DE102004039722A1 - Perfume, useful in the application of washing- or cleaning agents, comprises soda-containing particles - Google Patents

Abstract

Perfume (A) (exhibiting soda-containing particle) comprising 0.2-6 (preferably 2-2.5) mol water/mol soda of soda containing particle, is new. Independent claims are also included for: (1) finished product comprising soda-containing particle; (2) preparing soda-containing particle comprising producing fine-particles of soda-containing particles optionally containing carrier materials (where the amount of soda-containing particle is 0.2-4 (preferably 2-2.5) mol water/mol soda, applying at least (A) on the soda-containing particles, where the soda-containing particles absorbs (A) and the obtained 30-70 (preferably 0.5-20) %, by weight of particles exhibits (A); and (3) soda-containing particle obtained by the method of (2).

Description

The present invention relates to perfume containing soda-containing particles, and a process for their preparation. Furthermore, the invention relates to the Use of perfume containing soda-containing particles in dry neutralization. Furthermore The invention relates to a finished product comprising perfume soda-containing particles.

Usually become particulate Agents, such as washing, cleaning or care products by spray drying method produced. In the production of powdered detergents is in a watery first step Slurry "slurry" formed. The slurry contains thermally stable detergent ingredients that are among the Conditions of spray drying essentially neither volatilize still decompose like surfactants and builders. Subsequently, will the slurry over Pumping in a spray tower promoted and over in the upper part of the spray tower located nozzles sprayed. By means of ascending air with high temperature, the slurry is dried and the adhering water evaporates, leaving the detergent ingredients at the outlet of the tower, where temperatures of 80-120 ° C occur as a powder. The powder will then become more temperaturlabile ingredients such as bleach, nonionic surfactants or Perfumes, mixed.

devices for spray drying aqueous compositions are known in the art known. Often Devices used are, for example, spray towers with atomizing nozzles, which especially in liquid Starting materials, such as solutions, Suspensions or melts to provide a powdered product be used. Here, the aqueous liquid is usually atomized with pressure nozzles and then dries with hot gas in cocurrent or countercurrent. Subsequently, the dry product separated by cyclo or filter. If a melt is atomized and frozen in cold gas, this is called a Prill Tower.

Further known spray dryers are disk towers. These are - like also the nozzle towers - short-term dryers. They use for atomization rotating discs and are compared to the nozzle tower of squat design. The advantage of the atomizer disk is their insensitivity to blockage of the "nozzles" and highly variable liquid flow rates.

Known are as well spray dryer with integrated fluidized bed. By installing a fluidized bed at the bottom of the spray tower The product can be dried and sifted there. The drying gas with the fine dust is, for example, in the upper part of the tower deducted at the top of the tower and the fine dust after separation in the tower recycled. Therefore can also processed comparatively sticky and slowly drying starting materials become. The product obtained is readily dispersible particles, the bigger and thus mostly dustier as the powders of the nozzle and in particular the disk towers are.

in the further meaning are also to be counted among the spray dryers Fluidized bed spray granulators ("Agglomeration dryer"), the production from granules in the range of 0.3 mm to several mm of atomizable Solutions, suspensions and melting serve. For atomization become common Two-fluid nozzles used. The product is usually compact and abrasion resistant and by a relatively high bulk density characterized. The dissolution rate is therefore lower compared to other spray-drying products. Such a granulator can also be used for coating granules, so-called "coating", then used it is usually operated discontinuously.

The international patent applications WO 00/77148 (EP-A1 1 10 48 03), WO 00/7149 (EP-A1 1 10 48 04), WO 00/77158 (EP-A1 1 10 48 06), WO 00/23560 (EP-A1 1 04 11 39), WO 98/10052 (EP-A1 0 93 62 69), to the here for example, describe in full Granules as carrier material of surfactants for Laundry detergent.

The have known in the prior art detergents and cleaners usually substances on, during the manufacturing process in their acid form incurred and therefore with suitable neutralizing agents in their Alkaline or alkaline earth metal salts must be transferred.

So fall in particular anionic surfactants, phosphonates and soaps, the used as raw materials, in their acid form and must with suitable neutralizing agents are converted into their alkali or alkaline earth metal salts.

this Neutralization step can be done with solutions of alkali metal hydroxides carry out. In the neutralization with aqueous Alkalis fall surfactant salts in the form of aqueous formulations at. The neutralization by means of alkaline solutions has the disadvantage that one the solutions, usually water, by means of high energy and time use again remove got to. Especially with perfume-containing preparation forms leads the Use of heat to a loss of fragrance due to evaporation and / or decomposition. About that In addition, there is an increased risk of explosion, especially with volatile perfumes in the drying treatment with heat.

In addition to the neutralization step with alkaline solutions, there is the so-called dry neutralization process. Dry neutralization processes in which sulfonic acids are neutralized and granulated are described in US Pat EP 555,622 (Procter & Gamble). According to the teaching of this document, the neutralization of anionic surfactant acids in a high-speed mixer by an excess of finely divided neutralizing agent having an average particle size below 5 ppm instead.

A similar Method that is also performed in a high-speed mixer and at the 2 to 20 ppm milled sodium carbonate as a neutralizing agent is described in W098120104 (Procter & Gamble).

adversely is that with such usually used detergents and cleaners unwanted odor impairments or changes may occur, so that considerable efforts were made, odor changes dry-neutralized detergents and cleaners. For example, the detergent and cleaner components with high degrees of purity processed to an odor impairment or change to avoid the washing and cleaning agents. Furthermore, washing and detergents stored in moisture proof containers and the like. Ultimately, these efforts do not have the desired effect Success led, since it despite these measures again and again to odor impairments or changes of washing and cleaning agents comes.

adversely is also that high proportions by weight of copolymer and silicate as an aqueous component only partially or with considerable Reduction of system performance in a fluidized bed to a detergent granules, as dry neutralizer, can apply.

task the present invention has been perfume-containing particles, preferably with a high perfume weight concentration, preferred without the use of high-speed mixers, available too whose odor, i. Fragrance note or perfume note during the Production and storage are not adversely affected.

object The invention in a first embodiment are therefore perfume having soda-containing particles, characterized in that the soda-containing particles 0.2 mole to 6 moles of water per mole of soda, preferably 0.5 mole to 3.5 moles of water per mole of soda, more preferably 1 mole to 3 moles of water per mole of soda, more preferably 1.5 moles to 2.75 moles of water per mole of soda and most preferably 2 moles to 2.5 moles of water each Contain mol soda.

advantageously, these particles have from 10% to 70% by weight of soda and 0.5% by weight to 20% by weight of perfume, based on the total weight of the perfume having soda-containing particles. It is further preferred that the particles at least 20 wt .-%, but in particular at least 30 wt .-% Soda, based on the total weight of the soda-containing perfume Particles, included. The soda serves in particular as a carrier material.

• – 35 Gew.-% bis 65 Gew.-% Soda, besonders bevorzugt 40 Gew.-% bis 60 Gew.-% Soda und am meisten bevorzugt 45 Gew.-% bis 55 Gew.-% Soda; und/oder
• – 1 Gew.-% bis 15 Gew.-% Parfum, besonders bevorzugt 2 Gew.-% bis 10 Gew.-% Parfum und am meisten bevorzugt 3 Gew.-% bis 5 Gew.-% Parfum,

bezogen auf das Gesamtgewicht der sodahaltigen Partikel.The soda-containing particles according to the invention preferably comprise:

• From 35% to 65% by weight of soda, more preferably from 40% to 60% by weight of soda, and most preferably from 45% to 55% by weight of soda; and or
• From 1% by weight to 15% by weight of perfume, more preferably from 2% by weight to 10% by weight of perfume and most preferably from 3% by weight to 5% by weight of perfume,

based on the total weight of the soda-containing particles.

olfactory impairments or changes mean in the sense of this invention that a change the fragrance note or the perfume note of perfume containing soda-containing Particle does not change or at least does not change significantly. The review of Scent becomes human sensory by preferably 10 adult subjects carried out.

Surprisingly was found that the aforementioned disadvantages by the use according to the invention from mainly soda-containing particles containing at least one perfume in preferably high concentration, avoid.

Without being committed to a particular theory is believed that in the case of changing Fragrance notes possible acid nests react chemically in dry neutralizers with fragrances, since in the manufacture of dry neutralizers inclusions of unneutralized acids, so-called acid esters, not completely exclude. Due to a chemical reaction of such acid esters with fragrances or Perfume mixtures, such as perfume, it comes to one, if only minor, chemical decomposition of perfume with the formation of undesirable smelling fragrances, what a change the fragrance note or Parfumnote leads.

The term "perfume" in the sense of this invention Formation is at least one perfume, preferably perfume mixture of at least 2 fragrances, preferably up to 10 fragrances. Optionally, the perfume may also have more than 10 fragrances.

• – lineare Alkylbenzolsulfonat/e (LAS), vorzugsweise macht der Gewichtsanteil linearer Alkylbenzolsulfonate ≥ 0 Gew.-% und ≤ 25 Gew.-%, vorzugsweise ≥ 5 Gew.-% und ≤ 15 Gew.-%, weiter bevorzugt ≥ 5 Gew.-% und ≤ 10 Gew.-%; und/oder
• – Niotensid, vorzugsweise macht der Gehalt an Niotensid 1 Gew.-% bis 30 Gew.-% Niotensid, vorzugsweise 5 Gew.-% bis 20 Gew.-% Niotensid, besonders bevorzugt 10 Gew.-% bis 18 Gew.-% Niotensid und am meisten bevorzugt 14 Gew.-% bis 17 Gew.% % Niotensid;

bezogen auf das Gesamtgewicht der sodahaltigen Partikel, aus wobei die Gewichtsgehalte der Trägermaterialien der sodahaltigen Partikel einschließlich der Gewichtsgehalte von Parfum sowie weiterer Zusätze so gewählt sind, dass diese 100 Gew.-% nicht übersteigen.The soda-containing particles may also comprise surfactants, preferably selected from the group comprising:

• Linear alkylbenzene sulphonate (LAS), preferably the proportion by weight of linear alkylbenzenesulphonates is ≥0% by weight and ≤25% by weight, preferably ≥5% by weight and ≤15% by weight, more preferably ≥5% by weight. % and ≦ 10% by weight; and or
• Nonionic surfactant, preferably the content of nonionic surfactant is from 1% to 30% by weight of nonionic surfactant, preferably from 5% by weight to 20% by weight of nonionic surfactant, more preferably from 10% by weight to 18% by weight of nonionic surfactant and most preferably from 14% to 17% by weight of nonionic surfactant;

based on the total weight of the soda-containing particles, wherein the weight contents of the carrier materials of the soda-containing particles, including the weight contents of perfume and other additives are chosen so that they do not exceed 100 wt .-%.

It is possible, too, the soda-containing particles are linear alkyl benzene sulphonate (LAS) can have Preferably, the proportion by weight of linear alkylbenzenesulfonates ≥ 0 wt .-% and ≦ 25% by weight, preferably ≥ 5 Wt .-% and ≤ 15 wt .-%, more preferably ≥ 5 Wt .-% and ≤ 10 wt .-% and most preferably 0% by weight and ≦ 5% by weight, based on the total weight the soda-containing particles make up.

The soda-containing according to the invention However, particles are preferred except at least one nonionic surfactant, no further surfactants such as anion, cation and / or zwitterionic surfactants. Especially preferred are the soda-containing ones according to the invention Particles free of surfactants.

The the aforementioned invention, at least Parfum containing soda-containing particles may, among others, at least have one of the following advantages.

The soda-containing according to the invention Particles can be loaded with high perfume or perfume fractions, the soda being the liquid one Perfume or the liquid Perfume binds so that a reaction with acidic nests in the dry neutral prevents which leads to an odor stability of these particles. Especially prevents a loading of up to 20 wt .-% non-aqueous liquid components, such as perfumes or perfume, the soda-containing particles undesirable reactions these components with other ingredients in the finished product.

For example can these particles have significantly reduced adhesive properties, even if these soda-containing particles contained high levels of perfume have, for example, in improved flow properties of Particles and in particular of the finished product containing these particles expresses.

Advantageous is also that is filler components such as sodium sulfate substantially or completely due to the optimized Substituting water binding to soda.

One Another advantage of the inventive at least one perfume having soda-containing particles is that, if any, only one at most have a low tendency to form agglomerates.

It was further found that the inventive at least a perfume having soda-containing particles a high dissolution rate, improved flowability, have reduced sedimentation and / or low clump test values can. In particular, at least according to the invention a perfume containing soda-containing high-bulk particle a sufficiently good flowability can be observed.

Yet An advantage is that the invention at least one perfume having soda-containing particles practically do not tend to a so-called "cluster formation" what the Avoids danger of gelling. This is advantageous as a Greater to increased Residues in the flushing chamber and / or Detergent residues on with washed fabrics can. It should be emphasized that such a gag already by a plurality of and / or a few surfactant-related adhesives not according to the invention Particles can be caused.

The soda-containing particles can as a direct spray-drying product present, then at least one perfume are applied can. In the present invention is under a direct Spray drying product a product understood by spray drying without further treatment is obtained.

The soda-containing particles can as tower powder, preferably overdried Tower powder, present, then applied to the at least one perfume becomes.

Although surfactant particles are known to have a poor dissolution kinetics, as surfactant are usually tacky and agglomerate into larger particles, it has now been found that the soda-containing particles according to the invention having at least one perfume or no significantly lower tendency to form agglomerates together. Therefore, soda-containing particles having at least one perfume according to the invention may preferably be present as primary fine-particulate surfactant particles and / or secondary soda-containing particles. Primary soda-containing particles of the present invention are particles which do not agglomerate with themselves into larger diameter particles, although one would expect this due to the perfume contents. Thus, primary soda-containing particles containing perfume according to the invention are discrete particles.

On the other hand are secondary perfume of the invention containing soda-containing particles to particles that due to their Perfume conditional adhesive Properties under magnification of the Diameter to larger particles agglomerate.

Of the Proportion of primary and secondary at least one perfume, in particular perfume, having soda-containing Particles can be of different heights. For example, at least 10% by weight, preferably at least 30% by weight, preferably at least 50% by weight, more preferably at least 70% by weight, and particularly preferably at least 90% by weight of the soda-containing particles as the primary soda-containing Particles, based on the total weight of the soda-containing particles, available.

