DE102006023263A1 - Synergistic drug combinations - Google Patents

Abstract

The novel active compound combinations comprising compounds of the formula (I) where R represents methyl or cyclopropyl, and at least one compound selected from the active compound groups (1) to (24) listed in the description have very good insecticidal and fungicidal properties.

Description

The The present invention relates to novel drug combinations which a known compound of formula (I) on the one hand and at least on the other hand contain a known fungicidal active agent and very good to combat of unwanted animal pests like insects as well as unwanted phytopathogenic fungi are suitable.

It is already known that compounds of the formula (I) have insecticidal activity (cf. EP 0 539 588 A1 ).

Further It is already known that numerous triazole derivatives, aniline derivatives, Dicarboximides and other heterocycles used to combat fungi can be (See EP-A 0 040 345, DE-A 22 01 063, DE-A 23 24 010, pesticides Manual, 9th. Edition (1991), pages 249 and 827, EP-A 0 382 375, EP-A 0 515 901, DE-B2 2732257). Also, the effect of these substances is but not always sufficient at low application rates.

Further It is already known that 1- (3,5-dimethyl-isoxazole-4-sulfonyl) -2-chloro-6,6-difluoro [1,3] -dioxolo- [4,5f] -benzimidazole has fungicidal properties (see WO 97/06171).

Finally is also known that substituted halopyrimidines have fungicidal properties have (see DE-A1-196 46 407, EP-B-712 396).

wobei
R für Methyl oder Cyclopropyl steht,
und mindestens einen Wirkstoff, der aus den folgenden Gruppen (2) bis (24) ausgewählt ist: Gruppe (2) Strobilurine der allgemeinen Formel (II)

in welcher
A¹ für eine der Gruppen

steht,
A² für NH oder O steht,
A³ für N oder CH steht,
L für eine der Gruppen

steht, wobei die Bindung, die mit einem Stern (*) markiert ist an den Phenylring gebunden ist,
R¹¹ für jeweils gegebenenfalls einfach oder zweifach, gleich oder verschieden durch Chlor, Cyano, Methyl oder Trifluormethyl substituiertes Phenyl, Phenoxy oder Pyridinyl, oder für 1-(4-Chlorphenyl)-pyrazol-3-yl oder für 1,2-Propandion-bis(O-methyloxim)-1-yl steht,
R¹² für Wasserstoff oder Fluor steht; Gruppe (3) Triazole der allgemeinen Formel (III)

in welcher
Q für Wasserstoff oder SH steht,
m für 0 oder 1 steht,
R¹³ für Wasserstoff, Fluor, Chlor, Phenyl oder 4-Chlor-phenoxy steht,
R¹⁴ für Wasserstoff oder Chlor steht,
A⁴ für eine direkte Bindung, -CH₂-, -(CH₂)₂-, -O-, für *-CH₂-CHR¹⁷- oder *-CH=CR¹⁷- steht, wobei die mit * markierte Bindung mit dem Phenylring verknüpft ist, und
R¹⁵ und R¹⁷ dann zusammen für -CH₂-CH₂-CH[CH(CH₃)₂]- oder -CH₂-CH₂-C(CH₃)₂-stehen,
A⁵ für C oder Si (Silizium) steht,
A⁴ außerdem für -N(R¹⁷)- steht und A⁵ außerdem zusammen mit R¹⁵ und R¹⁶ für die Gruppe C=N-R¹⁸ steht, wobei R¹⁷ und R¹⁸ dann zusammen für die Gruppe

stehen, wobei die mit * markierte Bindung mit R¹⁷ verbunden ist,
R¹⁵ für Wasserstoff, Hydroxy oder Cyano steht,
R¹⁶ für 1-Cyclopropylethyl, 1-Chlorcyclopropyl, C₁-C₄-Alkyl, C₁-C₆-Hydroxyalkyl, C₁-C₄-Alkylcarbonyl, C₁-C₂-Halogenalkoxy-C₁-C₂-alkyl, Trimethylsilyl-C₁-C₂-alkyl, Monofluorphenyl, oder Phenyl steht,
R¹⁵ und R¹⁶ außerdem zusammen für -O-CH₂-CH(R¹⁸)-O-, -O-CH₂-CH(R¹⁸)-CH₂-, oder -O-CH-(2-Chlorphenyl)- stehen,
R¹⁸ für Wasserstoff, C₁-C₄-Alkyl oder Brom steht; Gruppe (4) Sulfenamide der allgemeinen Formel (IV)

in welcher R¹⁹ für Wasserstoff oder Methyl steht;New active compound combinations with very good insecticides and fungicidal properties have now been found, containing at least one compound of the formula (I) (group 1)

in which
R is methyl or cyclopropyl,
and at least one active ingredient selected from the following groups (2) to (24): group (2) strobilurins of the general formula (II)

in which
A ¹ for one of the groups

stands,
A ^{2 is} NH or O,
A ^{3 is} N or CH,
L for one of the groups

wherein the bond which is marked with an asterisk (*) is bound to the phenyl ring,
R ^{11 is} in each case optionally mono- or disubstituted by identical or different chlorine, cyano, methyl or trifluoromethyl-substituted phenyl, phenoxy or pyridinyl, or for 1- (4-chlorophenyl) -pyrazol-3-yl or for 1,2-propanedione bis (O-methyloxime) -1-yl,
R ^{12 is} hydrogen or fluorine; Group (3) triazoles of the general formula (III)

in which
Q is hydrogen or SH,
m is 0 or 1,
R ^{13 is} hydrogen, fluorine, chlorine, phenyl or 4-chlorophenoxy,
R ^{14 is} hydrogen or chlorine,
A ^{4 is} a direct bond, -CH ₂ -, - (CH ₂ ) ₂ -, -O-, for * -CH ₂ -CHR ¹⁷ - or * -CH = CR ¹⁷ -, wherein the bond marked with * the phenyl ring is linked, and
R ¹⁵ and R ¹⁷ then together represent -CH ₂ -CH ₂ -CH [CH (CH ₃ ) ₂ ] - or -CH ₂ -CH ₂ -C (CH ₃ ) ₂ -,
A ^{5 is} C or Si (silicon),
A ⁴ also represents -N (R ¹⁷ ) - and A ⁵ together with R ¹⁵ and R ^{16 also represents} the group C = NR ¹⁸ , where R ¹⁷ and R ¹⁸ then together represent the group

with the bond marked with * attached to R ¹⁷ ,
R ^{15 is} hydrogen, hydroxy or cyano,
R ^{16 is} 1-cyclopropylethyl, 1-chlorocyclopropyl, C ₁ -C ₄ -alkyl, C ₁ -C ₆ -hydroxyalkyl, C ₁ -C ₄ -alkylcarbonyl, C ₁ -C ₂ -haloalkoxy-C ₁ -C ₂ -alkyl , Trimethylsilyl-C ₁ -C ₂ -alkyl, monofluorophenyl, or phenyl,
R ¹⁵ and R ¹⁶ also together represent -O-CH ₂ -CH (R ¹⁸ ) -O-, -O-CH ₂ -CH (R ¹⁸ ) -CH ₂ -, or -O-CH- (2-chlorophenyl) - stand,
R ^{18 is} hydrogen, C ₁ -C ₄ alkyl or bromine; Group (4) sulfenamides of the general formula (IV)

in which R ^{19 is} hydrogen or methyl;

Group (5) Valinamide selected out

• (5-1) Iprovalicarb
• (5-2) N ¹ - [2- (4 - {[3- (4-chlorophenyl) -2-propynyl] oxy} -3-methoxyphenyl) ethyl] -N ² - (methylsulfonyl) -D-valinamide
• (5-3) Benthiavalicarb

• Group (6) Carboxamides of General Formula (V)
  
  in which X is 2-chloro-3-pyridinyl, 1-methylpyrazol-4-yl which is substituted in the 3-position by methyl or trifluoromethyl and in the 5-position by hydrogen or chlorine, for 4-ethyl-2-ethylamino 1,3-thiazol-5-yl, for 1-methyl-cyclohexyl, for 2,2-dichloro-1-ethyl-3-methyl-cyclopropyl, for 2-fluoro-2-propyl, 3,4-dichloro isothiazol-5-yl, 5,6-dihydro-2-methyl-1,4-oxathin-3-yl, 4-methyl-1,2,3-thiadiazol-5-yl, 4,5-dimethyl-2 trimethylsilylthiophen-3-yl, 1-methylpyrrol-3-yl which is substituted in the 4-position by methyl or trifluoromethyl and in the 5-position by hydrogen or chlorine, or represents phenyl which is monosubstituted to trisubstituted, identical or different is substituted by chlorine, methyl or trifluoromethyl, Y is a direct bond, optionally substituted by chlorine, cyano or oxo substituted C ₁ -C ₆ alkanediyl (alkylene), C ₂ -C ₆ alkylenediyl (alkenylene) or thiophenediyl , Z is hydrogen, C ₁ -C ₆ -alkyl or the group
  
  A ^{6 is} CH or N, R ^{20 is} hydrogen, chlorine, cyano, C ₁ -C ₆ alkyl, by optionally mono- or disubstituted by identical or different chlorine or di (C ₁ -C ₃ alkyl) aminocarbonyl-substituted phenyl R ^{21 is} hydrogen, chlorine or isopropoxy, R ^{22 is} hydrogen, chlorine, hydroxyl, methyl, trifluoromethyl or di (C ₁ -C ₃ -alkyl) aminocarbonyl, R ²⁰ and R ²¹ also together are * -CH ( CH ₃ ) -CH ₂ -C (CH ₃ ) ₂ - or * -CH (CH ₃ ) -OC (CH ₃ ) ₂ -, where the bond marked with * is linked to R ²⁰ ;

Group (7) dithiocarbamates selected out

• (7-1) Mancozeb
• (7-2) Maneb
• (7-3) Metiram
• (7-4) Propylene
• (7-5) Thiram
• (7-6) Zineb
• (7-7) Ziram

• Group (8) acylalanines of the general formula (VI)
  
  in which * denotes a carbon atom in the R or S configuration, preferably in the S configuration, R ^{23 represents} benzyl, furyl or methoxymethyl;

• Group (9): anilino-pyrimidines of the general formula (VII)
  
  in which R ^{24 is} methyl, cyclopropyl or 1-propynyl;

• Group (10): Benzimidazoles of the general formula (VIII)
  
  in which R ²⁵ and R ^{26 are} each hydrogen or together are -O-CF ₂ -O-, R ^{27 is} hydrogen, C ₁ -C ₄ -alkylaminocarbonyl or 3,5-dimethylisoxazol-4-ylsulfonyl, R ²⁸ is chloro, methoxycarbonylamino, chlorophenyl, furyl or thiazolyl;

• Group (11): carbamates of the general formula (IX)
  
  in which R ^{29 is} n- or isopropyl, R ^{30 is} di (C ₁ -C ₂ -alkyl) aminoC ₂ -C ₄ -alkyl or diethoxyphenyl, including salts of these compounds;

Group (12): dicarboximides selected out

• (12-1) Captafol
• (12-2) Captan
• (12-3) Folpet
• (12-4) Iprodione
• (12-5) procymidones
• (12-6) Vinclozoline

Group (13): guanidines selected out

• (13-1) Dodine
• (13-2) Guazatine
• (13-3) iminoctadine triacetate
• (13-4) iminoctadine tris (albesilate)

Group (14): imidazoles selected out

• (14-1) Cyazofamide
• (14-2) prochloraz
• (14-3) triazoxide
• (14-4) Pefurazoate

• Group (15): morpholines of the general formula (X)
  
  in which R ³¹ and R ^32, independently of one another, are hydrogen or methyl, R ^{33 is} C ₁ -C ₁₄ -alkyl (preferably C ₁₂ -C ₁₄ -alkyl), C ₅ -C ₁₂ -cycloalkyl (preferably C ₁₀ -C ₁₂₎ Cycloalkyl), phenyl-C ₁ -C ₄ -alkyl, which may be substituted in the phenyl moiety by halogen or C ₁ -C ₄ -alkyl, or by acrylyl which is substituted by chlorophenyl and dimethoxyphenyl;

• Group (16): Pyrroles of General Formula (XI)
  
  in which R ^{34 is} chlorine or cyano, R ^{35 is} chlorine or nitro, R ^{36 is} chlorine, R ³⁵ and R ³⁶ also together are -O-CF ₂ -O- stand;

Group (17): (thio) phosphonates selected out

• (17-1) fosetyl-Al,
• (17-2) phosphonic acid,
• (17-3) tolclophos-methyl;

• Group (18): phenylethanamides of the general formula (XII)
  
  wherein R ^{37 is} phenyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl or indanyl which is unsubstituted or substituted by fluorine, chlorine, bromine, methyl or ethyl;

Group (19): Fungicides selected out

• (19-1) acibenzolar S-methyl
• (19-2) chlorothalonil
• (19-3) cymoxanil
• (19-4) Edifenphos
• (19-5) Famoxadone
• (19-6) fluazinam
• (19-7) copper oxychloride
• (19-8) copper hydroxide
• (19-9) oxadixyl
• (19-10) spiroxamine
• (19-11) Dithianon
• (19-12) Metrafenone
• (19-14) 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) on
• (19-15) Sample azoles
• (19-16) isoprothiolanes
• (19-17) Kasugamycin
• (19-18) phthalides
• (19-19) Ferimzone
• (19-20) tricyclazole
• (19-21) Cyprosulfamide
• (19-22) Mandipropamide
• (19-23) Quinoxyfen (known from EP-A 326 330) of the formula
  
• (19-24) proquinazide (known from WO 94/26722) of the formula
  

Group (20): (thio) urea derivatives selected out

• (20-1) Pencycuron
• (20-2) thiophanate-methyl
• (20-3) thiophanate ethyl

• Group (21): amides of the general formula (XIII)
  
  in which A ^{7 is} a direct bond or -O-, A ^{8 is} -C (= O) NH- or -NHC (= O) -, R ^{38 is} hydrogen or C ₁ -C ₄ alkyl, R ^{39 is} C ₁ -C ₆ alkyl;

• Group (22): triazolopyrimidines of the general formula (XIV)
  
  in which R ^{40 is} C ₁ -C ₆ -alkyl or C ₂ -C ₆ -alkenyl, R ^{41 is} C ₁ -C ₆ -alkyl, R ⁴⁰ and R ⁴¹ also together are C ₄ -C ₅ -alkanediyl ( Alkylene), which is simply or twice by C ₁ -C ₆ -alkyl substituted, R ^{42 is} bromine or chlorine, R ⁴³ and R ^{41 are} independently hydrogen, fluorine, chlorine or methyl, R ⁴⁰ and R ^{46 are} independently hydrogen or fluorine, R ⁴⁵ is hydrogen, fluorine or methyl,

• Group (23): iodochromones of the general formula (XV)
  
  in which R ^{48 is} C ₁ -C ₆ -alkyl, R ^{49 is} C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl or C ₂ -C ₆ -alkynyl;

• Group (24): biphenylcarboxamides of the general formula (XVI)
  
  in which R ^{50 is} hydrogen or fluorine, R ^{51 is} fluorine, chlorine, bromine, methyl, trifluoromethyl, trifluoromethoxy, -CH = N-OMe or -C (Me) = N-OMe, R ^{52 is} hydrogen, fluorine, Chlorine, bromine, methyl or trifluoromethyl, Het is one of the following radicals Het1 to Het7:
  
  R ^{53 is} iodine, methyl, difluoromethyl or trifluoromethyl, R ^{54 is} hydrogen, fluorine, chlorine or methyl, R ^{55 is} methyl, difluoromethyl or trifluoromethyl, R ^{56 is} chlorine, bromine, iodine, methyl, difluoromethyl or trifluoromethyl, R ^{57 is} methyl or trifluoromethyl.

