DE3010669C2 - Flame retardant liquid - Google Patents

Flame retardant liquid

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Publication number
DE3010669C2
DE3010669C2 DE3010669A DE3010669A DE3010669C2 DE 3010669 C2 DE3010669 C2 DE 3010669C2 DE 3010669 A DE3010669 A DE 3010669A DE 3010669 A DE3010669 A DE 3010669A DE 3010669 C2 DE3010669 C2 DE 3010669C2
Authority
DE
Germany
Prior art keywords
phosphoric acid
acid ester
carbodiimide
hydrolysis
esters
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE3010669A
Other languages
German (de)
Other versions
DE3010669A1 (en
Inventor
Jürgen Dr. 2000 Hamburg Hübner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mobil Oil AG
Original Assignee
Mobil Oil AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil AG filed Critical Mobil Oil AG
Priority to DE3010669A priority Critical patent/DE3010669C2/en
Publication of DE3010669A1 publication Critical patent/DE3010669A1/en
Application granted granted Critical
Publication of DE3010669C2 publication Critical patent/DE3010669C2/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/74—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/24—Nitriles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/16—Nitriles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/003—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/023—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/0405—Phosphate esters used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049—Phosphite
    • C10M2223/0495—Phosphite used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/0603—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/08—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-nitrogen bonds
    • C10M2223/083—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-nitrogen bonds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/10—Phosphatides, e.g. lecithin, cephalin
    • C10M2223/103—Phosphatides, e.g. lecithin, cephalin used as base material

Description

!^,N'-Dicyclohexylcarbodilmid, Ν,Ν'-Diisopropylcarbodilmid oder N,NP-Bis(4-nitrophenyl)-carbodiimid! ^, N'-dicyclohexylcarbodilmide, Ν, Ν'-diisopropylcarbodilmide or N, NP-bis (4-nitrophenyl) -carbodiimide

enthält.contains.

1H Die Erfindung bezieht sich auf schwer entflammbare Flüssigkeiten, welche auf Phosphorsäuretrtarylestern basieren. Die Erfindung bezieht sich insbesondere auf eine schwer entflammbare Flüssigkeit, die auf Phosphorsäuretrialyrlestern basiert und einen Hydrolyseinhibitor enthält. 1 H The invention relates to flame-retardant liquids based on phosphoric acid trtaryl esters. The invention relates in particular to a flame-retardant liquid which is based on phosphoric acid trialyrlesters and which contains a hydrolysis inhibitor.

Hydraulikflüssigkeiten auf der Basis von Phosphorsäureestern werden seit einiger Zelt verwendet. Sie haben hierfür geeignete Eigenschaften, insbesondere sind sie schwer entflammbar, so daß sie vor allem In Systemen :> mit geschlossenen Hydraulikkreisläufen verwendet werden, beispielsweise In Hydrauliksystemen von Turbinen und von Druckguß-, Strangguß- und Pressenanlagen. Der Einsatz von derartigen Flüssigkeiten wird beispielsweise in den US-PS 34 68 802 und US-PS 37 23 315 beschrieben.Hydraulic fluids based on phosphoric acid esters have been used for some time. They have properties suitable for this purpose, in particular they are flame-retardant, so that they are mainly used in systems :> be used with closed hydraulic circuits, for example in hydraulic systems of turbines and of die-casting, continuous casting and press systems. The use of such liquids is described, for example, in US Pat. No. 3,468,802 and US Pat. No. 3,723,315.

Obgleich derartige Flüssigkeiten schwer entflammbar und auch thermisch relativ stabil sind, können sie in bestimmten Anwendungsfällen gegenüber Hydrolyse unzureichend widerstandsfähig sein.Although such liquids are flame-retardant and also relatively thermally stable, they can be used in be insufficiently resistant to hydrolysis in certain applications.

;.ii Der Erfindung Hegt nun die Aufgabe zugrunde, eine schwer entflammbare Flüssigkeit zu entwickeln, die gegenüber bekannten in Hydrauliksystemen verwendeten Flüssigkelten verbesserte Eigenschaften aufweist, und zwar insbesondere Im Hinblick auf die Hydrolysestabilität.; .ii The invention is based on the object of developing a flame-retardant liquid that has improved properties compared to known liquids used in hydraulic systems, and in particular with regard to hydrolytic stability.

