EP0029712B1 - An in-line method for the upgrading of coal - Google Patents
An in-line method for the upgrading of coal Download PDFInfo
- Publication number
- EP0029712B1 EP0029712B1 EP19800304161 EP80304161A EP0029712B1 EP 0029712 B1 EP0029712 B1 EP 0029712B1 EP 19800304161 EP19800304161 EP 19800304161 EP 80304161 A EP80304161 A EP 80304161A EP 0029712 B1 EP0029712 B1 EP 0029712B1
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- European Patent Office
- Prior art keywords
- coal
- oil
- water
- agglomerates
- liberated
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/001—Injecting additional fuel or reducing agents
- C21B5/003—Injection of pulverulent coal
- C21B5/004—Injection of slurries
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
- C10L1/322—Coal-oil suspensions
Definitions
- This invention relates to an in-line method for the upgrading of coal and the formation of a coal-in-oil combustible fuel therefrom.
- the coal fines may contain significant proportions of hydrophilic (or oleo- phobic) impurity or ash-forming particles composed of silica, alumina, pyrite, etc. to which the functional groups of the light hydrocarbon oil bridging liquid are incapable of attaching themselves so that when the coal particle agglomerates are formed, these particles remain suspended in the water and are thus effectively separated from the coal particles.
- hydrophilic or oleo- phobic impurity or ash-forming particles composed of silica, alumina, pyrite, etc.
- Controlled moisture content could also be useful when the coal-in-oil suspension is subjected to vibratory energy such as, for example, in burners which use vibratory energy to increase the combustion efficiency in combustion chambers.
- French patent application No. 2 323 754 describes a process for preparing a liquid fuel comprising a suspension of coal particles in a hydrocarbon oil by treating an aqueous suspension of coal particles in a first agglomeration device, separating the agglomerates, disintegrating the agglomerates and re-agglomerating them in a second agglomeration device, separating these agglomerates and taking them up in a hydrocarbon fuel.
- the agglomeration step is repeated in order to obtain the required degree of deashing.
- the largest coal particles are separated ground and recirculated.
- a method for the continuous beneficiation of coal and the continuous formation of a coal-in-oil combustible fuel therefrom in which coal is comminuted in water to produce a coal-in-water slurry, the coal-in-water slurry is mixed with an agglomerating liquid to agglomerate the coal particles, and the agglomerates are separated out and mixed with oil to form a coal-in-oil combustible fuel, characterized in that the method comprises the following steps:
- Figure 1 there is shown a method for continuous beneficiation of coal and the continuous formation of a coal-in-oil combustible fuel therefrom, comprising:
- a dry pulverizer 28 is used for the initial stage of grinding since this will generally pulverize coal faster and in a smaller equipment volume than with wet methods, although wet grinding may be used throughout, if desired.
- the coat is ground down to a required particle size sufficient to effect separation or dissociation of coal particles and impurities.
- Coal to be pulverized is fed from a storage hopper 30 to the dry pulverizer 28 which is swept with air from a supply 32.
- the swept air, with entrained pulverized coal is fed from the pulverizer 28 to a wet scrubber 34.
- Water containing the pulverized coal is fed from the wet scrubber 34 to the wet mill 1 while air, which has been scrubbed free from the pulverized coal in the wet scrubber 34, is exhausted therefrom at 36.
- coal-in-water slurry 2 from the wet mill 1 is stirred in three mixing devices 4 to 6 arranged in cascade.
- One mixing device could be used provided that the residence time for the coal of the coal-in-water slurry 2 therein to be micro-agglomerated is tolerable. With the embodiment shown in Figure 1, a residence time of four minutes was required and so the three mixing devices 4 to 6 were provided.
- the first mixing device 4 is a high shear mixing device and may be a conventional turbine mixer.
- the first mixing device 4 is used to disperse the light oil agglomerating liquid 8 in the coal-in-water slurry 2 and give an initial mixing.