It was found to have an adhesiveness, especially on the surface of the soda-containing according to the invention Particles can significantly or even completely reduce by the weight fraction of carrier material the soda-containing particle as selected below.

• – ≥ 0 Gew.-% bis 20 Gew.-% Silikat, besonders bevorzugt 1 Gew.-% bis 15 Gew.-% Silikat und am meisten bevorzugt 5 Gew.-% bis 10 Gew.-% Silikat; und/oder
• – 1 Gew.-% bis 40 Gew.-% Polymer, besonders bevorzugt 5 Gew.-% bis 30 Gew.-% Polymer und am meisten bevorzugt 10 Gew.-% bis 20 Gew.-% Polymer; und/oder
• – ≥ 0 Gew.-% bis 5 Gew.-% Phosphonat, besonders bevorzugt 0,01 Gew.-% bis 2 Gew.-% Phosphonat und am meisten bevorzugt 0,5 Gew.-% bis 1 Gew.-% Phosphonat; und/oder
• – ≥ 0 Gew.-% bis 30 Gew.-% Phosphat, besonders bevorzugt 5 Gew.-% bis 25 Gew.-% Phosphat und am meisten bevorzugt 10 Gew.-% bis 20 Gew.-% Phosphat; und/oder
• – ≥ 0 Gew.-% bis 50 Gew.-% Sulfat, besonders bevorzugt 5 Gew.-% bis 35 Gew.-% Sulfat und am meisten bevorzugt 10 Gew.-% bis 25 Gew.-% Sulfat; und/oder
• – ≥ 0 Gew.-% bis 5 Gew.-% Seife, besonders bevorzugt 0,01 Gew.-% bis 3 Gew.-% Seife und am meisten bevorzugt 0,05 Gew.-% bis 1 Gew.-% Seife; wobei

die Gewichtsgehalte der Trägermaterialien der sodahaltigen Partikel einschließlich der Gewichtsgehalte von Parfum sowie gegebenenfalls weiterer Zusätze so gewählt sind, dass diese 100 Gew.-% nicht übersteigen.The soda-containing particles according to the invention may comprise additional carrier materials selected from the group comprising:

• - ≥ 0 wt .-% to 20 wt .-% silicate, particularly preferably 1 wt .-% to 15 wt .-% silicate and most preferably 5 wt .-% to 10 wt .-% silicate; and or
• From 1% to 40% by weight of polymer, more preferably from 5% to 30% by weight of polymer, and most preferably from 10% to 20% by weight of polymer; and or
• - ≥ 0 wt .-% to 5 wt .-% phosphonate, particularly preferably 0.01 wt .-% to 2 wt .-% phosphonate and most preferably 0.5 wt .-% to 1 wt .-% phosphonate; and or
• - ≥ 0 wt .-% to 30 wt .-% phosphate, particularly preferably 5 wt .-% to 25 wt .-% of phosphate and most preferably 10 wt .-% to 20 wt .-% of phosphate; and or
• - ≥ 0 wt .-% to 50 wt .-% sulfate, more preferably 5 wt .-% to 35 wt .-% sulfate, and most preferably 10 wt .-% to 25 wt .-% sulfate; and or
• - ≥ 0 wt .-% to 5 wt .-% soap, particularly preferably 0.01 wt .-% to 3 wt .-% soap and most preferably 0.05 wt .-% to 1 wt .-% soap; in which

the weight contents of the carrier materials of the soda-containing particles, including the weight contents of perfume and, if appropriate, further additives are chosen such that they do not exceed 100% by weight.

It may be preferred that the total weight fraction (wt .-%) of support material, exceeds the total weight fraction (wt.%) of perfume, preferably at least by a factor of 1.5, preferably at least by a factor of 2 and even more more preferably at least by a factor of 3 to 5.

Around a sufficiently high capacity of perfume by means of the soda-containing To ensure particles are the usable carrier materials really important. Suitable carrier materials may be, for example at least one silicate, wherein the silicate is selected from the group comprising amorphous sodium silicates, aluminosilicates, in particular zeolites, preferably zeolite A, zeolite P, zeolite X, swellable Phyllosilicates, montmorillonites and / or bentonite.

suitable support materials can but also comprise at least one polymer, in particular homopolymer, wherein the polymer is selected from the group comprising polycarboxylate, polyacrylate or wherein the polymer, for example, a copolymer of acrylic acid with methacrylic acid, acrylic acid or methacrylic acid with maleic acid is.

One usable according to the invention Polymer, in particular homopolymer, preferably has a molecular weight of 500 g / mol to 20,000 g / mol, and preferably from 1,000 to 20,000 g / mol on. But it is also possible that the copolymer is a molecular weight from 500 to 2,000,000 g / mol, preferably one molecular weight of 1,000 to 1,000,000 g / mol, more preferably 10,000 molecular weight to 500,000 g / mol and particularly preferably a molecular weight of 15,000 to 50,000 g / mol.

Further suitable carrier materials are soaps, wherein preferably at least one soap of the carrier material is selected from the group comprising saturated fatty acid soaps, in particular salts of lauric acid, myristic acid, palmitic acid, stearic acid, hydrogenated erucic acid and / or behenic acid. Other preferred soap (s) are formed from natural soaps, especially coconut, palm kernel or tallow, derived soap mixtures, the soaps preferably in the form of their sodium, potassium and / or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine, may be present.

• – Trimethylenphosphonsäure;
• – Hydroxyethyliden-1,1-diphosphonsäure;
• – Ethylendiamintetramethylenphosphonsäue;
• – Hexamethylendiamintetramethylenphosphonsäure;
• – Diethylentriaminpentamethylenphosphonsäure;
• – Polyaminomethylenphosphonsäure;
• – Hexamethylentriaminpentamethylenphosphonsäure;
• – Phosphonobutantricarboxylsäure; und/oder
• – neutral-Salze der vorgenannten Phosphonate.

According to the invention, at least one phosphonate can also be used as the carrier material. Suitable phosphonates are, for example, the compounds mentioned below:

• Trimethylene phosphonic acid;
• Hydroxyethylidene-1,1-diphosphonic acid;
• Ethylenediamine tetramethylenephosphonic acid;
• Hexamethylenediamine tetramethylenephosphonic acid;
• Diethylenetriaminepentamethylenephosphonic acid;
• - polyaminomethylenephosphonic acid;
• Hexamethylenetriaminepentamethylenephosphonic acid;
• - phosphonobutane tricarboxylic acid; and or
• Neutral salts of the abovementioned phosphonates.

The Phosphonic / phosphonates can as aqueous solution present and so as a carrier material the other carrier materials be added.

According to the invention can as Carrier material phosphate be used, wherein at least one phosphate of the carrier material selected is from the group comprising pentasodium triphosphate, pyrophosphates, Orthophosphates and / or alkali metal phosphates, in particular Sodium and potassium salts of various phosphoric acids especially are preferred.

According to the invention can as Substrate also at least one sulfate, for example selected from the group of alkali metal sulphates, especially sodium sulfate can be used.

At least according to the invention A perfume-containing soda-containing particles may have a Having perfume or perfume concentration gradients, wherein the perfume or perfume concentration, expressed in weight percent, in Towards the particle core can decrease.

According to the invention preferred is when the outer upper surface the inventive at least a perfume or perfume containing soda-containing particles freely of perfume is. Since the carrier material used is the particles absorbent, is on the soda-containing particles applied perfume or perfume absorbed by the particles into the interior of the particles.

In addition, the at least according to the invention having a perfume or perfume containing soda-containing particles support material be aftertreated by the surface with carrier material or other soda-containing Powdered off components so as to obtain a particle surface, which have no or virtually no adhesive properties. As components for the aftertreatment can be solids, preferably alkali metal carbonates, Zeolite, silica, Citrate, urea or mixtures thereof, in particular in quantities from 2 to 15 wt .-%, based on the total weight of the aftertreated Products, use.

Of the Perfume fraction or perfume fraction in% by weight, based on the total weight the soda-containing invention Particles, on the outer surface according to the invention soda-containing Particles ≥ 0 Wt .-% to at most 1 wt .-%, preferably ≥ 0.01 wt .-% to 0.5 wt .-% and preferably ≥ 0 Wt .-% and ≤ 0.02 Make up wt .-%.

The soda-containing according to the invention Particles can have a low water content. It can thus be advantageous be so-called overdried To supply soda-containing particles with perfume or perfume. perfume or perfume, for example, by spraying on soda-containing particles and / or by mixing perfume or perfume with soda-containing particles be applied. The soda-containing particles according to the invention can be used in large quantities Absorb or absorb perfume or perfume.

Around the inventively high absorption capacity of perfume or to ensure perfume, it is necessary that the soda-containing particles 0.2 mole to 6 moles of water per mole of soda, preferably 0.5 Mol to 3.5 moles of water per mole of soda, more preferably 1 mole to 3 Mol of water per mole of soda, more preferably 1.5 moles to 2.75 moles of water per mole of soda, and most preferably from 2 moles to 2.5 moles of water per mole Soda included. The particles have a dry surface and are free-flowing.

Silicate according to the invention containing soda-containing particles can be 0.2 mol to 4 moles of water per mole of soda, preferably 0.5 mole to 1.5 moles of water per mole of soda and most preferably from 0.75 moles to 1 mole of water per mole of soda.

The soda-containing particles according to the invention may in particular have a water content of ≥0% by weight and ≤30% by weight, preferably ≥5% by weight and ≤25% by weight, more preferably 10% by weight and ≤15% by weight. -%, and most preferably ≥ 4 wt .-% and ≤ 6 wt .-%, based on the total weight of the soda-containing particles, comprise, based on the total weight of the soda-containing particles. However, the water content of the soda-containing particles can also be ≥ 5% by weight and ≦ 6 Make up wt .-%.

According to the invention, particles or mixtures of particles having a different composition of carrier materials, also referred to as compound or agglomerates, are suitable for receiving perfume or perfume which preferably comprise on carrier material:
16% by weight of silicate, 60% by weight of soda and 24% by weight of water; and or
22% by weight of silicate, 56% by weight of soda and 22% by weight of water; and or
10% by weight of silicate, 37% by weight of sulfate, 38% by weight of sodium carbonate and 15% by weight of water; and or
16% by weight of silicate, 34% by weight of sulfate, 36% by weight of soda and 14% by weight of water; and or
5% by weight of polyacrylate, 6% by weight of silicate, 38% by weight of sulfate, 37% by weight of sodium carbonate and 14% by weight of water; and or
6% by weight of polyacrylate, 7% by weight of silicate, 38% by weight of sulfate, 35% by weight of sodium carbonate and 14% by weight of water; and or
13% by weight of polyacrylate, 37% by weight of sulfate, 35% by weight of sodium carbonate and 15% by weight of water; and or
18% by weight of polyacrylate, 36% by weight of sulfate, 34% by weight of soda and 12% by weight of water; and or
11% by weight of polyacrylate, 39% by weight of sulfate, 36% by weight of sodium carbonate and 14% by weight of water; and or
16% by weight of polyacrylate, 37% by weight of sulfate, 36% by weight of sodium carbonate and 11% by weight of water.

In the context of the present invention, "d ₅₀ " is understood to mean that 50% of the soda-containing particles according to the invention have a smaller diameter and 50% of the soda-containing particles according to the invention have a larger diameter.

It may be preferred according to the invention that the soda-containing particles have a particle diameter D ₅₀ of 0.01 mm to 2 mm, preferably 0.02 mm to 1 mm and particularly preferably from 0.05 to 0.4 mm.

• – ≥ 0 bis 30 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von ≥ 1,6 mm,
• – 2 bis 5,5 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 1,6 mm bis 1,25 mm,
• – 1 bis 3,5 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 1,25 mm bis 1,0 mm,
• – 1 bis 3,5 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 1,0 mm bis 0,8 mm,
• – 1 bis 4,5 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 0,8 mm bis 0,63 mm,
• – 2 bis 28 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 0,63 mm bis 0,4 mm,
• – 22 bis 57 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 0,4 mm bis 0,2 mm,
• – 2 bis 34 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 0,2 mm bis 0,1 mm,
• – > 0 bis 10 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 0,1 mm bis 0,63 mm,

bezogen auf das Gesamtgewicht der sodahaltigen Partikel, aufweisen, wobei die jeweiligen Gewichtsanteile der sodahaltigen Partikel so gewählt sind, dass diese zusammen maximal 100 Gew.-% ausmachen.An advantageous embodiment of the soda-containing particles according to the invention has, for example, the following particle size distribution, wherein:

• - ≥ 0 to 30 wt .-% of the soda-containing particles has a particle diameter of ≥ 1.6 mm,
• From 2 to 5.5% by weight of the soda-containing particles have a particle diameter of from <1.6 mm to 1.25 mm,
• From 1 to 3.5% by weight of the soda-containing particles have a particle diameter of from <1.25 mm to 1.0 mm,
• From 1 to 3.5% by weight of the soda-containing particles have a particle diameter of from <1.0 mm to 0.8 mm,
• From 1 to 4.5% by weight of the soda-containing particles have a particle diameter of from <0.8 mm to 0.63 mm,
• 2 to 28% by weight of the soda-containing particles have a particle diameter of <0.63 mm to 0.4 mm,
• From 22 to 57% by weight of the soda-containing particles have a particle diameter of from <0.4 mm to 0.2 mm,
• From 2 to 34% by weight of the soda-containing particles have a particle diameter of from <0.2 mm to 0.1 mm,
• > 0 to 10% by weight of the soda-containing particles have a particle diameter of <0.1 mm to 0.63 mm,

based on the total weight of the soda-containing particles, wherein the respective weight proportions of the soda-containing particles are selected so that they together make up a maximum of 100 wt .-%.