Surprisingly is the fungicidal action of the active compound combinations according to the invention significantly higher as the sum of the effects of each agent. It is so an unpredictable, true synergistic effect before and not just an effect supplement.

Surprisingly is the insecticidal activity of the active compound combinations according to the invention also significantly higher as the sum of the effects of each agent. It is so an unpredictable, true synergistic effect before and not just an effect supplement.

(Ia): 4-[[(6-Chlorpyridin-3-yl)methyl](methylamino)]furan-2-(5H)-on

(Ib): 4-[[(6-Chlorpyridin-3-yl)methyl](cyclopropylamino)]furan-2-(5H)-on The formula (I) comprises the following preferred mixing partners:

(Ia): 4 - [[(6-Chloropyridin-3-yl) methyl] (methylamino)] furan-2 (5H) -one

(Ib): 4 - [[(6-Chloropyridin-3-yl) methyl] (cyclopropylamino)] furan-2- (5H) -one

highlighted are active compound combinations according to the invention, which in addition to the compound of formula (Ia) one or more, preferably one containing active ingredient of groups (2) to (24).

highlighted are active compound combinations according to the invention, which in addition to the compound of formula (Ib) one or more, preferably one containing active ingredient of groups (2) to (24).

The Formula (II) includes the following preferred mixing partners of the group (2):

(2-1) Azoxystrobin (known from EP-A 0 382 375) of the formula

(2-2) Fluoxastrobin (known from DE-A 196 02 095) of the formula

(2-3) (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy} phenyl) -2- (methoxyimino) -N-methylethanamide (known from DE-A 196 46 407, EP-B 0 712 396) of the formula

(2-4) Trifloxystrobin (known from EP-A 0 460 575) of the formula

(2-5) (2E) -2- (methoxyimino) -N-methyl-2- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) ethanamide (known from EP-A 0 569 384) of the formula

(2-6) (2E) -2- (methoxyimino) -N-methyl-2- {2 - [(E) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide (known from EP-A 0 596 254) of the formula

(2-7) Orysastrobin (known from DE-A 195 39 324) of the formula

(2-8) 5-Methoxy-2-methyl-4- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4 dihydro-3H-1,2,4-triazol-3-one (known from WO 98/23155) of the formula

(2-9) Kresoxim-methyl (known from EP-A 0 253 213) of the formula

(2-10) Dimoxystrobin (known from EP-A 0 398 692) of the formula

(2-11) Picoxystrobin (known from EP-A 0 278 595) of the formula

(2-12) Pyraclostrobin (known from DE-A 44 23 612) of the formula

(2-13) Metominostrobin (known from EP-A 0 398 692) of the formula

The Formula (III) includes the following preferred mixing partners of the group (3):

(3-1) Azaconazole (known from DE-A 25 51 560) of the formula

(3-2) Etaconazole (known from DE-A 25 51 560) of the formula

(3-3) Propiconazole (known from DE-A 25 51 560) of the formula

(3-4) Difenoconazole (known from EP-A 0 112 284) of the formula

(3-5) Bromuconazoles (known from EP-A 0 258 161) of the formula

(3-6) Cyproconazole (known from DE-A 34 06 993) of the formula

(3-7) Hexaconazole (known from DE-A 30 42 303) of the formula

(3-8) Penconazole (known from DE-A 27 35 872) of the formula

(3-9) Myclobutanil (known from EP-A 0 145 294) of the formula

(3-10) Tetraconazoles (known from EP-A 0 234 242) of the formula

(3-11) Flutriafol (known from EP-A 0 015 756) of the formula

(3-12) Epoxiconazoles (known from EP-A 0 196 038) of the formula

(3-13) Flusilazoles (known from EP-A 0 068 813) of the formula

(3-14) Simeconazole (known from EP-A 0 537 957) of the formula

(3-15) Prothioconazole (known from WO 96/16048) of the formula

(3-16) Fenbuconazole (known from DE-A 37 21 786) of the formula

(3-17) Tebuconazole (known from EP-A 0 040 345) of the formula

(3-18) Ipconazole (known from EP-A 0 329 397) of the formula

(3-19) Metconazole (known from EP-A 0 329 397) of the formula

(3-20) Triticonazole (known from EP-A 0 378 953) of the formula

(3-21) Bitertanol (known from DE-A 23 24 010) of the formula

(3-22) Triadimenol (known from DE-A 23 24 010) of the formula

(3-23) Triadimefon (known from DE-A 22 01 063) of the formula

(3-24) Fluquinconazole (known from EP-A 0 183 458) of the formula

(3-25) Quinconazole (known from EP-A 0 183 458) of the formula

The Formula (IV) includes the following preferred mixing partners of the group (4):

(4-1) Dichlofluanid (known from DE-A 11 93 498) of the formula

(4-2) Tolylfluanid (known from DE-A 11 93 498) of the formula

preferred Mixture partners of the group (5) are

(5-1) Iprovalicarb (known from DE-A 40 26 966) of the formula

(5-3) Benthiavalicarb (known from WO 96/04252) of the formula

The Formula (V) includes the following preferred mixing partners of the group (6):

(6-1) 2-chloro-N- (1,1,3-trimethyl-indan-4-yl) nicotinamide (known from EP-A 0 256 503) of the formula

(6-2) boscalid (known from DE-A 195 31 813) of the formula

(6-3) Furametpyr (known from EP-A 0 315 502) of the formula

(6-4) 1-Methyl-3-trifluoromethyl-1H-pyrazole-4-carboxylic acid (3-p-tolyl-thiophen-2-yl) -amide (known from EP-A 0 737 682) of the formula

(6-5) Ethaboxam (known from EP-A 0 639 574) of the formula

(6-6) Fenhexamide (known from EP-A 0 339 418) of the formula

(6-7) Carpropamide (known from EP-A 0 341 475) of the formula

(6-8) 2-Chloro-4- (2-fluoro-2-methylpropionylamino) -N, N-dimethylbenzamide (known from EP-A 0 600 629) of the formula

(6-9) Fluopicolide (known from WO 99/42447) of the formula

(6-10) Zoxamide (known from EP-A 0 604 019) of the formula

(6-12) Carboxin (known from US 3,249,499 ) of the formula

(6-13) Tiadinil (known from US 6,616,054 ) of the formula

(6-14) Penthiopyrad (known from EP-A 0 737 682) of the formula

(6-15) Silthiofam (known from WO 96/18631) of the formula

(6-16) N- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide (known from WO 02/38542) of the formula

(6-17) Flutolanil (known from DE-A 27 31 522) of the formula

(6-18) N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (known from EP-A 1 414 803) of the formula

(6-20) N- [2- (1,3-dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide (known from EP-A 1 519 913) of the formula

(6-21) N- [2- (1,3-dimethylbutyl) phenyl] -2-iodobenzamide (known from EP-A 1 519 913) of the formula

(6-22) N- (4'-chloro-3'-fluorobiphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide (known from EP-A 1 404 407) of the formula

(6-23) N- [5- (4-chlorophenyl) pyrimidin-4-yl] -2-iodo-N- (2-iodobenzoyl) benzamide of the formula

(6-24) N- (3 ', 4'-dichlorobiphenyl-2-yl) -2-methyl-4- (trifluoromethyl) -1,3-thiazole-5-carboxamide (known from EP-A 1 474 406) the formula

Preferred mixing partners of group (7) are (7-1) Mancozeb (known from DE-A 12 34 704) with the IUPAC name Manganese ethylenebis (dithiocarbamate) (polymeric) complex with zinc salt (7-2) Maneb (known from US 2,504,404 ) of the formula

(7-3) Metiram (known from DE-A 10 76 434) having the IUPAC name Zinc ammoniate ethylenebis (dithiocarbamate) - poly (ethylenethiuram disulfide) (7-4) Propineb (known from GB 935,981 ) of the formula

(7-5) Thiram (known from US 1,972,961 ) of the formula

(7-6) Zineb (known from DE-A 10 81 446) of the formula

(7-7) Ziram (known from US 2,588,428 ) of the formula

The Formula (VI) includes the following preferred mixing partners of the group (8th):

(8-1) Benalaxyl (known from DE-A 29 03 612) of the formula

(8-2) Furalaxyl (known from DE-A 25 13 732) of the formula

(8-3) metalaxyl (known from DE-A 25 15 091) of the formula

(8-4) metalaxyl-M (known from WO 96/01559) of the formula

(8-5) Benalaxyl-M of the formula

The Formula (VII) includes the following preferred mixing partners of the group (9):

(9-1) Cyprodinil (known from EP-A 0 310 550) of the formula

(9-2) mepanipyrim (known from EP-A 0 270 111) of the formula

(9-3) pyrimethanil (known from DD 151 404 ) of the formula

The Formula (VIII) includes the following preferred mixing partners of the group (10):

(10-1) 6-Chloro-5 - [(3,5-dimethylisoxazol-4-yl) sulfonyl] -2,2-difluoro-5H- [1,3] dioxolo [4,5-f] benzimidazole (known from WO 97/06171) of the formula

(10-2) Benomyl (known from US 3,631,176 ) of the formula

(10-3) Carbendazim (known from US 3,010,968 ) of the formula

(10-4) Chlorfenazoles of the formula

(10-5) Fuberidazole (known from DE-A 12 09 799) of the formula

(10-6) Thiabendazole (known from US 3,206,468 ) of the formula

The Formula (IX) includes the following preferred mixing partners of the group (11):

(11-1) Diethofencarb (known from EP-A 0 078 663) of the formula

(11-2) Propamocarb (known from US 3,513,241 ) of the formula

(11-3) Propamocarb hydrochloride (known from US 3,513,241 ) of the formula

(11-4) Propamocarb-Fosetyl of the formula

preferred Mixing partners of the group (12)

(12-1) Captafol (known from US 3,178,447 ) of the formula

(12-2) Captan (known from US 2,553,770 ) of the formula

(12-3) Folpet (known from US 2,553,770 ) of the formula

(12-4) Iprodione (known from DE-A 21 49 923) of the formula

(12-5) procymidones (known from DE-A 20 12 656) of the formula

(12-6) Vinclozoline (known from DE-A 22 07 576) of the formula

Preferred mixing partners of group (13) are (13-1) dodins (known from GB 11 03 989 ) of the formula

(13-2) Guazatine (known from GB 11 14 155 ) (13-3) iminoctadine triacetate (known from EP-A 0 155 509) of the formula

preferred Mixing partners of the group (14)

(14-1) Cyazofamide (known from EP-A 0 298 196) of the formula

(14-2) Prochloraz (known from DE-A 24 29 523) of the formula

(14-3) triazoxides (known from DE-A 28 02 488) of the formula

(14-4) Pefurazoate (known from EP-A 0 248 086) of the formula

The Formula (X) includes the following preferred mixing partners of the group (15):

(15-1) Aldimorph (known from DD 140 041 ) of the formula

(15-2) Tridemorph (known from GB 988 630 ) of the formula

(15-3) Dodemorph (known from DE-A 25 432 79) of the formula

(15-4) Fenpropimorph (known from DE-A 26 56 747) of the formula

(15-5) Dimethomorph (known from EP-A 0 219 756) of the formula

The Formula (XI) includes the following preferred mixing partners of the group (16):

(16-1) Fenpiclonil (known from EP-A 0 236 272) of the formula

(16-2) Fludioxonil (known from EP-A 0 206 999) of the formula

(16-3) pyrroline nitrines (known from JP 65-25876) of the formula

preferred Mixture partners of the group (17) are

(17-1) Fosetyl-Al (known from DE-A 24 56 627) of the formula

(17-2) Phosphonic acid of the formula

(17-3) Tolclofos-methyl (known from DE-A 25 01 040) of the formula

The Formula (XII) includes the following preferred mixing partners of the group (18), which are known from WO 96/23793 and each as E or Z-isomers may be present. Compounds of formula (XII) can therefore as a mixture of different isomers or in the form of a single isomers. Preference is given to compounds of the formula (XII) in the form of its E isomer:

(18-1) the compound 2- (2,3-dihydro-1H-inden-5-yl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula

(18-2) the compound N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) -2- (5,6,7,8-tetrahydronaphthalen-2-yl) acetamide of the formula

(18-3) the compound 2- (4-chlorophenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula

(18-4) the compound 2- (4-bromophenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula

(18-5) the compound 2- (4-methylphenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula

(18-6) the compound 2- (4-ethylphenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula

(19-2) Chlorothalonil (bekannt aus US 3,290,353 ) der Formel

(19-3) Cymoxanil (bekannt aus DE-A 23 12 956) der Formel

(19-4) Edifenphos (bekannt aus DE-A 14 93 736) der Formel

(19-5) Famoxadone (bekannt aus EP-A 0 393 911) der Formel

(19-6) Fluazinam (bekannt aus EP-A 0 031 257) der Formel

Preferred mixing partners of group (19) are (19-1) acibenzolar-S-methyl (known from EP-A 0 313 512) of the formula

(19-2) chlorothalonil (known from US 3,290,353 ) of the formula

(19-3) Cymoxanil (known from DE-A 23 12 956) of the formula

(19-4) Edifenphos (known from DE-A 14 93 736) of the formula

(19-5) Famoxadone (known from EP-A 0 393 911) of the formula

(19-6) fluazinam (known from EP-A 0 031 257) of the formula

(19-7) Copper oxychloride (19-9) Oxadixyl (known from DE-A 30 30 026) of the formula

