EP0518707B1 - Spark plug with a platinum tip on its outer electrode - Google Patents

Spark plug with a platinum tip on its outer electrode Download PDF

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Publication number
EP0518707B1
EP0518707B1 EP92305477A EP92305477A EP0518707B1 EP 0518707 B1 EP0518707 B1 EP 0518707B1 EP 92305477 A EP92305477 A EP 92305477A EP 92305477 A EP92305477 A EP 92305477A EP 0518707 B1 EP0518707 B1 EP 0518707B1
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EP
European Patent Office
Prior art keywords
outer electrode
spark plug
tip
nickel
core metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP92305477A
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German (de)
French (fr)
Other versions
EP0518707A3 (en
EP0518707A2 (en
Inventor
Junichi Kagawa
Wataru Matsutani
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Niterra Co Ltd
Original Assignee
NGK Spark Plug Co Ltd
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Publication date
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Application filed by NGK Spark Plug Co Ltd filed Critical NGK Spark Plug Co Ltd
Publication of EP0518707A2 publication Critical patent/EP0518707A2/en
Publication of EP0518707A3 publication Critical patent/EP0518707A3/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T13/00Sparking plugs
    • H01T13/20Sparking plugs characterised by features of the electrodes or insulation
    • H01T13/39Selection of materials for electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T13/00Sparking plugs
    • H01T13/20Sparking plugs characterised by features of the electrodes or insulation
    • H01T13/32Sparking plugs characterised by features of the electrodes or insulation characterised by features of the earthed electrode

