or more metals
- the method for producing the adhesion-promoting layer 18 is to
- metal oxides are preferably deposited in the oxidized mode, which may be achieved for
- reference numeral 30 is similar to the optical construction 20 of Figure 3
- the optical construction 30 includes a protective layer 16 that is
- each layer being composed of a
- parylene polymer selected from the group consisting of parylene N,
- protective layer 16 provides benefits of each parylene variant and/or mixtures of parylene variants for improved compatability with the reflective metal
- the protective layer 16 includes first parylene film 17 composed of a first
- the first parylene film 17 is
- the protective layer 16 further includes a second parylene film
- each parylene variant layer can be adjusted
- the first parylene film 17 is composed of parylene C,
- the second parylene film 19 is composed of parylene D.
- parylene D is known to possess an average chlorine content of two chlorine atoms
- the parylene polymer film may be reacting with the silver.
- parylene D is a suitable candidate for use as part of the protective layer.
- Parylene D is known to have a lower gas permeability value than parylene C for
- films from one parylene variant to another can be made gradually to form a
- first parylene polymer is gradually reduced while the vapor flow of the second
- parylene polymer is ramped up in proportion to the corresponding reduction of the
- layer can be annealed or heat-treated as desired to modify the properties of layer as
- reference numeral 50 generally comprises an elongated
- cylindrical body having concentric layers of glass for channeling light
- the fiber optic waveguide 50 of Figure 5 comprises a core 52
- parylene polymer protective layer 60 overlaying the reflective layer 56.
- fiber optic 50 includes the optical construction of the present invention where the
- the fiber optic 50 can
- oxide coating was evaporatively applied to one set of samples using conventional
- a layer of silver metal was applied to the surface of each sample substrate
- Parylene D and C were each obtained from Paratronix, Inc. of Attleboro,
- PMMA substrate and will include any absorption due to the PMMA or
- Accelerated silver tarnishing was induced by placing the sample in a
- the ammonium sulfide solution generated hydrogen sulfide as the
- the reflectance was measured using light with a wavelength of
- CPAP Absorber Paper
- the anticorrosion paper is designed to prevent tarnishing from the presence of air contaminants that cause oxidation and
- Parylene C and D films were deposited directly onto PMMA to test the
- silver coated waveguide structure does improve the robustness of the silver
- metal- or metalloid-oxides are l ⁇ iown to enhance
- the alumina interfacial layer improves the silver adhesion. Approximately 80%) of
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04008954A EP1445627A3 (en) | 2001-01-29 | 2002-01-29 | Robust highly reflective optical construction |
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US26482901P | 2001-01-29 | 2001-01-29 | |
US264829P | 2001-01-29 | ||
US828065 | 2001-04-04 | ||
US09/828,065 US6586048B2 (en) | 2001-04-05 | 2001-04-05 | Method for depositing a barrier coating on a polymeric substrate and composition comprising said barrier coating |
PCT/US2002/002559 WO2002060686A1 (en) | 2001-01-29 | 2002-01-29 | Robust highly reflective optical construction |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04008954A Division EP1445627A3 (en) | 2001-01-29 | 2002-01-29 | Robust highly reflective optical construction |
EP04008954.2 Division-Into | 2004-04-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1399312A1 true EP1399312A1 (en) | 2004-03-24 |
EP1399312A4 EP1399312A4 (en) | 2004-08-04 |
Family
ID=26950778
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02706051A Withdrawn EP1399312A4 (en) | 2001-01-29 | 2002-01-29 | Robust highly reflective optical construction |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP1399312A4 (en) |
JP (1) | JP2004532423A (en) |
AU (1) | AU2002240158C1 (en) |
CA (1) | CA2436584A1 (en) |
IL (1) | IL157094A (en) |
NZ (1) | NZ527275A (en) |