(19-10) spiroxamine (known from DE-A 37 35 555) of the formula

(19-11) Dithianone (known from JP-A 44-29464) of the formula

(19-12) Metrafenone (known from EP-A 0 897 904) of the formula

(19-14) 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) on (known from WO 99/14202) of the formula

(19-15) Probenazoles (known from US 3,629,428 ) of the formula

(19-16) isoprothiolanes (known from US 3,856,814 ) of the formula

(19-17) Kasugamycin (known from GB 1 094 567 ) of the formula

(19-18) Phthalides (known from JP-A 57-55844) of the formula

(19-19) Ferimzone (known from EP-A 0 019 450) of the formula

(19-20) tricyclazoles (known from DE-A 22 50 077) of the formula

(19-21) Cyprosulfamides of the formula

(19-22) Mandipropamide (known from WO 01/87822) of the formula

preferred Mixture partners of the group (20) are

(20-1) Pencycuron (known from DE-A 27 32 257) of the formula

(20-2) thiophanate-methyl (known from DE-A 18 06 123) of the formula

(20-3) Thiophanate-ethyl (known from DE-A 18 06 123) of the formula

preferred Mixture partners of the group (21)

(21-1) Fenoxanil (known from EP-A 0 262 393) of the formula

(21-2) Diclocymet (known from JP-A 7-206608) of the formula

preferred Mixing partners of the group (22)

(22-1) 5-Chloro-N - [(IS) -2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1 , 5-a] pyrimidin-7-amine (known from US 5,986,135 ) of the formula

(22-2) 5-Chloro-N - [(1R) -1,2-dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidine 7-amine (known from WO 02/38565) of the formula

(22-3) 5-Chloro-6- (2-chloro-6-fluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine (known out US 5,593,996 ) of the formula

(22-4) 5-Chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine (known from DE-A 101 24 208) of the formula

preferred Mixture partners of the group (23)

(23-1) 2-Butoxy-6-iodo-3-propyl-benzopyran-4-one (known from WO 03/014103) of the formula

(23-2) 2-Ethoxy-6-iodo-3-propyl-benzopyran-4-one (known from WO 03/014103) of the formula

(23-3) 6-iodo-2-propoxy-3-propyl-benzopyran-4-one (known from WO 03/014103) of the formula

(23-4) 2-But-2-ynyloxy-6-iodo-3-propyl-benzopyran-4-one (known from WO 03/014103) of the formula

(23-5) 6-iodo-2- (1-methyl-butoxy) -3-propyl-benzopyran-4-one (known from WO 03/014103) of the formula

(23-6) 2-But-3-enyloxy-6-iodobenzopyran-4-one (known from WO 03/014103) of the formula

(23-7) 3-Butyl-6-iodo-2-isopropoxy-benzopyran-4-one (known from WO 03/014103) of the formula

preferred Mixing partners of the group (24)

(24-1) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide ( known from WO 03/070705) of the formula

(24-2) 3- (Difluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1H pyrazole-4-carboxamide (known from WO 02/08197) of the formula

(24-3) 3- (trifluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1H pyrazole-4-carboxamide (known from WO 02/08197) of the formula

(24-4) N- (3 ', 4'-dichloro-1,1'-biphenyl-2-yl) -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (known from WO 00 / 14701) of the formula

(24-5) N- (4'-chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (trifluoromethyl) -1,3-thiazole-5-carboxamide ( known from WO 03/066609) of the formula

(24-6) N- (4'-chloro-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide (known from WO 03 / 066610) of the formula

(24-7) N- (4'-Bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide (known from WO 03 / 066610) of the formula

(24-8) 4- (Difluoromethyl) -2-methyl-N- [4 '- (trifluoromethyl) -1,1'-biphenyl-2-yl] -1,3-thiazole-5-carboxamide (known from WO 03/066610) of the formula

The Compound (6-7) Carpropamid has three asymmetric substituted ones Carbon atoms. The compound (6-7) can therefore be used as a mixture of different isomers or in the form of a single component available. Particularly preferred are the compounds

(1S, 3R) -2,2-dichloro-N - [(1R) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide of the formula

(1R, 3S) -2,2-dichloro-N - [(1R) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide of the formula

und eine Verbindung ausgewählt aus der Gruppe (2) bis (4).Emphasis is given to active ingredient combinations containing the compound of the formula (Ia)

and a compound selected from the group (2) to (4).

und eine Verbindung ausgewählt aus den Gruppen (2) bis (24).Also highlighted are active ingredient combinations containing the compound of the formula (Ib)

and a compound selected from the groups (2) to (24).

• (2-1) Azoxystrobin
• (2-2) Fluoxastrobin
• (2-3) (2E)-2-(2-{[6-(3-Chlor-2-methylphenoxy)-5-fluor-4-pyrimidinyl]oxy}phenyl)-2- (methoxyimino)-N-methylethanamid
• (2-4) Trifloxystrobin
• (2-5) (2E)-2-(Methoxyimino)-N-methyl-2-(2-{[({(1E)-1-[3-(trifluormethyl)phe nyl]ethyliden}amino)oxy]methyl}phenyl)ethanamid
• (2-6) (2E)-2-(Methoxyimino)-N-methyl-2-{2-[(E)-({1-[3-(trifluormethyl)phenyl] ethoxy}imino)methyl]phenyl}ethanamid
• (2-8) 5-Methoxy-2-methyl-4-(2-{[({(1E)-1-[3-(trifluormethyl)phenyl]ethyliden} amino)oxy]methyl}phenyl)-2,4-dihydro-3H-1,2,4-triazol-3-on
• (2-9) Kresoxim-methyl
• (2-10) Dimoxystrobin
• (2-11) Picoxystrobin
• (2-12) Pyraclostrobin
• (2-13) Metominostrobin
• (3-3) Propiconazole
• (3-4) Difenoconazole
• (3-6) Cyproconazole
• (3-7) Hexaconazole
• (3-8) Penconazole
• (3-9) Myclobutanil
• (3-10) Tetraconazole
• (3-12) Epoxiconazole
• (3-13) Flusilazole
• (3-15) Prothioconazole
• (3-16) Fenbuconazole
• (3-17) Tebuconazole
• (3-18) Ipconazole
• (3-19) Metconazole
• (3-20) Triticonazole
• (3-21) Bitertanol
• (3-22) Triadimenol
• (3-23) Triadimefon
• (3-24) Fluquinconazole
• (4-1) Dichlofluanid
• (4-2) Tolylfluanid
• (5-1) Iprovalicarb
• (5-3) Benthiavalicarb
• (6-2) Boscalid
• (6-5) Ethaboxam
• (6-6) Fenhexamid
• (6-7) Carpropamid
• (6-8) 2-Chlor-4-[(2-fluor-2-methylpropanoyl)amino]-N,N-dimethylbenzamid
• (6-9) Fluopicolid
• (6-10) Zoxamide
• (6-11) 3,4-Dichlor-N-(2-cyanophenyl)isothiazol-5-carboxamid
• (6-14) Penthiopyrad
• (6-16) N-[2-(1,3-Dimethylbutyl)phenyl]-1-methyl-4-(trifluormethyl)-1H-pyrrol-3-carboxamid
• (6-17) Flutolanil
• (6-18) N-[2-(1,3-dimethylbutyl)phenyl]-5-fluor-1,3-dimethyl-1H-pyrazol-4-carboxamid
• (7-1) Mancozeb
• (7-2) Maneb
• (7-4) Propineb
• (7-5) Thiram
• (7-6) Zineb
• (8-1) Benalaxyl
• (8-2) Furalaxyl
• (8-3) Metalaxyl
• (8-4) Metalaxyl-M
• (8-5) Benalaxyl-M
• (9-1) Cyprodinil
• (9-2) Mepanipyrim
• (9-3) Pyrimethanil
• (10-1) 6-Chlor-5-[(3,5-dimethylisoxazol-4-yl)sulfonyl]-2,2-difluor-5H-[1,3]dioxolo[4,5-f]benzimidazol
• (10-3) Carbendazim
• (11-1) Diethofencarb
• (11-2) Propamocarb
• (11-3) Propamocarb-hydrochloride
• (11-4) Propamocarb-Fosetyl
• (12-2) Captan
• (12-3) Folpet
• (12-4) Iprodione
• (12-5) Procymidone
• (13-1) Dodine
• (13-2) Guazatine
• (13-3) Iminoctadine triacetate
• (14-1) Cyazofamid
• (14-2) Prochloraz
• (14-3) Triazoxide
• (15-4) Fenpropimorph
• (15-5) Dimethomorph
• (16-2) Fludioxonil
• (17-1) Fosetyl-Al
• (17-2) Phosphonic acid
• (17-3) Tolclofos-methyl
• (19-1) Acibenzolar-S-methyl
• (19-2) Chlorothalonil
• (19-3) Cymoxanil
• (19-5) Famoxadone
• (19-6) Fluazinam
• (19-7) Kupferoxychlorid
• (19-9) Oxadixyl
• (19-10) Spiroxamine
• (19-21) Cyprosulfamide
• (19-22) Mandipropamid
• (20-1) Pencycuron
• (20-2) Thiophanate-methyl
• (22-1) 5-Chlor-N-[(1S)-2,2,2-trifluor-1-methylethyl]-6-(2,4,6-trifluorphenyl)[1,2,4]triazolo[1,5-a] pyrimidin-7-amin
• (22-2) 5-Chlor-N-[(1R)-1,2-dimethylpropyl]-6-(2,4,6-trifluorphenyl)[1,2,4]triazolo[1,5-a]pyri midin-7-amin
• (22-4) 5-Chlor-6-(2,4,6-trifluorphenyl)-7-(4-methylpiperidin-1-yl)[1,2,4]triazolo[1,5-a]pyrimidin
• (23-1) 2-Butoxy-6-iod-3-propyl-benzopyran-4-on
• (23-2) 2-Ethoxy-6-iod-3-propyl-benzopyran-4-on
• (23-3) 6-Iod-2-propoxy-3-propyl-benzopyran-4-on
• (24-1) N-(3',4'-Dichlor-5-fluor-1,1'-biphenyl-2-yl)-3-(difluormethyl)-1-methyl-1H-pyrazol-4- carboxamid
• (24-3) 3-(Trifluormethyl)-N-{3'-fluor-4'-[(E)-(methoxyimino)methyl]-1,1'-biphenyl-2-yl}-1- methyl-1H-pyrazol-4-carboxamid
• (24-7) N-(4'-Brom-1,1'-biphenyl-2-yl)-4-(difluormethyl)-2-methyl-1,3-thiazol-5-carboxamid

As active ingredient of groups (2) to (24), the following active substances are particularly preferred:

• (2-1) Azoxystrobin
• (2-2) Fluoxastrobin
• (2-3) (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy} phenyl) -2- (methoxyimino) -N-methylethanamide
• (2-4) Trifloxystrobin
• (2-5) (2E) -2- (methoxyimino) -N-methyl-2- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl } phenyl) ethanamide
• (2-6) (2E) -2- (methoxyimino) -N-methyl-2- {2 - [(E) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide
• (2-8) 5-Methoxy-2-methyl-4- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4 dihydro-3H-1,2,4-triazol-3-one
• (2-9) Kresoxim-methyl
• (2-10) dimoxystrobin
• (2-11) Picoxystrobin
• (2-12) Pyraclostrobin
• (2-13) Metominostrobin
• (3-3) propiconazole
• (3-4) difenoconazole
• (3-6) Cyproconazole
• (3-7) hexaconazole
• (3-8) Penconazole
• (3-9) myclobutanil
• (3-10) Tetraconazole
• (3-12) Epoxiconazoles
• (3-13) Flusilazole
• (3-15) prothioconazole
• (3-16) fenbuconazole
• (3-17) Tebuconazole
• (3-18) ipconazole
• (3-19) Metconazole
• (3-20) Triticonazole
• (3-21) Bitertanol
• (3-22) Triadimenol
• (3-23) Triadphone
• (3-24) Fluquinconazole
• (4-1) Dichlofluanid
• (4-2) tolylfluanid
• (5-1) Iprovalicarb
• (5-3) Benthiavalicarb
• (6-2) Boscalid
• (6-5) Ethaboxam
• (6-6) fenhexamide
• (6-7) carpropamide
• (6-8) 2-Chloro-4 - [(2-fluoro-2-methylpropanoyl) amino] -N, N-dimethylbenzamide
• (6-9) fluopicolide
• (6-10) Zoxamide
• (6-11) 3,4-Dichloro-N- (2-cyanophenyl) isothiazole-5-carboxamide
• (6-14) Penthiopyrad
• (6-16) N- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide
• (6-17) Flutolanil
• (6-18) N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide
• (7-1) Mancozeb
• (7-2) Maneb
• (7-4) Propylene
• (7-5) Thiram
• (7-6) Zineb
• (8-1) Benalaxyl
• (8-2) Furalaxyl
• (8-3) metalaxyl
• (8-4) metalaxyl-M
• (8-5) Benalaxyl-M
• (9-1) Cyprodinil
• (9-2) mepanipyrim
• (9-3) pyrimethanil
• (10-1) 6-Chloro-5 - [(3,5-dimethylisoxazol-4-yl) sulfonyl] -2,2-difluoro-5H- [1,3] dioxolo [4,5-f] benzimidazole
• (10-3) carbendazim
• (11-1) Diethofencarb
• (11-2) Propamocarb
• (11-3) Propamocarb hydrochloride
• (11-4) Propamocarb-Fosetyl
• (12-2) Captan
• (12-3) Folpet
• (12-4) Iprodione
• (12-5) procymidones
• (13-1) Dodine
• (13-2) Guazatine
• (13-3) iminoctadine triacetate
• (14-1) Cyazofamide
• (14-2) prochloraz
• (14-3) triazoxide
• (15-4) fenpropimorph
• (15-5) dimethomorph
• (16-2) fludioxonil
• (17-1) fosetyl-Al
• (17-2) Phosphonic acid
• (17-3) tolclofos-methyl
• (19-1) acibenzolar S-methyl
• (19-2) chlorothalonil
• (19-3) cymoxanil
• (19-5) Famoxadone
• (19-6) fluazinam
• (19-7) copper oxychloride
• (19-9) oxadixyl
• (19-10) spiroxamine
• (19-21) Cyprosulfamide
• (19-22) Mandipropamide
• (20-1) Pencycuron
• (20-2) thiophanate-methyl
• (22-1) 5-Chloro-N - [(1S) -2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1 , 5-a] pyrimidin-7-amine
• (22-2) 5-Chloro-N - [(1R) -1,2-dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyri midin-7-amine
• (22-4) 5-Chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine
• (23-1) 2-Butoxy-6-iodo-3-propyl-benzopyran-4-one
• (23-2) 2-ethoxy-6-iodo-3-propyl-benzopyran-4-one
• (23-3) 6-iodo-2-propoxy-3-propyl-benzopyran-4-one
• (24-1) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide
• (24-3) 3- (Trifluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1H pyrazole-4-carboxamide
• (24-7) N- (4'-Bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide

• (2-2) Fluoxastrobin
• (2-3) (2E)-2-(2-{[6-(3-Chlor-2-methylphenoxy)-5-fluor-4-pyrimidinyl]oxy}phenyl)-2- (methoxyimino)-N-methylethanamid
• (2-4) Trifloxystrobin
• (3-15) Prothioconazole
• (3-17) Tebuconazole
• (3-18) Ipconazole
• (3-20) Triticonazole
• (3-21) Bitertanol
• (3-22) Triadimenol
• (3-24) Fluquinconazole
• (4-1) Dichlofluanid
• (4-2) Tolylfluanid
• (5-1) Iprovalicarb
• (6-6) Fenhexamid
• (6-7) Carpropamid
• (6-9) Fluopicolid
• (6-14) Penthiopyrad
• (6-17) Flutolanil
• (6-18) N-[2-(1,3-dimethylbutyl)phenyl]-5-fluor-1,3-dimethyl-1H-pyrazol-4-carboxamid
• (7-4) Propineb
• (7-5) Thiram
• (8-3) Metalaxyl
• (8-4) Metalaxyl-M
• (8-5) Benalaxyl-M
• (9-3) Pyrimethanil
• (10-3) Carbendazim
• (11-4) Propamocarb-Fosetyl
• (12-4) Iprodione
• (14-2) Prochloraz
• (14-3) Triazoxide
• (16-2) Fludioxonil
• (17-3) Tolclofos-methyl
• (19-10) Spiroxamine
• (19-21) Cyprosulfamide
• (19-22) Mandipropamid
• (20-1) Pencycuron
• (22-4) 5-Chlor-6-(2,4,6-trifluorphenyl)-7-(4-methylpiperidin-1-yl)[1,2,4]triazolo[1,5-a]pyri midin
• (24-1) N-(3',4'-Dichlor-5-fluor-1,1'-biphenyl-2-yl)-3-(difluormethyl)-1-methyl-1H-pyrazol-4- carboxamid

As active ingredient of groups (2) to (24), the following active substances are very particularly preferred:

• (2-2) Fluoxastrobin
• (2-3) (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy} phenyl) -2- (methoxyimino) -N-methylethanamide
• (2-4) Trifloxystrobin
• (3-15) prothioconazole
• (3-17) Tebuconazole
• (3-18) ipconazole
• (3-20) Triticonazole
• (3-21) Bitertanol
• (3-22) Triadimenol
• (3-24) Fluquinconazole
• (4-1) Dichlofluanid
• (4-2) tolylfluanid
• (5-1) Iprovalicarb
• (6-6) fenhexamide
• (6-7) carpropamide
• (6-9) fluopicolide
• (6-14) Penthiopyrad
• (6-17) Flutolanil
• (6-18) N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide
• (7-4) Propylene
• (7-5) Thiram
• (8-3) metalaxyl
• (8-4) metalaxyl-M
• (8-5) Benalaxyl-M
• (9-3) pyrimethanil
• (10-3) carbendazim
• (11-4) Propamocarb-Fosetyl
• (12-4) Iprodione
• (14-2) prochloraz
• (14-3) triazoxide
• (16-2) fludioxonil
• (17-3) tolclofos-methyl
• (19-10) spiroxamine
• (19-21) Cyprosulfamide
• (19-22) Mandipropamide
• (20-1) Pencycuron
• (22-4) 5-Chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine
• (24-1) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide

• (2-2) Fluoxastrobin
• (2-4) Trifloxystrobin
• (3-15) Prothioconazole
• (3-17) Tebuconazole
• (3-18) Ipconazole
• (3-20) Triticonazole
• (3-22) Triadimenol
• (6-7) Carpropamid
• (6-18) N-[2-(1,3-dimethylbutyl)phenyl]-5-fluor-1,3-dimethyl-1H-pyrazol-4-carboxamid
• (7-5) Thiram
• (8-3) Metalaxyl
• (8-4) Metalaxyl-M
• (19-21) Cyprosulfamide
• (20-1) Pencycuron
• (24-1) N-(3',4'-Dichlor-5-fluor-1,1'-biphenyl-2-yl)-3-(difluormethyl)-1-methyl-1H-pyrazol-4- carboxamid

As a mixing partner, the following active ingredients are particularly preferred:

• (2-2) Fluoxastrobin
• (2-4) Trifloxystrobin
• (3-15) prothioconazole
• (3-17) Tebuconazole
• (3-18) ipconazole
• (3-20) Triticonazole
• (3-22) Triadimenol
• (6-7) carpropamide
• (6-18) N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide
• (7-5) Thiram
• (8-3) metalaxyl
• (8-4) metalaxyl-M
• (19-21) Cyprosulfamide
• (20-1) Pencycuron
• (24-1) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide

Noteworthy Drug combinations are listed in the following table.

highlighted embodiments of the invention for the treatment of seed are mixtures containing (Ia) and fluoxastrobin (2-2) and / or trifloxystrobin (2-4) and / or Prothioconazole (3-15) and / or tebuconazole (3-17) and / or ipconazole (3-18) and / or triticonazoles (3-20) and / or triadimenol (3-22) and / or carpropamide (6-7) and / or N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (6-18) and / or thiram (7-5) and / or metalaxyl (8-3) and / or metalaxyl-M (8-4) and / or N - ({4 - [(cyclopropylamino) carbonyl] phenyl} sulfonyl) -2-methoxybenzamide (19-21) and / or pencycuron (20-1) and / or N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) - 1-methyl-1H-pyrazole-4-carboxamide (24-1).

highlighted embodiments The invention for the treatment of seeds are still mixtures containing (Ib) and fluoxastrobin (2-2) and / or trifloxystrobin (2-4) and / or prothioconazole (3-15) and / or tebuconazole (3-17) and / or ipconazole (3-18) and / or triticonazole (3-20) and / or Triadimenol (3-22) and / or carpropamide (6-7) and / or N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (6-18) and / or thiram (7-5) and / or metalaxyl (8-3). and or Metalaxyl-M (8-4) and / or N - ({4 - [(cyclopropylamino) -carbonyl] -phenyl} -sulfonyl) -2-methoxy-benzamide (19-21) and / or pencycuron (20-1) and / or N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) - 1-methyl-1H-pyrazole-4-carboxamide (24-1).

The active compound combinations according to the invention contain in addition to an active substance of formula (I) from group 1 at least an active ingredient of the compounds of groups (2) to (24). she can about that In addition, other fungicidal Zumischkomponenten included.

If the active ingredients in the active compound combinations according to the invention in certain weight ratios are present, the synergistic effect is particularly evident. However, you can the weight ratios the active ingredients in the drug combinations in a relatively large area be varied. In general, the combinations according to the invention contain Active compounds of the formula (I) and a mixed partner from one of the groups 2 to 24 in the mixing ratios exemplified in the table below.

The mixing ratios are based on weight ratios. The ratio is to be understood as the active ingredient of the formula (I): Mischpartner

The mixing ratio is to be chosen in each case so that a synergistic mixture is obtained. The mixing ratios between the compound of formula (I) and a compound of one of the groups (2) to (24) can also be between the individual Compounds of a group vary.

The active compound combinations according to the invention have very good fungicidal properties and can be combated by phytopathogenic fungi, such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc. use.

The active compound combinations according to the invention are particularly suitable for controlling Phytophthora infestans, Plasmopara viticola and Botrytis cinerea.

By way of example, but not by way of limitation, some pathogens of fungal and bacterial diseases, which fall under the abovementioned generic terms, are mentioned:
The active compound combinations according to the invention have a strong microbicidal action and can be used for controlling unwanted microorganisms, such as fungi and bacteria, in crop protection and in the protection of materials.

fungicides can plant protection be used to combat Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes.

bactericidal can be used in crop protection to control Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae deploy.

By way of example but not limitation, some pathogens of fungal and bacterial diseases, which fall under the above-enumerated generic terms, are named:
Diseases caused by pathogens of powdery mildew such as
Blumeria species, such as Blumeria graminis;
Podosphaera species, such as Podosphaera leucotricha;
Sphaerotheca species, such as Sphaerotheca fuliginea;
Uncinula species, such as Uncinula necator;
Diseases caused by causative agents of rust diseases such as
Gymnosporangium species, such as Gymnosporangium sabinae
Hemileia species, such as Hemileia vastatrix;
Phakopsora species such as Phakopsora pachyrhizi and Phakopsora meibomiae;
Puccinia species, such as Puccinia recondita;
Uromyces species, such as Uromyces appendiculatus;
Diseases caused by pathogens of the group of Oomycetes such as
Bremia species, such as Bremia lactucae;
Peronospora species such as Peronospora pisi or P. brassicae;
Phytophthora species, such as Phytophthora infestans;
Plasmopara species, such as Plasmopara viticola;
Pseudoperonospora species, such as, for example, Pseudoperonospora humuli or Pseudoperonospora cubensis;
Pythium species such as Pythium ultimum;
Leaf spot diseases and leaf withering, caused by eg
Alternaria species, such as Alternaria solani;
Cercospora species, such as Cercospora beticola;
Cladiosporum species, such as Cladiosporium cucumerinum;
Cochliobolus species, such as Cochliobolus sativus
(Conidia form: Drechslera, Syn: Helminthosporium);
Colletotrichum species, such as Colletotrichum lindemuthanium;
Cycloconium species such as cycloconium oleaginum;
Diaporthe species, such as Diaporthe citri;
Elsinoe species, such as Elsinoe fawcettii;
Gloeosporium species, such as, for example, Gloeosporium laeticolor;
Glomerella species, such as Glomerella cingulata;
Guignardia species, such as Guignardia bidwelli;
Leptosphaeria species, such as Leptosphaeria maculans;
Magnaporthe species, such as Magnaporthe grisea;
Mycosphaerella species, such as Mycosphaerelle graminicola;
Phaeosphaeria species, such as Phaeosphaeria nodorum;
Pyrenophora species, such as, for example, Pyrenophora teres;
Ramularia species, such as Ramularia collo-cygni;
Rhynchosporium species, such as Rhynchosporium secalis;
Septoria species, such as Septoria apii;
Typhula species, such as Typhula incarnata;
Venturia species, such as Venturia inaequalis;
Root and stem diseases, caused by eg
Corticium species, such as Corticium graminearum;
Fusarium species such as Fusarium oxysporum;
Gaeumannomyces species such as Gaeumannomyces graminis;
Rhizoctonia species, such as Rhizoctonia solani;
Tapesia species, such as Tapesia acuformis;
Thielaviopsis species, such as Thielaviopsis basicola;
Ear and panicle diseases (including corncob), caused by eg
Alternaria species, such as Alternaria spp .;
Aspergillus species, such as Aspergillus flavus;
Cladosporium species such as Cladosporium spp .;
Claviceps species, such as Claviceps purpurea;
Fusarium species such as Fusarium culmorum;
Gibberella species, such as Gibberella zeae;
Monographella species, such as Monographella nivalis;
Diseases caused by fire fungi such as
Sphacelotheca species, such as Sphacelotheca reiliana;
Tilletia species, such as Tilletia caries;
Urocystis species, such as Urocystis occulta;
Ustilago species such as Ustilago nuda;
Fruit rot caused by eg
Aspergillus species, such as Aspergillus flavus;
Botrytis species, such as Botrytis cinerea;
Penicillium species such as Penicillium expansum;
Sclerotinia species, such as Sclerotinia sclerotiorum;
Verticilium species such as Verticilium alboatrum;
Seed and soil-borne rots and wilting, and seedling diseases, caused by eg
Fusarium species such as Fusarium culmorum;
Phytophthora species, such as Phytophthora cactorum;
Pythium species such as Pythium ultimum;
Rhizoctonia species, such as Rhizoctonia solani;
Sclerotium species, such as Sclerotium rolfsii;
Cancers, galls and witches brooms, caused by eg
Nectria species, such as Nectria galligena;
Wilting diseases caused by eg
Monilinia species, such as Monilinia laxa;
Deformations of leaves, flowers and fruits, caused by eg
Taphrina species, such as Taphrina deformans;
Degenerative diseases woody plants, caused by eg
Esca species, such as Phaemoniella clamydospora;
Flower and seed diseases, caused by eg
Botrytis species, such as Botrytis cinerea;
Diseases of plant tubers, caused by eg
Rhizoctonia species, such as Rhizoctonia solani;
Diseases caused by bacterial pathogens such as
Xanthomonas species, such as Xanthomonas campestris pv. Oryzae;
Pseudomonas species, such as Pseudomonas syringae pv. Lachrymans;
Erwinia species, such as Erwinia amylovora;
Preferably, the following diseases of soybean beans can be controlled:
Fungal diseases on leaves, stems, pods and seeds caused by eg
Alternaria leaf spot (Alternaria spec. Atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. Truncatum), Brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora infundibulifera trispora (Syn.)) , Dactuliophora leaf spot (Dactuliophora glycines), Downy Mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), Frogeye leaf spot (Cercospora sojina), Leptosphaerulina Leaf Spot (Leptosphaerulina trifolii), Phyllostica leaf spot (Phyllosticta sojaecola), Powdery Mildew (Phyllosticta sojaecola) Microsphaera diffusa), Pyrenochaeta Leaf Spot (Pyrenochaeta glycines), Rhizoctonia Aerial, Foliage and Web Blight (Rhizoctonia solani), Rust (Phakopsora pachyrhizi), Scab (Sphaceloma glycines), Stemphylium Leaf Blight (Stemphylium botryosum), Target Spot (Corynespora cassiicola ).
Fungal diseases at roots and stem base caused by eg
Black Root Red (Calonectria crotalariae), Charcoal Red (Macrophomina phaseolina), Fusarium Blight or Wilt, Root Red, and Pod and Collar Red (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), Mycoleptodiscus Root Red (Mycoleptodiscus terrestris), Neocosmospora (Neocosmopspora vasinfecta), Pod and Stem Blight (Diaporthe phaseolorum), Stem Canker (Diaporthe phaseolorum var. Caulivora), Phytophthora red (Phytophthora megasperma), Brown Stem Red (Phialophora gregata), Pythium Red (Pythium aphanidermatum, Pythium irregulare, Pythium Debaryanum, Pythium myriotylum, Pythium ultimum), Rhizoctonia Root Red, Stem Decay, and Damping Off (Rhizoctonia solani), Sclerotinia Stem Decay (Sclerotinia sclerotiorum), Sclerotinia Southern Blight (Sclerotinia rolfsii), Thielaviopsis Root Red (Thielaviopsis basicola).

