DE102010063248A1 - Substituted cycloalkane compounds in hair cleansing and conditioning agents - Google Patents

Abstract

The invention relates to hair cleaning and / or hair conditioning agents which contain a) 0.1 to 60% by weight of at least one surfactant selected from the group of anionic, amphoteric / zwitterionic, nonionic and / or cationic surfactants in a cosmetic carrier, and b ) 0.01 to 20% by weight of at least one compound of the formula (I) in which - Y is a cycloalkylene group having 5 to 7 carbon atoms and. - the radicals R1, R2 independently of one another stand for a group in which - R3 stands for a hydrogen atom, a methyl or an ethyl group, - p stands for an integer from 0 to 5, - R4 stands for a hydrogen atom or a methyl group, and q stands for an integer from 0 to 5, all quantitative data being based on the total weight of the hair cleaning and / or hair conditioning agent. The hair cleansing agents and / or hair conditioning agents impart advantageous properties to the hair treated therewith, in particular improved hair grip and improved surface gloss.

Description

The invention is in the field of cosmetics and relates to hair cleansing and / or hair conditioning compositions containing surfactants and substituted cycloalkane compounds. The invention further relates to the use of the hair cleansing and hair conditioning agents for improving the surface gloss of hair.

Cosmetic hair treatment preparations for the cleaning and / or care of the hair have long been known and are regularly improved or adapted to the changing needs of consumers.

For example, consumers expect a modern hair cleanser that it u. a. cleans, smoothes, combs easily, soft, shiny and easy to style, moisturizes, acts against dandruff and gives the hair more volume, so time, cost and environmental considerations no second hair treatment must be applied.

There are a variety of agents known which can meet one or more of the aforementioned requirements in a hair cleanser. However, the presence of a large amount of different active ingredients can destabilize a hair cleanser, which is why it is usually tried to meet as many of the aforementioned requirements with a small number of well-tolerated active ingredients.

Frequently repeated hair treatments, especially reductive and oxidative hair treatments, as well as UV light or hair dryer heat can still damage hair in their structure.

One consequence of this is that they appear unattractive visually and haptically.

An important goal in the production of hair cleansing and / or conditioning agents is therefore to preserve or restore the optical and haptic properties of healthy hair.

It is known to use silicones in hair cleansing and conditioners to increase hair shine, improve the feel and combability of hair. For this purpose, in the WO 1997/038667 Hair treatment compositions have been proposed which contain silicones of a particularly small particle size in an aqueous base.

The problem with the use of silicones in hair cleaners, however, is that silicones can lead to an undesirable weighting of the hair.

From the DE 19757508 It is also known to add a substance with a refractive index above 1.48 to hair-shine agents for hair shine improvement.

The in the DE 19757508 However, these compounds are water-insoluble and have the disadvantage that they must be stabilized in usually water-based cosmetic hair treatment agents, which can be time consuming and cost-intensive to make the preparation of the means.

There continues to be a need for hair cleansing and / or conditioners which offer a conditioning benefit for optically and haptically unattractive hair without the cleaning effect and / or the conditioning effect being diminished.

It is an object of the present invention to provide balanced and nourishing hair cleansing and / or hair conditioning agents which give the dry hair treated therewith more shine and improved hair sensor technology.

In particular, the treated hair should have a long-lasting sensation of moisture, suppleness and softness. A weighting of the hair should be avoided. Another object of the invention was to find nourishing agents or drug combinations for hair cleansing and / or hair conditioning, which can be easily incorporated into the respective means without negatively changing the texture and / or the foam properties of the agent.

• a) 0,1 bis 60 Gew.-% mindestens eines Tensids, ausgewählt aus der Gruppe der anionischen, amphoteren/zwitterionischen, nichtionischen und/oder kationischen Tenside, und
• b) 0,01 bis 20 Gew.-% mindestens einer Verbindung der Formel (I),
  
  in der
• – Y für eine Cycloalkylengruppe mit 5 bis 7 C-Atomen steht und
• – die Reste R¹, R² unabhängig voneinander für eine Gruppierung
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für eine ganze Zahl von 0 bis 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für eine ganze Zahl von 0 bis 5 steht, enthalten,

wobei sich alle Mengenangaben auf das Gesamtgewicht des Haarreinigungs- und/oder Haarkonditioniermittels beziehen.The invention relates to hair cleansing and / or hair conditioning agents which are in a cosmetic carrier

• a) 0.1 to 60 wt .-% of at least one surfactant selected from the group of anionic, amphoteric / zwitterionic, nonionic and / or cationic surfactants, and
• b) 0.01 to 20% by weight of at least one compound of the formula (I),
  
  in the
• Y is a cycloalkylene group having 5 to 7 C atoms and
• - The radicals R ¹ , R ² independently of one another for a grouping
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P is an integer from 0 to 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q is an integer from 0 to 5,

wherein all amounts are based on the total weight of the hair cleansing and / or hair conditioning agent.

The hair cleansing and / or hair conditioning compositions according to the invention contain the obligatory components in a cosmetic carrier, which may preferably be aqueous or aqueous-alcoholic.

The cosmetic carrier preferably contains at least 40% by weight of water.

Furthermore, the cosmetic carrier may contain 0.01 to 50% by weight, preferably 0.05 to 45% by weight and in particular 0.1 to 40% by weight of at least one alcohol which may be selected from ethanol, ethyl diglycol, 1-propanol, 2-propanol, isopropanol, 1,2-propylene glycol, glycerol, 1-butanol, 2-butanol, 1,2-butanediol, 1,3-butanediol, 1-pentanol, 2-pentanol, 1,2- Pentanediol, 1,5-pentanediol, 1, hexanol, 2-hexanol, 1,2-hexanediol, 1,6-hexanediol, sorbitol, benzyl alcohol, phenoxyethanol or mixtures of these alcohols.

Preference is given to the water-soluble alcohols.

Particularly preferred are ethanol, ethyl diglycol, 1-propanol, 2-propanol, isopropanol, 1,2-propylene glycol, glycerol, benzyl alcohol and / or phenoxyethanol and mixtures of these alcohols.

Preferred compounds of the aforementioned formula (I) are water-soluble. Water-soluble compounds within the meaning of the invention are to be understood as meaning those compounds which have a solubility of at least 2 g / 100 g of water under standard conditions (25 ° C., 1013 mbar). Preferred water-soluble compounds of the formula (I) have at least one water solubility, in each case under standard conditions, of at least 5 g / 100 g of water, preferably of at least 10 g / 100 g of water and particularly preferred compounds are completely water-soluble, by which it is to be understood that they in every proportion with water a solution. form.

Further preferred compounds of the aforementioned formula (I) have a refractive index n _D ²⁰ of at least 1.45, preferably of at least 1.46, more preferably of at least 1.47 and in particular of at least 1.48.

The refractive index n represents the deflection of an electromagnetic radiation at the interface between two optically different materials. The refractive index between air and a compound is a specific material property of this compound, which depends on the temperature and the wavelength of the measured radiation. Usually, the refractive index n between air and the compound to be measured at the standard wavelength (D-line of sodium, about 589 nm) and at room temperature (20 ° C) is determined. This refractive index is referred to as n _D ²⁰ . The measurement methods for refractive indices are familiar to the person skilled in the art and are reflected in common standard technical literature.

Further preferred compounds of the aforementioned formula (I) are those which are solid at room temperature and have a melting point in the range from 30 to 75 ° C, preferably from 35 to 70 ° C and in particular from 40 to 65 ° C.

It has been found that solid (waxy) compounds of the aforementioned formula (I) have a positive effect on the texture of the hair cleansers and / or hair conditioners. In particular, it was possible to prepare hair cleansers which, when combined with water, formed a rich, creamy, fine-pored foam.

• – Y für eine 1,2-Cyclopentylen-, eine 1,3-Cyclopentylen-, eine 1,2-Cyclohexylen-, eine 1,3-Cyclohexylen- oder eine 1,4-Cyclohexylengruppe, und
• – die Reste R¹ und R² für gleiche Gruppierungen
  
  stehen, wobei die Reste R³ und R⁴ bevorzugt für Wasserstoff oder eine Methylgruppe stehen, p bevorzugt eine ganze Zahl von 1–3 bedeutet und q bevorzugt für eine ganze Zahl von 0–3 steht.

Further preferred compounds of the aforementioned formula (I) are those in which

• Y is 1,2-cyclopentylene, 1,3-cyclopentylene, 1,2-cyclohexylene, 1,3-cyclohexylene or 1,4-cyclohexylene, and
• - The radicals R ¹ and R ² for the same groupings
  
  in which the radicals R ³ and R ^{4 are} preferably hydrogen or a methyl group, p is preferably an integer from 1 to ³ and q is preferably an integer from 0 to ³ .

• – Y für eine 1,4-Cyclohexylengruppe und
• – die Reste R¹ und R² für gleiche Gruppierungen
  
  stehen, in denen R³ Wasserstoff, und p die Zahlen 1 bis 3 bedeutet.

Particular preference is given to compounds of the abovementioned formula (I) in which

• Y is a 1,4-cyclohexylene group and
• - The radicals R ¹ and R ² for the same groupings
  
  in which R ^{3 is} hydrogen, and p is the numbers 1 to 3.

