EP0710717B1

EP0710717B1 - Dispensable powder detergent

Info

Publication number: EP0710717B1
Application number: EP19940308137
Authority: EP
Inventors: David M. Flower
Original assignee: Amway Corp
Current assignee: Amway Corp
Priority date: 1994-11-04
Filing date: 1994-11-04
Publication date: 1998-01-21
Anticipated expiration: 2014-11-04
Also published as: DE69408146T2; ES2111260T3; EP0710717A1; DE69408146D1

Description

This invention relates to granular or powder detergent compositions, and especially to those compositions intended for use in washing machines having a detergent- dispensing feature.

Granular or powder detergent compositions usually contain, in addition to detergent active materials or surfactants, a detergency builder which functions, among other things, to improve the detergency or cleaning level of the compositions, in comparison to unbuilt compositions. In addition to those materials, conventional additives, such as fabric softeners, whiteners, hydrotropes, bleaching agents, bleach activators, enzymes, soil anti-redeposition agents and the like can also be incorporated into granular detergents.

Recently, there has been a trend within the detergent industry toward powders having higher bulk densities than has been customary in the past. This trend is market driven, spurred on by ecological considerations, to produce powdered detergents such that a greater weight of powder can be packed in a given volume of a container or box. However, it has been found that the higher density granules often suffer from poor dispensability in automatic washing machines. In these machines, water enters the dispenser which is charged with the granular detergent and flushes the granules into the wash liquor. If the water does not flush out the entire amount of powder, the powder, when it solidifies, can form relatively large clumps which can eventually block the dispenser and/or the feed pipe from the dispenser to the washing compartment of the machine. This results in a wastage of detergent and a lower level of cleaning, or it requires that the user clean out the dispenser and/or feed line, preferably after each wash cycle. The problem is more prevalent with higher density powders, particularly in non-phosphate, zeolite-containing products, at low wash temperatures, including cold-water washes, and at low water pressure and/or water flow rates; and is most extreme in formulas with a high ratio of nonionic, e.g., more than 90% nonionic with respect to ionic surfactant. While the phenomenon is not fully understood, solubilization of at least a portion of the granular detergent to form a pasty- or syrupy-consistency slurry before the granules have been washed out of the dispenser into the wash liquor appears to be a contributing factor.

Several proposals have been offered for improving the dispensability of granular detergent compositions. EP-A-360,330 (Unilever PLC) discloses a process for the preparation of a detergent powder, which includes the steps of preparing an intermediate powder, and spraying onto the intermediate powder an intimate mixture of a C_8-22 fatty acid and a liquid or liquifiable nonionic surfactant. The final detergent powder is said to have a dynamic flow rate of at least 90 ml/s. In US-A-4966606 a method is proposed for improving dispensability of granular detergent compositions containing sodium carbonate and finely-divided calcite by providing detergent granules or particles which have a mean size of at least 500 µm, with less than two percent by weight of the particles having a size of less than 50 µm. The '606 patent also references other proposals, including those of GB-A-2120293 (addition of a siliconate to bentonite-containing powders) and EP-A-49920 (addition of hydrophobic material such as calcium stearate to phosphate/silicate granular dishwashing compositions). In US-A-4849125 it is proposed to employ a powder component which has a certain grain specification and certain additives and quantitative ratios in order to avoid subsequent separation of the granulate and optimize detergent properties. The powders are subsequently impregnated with nonionic surfactant.

EP-A-354331 discloses a granular detergent in which the granules comprise a carrier impregnated with a nonionic surfactant, a fatty acid and a fatty alcohol. US-A-3216946 also discloses a granular detergent material comprising a carrier impregnated with alcohol or a fatty acid or a nonionic surfactant.

It is an object of the present invention to improve on these previous compositions and methods of manufacture.