The good plant tolerance the drug combinations in the fight against plant diseases necessary concentrations allows treatment of whole plants (above-ground parts of plants and roots), of planting and seed, and the soil. The active compound combinations according to the invention can used for foliar application or as a mordant.

The good plant tolerance the useful agents in the control of plant diseases necessary concentrations allows treatment of the seed. The active compounds according to the invention can thus be used as a mordant.

Much of the damage to crops caused by phytopathogenic fungi is already produced by infestation of the seed during storage and after introduction of the seed into the soil as well as during and immediately after the germination of the plants. This phase is particularly critical, as the roots and shoots of the growing plant are particularly sensitive and even minor damage can lead to the death of the entire plant. There is therefore a particular interest in protecting the seed and the germinating plant by the use of suitable agents.

The fight of phytopathogenic fungi that damage plants after emergence occurs primarily by the treatment of the soil and the above ground Plant parts with pesticides. Due to concerns about of a possible Influence of plant protection products on the environment and health of people and animals there are efforts, the amount of applied To reduce active ingredients.

The fight of phytopathogenic fungi by the treatment of the seed of Plants has long been known and is the subject of constant improvement. Nevertheless, there are a number of treatments for seeds Problems that are not always solved satisfactorily can. So it is worthwhile, procedures for the protection of the seed and To develop the germinating plant, the additional application of pesticides make it redundant after sowing or after emergence of the plants or at least significantly reduce. It is still desirable to optimize the amount of active ingredient used to that the seed and the germinating plant from infestation by phytopathogenic Mushrooms best possible protected is, but without the plant itself by the active ingredient used to harm. In particular, seed treatment methods should also include involve intrinsic fungicidal properties of transgenic plants, for optimal protection of the seed and the germinating plant to achieve a minimum of pesticides.

The The present invention therefore more particularly relates to Method for protecting seed and germinating plants from the Infestation of phytopathogenic fungi by adding the seed with an agent according to the invention is treated.

The The invention also relates to the use of the agents according to the invention for the treatment of seed for the protection of seed and germinating Plant in front of phytopathogenic fungi.

Farther The invention relates to seed, which protects against phytopathogenic Mushrooms with an agent according to the invention was treated.

one the advantages of the present invention is that due to the particular systemic properties of the agents according to the invention the treatment of the seed with these means not only the seed itself, but also the resulting plants after the Protrusion against phytopathogenic fungi protects. In this way, the immediate treatment of the culture at the time of sowing or shortly then omitted.

As well it is to be regarded as advantageous that the mixtures according to the invention especially in transgenic seeds can be used.

The agents according to the invention are suitable for the protection of seed of any plant variety that in agriculture, in the greenhouse, used in forestry or horticulture. In particular, acts these are seeds of cereals (such as wheat, barley, rye, Millet and oats), corn, cotton, soy, rice, potatoes, sunflower, Bean, coffee, turnip (for example, sugar beet and fodder beet), Peanut, vegetables (like tomato, cucumber, onions and lettuce), turf and ornamental plants. Of particular importance is the treatment of the seed of cereals (like wheat, barley, rye and oats), corn and rice too.

in the Within the scope of the present invention is the agent according to the invention applied alone or in a suitable formulation on the seed. Preferably, the seed is treated in a state in which it is so stable that no damage occur during treatment. In general, the treatment can of the seed at any time between harvesting and sowing respectively. Usually seed separated from the plant and used by flasks, Shells, stalks, shell Wool or pulp was freed. For example, seeds used, harvested, cleaned and up to a moisture content was dried below 15 wt .-%. Alternatively, seed can also be used used after drying, e.g. treated with water and then dried again.

In general, when treating the seed, care must be taken that the amount of the agent and / or other additives applied to the seed is chosen that the germination of the seeds is not impaired or that the resulting plant is not damaged. This is especially important for active ingredients, which can show phytotoxic effects in certain application rates.

The agents according to the invention can be applied directly, ie without containing further components and without being diluted. In general, it is preferable to apply the agents to the seed in the form of a suitable formulation. Suitable formulations and methods for seed treatment are known to the person skilled in the art and are described, for example, in the following documents: US 4,272,417 A . US 4,245,432 A . US 4,808,430 A . US 5,876,739 A , US 2003/0176428 A1, WO 2002/080675 A1, WO 2002/028186 A2.

The active compound combinations according to the invention are also suitable for increasing crop yield. They are also less toxic and have good plant tolerance.

The active compound combinations according to the invention also have a strong restorative Effect in plants. They are therefore suitable for mobilization plant's own defenses against infestation by unwanted Microorganisms.

Under plant-strengthening (resistance-inducing) substances are in the present context to understand such substances that are capable of the immune system of plants to stimulate so that the treated plants at subsequent inoculation with unwanted microorganisms extensive resistance unfold against these microorganisms.

Under undesirable Microorganisms in the present case are phytopathogenic fungi, To understand bacteria and viruses. The substances according to the invention can So be used to plants within a period of time after the treatment against the infestation by the mentioned pathogens to protect. The period within which protection is provided extends in the Generally from 1 to 10 days, preferably 1 to 7 days after Treatment of plants with the active ingredients.

The good plant tolerance the drug combinations in the fight against plant diseases necessary concentrations allows treatment of above ground Plant parts, of plant and seed, and of the soil.

there let the active compound combinations according to the invention with particular success in combating cereal diseases, such as. against Puccinia species and diseases in wine, fruit and and vegetable growing, such as. against Botrytis, Venturia or Alternaria species.

The active compound combinations according to the invention are also suitable for increasing crop yield. They are also less toxic and have good plant tolerance.

The active compound combinations according to the invention can optionally in certain concentrations and application rates also as herbicides, for influencing plant growth, as well as for fight of animal pests be used. Where appropriate, they may also be considered as intermediate and precursors for use the synthesis of other drugs.

According to the invention, all Plants and parts of plants are treated. Among plants are here understood all plants and plant populations, as desired and undesirable Wild plants or crops (including naturally occurring crops). Crops can Be plants by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or Combinations of these methods can be obtained, including transgenic ones Plants and including protected by plant variety rights or non-protectable plant varieties. Under plant parts are all above ground and underground Parts and organs of plants, such as shoot, leaf, flower and root By way of example, leaves, needles, stems, stems, flowers, fruiting bodies, fruits and Seeds as well as roots, tubers and rhizomes. To the plant parts belongs also harvested material as well as vegetative and generative propagation material, For example, cuttings, tubers, rhizomes, offshoots and seeds.

The treatment according to the invention of the plants and plant parts with the active ingredient combinations takes place directly or by acting on their environment, habitat or storage space according to the usual treatment methods, for example by dipping, spraying, vaporizing, atomizing, spreading, brushing on and Propagating material, especially in seeds, further by single or multi-layer wrapping. In this case, the active ingredient combinations can be prepared before the treatment by mixing the individual active ingredients. Or the treatment is carried out successively by using first a phthalamide of the group (1) followed by the treatment with an active ingredient of the groups (2) to (24). However, it is also possible to first treat the plants or plant parts with an active compound of groups (2) to (24) and to attach the treatment with a phthalamide of group (1).

in the Material protection can be the active ingredient combinations of the invention for the protection of technical materials against infestation and destruction by undesirable Use microorganisms.

Under technical materials are non-living in the present context Understand materials for the use has been prepared in the art. For example can technical materials, by the active compounds according to the invention before microbial change or destruction protected adhesives, glues, paper and board, textiles, Leather, wood, paints and plastics, coolants and other materials that are infested by microorganisms or can be decomposed. As part of the protected Materials are also parts of production plants, such as cooling water circuits, called, which can be affected by the proliferation of microorganisms. As part of of the present invention are preferred as engineering materials Adhesives, glues, papers and cartons, leather, wood, paints, coolant and heat transfer fluids called, more preferably wood.

When Microorganisms that cause degradation or alteration of engineering materials can cause are for example bacteria, fungi, yeasts, algae and slime organisms called. The active compounds according to the invention preferably act against fungi, especially molds, wood-discolouring and wood-destroying fungi (Basidiomycetes) and against slime organisms and algae.

There may be mentioned, for example, microorganisms of the following genera:
Alternaria, such as Alternaria tenuis,
Aspergillus, such as Aspergillus niger,
Chaetomium, such as Chaetomium globosum,
Coniophora, like Coniophora puetana,
Lentinus, like Lentinus tigrinus,
Penicillium, such as Penicillium glaucum,
Polyporus, such as Polyporus versicolor,
Aureobasidium, such as Aureobasidium pullulans,
Sclerophoma, such as Sclerophoma pityophila,
Trichoderma, like Trichoderma viride,
Escherichia, like Escherichia coli,
Pseudomonas, such as Pseudomonas aeruginosa,
Staphylococcus, such as Staphylococcus aureus.

Furthermore have the active compound combinations according to the invention also very good antifungal effects. You own a lot broad antifungal activity spectrum, especially against dermatophytes and budworms, molds and diphasic fungi (e.g., against Candida species such as Candida albicans, Candida glabrata) and Epidermophyton floccosum, Aspergillus species such as Aspergillus niger and Aspergillus fumigatus, Trichophyton species such as Trichophyton mentagrophytes, Microsporon species like Microsporon canis and audouinii. The listing of these mushrooms does not under any circumstances a restriction of the detectable mycotic spectrum, but has only illustrative Character.

The Drug combinations can as such, in the form of their formulations or the ones prepared from them Application forms, such as ready-to-use solutions, suspensions, wettable powders, Pastes, soluble Powder, dusts and granules are applied. The application happens in usual Way, e.g. by pouring, Spraying, spraying, Scattering, dusting, foaming, Brushing, etc. It is also possible to dispense the active ingredients according to the ultra-low-volume method or the preparation of active ingredient or inject the drug itself into the soil. It can also the seeds of the plants are treated.

When using the active compound combinations according to the invention as fungicides, the application rates can be varied within a relatively wide range, depending on the mode of administration. In the treatment of parts of plants, the application rates of active ingredient are generally between 0.1 and 10,000 g / ha, preferably between 10 and 1,000 g / ha. In seed treatment, the application rates of active ingredient are generally between 0.001 and 50 g per kilogram of seed, preferably between 0.01 and 10 g per kilogram of seed. In the treatment of the soil, the application rates of active ingredient are generally between 0.1 and 10,000 g / ha, preferably between 1 and 5,000 g / ha.

The listed Plants can particularly advantageous according to the invention with the drug mixtures be treated. The specified in the active ingredients or mixtures above Preferential ranges also apply to the treatment of these plants. Particularly emphasized is the Plant treatment with the compounds specifically listed herein or mixtures.

The active compound combinations according to the invention are also suitable for controlling animal pests, preferably arthropods and nematodes, in particular nematodes and insects, which occur in agriculture, animal health, in forests, in the protection of stored products and materials, and in the hygiene sector. They are effective against normally sensitive and resistant species as well as against all or individual stages of development. The above mentioned pests include:
From the order of the Isopoda eg Oniscus asellus, Armadillidium vulgare, Porcellio scaber.
From the order of Diplopoda eg Blaniulus guttulatus.
From the order of Chilopoda eg Geophilus carpophagus, Scutigera spp.
From the order of Symphyla eg Scutigerella immaculata.
From the order of Thysanura eg Lepisma saccharina.
From the order of the Collembola eg Onychiurus armatus.
From the order of the Orthoptera eg Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.
From the order Blattaria orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica.
From the order of the Dermaptera eg Forficula auricularia.
From the order of the Isoptera eg Reticulitermes spp.
From the order of Phthiraptera, for example, Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp.
From the order of Thysanoptera eg Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.
From the order of Heteroptera eg Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.
From the order of the Homoptera, for example, Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigus spp., Macro siphum avenae, Myzus spp. , Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp.
From the order of Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp , Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretella , Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae.
From the order Coleoptera eg Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp. , Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus.
From the order of Hymenoptera eg Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
From the order of Diptera eg Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp , Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hyle myia spp., Liriomyza spp.
From the order of Siphonaptera eg Xenopsylla cheopis, Ceratophyllus spp.
From the class Arachnida eg Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp , Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.
Examples of plant parasitic nematodes include Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp.

The Drug combinations can dependent on from their respective physical and / or chemical properties in the usual Formulations are transferred, like solutions, Emulsions, wettable powders, suspensions, powders, foams, dusts, Pastes, soluble Powders, granules, aerosols, suspension emulsion concentrates, Impregnated with active Natural and synthetic Substances, ultra-fine encapsulations in polymeric materials and in shell materials for seeds, as well as ULV cold and warm mist formulations.

These Formulations are prepared in a known manner, e.g. by Mixing the active ingredients with extenders, ie liquid solvents and / or solid carriers, optionally using surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents.

in the Traps of using water as diluent may be e.g. also organic solvents as auxiliary solvent be used. As liquid solvent are essentially in question: aromatics, such as xylene, toluene, or Alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic Hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, Alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide and dimethyl sulfoxide, as well as water.

Suitable solid carriers are:
For example, ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic minerals, such as finely divided silica, alumina and silicates, as solid carriers for granules in question: eg broken and fractionated natural rocks such Calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, coconut shells, corn cobs and tobacco stalks; as emulsifying and / or foam-producing agents come into question: eg
nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, arylsulfonates and protein hydrolysates; suitable dispersants are: for example lignin-sulphite liquors and methylcellulose.

It can in the formulations adhesives such as carboxymethylcellulose, natural and synthetic powdery, granular or latex-shaped Polymers such as gum arabic, polyvinyl alcohol, Polyvinyl acetate, as well as natural Phospholipids such as cephalins and lecithins and synthetic phospholipids. Other additives can mineral and vegetable oils be.

It can Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, Ferrocyan blue and organic dyes such as alizarin, azo and Metal phthalocyanine dyes and trace nutrients such as salts of iron, Manganese, boron, copper, cobalt, molybdenum and zinc are used.

The Formulations generally contain between 0.1 and 95% by weight Active ingredient, preferably between 0.5 and 90%.

The active compound combinations according to the invention can in commercial Formulations and in those prepared from these formulations Forms of use mixed with other active substances, such as insecticides, Attractants, sterilants, bactericides, acaricides, nematicides, Fungicides, growth regulators or herbicides. To the insecticides count For example, phosphoric acid esters, carbamates, Carbonsäureester, chlorinated hydrocarbons, phenylureas, by microorganisms Fabrics u.a.