• – ≥ 0 bis 20 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von ≥ 1,6 mm,
• – 2 bis 4,5 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 1,6 mm bis 1,25 mm,
• – 1 bis 3,0 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 1,25 mm bis 1,0 mm,
• – 1 bis 3,5 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 1,0 mm bis 0,8 mm,
• – 1 bis 4,5 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 0,8 mm bis 0,63 mm,
• – 2 bis 28 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 0,63 mm bis 0,4 mm,
• – 45 bis 56 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 0,4 mm bis 0,2 mm,
• – 2 bis 28 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 0,2 mm bis 0,1 mm,
• – > 0,1 bis 2 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 0,1 mm bis 0,63 mm,

bezogen auf das Gesamtgewicht der sodahaltigen Partikel, aufweisen, wobei die jeweiligen Gewichtsanteile der sodahaltigen Partikel so gewählt sind, dass diese zusammen maximal 100 Gew.-% ausmachen.A further advantageous embodiment of the soda-containing particles according to the invention has, for example, the following particle size distribution, wherein:

• - ≥ 0 to 20 wt .-% of the soda-containing particles has a particle diameter of ≥ 1.6 mm,
• From 2 to 4.5% by weight of the soda-containing particles have a particle diameter of from <1.6 mm to 1.25 mm,
• From 1 to 3.0% by weight of the soda-containing particles have a particle diameter of <1.25 mm to 1.0 mm,
• From 1 to 3.5% by weight of the soda-containing particles have a particle diameter of from <1.0 mm to 0.8 mm,
• From 1 to 4.5% by weight of the soda-containing particles have a particle diameter of from <0.8 mm to 0.63 mm,
• 2 to 28% by weight of the soda-containing particles have a particle diameter of <0.63 mm to 0.4 mm,
• 45 to 56% by weight of the soda-containing particles have a particle diameter of <0.4 mm to 0.2 mm,
• 2 to 28% by weight of the soda-containing particles have a particle diameter of <0.2 mm to 0.1 mm,
• > 0.1 to 2% by weight of the soda-containing particles have a particle diameter of <0.1 mm to 0.63 mm,

based on the total weight of the soda-containing particles, wherein the respective weight proportions of the soda-containing particles are selected so that they together make up a maximum of 100 wt .-%.

• – ≥ 7 bis 9 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von ≥ 1,6 mm,
• – 2 bis 3 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 1,6 mm bis 1,25 mm,
• – 1,2 bis 2,5 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 1,25 mm bis 1,0 mm,
• – 1 bis 3,2 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 1,0 mm bis 0,8 mm,
• – 1 bis 4,5 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 0,8 mm bis 0,63 mm,
• – 2 bis 28 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 0,63 mm bis 0,4 mm,
• – 50 bis 56 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 0,4 mm bis 0,2 mm,
• – 2 bis 28 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 0,2 mm bis 0,1 mm,
• – > 0,2 bis 1,5 Gew.-% der sodahaltigen Partikel einen Partikeldurchmesser von < 0,1 mm bis 0,63 mm,

bezogen auf das Gesamtgewicht der sodahaltigen Partikel, aufweisen, wobei die jeweiligen Gewichtsanteile der sodahaltigen Partikel so gewählt sind, dass diese zusammen maximal 100 Gew.-% ausmachen.Yet another advantageous embodiment of the soda-containing particles according to the invention has, for example, the following particle size distribution, wherein:

• - ≥ 7 to 9 wt .-% of the soda-containing particles has a particle diameter of ≥ 1.6 mm,
• From 2 to 3% by weight of the soda-containing particles have a particle diameter of from <1.6 mm to 1.25 mm,
• 1.2 to 2.5% by weight of the soda-containing particles have a particle diameter of <1.25 mm to 1.0 mm,
• From 1 to 3.2% by weight of the soda-containing particles have a particle diameter of from <1.0 mm to 0.8 mm,
• 1 to 4.5% by weight of the soda-containing particles Particle diameter of <0.8 mm to 0.63 mm,
• 2 to 28% by weight of the soda-containing particles have a particle diameter of <0.63 mm to 0.4 mm,
• 50 to 56% by weight of the soda-containing particles have a particle diameter of <0.4 mm to 0.2 mm,
• 2 to 28% by weight of the soda-containing particles have a particle diameter of <0.2 mm to 0.1 mm,
• > 0.2 to 1.5% by weight of the soda-containing particles have a particle diameter of <0.1 mm to 0.63 mm,

based on the total weight of the soda-containing particles, wherein the respective weight proportions of the soda-containing particles are selected so that they together make up a maximum of 100 wt .-%.

by virtue of the good recording capacity the carrier materials the soda-containing invention Particles have at most low adhesive properties on the particle surface, such that the soda-containing ones according to the invention Particles a bulk density from 300 g / l to 1000 g / l, preferably 400 g / l to 700 g / l and preferred 450 g / l to 600 g / l.

The soda-containing according to the invention Particles have a very low dust value, as fragrance or perfume a good cohesion of the respective soda-containing Ensure particles. In particular, by the high content of perfume or perfume is a particularly low dust value of the soda-containing invention Particles reached.

The soda-containing according to the invention Particles can preferably a dust value of ≥ 0.001 % and ≤ 0.05 %, preferably ≥ 0.003 % and ≤ 0.02 % and more preferably ≥ 0.007 % and ≤ 0.01 % exhibit.

The soda-containing according to the invention Particles can before the perfume loading a high oil count in ml / 100g of 50 to 150, preferably 60 to 140, preferably of 70 to 130, more preferably from 80 to 120 and more preferably from 90 to 110. The high oil count is in particular on the high liquid absorption capacity attributed to the soda.

For the soda-containing particles according to the invention can for the aforementioned reasons also a low Klumptestwert be obtained. The soda-containing according to the invention Particles can a Klumptestwert based on 500g soda-containing particles of ≥ 0 g and ≤ 7 g, preferably ≤ 5 g, preferably ≤ 3 g and especially preferably ≦ 1 g have.

The soda-containing invention Particles containing from 30% to 60% by weight of soda, a Silicate content of at least 9 wt .-% to 25 wt .-%, and a nonionic surfactant content of up to 5% by weight a Klumptestwert based on 500g soda-containing particles of ≥ 0 g and ≤ 1 g, have.

The soda-containing invention Particles containing from 30% to 60% by weight of soda, a Silicate content of at least 9 wt .-% to 25 wt .-%, and a nonionic surfactant content of up to 10% by weight a Klumpestwert based on 500g soda-containing particles of ≥ 2 g and ≤ 3 g, have.

Efrindungsgemäße soda-containing Particles containing from 30% to 60% by weight of soda, a Silicate content of at least 9 wt .-% to 25 wt .-%, and a nonionic surfactant content of up to 15% by weight a Klumpestwert related to 500g soda-containing particles of ≥ 6 g and ≤ 9 g, have.

The soda-containing invention Particles containing from 30% to 60% by weight of soda, a Silicate content of at least 9 wt .-% to 25 wt .-%, and a nonionic surfactant content of up to 20% by weight a Klumpestwert related to 500g soda-containing particles of ≥ 8 g and ≤ 14 g, have.

The soda-containing invention Particles containing from 30% to 60% by weight of soda, a Silicate content of at least 9 wt .-% to 25 wt .-%, and a nonionic surfactant content of up to 25% by weight a Klumpestwert based on 500g soda-containing particles of ≥ 28 g and ≤ 52 g, have.

Farther could for the soda-containing invention Particles in the sedimentation test a value of preferably ≥ 0 ml and ≤ 5 ml, advantageously ≥ 0.01 ml and ≤ 3 ml and preferably ≥ 0.05 ml and ≤ 2 ml are determined.

The soda-containing according to the invention Particles can also a good flowability advantageously at least 40%, in particular at least 50%, preferably at least 70% and preferably 90% to ≤ 100%.

One Another advantage of the soda-containing particles according to the invention is their high solubility. So can the soda-containing invention Particles at a water temperature of 10 ° C a dissolution time of preferably maximum 3.5 minutes and / or at a water temperature of 30 ° C a dissolution time of preferably have a maximum of 1.5 minutes seconds.

For example may 1g of the soda-containing according to the invention Particles a residue behavior in 200 ml at 10 ° C tempered tap water with 15 ° d H of ≥ 0% and ≤ 5%, preferably ≥ 0.001% and ≤ 4%, preferably ≥ 0.01% and ≤ 3% and especially preferably of ≥ 0.1 % and ≤ 2 % exhibit.

Further can 1g of the soda-containing invention Particles a residue behavior in 200 ml at 30 ° C tempered tap water with 15 ° d H of ≥ 0% and ≤ 5%, preferably ≥ 0.001% and ≤ 4%, preferably ≥ 0.01% and ≤ 2% and more preferably of ≥ 0.1 % and ≤ 1 % exhibit.

If Unless stated otherwise, the water hardness is given in degrees of German hardness.

The Measurements of the oil number, the residue value, of the clot test, the dust test and the sedimentation test described below in the information on the methods of measurement.

As a general rule can the soda-containing particles have all the fragrance (s) that are for the consumer give a pleasant fragrance smell.

According to the invention preferred Fragrances include fragrances that are pleasant in humans Trigger the sensation of smell.

• – eine Kopfnote, gebildet vorzugsweise aus den flüchtigsten Bestandteilen und bestimmen den ersten Dufteindruck; und/oder
• – eine Herznote, vorzugsweise gebildet aus den schweren, süßen Blütenaromen; und/oder
• – eine Basisnote, auf Anhieb schwer wahrnehmbar, welches die sinnlichen Töne ausmacht.

Fragrances according to the invention may comprise at least a part, preferably three parts of the following fragrance notes:

• A top note, formed preferably of the most volatile constituents and determining the first fragrance impression; and or
• - A heart note, preferably formed from the heavy, sweet flower aromas; and or
• - a base note, difficult to discern right away, which makes up the sensual notes.

As a general rule All conceivable suitable fragrances can be used according to the invention. This can be from a variety of plant sources usable according to the invention Attracting fragrances, for example from flowers of lavender, roses, jasmine, neroli; for example, stems and leaves of geranium, patchouli, Petit grain; from fruits, for example anise, coriander, caraway, juniper; from fruit peel for example, of citrus fruits such as bergamot, lemons, oranges; from seeds for example, macis, angelica, celery, cardamom; Roots, for example Angelika, Costus, Iris, Calmus; made of wood, for example sandal, Guaiac, cedar, rosewood; from herbs and grasses, for example Tarragon, lemongrass, sage, thyme; from needles and branches, for example of spruces, firs, pines, pines; from resins and balm for example from galbanum, elemi, benzoin, myrrh, olibanum and opoponax.

But also from animal raw materials can be suitable fragrances amber, for example, amber, a sperm whale secreted pathological metabolism product; Musk, the glands content of a Central Asian antlerless deer; Civet, the glandular secretion the civet cat; and Castoreum, a gland secretion from the Canadian beaver.

To isolate the fragrance (s) from the raw materials, various methods are used, for example, squeezing the fruit peels for citrus oils, extracting resinoids from resins, balsams, lichens and mosses by means of volatile solvents such as alcohol or hexane, steam distillation of previously prepared comminuted plant parts for recovery of essential oils. The enfleurage, which has been known since ancient times, is an extraction of the especially delicate floral fragrances by means of odor-neutral fats, is rarely used today, but the particularly gentle removal by means of supercritical gases, for example CO ₂ , has become increasingly important.

From the semisynthetic, obtained by chemical modification of natural starting materials Fragrances can including isoeugenol from eugenol, the main constituent of clove oil, vanillin from isoeugenol, hydroxycitronellal from citronellal, citronellol from geraniol or citronellal, geranyl acetate from geraniol, Jonone and citral methylionones are used in the invention.

at The fully synthetic fragrances are nature-identical as well those whose molecular structures without natural Model are. Some of these products give the odor notes more natural Fragrances again, but many have no odor model in the nature. They allow the creation of various fantasy fragrance compositions.

• – "Grün-Noten" sind herb-frische Düfte und riechen nach Blättern, Gräsern, Wiesen usw;
• – "Citrus-Noten" bestehen meist aus den etherischen Ölen der Citrus-Früchte mit erfrischendem Charakter;
• – "Lavendel-Noten" sind in vielen Kompositionen enthalten und bilden den Hauptbestandteil der "Lavendel-Wässer";
• – "Blumige Noten" sind überwiegend zusammengesetzt aus mehreren Einzelblumen-Noten, beispielsweise der Richtungen Jasmin, Flieder, Rose, Maiglöckchen, Iris/Veilchen, Nelke;
• – "Aldehyd-Noten" basieren überwiegend auf synthetischen Riechstoffen mit blumigem, zum Teil auch holzigem, balsamischen und animalischem Charakter; sie sind Bestandteil vieler ModeParfums;
• – "Chypre-Noten" (Moos-Noten) bestehen überwiegend aus Eichenmoos-Extrakten, zum Teil in Kombination mit Bergamotteöl und haben herb-frischen Charakter;
• – "Fougere-Noten" (Farn-Noten) sind den Chypre-Noten verwandt;
• – "Gewürz-Noten" enthalten Gewürz-Extrakte von beispielsweise Thymian, Pfeffer, Muskat, Zimt, Nelken, Ingwer, Majoran, Kardamom, Koriander usw., zum Teil auch synthetische Riechstoffe und speziell kombinierte Gewürz-Basen;
• – "Orientalische Noten" kombinieren Gewürz-Noten mit schweren, süßen, balsamischen oder animalischen Noten zu Düften mit würzig-süßem bis zu süßlich-schwerem Charakter;
• – "Holz-Noten" basieren auf beispielsweise Zedern-, Sandel- u.a. Holz- und Wurzel-Ölen und variieren von herb-frisch bis holzig-herb;
• – "Tabak-Noten" gibt es in vielen Variationen von frisch-herb-würzig bis schwer-süßhonigartig, ursprünglich basierend auf dem Duft von Tabakblüten und fermentiertem Tabak;
• – "Leder-Noten" erinnern an den Geruch feinster Lederwaren, beispielsweise der Duftrichtung Juchten;
• – „Metall-Noten" erinnern an den Geruch von Metall.