- the second and third mixing devices 5 and 6 respectively are relatively lower blade speed, intermediate intensity mixing devices as compared with the mixing device 4 and are for producing the micro-agglomerates. It should be noted that in different embodiments of the present invention, only one lower intermediate- intensity mixing device is necessary and in other embodiments different mixing devices may be used, such as, for example, one or more emulsifying units with or without one or more lower, intermediate intensity mixing devices.
- the light oil agglomerating liquid additive 8 is fed to the first mixing device 4 from a storage tank 38.
- micro-agglomerated, impurity-liberated coal is separated from the dissociated components comprising primarily a large amount of inorganic impurities and some water on the screen 10, which in this embodiment is a stationary, inclined screen down which the separated, micro-agglom- .erated, impurity-liberated coal rolls and emerges as micro-agglomerates 12 while the dissociated inorganic impurities and water, designated 40, drain through the screen and are conveyed to a settling pond 42.
- a vibrating screen separator or wet cyclone separator could be used at this stage if the micro-agglomerates possess sufficient strength not to break up in such apparatus.
- the embodiment shown in Figure 1 is arranged to recycle most of the water from delivery 40 to the settling tank 42, together with make-up water 44 which is fed thereto.
- the water 46 from the settling tank provides feed to the wet scrubber 34, wet mill 1 and the first mixing device 4.
- the micro-agglomerates 12 then pass to the mixing device 14 which is also a relatively lower blade speed, intermediate intensity mixing device as compared with the mixing device 4.
- the relatively larger agglomerates are separated from the dissociated water and inorganic impurities on the vibrating screen 18 because the relatively larger agglomerates have sufficient strength not to break up on the vibrating screen 18, which is an efficient separator for the purpose.
- a wet cyclone separator, other types of screens, etc., could also be used at this stage if desired.
- the dissociated water and inorganic impurities designated 48 drain through the vibrating screen 18 and are conveyed to a separation tank 50 from which a portion 52 of the water is returned to the stirrer 14 while the remaining water and inorganic impurities 54 are conveyed to the settling pond 42.
- the reason why the water portion 52 is returned to the mixing device 14 is to ensure that sufficient water is delivered, with the relatively larger agglomerates, to the vibrating screen 18 to ensure that the inorganic impurities are thoroughly washed from the relatively larger agglomerates. This substantially reduces the possibility of inorganic impurities being carried over the vibrating screen 18 with the relatively larger agglomerates.
- the water in mixing device 14 would usually be heated to about 60°C to reduce the viscosity of the heavy fuel oil 16. Recirculation of water portion 52 avoids loss of thermal energy in discarded hot water.
- the mixer 22, to which the relatively larger agglomerates 20 are conveyed in this embodiment is a stationary, cylindrical vessel having a mixing device rotating about a horizontal axis.
- Other types of mixers may also be used such as, for example, a paddle type mixer.
- the coal-in-oil combustible fuel 26 is stored in an agitated condition in a holding tank 56 from which it is withdrawn by a pump 58 at the desired rate for consumption as a combustible fuel in, for example, an electrical power generating installation (not shown).
- the method can be matched to the desired rate of consumption of the combustible fuel so that the holding tank 56 is merely provided for storage to accommodate any fluctuations in the production of the coal-in-oil combustible fuel or the consumption thereof.
- Minto coal A typical analysis of the Minto coal is given below which shows that this is a coal having a high ash and sulphur content.
- the weight ratio of air to coal fed to the dry pulveriser 28 was in the range 1.5:1 to 2:1. 40 wt % coal and 60 wt % water were present in the wet mill 1.
- the first mixing device 4 was fed with 20 wt % coal, 3 wt % No. 2 fuel oil and 77 wt % water.
- the plant was a pilot plant designed to be capable of treating 100 Imperial gallons/min. (455 I/min.) of slurry 2, which is equivalent to about 6 tons/hour (5.44 tonnes/hour) of coal solids (including impurities) based on the 20 wt % slurry fed to the first mixing device 4.