Particular preference is given to hair cleansing and / or hair conditioning compositions which are known as. Compound (s) of formula (I) contain 1,4-cyclohexanedimethanol (Y = 1,4-cyclohexylene group; R ¹ , R ² = - (CHR ³ ) _p -OH; R ³ = H and p = 1).

In principle, 1,4-cyclohexanedimethanol can be in the form of two stereoisomers. For the effect according to the invention, it is irrelevant whether 1,4-cyclohexanedimethanol is used as pure cis isomer, as pure trans isomer or as isomer mixture of cis and trans isomers.

A suitable for use in the inventive hair cleaning and / or hair conditioners isomer mixture consists for example of about 31% cis-isomer and about 69% trans-isomer and is commercially available under the designation Vertiyl ^® AB-1000 (Fa. Eastman Chemical Company).

The compound (s) of the formula (I) may be present in the hair-cleansing and / or hair-conditioning compositions according to the invention preferably in an amount of from 0.05 to 15% by weight, preferably from 0.1 to 12.5% by weight. % and in particular from 0.5 to 10 wt .-% are used.

As a further compulsory component, the hair cleansing and / or hair conditioning compositions according to the invention contain (based on their total weight) 0.1 to 60 wt .-% of at least one surfactant selected from the group of anionic, amphoteric / zwitterionic, nonionic and / or cationic surfactants.

Anionic surfactants may preferably be added to the compositions according to the invention, based on their total weight, in amounts of from 0.1 to 20% by weight, more preferably from 0.5 to 17.5% by weight and in particular from 1 to 15% by weight. be added.

• – lineare und verzweigte Fettsäuren mit 8 bis 30 C-Atomen (Seifen),
• – Ethercarbonsäuren der Formel R-O-(CH₂-CH₂O)_x-CH₂-COOH, in der R eine lineare oder verzweigte, gesättigte oder ungesättigte Alkylgruppe mit 8 bis 30 C-Atomen und x = 0 oder 1 bis 16 ist,
• – Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acyltauride mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acylisethionate mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Sulfobernsteinsäuremono- und/oder -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 24 C-Atomen in der Alkylgruppe und 1 bis 6 Oxyethylgruppen,
• – Alpha-Olefinsulfonate mit 8 bis 24 C-Atomen,
• – Alkylsulfat- und/oder Alkylpolyglykolethersulfatsalze der Formel R-O(CH₂-CH₂O)_x-OSO₃ ^–X⁺, in der R eine bevorzugt lineare oder verzweigte, gesättigte oder ungesättigte Alkylgruppe mit 8 bis 30 C-Atomen, x = 0 oder 1 bis 12 und X ein Alkali- oder Ammoniumion ist,
• – Sulfonate ungesättigter Fettsäuren mit 8 bis 24 C-Atomen und 1 bis 6 Doppelbindungen,
• – Ester der Weinsäure und Zitronensäure mit Alkoholen, die Anlagerungsprodukte von etwa 2-15 Molekülen Ethylenoxid und/oder Propylenoxid an Fettalkohole mit 8 bis 22 C-Atomen darstellen,
• – Alkyl- und/oder Alkenyletherphosphate der Formel,
  
  in der R¹ bevorzugt für einen aliphatischen Kohlenwasserstoffrest mit 8 bis 30 Kohlenstoffatomen, R² für Wasserstoff, einen Rest (CH₂CH₂O)_nR¹ oder X, n für Zahlen von 0 bis 10 und X für Wasserstoff, ein Alkali- oder Erdalkalimetall oder NR³R⁴R⁵R⁶, mit R³ bis R⁶ unabhängig voneinander stehend für einen C₁ bis C₄-Kohlenwasserstoffrest, steht.

Suitable anionic surfactants which may be used in the compositions of the invention include:

• - linear and branched fatty acids with 8 to 30 carbon atoms (soaps),
• Ether carboxylic acids of the formula RO- (CH ₂ -CH ₂ O) _x -CH ₂ -COOH, in which R is a linear or branched, saturated or unsaturated alkyl group having 8 to 30 C atoms and x = 0 or 1 to 16,
• Acylsarcosides having 8 to 24 C atoms in the acyl group,
• Acyltaurides having 8 to 24 carbon atoms in the acyl group,
• Acyl isethionates having 8 to 24 C atoms in the acyl group,
• Sulfosuccinic acid mono- and / or dialkyl esters having 8 to 24 C atoms in the alkyl group and sulfosuccinic acid monoalkyl polyoxyethyl esters having 8 to 24 C atoms in the alkyl group and 1 to 6 oxyethyl groups,
• Alpha-olefin sulfonates having 8 to 24 C atoms,
• - Alkyl sulfate and / or Alkylpolyglykolethersulfatsalze of the formula RO (CH ₂ -CH ₂ O) _x -OSO ₃ ^- X ⁺ , in which R is a preferably linear or branched, saturated or unsaturated alkyl group having 8 to 30 carbon atoms, x = 0 or 1 to 12 and X is an alkali or ammonium ion,
• Sulfonates of unsaturated fatty acids having 8 to 24 C atoms and 1 to 6 double bonds,
• Esters of tartaric acid and citric acid with alcohols which are adducts of about 2-15 molecules of ethylene oxide and / or propylene oxide with fatty alcohols containing 8 to 22 carbon atoms,
• Alkyl and / or alkenyl ether phosphates of the formula
  
  in the R ^{1 is} preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms, R ^{2 is} hydrogen, a radical (CH ₂ CH ₂ O) _n R ¹ or X, n is from 0 to 10 and X is hydrogen, an alkali metal radical or alkaline earth metal or NR ³ R ⁴ R ⁵ R ⁶ , where R ³ to R ⁶ are each independently a C ₁ to C ₄ hydrocarbon radical.

Preferred anionic surfactants are ether carboxylic acids of the abovementioned formula, acylsarcosides having 8 to 24 C atoms in the acyl group, sulfosuccinic acid mono- and / or dialkyl esters having 8 to 24 C atoms in the alkyl group and sulfosuccinic acid monoalkylpolyoxyethyl esters having 8 to 24 C atoms in the alkyl group and 1 to 6 oxyethyl groups, alpha-olefin sulfonates having 8 to 24 carbon atoms and / or alkyl sulfate and / or Alkylpolyglykolethersulfatsalze the aforementioned formula.

Particularly preferred anionic surfactants are straight-chain or branched alkyl ether sulfates which contain an alkyl radical having 8 to 18 and in particular 10 to 16 C atoms and 1 to 6 and in particular 2 to 4 ethylene oxide units.

Further particularly preferred anionic surfactants are straight-chain or branched alkyl sulfonates which contain an alkyl radical having 8 to 18 and in particular 10 to 16 carbon atoms.

Particular preference is given to the sodium, magnesium and / or triethanolamine salts of linear or branched lauryl, tridecyl and / or myristyl sulfates which have a degree of ethoxylation of from 2 to 4.

Amphoteric / zwitterionic surfactants can the inventive agents - based on the total weight - preferably in amounts of 0.1 to 15 wt .-%, more preferably from 0.5 to 12.5 wt .-% and in particular from 1 to 10 wt. -% to be added.

Suitable amphoteric / zwitterionic surfactants can be selected from compounds of the following formulas (i) to (v) in which the radical R is in each case a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms stands,

Particularly suitable amphoteric / zwitterionic surfactants are alkylamidoalkylbetaines and / or alkylampho (di) acetates of the abovementioned formulas (i) to (v).

Particularly suitable amphoteric / zwitterionic surfactants include the surfactants cocamidopropyl betaine and disodium cocoamphodiacetate known under the INCI name.

Cationic surfactants may be added to the compositions according to the invention - preferably based on the total weight thereof - in amounts of from 0.1 to 10% by weight, based on the total composition. Amounts of 0.2 to 7.5 wt .-% and in particular from 0.3 to 5 wt .-% are particularly preferred.

Suitable cationic surfactants are, for example, quaternary ammonium compounds, esterquats and / or amidoamines.

Preferred quaternary ammonium compounds are ammonium halides, especially chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g. For example, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride, as well as the imidazolium compounds known under the INCI names Quaternium-27, Quaternium-83 and Quaternium-87. The alkyl chains of the above-mentioned surfactants preferably have 10 to 18 carbon atoms.

Esterquats are known substances which contain both at least one ester function and at least one quaternary ammonium group as a structural element. Preferred ester quats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids Diethanolalkylaminen and quaternized ester salts of fatty acids with 1,2-Dihydroxypropyldialkylaminen. Such products are marketed under the trade names Stepantex® ^®, Dehyquart® ^{®, ®} and Armocare® Quartamin ^®.

The alkylamidoamines are usually prepared by amidation of natural or synthetic fatty acids and fatty acid cuts with dialkylaminoamines. A particularly suitable compound from this group of substances under the name Tegoamid ^® S 18 stearamidopropyl commercially represent.

Nonionic surfactants and / or nonionic emulsifiers may, preferably in an amount of from 0.1 to 15% by weight, preferably from 0.5 to 12.5% by weight and in particular from 1 to 10% by weight, based on the total weight of the compositions according to the invention .-% be added.