For the odor directions, there is no generally binding classification. Mostly a distinction is made between "scent families" of certain notes:

• - "Green notes" are fresh and harsh scents and smell of leaves, grasses, meadows etc;
• - "Citrus notes" usually consist of the essential oils of citrus fruits with a refreshing character;
• - "Lavender notes" are contained in many compositions and form the main ingredient of "lavender waters";
• - "Flowery notes" are predominantly composed of several single floral notes, for example, the directions of jasmine, lilac, rose, lily of the valley, iris / violet, carnation;
• - "aldehyde notes" are predominantly based on synthetic fragrances with floral, partly also woody, balsamic and animal character; they are part of many fashion perfumes;
• - "Chypre notes" (moss notes) consist predominantly of oak moss extracts, partly in combination with bergamot oil and have a tart-fresh character;
• - "Fougere notes" (fern notes) are related to the chypre notes;
• - "spice notes" contain spice extracts of, for example, thyme, pepper, nutmeg, cinnamon, cloves, ginger, marjoram, cardamom, coriander, etc., in part also synthetic fragrances and especially combined spice bases;
• - "Oriental notes" combine spice notes with heavy, sweet, balsamic or animal notes to scents with spicy-sweet to sweet-heavy character;
• - "wood notes" are based on, for example, cedar, sandal, etc. wood and root oils and vary from herb-fresh to woody-herb;
• - "Tobacco notes" are available in many variations from fresh-tart-spicy to hard-honeyy, originally based on the scent of tobacco blossoms and fermented tobacco;
• - "Leather notes" reminiscent of the smell of fine leather goods, such as the scent direction Juchten;
• - "Metal notes" reminiscent of the smell of metal.

Natural essences or with natural flavorings Prepared essences are preparations whose odor or tasteful ingredients are exclusively of natural origin.

Next the above listed Fragrances can be as fragrances but also essences of fruits, fruit parts and / or other parts of plants, such as herbs, drugs, as well as it recovered essential oils, also terpene-free oils use according to the invention.

It can but also artificial Essences used in the invention are made from synthetic odorants or flavors are. It can the synthetic products are identical to the natural flavorings For example, vanillin, menthol, biacetyl, eucalyptol and like.

Farther can as fragrances also aromas are used according to the invention. suitable Flavors include essential oils, such as anise oil, Bitter almond oil, fennel oil and caraway oil. Further are mixes of single, generally synthetically produced - one speaks here of "nature identical" - components of these oils as fragrances usable according to the invention. There are currently about 600 natural ones and about 4200 nature-identical flavorings for food and pharmaceutical products. As such, hydrocarbons, heterocycles, Alcohols, aldehydes, ketones, acetates, esters, phenols and phenol ethers and Sulfides and thiols.

When Flavorings are preferably peppermint oil, spearmint oil, aniseed oil, star aniseed oil, caraway oil, eucalyptus oil, fennel oil, lemon oil, wintergreen oil, clove oil, menthol and the like are suitable for use in the invention.

When Fragrances can in the context of the present invention, individual fragrance compounds, for example the synthetic products of the ester type, ethers, aldehydes, ketones, Alcohols and hydrocarbons are used. fragrance compounds of the ester type are, for example, benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzyl-carbinyl acetate, Phenylethyl acetate, linalyl benzoate, benzyl formate, ethyl methyl phenyl glycinate, Allyl cyclohexyl propionate, styrallyl propionate and benzyl salicylate. To count the Ethern for example, benzyl ethyl ether, to the aldehydes, for example the linear alkanals with 8-18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, Cyclamenaldehyde, Hydroxycitronellal, Lilial and Bourgeonal, to the Ketones, for example, the ionone, isomethylionone and methyl cedryl ketone, to the alcohols anethol, citronellol, eugenol, geraniol, linalool, Phenylethyl alcohol and terpineol, the hydrocarbons include mainly Terpenes like limes and pinas. However, mixtures are preferred different fragrances used, which together create an appealing Create a fragrance. Such fragrances also include perfume oils, wherein These are also natural fragrance mixtures can contain as are available from plant sources, such as pine, Citrus, jasmine, patchouly, rose or ylang-ylang oil. Also Muscat, sage, chamomile, clove, lemon balm, mint, cinnamon, lime, juniper, vetiver, olibanum, galbanum and labdanum oils are also suitable Orange blossom oil, neroliol, Orange peel oil and Sandalwood oil.

The general description of the usable fragrances is doing in general the different substance classes of fragrances represents.

To be perceptible, a fragrance, also called fragrance, must be volatile, whereby in addition to the nature of the functional groups and the structure of the chemical compound and the molecular weight plays an important role. For example, most odorants have molecular weights up to about 200 daltons, while molecular weights of 300 daltons and above are more of an exception. Due to the different volatility of fragrances, the smell of one of several fragrances changes The fragrance impressions as described above in "top note", "heart or middle note" (middle note or body) and "base note" (end note or dry divided out). Since the smell perception is based to a large extent on the odor intensity, the top note of a perfume or fragrance is not only from volatile compounds, while the base note for the most part consists of less volatile, ie adherent fragrances. For example, in the composition of perfumes, more volatile fragrances can be bound to certain fixatives, preventing them from evaporating too quickly. In the subsequent classification of the fragrances in "more volatile" or "adherent" fragrances so nothing about the olfactory impression and whether the corresponding fragrance is perceived as a head or middle note, nothing said.

By a suitable choice of said fragrances can be made in this way for agents according to the invention both the product odor, and, after completion of the cleaning and care process, in addition, for example the laundry smell or textile air.

For the latter Odor impression, the use of more adhesive fragrances is advantageous, while for product scenting also more volatile fragrances can be used are.

Tenacious Fragrances that can be used in the context of the present invention are, for example, the essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, bay oil, bergamot oil, Champacablütenöl, Edeltannöl, Edeltannenzapfenapfen, Elemiöl, eucalyptus oil, fennel oil, spruce alder oil, galbanum oil, geranium oil, ginger grass oil, guaiac wood oil, Gurjunbalsamöl, Helichrysumöl, Ho oil, Ginger oil, iris oil, cajeput oil, calamus oil, camomile oil, camphor oil, kanaga oil, cardamom oil, cassia oil, pine oil, copaiba balsam, coriander oil, spearmint oil, caraway oil, cumin oil, lavender oil, lemongrass oil, lime oil, tangerine oil, lemon balm oil, musk kernel oil, myrrh oil, clove oil, neroli oil, niaouli oil, Olibanum Oil, Orange Oil, Origanum Oil, Palmarosa Oil, Patchouli Oil, Peru Balsam Oil, Petitgrain Oil, Pepper Oil, Peppermint Oil, Pimento Oil, Pine Oil, Rose Oil, Rosemary Oil, Sandalwood Oil, Celery Oil, Spik Oil, Star Aniseed Oil, Turpentine Oil, Thuja Oil, Thyme Oil, Verbena Oil, Vetiver Oil, Juniper Berry Oil, Vermouth Oil, Wintergreen oil, Ylang-Ylan g oil, hyssop oil, cinnamon oil, cinnamon oil, lemon oil, lemon oil as well Cypress oil.

But also the higher-boiling ones or solid odoriferous natural or of synthetic origin in the context of the present invention as adherent fragrances or Fragrance mixtures, so fragrances are used. To these connections counting the following compounds as well as mixtures of these: Ambrettolide, α-amylcinnamaldehyde, Anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, Acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, Benzyl alcohol, benzyl acetate, benzyl benzoate, benzyl formate, benzyl valerate, Borneol, bornyl acetate, α-bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, Eugenof, eugenol methyl ether, eucalyptol, farnesol, Fenchone, fenchyl acetate, geranyl acetate, geranyl formate, heliotropin, Heptincarbonsäuremethylester, Heptaldehyde, hydroquinone dimethyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, Indole, iron, isoeugenol, isoeugenol methyl ether, isosafrole, jasmon, Camphor, Karvakrol, Karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, Methyl n-amyl ketone, Methylanthranilsäuremethylester, p-methylacetophenone, methylchavikole, p-methylquinoline, methyl-β-naphthylketone, Methyl-n-nonylacetaldehyde, methyl n-nonyl ketone, Muskon, β-naphthol ethyl ether, β-naphthol methyl ether, nerol, Nitrobenzene, n-nonylaldehyde, nonyl alcohol, n-octylaldehyde, p-oxy-acetophenone, Pentadecanolide, β-phenylethyl alcohol, Phenylacetaldehyde dimethyacetal, phenylacetic acid, pulegone, safrole, salicylic acid isoamyl ester, methyl salicylate, Salicylsäurehexylester, Salicylic acid cyclohexyl ester, Santalol, Skatole, terpineol, thymen, thymol, γ-undelactone, vanilin, veratrum aldehyde, Cinnamaldehyde, cinnamyl alcohol, cinnamic acid, cinnamate, Zimtsäurebenzylester.

To the more volatile In particular, fragrances count the lower-boiling fragrances natural or synthetic Origin, which can be used alone or in mixtures.

Examples for easier volatile Fragrances are alkyl isothiocyanates (alkyl mustard oils), butanedione, limonene, linalool, Linayl acetate and propionate, menthol, menthone, methyl-n-heptenone, Phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.

• – Essenzen aus Früchten, Fruchtteilen und/oder anderen Pflanzenteilen, vorzugsweise Kräutern, Drogen, daraus gewonnene etherische Ölen, bevorzugt terpenfreie Öle; und/oder
• – künstliche Essenzen, vorzugsweise aus synthetischen Geruchs- und/oder Geschmacksstoffen, besonders bevorzugt Vanillin, Menthol, Biacetyl und/oder Eucalyptol; und/oder
• – Aromen, vorzugsweise ätherische Öle, Anisöl, Sternanisöl, Bittermandelöl, Eukalyptusöl, Fenchelöl, Pfefferminzöl, Citronenöl, Wintergrünöl, Nelkenöl, Menthol und/oder Kümmelöl; und/oder
• – synthetische Riechstoffverbindungen vom Typ der Ester, vorzugsweise Benzylacetat, Phenoxyethylisobutyrat, p-tert.-Butylcyclohexylacetat, Linalylacetat, Dimethylbenzylcarbinylacetat, Phenylethylacetat, Linalylbenzoat, Benzylformiat, Ethylmethylphenyl- glycinat, Allylcyclohexylpropionat, Styrallylpropionat und/oder Benzylsalicylat; und/oder
• – synthetische Riechstoffverbindungen vom Typ der Ether, vorzugsweise Benzylethylether; und/oder
• – synthetische Riechstoffverbindungen vom Typ der Aldehyde, vorzugsweise lineare Alkanale mit 8-18 C-Atomen, Citral, Citronellal, Citronellyloxyacetaldehyd, Cyclamenaldehyd, Hydroxycitronellal, Lilial und/oder Bourgeonal; und/oder
• – synthetische Riechstoffverbindungen vom Typ der Ketone, vorzugsweise Jonone, Isomethylionon und/oder Methyl-cedrylketon; und/oder
• – synthetische Riechstoffverbindungen vom Typ der Alkohole, vorzugsweise Anethol, Citronellol, Eugenol, Geraniol, Linalool, Phenylethylalkohol und/oder Terpineol; und/oder
• – synthetische Riechstoffverbindungen vom Typ der Kohlenwasserstoffe, vorzugsweise Terpene, bevorzugt Limonen und Pinien; und/oder
• – natürliche Riechstoffgemische aus pflanzlichen Quellen, vorzugsweise Pine-, Citrus-, Jasmin-, Patchouly-, Rosen- oder Ylang-Ylang-Öl, Muskateller, Salbeiöl, Kamillenöl, Nelkenöl, Melissenöl, Minzöl, Zimtblätteröl, Lindenblütenöl, Wacholderbeeröl, Vetiveröl, Olibanumöl, Galbanumöl, Labdanumöl, Orangenblütenöl, Neroliol, Orangenschalenöl und/oder Sandelholzöl; und/oder
• – metallische Riechstoffverbindungen umfassend Oxacyclododecan-2-on, 4,5-Decamethylenoxazol, Sclarene, Derivate davon und/oder Vorstufen davon, wobei die Derivate vorzugsweise in Form von Estern und/oder Ethern vorliegen.

It is particularly preferred if the soda-containing particles have at least one perfume which is selected from the group comprising:

• Essences of fruits, fruit parts and / or other parts of plants, preferably herbs, drugs, essential oils derived therefrom, preferably terpene-free oils; and or
• Artificial essences, preferably of synthetic odorants and / or flavorings, more preferably vanillin, menthol, biacetyl and / or eucalyptol; and or
• Flavorings, preferably essential oils, aniseed oil, star aniseed oil, bitter almond oil, eucalyptus oil, fennel oil, peppermint oil, lemon oil, wintergreen oil, clove oil, menthol and / or caraway oil; and or
• Synthetic fragrance compounds of the ester type, preferably benzyl acetate, phenoxy ethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinyl acetate, phenylethyl acetate, linalyl benzoate, benzylformate, ethylmethylphenyl glycinate, allylcyclohexylpropionate, styrallylpropionate and / or benzylsalicylate; and or
• Synthetic fragrance compounds of the ether type, preferably benzyl ethyl ether; and or
• Synthetic fragrance compounds of the aldehyde type, preferably linear alkanals of 8-18 C atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial and / or bourgeonal; and or
• - Synthetic fragrance compounds of the ketone type, preferably ionone, isomethylionone and / or methyl cedrylketone; and or
• Synthetic fragrance compounds of the alcohol type, preferably anethole, citronellol, eugenol, geraniol, linalool, phenylethyl alcohol and / or terpineol; and or
• Synthetic perfume compounds of the hydrocarbon type, preferably terpenes, preferably limonene and pine; and or
• - Natural fragrance mixtures from plant sources, preferably pine, citrus, jasmine, patchouly, rose or ylang-ylang oil, muscatel, sage oil, camomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, olibanum oil , Galbanum oil, labdanum oil, orange blossom oil, neroliol, orange peel oil and / or sandalwood oil; and or
• - Metallic fragrance compounds comprising oxacyclododecan-2-one, 4,5-decamethyleneoxazole, Sclarene, derivatives thereof and / or precursors thereof, wherein the derivatives are preferably in the form of esters and / or ethers.