Dies wird durch «Ine schwer entflammbare Flüssigkeit erreicht, welche auf einem PhosphorsäuretrtarylesterThis is achieved by using a flame-retardant liquid based on a phosphoric acid trtaryl ester

oder einem Gemisch von Phosphorsäuretriarylestern basiert und gekennzeichnet 1st durch Carbodiimide,or a mixture of phosphoric acid triaryl esters and is characterized by carbodiimides,

is vorzugsweise 0,001 bis 0,5% eines Carbodiimides, Insbesondere Ν,Ν'-Dlcylohexylcarbodilmid, Ν,Ν'-Dllsopropylis preferably 0.001 to 0.5% of a carbodiimide, in particular Ν, Ν'-Dlcylohexylcarbodilmid, Ν, Ν'-Isopropyl carbodlimid, oder N,N'-Bis(4-nltrophenyl)-Carbodilmld, als Hydrolyseinhibitor und durch andere Additivecarbodlimid, or N, N'-bis (4-nltrophenyl) -carbodilmld, as a hydrolysis inhibitor and by other additives (Antioxidantien, Schauminhibitoren, Korrosionsinhibitoren, weitere Hydrolyseinhibitoren u. dgl.).(Antioxidants, foam inhibitors, corrosion inhibitors, further hydrolysis inhibitors and the like).

Die Hydrolysestabilltat eines Produktes auf der Basis von Phosphorsäuretriarylestern wird zunächst durch die chemische Struktur sowie durch die Herstellungsbedingungen und die Reinigung und Behandlung der Grund-4Ii flüssigkeit beeinflußt. Es zeigt sich, daß die Hydrolysestabllltät von Produkten auf der Basis von Phorphorsäuretriarylestern durch Zusatz eines Carbodiimides ganz erheblich verbessert werden kann.The hydrolysis stability of a product based on phosphoric acid triaryl esters is initially determined by the chemical structure as well as by the manufacturing conditions and the cleaning and treatment of the basic liquid. It turns out that the hydrolysis stability of products based on phosphoric acid triaryl esters can be improved quite considerably by adding a carbodiimide.

Die hinsichtlich der Hydrolysestabilität Im BBC-Hydrolysetest (BBC ZLC 2-5-40) erzielten Verbesserungen sind in der Tabelle zusammengefaßt.The improvements achieved in terms of hydrolytic stability in the BBC hydrolysis test (BBC ZLC 2-5-40) are summarized in the table.

Die Hydrolyse von Phosphorsäureestern wird durch Spuren saurer Produkte, insbesondere durch saure Phosphorsäurepartlalester (sekundäre Phosphorsäureester), beschleunigt.The hydrolysis of phosphoric acid esters is accelerated by traces of acidic products, in particular by acidic phosphoric acid partial esters (secondary phosphoric acid esters).

Carbodiimide reagieren mit diesen sauren Phosphorsäurepartlalestern zu Harnstoffderivaten und neutralen höhermolekularen Phosphorsäureestern und entfernen sie damit aus der Flüssigkeit. Carbodiimide unterdrücken so außerordentlich wirksam die Hydrolyse.Carbodiimides react with these acidic phosphoric acid partal esters to form urea derivatives and neutral ones higher molecular weight phosphoric acid esters and remove them from the liquid. Suppress carbodiimides so extraordinarily effective is hydrolysis.

Niedrigviskose Phosphorsäuretriarylester zeigen (wegen des unvermeidlich höheren Gehaltes an Triphenyl-5(i phosphorsäureester und ähnliche Verbindungen mit nicht substituierter Phenylgruppe) eine schlechte Hydrolysestabllltät. Bisher waren z. B. keine synthetischen Phosphorsäureester der Viskositätsklasse ISO VG 22 verfügbar, die der BBC-Spezlfikatlon hinsichtlich der Hydrolysestabllltät (NZ-Anstleg Im Test mit vorheriger Erdebehandlung max. 0,20 mg KOH/g) genügten. Durch die Verwendung von Carbodlimlden können auch niedrigviskose Phosphorsäureester den BBC-Hydrolysetest ohne Schwierigkelten bestehen.Low-viscosity phosphoric acid triaryl esters show poor hydrolysis stability (because of the inevitable higher content of triphenyl-5 (phosphoric acid ester and similar compounds with unsubstituted phenyl group). So far, for example, no synthetic phosphoric acid esters of viscosity class ISO VG 22 have been available, which the BBC speclfikatlon with regard to the hydrolysis stability (NZ-Anstleg in the test with previous soil treatment max. 0.20 mg KOH / g) was sufficient. By using Carbodlimlden you can also get low-viscosity Phosphoric acid esters pass the BBC hydrolysis test without difficulty.