• – C₈-C₃₀-Fettsäuremono- und -diester von Anlagerungsprodukten von 1 bis 30 Mol Ethylenoxid an Glycerin,
• – Aminoxide,
• – Anlagerungsprodukte von 2 bis 50 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, an Fettsäuren mit 8 bis 30 C- Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe,
• – Sorbitanfettsäureester und Anlagerungeprodukte von Ethylenoxid an Sorbitanfettsäureester wie beispielsweise Polysorbate,
• – Zuckerfettsäureester und Anlagerungsprodukte von Ethylenoxid an Zuckerfettsäureester,
• – Anlagerungsprodukte von Ethylenoxid an Fettsäurealkanolamide und Fettamine und/oder
• – Alkylpolyglucoside.

Examples of suitable nonionic surfactants / emulsifiers include

• C ₈ -C ₃₀ -fatty acid mono- and diesters of addition products of 1 to 30 mol of ethylene oxide with glycerol,
• - amine oxides,
• - Addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 carbon atoms and to alkylphenols having 8 to 15 carbon atoms in the alkyl group,
• Sorbitan fatty acid esters and adducts of ethylene oxide with sorbitan fatty acid esters such as polysorbates,
• Sugar fatty acid esters and addition products of ethylene oxide with sugar fatty acid esters,
• - Addition products of ethylene oxide to fatty acid alkanolamides and fatty amines and / or
• - Alkyl polyglucosides.

In the event that a nonionic surfactant is used in the hair treatment compositions, alkyl oligoglucosides, in particular alkyl oligoglucosides based on hydrogenated C _12/14 cocoalcohol having a DP of 1-3, as described for example under the INCI name "Coco-glucosides "Are commercially available, preferably.

Further preferred nonionic surfactants are the C ₈ -C ₃₀ fatty acid mono- and diesters of addition products of 1 to 30 moles of ethylene oxide with glycerol. Particularly preferred are the C ₁₀ -C ₁₆ -Fetsäuremono- and diesters of addition products of 1 to 10 moles of ethylene oxide to glycerol. Especially preferred is the PEG-7 glyceryl cocoate known under the INCI name.

• a) (i) 0,1 bis 10 Gew.-%, mehr bevorzugt 0,2 bis 7,5 Gew.-% und insbesondere 0,3 bis 5 Gew.-% mindestens eines kationischen Tensids aus der Gruppe der quartären Ammoniumverbindungen, der Esterquats und der Amidoamine und/oder
• (ii) 0,1 bis 20 Gew.-%, bevorzugt 0,5 bis 17,5 Gew.-% und insbesondere 1 bis 15 Gew.-% mindestens eines anionischen Tensids aus der Gruppe der Alkyl(ether)sulfate, der Ethercarbonsäuren, der Sulfobernsteinsäuremono- und -dialkylester, der Olefinsulfonate und der Acylsarcoside und/oder
• (iii) 0,1 bis 15 Gew.-%, bevorzugt 0,5 bis 12,5 Gew.-% und insbesondere 1 bis 10 Gew.-% mindestens eines amphoteren/zwitterionischen Tensids aus der Gruppe der Alkylbetaine, der Alkylamidoalkylbetaine und der Alkylampho(di)acetate und/oder
• (iv) 0,1 bis 15 Gew.-%, bevorzugt 0,5 bis 12,5 Gew.-% und insbesondere 1 bis 10 Gew.-% mindestens eines nichtionischen Tensids aus der Gruppe der Anlagerungsprodukte von Ethylenoxid und/oder Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, an Fettsäuren mit 8 bis 30 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe, der Fettsäuremono- und -diester von Anlagerungsprodukten von Ethylenoxid an Glycerin, der Anlagerungsprodukte von Ethylenoxid an Rizinusöl und gehärtetes Rizinusöl, der Aminoxide, der Anlagerungsprodukte von Ethylenoxid an Fettsäurealkanolamide und Fettamine, und der Alkylpolyglucoside, und
• b) 0,05 bis 15 Gew.-%, bevorzugt 0,1 bis 12,5 Gew.-% und insbesondere 0,5 bis 10 Gew.-% 1,4-Cyclohexandimethanol.

In a first preferred embodiment, hair cleansing and / or hair conditioning compositions according to the invention contain, based on their total weight,

• a) (i) 0.1 to 10 wt .-%, more preferably 0.2 to 7.5 wt .-% and in particular 0.3 to 5 wt .-% of at least one cationic surfactant from the group of quaternary ammonium compounds, the esterquats and the amidoamines and / or
• (Ii) 0.1 to 20 wt .-%, preferably 0.5 to 17.5 wt .-% and in particular 1 to 15 wt .-% of at least one anionic surfactant from the group of alkyl (ether) sulfates, the ether carboxylic acids , the sulfosuccinic acid mono and dialkyl esters, the olefin sulfonates and the acyl sarcosides and / or
• (Iii) 0.1 to 15 wt .-%, preferably 0.5 to 12.5 wt .-% and in particular 1 to 10 wt .-% of at least one amphoteric / zwitterionic surfactant from the group of alkyl betaines, Alkylamidoalkylbetaine and Alkylampho (di) acetates and / or
• (Iv) 0.1 to 15 wt .-%, preferably 0.5 to 12.5 wt .-% and in particular 1 to 10 wt .-% of at least one nonionic surfactant from the group of addition products of ethylene oxide and / or propylene oxide linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 carbon atoms and alkylphenols having 8 to 15 carbon atoms in the alkyl group, the fatty acid mono- and diesters of addition products of ethylene oxide to glycerol, the addition products of ethylene oxide with castor oil and hydrogenated castor oil, the amine oxides, the adducts of ethylene oxide with fatty acid alkanolamides and fatty amines, and the alkyl polyglucosides, and
• b) 0.05 to 15 wt .-%, preferably 0.1 to 12.5 wt .-% and in particular 0.5 to 10 wt .-% 1,4-cyclohexanedimethanol.

Particularly preferred according to the invention within this first embodiment are hair-cleansing compositions which, in addition to component b), contain in each case at least one surfactant from the abovementioned groups (ii) and (iii).

For the production of particularly mild and scalp-friendly hair cleansers, it is particularly advantageous within this embodiment if the surfactants from groups (ii) and (iii) have a weight ratio of 4: 1 to 1: 3, preferably 3.5: 1 to 1 : 2 and in particular from 3: 1 to 1: 1.

Furthermore, particularly preferred within this first embodiment are hair cleansing compositions which contain, in addition to component b), at least one surfactant from the abovementioned groups (ii), (iii) and (i).

Furthermore, particularly preferred within this first embodiment are hair cleansing compositions which, in addition to component b), each contain at least one surfactant from the abovementioned groups (ii), (iii) and (iv).

Within this embodiment, it is particularly advantageous if the surfactants from groups (ii), (iii) and (iv) have a weight ratio of (3 - 5) :( 1 - 3) :( 1 - 2).

Further particularly preferred within this first embodiment are hair conditioning agents which, in addition to component b), contain at least one surfactant from the aforementioned group (i).

A long-lasting feeling of hair care is one of the objects of the present invention. In order to achieve this goal, it is advantageous if the nourishing component (s) b) can penetrate into the hair fibers from the hair cleaners and / or hair care agents or can be deposited on the fibers.

To support the penetration or deposition of the care component (s) b) and / or further care components, the hair cleansing and / or hair conditioning compositions according to the invention may in another preferred embodiment 0.01 to 10 wt .-%, preferably 0.05 to 7 , 5 wt .-% and in particular 0.1 to 5 wt .-% of at least one cationic polymer.

• – quaternisierte Cellulose-Derivate, wie sie unter den Bezeichnungen Celquat^® und Polymer JR^® im Handel erhältlich sind,
• – hydrophob modifizierte Cellulosederivate, beispielsweise die unter dem Handelsnamen SoftCat^® vertriebenen kationischen Polymere,
• – kationische Alkylpolyglycoside,
• – kationiserter Honig, beispielsweise das Handelsprodukt Honeyquat^®50,
• – kationische Guar-Derivate, wie insbesondere die unter den Handelsnamen Cosmedia^®Guar und Jaguar^® vertriebenen Produkte,
• – polymere Dimethyldiallylammoniumsalze und deren Copolymere mit Estern und Amiden von Acrylsäure und Methacrylsäure. Die unter den Bezeichnungen Merquat^®100 (Poly(dimethyldiallylammoniumchlorid)) und Merquat^®550 (Dimethyldiallylammoniumchlorid-Acrylamid-Copolymer) im Handel erhältlichen Produkte sind Beispiele für solche kationischen Polymere,
• – Copolymere des Vinylpyrrolidons mit quaternierten Derivaten des Dialkylaminoalkylacrylats und -methacrylats, wie beispielsweise mit Diethylsulfat quaternierte Vinylpyrrolidon-Dimethylaminoethylmethacrylat-Copolymere. Solche Verbindungen sind unter den Bezeichnungen Gafquat^®734 und Gafquat^®755 im Handel erhältlich,
• – Vinylpyrrolidon-Vinylimidazoliummethochlorid-Copolymere, wie sie unter den Bezeichnungen Luviquat^®FC 370, FC 550, FC 905 und HM 552 angeboten werden,
• – quaternierter Polyvinylalkohol, sowie die unter den Bezeichnungen
• – Polyquaternium 2, Polyquaternium 17, Polyquaternium 18, Polyquaternium-24, Polyquaternium 27, Polyquaternium-32, Polyquaternium-37, Polyquaternium 74 und Polyquaternium 89 bekannten Polymere.