The soda-containing according to the invention Particles can as stated above Nonionic surfactant, also called nonionic surfactants have. Preferably is at least one nonionic surfactant selected from the group comprising alkoxylated fatty alcohols, alkyl glycosides, fatty acid alkyl esters and / or amine oxides containing alkoxylated fatty acid alkyl esters, ethoxylated fatty acid alkyl ester or ethoxylated and propoxylated fatty acid alkyl esters are preferred.

As nonionic surfactants (nonionic surfactants) are preferably alkoxylated, preferably ethoxylated, especially primary alcohols having preferably 8 to 18 carbon atoms and an average of 1 to 12 moles of ethylene oxide (EO) per mole of alcohol used in which the alcohol radical linear or preferably in the 2-position may be methyl branched or contain linear and methyl-branched radicals in the mixture, as they are usually present in Oxoalkoholresten. In particular, however, alcohol ethoxylates with linear radicals of alcohols of natural origin having 12 to 18 carbon atoms, for example of coconut, palm, palm kernel, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred. The preferred ethoxylated alcohols include, for example, C ₁₂ -C ₁₄ -alcohols with 3 EO or 4 EO, C ₉ -C ₁₁ -alcohols with 7 EO, C ₁₃ -C ₁₅ -alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C ₁₂ -C ₁₈ -alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C ₁₂ -C ₁₄ -alcohol with 3 EO and C ₁₂ -C ₁₈ -alcohol with 7 EO. The degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number. Preferred alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE). In addition to these nonionic surfactants, fatty alcohols with more than 12 EO can also be used. Examples include (tallow) fatty alcohols with 14 EO, 16 EO, 20 EO, 25 EO, 30 EO or 40 EO.

In addition, as further nonionic surfactants and alkyl glycosides of the general formula RO (G) _x can be used in which R is a primary straight-chain or methyl-branched, especially in the 2-position methylverzwe th aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol representing a glycose moiety having 5 or 6 C atoms, preferably glucose. The degree of oligomerization x, which indicates the distribution of monoglycosides and oligoglycosides, is any number from 1 to 10; preferably x is 1.1 to 1.4.

Another class of preferred nonionic surfactants used either as the sole nonionic surfactant or in combination with other nonionic surfactants, in particular together with alkoxylated fatty alcohols and / or alkyl glycosides, are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably from 1 to 4 carbon atoms in the alkyl chain, in particular fatty acid methyl esters, as described for example in Japanese Patent Application JP 58/217598 or which are preferably prepared according to the method described in the international patent application WO-A-90/13533. Particularly preferred are C ₁₂ -C ₁₈ fatty acid methyl esters having an average of 3 to 15 EO, in particular having an average of 5 to 12 EO.

Also nonionic surfactants of the amine oxide type, for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallow alkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamide can be suitable. The amount of these nonionic surfactants is preferably not more than that of the ethoxylated fatty alcohols, in particular not more than half from that.

For soda-containing particles according to the invention, Particularly suitable for automatic dishwashing, the non-ionic surfactants which are particularly suitable as nonionic surfactants are, in particular, low-foaming surfactants. Particularly preferred are the alkoxylated alcohols, especially the ethoxylated and / or propoxylated alcohols. The skilled worker generally understands alkoxylated alcohols, the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, preferably in the context of the present invention, the longer-chain alcohols (C ₁₀ to C ₁₈ , preferably C ₁₂ to C ₁₆ , such as C ₁₁ -, C ₁₂ -, C ₁₃ -, C ₁₄ -, C ₁₅ -, C ₁₆ -, C ₁₇ - and C ₁₈ -alcohols). As a rule, n moles of ethylene oxide and one mole of alcohol, depending on the reaction conditions, form a complex mixture of addition products of different degrees of ethoxylation. A further embodiment consists in the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide. Optionally, a final etherification with short-chain alkyl groups, such as preferably the butyl group, may also yield the class of "closed" alcohol ethoxylates which can likewise be used in the context of the invention. Very particularly preferred for the purposes of the present invention are highly ethoxylated fatty alcohols or mixtures thereof with end-capped fatty alcohol ethoxylates.

The perfume of the invention having soda-containing particles can at least one, preferably have several of the ingredients listed below, selected from the group comprising builders, bleaches, bleach activators, Bleach stabilizers, bleach catalysts, enzymes, polymers, cobuilders, Alkalizing agents, acidifying agents, anti-redeposition agents, silver protectants, dye, optical brighteners, UV protectants, softeners and / or rinse aids, as well optionally further admixed ingredients.

Further Ingredients of the perfume of the invention containing soda-containing particles containing particle mixture particles according to the invention and / or finished product can be inorganic and optionally organic builders.

The inorganic builder substances also include non-water-insoluble ingredients such as aluminosilicates and in particular zeolites. The preferably usable finely crystalline, synthetic and bound water-containing zeolite is preferably zeolite A and / or P. As zeolite P, for example, zeolite MAP ^(R) (commercial product from Crosfield) is particularly preferred. Also suitable however are zeolite X and mixtures of A, X and / or P. Of particular interest is a co-crystallized sodium / potassium aluminum silicate of zeolite A and zeolite X, which as VEGOBOND AX ^® (a product of Condea Augusta SpA) Trade is available. This product is described below. The zeolite can be used as a spray-dried powder or else as undried, still moist, stabilized suspension of its preparation. In the event that the zeolite is used as a suspension, it may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3 wt .-%, based on zeolite, of ethoxylated C ₁₂ -C ₁₈ fatty alcohols having 2 to 5 ethylene oxide groups , C ₁₂ -C ₁₄ fatty alcohols having 4 to 5 ethylene oxide groups or ethoxylated isotridecanols. Suitable zeolites have an average particle size of less than 10 μm (volume distribution, measuring method: Coulter Counter) and preferably contain 18 to 22% by weight, in particular 20 to 22% by weight, of bound water.

When other particularly suitable zeolites are zeolites of the faujasite type to call. Together with the zeolites X and Y belongs the mineral faujasite to the faujasite types within the zeolite structure group 4, the are characterized by the double-six-membered subunit D6R (Comparisons Donald W. Breck: "Zeolite Molecular Sieves, "John Wiley & Sons, New York, London, Sydney, Toronto, 1974, page 92). To the zeolite structure group 4 count in addition to the mentioned faujasite types, the minerals chabazite and gmelinite and the synthetic zeolites R (chabazite type), S (gmelinite type), L and ZK-5. The latter two synthetic Zeolites have no mineral analogues.

Faujasite-type zeolites are composed of β-cages linked tetrahedrally via D6R subunits, with the β-cages arranged similarly to the carbon atoms in the diamond. The three-dimensional network of the faujasite-type zeolites useful in the present invention has pores of 2.2 and 7.4 Å, the unit cell also contains 8 wells of about 13 Å in diameter, and can be represented by the formula Na ₈₆ [(AlO ₂ ). ₈₆ (SiO ₂ ) ₁₀₆ ] · 264 H ₂ O describe. The network of zeolite X contains a void volume of about 50%, based on the dehydrated crystal, which represents the largest void space of all known zeolites (zeolite Y: about 48% void volume, faujasite: about 47% void volume). (All data from: Donald W. Breck: "Zeolite Molecular Sieves", John Wiley & Sons, New York, London, Sydney, Toronto, 1974, pages 145, 176, 177).

In the context of the present invention, the term "faujasite-type zeolite" denotes all three zeolites which form the faujasite subgroup of the zeolite structural group 4. In addition to the zeolite X, therefore, the invention also includes zeolite Y and Faujasite and mixtures of these compounds suitable, wherein the pure zeolite X is preferred.

Also Mixtures or cocrystallizates of faujasite-type zeolites with other zeolites, not necessarily the zeolite structure group 4 belong have to, are suitable according to the invention, wherein preferably at least 50% by weight of the zeolites of faujasite-type zeolites are.

The suitable aluminum silicates are commercially available, and the methods for their presentation are in standard monographs described.

Examples of commercially available X-type zeolites can be described by the following formulas: Na ₈₆ [(AlO ₂ ) ₈₆ (SiO ₂ ) ₁₀₆ ] .xH ₂ O, K ₈₆ [(AlO ₂ ) ₈₆ (SiO ₂ ) ₁₀₆ ] .xH ₂ O, Ca ₄₀ Na ₆ [(AlO ₂ ) ₈₆ (SiO ₂ ) ₁₀₆ ] xH ₂ O, Sr ₂₁ Ba ₂₂ [(AlO ₂ ) ₈₆ (SiO ₂ ) ₁₀₆ ] x H ₂ O, where x can take values greater than 0 to 276. These zeolites have pore sizes of 8.0 to 8.4 Å.

Also suitable is, for example, the zeolite A-LSX described in the European patent application EP-A-816,291, which corresponds to a co-crystallizate of zeolite X and zeolite A and in its anhydrous form has the formula (M _{2 / n} O + M ' _{2 / n} O) · Al ₂ O ₃ · zSiO ₂ , where M and M 'may be alkali or alkaline earth metals and z is a number from 2.1 to 2.6. Commercially available this product is under the brand name VEGOBOND AX by the company CONDEA Augusta SpA

Y-type zeolites are also commercially available and can be obtained, for example, by the formulas Na ₅₆ [(AlO ₂ ) ₅₆ (SiO ₂ ) ₁₃₆ ] xH ₂ O, K ₅₆ [(AlO ₂ ) ₅₆ (SiO ₂ ) ₁₃₆ ] xH ₂ O, where x is numbers greater than 0 to 276. These zeolites have pore sizes of 8.0 Å.

The Particle sizes of suitable zeolites of the faujasite type is in the range of 0.1 μm to to 100 μm, preferably 0.5 μm up to 50 μm and in particular of 1 μm up to 30 μm, each measured by standard particle size determination methods.

In another basic embodiment The invention, however, the contained inorganic constituents water soluble be. In these embodiments Therefore, other builders than the mentioned zeolites used.

In cases In which a phosphate content is tolerated, phosphates can also be used especially pentasodium triphosphate, if appropriate Pyrophosphates and orthophosphates, primarily as precipitants for lime salts Act. Phosphates become predominant in automatic dishwashing detergents, partly but also used in detergents.

Alkali metal phosphates is the summary term for the alkali metal (especially sodium and potassium) salts of various phosphoric acids, in which one can distinguish metaphosphoric acids (HPO ₃ ) _n and orthophosphoric H ₃ PO _{4 in} addition to higher molecular weight representatives. The phosphates combine several advantages: they act as alkali carriers, prevent lime deposits on machine parts or lime incrustations in fabrics and also contribute to the cleaning performance.

Sodium dihydrogen phosphate, NaH ₂ PO ₄ , exists as a dihydrate (density 1.91 gcm ^-3 , melting point 60 °) and as a monohydrate (density 2.04 gcm ^-3 ). Both salts are white powders which are very soluble in water and which lose their water of crystallization when heated and at 200 ° C into the weak acid diphosphate (disodium hydrogen diphosphate, Na ₂ H ₂ P ₂ O ₇ ), at higher temperature in sodium trimetaphosphate (Na ₃ P ₃ O ₉ ) and Maddrell's salt (see below). NaH ₂ PO _{4 is} acidic; It arises when phosphoric acid is adjusted to a pH of 4.5 with sodium hydroxide solution and the mash is sprayed. Potassium dihydrogen phosphate (potassium phosphate primary or monobasic potassium phosphate, KDP), KH ₂ PO ₄ , is a white salt of 2.33 gcm ^-3 density, has a melting point of 253 ° [decomposition to form potassium polyphosphate (KPO ₃ ) _x ] and is light soluble in water.

Disodium hydrogen phosphate (secondary sodium phosphate), Na ₂ HPO ₄ , is a colorless, very slightly water-soluble crystalline salt. It exists anhydrous and with 2 moles (density 2.066 gcm ^-3 , loss of water at 95 °), 7 moles (density 1.68 gcm ^-3 , melting point 48 ° with loss of 5 H ₂ O) and 12 moles water ( Density 1.52 gcm ^-3 , melting point 35 ° with loss of 5 H ₂ O) becomes anhydrous at 100 ° C and, upon increased heating, passes into the diphosphate Na ₄ P ₂ O ₇ . Disodium hydrogen phosphate is prepared by neutralization of phosphoric acid with soda solution using phenolphthalein as an indicator. Dipotassium hydrogen phosphate (se Secondary or dibasic potassium phosphate), K ₂ HPO ₄ , is an amorphous, white salt that is readily soluble in water.

Trisodium phosphate, tertiary sodium phosphate, Na ₃ PO ₄ , are colorless crystals which have a density of 1.62 gcm ^-3 as dodecahydrate and a melting point of 73-76 ° C (decomposition), as decahydrate (corresponding to 19-20% P ₂ O ₅ ) have a melting point of 100 ° C and in anhydrous form (corresponding to 39-40% P ₂ O ₅ ) have a density of 2.536 gcm ^-3 . Trisodium phosphate is readily soluble in water under alkaline reaction and is prepared by evaporating a solution of exactly 1 mole of disodium phosphate and 1 mole of NaOH. Tripotassium phosphate (tertiary or tribasic potassium phosphate), K ₃ PO ₄ , is a white, deliquescent, granular powder of density 2.56 gcm ^-3 , has a melting point of 1340 ° and is readily soluble in water with an alkaline reaction. It arises, for example, when heating Thomasschlacke with coal and potassium sulfate. Despite the higher price, the more soluble, therefore highly effective, potassium phosphates are often preferred over the corresponding sodium compounds in the detergent industry.

Tetrasodium diphosphate (sodium pyrophosphate), Na ₄ P ₂ O ₇ , exists in anhydrous form (density 2.534 gcm ^-3 , melting point 988 °, also indicated 880 °) and as decahydrate (density 1.815-1.836 gcm ^-3 , melting point 94 ° with loss of water) , Both substances are colorless crystals which are soluble in water with an alkaline reaction. Na ₄ P ₂ O ₇ is formed on heating of disodium phosphate to> 200 ° or by reacting phosphoric acid with soda in a stoichiometric ratio and dewatering the solution by spraying. The decahydrate complexes heavy metal salts and hardness agents and therefore reduces the hardness of the water. Potassium diphosphate (potassium pyrophosphate), K ₄ P ₂ O ₇ , exists in the form of the trihydrate and is a colorless, hygroscopic powder with a density of 2.33 gcm ^-3 , which is soluble in water, the pH being 1% Solution at 25 ° 10.4.