Definitions

  • This invention relates to a spark plug having a platinum tip welded to its outer electrode, and particularly concerns an improvement intended to avoid deterioration of the welded portion between the tip and the outer electrode.
  • the outer electrode be made of a high heat conductivity core such as copper, clad by a nickel-alloy matrix, while platinum tips are welded to the opposing ends of both outer and center electrodes so as to improve oxidation and corrosion-resistance.
  • the outer electrode Compared to the center electrode, the outer electrode, however, is exposed to higher ambient temperature to such a degree that the platinum tip tends to fall off the outer electrode at the welded portion.
  • the outer electrode is all the more exposed to higher ambient temperature, and successively cooled by newly introduced mixture of gasoline.
  • EP-A-0,474,351 which is prior art under Article 54(3) EPC for the designations of Germany, France and the United Kingdom only, describes a spark plug including an outer electrode, a rear end of which is securely connected to a metallic shell of the spark plug by means of welding, a spark gap being formed between a front end of the outer electrode and a firing tip of a center electrode which is concentrically placed within the metallic shell through an insulator, the outer electrode comprising: a middle core which is made of copper to provide heat-conduction; a heat and spark-erosion resistant metal cladding the middle core; and an innermost core clad by the middle core, the innermost core being made of a metal weldable to that of the metallic shell, and the rear end of the innermost core being welded to the metallic shell so as to reinforce a welding portion between the metallic shell and the outer electrode.
  • a spark plug comprising a center electrode disposed within an insulator in a metallic shell, an outer electrode extending from the metallic shell, and a platinum tip welded to the outer electrode by means of resistance welding and opposing the front end of the center electrode to form a spark gap therebetween, the outer electrode comprising a heat-conductive core metal clad by a matrix metal made from nickel-based alloy, characterised in that said alloy contains 10-20% by weight of chromium, and the distance between a circumferential edge of the weld, between the outer electrode and the tip, and the front end of the core metal is between 0.0 mm and 2.0 mm at their closest point and when measured in the direction of longitudinal extent of the outer electrode at said tip attachment portion.
  • the dimensional arrangement between the platinum tip and the core metal is such that a significant amount of heat is smoothly dissipated from a front end of the outer electrode to the metallic shell by way of the core metal. This prevents the temperature of the front end of the outer electrode from rising excessively, and reduces the thermal stress occurring at the welded portion between the tip and the outer electrode, and at the same time, reduces oxidation of the welded portion so as to prevent the tip from falling off the outer electrode.
  • the core metal is liable to be softened, and the outer electrode to deform at the time of welding the tip to the outer electrode.
  • the platinum tip begins to fall off the outer electrode when the spaced distance exceeds 2.0 mm.
  • the spaced distance is determined to fall within the range from 0.0 mm to 2.0 mm.
  • a spark plug shown in Fig. 1 there is shown a cylindrical metallic shell 2, to a front end of which a L-shaped outer electrode 1 is welded.
  • a tubular insulator 3 is placed whose inner space acts as an axial bore 31.
  • a middle axis 4 is placed whose rear end has a terminal 41 to which a high tension cord of an ignition circuit (not shown) is to be connected.
  • a glass sealant resistor 42 and a center electrode 5 are in turn connected in linear relationship with each other.
  • a front end 5A of the center electrode 5 extends from the metallic shell 2 to oppose a front end 1A of the outer electrode 1 so as to form a spark gap (Gp) therebetween.
  • the spark plug is an extension-type one in which the front end 5A of the center electrode 5 extends from the metallic shell 2 by 1.5 ⁇ 15.0 mm so that the front end 5A projects into a combustion chamber (Ch) by 3.0 ⁇ 17.0 mm when the spark plug is mounted on an internal combustion engine.