According to one aspect of the present invention, a granular detergent composition having a bulk density of at least 400 g/l, comprising 12.5 to 60 percent by weight of at least one nonionic surfactant; from 10 to 85 weight percent of a granular base comprising at least one builder; the base granules being impregnated with an intimate mixture of at least a portion of the nonionic surfactant and from 0.5 to 5 weight percent of at least one fatty acid having from 8 to 22 carbon atoms; and from 0.5 to 5 weight percent of at least one fatty alcohol having from 8 to 22 carbon atoms; the base granules also being impregnated with the balance of any of the nonionic surfactant not intimately mixed with the fatty alcohol and the fatty acid.

A second aspect of the present invention comprises the use of a composition of matter for enhancing the dispensability of granular detergent compositions having a bulk density of at least 400 g/l, by impregnating the granular detergent with the composition of matter, the granular detergent comprising at least one builder, the composition of matter comprising an intimate mixture of at least one nonionic surfactant, at least one fatty acid having from 8 to 22 carbon atoms and at least one fatty alcohol having from 8 to 22 carbon atoms, wherein the combined amount of the fatty acid and the fatty alcohol is in the range from 3 to 16 (preferably 9 to 12) weight percent, based on the weight of the nonionic surfactant and wherein the amount of fatty acid relative to fatty alcohol is in the range of 0.7-1.2 (preferably 0.9 to 1.05) parts by weight fatty acid per part by weight fatty alcohol, and whereby the final detergent composition comprises 10 to 85 weight percent of the builder, 12.5 to 60 weight percent of the nonionic surfactant, 0.5 to 5 weight percent of the fatty acid and 0.5 to 5 weight percent of the fatty alcohol.

According to a third aspect of the invention, a method for enhancing dispersability of granular detergent compositions having a bulk density of at least 400 g/l, which comprise at least one nonionic surfactant and at least one detergent builder, the method comprising: contacting 10 to 85 weight percent of a granular detergent base composition comprising at least one builder with a liquified intimate mixture comprising 12.5 to 60 weight percent of at least one nonionic surfactant, 0.5 to 5 weight percent of at least one fatty acid having from 8 to 22 carbon atoms and 0.5 to 5 weight percent of at least one fatty alcohol having from 8 to 22 carbon atoms.

Thus, the present invention involves enhancing dispensability of high bulk density powder detergents by applying onto detergent granules an intimate mixture of a nonionic surfactant, a fatty acid and a fatty alcohol. Detergent powders made with this technique contain high levels of surfactant, are almost totally nonionic, and have been found to completely dispense an 80-100 gram dosage in a European side-flush dispenser at 1.9 l (0.5 U.S. gallons) per minute flow rate, in less than two minutes, and more typically in 30-45 seconds.

In the preferred embodiment, the dispensing properties of a detergent powder are improved by the application of an intimate mixture of a fatty acid, fatty alcohol and a liquid or liquifiable nonionic surfactant into and onto the detergent base powder, prior to the dry-dosing and/or spraying of other components. In a particularly preferred embodiment of the invention, the detergent base powder is contacted with a portion of the liquid or liquifiable nonionic surfactant followed by the application of the remainder of the nonionic surfactant, the fatty acid and the fatty alcohol. It is believed that this most preferred embodiment tends to leave the fatty acid and fatty alcohol components concentrated to a greater degree at the base particle surface.

The base detergent powders which are suitable for treating in accordance with the present invention can be prepared by substantially any method known in the art. For example, some detergent powders are prepared by spray drying an aqueous slurry of heat-insensitive and mutually compatible ingredients to form a spray-dried granular product, normally referred to as the "base powder." Other desired ingredients that are not to be incorporated via the slurry because of heat sensitivity or incompatibility with other slurry ingredients are then dry-mixed or sprayed onto the base powder. Such base detergent powders can also be prepared by straightforward blending of the ingredients in the presence of less than about 5% water, or by mixing in the substantial absence of water but in the presence of non-aqueous liquid or liquifiable materials, including detergent active materials, such as nonionic surfactants. The base powder which forms from this simplified technique can then be post-dosed with other dry or liquid materials to provide base detergent granules which are then treated with the mixture of fatty acid, fatty alcohol and nonionic surfactant, in accordance with the precepts of the invention.