Condensation of the NaH ₂ PO ₄ or the KH ₂ PO ₄ results in higher molecular weight sodium and potassium phosphates, in which one can distinguish cyclic representatives, the sodium or potassium metaphosphates and chain types, the sodium or potassium polyphosphates. Especially for the latter, a variety of names are in use:
Melted or calcined phosphates, Graham's salt, Kurrolsches and Maddrell's salt. All higher sodium and potassium phosphates are collectively referred to as condensed phosphates.

The technically important pentasodium triphosphate, Na ₅ P ₃ O ₁₀ (sodium tripolyphosphate), is an anhydrous or with 6 H ₂ O crystallizing, non-hygroscopic, white, water-soluble salt of the general formula NaO- [P (O) (ONa) -O] _n -Na with n = 3. In 100 g of water dissolve at room temperature about 17 g, at 60 ° about 20 g, at 100 ° around 32 g of the salt water-free salt; after two hours of heating the solution to 100 ° caused by hydrolysis about 8% orthophosphate and 15% diphosphate. In the preparation of pentasodium triphosphate, phosphoric acid is reacted with soda solution or sodium hydroxide solution in a stoichiometric ratio and the solution is dehydrated by spraying. Similar to Graham's salt and sodium diphosphate, pentasodium triphosphate dissolves many insoluble metal compounds (including lime soaps, etc.). Pentakaliumtriphosphat, K ₅ P ₃ O ₁₀ (potassium tripolyphosphate), for example, in the form of a 50 wt .-% solution (> 23% P ₂ O ₅ , 25% K ₂ O) in the trade. The potassium polyphosphates are widely used in the washing and cleaning industry. There are also sodium potassium tripolyphosphates which can also be used in the context of the present invention. These arise, for example, when hydrolyzed sodium trimetaphosphate with KOH: (NaPO ₃ ) ₃ + 2 KOH → Na ₃ K ₂ P ₃ O ₁₀ + H ₂ O

These are exact according to the invention such as sodium tripolyphosphate, potassium tripolyphosphate or mixtures can be used from these two; also mixtures of sodium tripolyphosphate and sodium potassium tripolyphosphate or mixtures of potassium tripolyphosphate and sodium potassium tripolyphosphate or mixtures of sodium tripolyphosphate and potassium tripolyphosphate and sodium potassium tripolyphosphate used according to the invention.

In a preferred embodiment however, as inorganic builders in particular Carbonates and / or silicates used.

Mention here crystalline, layered sodium silicates of the general formula NaM-Si _x O _{2x + 1} · yH ₂ O, where M is sodium or hydrogen, x is a number from 1.6 to 4, preferably 1.9 to 4.0 and y is a number from 0 to 20 and preferred values for x are 2, 3 or 4. However, since such crystalline silicates at least partially lose their crystalline structure in a spray-drying process, crystalline silicates are preferably subsequently added to the direct or post-treated spray-drying product. Such crystalline layered silicates are described, for example, in European Patent Application EP-A-0 164 514. Preferred crystalline layered silicates of the formula given are those in which M is sodium and x assumes the values 2 or 3. In particular, both β- and δ-sodium disilicates Na ₂ Si ₂ O ₅ .yH ₂ O are preferred. Such compounds are commercially available, for example, under the Be drawing ^SKS® (from Clariant). Thus, it is SKS-6 ^® primarily a δ-sodium having the formula Na ₂ Si ₂ O ₅ · yH ₂ O, SKS-7 ^® primarily the β-sodium disilicate. Reaction with acids (eg citric acid or carbonic acid) gives kanemite NaHSi ₂ O ₅ .yH ₂ O, commercially available under the names SKS- ^9® and SKS- ^10® (from Clariant) from the δ-sodium disilicate. It may also be advantageous to use chemical modifications of these phyllosilicates. For example, the alkalinity of the layered silicates can be suitably influenced. Phyllosilicates doped with phosphate or with carbonate have, in comparison to the δ-sodium disilicate, different crystal morphologies, dissolve more rapidly and show an increased calcium binding capacity in comparison to δ-sodium disilicate. Thus, phyllosilicates of the general empirical formula x Na ₂ O.y SiO ₂ .z P ₂ O ₅ in which the ratio x to y is a number 0.35 to 0.6, the ratio x to z a number of 1.75 to 1200 and the ratio y to z of a number from 4 to 2800 corresponds to that described in the patent application DE-A-196 01 063. The solubility of the layered silicates can also be increased by using particularly finely divided layered silicates. It is also possible to use substances from the crystalline layered silicates with other ingredients. In particular, substances with cellulose derivatives which have advantages in the disintegrating action, as well as substances with polycarboxylates, for example citric acid, or polymeric polycarboxylates, for example copolymers of acrylic acid, may be mentioned.

The preferred builder substances also include amorphous sodium silicates having a modulus Na ₂ O: SiO _{2 of} from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2, 6, which have secondary washing properties. In the context of this invention, the term "amorphous" is also understood to mean "X-ray amorphous". This means that the silicates do not yield sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but at most one or more maxima of the scattered X-rays which have a width of several degrees of diffraction angle. However, it may well even lead to particularly good builder properties if the silicate particles provide blurred or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of size 10 to a few hundred nm, with values of up to max. 50 nm and in particular up to max. 20 nm are preferred. Such so-called X-ray-amorphous silicates, which likewise have a dissolution delay compared to the conventional water glasses, are described, for example, in German patent application DE-A-44 00 024. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates. The content of (X-ray) amorphous silicates is preferably 1 to 10% by weight.

useful organic builders are for example, in the form of their alkali and in particular sodium salts usable polycarboxylic acids, like citric acid, adipic acid, Succinic acid, glutaric, Tartaric acid, Sugar acids, amino carboxylic acids, nitrilotriacetic (NTA), if such an operation is not for environmental reasons is objectionable, as well as mixtures of these. Preferred salts are the salts of polycarboxylic acids like citric acid, adipic acid, Succinic acid, glutaric, Tartaric acid, Sugar acids and Mixtures of these.

Further suitable organic builders are polymeric polycarboxylates, for example the alkali metal salts of polyacrylic acid or of polymethacrylic acid, for example those having a relative molecular mass of 500 to 70,000 g / mol. For the purposes of this document, the molecular weights stated for polymeric polycarboxylates are weight-average molar masses M _{w of} the particular acid form, which were determined in principle by means of gel permeation chromatography (GPC), a UV detector being used. The measurement was carried out against an external polyacrylic acid standard, which provides realistic molecular weight values due to its structural relationship with the polymers investigated. These data differ significantly from the molecular weight data, in which polystyrene sulfonic acids are used as standard. The molar masses measured against polystyrenesulfonic acids are generally significantly higher than the molecular weights specified in this document.

suitable Polymers are in particular polyacrylates, which preferably have a molecular weight of 2,000 to 20,000 g / mol. Because of their superior solubility can from this group again the short-chain polyacrylates, the molecular weights from 2,000 to 10,000 g / mol, and more preferably from 3,000 to 5,000 g / mol, be preferred.

Suitable are furthermore copolymeric polycarboxylates, especially those of acrylic acid with methacrylic acid and the acrylic acid or methacrylic acid with maleic acid. Particularly suitable are copolymers of acrylic acid with Proved maleic acid, the 50 to 90 wt .-% acrylic acid and 50 to 10% by weight of maleic acid contain. Your molecular weight, based on free acids, is in general from 2000 to 70000 g / mol, preferably from 20,000 to 50,000 g / mol and in particular 30,000 to 40,000 g / mol.

The content of organic builders of the fine particulate surfactant according to the invention Particles, particles and / or finished product may also vary widely. Levels of from 2 to 20% by weight are preferred, with contents of not more than 10% by weight finding particular favor, especially for cost reasons.

Out more usual for the rest of the groups Detergent ingredients are included in the perfume of the invention containing soda-containing particles containing particle mixture particles according to the invention and / or finished product, in particular ingredients from the classes the grayness inhibitors (contaminants), the neutral salts and the fabric softening aid into consideration.

graying have the task of suspending the detached from the fiber dirt in the fleet to keep the dirt from being rebuilt. These are water-soluble Colloids mostly organic nature suitable, for example, the water-soluble Salts of polymeric carboxylic acids, Glue, gelatin, salts of ether carboxylic acids or ether sulfonic acids of Strength or the cellulose or salts of acidic sulfuric acid esters cellulose or starch. Also water-soluble, Acidic group-containing polyamides are suitable for this purpose. Farther can be soluble Starch preparations and other than the aforesaid starch products use, e.g. degraded starch, aldehyde etc .. Also, polyvinylpyrrolidone is useful. However, preference is given Cellulose ethers, such as carboxymethyl cellulose (Na salt), methyl cellulose, Hydroxyalkylcellulose and mixed ethers, such as methylhydroxyethylcellulose, Methylhydroxypropylcellulose, methylcarboxymethylcellulose and their Mixtures, and polyvinylpyrrolidone, for example, in amounts of 0.1 to 5 wt .-%, based on the total weight of the perfume invention soda-containing particles, particle mixture containing particles of the invention and / or Finished product, used.

When typical example of a suitable representative of neutral salts is sodium sulfate to call. It can be used in amounts of, for example, 2 to 45% by weight. be used.

suitable Plasticizers are, for example, swellable phyllosilicates of the Type of corresponding montmorillonites, for example bentonite.

Among the compounds which serve as bleaches and deliver H ₂ O ₂ in water, sodium perborate monohydrate or tetrahydrate and sodium percarbonate have particular significance. Other useful bleaching agents are, for example, peroxypyrophosphates, citrate perhydrates and H ₂ O ₂ -forming peracidic salts or peracids, such as perbenzoates, peroxophthalates, diperazelaic acid, phthaloiminoperacid or diperdodecanedioic acid. The content of bleaching agents in the composition is from 0 to 30% by weight and in particular from 5 to 25% by weight, it being advantageous to use perborate monohydrate or percarbonate.

Around when washing or cleaning at temperatures of 60 ° C and below To achieve an improved bleaching effect, bleach activators can be incorporated become. As bleach activators can Compounds which, under perhydrolysis conditions, are aliphatic peroxycarboxylic acids preferably 1 to 10 C atoms, in particular 2 to 4 C atoms, and / or optionally substituted perbenzoic acid, are used. Suitable substances are the O- and / or N-acyl groups of the mentioned C atom number and / or optionally substituted benzoyl groups wear. Preference is given to polyacylated alkylenediamines, in particular Tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated Glycolurils, in particular tetraacetylglycoluril (TAGU), N-acylimides, in particular N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates, in particular n-nonanoyl- or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic, in particular phthalic anhydride, acylated polyhydric alcohols, especially triacetin, ethylene glycol diacetate and 2,5-diacetoxy-2,5-dihydrofuran.

In addition to The conventional bleach activators or in their place may also so-called bleach catalysts are incorporated. In these Substances are bleach-enhancing transition metal salts or transition metal complexes such as Mn, Fe, Co, Ru or Mo saline complexes or carbonyl complexes. Also Mn, Fe, Co, Ru, Mo, Ti, V and Cu complexes with N-containing tripod ligands and Co, Fe, Cu and Ru ammine complexes are useful as bleach catalysts.

Suitable enzymes are those from the class of proteases, lipases, amylases, cellulases or mixtures thereof. Particularly suitable are bacterial strains or fungi, such as Bacillus subtilis, Bacillus licheniformis and Streptomyces griseus derived enzymatic agents. Preferably, subtilisin-type proteases and in particular proteases derived from Bacillus lentus are used. Here, enzyme mixtures, for example from protease and amylase or protease and lipase or protease and cellulase or from cellulase and lipase or from protease, amylase and lipase or protease, lipase and cellulase, but in particular cellulase-containing mixtures are of particular interest. Peroxidases or oxidases have also proved suitable in some cases. The enzymes can bind to carriers be adsorbed and / or embedded in encasing substances to protect them against premature decomposition. The proportion of enzymes, enzyme mixtures or enzyme granules in the moldings according to the invention can be, for example, about 0.1 to 5% by weight, preferably 0.1 to about 2% by weight. The most commonly used enzymes include lipases, amylases, cellulases and proteases. Preferred proteases are, for. B. BLAP ^® 140 from. Biozym, Optimase ^® -M-440 and Opticlean ^® -M-250 from. Solvay enzyme; Maxacal ^® CX and Maxapem ^® or Esperase ^® from Novo. Gist Brocades or Savinase ^® from.. Particularly suitable cellulases and lipases are Celluzym ^® 0.7 T and Lipolase ^® 30 T of Messrs. Novo Nordisk. Particular use as amylases Duramyl ^® and Termamyl ^® 60 T and Termamyl ^® 90 T from. Novo, Amylase-LT ^® from. Solvay Enzymes or Maxamyl ^® P5000 Messrs. Gist Brocades. Other enzymes can also be used.