  • the outer electrode 1 consists a composite base metal 10 having a heat-conductive core metal 12 cladded by a nickel-alloyed matrix 11 which contains 10 ⁇ 20 wt% chrominum.
  • a column platinum tip 6 is welded at a welded portion (WI) in a manner to oppose the front end 5A of the center electrode 5. It is noted that the tip 6 may contain 20 wt% iridium (Ir).
  • the nickel-alloyed matrix 11 increases its oxidation-resistance with an increased addition of chromium, while inviting an increased hardness and reduced thermal conductivity.
  • the nickel-alloyed matrix 11 containing chromium less than 10 wt% causes to deteriorate its oxidation-resistance. Hence the chromium content is 10-20 wt%.
  • the core metal 12 is made from copper, silver, copper-based alloy or silver-based alloy, and having a front end 12a and a rear end 12b, the latter of which is placed in heat-transferable contact relationship with a front end of the metallic shell 2.
  • the core metal 12 clads an innermost core 13 which is made of pure nickel or pure iron. This contributes to improving a weld-intensity of the outer electrode 1 to the metallic shell 2, and at the same time, preventing the deformation of the outer electrode 1 which arises from the heat-cool cycle of the internal combustion engine.
  • the welded portion (WI) of the tip 6 is arranged to terminate slightly short of the core metal 12, so that the distance (L) between a circumferential edge (Wx) of the welded portion (WI) and the front end 12a of the core metal 12 falls in a range between 0.0 mm and 2.0 mm at their closest point and when measured in the direction of longitudinal extent of the outer electrode at the tip attachement point, as shown in Fig. 2.
  • the nickel-alloyed matrix 11 which contains 10-20 wt% chromium, is somewhat inferior in thermal conductivity, but superior in both high-temperature strength and oxidation -resistance compared to a nickel-alloyed outer electrode which usually contains more than 90 wt% nickel.
  • the front end 12a of the core metal 12 is extended toward the circumferential edge (Wx) of the welded portion (WI) within a range between 0.0 mm and 2.0 mm.
  • the spaced distance (L) makes it possible to prevent an excessive temperature rise of the front end 1A of the outer electrode 1, and thus prevents increased thermal stress from occurring at the welded portion (WI), keeping the tip 6 in place.
  • the straight-type outer electrode is firstly welded to the metallic shell 2. Then, the insulator 3 is placed within the metallic shell 2. Before bending the outer electrode 1 into L-shaped configuration, the tip 6 is secured to the outer electrode 1 by means of resistance welding.
  • the copper or silver core 12 may be softened and buckled during the resistance welding when the circumferential edge (Wx) of the welded portion (WI) partly overlaps with the front end 12a of the core metal 12.
  • the lower limit of the spaced distance (L) is determined to be 0.0 mm, preventing an overlapping relationship between the circumferential edge (Wx) of the welded portion (WI) and the front end 12a of the core metal 12.
  • the center electrode 5 consists of a composite base metal 50 having a copper core 51 cladded by a nickel-alloyed matrix 52 which contains more than 90 wt% nickel.
  • a nickel-alloyed layer 53 which contains 20 ⁇ 25 wt% chronium is secured by means of resistance welding.
  • a platinum tip 7 is secured by means of resistance welding. The platinum tip 7 has a diameter-increased portion 71 welded to the nickel-alloyed layer 53, and a diameter-reduced portion 72 which opposes the platinum tip 6 across the spark gap (Gp).
  • outer configuration of the nickel-alloyed layer 53 and the platinum tip 7 may be shaped after carrying out the resistance welding in order to prevent their unfavorable deformations during the welding operation.
  • the nickel-alloyed layer 53 may be left out, and the platinum tip 7 may be welded directly to a front end of the diameter-reduced portion of the nickel-alloyed matrix 52 instead of the nickel-alloyed layer 53.
  • Fig. 3a shows a partly broken outer electrode 1 to define an axial length (A) of the platinum tip 6 and an axial length (B) of the welded portion. (WI).
  • the amount of corrosion (S) of the welded portion (WI) is expressed by (A-B)/A for the purpose of convenience.