Suitable cationic polymers are, for example:

• - quaternized cellulose derivatives, such as are available under the names of Celquat ^® and Polymer JR ^® commercially
• - hydrophobically modified cellulose derivatives, for example those sold under the trade name SOFTCAT ^® cationic polymers,
• Cationic alkyl polyglycosides,
• - cationized honey, for example the commercial product Honeyquat ^® 50,
• - cationic guar derivatives, such as in particular the products sold under the trade names Cosmedia® ^® Guar and Jaguar ^®,
• - Dimethyldiallylammoniumsalze polymeric and their copolymers with esters and amides of acrylic acid and methacrylic acid. Under the names Merquat ^® 100 (Poly (dimethyldiallylammonium chloride)) and Merquat ^® 550 (dimethyldiallylammonium chloride-acrylamide copolymer) are examples of such cationic polymers,
• - Copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoalkyl acrylate and methacrylate, such as diethyl sulfate quaternized vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers. Such compounds are sold under the names Gafquat ^® 734 and Gafquat ^® 755 commercially,
• - vinylpyrrolidone vinylimidazoliummethochloride copolymers, such as those offered under the names Luviquat.RTM ^® FC 370, FC 550, FC 905 and HM 552,
• - Quaternized polyvinyl alcohol, as well as those under the names
• Polyquaternium 2, Polyquaternium 17, Polyquaternium 18, Polyquaternium-24, Polyquaternium 27, Polyquaternium-32, Polyquaternium-37, Polyquaternium 74 and Polyquaternium 89 known polymers.

Further suitable cationic polymers are the so-called "temporary cationic" polymers. These polymers usually contain an amino group which, at certain pH values, is present as quaternary ammonium group and thus cationic. For example, chitosan and its derivatives are preferred as Hydagen CMF ^{®, ®} Hydagen -HCMF, Kytamer ^® PC and Chitolam ^® NB / 101 are freely available commercially, for example under the trade names. Chitosans are deacetylated chitins, which are commercially available in different degrees of deacetylation and different degrees of degradation (molecular weights).

Particularly preferred cationic polymers which can be used in the hair treatment compositions according to the invention are quaternized cellulose polymers, cationic guar derivatives and / or cationic polymers based on acrylic acid (derivative), which are in particular selected from the polymers known under the INCI names Polyquaternium-6, Polyquaternium -7, Polyquaternium-10, Polyquaternium-37 and / or Polyquaternium-67.

• a) (i) 0,1 bis 10 Gew.-%, bevorzugt 0,2 bis 7,5 Gew.-% und insbesondere 0,3 bis 5 Gew.-% mindestens eines kationischen Tensids aus der Gruppe der quartären Ammoniumverbindungen, der Esterquats und der Amidoamine und/oder
• (ii) 0,1 bis 20 Gew.-%, bevorzugt 0,5 bis 17,5 Gew.-% und insbesondere 1 bis 15 Gew.-% mindestens eines anionischen Tensids aus der Gruppe der Alkyl(ether)sulfate, der Ethercarbonsäuren, der Sulfobernsteinsäuremono- und -dialkylester, der Olefinsulfonate und der Acylsarcoside und/oder
• (iii) 0,1 bis 15 Gew.-%, bevorzugt 0,5 bis 12,5 Gew.-% und insbesondere 1 bis 10 Gew.-% mindestens eines amphoteren/zwitterionischen Tensids aus der Gruppe der Alkylbetaine, der Alkylamidoalkylbetaine und der Alkylampho(di)acetate und/oder
• (iv) 0,1 bis 15 Gew.-%, bevorzugt 0,5 bis 12,5 Gew.-% und insbesondere 1 bis 10 Gew.-% mindestens eines nichtionischen Tensids aus der Gruppe der Anlagerungsprodukte von Ethylenoxid und/oder Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, an Fettsäuren mit 8 bis 30 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe, der Fettsäuremono- und -diester von Anlagerungsprodukten von Ethylenoxid an Glycerin, der Anlagerungsprodukte von Ethylenoxid an Rizinusöl und gehärtetes Rizinusöl, der Aminoxide, der Anlagerungsprodukte von Ethylenoxid an Fettsäurealkanolamide und Fettamine, und der Alkylpolyglucoside, und
• b) 0,05 bis 15 Gew.-%, bevorzugt 0,1 bis 12,5 Gew.-% und insbesondere 0,5 bis 10 Gew.-% 1,4-Cyclohexandimethanol und
• c) 0,01 bis 10 Gew.-%, bevorzugt 0,05 bis 7,5 Gew.-% und insbesondere bevorzugt 0,1 bis 5 Gew.-% mindestens eines kationischen Polymeren, ausgewählt aus quaternisierten Cellulosepolymeren, kationischen Guarderivaten und/oder kationischen Polymeren auf Acrylsäure(derivat)basis.

In a second particularly preferred embodiment of the invention, hair cleansers and / or hair conditioning agents according to the invention contain, based on their total weight, preference

• a) (i) 0.1 to 10 wt .-%, preferably 0.2 to 7.5 wt .-% and in particular 0.3 to 5 wt .-% of at least one cationic surfactant from the group of quaternary ammonium compounds, the Esterquats and amidoamines and / or
• (Ii) 0.1 to 20 wt .-%, preferably 0.5 to 17.5 wt .-% and in particular 1 to 15 wt .-% of at least one anionic surfactant from the group of alkyl (ether) sulfates, the ether carboxylic acids , the sulfosuccinic acid mono and dialkyl esters, the olefin sulfonates and the acyl sarcosides and / or
• (Iii) 0.1 to 15 wt .-%, preferably 0.5 to 12.5 wt .-% and in particular 1 to 10 wt .-% of at least one amphoteric / zwitterionic surfactant from the group of alkyl betaines, Alkylamidoalkylbetaine and Alkylampho (di) acetates and / or
• (Iv) 0.1 to 15 wt .-%, preferably 0.5 to 12.5 wt .-% and in particular 1 to 10 wt .-% of at least one nonionic surfactant from the group of addition products of ethylene oxide and / or propylene oxide linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 carbon atoms and alkylphenols having 8 to 15 carbon atoms in the alkyl group, the fatty acid mono- and diesters of addition products of ethylene oxide to glycerol, the addition products of ethylene oxide with castor oil and hydrogenated castor oil, the amine oxides, the adducts of ethylene oxide with fatty acid alkanolamides and fatty amines, and the alkyl polyglucosides, and
• b) 0.05 to 15 wt .-%, preferably 0.1 to 12.5 wt .-% and in particular 0.5 to 10 wt .-% 1,4-cyclohexanedimethanol and
• c) 0.01 to 10 wt.%, preferably 0.05 to 7.5 wt.% and particularly preferably 0.1 to 5 wt.% of at least one cationic polymer selected from quaternized cellulose polymers, cationic guar derivatives and / or or cationic polymers based on acrylic acid (derivative).

Particularly preferred according to the invention within this second embodiment are hair cleansing compositions which, in addition to component b), contain in each case at least one surfactant from the abovementioned groups (ii) and (iii).

For the production of particularly mild and scalp-friendly hair cleansers, it is particularly advantageous within this embodiment if the surfactants from groups (ii) and (iii) have a weight ratio of 4: 1 to 1: 3, preferably 3.5: 1 to 1 : 2 and in particular from 3: 1 to 1: 1.

Furthermore, particularly preferred within this second embodiment are hair cleansing compositions which contain, in addition to component b), at least one surfactant from the abovementioned groups (ii), (iii) and (i).

Furthermore, particularly preferred within this second embodiment are hair cleansing compositions containing, in addition to component b), at least one surfactant from the abovementioned groups (ii), (iii) and (iv).

Within this embodiment, it is particularly advantageous if the surfactants from groups (ii), (iii) and (iv) have a weight ratio of (3 - 5) :( 1 - 3) :( 1 - 2).

Further particularly preferred within this second embodiment are hair conditioning agents which, in addition to component b), contain at least one surfactant from the aforementioned group (i).

In addition to the aforementioned active substances, the hair-cleansing and / or hair-conditioning compositions according to the invention may also contain a number of other active ingredients which give them advantageous properties.

• – Öl-, Wachs- und/oder Fettkomponenten, die die in den jeweiligen Haarbehandlungsmitteln (bezogen auf ihr Gesamtgewicht) bevorzugt in einer Menge von 0,01–20 Gew.-%, besonders bevorzugt von 0,05–15 Gew.-% und insbesondere von 0,1–10 Gew.-% eingesetzt werden können,
• – Antischuppenwirkstoffe, die in den jeweiligen Haarbehandlungsmitteln (bezogen auf ihr Gesamtgewicht) bevorzugt in einer Menge von 0,025 bis 7,5 Gew.-%, besonders bevorzugt von 0,05 bis 5 Gew.-% und insbesondere von 0,075 bis 3 Gew.-% eingesetzt werden können.

The preferred optional active substances that can be used in the hair-cleansing and / or hair-conditioning compositions according to the invention include, for example:

• Oily, waxy and / or fatty components which in the respective hair treatment compositions (based on their total weight) preferably in an amount of 0.01-20% by weight, particularly preferably 0.05-15% by weight and in particular from 0.1-10% by weight,
• Antidandruff active ingredients which in the respective hair treatment compositions (based on their total weight) are preferably present in an amount of from 0.025 to 7.5% by weight, particularly preferably from 0.05 to 5% by weight and in particular from 0.075 to 3% by weight. % can be used.