Also, the agent may have UV absorbers which are applied to the treated fabrics and improve the light fastness of the fibers and / or the lightfastness of other formulation ingredients. Under UV absorber are organic substances (sunscreen) to understand, which are able to absorb ultraviolet rays and the absorbed energy in the form of longer-wave radiation, eg heat to give back. Compounds having these desired properties include, for example, the non-radiative deactivating compounds and derivatives of benzophenone having substituents in the 2- and / or 4-position. Also suitable are substituted benzotriazoles, phenyl-substituted acrylates (cinnamic acid derivatives) in the 3-position, optionally with cyano groups in the 2-position, salicylates, organic Ni complexes and natural substances such as umbelliferone and the body's own urocanic acid. Of particular importance are biphenyl and especially Stilbenderivate as described for example in the EP 0728749 A are described and are available as Tinosorb FD ^{® ®} or Tinosorb FR ex Ciba commercially. As UV-B absorber are 3-benzylidene camphor or 3-Benzylidennorcampher and its derivatives, for example 3- (4-methylbenzylidene) camphor, as in EP 0693471 B1 described; 4-aminobenzoic acid derivatives, preferably 2-ethylhexyl 4- (dimethylamino) benzoate, 2-octyl 4- (dimethylamino) benzoate and 4- (dimethylamino) benzoic acid ester; Esters of cinnamic acid, preferably 4-methoxycinnamic acid 2-ethylhexyl ester, 4-methoxycinnamic acid propyl ester, 4-methoxycinnamic acid isoamyl ester, 2-cyano-3,3-phenylcinnamic acid 2-ethylhexyl ester (octocrylene); Esters of salicylic acid, preferably 2-ethylhexyl salicylate, 4-isopropylbenzyl salicylate, homomenthyl salicylate; Derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone; Esters of benzalmalonic acid, preferably di-2-ethylhexyl 4-methoxybenzmaic acid; Triazine derivatives such as 2,4,6-trianilino (p-carbo-2'-ethyl-1'-hexyloxy) -1,3,5-triazine and octyl triazone, as described in U.S. Pat EP 0818450 A1 Dioctyl Butamido Triazone or described (Uvasorb HEB ^®); Propane-1,3-diones such as 1- (4-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1,3-dione; Ketotricyclo (5.2.1.0) decane derivatives as described in U.S.P. EP 0694521 B1 described. Also suitable are 2-phenylbenzimidazole-5-sulfonic acid and its alkali metal, alkaline earth metal, ammonium, alkylammonium, alkanolammonium and glucammonium salts; Sulfonic acid derivatives of benzophenones, preferably 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its salts; Sulfonic acid derivatives of 3-Benzylidencamphers, such as 4- (2-oxo-3-bomylidenemethyl) benzenesulfonic acid and 2-methyl-5- (2-oxo-3-bomylidene) sulfonic acid and salts thereof.

As a typical UV-A filter in particular derivatives of benzoylmethane are suitable, such as 1- (4'-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1,3-dione, 4-tert-butyl 4'-methoxydibenzoylmethane (Parsol 1789), 1-phenyl-3- (4'-isopropylphenyl) -propane-1,3-dione, and enamine compounds as described in U.S.P. DE 19712033 A1 (BASF). Of course, the UV-A and UV-B filters can also be used in mixtures. In addition to the soluble substances mentioned, insoluble photoprotective pigments, namely finely dispersed, preferably nano-metal oxides or salts, are also suitable for this purpose. Examples of suitable metal oxides are in particular zinc oxide and titanium dioxide and, in addition, oxides of iron, zirconium, silicon, manganese, aluminum and cerium and mixtures thereof. As salts silicates (talc), barium sulfate or zinc stearate can be used. The oxides and salts are already used in the form of the pigments for skin-care and skin-protecting emulsions and decorative cosmetics. The particles should have an average diameter of less than 100 nm, preferably from 5 to 50 nm and in particular from 15 to 30 nm. They may have a spherical shape, but it is also possible to use those particles which have an ellipsoidal or otherwise deviating shape from the spherical shape. The pigments can also be surface-treated, ie hydrophilized or hydrophobized. Typical examples are coated titanium dioxides, for example Titandioxid T 805 (Degussa) or Eusolex ^® T2000 (Merck). Suitable hydrophobic coating agents are in particular silicones and in particular trialkoxyoctylsilanes or simethicones. Preferably, micronized zinc oxide is used.

Other suitable UV photoprotective filters are in the review by P.Finkel in SÖFW Journal 122, 543 (1996).

The UV absorbers are usually in amounts of 0.01% by weight to 5% by weight, preferably of 0.03% by weight to 1 wt .-%, used.

Further conceivable additives are foam inhibitors, for example foam-inhibiting paraffin oil or foam-inhibiting silicone oil, for example dimethylpolysiloxane. The use of mixtures of these agents is possible. Suitable additives which are solid at room temperature include, in particular in the foam-inhibiting active ingredients mentioned, paraffin waxes, silicic acids which may also be hydrophobic in a known manner, and bisamides derived from C _2-7 -diamines and C _12-22 -carboxylic acids.

Suitable foam-inhibiting paraffin oils for use in admixture with paraffin waxes are generally complex mixtures without a sharp melting point. For characterization, the melting range is usually determined by differential thermal analysis (DTA) as described in "The Analyst". 87 (1962), 420, and / or the solidification point. This is the temperature at which the paraffin passes from the liquid to the solid state by slow cooling. Paraffins with less than 17 carbon atoms are not useful in the invention, their proportion in the paraffin oil mixture should therefore be as low as possible and is preferably below the limit significantly measurable by conventional analytical methods, for example gas chromatography. Preferably paraffins are used which solidify in the range of 20 ° C to 70 ° C. It should be noted that even at room temperature appearing paraffin wax mixtures may contain different proportions of liquid paraffin oils. In the case of the paraffin waxes which can be used according to the invention, the liquid fraction at 40 ° C. is as high as possible, without already being 100% at this temperature. Preferred paraffin wax mixtures have at 40 ° C a liquid content of at least 50 wt .-%, in particular from 55 wt .-% to 80 wt .-%, and at 60 ° C, a liquid content of at least 90 wt .-% to. This has the consequence that the paraffins are flowable and pumpable at temperatures down to at least 70 ° C, preferably down to at least 60 ° C. It should also be ensured that the paraffins contain as far as possible no volatile components. Preferred paraffin waxes contain less than 1 wt .-%, in particular less than 0.5 wt .-% at 110 C and atmospheric pressure vaporizable fractions. According to Paraffins for example, under the trade names Luna Flex ^® from Fuller and Deawax ^® DEA Mineralöl AG are based.

The paraffin oils can bisamides solid at room temperature, which differ from saturated ones Fatty acids with 12 to 22, preferably 14 to 18 carbon atoms and of alkylenediamines with 2 to 7 carbon atoms derived. Suitable fatty acids are Laurine, myristic, stearic, arachinic and behenic acid and their Mixtures, as they are made of natural Greases or hardened oils, such as Tallow or hydrogenated palm oil, available are. Suitable diamines are, for example, ethylenediamine 1,3-propylenediamine, Tetamethylenediamine, pentamethylenediamine, hexamethylenediamine, p-phenylenediamine and toluenediamine. Preferred diamines are ethylenediamine and hexamethylenediamine. Particularly preferred bisamides are bis-myristoyl-ethylenediamine, bis-palmitoyl-ethylenediamine, Bis-stearoyl-ethylenediamine and mixtures thereof and the corresponding Derivatives of hexamethylenediamine.

In some embodiments of the invention the foam inhibitors mentioned in the perfume of the invention having soda-containing particles and / or particle mixture containing particles according to the invention and / or finished product.

The soda-containing according to the invention Particles, mixtures and / or finished products may contain dyes, the amount of one or more dyes being so low choose is that after application of the agent no visible residues remain. Preferably, however, the agent according to the invention is free of dyes.

A another embodiment The invention relates to a mixture in addition to perfume according to the invention containing soda-containing particles additionally other soda-containing particles having.

It is inventively preferred that these other soda-containing particles are not nonionic surfactant and / or none Have perfume.

It is further preferred according to the invention that these other soda-containing particles contain at least one anionic surfactant, Have cation surfactant and / or zwitterionic surfactant, wherein it is preferred that they contain at least one anionic surfactant. Most preferably, it is exclusively at least as a surfactant have an anionic surfactant.

The mixture according to the invention may include such soda-containing particles with> 0% by weight and 50% by weight anionic surfactant, preferably ≥5% by weight and ≤40% by weight anionic surfactant, more preferably ≥10% by weight and ≤35 % By weight of anionic surfactant, more preferably> 15% by weight and ≦ 30% by weight of anionic surfactant, and most preferably ≥ 20% by weight and ≦ 26% by weight of anionic surfactant, based on the total weight of soda-containing particles.

Of the Weight fraction of the soda-containing particles, based on the total weight the mixture according to the invention, may be at least 5 wt% to at most 90 wt%, preferably 10 Wt .-% to 80 wt .-%, preferably 20 wt .-% to 70 wt .-%, more preferably from 30% to 60%, and most preferably 40% by weight make up to 50 wt .-%.

The soda-containing particles of the mixture may at least one, preferably have multiple ingredients selected from the group comprising washing, care and / or cleaning substances, anionic Surfactants, cationic surfactants, amphoteric surfactants, builders, Bleaching agents, bleach activators, bleach stabilizers, bleach catalysts, Enzymes, polymers, cobuilders, alkalizers, acidifiers, Anti redeposition agents, silver protectants, colorants, optical brighteners, UV protection substances, fabric softeners, foam inhibitors and / or rinse aid, and optionally further admixed ingredients. As already As described above, it is preferred according to the invention that the others soda-containing particles of the mixture no nonionic surfactant and / or no Have perfume.

In addition, the aftertreated particles containing at least one component, wherein the component amount is preferably up to 20 wt .-%, in particular 1 wt .-% to 15 wt .-%, each based on the total weight of the post-treated soda-containing particles. As components for the Aftertreatment can be solids, preferably bicarbonate, carbonate, Zeolite, silica, Citrate, urea or mixtures thereof, in particular in quantities from 2 to 15 wt .-%, based on the total weight of the aftertreated Products, use.

ingredients the soda-containing particles can in addition to the ingredients already mentioned also anionic surfactants, cationic surfactants, amphoteric surfactants (= zwitterionic surfactants) be.

As anionic surfactants, for example, those of the sulfonate type and sulfates are used. The surfactants of the sulfonate type are preferably C _9-13 -alkylbenzenesulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as are obtained, for example, from C _12-18 -monoolefins having terminal or internal double bonds by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acid hydrolysis of the sulfonation products into consideration. Also suitable are alkanesulfonates which are obtained from C _12-18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization. Likewise, the esters of α-sulfo fatty acids (ester sulfonates), for example the α-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids are suitable.

Further Suitable anionic surfactants are sulfated fatty acid glycerol esters. Among fatty acid glycerol esters are the mono-, di- and triesters and their mixtures to understand as in the preparation by esterification of a monoglycerol with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 moles of glycerol to be obtained. Preferred sulfated fatty acid glycerol esters are included the sulphonated products of saturated Fatty acids with 6 to 22 carbon atoms, for example the caproic acid, caprylic acid, capric acid, myristic acid, lauric acid, palmitic acid, stearic acid or behenic acid.

Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C ₁₂ -C ₁₈ fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C ₁₀ -C ₂₀ oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Also preferred are alk (en) ylsulfates of said chain length, which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials. Of washing technology interest, the C ₁₂ -C ₁₆ alkyl sulfates and C ₁₂ -C ₁₅ alkyl sulfates and C ₁₄ -C ₁₅ alkyl sulfates are preferred. 2,3-alkyl sulfates can be obtained as commercial products from Shell Oil Company under the name DAN ^®, are suitable anionic surfactants.

The sulfuric acid monoesters of straight-chain or branched C _7-21 -alcohols ethoxylated with from 1 to 6 mol of ethylene oxide, such as 2-methyl-branched C _9-11- alcohols having on average 3.5 mol of ethylene oxide (EO) or C _12-18 . Fatty alcohols with 1 to 4 EO are suitable. Due to their high foaming behavior, they are only used in detergents in relatively small amounts, for example in amounts of from 1 to 5% by weight.

Further suitable anionic surfactants are also the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or as sulfosuccinic acid esters and the monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols. Preferred sulfosuccinates contain C _8-18 fatty alcohol residues or mixtures of these. Particularly preferred sulfosuccinates contain a fatty alcohol residue derived from ethoxy derived fatty alcohols, which in themselves constitute nonionic surfactants (see description below). Sulfosuccinates, whose fatty alcohol residues are derived from ethoxylated fatty alcohols with a narrow homolog distribution, are again particularly preferred. Likewise, it is also possible to use alk (en) ylsuccinic acid having preferably 8 to 18 carbon atoms in the alk (en) yl chain or salts thereof.

Of the Content of said anionic surfactants is preferably From 2 to 30% by weight, and more preferably from 5 to 25% by weight, with concentrations above 10% by weight and even above 15% by weight particular Find Favorurng.

In addition to The said anionic surfactants may contain soaps. Particularly suitable are saturated Fatty acid soaps, like the salts of lauric acid, myristic, Palmitic acid, stearic acid, hydrogenated erucic and behenic acid as well in particular of natural fatty acids, e.g. Coconut, palm kernel or tallow fatty acids, derived soap mixtures. The content of direct spray-drying products of soaps preferably not more than 3% by weight and in particular from 0.5 to 2.5% by weight.

The anionic surfactants and soaps can be used in Form their sodium, potassium or ammonium salts and as soluble salts organic bases, such as mono-, di- or triethanolamine. Preferably, they are in the form of their sodium or potassium salts, especially in the form of the sodium salts. Anionic surfactants and Soaps can also be prepared in situ by being spray dried Composition of the anionic surfactant acids and optionally fatty acids are introduced, which then by the alkali carriers in the spray dried Composition be neutralized.

The optionally soda-containing particles and / or finished product may also be cationic Containing surfactants. Suitable cationic surfactants are, for example, surface-active quaternary re Compounds, in particular with an ammonium, sulfonium, phosphonium, Iodonium or arsonium group, as, for example, K. H. Wallhäußer in "Praxis des Sterilisation, Disinfection - preservation : Identification of germs - occupational hygiene "(5th ed. - Stuttgart; New York: Thieme, 1995) as antimicrobial agents. Through the use of quaternary surfactants Compounds having antimicrobial activity may be the particles of the invention and / or particles according to the invention containing finished product designed with an antimicrobial effect or its optionally due to other ingredients already existing antimicrobial effect can be improved.

Particularly preferred cationic surfactants are the quaternary, partially antimicrobial ammonium compounds (QAV, INCI quaternary ammonium Substances) according to the general formula (R ^I ) (R ^II ) (R ^III ) (R ^IV ) N ⁺ X ^- , in which R ^I to R ^IV identical or different C _1-22 -alkyl radicals, C _7-28 -aralkyl radicals or heterocyclic radicals, where two or in the case of an aromatic inclusion as in pyridine even three radicals together with the nitrogen atom, the heterocycle, for example a pyridinium or imidazolinium compound, and X ^{- are} halide ions, sulfate ions, hydroxide ions or like anions. For optimum antimicrobial activity, preferably at least one of the radicals has a chain length of 8 to 18, in particular 12 to 16, carbon atoms.