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  • Spark Plugs (AREA)

Description

  • This invention relates to a spark plug having a platinum tip welded to its outer electrode, and particularly concerns an improvement intended to avoid deterioration of the welded portion between the tip and the outer electrode.
  • With the recent demand for cleaner emission gas and enhanced fuel consumption from internal combustion engines, it has been needed to run the engine with a leaner mixture of gasoline. With higher temperatures in the combustion chamber the outer electrode of the spark plug tends to be exposed to higher temperatures.
  • With the further demand for continuous running of engines for more than 100,000 Km without replacing the spark plugs it has been suggested, for example in US-A-2,296,033 on which the preamble of claim 1 is based, that the outer electrode be made of a high heat conductivity core such as copper, clad by a nickel-alloy matrix, while platinum tips are welded to the opposing ends of both outer and center electrodes so as to improve oxidation and corrosion-resistance.
  • Compared to the center electrode, the outer electrode, however, is exposed to higher ambient temperature to such a degree that the platinum tip tends to fall off the outer electrode at the welded portion.
  • In an extension-type spark plug in which a firing end of the spark plug is extended into the combustion chamber, the outer electrode is all the more exposed to higher ambient temperature, and successively cooled by newly introduced mixture of gasoline.
  • As a result, a greater intensity of thermal stress occurs at the welded portion between the tip and the outer electrode so that the tip is liable to fall off the outer electrode.
  • Therefore, it is an object of the invention to provide a spark plug having a platinum tip welded to an outer electrode which is capable of effectively reducing the effect of thermal stress between the platinum tip and the outer electrode and increasing the oxidation resistance, thus contributing to an extended period of service life with a relatively simple structure.
  • EP-A-0,474,351, which is prior art under Article 54(3) EPC for the designations of Germany, France and the United Kingdom only, describes a spark plug including an outer electrode, a rear end of which is securely connected to a metallic shell of the spark plug by means of welding, a spark gap being formed between a front end of the outer electrode and a firing tip of a center electrode which is concentrically placed within the metallic shell through an insulator, the outer electrode comprising: a middle core which is made of copper to provide heat-conduction; a heat and spark-erosion resistant metal cladding the middle core; and an innermost core clad by the middle core, the innermost core being made of a metal weldable to that of the metallic shell, and the rear end of the innermost core being welded to the metallic shell so as to reinforce a welding portion between the metallic shell and the outer electrode.
  • According to the present invention there is provided a spark plug comprising a center electrode disposed within an insulator in a metallic shell, an outer electrode extending from the metallic shell, and a platinum tip welded to the outer electrode by means of resistance welding and opposing the front end of the center electrode to form a spark gap therebetween, the outer electrode comprising a heat-conductive core metal clad by a matrix metal made from nickel-based alloy, characterised in that said alloy contains 10-20% by weight of chromium, and the distance between a circumferential edge of the weld, between the outer electrode and the tip, and the front end of the core metal is between 0.0 mm and 2.0 mm at their closest point and when measured in the direction of longitudinal extent of the outer electrode at said tip attachment portion.
  • In the hereinafter described and illustrated embodiment of a spark plug in accordance with the present invention the dimensional arrangement between the platinum tip and the core metal is such that a significant amount of heat is smoothly dissipated from a front end of the outer electrode to the metallic shell by way of the core metal. This prevents the temperature of the front end of the outer electrode from rising excessively, and reduces the thermal stress occurring at the welded portion between the tip and the outer electrode, and at the same time, reduces oxidation of the welded portion so as to prevent the tip from falling off the outer electrode.
  • When the welded portion is positioned so as partly to overlap with the front end of the core metal, the core metal is liable to be softened, and the outer electrode to deform at the time of welding the tip to the outer electrode.
  • Meanwhile, the platinum tip begins to fall off the outer electrode when the spaced distance exceeds 2.0 mm. Hence the spaced distance is determined to fall within the range from 0.0 mm to 2.0 mm.
  • The invention will be further understood from the following description, when taken together with the attached drawings which are given by way of example only, and in which:
    • Fig. 1 is a sectional view of a spark plug.
    • Fig. 2 is an enlarged longitudinal cross sectional view of an outer electrode showing the front end portion of the spark plug;
    • Fig. 3 is a graph showing how corrosion (S) changes with operating time (T) and a spaced distance (L); and
    • Fig. 3a is a partly broken view of the outer electrode to define an axial length (A) of a platinum tip and an axial length (B) of a welded portion.
  • Referring to a spark plug shown in Fig. 1, there is shown a cylindrical metallic shell 2, to a front end of which a L-shaped outer electrode 1 is welded. Within the metallic shell 2, a tubular insulator 3 is placed whose inner space acts as an axial bore 31. Within the axial bore 31 of the insulator 3, a middle axis 4 is placed whose rear end has a terminal 41 to which a high tension cord of an ignition circuit (not shown) is to be connected. To a front end of the middle axis 4, a glass sealant resistor 42 and a center electrode 5 are in turn connected in linear relationship with each other. A front end 5A of the center electrode 5 extends from the metallic shell 2 to oppose a front end 1A of the outer electrode 1 so as to form a spark gap (Gp) therebetween.