- the blades of the high shear mixing device 4 which were driven by a 5 HP motor at 3,220 rpm, comprised two groups of four high shear impeller blades, two of which are shown for each group and designated 60 to 63, which tapered radially outwardly towards truncated extremities.
- the high shear impeller blades 60 and 62 were mounted in an 18 inch (0.46 m) internal diameter tank 64 having a 35 inch (0.89 m) height with an annular baffle 66 between the impeller blades 60 and 62 and four vertical baffles, two of which are shown and designated 68 and 70, equally spaced therearound to enhance their shearing effect on the coal-in-water slurry 2.
- the four blades of each of the relatively lower blade speed, intermediate intensity mixing devices 5, and 6 and 14, which were driven by a 5 HP motor at 280 rpm comprised pitched, turbine impeller blades two of which are shown and designated 72 and 74.
- the blades 72 and 74 were mounted in a 40 in. (1.02 m) internal diameter vessel having a 40 in. (1.02 m) overflow height with four vertical baffles, two of which are shown and designated 76 and 78, equally spaced around the blades 72 and 74 to enhance their shearing effect.
- the dissociated inorganic impurities and water, designated 40 mainly comprised 96 wt % water and 3 wt % ash and sulphur as the main inorganic impurities together with 1 wt % unagglomerated combustible matter.
- the relatively larger agglomerates produced by mixer 14 comprised 70 wt % coal, 20 wt % oil and 10 wt % water to which was added sufficient No. 6 fuel oil in the mixer 22 for the coal-in-oil combustible fuel 26 to comprise a coal/oil weight ratio of 40/60.
- Preferred light oils/as agglomerating liquid are No. 2 fuel oil and diesel oil.
- Other light oils as agglomerating liquid are, for example, light petroleum fractions, kerosene, coke oven light oil and light crude and residual and waste oils.
- Preferred heavy fuel oils as agglomerating liquid are No. 6 fuel oil and heavy residual oils.
- Other heavy fuel oils as agglomerating liquid are, for example, crude oils and coke oven tar.
- the quantity of light oil agglomerating liquid additive used will depend upon the type of coal being processed and how finely the coal must be ground to produce impurity-liberated coal particles. While a greater quantity of light oil agglomerating liquid additive could be used than 20 wt % of the total weight of solids of the coal-in-water slurry the desirable thing according to the present invention is that only up to 20 wt % need be used so that the final coal-in-oil combustible fuel will contain, for example, the maximum amount of heavy oil for which an oil-fired installation was originally designed, when the coal-in-oil combustible fuel is for use in this manner.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Description
- This invention relates to an in-line method for the upgrading of coal and the formation of a coal-in-oil combustible fuel therefrom.
- It has already been proposed in United States Patent No. 3,665,066, dated May 23, 1972, "Beneficiation of Coals", Capes et al, to beneficiate a coal slurry effluent by mixing a bridging liquid (light hydrocarbon oil) with coal fines and agitating the formed mixture in an aqueous medium to cause agglomeration of the coal particles. The coal particle agglomerates are then at least partially dewatered and fed to a balling device, together with balling nuclei of relative coarse coal particles and binding oil (heavy hydrocarbon oil) to form a balled product in which each ball comprises at least one balling nucleus in association with coal particles from the agglomerates. The coal fines may contain significant proportions of hydrophilic (or oleo- phobic) impurity or ash-forming particles composed of silica, alumina, pyrite, etc. to which the functional groups of the light hydrocarbon oil bridging liquid are incapable of attaching themselves so that when the coal particle agglomerates are formed, these particles remain suspended in the water and are thus effectively separated from the coal particles.