Suitable oil and / or fat components may preferably be selected from mineral, natural and synthetic oil components and / or fatty substances.

As natural (vegetable) oils usually triglycerides and mixtures of triglycerides are used. Preferred natural oils are coconut oil, (sweet) almond oil, walnut oil, peach kernel oil, apricot kernel oil, avocado oil, tea tree oil, soybean oil, sesame oil, sunflower oil, tsubaki oil, evening primrose oil, rice bran oil, palm kernel oil, mango seed oil, meadowfoam seed oil, thistle oil, macadamia nut oil, grapeseed oil, Amaranth seed oil, argan oil, bamboo oil, olive oil, wheat germ oil, pumpkin seed oil, mallow oil, hazelnut oil, safflower oil, canola oil, sasanqua oil, jojoba oil, rambutan oil, cocoa butter and shea butter.

As mineral oils are used in particular mineral oils, paraffin and Isoparaffinöle and synthetic hydrocarbons. An example of a usable hydrocarbon is for example that available as a commercial product 1,3-di- (2-ethyihexyl) -cyclohexane (Cetiol ^® S).

Suitable synthetic oils are silicone compounds. Silicones have excellent conditioning properties on the hair. In particular, they cause better combability of the hair in the wet and dry state and in many cases have a positive effect on the hair and the softness of the hair.

• (i) Polyalkylsiloxanen, Polyarylsiloxanen, Polyalkylarylsiloxanen, die flüchtig oder nicht flüchtig, geradkettig, verzweigt oder cyclisch, vernetzt oder nicht vernetzt sind;
• (ii) Polysiloxanen, die in ihrer allgemeinen Struktur eine oder mehrere organofunktionelle Gruppen enthalten, die ausgewählt sind unter:
• a) substituierten oder unsubstituierten aminierten Gruppen;
• b) (per)fluorierten Gruppen;
• c) Thiolgruppen;
• d) Carboxylatgruppen;
• e) hydroxylierten Gruppen;
• f) alkoxylierten Gruppen;
• g) Acyloxyalkylgruppen;
• h) amphoteren Gruppen;
• i) Bisulfitgruppen;
• j) Hydroxyacylaminogruppen;
• k) Carboxygruppen;
• l) Sulfonsäuregruppen; und
• m) Sulfat- oder Thiosulfatgruppen;
• (iii) linearen Polysiloxan(A)-Polyoxyalkylen(B)-Blockcopoylmeren vom Typ (A-B)_n mit n > 3;
• (iv) gepfropften Siliconpolymeren mit nicht siliconhaltigem, organischen Grundgerüst, die aus einer organischen Hauptkette bestehen, welche aus organischen Monomeren gebildet wird, die kein Silicon enthalten, auf die in der Kette sowie gegebenenfalls an mindestens einem Kettenende mindestens ein Polysiloxanmakromer gepfropft wurde;
• (v) gepfropften Siliconpolymeren mit Polysiloxan-Grundgerüst, auf das nicht siliconhaltige, organische Monomere gepfropft wurden, die eine Polysiloxan-Hauptkette aufweisen, auf die in der Kette sowie gegebenenfalls an mindestens einem ihrer Enden mindestens ein organisches Makromer gepfropft wurde, das kein Silicon enthält;
• (vi) oder deren Gemischen.

It is therefore desirable to use silicones in the cosmetic hair treatment compositions. Suitable silicones may be selected from:

• (i) polyalkyl siloxanes, polyaryl siloxanes, polyalkylaryl siloxanes which are volatile or nonvolatile, straight chain, branched or cyclic, crosslinked or uncrosslinked;
• (ii) Polysiloxanes containing in their general structure one or more organofunctional groups selected from:
• a) substituted or unsubstituted aminated groups;
• b) (per) fluorinated groups;
• c) thiol groups;
• d) carboxylate groups;
• e) hydroxylated groups;
• f) alkoxylated groups;
• g) acyloxyalkyl groups;
• h) amphoteric groups;
• i) bisulfite groups;
• j) hydroxyacylamino groups;
• k) carboxy groups;
• l) sulfonic acid groups; and
• m) sulphate or thiosulphate groups;
• (iii) linear polysiloxane (A) polyoxyalkylene (B) block copolymers of the (AB) _{n type} with n>3;
• (iv) grafted silicone polymers having a non-silicone organic backbone consisting of an organic backbone formed from organic monomers containing no silicone grafted with at least one polysiloxane macromer in the chain and optionally at least one chain end;
• (v) grafted polysiloxane backbone silicone polymers having grafted thereto non-silicone organic monomers having a polysiloxane backbone to which at least one organic macromer not containing silicone has been grafted in the chain, and optionally at least at one of its ends ;
• (vi) or mixtures thereof.

As the oil component may further serve a dialkyl ether.

Useful dialkyl ethers are, in particular, di-n-alkyl ethers having a total of from 12 to 36 carbon atoms, in particular from 12 to 24 carbon atoms, such as, for example, di-n-octyl ether, di-n-decyl ether, di-n-nonyl ether, Di-n-undecyl ether, di-n-dodecyl ether, n-hexyl n-octyl ether, n-octyl n-decyl ether, n-decyl n-undecyl ether, n-undecyl n-dodecyl ether and n-hexyl-n-n-octyl n-octyl ether. undecyl ether and di-tert-butyl ether, di-isopentyl ether, di-3-ethyldecyl ether, tert-butyl-n-octyl ether, iso-pentyl-n-octyl ether and 2-methylpentyl-n-octyl ether.

Particularly preferred is the di-n-octyl ether, which is commercially available under the name Cetiol ^® OE.

Fatty substances are to be understood fatty acids, fatty alcohols and natural and synthetic waxes, which may be present both in solid form and liquid in aqueous dispersion.

As fatty acids can be used linear and / or branched, saturated and / or unsaturated fatty acids with 6-30 carbon atoms. Preference is given to fatty acids having 10 to 22 carbon atoms. Among these could be mentioned, for example, isostearic as the commercial products Emersol ^® 871 and Emersol ^® 875, and isopalmitic like that. Commercial product Edenor ^® IP 95, and all other products sold under the trade names Edenor ^® (Cognis) fatty acids. Other typical examples of such fatty acids include caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitoleic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic and erucic acid and their technical mixtures.

Particularly preferred are usually the fatty acid cuttings obtainable from coconut oil or palm oil; In particular, the use of stearic acid is usually preferred.

As fatty alcohols it is possible to use saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols with C ₆ -C ₃₀ -, preferably C ₁₀ -C ₂₂ - and very particularly preferably C ₁₂ -C ₂₂ -carbon atoms. For example, decanol, octanol, octenol, dodecenol, decenol, octadienol, dodecadienol, decadienol, oleyl alcohol, erucalcohol, ricinoleic alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol, arachidyl alcohol, capryl alcohol, capric alcohol, linoleyl alcohol, linolenyl alcohol and behenyl alcohol, as well as their guerbet alcohols can be used , this list should have exemplary and non-limiting character. However, the fatty alcohols are derived from preferably natural fatty acids, which can usually be based on recovery from the esters of fatty acids by reduction. Also usable according to the invention are those fatty alcohol cuts which are produced by reduction of naturally occurring triglycerides such as beef tallow, palm oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil and linseed oil or fatty acid esters formed from their transesterification products with corresponding alcohols, and thus represent a mixture of different fatty alcohols. Such substances are, for example, under the names Stenol ^® , z. B. Stenol ^® 1618 or Lanette ^®, z. B. Lanette ^® O or Lorol ^®, z. B. Lorol® ^® C8, Lorol® ^® C14, C18 Lorol® ^{®, ®} Lorol® C8-18, HD Ocenol ^®, Crodacol ^®, z. B. Crodacol CS ^{®, ®} Novol, Eutanol ^® G, Guerbitol ^® 16, Guerbitol ^® 18, Guerbitol ^® 20, Isofol ^® 12, Isofol ^® 16, Isofol ^® 24, Isofol ^® 36, Isocarb 12 ^{®, ®} Isocarb 16 or Isocarb ^® 24 for sale. Of course, wool wax alcohols, as are commercially available, for example under the names of Corona ^®, White Swan ^®, Coronet ^® or Fluilan ^® can be used according to the invention.

As natural or synthetic waxes there may be used solid paraffins or isoparaffins, carnauba waxes, beeswaxes, candelilla waxes, ozokerites, ceresin, spermaceti, sunflower wax, fruit waxes such as apple wax or citrus wax, microwaxes of PE or PP. Such waxes are available, for example, from Kahl & Co., Trittau.