Darüber hinaus führt die Inhibierung mit Carbodiimiden auch bei höherviskosen Phosphorsäureestern zu einer deutlich besseren Hydrolysestabllltät.In addition, the inhibition with carbodiimides also leads to higher viscosity phosphoric acid esters a significantly better hydrolysis stability.

Die Versuchsergebnisse zeigen, daß die geprüften aliphatischen bzw. cydoallphatlschen Carbodiimide wesentlich wirksamer als das untersuchte aromatische Carbodlimld sind.The test results show that the tested aliphatic or cydoallphatic carbodiimides are significantly more effective than the aromatic carbodiimides tested.

TabelleTabel

BBC Hydrolysetest (BBC ZLC 2-5-40) (50 g Flüssigkeit, 50 g Wasser, 96 Stunden, 100° C) Tests ohne ErdebehandlungBBC hydrolysis test (BBC ZLC 2-5-40) (50 g liquid, 50 g water, 96 hours, 100 ° C) Tests without soil treatment

Neutralisationszahl (DIN 51 558)Neutralization number (DIN 51 558)

vor dem nach dem Anstiegbefore after the climb

Test Test Δ mgTest test Δ mg

mg mg KOH/gmg mg KOH / g

KOH/g KOH/gKOH / g KOH / g

Phosphorsäureester APhosphoric acid ester A

Phosphorsäureester A + 0,20% N.N'-Dicyclohexyl-carbodiimidPhosphoric acid ester A + 0.20% N.N'-dicyclohexyl-carbodiimide

Phosphorsäureester A +
Phosphorsäureester A +
Phosphorsäureester A +
Phosphorsäureester A +
Phosphorsäureester A +
Phosphorsäureester A +
Phosphorsäureester B
Phosphorsäureester B +
Phosphorsäureester C
Phosphorsäureester C +
Phosphorsäureester C +
Phosphorsäureester C +
Phosphorsäureester D
Phosphorsäureester D +Phosphoric acid ester A +
Phosphoric acid ester A +
Phosphoric acid ester A +
Phosphoric acid ester A +
Phosphoric acid ester A +
Phosphoric acid ester A +
Phosphoric acid ester B
Phosphoric acid ester B +
Phosphoric acid ester C
Phosphoric acid ester C +
Phosphoric acid ester C +
Phosphoric acid ester C +
Phosphoric acid ester D
Phosphoric acid ester D +

O.OSWN.N-Dicyclohexyl-carbodiimidO.OSWN.N-dicyclohexyl-carbodiimide

0,02%N,N'-Dicyclohexyl-carbodiimid0.02% N, N'-dicyclohexyl-carbodiimide

0,01 % N^'-Dicyclohexyl-carbodiimid0.01% N ^ '- dicyclohexyl-carbodiimide

0,20%N,N'-Diisopropyl-carbodiimid0.20% N, N'-diisopropyl-carbodiimide

0,05%N,N'-Diisopropyl-carbodiimid0.05% N, N'-diisopropyl-carbodiimide

0,20%N,N'-Bis(4-nitrophenyl)-carbodiimid0.20% N, N'-bis (4-nitrophenyl) carbodiimide

0,20%N,N'-Dicyclohexyl-carbodiimid0.20% N, N'-dicyclohexyl-carbodiimide

O.lOo/oT^N'-Dicyclohexyl-carbodiimidO.lOo / oT ^ N'-dicyclohexyl-carbodiimide

0,lx)%N,N'-Diisopropyl-carbodiimid0.1x)% N, N'-diisopropyl-carbodiimide

0,10%N,N'-Bis(4-nitrophenyl)-carbodiimid0.10% N, N'-bis (4-nitrophenyl) carbodiimide