- While the process disclosed in the Capes et al Patent has proved to be useful for the production of relatively coarse, balled coal products in the range 1/8 inch (3.2 mm) to 1 inch (25.4 mm) which are sufficiently strong to be transported in the balled form without the balls disintegrating or releasing coal dust, there is a need for a process for the production of relatively fine, impurity-liberated, balled coal products having an average size no greater than of the order of 3 mm in order that the balls will easily disperse in oil to form a combustible fuel comprising a coal-in-oil suspension. Impurity-liberated coal-in-oil suspensions would be a useful alternative fuel for existing oil-fired electrical generating facilities resulting in a saving in the oil consumption. Other possible uses for these suspensions are marine fuels, fuel for industrial boilers and as injected fuels for blast furnaces.
- In Canadian Patent No. 1,020,880, dated November 15, 1977, "A method of displacing liquid suspendant of a particulate material. liquid suspendant mixture by micro-agglomeration" Capes et al, there is described an in-line, one-stage, agglomerating process for producing microagglomerates of coal fines which is particularly useful for minimizing the moisture content of coal-in-oil suspensions for transportation along long distance pipelines. While this process is useful for the purpose for which it was developed, there is still a need for this process to be developed further to produce a combustible fuel comprising an impurity-liberated, coal-in-oil suspension wherein the retention of larger amounts of the residual moisture content in the fuel from the original coal-in-water slurry can be achieved together with a more accurate control of the larger amount. One reason for this may be that the residual moisture content of the coal-in-oil suspension explodes in a combustion chamber and this possibly aids in dispersing the oil and coal and thereby improving combustion efficiency.
- Controlled moisture content could also be useful when the coal-in-oil suspension is subjected to vibratory energy such as, for example, in burners which use vibratory energy to increase the combustion efficiency in combustion chambers.
- French patent application No. 2 323 754 describes a process for preparing a liquid fuel comprising a suspension of coal particles in a hydrocarbon oil by treating an aqueous suspension of coal particles in a first agglomeration device, separating the agglomerates, disintegrating the agglomerates and re-agglomerating them in a second agglomeration device, separating these agglomerates and taking them up in a hydrocarbon fuel. The agglomeration step is repeated in order to obtain the required degree of deashing. After the first agglomeration step the largest coal particles are separated ground and recirculated.
- According to the present invention there is provided a method for the continuous beneficiation of coal and the continuous formation of a coal-in-oil combustible fuel therefrom, in which coal is comminuted in water to produce a coal-in-water slurry, the coal-in-water slurry is mixed with an agglomerating liquid to agglomerate the coal particles, and the agglomerates are separated out and mixed with oil to form a coal-in-oil combustible fuel, characterized in that the method comprises the following steps:
- a) comminuting coal in water, to produce a coal-in-water slurry comprising impurity-liberated coal particles at least as fine as 40 µm weight means particle size, then
- b) mixing the coal-in-water slurry with light oil as agglomerating liquid having a specific gravity of less than 1 g/cm3 to agglomerate the impurity-liberated coal particles into relatively small agglomerates and primarily dissociate inorganic impurities and some water therefrom, the light oil agglomerating liquid being added at not more than 20 wt % of the total weight of the solids of the coal-in-water slurry, then
- c) separating the impurity-liberated relatively small agglomerates from the dissociated inorganic impurities and water, and
- d) mixing the separated, relatively small impurity-liberated agglomerates with heavy fuel oil, having a specific gravity greater than 0.9 g/cm3 and greater than that of the light oil, as agglomerating liquid to produce relatively larger agglomerates comprising an average size no greater than 3 mm and primarily dissociate water with some inorganic impurities which were present in the relatively small impurity-liberated agglomerates and leave a residual amount of at least 5 wt % water in the relatively larger agglomerates, then
- e) separating the relatively larger agglomerates from the dissociated water and inorganic impurities, and then
- f) mixing the separated, relatively larger agglomerates with make-up heavy oil additive to form a coal-in-oil combustible fuel.
- In the accompanying drawing which illustrates, by way of example, an embodiment of the present invention there is shown a flow diagram of a method for the continuous beneficiation of coal and the continuous formation of a coal-in-oil combustible fuel therefrom.