• – Esteröle. Unter Esterölen sind zu verstehen die Ester von C₆-C₃₀-Fettsäuren mit C₂–C₃₀-Fettalkoholen. Bevorzugt sind die Monoester der Fettsäuren mit Alkoholen mit 2 bis 24 C-Atomen. Beispiele für eingesetzte Fettsäurenanteile in den Estern sind Capronsäure, Caprylsäure, 2-Ethylhexansäure, Caprinsäure, Laurinsäure, Isotridecansäure, Myristinsäure, Palmitinsäure, Palmitoleinsäure, Stearinsäure, Isostearinsäure, Ölsäure, Elaidinsäure, Petroselinsäure, Linolsäure, Linolensäure, Elaeostearinsäure, Arachinsäure, Gadoleinsäure, Behensäure und Erucasäure sowie deren technische Mischungen. Beispiele für die Fettalkoholanteile in den Esterölen sind Isopropylalkohol, Capronalkohol, Caprylalkohol, 2-Ethylhexylalkohol, Caprinalkohol, Laurylalkohol, Isotridecylalkohol, Myristylalkohol, Cetylalkohol, Palmoleylalkohol, Stearylalkohol, Isostearylalkohol, Oleylalkohol, Elaidylalkohol, Petroselinylalkohol, Linolylalkohol, Linolenylalkohol, Elaeostearylalkohol, Arachylalkohol, Gadoleylalkohol, Behenylalkohol, Erucylalkohol und Brassidylalkohol sowie deren technische Mischungen. Besonders bevorzugt sind Isopropylmyristat (Rilanit^®IPM), Isononansäure-C16-18-alkylester (Cetiol^®SN), 2-Ethylhexylpalmitat (Cegesoft^®24), Stearinsäure-2-ethylhexylester (Cetiol^®868), Cetyloleat, Glycerintricaprylat, Kokosfettalkohol- caprinat/-caprylat (Cetiol^®LC), n-Butylstearat, Oleylerucat (Cetiol^®J 600), Isopropylpalmitat (Rilanit^®IPP), Oleyl Oleate (Cetiol^®), Laurinsäurehexylester (Cetiol^®A), Di-n-butyladipat (Cetiol^®B), Myristylmyristat (Cetiol^®MM), Cetearyl Isononanoate (Cetiol^®SN), Ölsäuredecylester (Cetiol^®V).
• – Dicarbonsäureester wie Di-n-butyladipat, Di-(2-ethylhexyl)-adipat, Di-(2-ethylhexyl)-succinat und Di-isotridecylacelaat sowie Diolester wie Ethylenglykol-dioleat, Ethylenglykol-di-isotridecanoat, Propylenglykol-di(2-ethylhexanoat), Propylenglykol-di-isostearat, Propylenglykol-di-pelargonat, Butandiol-di-isostearat, Neopentylglykoldicaprylat,
• – symmetrische, unsymmetrische oder cyclische Ester der Kohlensäure mit Fettalkoholen,
• – Glycerincarbonat oder Dicaprylylcarbonat (Cetiol^®CC),
• – ethoxylierte oder nicht ethoxylierte Mono,- Di- und Trifettsäureester von gesättigten und/oder ungesättigten linearen und/oder verzweigten Fettsäuren mit Glycerin, wie beispielsweise Monomuls^®90-O18, Monomuls^®90-L12, Cetiol^®HE oder Cutina^®MD.

Other fatty substances are, for example

• - Ester oils. Ester oils are understood as meaning the esters of C ₆ -C ₃₀ -fatty acids with C ₂ -C ₃₀ -fatty alcohols. The monoesters of the fatty acids with alcohols having 2 to 24 carbon atoms are preferred. Examples of fatty acid components used in the esters are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and Erucic acid and its technical mixtures. Examples of the fatty alcohol components in the ester oils are isopropyl alcohol, caproic alcohol, capryl alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, gadoleyl alcohol, Behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures. Particularly preferred are isopropyl myristate (IPM Rilanit ^®), isononanoic acid C16-18 alkyl ester (Cetiol ^® SN), 2-ethylhexyl palmitate (Cegesoft ^® 24), Stearic acid-2-ethylhexyl ester (Cetiol ^® 868), cetyl oleate, glycerol tricaprylate, caprate Kokosfettalkohol- / caprylate (Cetiol ^® LC), n-butyl stearate, oleyl erucate (Cetiol ^® J 600), isopropyl palmitate (IPP Rilanit ^®), Oleyl Oleate (Cetiol ^®), hexyl laurate (Cetiol ^® A), di-n-butyl adipate (Cetiol ^® B), myristyl myristate (Cetiol ^® MM), Cetearyl Isononanoate (Cetiol ^® SN), decyl oleate (Cetiol ^® V).
• Dicarboxylic acid esters such as di-n-butyl adipate, di (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecyl acelate, and diol esters such as ethylene glycol dioleate, ethylene glycol diisotridecanoate, propylene glycol di (2 ethylhexanoate), propylene glycol diisostearate, propylene glycol di-pelargonate, butanediol diisostearate, neopentyl glycol dicaprylate,
• Symmetrical, unsymmetrical or cyclic esters of carbonic acid with fatty alcohols,
• - glycerol carbonate or dicaprylyl ether (Cetiol ^® CC)
• - ethoxylated or non ethoxylated mono, - di- and trifatty acid esters of saturated and / or unsaturated linear and / or branched fatty acids with glycerol such as ^® Monomuls 90-O18, Monomuls 90-L12 ^®, Cetiol ^® HE or Cutina ^® MD.

Suitable antidandruff active ingredients may be selected from Piroctone olamine, climbazole, zinc pyrithione, ketoconazole, salicylic acid, sulfur, selenium sulfide, tar preparations, undecenoic acid derivatives, burdock root extracts, poplar extracts, nettle extracts, walnut shell extracts, birch extracts, willow bark extracts, rosemary extracts and / or arnica extracts. Preferred are climbazole, zinc pyrithione and piroctone olamine.

• – Vitamine, Vitaminderivate und/oder Vitaminvorstufen,
• – Pflanzenextrakte und/oder
• – Feuchthaltemittel.

Other optional components that can be used in the hair cleansing and / or hair conditioning compositions of the present invention include, for example

• - vitamins, vitamin derivatives and / or vitamin precursors,
• - Plant extracts and / or
• - Humectants.

• • Vitamin B₁ (Thiamin)
• • Vitamin B₂ (Riboflavin).
• • Vitamin B₃. Unter dieser Bezeichnung werden häufig die Verbindungen Nicotinsäure und Nicotinsäureamid (Niacinamid) geführt.
• • Vitamin B₅ (Pantothensäure und Panthenol). Im Rahmen dieser Gruppe wird bevorzugt das Panthenol eingesetzt. Einsetzbare Derivate des Panthenols sind insbesondere die Ester und Ether des Panthenols sowie kationisch derivatisierte Panthenole. Einzelne Vertreter sind beispielsweise das Panthenoltriacetat, der Panthenolmonoethylether und dessen Monoacetat sowie kationische Panthenolderivate.
• • Vitamin B₆ (Pyridoxin sowie Pyridoxamin und Pyridoxal). Vitamin C (Ascorbinsäure): die Verwendung in Form des Palmitinsäureesters, der Glucoside oder Phosphate kann bevorzugt sein. Die Verwendung in Kombination mit Tocopherolen kann ebenfalls bevorzugt sein. Vitamin E (Tocopherole, insbesondere α-Tocopherol). Vitamin F: unter dem Begriff ”Vitamin F” werden üblicherweise essentielle Fettsäuren, insbesondere Linolsäure, Linolensäure und Arachidonsäure, verstanden. Vitamin H: Als Vitamin H wird die Verbindung (3aS,4S,6aR)-2-Oxohexahydrothienol[3,4-d]-imidazol-4-valeriansäure bezeichnet, für die sich aber zwischenzeitlich der Trivialname Biotin durchgesetzt hat.

Suitable vitamins are preferably the following vitamins, provitamins and vitamin precursors and their derivatives:
Vitamin A: the group of substances called vitamin A includes retinol (vitamin A1) and 3,4-didehydroretinol (vitamin A ₂ ). The β-carotene is the provitamin of retinol. As vitamin A component, for example, vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as palmitate and acetate into consideration.
Vitamin B: belong to the vitamin B group or to the vitamin B complex among others

• • Vitamin B ₁ (thiamine)
• • Vitamin B ₂ (riboflavin).
• • Vitamin B ₃ . Under this name, the compounds nicotinic acid and nicotinamide (niacinamide) are often performed.
• • Vitamin B ₅ (pantothenic acid and panthenol). Within this group the panthenol is preferred. Useful derivatives of panthenol are, in particular, the esters and ethers of panthenol, as well as cationically derivatized panthenols. Individual representatives are, for example, panthenol triacetate, panthenol monoethyl ether and its monoacetate, as well as cationic panthenol derivatives.
• • Vitamin B ₆ (pyridoxine and pyridoxamine and pyridoxal). Vitamin C (ascorbic acid): use in the form of palmitic acid ester, glucosides or phosphates may be preferred. The use in combination with tocopherols may also be preferred. Vitamin E (tocopherols, especially α-tocopherol). Vitamin F: the term "vitamin F" is usually understood as meaning essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid. Vitamin H: Vitamin H is the compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] -imidazole-4-valeric acid, for which, in the meantime, the trivial name biotin has prevailed.

The hair cleansing and / or hair conditioning compositions according to the invention may preferably contain vitamins, provitamins and vitamin precursors from groups A, B, E and H.

Particularly preferred are nicotinic acid amide, biotin, pantolactone and / or panthenol.