The principal ingredients of the high density, free-flowing, easily-dispensed granular laundry detergent powder of the invention include at least one nonionic surfactant, at least one builder, at least one fatty alcohol, at least one fatty acid and, optionally, other additives conventionally employed in granular detergent compositions. These principal ingredients are included in the detergent compositions in the following percentage ranges, based on total weight of detergent:

Ingredient	Range	Preferred Range	Especially Preferred Range
Nonionic surfactant	12.5-60	12.5-40	15-25
Builder	10-85	25-80	40-75
Fatty alcohol	0.5-5	0.75-2	0.75-1.25
Fatty acid	0.5-5	0.75-2	0.75-1.25
Optionals	to 100%	to 100%	to 100%

Nonionic Surfactants

Substantially any liquid or liquifiable nonionic surfactants which have been habitually used in detergent compositions can be employed in the present invention. A comprehensive listing and discussion of nonionic surfactants or detergents can be found in McCutcheon's Detergents and Emulsifiers, 1973 Annual and in the textbook Surface Active Agents, Vol. II, by Schwartz, Perry and Berch (Inter. Science Publishers, 1958). Particularly preferred nonionic surfactants include: polyethylene oxide condensates of alkyl phenols having from 4 to 25, preferably 4-16, moles of ethylene oxide per mole of alkyl phenol; condensation products of aliphatic alcohols and from 1 to about 25, preferably about 3 to about 16, moles of ethylene oxide per mole of alcohol; condensation products of ethylene oxide with a hydrophobic base formed by the condensation of propylene oxide with propylene glycol; condensation products of ethylene oxide with propylene oxide-ethylene diamine reaction products; water-soluble amine oxides, phosphine oxides and sulfoxides having one alkyl moiety having from about 10 to about 18 carbon atoms and two moieties selected from the group consisting of alkyl groups and hydroxyalkyl groups having from 1 to about 3 carbon atoms; alkyl polysaccharides and fatty acid amides. Currently preferred are ethoxylated alcohols such as Neodol's (Trade Mark) 25-3, 23-6.5, 25-7, 45-7 and 45-9 marketed by Shell Chemical Company.

Builders

The preferred granular detergent compositions of the invention also contain at least 10% by weight of at least one water-soluble or water-insoluble inorganic and/or organic detergency builder.

Non-limiting examples of suitable water-soluble inorganic detergent builders include alkali metal carbonates, borates, phosphates, polyphosphates, bicarbonates, silicates, sulphates and chlorides. Specific examples of such salts include sodium and potassium tetraborates, perborates, bicarbonates, carbonates, tripolyphosphates, orthophosphates, pyrophosphates, hexametaphosphates and sulphates.

Examples of suitable organic alkaline detergency builders include water-soluble amino carboxylates and amino polyacetates, such as sodium and potassium glycinates, ethylene diamine tetraacetates, nitrilotriacetates and N-(2-hydroxy ethyl) nitrilodiacetates and diethylenetriamine pentaacetates; water-soluble salts of phytic acid, such as sodium and potassium phytates; water-soluble polyphosphonates including sodium, potassium and lithium salts of ethane-1-hydroxy-1,1-diphosphonic acid, the sodium, potassium and lithium salts of ethylene diphosphonic acid and the like; water-soluble polycarboxylates such as the salts of lactic acid, succinic acid, malonic acid, maleic acid, citric acid, carboxymethyloxysuccinic acid, 2-oxo-xa-1,1,3-propane tricarboxylic acid, 1,1,2,2-ethane tetracarboxylic acid, cyclopentane-cis,cis,cis-tetracarboxylic acid mellitic acid and pyromellitic acid; water-soluble organic amines and amine salts such as monoethanolamine, diethanolamine and triethanolamine and salts thereof.

Another type of detergency builder useful in the present composition comprises a water-soluble material capable of forming a water-insoluble reaction product with water hardness cations preferably in combination with a crystallization seed which is capable of providing growth sites for said reaction product.

The invention is particularly useful when the detergency builder materials comprise insoluble sodium aluminosilicates, especially those having a calcium ionic exchange capacity of at least 200 milligrams equivalent per gram and a calcium ion exchange rate of at least 0.53 grams per litre per minute per gram (2 grams per gallon per minute per gram). Particularly preferred builders of this type are the zeolites A and X, preferably containing from about 7 to about 26% water of hydration.