  • In this instance, the spark plug is an extension-type one in which the front end 5A of the center electrode 5 extends from the metallic shell 2 by 1.5 ∼ 15.0 mm so that the front end 5A projects into a combustion chamber (Ch) by 3.0 ∼ 17.0 mm when the spark plug is mounted on an internal combustion engine.
  • The outer electrode 1 consists a composite base metal 10 having a heat-conductive core metal 12 cladded by a nickel-alloyed matrix 11 which contains 10 ∼ 20 wt% chrominum. To the front end 1A of the nickel-alloyed matrix 11, a column platinum tip 6 is welded at a welded portion (WI) in a manner to oppose the front end 5A of the center electrode 5. It is noted that the tip 6 may contain 20 wt% iridium (Ir).
  • The nickel-alloyed matrix 11 increases its oxidation-resistance with an increased addition of chromium, while inviting an increased hardness and reduced thermal conductivity. The nickel-alloyed matrix 11 containing chromium less than 10 wt% causes to deteriorate its oxidation-resistance. Hence the chromium content is 10-20 wt%.
  • The core metal 12 is made from copper, silver, copper-based alloy or silver-based alloy, and having a front end 12a and a rear end 12b, the latter of which is placed in heat-transferable contact relationship with a front end of the metallic shell 2.
  • In order to provide the composite base metal 10 with three-layer structure according to a further embodiment of the invention, the core metal 12 clads an innermost core 13 which is made of pure nickel or pure iron. This contributes to improving a weld-intensity of the outer electrode 1 to the metallic shell 2, and at the same time, preventing the deformation of the outer electrode 1 which arises from the heat-cool cycle of the internal combustion engine.
  • The welded portion (WI) of the tip 6 is arranged to terminate slightly short of the core metal 12, so that the distance (L) between a circumferential edge (Wx) of the welded portion (WI) and the front end 12a of the core metal 12 falls in a range between 0.0 mm and 2.0 mm at their closest point and when measured in the direction of longitudinal extent of the outer electrode at the tip attachement point, as shown in Fig. 2.
  • The nickel-alloyed matrix 11, which contains 10-20 wt% chromium, is somewhat inferior in thermal conductivity, but superior in both high-temperature strength and oxidation -resistance compared to a nickel-alloyed outer electrode which usually contains more than 90 wt% nickel. In order to compensate for the insufficient thermal conductivity of the nickel-alloyed matrix 11, the front end 12a of the core metal 12 is extended toward the circumferential edge (Wx) of the welded portion (WI) within a range between 0.0 mm and 2.0 mm. The spaced distance (L) makes it possible to prevent an excessive temperature rise of the front end 1A of the outer electrode 1, and thus prevents increased thermal stress from occurring at the welded portion (WI), keeping the tip 6 in place.
  • In assembling the spark plug, the straight-type outer electrode is firstly welded to the metallic shell 2. Then, the insulator 3 is placed within the metallic shell 2. Before bending the outer electrode 1 into L-shaped configuration, the tip 6 is secured to the outer electrode 1 by means of resistance welding. The copper or silver core 12 may be softened and buckled during the resistance welding when the circumferential edge (Wx) of the welded portion (WI) partly overlaps with the front end 12a of the core metal 12. Hence the lower limit of the spaced distance (L) is determined to be 0.0 mm, preventing an overlapping relationship between the circumferential edge (Wx) of the welded portion (WI) and the front end 12a of the core metal 12.
  • On the other hand, the center electrode 5 consists of a composite base metal 50 having a copper core 51 cladded by a nickel-alloyed matrix 52 which contains more than 90 wt% nickel. To a front end of the composite base metal 50. A nickel-alloyed layer 53 which contains 20 ∼ 25 wt% chronium is secured by means of resistance welding. To a front end of the nickel-alloyed layer 53, a platinum tip 7 is secured by means of resistance welding. The platinum tip 7 has a diameter-increased portion 71 welded to the nickel-alloyed layer 53, and a diameter-reduced portion 72 which opposes the platinum tip 6 across the spark gap (Gp).
  • It is noted that outer configuration of the nickel-alloyed layer 53 and the platinum tip 7 may be shaped after carrying out the resistance welding in order to prevent their unfavorable deformations during the welding operation.
  • It is noted that the nickel-alloyed layer 53 may be left out, and the platinum tip 7 may be welded directly to a front end of the diameter-reduced portion of the nickel-alloyed matrix 52 instead of the nickel-alloyed layer 53.
  • Fig. 3 shows a graph showing how corrosion (S) of the welded portion (WI) changes with operating time (T) and the spaced distance (L) after carrying out an endurance experiment with the spark plug mounted on a four-cylinder, 2000 cc, four-cycle internal combustion engine which is alternately operated idling and full throttle at the heat-cool cycle process.
  • In this experiment, Fig. 3a shows a partly broken outer electrode 1 to define an axial length (A) of the platinum tip 6 and an axial length (B) of the welded portion. (WI). The amount of corrosion (S) of the welded portion (WI) is expressed by (A-B)/A for the purpose of convenience.
  • As a result, it is found that a rapid corrosion occurs at the welded portion (WI) in the cases when the spaced distance is 5.0 mm or 3.0 mm with the innermost core 13 provided in the core metal 12 to form the three-layer structure, and in the case when no core metal is provided.
  • It is also found that only small amount of corrosion (S) occurs at the welded portion (WI), but the outer electrode is subjected to an unfavorable deformation (the spark gap widens) when the spaced distance is 0.0 mm with no innermost core provided in the core metal 12 to merely form a two-layer structure. Therefore it is desirable to exclude the case when the spaced distance is 0.0 mm upon putting the invention into practical use.
  • It is, however, understood that only small amount of corrosion (S) occurs at the welded portion (WI) when the spaced distance is kept within the range from 0.0 mm to 2.0 mm.
  • It is appreciated that the invention is not restricted to the extension-type spark plug in which the center electrode 5 projects into the combustion chamber (Ch).