Vitamins, vitamin derivatives and / or vitamin precursors may be present in the hair cleansing and / or hair conditioning agents (based on their total weight) preferably in an amount of 0.001 to 10% by weight, preferably 0.005 to 7.5% by weight and in particular 0.01 be used to 5 wt .-%.

Suitable plant extracts are extracts that can be made from any part of a plant.

Usually these extracts are produced by extraction of the whole plant. However, in individual cases it may also be preferred to prepare the extracts exclusively from flowers and / or leaves of the plant.

Particularly suitable are the extracts of green tea, oak bark, stinging nettle, witch hazel, hops, chamomile, burdock root, horsetail, linden, lychee, almond, aloe vera, spruce needle, horse chestnut, sandalwood, juniper, coconut, mango, apricot, lime , Wheat, Kiwi, Melon, Orange, Grapefruit, Sage, Rosemary, Birch, Mallow, Meadowfoam, Quendel, Yarrow, Thyme, Melissa, Hominy, Coltsfoot, Marshmallow, Ginseng, Ginger root, Echinacea purpurea, Olea europea, Boerhavia diffusa roots, Foeniculum vulgaris and Apim graveolens.

Particularly preferred for use in the hair treatment compositions according to the invention are the extracts of green tea, stinging nettle, witch hazel, chamomile, aloe vera, ginseng, Echinacea purpurea, Olea europea and / or Boerhavia diffusa roots.

As extraction agent for the preparation of said plant extracts water, alcohols and mixtures thereof can be used. Among the alcohols are lower alcohols such as ethanol and isopropanol, but especially polyhydric alcohols such as ethylene glycol and propylene glycol, both as the sole extractant and in admixture with water, are preferred. Plant extracts based on water / propylene glycol in a ratio of 1:10 to 10: 1 have proven to be particularly suitable.

The plant extracts can be used both in pure and in diluted form. If they are used in diluted form, they usually contain about 2-80 wt .-% of active substance and as a solvent used in their extraction agent or extractant mixture.

The plant extracts may in the hair cleansing and / or hair conditioning compositions according to the invention (based on their total weight) preferably in an amount of 0.01 to 10 wt .-%, preferably 0.05 to 7.5 wt .-% and in particular 0.1 be used to 5 wt .-%.

Suitable humectants or penetrants and / or swelling agents which can be added to the hair cleansing and / or hair conditioning agents according to the invention are, for example, urea and urea derivatives, guanidine and its derivatives, arginine and its derivatives, water glass, imidazole and its derivatives, histidine and its derivatives , Benzyl alcohol, glycerol, glycol and glycol ethers, propylene glycol and propylene glycol ethers, for example, propylene glycol monoethyl ether, carbonates, bicarbonates, diols and triols, and especially 1,2-diols and 1,3-diols such as 1,2-propanediol, 1,2-pentanediol , 1,2-hexanediol, 1,2-dodecanediol, 1,3-propanediol, 1,6-hexanediol, 1,5-pentanediol, 1,4-butanediol.

The humectants may in the compositions of the invention - based on the total weight - in amounts of 0.01 to 10 wt .-%, preferably in amounts of 0.05 to 5 wt .-% and in particular in amounts of 0.1 to 3 wt .-% are used.

• – UV-Filter,
• – Verdickungsmittel wie Gelatine oder Pflanzengumme, beispielsweise Agar-Agar, Guar-Gum, Alginate, Xanthan-Gum, Gummi arabicum, Karaya-Gummi, Johannisbrotkernmehl, Leinsamengummen, Dextrane, Cellulose-Derivate, z. B. Methylcellulose, Hydroxyalkylcellulose und Carboxymethylcellulose, Stärke-Fraktionen und Derivate wie Amylose, Amylopektin und Dextrine, Tone und Schichtsilikate wie z. B. Bentonit oder vollsynthetische Hydrokolloide wie z. B. Polyvinylalkohol, die Ca-, Mg- oder Zn-Seifen,
• – Strukturanten wie Maleinsäure und Milchsäure,
• – Dimethylisosorbid,
• – Cyclodextrine,
• – faserstrukturverbessernde Wirkstoffe, insbesondere Mono-, Di- und Oligosaccharide wie beispielsweise Glucose, Galactose, Fructose, Fruchtzucker und Lactose,
• – Farbstoffe zum Anfärben des Mittels,
• – Substanzen zur Einstellung des pH-Wertes, beispielsweise α- und β-Hydroxycarbonsäuren wie Citronensäure, Milchsäure, Apfelsäure, Glycolsäure,
• – Wirkstoffe wie Bisabolol,
• – Komplexbildner wie EDTA, NTA, β-Alanindiessigsäure und Phosphonsäuren,
• – Ceramide. Unter Ceramiden werden N-Acylsphingosin (Fettsäureamide des Sphingosins) oder synthetische Analogen solcher Lipide (sogenannte Pseudo-Ceramide) verstanden,
• – Treibmittel wie Propan-Butan-Gemische, N₂O, Dimethylether, CO₂ und Luft,
• – Antioxidantien,
• – Konsistenzgeber wie Zuckerester, Polyolester oder Polyolalkylether,
• – Konservierungsmittel, wie beispielsweise Natriumbenzoat oder Salicylsäure,
• – Viskositätsregler wie Salze (NaCl).

Further active ingredients, auxiliaries and additives which can be used in the hair-cleansing and / or hair-conditioning compositions according to the invention are, for example:

• - UV filters,
• Thickeners such as gelatin or vegetable gums, for example agar-agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, e.g. As methylcellulose, hydroxyalkylcellulose and carboxymethylcellulose, starch fractions and derivatives such as amylose, amylopectin and dextrins, clays and phyllosilicates such. As bentonite or fully synthetic hydrocolloids such. As polyvinyl alcohol, the Ca, Mg or Zn soaps,
• - structurants such as maleic acid and lactic acid,
• - dimethyl isosorbide,
• - cyclodextrins,
• Fiber-structure-improving active substances, in particular mono-, di- and oligosaccharides such as, for example, glucose, galactose, fructose, fructose and lactose,
• Dyes for staining the agent,
• Substances for adjusting the pH, for example α- and β-hydroxycarboxylic acids such as citric acid, lactic acid, malic acid, glycolic acid,
• - active substances such as bisabolol,
• Complexing agents such as EDTA, NTA, β-alaninediacetic acid and phosphonic acids,
• - Ceramides. Ceramides are understood as meaning N-acylsphingosine (fatty acid amides of sphingosine) or synthetic analogs of such lipids (so-called pseudo-ceramides),
• Propellants such as propane-butane mixtures, N ₂ O, dimethyl ether, CO ₂ and air,
• - antioxidants,
• Bodying agents such as sugar esters, polyol esters or polyol alkyl ethers,
• Preservatives, such as sodium benzoate or salicylic acid,
• - Viscosity regulator such as salts (NaCl).

The hair cleansing and / or hair conditioning agents according to the invention preferably have pH values in the range from 1 to 7, preferably from 2 to 6.5 and in particular from 3 to 6.

The hair cleansing and / or hair conditioning compositions according to the invention have excellent properties when applied to the hair.

In addition to cleaning and / or care, they give the treated hair better visual and tactile properties.

Treated dry hair has an improved hair feel and increased hair shine. They feel soft, supple and elastic.

The combination of active substances according to the invention can be incorporated very well into an aqueous or aqueous-alcoholic base. Stable, rich hair conditioners and / or hair conditioners with excellent foaming properties can be made.

A second object of the invention is the cosmetic use of a hair cleansing and / or hair conditioning agent according to any one of claims 1 to 9 for improving the hair grip and the surface gloss of hair.

Examples:

The following working examples were prepared (the amounts are based on wt .-%, unless otherwise stated): 1) hair shampoos 1 2 3 4 ^Texapon®1 N70 15 15 12 18 Dehyton ^®2 K 10 - - 15 Dehyton ^®3 G - 15 12 - Plantacare® ^®4 818 UP 4 - 2 - Dehyquart ® ⁵ A CA - 0.5 0.1 0.2 D-panthenol - 0.2 0.2 0.1 nicotinamide 0.3 - 0.15 0.2 Cutina ^®6 HR 0.4 0.6 0.5 0.3 ^Cetiol®7 HE 1 0.8 0.4 0.6 Polymer ^JR®8 400 0.3 0.5 - 0.3 Polyquaternium-7 - - - 0.3 Guar hydroxypropyltrimonium chlorides - 0.1 0.2 - Verityl ^®9 AB-1000 1 1.5 3 2 Dow ^Corning®8 200 - 0.1 - 0.1 Aprikosenkernlöl 0.1 - 0.2 - citric acid 0.5 0.6 0.2 0.4 NaCl 1.3 1 0.7 1 Zinc pyrithione - 0.5 0.2 0.3 Preservative, perfume qs qs qs qs water ad 100 ad 100 ad 100 ad 100

• 1 INCI-Bezeichnung: Sodium Laureth Sulfate; AS 68–73%; Cognis,
• 2 INCI-Bezeichnung: Cocamidopropyl Betaine; AS 29–32%; Cognis,
• 3 INCI-Bezeichnung: Disodium Cocoamphodiacetate; AS 30%; Cognis,
• 4 INCI-Bezeichnung: Coco Glucoside; AS 51–53%; Cognis,
• 5 INCI-Bezeichnung: Aqua, Cetrimonium Chloride, AS 24–26%; Cognis,
• 6 INCI-Bezeichnung: Hydrogenated Castor Oil; Cognis
• 7 INCI-Bezeichnung: PEG-7 Glyceryl Cocoate; Cognis
• 8 INCI-Bezeichnung: Polyquaternium-10; Dow
• 9 INCI-Bezeichnung: Dimethicone (30,000 cst); Dow Corning