Fatty alcohols which can be employed in the practice of the invention include substantially any of the known fatty alcohols having from 8 to 22 carbon atoms with fatty alcohols having from 14 to 18 carbon atoms being preferred. Particularly preferred are the C₁₆ fatty alcohols, such as cetyl alcohols. Other useful fatty alcohols include capryl alcohol, decanol, lauryl alcohol, myristic alcohol, septa decanoic alcohol, octedecanoic alcohol and behenic alcohol.

Substantially any fatty acids from 8 to 22 carbon atoms can be employed in the practice of the invention, with fatty acids having from 16-22 carbon atoms being preferred. Stearic acid is currently the preferred acid of choice. Other useful fatty acids include caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, margaric acid and behenic acid.

The fatty acid and the fatty alcohol will normally be combined in an amount in the range from about 3 to about 16%, preferably from about 9 to about 12% by weight, based on the weight of total nonionic surfactant. The amount of fatty acid relative to fatty alcohol will generally be in a ratio of 0.7-1.2 parts by weight fatty acid per part by weight of fatty alcohol. Preferably, the ratio of fatty acid:fatty alcohol will be in the range of 0.9-1.05:1. Currently, a ratio of one part fatty acid to one part fatty alcohol is most preferred.

Additional Ingredients

The granular detergent composition of the present invention can be supplemented by the usual additives conventionally employed in detergent compositions. Optional ingredients include other surfactants, e.g., anionic, cationic, amphoteric and zwitterionic surfactants, soil suspending agents at about 0.1% to 10% by weight, including water-soluble salts of carboxymethylcellulose carboxyhydroxymethylcellulose and polyethylene glycols having a molecular weight of about 400 to 10,000. Dyes, optical brighteners and perfumes, enzymes, anti-caking agents such as sodium sulfosuccinate, preservatives such as sodium benzoate, alkaline metal or alkaline earth metal silicates, suds regulating or suppressing agents, natural and synthetic microcrystalline and oxidized microcrystalline waxes, inorganic and organic peroxy bleaching agents, bleaching agent activators, polyphosphonic acids and acid salts. These materials will be employed in the practice of this invention at conventional levels at which they are typically used in detergent formulations.

FORMULATION PROCEDURE

The mixtures are preferably formed by liquifying the nonionic surfactant, if the nonionic surfactant is not naturally a liquid, and melting and blending the fatty alcohol and fatty acid into the liquified nonionic surfactant. As indicated, the treating mixture is preferably applied in two portions, with a first portion comprising approximately at least 50% and more preferably about 65% of the nonionic surfactant charge, which is initially sprayed onto or otherwise combined with the detergent granule. The liquified mixture of the remaining nonionic surfactant, the fatty acid and the fatty alcohol is sprayed onto or otherwise combined with the previously nonionic surfactant-impregnated granule. After this, final components including oxygen-containing bleaches such as sodium perborate, sodium silicate, the tetraacetyl ethylenediamine bleach activator and enzymes are post-dosed onto the treated granules.

The granular detergent compositions of this invention are typically employed in an amount to provide aqueous solutions containing from about 100 to about 3,000 parts per million, especially from about 500 to 1,500 parts per million of detergent compositions.

The detergent compositions of the invention may be prepared following conventional techniques. For example, the base granular detergent compositions of the present invention can be made by spray drying a crutcher mix containing the builder and optional components to form a granular powder base and subsequently treating the powder base with the nonionic surfactant, fatty acid and fatty alcohol mixture in accordance with this invention.

Currently, the preferred method of preparing the granular laundry detergent is to blend the dry powder ingredients, such as builders, and the like, with about 50% by weight of the total nonionic surfactant (which has been liquified) to obtain a substantially homogeneous mixture. The resulting granules will have the nonionic surfactant sorbed into the granules. This granular base is then treated with the intimate mixture of the remainder of the liquified nonionic surfactant, fatty acid and fatty alcohol as previously described.