- In Figure 1 there is shown a method for continuous beneficiation of coal and the continuous formation of a coal-in-oil combustible fuel therefrom, comprising:
- a) comminuting coal-in-water, in a wet mill 1, to produce a coal-in-water slurry 2 comprising impurity-liberated coal particles at least as fine as 40,um weight mean particle size, then
- b) mixing the coal-in-water slurry 2, in three stirring devices 4 to 6 arranged in cascade, with
light oil 8 having a specific gravity of less than 1 g/cm3, as agglomerating liquid to micro- agglomerate (that is to make into relatively small agglomerates) the impurity-liberated coal particles and to dissociate primarily a large amount of inorganic impurities and some water therefrom, the lightoil agglomerating liquid 8 being added at not more than 20 wt % of the total weight of the solids of the coal-in-water slurry 2, then - c) separating, on a dewatering
screen 10 the micro-agglomerated impurity-liberated coal from the dissociated inorganic impurities and water, then - d) mixing the separated, micro-agglomerated impurity-liberated coal 12, in a
stirrer 14, withheavy fuel oil 16, having a specific gravity greater than 0.9 g/cm3, as agglomerating liquid to produce relative larger agglomerates comprising an average size no greater than 3 mm and to dissociate primarily water with some inorganic impurities which were present in the micro-agglomerated, impurity-liberated coal and leave a residual amount of at least 5 wt % water in the relatively larger agglomerates, then - e) separating the relatively larger agglomerates on a vibrating
screen 18, from the dissociated water and inorganic impurities, and then - f) mixing the separated, relatively
larger agglomerates 20, in amixer 22, with make-up,heavy oil additive 24 to form a coal-in-oil combustible fuel 26. - A
dry pulverizer 28 is used for the initial stage of grinding since this will generally pulverize coal faster and in a smaller equipment volume than with wet methods, although wet grinding may be used throughout, if desired. During pulverization, the coat is ground down to a required particle size sufficient to effect separation or dissociation of coal particles and impurities. - Coal to be pulverized is fed from a
storage hopper 30 to thedry pulverizer 28 which is swept with air from asupply 32. The swept air, with entrained pulverized coal, is fed from thepulverizer 28 to awet scrubber 34. Water containing the pulverized coal is fed from thewet scrubber 34 to the wet mill 1 while air, which has been scrubbed free from the pulverized coal in thewet scrubber 34, is exhausted therefrom at 36. - As previously stated the coal-in-water slurry 2 from the wet mill 1 is stirred in three mixing devices 4 to 6 arranged in cascade. One mixing device could be used provided that the residence time for the coal of the coal-in-water slurry 2 therein to be micro-agglomerated is tolerable. With the embodiment shown in Figure 1, a residence time of four minutes was required and so the three mixing devices 4 to 6 were provided.