2) Haarspülung 1 2 3 Lanette^®O 6,25 5,75 7 Varisoft^®11W575 PG 0,75 1 - Cutina^{® 12}AGS 1 - 1,2 Shea Butter 1,5 - 1 Aprikosenkernöl - 1 l - Pantolacton - 0,2 0,2 Quartamin^®13BTC-131 1,5 - 1,2 Dehyquart^®14F75 0,75 - 0,5 Dehyquart^®5A CA - 1 - Cosmedia^®15CTH 0,4 0,5 0,6 Verityl^®9AB-1000 1 1,5 3 Glycerin 0,1 0,3 0,5 Dow Corning^®8200 1 1,2 1 Milchsäure 0,1 0,4 0,15 Zink Pyrithion - - 0,2 Konservierungsmittel, Parfum q. s. q. s. q. s. Wasser ad 100 ad 100 ad 100 In the aforementioned hair shampoos, the following commercial products were used:

• 1 INCI name: Sodium Laureth Sulfate; AS 68-73%; Cognis,
• 2 INCI name: Cocamidopropyl Betaine; AS 29-32%; Cognis,
• 3 INCI name: Disodium Cocoamphodiacetate; AS 30%; Cognis,
• 4 INCI name: Coco Glucoside; AS 51-53%; Cognis,
• 5 INCI name: Aqua, Cetrimonium Chloride, AS 24-26%; Cognis,
• 6 INCI name: Hydrogenated Castor Oil; Cognis
• 7 INCI name: PEG-7 glyceryl cocoate; Cognis
• 8 INCI name: Polyquaternium-10; Dow
• 9 INCI name: dimethicone (30,000 cst); Dow Corning

2) hair conditioner 1 2 3 Lanette ^® O 6.25 5.75 7 Varisoft ^®11 W575 PG 0.75 1 - Cutina ^{® 12} AGS 1 - 1.2 Shea butter 1.5 - 1 Apricot kernel oil - 1 l - pantolactone - 0.2 0.2 Quart amine ^®13 BTC-131 1.5 - 1.2 ^{Dehyquart®14} F75 0.75 - 0.5 Dehyquart ® ⁵ A CA - 1 - ^Cosmedia®15 CTH 0.4 0.5 0.6 Verityl ^®9 AB-1000 1 1.5 3 glycerin 0.1 0.3 0.5 Dow ^Corning®8 200 1 1.2 1 lactic acid 0.1 0.4 0.15 Zinc pyrithione - - 0.2 Preservative, perfume qs qs qs water ad 100 ad 100 ad 100

• 10 INCI-Bezeichnung: Cetearyl Alcohol; Cognis,
• 11 INCI-Bezeichnung: Quaternium-87, Propylene Glycol; Evonik,
• 12 INCI-Bezeichnung: Glycol Distearate; Cognis,
• 13 INCI-Bezeichnung: Behenoyl PG-Trimonium Chloride; AS 50%; Kao,
• 14 INCI-Bezeichnung: Distearoylethyl Hydroxyethylmonium Methosulfate, Cetearyl Alcohol, AS 65–72%; Cognis,
• 15 INCI-Bezeichnung: Polyquaternium-37, Propylene Glycol Dicaprylate/Dicaprate, PPG-1Trideceth-6, Cognis

The following commercial products were used in the aforementioned hair rinses:

• 10 INCI name: Cetearyl Alcohol; Cognis,
• 11 INCI name: Quaternium-87, propylene glycol; Evonik,
• 12 INCI name: Glycol Distearate; Cognis,
• 13 INCI name: Behenoyl PG-Trimonium Chloride; AS 50%; Kao,
• 14 INCI name: distearoylethyl hydroxyethylmonium methosulfate, cetearyl alcohol, AS 65-72%; Cognis,
• 15 INCI name: Polyquaternium-37, Propylene Glycol Dicaprylate / Dicaprate, PPG-1 Trideceth-6, Cognis

QUOTES INCLUDE IN THE DESCRIPTION

This list of the documents listed by the applicant has been generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.

Cited patent literature

• WO 1997/038667 [0008]
• DE 19757508 [0010, 0011]

Claims (10)

Hair cleansing and / or hair conditioning compositions containing in a cosmetic carrier a) from 0.1 to 60% by weight of at least one surfactant selected from the group of anionic, amphoteric / zwitterionic, nonionic and / or cationic surfactants, and b) 0, From 01 to 20% by weight of at least one compound of the formula (I),

in which - Y is a cycloalkylene group having 5 to 7 C atoms and - the radicals R ¹ , R ² independently of one another for a grouping

in which - R ^{3 is} a hydrogen atom, a methyl or an ethyl group, - p is an integer from 0 to 5, - R ^{4 is} a hydrogen atom or a methyl group, and - q is an integer from 0 to 5, wherein all amounts are based on the total weight of the hair cleansing and / or hair conditioning agent. Hair cleansing and / or hair conditioning composition according to claim 1, characterized in that in the formula (I) Y is a 1,2-cyclopentylene, a 1,3-cyclopentylene, a 1,2-cyclohexylene, a 1,3 -Cyclohexylen- or a 1,4-cyclohexylene group and the radicals R ¹ and R ² for identical groups

in which R ³ and R ^{4 are} hydrogen or a methyl group, p is an integer of 1-3 and q is an integer of 0-3. Hair cleansing and / or hair conditioning composition according to one of claims 1 or 2, characterized in that in the formula (I) - Y is a 1,4-cyclohexylene group and - the radicals R ¹ and R ^{2 are} identical for groupings

in which R ^{3 is} hydrogen and p is the numbers 1 to 3. Hair-cleansing and / or hair-conditioning composition according to one of Claims 1 to 3, characterized in that it contains, as compound of the formula (I), 1,4-cyclohexanedimethanol (Y = 1,4-cyclohexylene group; R ¹ , R ² = - (CHR ³ ) _p -OH; R ³ = H and p = 1). Hair cleansing and / or hair conditioning agent according to any one of claims 1 to 4, characterized in that it - based on its total weight - a) (i) 0.1 to 10 wt .-%, preferably 0.2 to 7.5 wt. -% and in particular 0.3 to 5 wt .-% of at least one cationic surfactant from the group of quaternary ammonium compounds, the esterquats and amidoamines and / or (ii) 0.1 to 20 wt .-%, preferably 0.5 to 17.5 wt .-% and in particular 1 to 15 wt .-% of at least one anionic surfactant from the group of alkyl (ether) sulfates, the ether carboxylic acids, the Sulfobernsteinsäuremono- and -dialkylester, the Olefinsulfonate and the acylsarcosides and / or (Iii) 0.1 to 15 wt .-%, preferably 0.5 to 12.5 wt .-% and in particular 1 to 10 wt .-% of at least one amphoteric / zwitterionic surfactant from the group of alkyl betaines, Alkylamidoalkylbetaine and Alkylampho (di) acetate and / or (iv) 0.1 to 15 wt .-%, preferably 0.5 to 12.5 wt .-% and in particular 1 to 10 wt .-% of at least one nonionic surfactant from the group of Addition products of ethylene oxide and / or propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 carbon atoms and to alkylphenols having 8 to 15 carbon atoms in the alkyl group, the fatty acid mono- and diesters of Addition products of ethylene oxide with glycerol, the adducts of ethylene oxide with castor oil and hydrogenated castor oil, the amine oxides, the adducts of ethylene oxide with fatty acid alkanolamides and fatty amines, and the alkyl polyglucosides, and b) 0.05 to 15 wt .-%, preferably 0.1 to 12.5 wt .-% and in particular 0.5 to 10 wt .-% 1,4-cycloh contains exandimethanol. Hair cleansing and / or hair conditioning composition according to claim 5, characterized in that that there is at least one surfactant from the groups - (ii) and (iii) or - (ii) and (iii) and (i) or - (ii) and (iii) and (iv) or - (i) contains. Hair cleansing and / or hair conditioning agent according to one of claims 1 to 6, characterized in that it - based on its total weight - additionally 0.01 to 10 wt .-%, preferably 0.05 to 7.5 wt .-% and in particular 0.1 to 5 wt .-% of at least one cationic polymer. Hair cleansing and / or hair conditioning agent according to one of claims 1 to 7, characterized in that it additionally contains 0.025 to 7.5 wt .-%, more preferably 0.05 to 5 wt .-% and in particular 0.075 to 3 wt .-% contains at least one antidandruff active ingredient. Hair cleansing and / or hair conditioner according to one of claims 1 to 8, characterized in that it - based on its total weight - additionally 0.01 to 20 wt .-%, preferably 0.05 to 15 wt .-% and in particular 0, 1 to 10 wt .-% of at least one oil, wax and / or fat component. Cosmetic use of a hair cleansing and / or hair conditioning composition according to any one of claims 1 to 9 for improving the hair grip and the surface gloss of hair.