0,02%N,N'-Dicyclohexyl-carbodiimid0.02% N, N'-dicyclohexyl-carbodiimide

Tests mit vorheriger ErdebehandlungTests with previous soil treatment

Phosphorsäureester BPhosphoric acid ester B

Phosphorsäureester B + 0,20% N.N'-Dicyclohexyl-carbodiimidPhosphoric acid ester B + 0.20% N.N'-dicyclohexyl-carbodiimide

Phosphorsäureester A = Phosphorsäure-triarylester-Gemisch - (38 cSt/40° C)Phosphoric acid ester A = phosphoric acid triaryl ester mixture - (38 cSt / 40 ° C) Phosphorsäureester B = Phosphorsäure-triarylester-Gemisch - (22 cSt/40°C)Phosphoric acid ester B = phosphoric acid triaryl ester mixture - (22 cSt / 40 ° C) Phosphorsäureester C = Phosphorsäure-triarylester-Gemisch - (43 cSt/40° C)Phosphoric acid ester C = phosphoric acid triaryl ester mixture - (43 cSt / 40 ° C) Phosphorsäureester D = Phosphorsäure-triarylester-Gemisch - (43 cSt/40o C)Phosphoric acid ester D = phosphoric acid triaryl ester mixture - (43 cSt / 40 o C)

0,080.08 5,25.2 5,15.1 0,080.08 0,190.19 0,110.11 0,210.21 0,130.13 0,170.17 0,090.09 0,080.08 0,190.19 0,110.11 0,080.08 1,01.0 0,90.9 0,080.08 1,51.5 1,41.4 0,080.08 0,290.29 0,210.21 0,080.08 0,210.21 0,130.13 0,080.08 3,13.1 3,03.0 0,110.11 8,28.2 8,18.1 0,110.11 0,270.27 0,160.16 0,010.01 4,74.7 4,74.7 0,010.01 0,120.12 0,110.11 0,010.01 0,370.37 0,360.36 0,010.01 3,93.9 3,93.9 <0,01<0.01 0,990.99 0,990.99 <0,01<0.01 0,160.16 0,160.16 0,110.11 3,03.0 2,92.9 0,110.11 0,110.11 <0,01<0.01

Claims (2)

Patentansprüche:Patent claims: 1. Schwer entflammbare Flüssigkeit auf der Basis eines Phosphorsäuretrlaryiester oder eines Gemisches von Phosphorsäuretrialrylestern, enthaltend einen Hydrolyseinhibitor, dadurch gekennzeichnet, daß sie als Hydrolyseinhibitor Carbodiimide, vorzugsweise 0,001 bis 0,5% eines Carbondiimides sowie übliche Additive enthält.1. Flame-retardant liquid based on a phosphoric acid traryiester or a mixture of phosphoric acid trialryl esters containing a hydrolysis inhibitor, characterized in that they are carbodiimides as hydrolysis inhibitors, preferably 0.001 to 0.5% of a carbondiimide, as well as customary ones Contains additives. 2. Schwer entflammbare Flüssigkeit nach Anspruch 1, dadurch gekennzeichnet, daß sie als Hydrolyseinhibitor2. Flame-resistant liquid according to claim 1, characterized in that it is used as a hydrolysis inhibitor
DE3010669A 1980-03-20 1980-03-20 Flame retardant liquid Expired DE3010669C2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE3010669A DE3010669C2 (en) 1980-03-20 1980-03-20 Flame retardant liquid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3010669A DE3010669C2 (en) 1980-03-20 1980-03-20 Flame retardant liquid

Publications (2)

Publication Number Publication Date
DE3010669A1 DE3010669A1 (en) 1981-09-24
DE3010669C2 true DE3010669C2 (en) 1986-02-20

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
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Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3855365A (en) * 1972-06-27 1974-12-17 Stauffer Chemical Co Halobenzylphenyl phosphates
US3933663A (en) * 1972-10-02 1976-01-20 Sun Ventures, Inc. Tertiary diamide as swelling agent for elastomeric seal
US3933669A (en) * 1973-10-15 1976-01-20 Monsanto Company Functional fluid compositions
AR208190A1 (en) * 1974-02-11 1976-12-09 Stauffer Chemical Co AMMONIA SALTS OF PHOSPHORATED ACIDS ADDITIVE FOR FUNCTIONAL FLUIDS

Also Published As

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DE3010669A1 (en) 1981-09-24

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Owner name: MOBIL OIL AG, 2000 HAMBURG, DE

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