Also a mixture with other known active substances, like herbicides or with fertilizers and Growth regulators is possible.

The active compound combinations according to the invention can also when used as insecticides in their commercial Formulations and in those prepared from these formulations Application forms in mixture with synergists are present. synergists are compounds that increase the effect of the active ingredients without the added synergist itself being active got to.

Of the Active substance content prepared from the commercial formulations Application forms can vary widely. The drug concentration the application forms may range from 0.0000001 up to 95% by weight of active ingredient, preferably between 0.0001 and 1 wt .-%.

The Application is done in a custom forms adapted to the applications Wise.

at the application against hygiene and storage pests are characterized by the drug combinations an excellent residual effect on wood and clay as well as by a good alkali stability on limed Documents out.

The active compound combinations of the invention not only against plant, hygiene and storage pests, but also in the veterinary sector against animal parasites (ectoparasites) such as ticks, leather ticks, mange mites, mites, flies (stinging and licking), parasitic fly larvae, lice, hair pieces, Featherlings and fleas. These parasites include:
From the order of the Anoplurida eg Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.
From the order of Mallophagida and the suborders Amblycerina and Ischnocerina eg Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp.
From the order Diptera and the suborders Nematocerina and Brachycerina eg Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp. , Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora Spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp.
From the order of the siphon adapter eg Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.
From the order of the Heteropterida eg Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.
From the order Blattarida eg Blatta orientalis, Periplaneta americana, Blattela germanica, Supella spp.
From the subclass of Acaria (Acarida) and the orders of Meta and Mesostigmata eg Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalomma Spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp., Varroa spp.
From the order of Actinedida (Prostigmata) and Acaridida (Astigmata) eg Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp. Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.

The active compound combinations according to the invention are also suitable for fighting of arthropods, farm animals, e.g. Bovine, Sheep, goats, horses, pigs, donkeys, camels, buffalo, rabbits, Chicken, Turkeys, ducks, geese, Bees, other pets such as e.g. Dogs, cats, caged birds, aquarium fish and so-called experimental animals, e.g. Hamster, guinea pig, Rats and mice affected. By fighting These arthropods are said to be deaths and reductions in performance (in the case of meat, milk, wool, hides, eggs, Honey, etc.) are reduced, so that through the use of the active compound combinations according to the invention a more economical and easier animal husbandry is possible.

The application of the active compound combinations according to the invention is done in the veterinary sector in a known manner by enteral administration in the form of, for example, tablets, capsules, infusions, Drenchen, granules, pastes, boluses, the feed-through process, suppositories, by parenteral administration, such as by Injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.), implants, by nasal application, by dermal application in the form of, for example, dipping or bathing (dipping), spraying, pouring and spot-on, washing , powdering and with the help of active substance-containing moldings, such as collars, ear tags, tail marks, limb bands, holsters, marking devices, etc.

at the application for Livestock, poultry, Pets etc. can be the drug combinations as formulations (For example, powders, emulsions, flowable agents) containing the active ingredients in an amount of 1 to 80 wt .-%, directly or after 100 up to 10 000-fold dilution apply or use as a chemical bath.

It was also found that the drug combinations of the invention show a high insecticidal activity against insects, the technical Destroy materials.

By way of example and preferably without limiting however, the following insects are mentioned:
Beetles such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus.

Hymenoptera like Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur.

termites like Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus.

Bristle tails like Lepisma saccharina.

Under technical materials are non-living in the present context Materials, such as preferably plastics, adhesives, Glues, papers and cartons, leather, wood, woodworking products and paints.

All it is particularly preferable for the insect infestation protected Material around wood and woodworking products.

Under Wood and woodworking products, which by the agent according to the invention or this containing mixtures can be protected, is exemplary to understand: timber, wooden beams, railway sleepers, bridge parts, Jetties, wooden vehicles, crates, pallets, containers, telephone poles, Wooden cladding, wooden windows and doors, plywood, chipboard, Carpentry or wood products, which are generally used in house construction or use in the joinery.

The Drug combinations can as such, in the form of concentrates or general Formulations such as powders, granules, solutions, suspensions, emulsions or pastes are applied.

The mentioned formulations in a manner known per se, e.g. by mixing the active ingredients with at least one solvent or diluent, Emulsifier, dispersing and / or binding or fixing agent, water repellent, optionally siccatives and UV stabilizers and optionally dyes and pigments and other processing aids.

The insecticides used to protect wood and wood-based materials Agents or concentrates contain the active ingredient according to the invention in a concentration of 0.0001 to 95 wt .-%, in particular 0.001 to 60% by weight.

The Amount of funds used or concentrates is of the type and depending on the occurrence of the insects and on the medium. The optimal application rate can be determined in each case by test series become. In general, however, it is sufficiently from 0.0001 to 20% by weight, preferably 0.001 to 10 wt .-%, of the active ingredient, based on the to be protected Material to use.

When solvent and / or diluents serves an organic-chemical solvent or solvent mixture and / or an oily one or oily heavy volatile organic-chemical solvent or Solvent mixture and / or a polar organic-chemical solvent or solvent mixture and / or water and optionally an emulsifier and / or wetting agent.

When organic-chemical solvents are preferably oily or oil-like solvent with an evaporation number over 35 and a flash point above 30 ° C, preferably above 45 ° C used. As such low-volatility, water-insoluble, oily and oily solvent become appropriate mineral oils or their aromatic fractions or mineral oil-containing solvent mixtures, preferably White spirit, petroleum and / or alkylbenzene used.

Advantageous get mineral oils with a boiling range of 170 to 220 ° C, white spirit with a boiling range from 170 to 220 ° C, spindle oil with a boiling range of 250 to 350 ° C, petroleum or aromatics from Boiling range of 160 to 280 ° C, turpentine and the like. For use.

In a preferred embodiment become liquid aliphatic hydrocarbons having a boiling range of 180 to 210 ° C or high-boiling mixtures of aromatic and aliphatic hydrocarbons with a boiling range of 180 to 220 ° C and / or spindle oil and / or Monochloronaphthalene, preferably α-monochloronaphthalene.

The organic low volatility oily or oily solvent with an evaporation number over 35 and a flash point above 30 ° C, preferably above 45 ° C, can partially by light or medium volatile organic-chemical solvents be replaced, with the proviso that the solvent mixture also an evaporation number over 35 and a flash point above 30 ° C, preferably above 45 ° C, having and that the mixture in this solvent mixture soluble or emulsifiable.

To a preferred embodiment becomes part of the organic chemical solvent or solvent mixture or an aliphatic polar organic chemical solvent or solvent mixture replaced. Preferably, hydroxyl and / or ester and / or Ether group-containing aliphatic organic-chemical solvents such as glycol ethers, esters or the like. For use.

When Organic-chemical binders are used in the present Invention the known water-dilutable and / or in the used organic-chemical solvents soluble or dispersible or emulsifiable synthetic resins and / or binding drying oils, in particular Binder consisting of or containing an acrylate resin, a vinyl resin, e.g. Polyvinyl acetate, polyester resin, polycondensation or polyaddition resin, Polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, Hydrocarbon resin such as indene coumarone resin, silicone resin, drying vegetable and / or drying oils and / or physically drying binders based on a natural and / or Resin used.

The Resin used as a binder may be in the form of an emulsion, Dispersion or solution, be used. Bitumen or bituminous substances can also be used as binders up to 10% by weight. In addition, known dyes, Pigments, water repellents, scents and inhibitors or corrosion inhibitors and the like. Be used.

Prefers is according to the invention as organic-chemical binder at least one alkyd resin or modified alkyd resin and / or a drying vegetable oil on average or in the concentrate. Preferred according to the invention Alkyd resins with an oil content of more than 45% by weight, preferably 50 to 68% by weight.

The mentioned Binder may be wholly or partly by a fixative (mixture) or a plasticizer (mixture) are replaced. These additives should a volatilization prevent the active ingredients and crystallization or precipitation. Preferably, they replace 0.01 to 30% of the binder (based on 100% of the binder used).

The Plasticizers come from the chemical classes of phthalates such as dibutyl, dioctyl or Benzylbutylphthalat, phosphoric acid esters such as tributyl phosphate, adipic acid ester such as di (2-ethylhexyl) adipate, stearates such as butyl stearate or amyl stearate, Oleates such as butyl oleate, glycerol ethers or higher molecular weight glycol ethers, Glycerol ester and p-toluenesulfonic acid ester.

fixative are chemically based on polyvinyl alkyl ethers such as e.g. polyvinyl methyl or ketones such as benzophenone, ethylene benzophenone.

Particularly suitable solvents or diluents are also water, optionally in admixture with one or more of the abovementioned organic-chemical solvents or diluents medium, emulsifiers and dispersants.

One particularly effective wood protection is achieved by large-scale impregnation e.g. Vacuum, double vacuum or printing process achieved.

at the same time can the active compound combinations according to the invention for protection against the growth of objects, in particular hulls, sieves, Nets, structures, wharves and signal systems connected with sea or brackish water are used.

growth by sessile Oligochaeten, like Kalkröhrenwürmer as well as by shells and Species of the group Ledamorpha (barnacles), like different lepas and scalpel species, or by species of the group Balanomorpha (barnacles), like Balanus or Pollicipes species, increases the frictional resistance of Ships and guides increased in consequence by Energy consumption and above Beyond frequent Dry dock stays at a significant increase in operating costs.

Next the vegetation by algae, for example Ectocarpus sp. and ceramium sp., comes in particular from the vegetation by sessile Entomostraken groups, which are summarized under the name cirripedia (cirriped crayfish), special importance.

It was now surprisingly found that the drug combinations of the invention a have excellent antifouling (antifouling) effect.

By Use of the active compound combinations according to the invention may indicate the use of heavy metals, e.g. in bis (trialkyltin) sulfides, Tri-n-butyltin laurate, tri-n-butyltin chloride, copper (I) oxide, triethyltin chloride, Tri-n-butyl (2-phenyl-4-chlorophenoxy) -tin, tributyltin oxide, molybdenum disulfide, Antimony oxide, polymeric butyl titanate, phenyl (bispyridine) bismuth chloride, Tri-n-butyltin fluoride, manganese ethylene bis-thiocarbamate, zinc dimethyldithiocarbamate, Zinc ethylenebisthiocarbamate, zinc and copper salts of 2-pyridinethiol-1-oxide, bisdimethyldithiocarbamoylzincethylenebisthiocarbamate, Zinc oxide, copper (I) ethylene-bisdithiocarbamate, copper thiocyanate, Copper naphthenate and Tributylzinnhalogeniden be omitted or the concentration of these compounds are decisively reduced.

The ready-to-use antifouling paints may possibly have others Active ingredients, preferably algicides, fungicides, herbicides, molluscicides or other antifouling agents.

Suitable combination partners for the antifouling agents according to the invention are preferably:
Algicides such as 2-tert-butylamino-4-cyclopropylamino-6-methylthio-1,3,5-triazine, dichlorophene, diuron, endothal, fentin acetate, isoproturon, methabenzthiazuron, oxyfluorfen, quinoclamine and terbutryn;
Fungicides such as benzo [b] thiophenecarboxylic cyclohexylamide S, S-dioxide, dichlorofluanide, fluoro-folpet, 3-iodo-2-propynyl-butylcarbamate, tolylfluanid and azoles such as azaconazoles, cyproconazoles, epoxyconazoles, hexaconazoles, metconazoles, propiconazoles and tebuconazoles;
Molluscicides such as fentin acetate, metaldehyde, methiocarb, niclosamide, thiodicarb and trimethacarb;
or conventional antifouling agents such as 4,5-dichloro-2-octyl-4-isothiazolin-3-one, diiodomethylparatrylsulfone, 2- (N, N-dimethylthiocarbamoylthio) -5-nitrothiazyl, potassium, copper, sodium and zinc salts of 2-pyridinethiol-1-oxide, pyridine-triphenylborane, tetrabutyldistannoxane, 2,3,5,6-tetrachloro-4- (methylsulfonyl) -pyridine, 2,4,5,6-tetrachloroisophthalonitrile, tetramethylthiuram disulfide and 2,4,6 -Trichlorphenylmaleinimid.

The antifouling agents used contain the active compound combinations according to the invention in a concentration of 0.001 to 50 wt .-%, in particular of 0.01 to 20 wt .-%.

The Antifouling agent according to the invention also contain the usual Ingredients such as e.g. in Ungerer, Chem. Ind. 1985, 37, 730-732 and Williams, Antifouling Marine Coatings, Noyes, Park Ridge, 1973.

Antifouling paints contained in addition to the algicides, fungicides, molluscicides and insecticides according to the invention Active ingredients, in particular binders.

Examples of approved binders are polyvinyl chloride in a solvent system, chlorinated rubber in a solvent system, acrylic resins in a solvent system, especially in an aqueous system, vinyl chloride / vinyl acetate copolymer systems in the form of aqueous dispersions or in the form of organic solvent systems, butadiene / styrene / acrylonitrile rubbers, drying oils, such as Leinsa oil, rosin ester or modified hard resins in combination with tar or bitumen, asphalt and epoxy compounds, small amounts of chlorinated rubber, chlorinated polypropylene and vinyl resins.

Possibly Paint also contains inorganic pigments, organic Pigments or dyes which are preferably insoluble in seawater. Furthermore, can Coating materials, such as rosin, contain a controlled Allow release of the active ingredients. The paintings can also Plasticizers, modifiers which influence the rheological properties as well as other conventional ones Contain ingredients. Even in self-polishing antifouling systems, the Compounds of the invention or the above mixtures are incorporated.

The active substance combinations are also suitable for controlling animal pests, in particular insects, arachnids and mites, which are used in enclosed spaces such as, for example, apartments, factory halls, offices, vehicle cabins and the like. occurrence. They can be used to control these pests in household insecticide products. They are effective against sensitive and resistant species and against all stages of development. These pests include:
From the order of Scorpionidea eg Buthus occitanus.
From the order of the Acarina eg Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae.
From the order of the Araneae eg Aviculariidae, Araneidae.
From the order of the Opiliones eg Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.
From the order of the Isopoda eg Oniscus asellus, Porcellio scaber.
From the order of the Diplopoda eg Blaniulus guttulatus, Polydesmus spp.
From the order of Chilopoda eg Geophilus spp.
From the order of Zygentoma eg Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.
From the order of the Blattaria eg Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa.
From the order of Saltatoria eg Acheta domesticus.
From the order of the Dermaptera eg Forficula auricularia.
From the order of the Isoptera eg Kalotermes spp., Reticulitermes spp.
From the order of Psocoptera eg Lepinatus spp., Liposcelis spp.
From the order of Coleptera, for example, Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum.
From the order of Diptera eg Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria , Simulium spp., Stomoxys calcitrans, Tipula paludosa.
From the order of Lepidoptera eg Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.
From the order of the Siphonaptera, for example, Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.
From the order of the Hymenoptera, for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.
From the order of Anoplura eg Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis.
From the order of Heteroptera eg Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.