WO (1) | WO2002060686A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6906257B2 (en) * | 2001-01-29 | 2005-06-14 | Honeywell International Inc. | Metallic coated dielectric substrates |
JP2005234025A (en) * | 2004-02-17 | 2005-09-02 | Omron Corp | Optical waveguide apparatus |
DE102004034369B4 (en) * | 2004-07-16 | 2007-04-26 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | halogen lamp |
JP4813856B2 (en) * | 2005-09-12 | 2011-11-09 | 昭和電工株式会社 | Manufacturing method of semiconductor light emitting device |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4225647A (en) * | 1977-12-02 | 1980-09-30 | Parent Richard A | Articles having thin, continuous, impervious coatings |
US4333985A (en) * | 1980-04-24 | 1982-06-08 | Fuji Photo Film Co., Ltd. | Magnetic recording medium |
EP0412242A1 (en) * | 1989-08-11 | 1991-02-13 | KABEL RHEYDT Aktiengesellschaft | Optical fiber |
EP0745872A2 (en) * | 1995-05-31 | 1996-12-04 | Mitsui Toatsu Chemicals, Incorporated | Reflecting film and reflector making use of the same |
US5589280A (en) * | 1993-02-05 | 1996-12-31 | Southwall Technologies Inc. | Metal on plastic films with adhesion-promoting layer |
JP2000071451A (en) * | 1998-09-02 | 2000-03-07 | Konica Corp | Piezoelectric ceramic element and production thereof |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4762392A (en) * | 1984-05-30 | 1988-08-09 | Mitsubishi Rayon Co., Ltd. | Plastic optical fibers |
US5253312A (en) * | 1992-06-26 | 1993-10-12 | Cytocare, Inc. | Optical fiber tip for use in a laser delivery system and a method for forming same |
FR2700619B1 (en) * | 1993-01-21 | 1995-03-31 | Aerospatiale | Optical fiber with improved mechanical and thermal resistance. |
US5879808A (en) * | 1995-10-27 | 1999-03-09 | Alpha Metals, Inc. | Parylene polymer layers |
US6261006B1 (en) * | 1999-09-24 | 2001-07-17 | Amphenol Corporation | Environmental sealing for fiber optic cable assemblies |
-
2002
- 2002-01-29 AU AU2002240158A patent/AU2002240158C1/en not_active Ceased
- 2002-01-29 WO PCT/US2002/002559 patent/WO2002060686A1/en active IP Right Grant
- 2002-01-29 JP JP2002560856A patent/JP2004532423A/en active Pending
- 2002-01-29 EP EP02706051A patent/EP1399312A4/en not_active Withdrawn
- 2002-01-29 CA CA002436584A patent/CA2436584A1/en not_active Abandoned
- 2002-01-29 IL IL157094A patent/IL157094A/en not_active IP Right Cessation
- 2002-01-29 NZ NZ527275A patent/NZ527275A/en unknown
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4225647A (en) * | 1977-12-02 | 1980-09-30 | Parent Richard A | Articles having thin, continuous, impervious coatings |
US4225647B1 (en) * | 1977-12-02 | 1995-05-09 | Richard A Parent | Articles having thin, continuous, impervious coatings |
US4333985A (en) * | 1980-04-24 | 1982-06-08 | Fuji Photo Film Co., Ltd. | Magnetic recording medium |
EP0412242A1 (en) * | 1989-08-11 | 1991-02-13 | KABEL RHEYDT Aktiengesellschaft | Optical fiber |
US5589280A (en) * | 1993-02-05 | 1996-12-31 | Southwall Technologies Inc. | Metal on plastic films with adhesion-promoting layer |
EP0745872A2 (en) * | 1995-05-31 | 1996-12-04 | Mitsui Toatsu Chemicals, Incorporated | Reflecting film and reflector making use of the same |
JP2000071451A (en) * | 1998-09-02 | 2000-03-07 | Konica Corp | Piezoelectric ceramic element and production thereof |
Non-Patent Citations (3)
Title |
---|
GREINER A: "Poly(1,4-xylylene)s: Polymer Films by Chemical Vapour Deposition" TRENDS IN POLYMER SCIENCE, ELSEVIER SCIENCE PUBLISHERS B.V. AMSTERDAM, NL, vol. 5, no. 1, 1997, pages 12-16, XP004016846 ISSN: 0966-4793 * |
PATENT ABSTRACTS OF JAPAN vol. 2000, no. 06, 22 September 2000 (2000-09-22) & JP 2000 071451 A (KONICA CORP), 7 March 2000 (2000-03-07) * |
See also references of WO02060686A1 * |
Also Published As
Publication number | Publication date |
---|---|
IL157094A0 (en) | 2004-02-08 |
JP2004532423A (en) | 2004-10-21 |
NZ527275A (en) | 2005-04-29 |
EP1399312A4 (en) | 2004-08-04 |
IL157094A (en) | 2006-06-11 |
CA2436584A1 (en) | 2002-08-08 |
AU2002240158B2 (en) | 2005-06-23 |
AU2002240158C1 (en) | 2006-05-18 |
WO2002060686A1 (en) | 2002-08-08 |
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