Granular detergent compositions produced in accordance with this invention have conventional particle sizes in the range of 2.38 mm to 0.149 mm (8 to 100 mesh) with a powder density of at least 400 grams per litre, preferably in the range from about 450 to 900 grams per litre and most preferably in the range of about 550 to 800 grams per litre.

EXAMPLES

The following exemplary data show the surfactant systems and dispensing properties of a series of European non-phosphate detergent formulations. The test samples were prepared using the same granular base (zeolite, carbonate, citrate, CMC, polyacrylate, bicarbonate, phosphonate). The melted/liquid nonionic surfactant(s) were added in two portions, the latter containing the stearic acid and/or fatty alcohol (as well as optional liquid ingredients: fragrance and defoaming agent). After this, final post add components including perborate, silicate, TAED (bleach activator) and enzymes were added and mixed.

Detergent compositions are prepared according to the following formulations:

The resulting product comprised free-flowing granules having a density of about 650 grams per litre. The granular detergent was dosed (100 grams) to an automatic washing machine equipped with a European-style side flush dispenser. Water at a rate of 1.9 l (0.5 gallons) per minute was fed to the dispenser. As the data show, detergent granules prepared in accordance with the invention (Examples 4 and 6) were completely dispensed in 35 to 45 seconds whereas detergent granules coated with nonionic surfactant/fatty acid (Examples 1-3 and 7) or nonionic surfactant/fatty alcohol (Example 5) were incompletely dispensed, leaving substantial quantities of clumped detergent in the dispenser and feed line between the dispenser and the washing tub.

By way of further illustration and clarification of the invention, it is strongly preferred that the nonionic, fatty alcohol and fatty acid be added to the principle granular builder ingredient. In the above examples, the principle builder ingredient is the granular zeolite A at 39% of the final detergent composition. In other formulations, the principle builder might be sodium carbonate, a phosphate or some other ingredient. Thus, in the formulas of the above examples, one could have added the first portion of nonionic to the granular zeolite A only, then blended in the remaining Part I ingredients and, thereafter, blended in the Part II liquid ingredients.

Alternatively, one might have impregnated only the granular zeolite A component with the first portion of nonionic surfactant, and then have coated only those impregnated builder ingredients with the Part II liquids. All of the remaining Part I ingredients could have then been added as Part III post add ingredients.

In yet another variation, the various Part I granular ingredients might first be agglomerated together. These Part I agglomerated granules would then be impregnated with the first portion of nonionic surfactant, followed by contact with the Part II liquid ingredients.

It should be further noted that the Part II liquid ingredients must contain a portion of the nonionic, the fatty acid and the fatty alcohol. The incorporation of other liquid ingredients into this liquid mixture is optional (e.g., the fragrance and defoaming agents). The optional liquid ingredients could be treated as post adds, or even incorporated into the Part I granule mix or agglomerated granules.

Finally, it should be noted that the Part III post add ingredients, while conveniently added last, could alternatively be incorporated into the Part I base granule mix.

The above examples are considered that of the preferred embodiments only. Modifications of the invention will occur to those who make or use the invention.