The Application is in aerosols, non-pressurized sprays, e.g. Pump and atomizer sprays, Fog machines, foggers, foams, Gels, evaporator products with evaporator plates made of cellulose or plastic, Liquid evaporators, Gel and membrane evaporators, propeller-driven evaporators, energy-free or passive evaporation systems, moth papers, moth bags and Moth gels, as granules or dusts, in straw baits or Bait stations.

According to the invention, all plants and parts of plants can be treated. In this context, plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants). Crop plants may be plants produced by conventional breeding and optimization methods or by biotechnological and gen technological methods or combinations of these methods can be obtained, including transgenic plants and including those protected by plant breeders' rights or non-protectable plant varieties. Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, by way of example, leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and roots, tubers and rhizomes , The plant parts also include crops as well as vegetative and generative propagation material, for example cuttings, tubers, rhiomes, offshoots and seeds.

As already mentioned above, can According to the invention, all plants and their parts are treated. In a preferred embodiment are wild or by conventional biological breeding methods, such as crossing or protoplast fusion obtained plant species and Treated plant varieties and their parts. In a further preferred embodiment are transgenic plants and plant varieties produced by genetic engineering Methods if necessary in combination with conventional methods were obtained (Genetically Modified Organisms) and their parts treated. The term "parts" or "parts of plants" or "plant parts" has been explained above.

Especially plants according to the invention are preferred the respective commercial or plant varieties in use.

ever according to plant species or plant varieties, their location and growth conditions (Floors, Climate, vegetation period, nutrition) can by the treatment according to the invention also superadditives ("Synergistic") effects occur. For example, reduced application rates and / or expansions of the Spectrum of action and / or an increase in the effect of the invention can be used Substances and agents, better plant growth, increased tolerance across from high or low temperatures, increased tolerance to dryness or against water or soil salt content, increased flowering efficiency, easier harvest, Acceleration of maturity, higher Crop yields, higher quality and / or higher Nutritional value of Harvested products, higher Shelf life and / or workability of the harvested products possible, beyond the actually expected Go beyond effects.

The preferred plants or plant cultivars to be treated according to the invention include all plants which have obtained genetic material by the genetic engineering modification which gives these plants particularly advantageous valuable properties ("traits") Examples of such properties are better plant growth. increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms, increased flowering efficiency, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or machinability Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, such as insects, mites, phytopathogenic fungi, bacteria and / or viruses and increased tolerance of the plants to certain herbicidal substances. Examples of transgenic plants include the important crops such as cereals (wheat, rice), corn, soy, potato, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soy, potato, cotton and rapeseed should be highlighted. Traits that are particularly emphasized are the increased defense of the plants against insects by toxins formed in the plants, in particular those which are produced by the genetic material from Bacillus thuringiensis (for example by the genes CryIA (a), CryIA (b), CryIA (c), CryIIA, CryIIIA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CryIF and their combinations) in the plants (hereafter "Bt plants"). Traits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene). Each having the desired properties ( "traits") conferring genes may also occur in combinations with one another in the transgenic plants. Examples of "Bt plants" are maize varieties, cotton varieties, soya bean varieties and potato varieties which are sold under the trade names YIELD GARD ^® (for example maize , cotton, soybeans), KnockOut ^® (for example maize), StarLink ^® (for example maize), Bollgard ^® (cotton), NuCOTN ^® (cotton) and NewLeaf ^® (potato). Examples of herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties which are resistant under the trade names Roundup Ready ^® (tolerance to glyphosate, for example maize, cotton, soya bean), Liberty Link ^® (tolerance to phosphinotricin, for example oilseed rape), IMI ^® (tolerance Imidazolinone) and STS ^® (tolerance to sulfonylureas such as corn) are sold. Herbicide-resistant (conventionally grown on herbicide tolerance) plants are also the varieties marketed under the name Clearfield ^® (eg corn) mentioned. Of course, these statements also apply to plant varieties developed or to be marketed in the future with these or future developed genetic properties ( "Traits").

The listed Plants can particularly advantageous according to the invention with the active substance mixtures according to the invention be treated. The preferred ranges given above for the mixtures apply also for the treatment of these plants. Particularly emphasized is the Plant treatment with the mixtures specifically mentioned herein.

The good insecticidal and fungicidal action of the active compound combinations according to the invention is apparent from the examples below. While the individual active ingredients weaknesses in their effect show the combinations have an effect over a simple effect summation goes beyond.

One synergistic effect is always with insecticides and fungicides then before, if the insecticidal or fungicidal action of the drug combinations is larger as the sum of the effects of the individually applied active ingredients.

The expected insecticidal or fungicidal activity for a given combination of two drugs can be calculated according to SR Colby ("Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 1 67, 15, 20-22) as follows:
If
X means the degree of killing or efficiency, expressed in% of the untreated control, when using the active substance A in an application rate of m ppm or g / ha,
Y means the degree of killing or efficiency, expressed in% of the untreated control, when using the active substance B in an application rate of n ppm or g / ha, and
E means the degree of killing or efficiency, expressed in% of the untreated control, when using the active compounds A and B in application rates of m and n ppm or g / ha,
then

there becomes the kill rate or efficiency in% determined. It means 0% kill rate or Efficiency, which corresponds to that of the control, while a kill rate of 100% means that all animals are dead and an efficiency 100% means that no infestation is observed.

is the actual fungicidal or insecticidal action greater than calculated, so is the Combination in its effect superadditive, i.e. there is a synergistic effect. In this case, must the actual observed efficiency to be greater as the one from the above Formula calculated value for the expected efficiency (E).

Claims (10)

Active substance combinations containing (a) at least one active substance of group 1 according to formula (I)

wherein R is methyl or cyclopropyl, and (b) at least one drug selected from the following groups (2) to (24): Group (2) strobilurins of the general formula (II)

in which A ¹ for one of the groups

A ^{2 is} NH or O, A ^{3 is} N or CH, L is one of the groups

wherein the bond which is marked with an asterisk (*) is bound to the phenyl ring, R ^{11 is} in each case optionally mono- or disubstituted by identical or different chlorine, cyano, methyl or trifluoromethyl-substituted phenyl, phenoxy or pyridinyl, or 1- (4-chlorophenyl) pyrazol-3-yl or 1,2-propanedione bis (O-methyloxime) -1-yl; R ^{12 is} hydrogen or fluoro; Group (3) triazoles of the general formula (III)

in which Q is hydrogen or SH, m is 0 or 1, R ^{13 is} hydrogen, fluorine, chlorine, phenyl or 4-chlorophenoxy, R ^{14 is} hydrogen or chlorine, A ^{4 is} a direct bond, CH ₂ -, - (CH ₂ ) ₂ -, -O-, for * -CH ₂ -CHR ¹⁷ - or * -CH = CR ¹⁷ -, wherein the bond marked with * is linked to the phenyl ring, and R ¹⁵ and R ¹⁷ then together represent -CH ₂ -CH ₂ -CH [CH (CH ₃ ) ₂ ] - or -CH ₂ -CH ₂ -C (CH ₃ ) ₂ -, A ^{5 is} C or Si (silicon) , A ⁴ also represents -N (R ¹⁷ ) - and A ⁵ together with R ¹⁵ and R ^{16 also represents} the group C = NR ¹⁸ , where R ¹⁷ and R ¹⁸ then together represent the group

wherein the bond marked with * is connected to R ¹⁷ , R ^{15 is} hydrogen, hydroxy or cyano, R ^{16 is} 1-cyclopropylethyl, 1-chlorocyclopropyl, C ₁ -C ₄ -alkyl, C ₁ -C ₆ -hydroxyalkyl , C ₁ -C ₄ -alkylcarbonyl, C ₁ -C ₂ -haloalkoxy-C ₁ -C ₂ -alkyl, trimethylsilyl-C ₁ -C ₂ -alkyl, monofluorophenyl, or phenyl, R ¹⁵ and R ¹⁶ also together are -O-CH ₂ -CH (R ¹⁸ ) -O-, -O-CH ₂ -CH (R ¹⁸ ) -CH ₂ -, or -O-CH- (2-chlorophenyl) -, R ^{18 is} hydrogen, C ₁ -C ₄ -alkyl or bromine ; Group (4) sulfenamides of the general formula (IV)

in which R ^{19 is} hydrogen or methyl; Group (5) valine amides selected from (5-1) iprovalicarb (5-2) N '- [2- (4 - {[3- (4-chlorophenyl) -2-propynyl] oxy} -3-methoxyphenyl) ethyl] -N ² - (methylsulfonyl) -D-valinamide (5-3) Benthiavalicarb group (6) Carboxamides of general formula (V)

in which X is 2-chloro-3-pyridinyl, 1-methylpyrazol-4-yl which is substituted in the 3-position by methyl or trifluoromethyl and in the 5-position by hydrogen or chlorine, for 4-ethyl-2-ethylamino 1,3-thiazol-5-yl, for 1-methyl-cyclohexyl, for 2,2-dichloro-1-ethyl-3-methyl-cyclopropyl, for 2-fluoro-2-propyl, 3,4-dichloro isothiazol-5-yl, 5,6-dihydro-2-methyl-1,4-oxathin-3-yl, 4-methyl-1,2,3-thiadiazol-5-yl, 4,5-dimethyl-2 trimethylsilylthiophen-3-yl, 1-methylpyrrol-3-yl which is substituted in the 4-position by methyl or trifluoromethyl and in the 5-position by hydrogen or chlorine, or represents phenyl which is monosubstituted to trisubstituted, identical or different is substituted by chlorine, methyl or trifluoromethyl, Y is a direct bond, optionally substituted by chlorine, cyano or oxo substituted C ₁ -C ₆ alkanediyl (alkylene), C ₂ -C ₆ alkylenediyl (alkenylene) or thiophenediyl , Z is hydrogen, C ₁ -C ₆ -alkyl or the group

in which A ^{6 is} CH or N, R ^{20 is} hydrogen, chlorine, cyano, C ₁ -C ₆ -alkyl, by optionally single or double, identically or differently by chlorine or di (C ₁ -C ₃ -alkyl ) Amino carbonyl substituted phenyl, R ^{21 is} hydrogen, chlorine or isopropoxy, R ^{22 is} hydrogen, chlorine, hydroxy, methyl, trifluoromethyl or di (C ₁ -C ₃ alkyl) aminocarbonyl, R ²⁰ and R ²¹ also together * -CH (CH ₃ ) -CH ₂ -C (CH ₃ ) ₂ - or * -CH (CH ₃ ) -OC (CH ₃ ) ₂ -, wherein the bond marked with * is linked to R ²⁰ ; Group (7) Dithiocarbamates selected from (7-1) Mancozeb (7-2) Maneb (7-3) Metiram (7-4) Propyneb (7-5) Thiram (7-6) Zineb (7-7) Ziram Group (8) acylalanines of the general formula (VI)

in which * denotes a carbon atom in the R or S configuration, preferably in the S configuration, R ^{23 represents} benzyl, furyl or methoxymethyl; Group (9): anilino-pyrimidines of the general formula (VII)

in which R ^{24 is} methyl, cyclopropyl or 1-propynyl; Group (10): Benzimidazoles of the general formula (VIII)

in which R ²⁵ and R ^{26 are} each hydrogen or together are -O-CF ₂ -O-, R ^{27 is} hydrogen, C ₁ -C ₄ -alkylaminocarbonyl or 3,5-dimethylisoxazol-4-ylsulfonyl, R ²⁸ is chloro, methoxycarbonylamino, chlorophenyl, furyl or thiazolyl; Group (11): carbamates of the general formula (IX)

in which R ^{29 is} n- or isopropyl, R ^{30 is} di (C ₁ -C ₂ -alkyl) aminoC ₂ -C ₄ -alkyl or diethoxyphenyl, including salts of these compounds; Group (12): dicarboximides selected from (12-1) captafol (12-2) captan (12-3) folpet (12-4) iprodione (12-5) procymidone (12-6) vinclozolin group (13): guanidines selected from (13-1) dodine (13-2) guazatine (13-3) iminoctadine triacetate (13-4) iminoctadine tris (albesilate) group (14): imidazoles selected from (14-1) cyazofamide (14-2) prochlorazole (14-3) triazoxides (14-4) pefurazoate group (15): morpholines of general formula (X)

in which R ³¹ and R ^32, independently of one another, are hydrogen or methyl, R ^{33 is} C ₁ -C ₁₄ -alkyl (preferably C ₁₂ -C ₁₄ -alkyl), C ₅ -C ₁₂ -cycloalkyl (preferably C ₁₀ -C ₁₂₎ Cycloalkyl), phenyl-C ₁ -C ₄ -alkyl, which may be substituted in the phenyl moiety by halogen or C ₁ -C ₄ -alkyl, or by acrylyl which is substituted by chlorophenyl and dimethoxyphenyl; Group (16): Pyrroles of General Formula (XI)

in which R ^{34 is} chlorine or cyano, R ^{35 is} chlorine or nitro, R ^{36 is} chlorine, R ³⁵ and R ³⁶ also together are -O-CF ₂ -O- stand; Group (17): (thio) phosphonates selected from (17-1) fosetyl-Al, (17-2) phosphonic acid, (17-3) tolclophos-methyl; Group (18): phenylethanamides of the general formula (XII)

wherein R ^{37 is} phenyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl or indanyl which is unsubstituted or substituted by fluorine, chlorine, bromine, methyl or ethyl; Group (19): Fungicides selected from (19-1) acibenzolar-S-methyl (19-2) chlorothalonil (19-3) cymoxanil (19-4) edifenphos (19-5) famoxadone (19-6) fluazinam (19 -7) Copper Oxychloride (19-8) Copper Hydroxide (19-9) Oxadixyl (19-10) Spiroxamine (19-11) Dithianone (19-12) Metrafenone (19-14) 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) one (19-15) sample azoles (19-16) isoprothiolanes (19-17) kasugamycin (19 -18) phthalides (19-19) ferric zone (19-20) tricyclazoles (19-21) cyprosulfamides (19-22) mandipropamide group (20): (thio) urea derivatives selected from (20-1) pencycuron (20- 2) thiophanate-methyl (20-3) thiophanate-ethyl group (21): amides of general formula (XIII)

in which A ^{7 is} a direct bond or -O-, A ^{8 is} -C (= O) NH- or -NHC (= O) -, R ^{38 is} hydrogen or C ₁ -C ₄ alkyl, R ^{39 is} C ₁ -C ₆ alkyl; Group (22): triazolopyrimidines of the general formula (XIV)

in which R ^{40 is} C ₁ -C ₆ -alkyl or C ₂ -C ₆ -alkenyl, R ^{41 is} C ₁ -C ₆ -alkyl, R ⁴⁰ and R ⁴¹ also together are C ₄ -C ₅ -alkanediyl ( Alkylene), which is monosubstituted or disubstituted by C ₁ -C ₆ alkyl, R ^{42 is} bromine or chlorine, R ⁴³ and R ^{47 are} independently hydrogen, fluorine, chlorine or methyl, R ⁴⁴ and R ^{46 are} independent of one another are hydrogen or fluorine, R ⁴⁵ represents hydrogen, fluorine or methyl, group (23): Iodochromones the general formula (XV)

in which R ^{48 is} C ₁ -C ₆ -alkyl, R ^{49 is} C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl or C ₂ -C ₆ -alkynyl; Group (24): biphenylcarboxamides of the general formula (XVI)

in which R ^{50 is} hydrogen or fluorine, R ^{51 is} fluorine, chlorine, bromine, methyl, trifluoromethyl, trifluoromethoxy, -CH = N-OMe or -C (Me) = N-OMe, R ^{52 is} hydrogen, fluorine, Chlorine, bromine, methyl or trifluoromethyl, Het is one of the following radicals Het1 to Het7:

R ^{53 is} iodine, methyl, difluoromethyl or trifluoromethyl, R ^{54 is} hydrogen, fluorine, chlorine or methyl, R ^{55 is} methyl, difluoromethyl or trifluoromethyl, R ^{56 is} chlorine, bromine, iodine, methyl, difluoromethyl or trifluoromethyl, R ^{57 is} methyl or trifluoromethyl. Composition according to Claim 1, containing the compound of the formula (Ia)

and at least one of the following compounds - azoxystrobin - fluoxastrobin - (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy} phenyl) -2 - (methoxyimino) -N-methylethanamide - trifloxystrobin - (2E) -2- (methoxyimino) -N-methyl-2- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) ethanamide - (2E) -2- (methoxyimino) -N-methyl-2- {2 - [(E) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide - orysastrobin - 5-methoxy-2-methyl-4- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) - 2,4-dihydro-3H-1,2,4-triazol-3-one - kresoxime-methyl-dimoxystrobin-picoxystrobin - Pyraclostrobin - Metominostrobin - Azaconazole - Etaconazole - Propiconazole - Difenoconazole - Bromuconazole - Cyproconazole - Hexaconazole - Penconazole - Myclobutanil - Tetraconazole - Flutriafol - Epoxiconazole - Flusilazole - Simeconazole - Prothioconazole - Fenbuconazole - Tebuconazole - Ipconazole - Metconazole - Triticonazole - Bitertanol - Triadimenol - Triadimefon - fluquinconazole - quinconazole - dichlofluanid - tolylfluanid - iprovalicarb - benthiavalicarb - 2-chloro-N- (1,1,3-trimethyl-indan-4-yl) nicotinamide - boscalid - furametpyr - 1-methyl-3-trifluoromethyl-1H pyrazole-4-carboxylic acid (3-p-tolylthiophene-2-yl) amide-ethaboxam-fenhexamide carpropamide - 2-chloro-4- (2-fluoro-2-methylpropionylamino) -N, N-dimethyl benzamide - fluopicolide - zoxamides - 3,4-dichloro-N- (2-cyanophenyl) isothiazole-5-carboxamide - carboxy - tiadinil - penthiopyrad - silthiofam - N - [2- (1,3 - dimethylbutyl) phenyl] -1 - Methyl 4- (trifluoromethyl) -1H-pyrrole-3-carboxamide - Flutolanil - N - [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide - N- {2- [3-chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2- (trifluoromethyl) benzamide - Mancozeb having the IUPAC name Manganese ethylenebis (dithiocarbamate) (polymeric) complex with zinc salt - Maneb - metiram having the IUPAC name Zinc ammoniate ethylenebis (dithiocarbamate) poly (ethylenethiuram disulphide) - propineb - thiram - zineb - ziram - benalaxyl - furalaxyl - Metalaxyl - Metalaxyl-M - Benalaxyl-M of the formula - Cyprodinil - mepanipyrim - Pyrimethanil - 6-chloro-5 - [(3,5-dimethylisoxazol-4-yl) sulfonyl] -2,2-difluoro-5H- [1 , 3] dioxolo [4,5-f] benzimidazole - Benomyl - Carbendazim - Chlorfenazole - Fuberidazole - Thiabendazole - Diethofencarb - Propamocarb - Propamocarb-hydrochloride - Propamocarb-Fosetyl - Captafol - Captan - Folpet - Iprodione - Procymidone - Vinclozolin - Dodine - Guazatine - iminoctadine triacetate - cyazofamide - prochloraz - triazoxide - pefurazoate - aldimorph - tridemorph - dodemorph - fenpropimorph - dimethomorph - fenpiclonil - fludioxonil - pyrroleine - fosetyl - Al - phosphonic acid - tolclofos-methyl - 2- (2,3-dihydro-1H- inden-5-yl) - N - [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide - N - [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) - 2- (5,6,7,8-tetrahydronaphthalen-2-yl) acetamide - 2- (4-chlorophenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide - 2- (4-bromophenyl) - N - [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide - 2- (4-methylphenyl) -N- [2- (3 , 4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide - 2- (4-ethylphenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide - Acibenzolar-S-methyl - chlorothalonil - cymoxanil - edifenphos - famoxadone - fluazinam - copper oxychloride - oxadixyl - spiroxamine - dithianone - metrafenone - 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) on - Probenazole - isoprothiolane - kasugamycin - phthalides ferimzone - tricyclazoles - N - ({4 - [(cyclopropylamino) carbonyl] phenyl} sulfonyl) -2-methoxybenzamide - 2- (4-chlorophenyl) -N- {2- [3-methoxy-4- ( prop-2-yn-1-yloxy) phenyl] ethyl} -2- (prop-2-yn-1-yloxy) acetamide - pencycuron - thiophanate-methyl - thiophanate-ethyl-fenoxanil-diclocymet-5-chloro-N- [(1S) -2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidin-7-amine - 5-chloro-N - [(1R) -1,2-dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidin-7-amine - 5-Chloro-6- (2-chloro-6-fluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine - 5-chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine - 2-butoxy-6-iodo-3-propyl benzopyran-4-one - 2-ethoxy-6-iodo-3-propyl-benzopyran-4-one - 6-iodo-2-propoxy-3-propyl-benzopyran-4-one - 2-but-2-ynyloxy 6-iodo-3-propyl-benzopyran-4-one - 6-iodo-2- (1-methyl-butoxy) -3-propyl-benzopyran-4-one - 2-but-3-enyloxy-6-iodo benzop yran-4-one - 3-butyl-6-iodo-2-isopropoxy-benzopyran-4-one - N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide - 3- (difluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1 '-biphenyl-2-yl} -1-methyl-1H-pyrazole-4-carboxamide - 3- (trifluoromethyl) -N- {3'-fluoro-4' - [(E) - (methoxyimino) methyl] -1 , 1'-biphenyl-2-yl} -1-methyl-1H-pyrazole-4-carboxamide - N- (3 ', 4'-dichloro-1,1'-biphenyl-2-yl) -5-fluoro 1,3-dimethyl-1H-pyrazole-4-carboxamide - N- (4'-chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (trifluoromethyl) -1 , 3-thiazole-5-carboxamide - N- (4'-chloro-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide - N - (4'-Bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide - 4- (difluoromethyl) -2-methyl-N - [4 '- (trifluoromethyl) -1,1'-biphenyl-2-yl] -1,3-thiazole-5-carboxamide. Composition according to Claim 1, containing the compound of the formula (Ib)

and at least one of the following compounds - azoxystrobin - fluoxastrobin - (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy} phenyl) -2 - (methoxyimino) -N-methylethanamide - trifloxystrobin - (2E) -2- (methoxyimino) -N-methyl-2- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) ethanamide - (2E) -2- (methoxyimino) -N-methyl-2- {2 - [(E) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide - orysastrobin - 5-methoxy-2-methyl-4- (2 - {[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) - 2,4-dihydro-3H-1,2,4-triazol-3-one - kresoxime-methyl-dimoxystrobin - picoxystrobin - pyraclostrobin - metominostrobin - azaconazole - Etaconazole - propiconazole - Difenoconazole - bromuconazole - cyproconazole - hexaconazole - penconazole - myclobutanil - tetraconazole - flutriafol - epoxiconazole - flusilazole - Simeconazole - prothioconazole - Fenbuconazole - tebuconazole - ipconazole - metconazole - triticonazole - bitertanol - triadimenol - triadimefon - fluquinconazole - quinconazole - dichlofluanid - tolylfluanid - iprovalicarb - benthiavalicarb - 2-chloro-N- (1,1,3-trimethyl-indan-4-yl) nicotinamide - boscalid - furametpyr - 1-methyl-3-trifluoromethyl -1H-pyrazole-4-carboxylic acid (3-p-tolyl-thiophen-2-yl) -amide - ethaboxam-fenhexamide carpropamide - 2-chloro-4- (2-fluoro-2-methylpropionylamino) -N, N dimethyl benzamide - fluopicolide - zoxamides - 3,4-dichloro-N- (2-cyanophenyl) isothiazole-5-carboxamide - carboxy - tiadinil - penthiopyrad - silthiofam - N - [2- (1,3-dimet butylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide - flutolanil - N - [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl 1H-pyrazole-4-carboxamide - N- {2- [3-chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2- (trifluoromethyl) benzamide - Mancozeb having the IUPAC name Manganese ethylenebis (dithiocarbamate) (polymeric) complex with zinc salt - Maneb - metiram having the IUPAC name Zinc ammoniate ethylenebis (dithiocarbamate) poly (ethylenethiuram disulphide) - propyneb - thiram - zineb - ziram - benalaxyl - furalaxyl - metalaxyl - metalaxyl-M - benalaxyl-M of the formula - cyprodinil - mepanipyrim - pyrimethanil - 6-chloro-5 - [(3,5-dimethylisoxazol-4-yl) sulfonyl] -2,2-difluoro-5H- [1,3] dioxolo [4,5-f] benzimidazole - benomyl - carbendazim - chlorfenazoles - fuberidazole - thiabendazole - diethofencarb - propamocarb - propamocarb-hydrochloride - propamocarb-fosetyl-captafol-captan-folpet-iprodione-procymidone-vinclozolin-dodine - guazatine - iminoctadine triacetate - cyazofamide - prochloraz - triazoxide - pefurazoate - aldimorph - tridemorph - dodemorph - fenpropimorph - dimethomorph - fenpiclonil - fludioxonil - pyrroline nitrate - fosetyl-Al - phosphonic acid - tolclofos-methyl - 2- (2,3-dihydroxy) 1H-inden-5-yl) - N - [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide - N - [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino ) -2- (5,6,7,8-tetrahydronaphthalen-2-yl) acetamide - 2- (4-chlorophenyl) -N- [2- (3,4-dimethoxyph enyl) ethyl] -2- (methoxyimino) acetamide - 2- (4-bromophenyl) - N - [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide - 2- (4-methylphenyl) - N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide - 2- (4-ethylphenyl) - N - [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide - acibenzolar-S-methyl-chlorothalonil-cymoxanil-edifenphos-famoxadone-fluazinam-copper oxychloride-oxadixyl-spiroxamine-dithianone-metrafenone-2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidine-4 ( 3H) on - sample azoles - isoprothiolanes - kasugamycin - phthalides ferimzone - tricyclazoles - N - ({4 - [(cyclopropylamino) carbonyl] phenyl} sulfonyl) -2-methoxybenzamide - 2- (4-chlorophenyl) -N- {2- [3-methoxy-4 - (prop-2-yn-1-yloxy) phenyl] ethyl} -2- (prop-2-yn-1-yloxy) acetamide - pencycuron - thiophanate-methyl - thiophanate-ethyl-fenoxanil-diclocymet-5-chloro N - [(1S) -2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) (1,2,4] triazolo [1,5-a] pyrimidin-7- amine - 5-chloro-N - [(1R) -1,2-dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidine-7 amine - 5-chloro-6- (2-chloro-6-fluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine - 5-chloro 6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine - 2-butoxy-6-iodo-3- propyl-benzopyran-4-one - 2-ethoxy-6-iodo-3-propyl-benzopyran-4-one - 6-iodo-2-propoxy-3-propyl-benzopyran-4-one - 2-but-2-one inyloxy-6-iodo-3-propyl-benzopyran-4-one - 6-iodo-2- (1-methyl-butoxy) -3-propyl-benzopyran-4-one - 2-but-3-e Nyloxy-6-iodo-benzopyran-4-one - 3-butyl-6-iodo-2-isopropoxy-benzopyran-4-one - N- (3 ', 4'-dichloro-5-fluoro-1,1'- biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide - 3- (difluoromethyl) -N- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1H-pyrazole-4-carboxamide - 3- (trifluoromethyl) -N- {3'-fluoro-4 '- [(E) - ( methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1H-pyrazole-4-carboxamide - N- (3 ', 4'-dichloro-1,1'-biphenyl-2-yl ) -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide - N- (4'-chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4 - (trifluoromethyl) -1,3-thiazole-5-carboxamide - N- (4'-chloro-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole -5-carboxamide - N- (4'-bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide - 4- (difluoromethyl) -2-methyl-N- [4 '- (trifluoromethyl) -1,1'-biphenyl-2-yl] -1,3-thiazole-5-carboxamide. Use of mixtures as in claim 1, 2 or 3 defined, to combat animal pests. Use of a composition according to claim 1, 2 or 3 for the treatment of seeds. Use of compositions according to claim 1, 2 or 3 for the treatment of transgenic plants. Use of compositions according to claim 1, 2 or 3 for the treatment of seeds of transgenic plants. Seed having a composition according to claim 1, 2 or 3 was treated. Method of control of unwanted animal pests and / or phytopathogenic fungi, characterized in that you drug combinations according to claim 1, 2 or 3 on the unwanted animal pests and / or their habitat and / or seed. Process for the preparation of insecticidal and acaricidal Means, characterized in that mixtures as claimed 1, 2 or 3, with extenders and / or surface-active Mixed substances.