- The first mixing device 4 is a high shear mixing device and may be a conventional turbine mixer. The first mixing device 4 is used to disperse the light
oil agglomerating liquid 8 in the coal-in-water slurry 2 and give an initial mixing. - The second and
third mixing devices - The light oil agglomerating
liquid additive 8 is fed to the first mixing device 4 from astorage tank 38. - As previously stated the micro-agglomerated, impurity-liberated coal is separated from the dissociated components comprising primarily a large amount of inorganic impurities and some water on the
screen 10, which in this embodiment is a stationary, inclined screen down which the separated, micro-agglom- .erated, impurity-liberated coal rolls and emerges as micro-agglomerates 12 while the dissociated inorganic impurities and water, designated 40, drain through the screen and are conveyed to a settlingpond 42. A vibrating screen separator or wet cyclone separator could be used at this stage if the micro-agglomerates possess sufficient strength not to break up in such apparatus. - The embodiment shown in Figure 1 is arranged to recycle most of the water from
delivery 40 to the settlingtank 42, together with make-upwater 44 which is fed thereto. Thewater 46 from the settling tank provides feed to thewet scrubber 34, wet mill 1 and the first mixing device 4. - The micro-agglomerates 12 then pass to the
mixing device 14 which is also a relatively lower blade speed, intermediate intensity mixing device as compared with the mixing device 4. - The relatively larger agglomerates are separated from the dissociated water and inorganic impurities on the vibrating
screen 18 because the relatively larger agglomerates have sufficient strength not to break up on the vibratingscreen 18, which is an efficient separator for the purpose. A wet cyclone separator, other types of screens, etc., could also be used at this stage if desired. - The dissociated water and inorganic impurities designated 48, drain through the vibrating
screen 18 and are conveyed to aseparation tank 50 from which aportion 52 of the water is returned to thestirrer 14 while the remaining water andinorganic impurities 54 are conveyed to the settlingpond 42. - The reason why the
water portion 52 is returned to themixing device 14 is to ensure that sufficient water is delivered, with the relatively larger agglomerates, to the vibratingscreen 18 to ensure that the inorganic impurities are thoroughly washed from the relatively larger agglomerates. This substantially reduces the possibility of inorganic impurities being carried over the vibratingscreen 18 with the relatively larger agglomerates. In addition, the water in mixingdevice 14 would usually be heated to about 60°C to reduce the viscosity of theheavy fuel oil 16. Recirculation ofwater portion 52 avoids loss of thermal energy in discarded hot water. - The
mixer 22, to which the relativelylarger agglomerates 20 are conveyed in this embodiment is a stationary, cylindrical vessel having a mixing device rotating about a horizontal axis. Other types of mixers may also be used such as, for example, a paddle type mixer. - The coal-in-
oil combustible fuel 26 is stored in an agitated condition in a holding tank 56 from which it is withdrawn by apump 58 at the desired rate for consumption as a combustible fuel in, for example, an electrical power generating installation (not shown). The method can be matched to the desired rate of consumption of the combustible fuel so that the holding tank 56 is merely provided for storage to accommodate any fluctuations in the production of the coal-in-oil combustible fuel or the consumption thereof. - Details of an example using the method shown in Figure 1 to beneficiate coal mined from Minto, New Brunswick, Canada and to form a coal-in-oil combustible fuel therefrom will now be given.
-
- The weight ratio of air to coal fed to the
dry pulveriser 28 was in the range 1.5:1 to 2:1. 40 wt % coal and 60 wt % water were present in the wet mill 1. - The first mixing device 4 was fed with 20 wt % coal, 3 wt % No. 2 fuel oil and 77 wt % water.
- The plant was a pilot plant designed to be capable of treating 100 Imperial gallons/min. (455 I/min.) of slurry 2, which is equivalent to about 6 tons/hour (5.44 tonnes/hour) of coal solids (including impurities) based on the 20 wt % slurry fed to the first mixing device 4. The blades of the high shear mixing device 4, which were driven by a 5 HP motor at 3,220 rpm, comprised two groups of four high shear impeller blades, two of which are shown for each group and designated 60 to 63, which tapered radially outwardly towards truncated extremities. The high
shear impeller blades 60 and 62 were mounted in an 18 inch (0.46 m)internal diameter tank 64 having a 35 inch (0.89 m) height with anannular baffle 66 between theimpeller blades 60 and 62 and four vertical baffles, two of which are shown and designated 68 and 70, equally spaced therearound to enhance their shearing effect on the coal-in-water slurry 2. - The four blades of each of the relatively lower blade speed, intermediate
intensity mixing devices blades blades - The dissociated inorganic impurities and water, designated 40, mainly comprised 96 wt % water and 3 wt % ash and sulphur as the main inorganic impurities together with 1 wt % unagglomerated combustible matter.