Claims

A granular detergent composition having a bulk density of at least 400 g/l, comprising 12.5 to 60 percent by weight of at least one nonionic surfactant; from 10 to 85 weight percent of a granular base comprising at least one builder; the base granules being impregnated with an intimate mixture of at least a portion of the nonionic surfactant and from 0.5 to 5 weight percent of at least one fatty acid having from 8 to 22 carbon atoms; and from 0.5 to 5 weight percent of at least one fatty alcohol having from 8 to 22 carbon atoms; the base granules also being impregnated with the balance of any of the nonionic surfactant not intimately mixed with the fatty alcohol and the fatty acid.
A granular detergent composition according to claim 1 in which the base granules are impregnated with the fatty alcohol.
A granular detergent composition according to claim 1 or claim 2 in which the base granules are impregnated with a first application of the nonionic surfactant in an amount less than the total amount of the nonionic surfactant, followed by a second application of an intimate mixture of the remaining amount of the nonionic surfactant, and the fatty acid and the fatty alcohol, wherein the combined amount of the fatty acid and the fatty alcohol is in the range from 3 to 16 (preferably 9-12) weight percent, based upon the total weight of nonionic surfactant and wherein the weight ratio of fatty acid:fatty alcohol is 0.7-1.2:1 (preferably 0.9-1.05:1), whereby the resulting concentration of the fatty acid and the fatty alcohol is greater at the surface of the base granules than the concentration at regions of the base granules other than at the surface.
A granular detergent composition according to claim 3 in which at least 50% (preferably at least 65%) of the nonionic surfactant is impregnated first into the base granules.
A granular detergent composition according to any of claims 1 to 4 in which the builder comprises a water-insoluble zeolite.
A granular detergent composition according to any of claims 1 to 5 in which the fatty alcohol represents 0.75 to 1.25 weight percent and the fatty acid represents 0.75 to 1.25 weight percent.
The use of a composition of matter for enhancing the dispensability of granular detergent compositions having a bulk density of at least 400 g/l, by impregnating the granular detergent with the composition of matter, the granular detergent comprising at least one builder, the composition of matter comprising an intimate mixture of at least one nonionic surfactant, at least one fatty acid having from 8 to 22 carbon atoms and at least one fatty alcohol having from 8 to 22 carbon atoms, wherein the combined amount of the fatty acid and the fatty alcohol is in the range from 3 to 16 (preferably 9 to 12) weight percent, based on the weight of the nonionic surfactant and wherein the amount of fatty acid relative to fatty alcohol is in the range of 0.7-1.2 (preferably 0.9-1.05) parts by weight fatty acid per part by weight fatty alcohol and whereby the final detergent composition comprises 10 to 85 weight percent of the builder, 12.5 to 60 weight percent of the nonionic surfactant, 0.5 to 5 weight percent of the fatty acid and 0.5 to 5 weight percent of the fatty alcohol.
The use of composition of matter according to claim 7 wherein the fatty acid:fatty alcohol ratio is 0.9-1.05:1.
The use of a composition of matter according to claim 7 or claim 8 wherein the fatty acid is stearic acid and the fatty alcohol comprises cetyl alcohol.
The use of a composition of matter according to any of claims 7 to 9 in which the fatty alcohol represents 0.75 to 1.25 weight percent and the fatty acid represents 0.75 to 1.25 weight percent.
A method for enhancing dispensability of granular detergent compositions having a bulk density of at least 400 g/l, which comprise at least one nonionic surfactant and at least one detergent builder, the method comprising: contacting 10 to 85 weight percent of a granular detergent base composition comprising at least one builder with a liquified intimate mixture comprising 12.5 to 60 weight percent of at least one nonionic surfactant, 0.5 to 5 weight percent of at least one fatty acid having from 8 to 22 carbon atoms and 0.5 to 5 weight percent of at least one fatty alcohol having from 8 to 22 carbon atoms.
A method according to claim 11 wherein the granular detergent base composition is first contacted with at least a portion (preferably at least 50% and more preferably at least 65%) of the nonionic surfactant and subsequently contacted with the mixture comprising the remainder of the nonionic surfactant, fatty acid and fatty alcohol.
A method according to claim 11 or claim 12 wherein the combined amount of the fatty acid and the fatty alcohol is in the range from 3 to 16 (preferably 9-12) weight percent, based on the weight of the nonionic surfactant and wherein the amount of fatty acid relative to fatty alcohol is in the range of 0.7-1.2 parts (preferably 0.9 to 1.05 parts) by weight fatty acid per part by weight fatty alcohol.
A method according to any of claims 11 to 13 in which the fatty alcohol represents 0.75 to 1.25 weight percent and the fatty acid represents 0.75 to 1.25 weight percent.
A composition according to any of claims 1 to 6 or a method according to any of claims 11 to 14 wherein the fatty acid is stearic acid and the fatty alcohol comprises cetyl alcohol.
A method according to any of claims 11 to 14 wherein the builder comprises a water-insoluble zeolite.