Claims (4)

  1. A spark plug comprising a center electrode (5) disposed within an insulator (3) in a metallic shell (2), an outer electrode (1) extending from the metallic shell (2), and a platinum tip (6) welded to a tip attachment portion of the outer electrode (1) by means of resistance welding and opposing the front end of the center electrode (5) to form a spark gap (Gp) therebetween, the outer electrode (1) comprising a heat-conductive core metal (12) clad by a matrix metal (11) made from nickel-based alloy, characterised in that said alloy contains 10-20% by weight of chromium, and the distance between a circumferential edge (Wx) of the weld (WI), between the outer electrode and the tip (6), and the front end (12a) of the core metal (12) is between 0.0 mm and 2.0 mm at their closest point and when measured in the direction of longitudinal extent of the outer electrode at said tip attachment portion.
  2. A spark plug according to claim 1, wherein the core metal is made of one of the following:
       silver, copper, a silver-based alloy or a copper-based alloy.
  3. A spark plug according to claim 1 or 2 where in the outer electrode includes an innermost core (13) clad by the core metal (12), the innermost core (13) being made of substantially pure nickel or substantially pure iron.
  4. An internal combustion engine comprising a spark plug according to any one of the preceding claims.
EP92305477A 1991-06-13 1992-06-15 Spark plug with a platinum tip on its outer electrode Expired - Lifetime EP0518707B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP14209491A JP3226294B2 (en) 1991-06-13 1991-06-13 Spark plug
JP142094/91 1991-06-13

Publications (3)

Publication Number Publication Date
EP0518707A2 EP0518707A2 (en) 1992-12-16
EP0518707A3 EP0518707A3 (en) 1993-11-18
EP0518707B1 true EP0518707B1 (en) 1996-05-15

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Application Number Title Priority Date Filing Date
EP92305477A Expired - Lifetime EP0518707B1 (en) 1991-06-13 1992-06-15 Spark plug with a platinum tip on its outer electrode

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EP (1) EP0518707B1 (en)
JP (1) JP3226294B2 (en)
DE (1) DE69210686T2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8217561B2 (en) 2007-09-17 2012-07-10 Ngk Spark Plug Co., Ltd. Spark plug having laminated ground electrode

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69400173T2 (en) * 1993-07-06 1996-09-19 Ngk Spark Plug Co Spark plug for internal combustion engines and their manufacturing process
US5456624A (en) * 1994-03-17 1995-10-10 Alliedsignal Inc. Spark plug with fine wire rivet firing tips and method for its manufacture
JPH08213149A (en) * 1995-02-01 1996-08-20 Ngk Spark Plug Co Ltd Spark plug
JP4419327B2 (en) * 2000-04-03 2010-02-24 株式会社デンソー Spark plug for internal combustion engine and method for manufacturing the same
CZ297483B6 (en) * 2001-11-29 2006-12-13 BRISK Tábor a. s. Spark plug
JP4261573B2 (en) 2006-11-23 2009-04-30 日本特殊陶業株式会社 Spark plug
JP5216131B2 (en) * 2011-12-08 2013-06-19 日本特殊陶業株式会社 Spark plug
AT522986B1 (en) * 2019-10-04 2023-06-15 Brigitte Gruber spark plug

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61179837A (en) * 1985-02-05 1986-08-12 Toshiba Corp Nickel-base alloy for spark plug electrode
EP0474351A1 (en) * 1990-09-07 1992-03-11 Ngk Spark Plug Co., Ltd An outer electrode for spark plug and a method of manufacturing thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2296033A (en) * 1941-01-18 1942-09-15 Gen Motors Corp Spark plug
GB2210103B (en) * 1987-09-17 1992-02-05 Champion Spark Plug Europ Spark plug for internal combustion engine

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61179837A (en) * 1985-02-05 1986-08-12 Toshiba Corp Nickel-base alloy for spark plug electrode
EP0474351A1 (en) * 1990-09-07 1992-03-11 Ngk Spark Plug Co., Ltd An outer electrode for spark plug and a method of manufacturing thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8217561B2 (en) 2007-09-17 2012-07-10 Ngk Spark Plug Co., Ltd. Spark plug having laminated ground electrode

Also Published As

Publication number Publication date
EP0518707A3 (en) 1993-11-18
DE69210686T2 (en) 1996-09-19
EP0518707A2 (en) 1992-12-16
JPH04366581A (en) 1992-12-18
JP3226294B2 (en) 2001-11-05
DE69210686D1 (en) 1996-06-20

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