- The relatively larger agglomerates produced by
mixer 14 comprised 70 wt % coal, 20 wt % oil and 10 wt % water to which was added sufficient No. 6 fuel oil in themixer 22 for the coal-in-oilcombustible fuel 26 to comprise a coal/oil weight ratio of 40/60. - Tests have shown that using apparatus of the type shown in Figure 1, then:
- i) the preferred blade tip speed of the high
shear impeller blades 60 to 63 is in the range of 10 m/sec. to 30 m/sec. better still of 20 m/sec. to 25 m/sec. - ii) the preferred blade tip speed of the pitched,
turbine impeller blades - Preferred light oils/as agglomerating liquid are No. 2 fuel oil and diesel oil. Other light oils as agglomerating liquid are, for example, light petroleum fractions, kerosene, coke oven light oil and light crude and residual and waste oils. Preferred heavy fuel oils as agglomerating liquid are No. 6 fuel oil and heavy residual oils. Other heavy fuel oils as agglomerating liquid are, for example, crude oils and coke oven tar.
- The quantity of light oil agglomerating liquid additive used will depend upon the type of coal being processed and how finely the coal must be ground to produce impurity-liberated coal particles. While a greater quantity of light oil agglomerating liquid additive could be used than 20 wt % of the total weight of solids of the coal-in-water slurry the desirable thing according to the present invention is that only up to 20 wt % need be used so that the final coal-in-oil combustible fuel will contain, for example, the maximum amount of heavy oil for which an oil-fired installation was originally designed, when the coal-in-oil combustible fuel is for use in this manner.
Claims (6)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA340749 | 1979-11-22 | ||
CA000340749A CA1117884A (en) | 1979-11-22 | 1979-11-22 | In-line method for the beneficiation of coal and the formation of a coal-in-oil combustible fuel therefrom |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0029712A2 EP0029712A2 (en) | 1981-06-03 |
EP0029712A3 EP0029712A3 (en) | 1981-11-11 |
EP0029712B1 true EP0029712B1 (en) | 1984-07-25 |
Family
ID=4115706
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19800304161 Expired EP0029712B1 (en) | 1979-11-22 | 1980-11-20 | An in-line method for the upgrading of coal |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0029712B1 (en) |
CA (1) | CA1117884A (en) |
DE (1) | DE3068727D1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2526680B2 (en) * | 1978-12-04 | 1990-03-02 | American Minechem Corp | METHOD OF CONVERTING COAL MATERIALS INTO AN IMPROVED FEEDSTOCK |
CA1216551A (en) * | 1984-05-23 | 1987-01-13 | Her Majesty The Queen In Right Of The Province Of Alberta As Represented By The Minister Of Energy And Natural Resources | Process for the selective agglomeration of sub- bituminous coal fines |
US4730787A (en) * | 1984-06-19 | 1988-03-15 | The University Of Toronto Innovations Foundation | Method of separating solids by simultaneous comminution and agglomeration |
AU5349090A (en) * | 1989-03-31 | 1990-11-05 | Union Oil Company Of California | Separable coal-in-oil mixtures having controlled sedimentation properties and method for making same |
US5096461A (en) * | 1989-03-31 | 1992-03-17 | Union Oil Company Of California | Separable coal-oil slurries having controlled sedimentation properties suitable for transport by pipeline |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3665066A (en) * | 1969-11-28 | 1972-05-23 | Canadian Patents Dev | Beneficiation of coals |
NL7609905A (en) * | 1975-09-09 | 1977-03-11 | Shell Int Research | PROCESS FOR PREPARING A SUSPENSION OF PARTICLES IN A HYDROCARBON OIL. |
-
1979
- 1979-11-22 CA CA000340749A patent/CA1117884A/en not_active Expired
-
1980
- 1980-11-20 DE DE8080304161T patent/DE3068727D1/en not_active Expired
- 1980-11-20 EP EP19800304161 patent/EP0029712B1/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
EP0029712A3 (en) | 1981-11-11 |
EP0029712A2 (en) | 1981-06-03 |
CA1117884A (en) | 1982-02-09 |
DE3068727D1 (en) | 1984-08-30 |
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