QAC are tertiary by implementation Amines with alkylating agents, e.g. Methyl chloride, benzyl chloride, Dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced. The alkylation of tertiary amines with a long alkyl radical and two methyl groups succeeds especially easy, also the quaternization of tertiary amines with two long ones Remains and a methyl group can be with the help of methyl chloride be carried out under mild conditions. Amines, over three are long alkyl radicals or hydroxy-substituted alkyl radicals little reactive and are preferably quaternized with dimethyl sulfate.

Suitable QACs are, for example, benzalkonium chloride (N-alkyl-N, N-dimethylbenzylammonium chloride, CAS No. 8001-54-5), benzalkone B (m, p-dichlorobenzyl-dimethyl-C ₁₂ -alkylammonium chloride, CAS No. 58390-78 -6), benzoxonium chloride (benzyldodecyl-bis (2-hydroxyethyl) ammonium chloride), cetrimonium bromide (N-hexadecyl-N, N-trimethyl-ammonium bromide, CAS No. 57-09-0), benzetonium chloride (N, N Dimethyl N- [2- [2- [p- (1,1,3,3-tetramethylbutyl) phenoxy] ethoxy] ethyl] benzyl ammonium chloride, CAS No. 121-54-0), dialkyldimethylammonium chlorides such as di-n- decyl-dimethyl-ammonium chloride (CAS No. 7173-51-5-5), didecyldimethylammonium bromide (CAS No. 2390-68-3), dioctyl-dimethyl-ammoniumchloric, 1-cetylpyridinium chloride (CAS No. 123-03-5) and thiazoline iodide (CAS No. 15764-48-1) and mixtures thereof. Preferred QACs are the benzalkonium chlorides having C ₈ -C ₁₈ -alkyl radicals, in particular C ₁₂ -C ₁₄ -alkyl-benzyl-dimethylammonium chloride. A particularly preferred QAC Kokospentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ^®).

To avoid possible incompatibilities of the antimicrobial cationic surfactants with anionic surfactants contained anionic surfactant and / or as little cationic surfactant as possible or in a particular Embodiment of the invention entirely dispenses with antimicrobial cationic surfactants. Parabens, benzoic acid and / or benzoate, lactic acid and / or lactates can be used as antimicrobial substances. Particularly preferred are benzoic acid and / or lactic acid.

A another embodiment The invention relates to a finished product, the inventive perfume comprising soda-containing particles.

at a finished product according to the invention can it is a detergent, a detergent for hard and / or soft surfaces, a stainless steel cleaner, a household cleaner, an oven cleaner, a conditioner, a laundry detergent, a laundry care product, a fragrance agent, a Hair treatment products, a hair dye, a conditioner, a fabric softener, a conditioning substrate, a medicine, a plant protection product, a food Cosmetic, a fertilizer, a building material, an adhesive, a bleach, a disinfectant and / or a precursor of the aforementioned finished products.

One Inventive finished product can additionally to the perfume of the invention containing soda-containing particles at least one, preferably have multiple components selected from the group comprising as washing, care and / or cleaning substances anionic Surfactants, cationic surfactants, amphoteric surfactants, builders, Bleaching agents, bleach activators, bleach stabilizers, bleach catalysts, Enzymes, polymers, cobuilders, alkalizers, acidifiers, Anti-redeposition agents, silver protectants, colorants, optical brighteners, UV protectants, Fabric softener, foam inhibitors and / or rinse aid, and optionally further admixed ingredients.

It is preferred when the finished product according to the invention, in particular Washing, cleaning and / or care product, at least at least 1% by weight and at most 70% by weight, preferably at most 50 wt .-%, preferably at most 30 wt .-%, more preferably maximum 20 wt%, more preferably 3 wt% to 15 wt%, and most preferably from 5% by weight to 10% by weight of the perfume laden soda-containing material according to the invention Particle, based on the total weight of the finished product, wherein the respective weight fractions are chosen so that these together maximally Make up 100% by weight.

One preferred finished product of the invention relates to tablets or moldings the perfume of the invention have loaded soda-containing particles. As "tablet" or "shaped body" are used in the present application independent of the form of their production dimensionally stable, solid body called. such body can be, for example, by crystallization, molding, injection molding, reactive or thermal sintering, (co) extrusion, compounding, pastillation, or compaction processes such as calendering or tableting produce. The preparation of the "tablets" or "shaped bodies" by tableting is particularly preferred in the context of the present application. The Tablet or shaped body So it is preferably made of compressed, particulate material. Most preferred are tablets or shaped articles in which exclusively the soda-containing particles according to the invention Have perfume.

The having soda-containing perfume according to the invention described above Particles are ideal for incorporation into washing and Cleaning tablets as detergent tablets for the Washing of textiles, automatic dishwashing detergent tablets or the cleaning of hard surfaces, bleach moldings for Use in washing machines or dishwashers, water softening tablets or Stain remover tablets.

One preferred subject of the present invention is therefore the Use of perfume having soda-containing particles, which Mixing with finely divided conditioning components in itself known manner pressed into detergent tablets be, to the stability and solubility of detergent tablets.

By the use of the perfume of the invention having soda-containing particles, which after mixing with further Components are pressed to detergent tablets, the physical properties of the moldings, in particular the mechanical stability and the solubility behavior, be significantly improved. This can be done with low Press Press Detergent tablets produce sufficient mechanical stability in packaging, Transport and handling exhibit. That way you can directly stable tablets at lower pressures, so that the Wear on the tableting machines significantly reduced and their lifetime extended becomes.

One Another object of the present invention relates to washing and Cleaning tablets of compacted particulate Detergents and cleaners, the soda-containing perfume according to the invention Contain particles.

Depending on the intended use, the perfume-containing soda-containing particles can be of the washing and cleaning agent form according to the invention body may be contained in varying amounts in the moldings. In this case, detergent tablets are preferred which contain, based on the weight of the tablet, from 10 to 90% by weight, preferably from 20 to 80% by weight and in particular from 25 to 70% by weight of the soda-containing particles according to the invention.

Around It is to facilitate the disintegration of highly compressed moldings possible, Disintegration aids, so-called tablet disintegrants, in to incorporate these to shorten the disintegration times. Under tablet disintegrants or decay accelerators are according to Römpp (9th edition, Bd. 6, p. 4440) and Voigt "textbook pharmaceutical technology "(6. Edition, 1987, pp. 182-184) understood excipients that are suitable for rapid Disintegration of tablets in water or gastric juice and for release provide the pharmaceuticals in resorbable form.

These Substances that are also referred to as "disintegrants" due to their effect increase in size Water enters its volume, whereby on the one hand the own volume is increased (swelling), on the other hand also over the release of gases can be generated a pressure that the Tablet disintegrates into smaller particles. Well-known disintegration aids are, for example, carbonate / citric acid systems, and others organic acids can be used. Swelling disintegration aids are, for example, synthetic polymers such as polyvinylpyrrolidone (PVP) or natural polymers or modified Natural substances such as cellulose and starch and their derivatives, alginates or casein derivatives.

In a preferred variant of the invention include the washing and Cleaning tablets no disintegration aids. You alone by the Incorporation of the perfume of the invention having soda-containing particles a sufficiently high dissolution rate on.

In another, likewise preferred variant contain the washing and detergent tablets 0.5 to 10 wt .-%, preferably 3 to 7 wt .-% and in particular 4 to 6 wt .-% of one or more disintegration aids, respectively based on the molding body weight.

When preferred disintegrants are within the scope of the present invention Invention disintegrating agent used on cellulose basis, so that preferred detergent tablets and cleaning agent such a disintegrating agent based on cellulose in amounts of 0.5 to 10 wt .-%, preferably Contain 3 to 7 wt .-% and in particular 4 to 6 wt .-%. Pure Cellulose has the gross formal composition (C6H1005) n and formally represents a β-1,4-polyacetate of cellobiose, which in turn consists of two molecules of glucose is constructed. Suitable celluloses consist of about 500 to 5000 Glucose units and therefore have average molecular weights from 50,000 to 500,000. As disintegrating agent based on cellulose it is also possible to use cellulose derivatives in the context of the present invention, which are obtainable by polymer-analogous reactions of cellulose. Such chemically modified celluloses include, for example Products of esterifications or etherifications in which substituted hydroxy hydrogen atoms were. But also celluloses in which the hydroxy groups against functional groups that do not have over an oxygen atom are bonded, can be as Cellulose derivatives deploy. For example, fall into the group of cellulose derivatives Alkali celluloses, carboxymethylcellulose (CMC), cellulose esters and ethers and aminocelluloses. The cellulose derivatives mentioned are preferably not used alone as a cellulose-based disintegrant, but used in mixture with cellulose. The content of these mixtures of cellulose derivatives preferably below 50% by weight, more preferably below 20 Wt .-%, based on the disintegrating agent based on cellulose. Particularly preferred is cellulose-based disintegrant pure cellulose used, which is free of cellulose derivatives.

The cellulose used as a disintegration aid is preferably not used in finely divided form, but converted into a coarser form, for example granulated or compacted, before it is added to the premixes to be tabletted. Detergents and cleaning agent tablets containing disintegrators in granular or optionally cogranulated form are described in the German patent applications DE 197 09 991 and DE 197 10 254 and International Patent Application W098 / 40463. Further details of the production of granulated, compacted or cogranulated cellulose explosives can be found in these publications. The particle sizes of such disintegrating agents are usually above 200 .mu.m, preferably at least 90 wt .-% between 300 and 1600 .mu.m and in particular at least 90 wt .-% between 400 and 1200 microns. The above and described in more detail in the documents cited coarser disintegration aids, are preferred as disintegration aids and are commercially available, for example under the name of Arbocel ^® TF-30-HG from Rettenmaier available in the present invention.

As a further disintegrating agent based on cellulose or as a component of this component, microcrystalline cellulose can be used. This microcrystalline cellulose is prepared by partial hydrolysis of celluloses under such conditions receive only the amorphous areas (about 30% of the total cellulose mass) of the celluloses and completely dissolve, the crystalline areas (about 70%) but leave undamaged. Subsequent deaggregation of the microfine celluloses produced by the hydrolysis yields the microcrystalline celluloses which have primary particle sizes of about 5 μm and can be compacted, for example, into granules having an average particle size of 200 μm.

in the Within the scope of the present invention, preferred washing and cleaning agent tablets additionally a disintegration aid, preferably a disintegration aid based on cellulose, preferably in granular, cogranulated or compacted form, in amounts of 0.5 to 10 wt .-%, preferably from 3 to 7% by weight and especially from 4 to 6% by weight, respectively based on the molding body weight.

Next the ingredients mentioned as the perfume of the invention containing soda-containing particles and disintegration aids, can they detergent and cleaner tablets according to the invention additionally or several substances preferably from the groups of bleaches, bleach activators, Enzymes, pH modifiers, fluorescers, dyes, foam inhibitors, Silicone oils, Anti redeposition agents, optical brighteners, grayness inhibitors, Color transfer inhibitors, corrosion inhibitors and silver protectants. Suitable substances have already been above, for the perfume of the invention containing soda-containing particles described here in the is fully referred to.

Also When using the bleach, it is possible to rely on the use of Surfactants and / or builders to dispense, so that pure bleach tablets can be produced. If such bleach tablets are to be used for textile washing, is a combination of sodium percarbonate with sodium sesquicarbonate preferred, independent of which other ingredients are contained in the moldings.

Become Prepared cleaning or bleaching tablets for automatic dishwashing, see above can Also bleach from the group of organic bleach used become. Typical organic bleaches are the diacyl peroxides, like dibenzoyl peroxide. Other typical organic bleaches are the peroxyacids, Examples being the alkyl peroxyacids and the aryl peroxyacids become. Preferred representatives are (a) the peroxybenzoic acid and their ring-substituted derivatives, such as alkylperoxybenzoic acids, but also peroxy-α-naphthoic acid and Magnesium monoperphthalate, (b) the aliphatic or substituted aliphatic peroxyacids, like peroxylauric acid, Peroxystearic acid, ε-phthalimidoperoxycaproic acid [phthaloiminoperoxyhexanoic acid (PAP)], o-carboxybenzamidoperoxycaproic acid, N-nonenylamidoperadipic acid and N-nonenylamidopersuccinates, and (c) aliphatic and araliphatic peroxydicarboxylic, such as 1,12-diperoxy carboxylic acid, 1,9-diperoxyazelaic acid, Diperocysebacinsäure, diperoxybrassylic, the diperoxyphthalic acids, 2-decyldiperoxybutane-1,4-dioic acid, N, N-Terephthaloyl-di (6-aminopercapronate) can be used.

When Bleaching agents in moldings for the automatic dishwashing can Chlorine or bromine releasing substances are used. Under the appropriate chlorine or bromine releasing materials come for example, heterocyclic N-bromo and N-chloroamides, for example trichloroisocyanuric, tribromoisocyanuric, dibromoisocyanuric and / or dichloroisocyanuric acid (DICA) and / or their salts with cations such as potassium and sodium into consideration. Hydantoin compounds, such as 1,3-dichloro-5,5-dimethylhydanthoin are also suitable.

In addition to The conventional bleach activators or in their place may also so-called bleach catalysts are incorporated into the moldings, which have already been described above.

In addition, the Detergent tablets Also contain components that the oil and Fettauswaschbarkeit from textiles positively influence (so-called soil repellents). This effect is particularly evident when a textile is dirty is, which previously several times with a detergent according to the invention, that this oil and fat-dissolving Component contains was washed. Among the preferred oil and fat dissolving components counting for example, nonionic cellulose ethers such as methyl cellulose and methylhydroxypropylcellulose with a proportion of methoxyl groups from 15 to 30% by weight and of hydroxypropoxyl groups from 1 to 15 Wt .-%, each based on the nonionic cellulose ether, and the known from the prior art polymers of phthalic acid and / or of terephthalic acid or of their derivatives, in particular polymers of ethylene terephthalates and / or polyethylene glycol terephthalates or anionic and / or nonionically modified derivatives of these. Especially preferred of these are the sulfonated derivatives of phthalic acid and the terephthalic acid polymers.

The shaped bodies may contain, as optical brighteners, derivatives of diaminostilbenedisulfonic acid or its alkali metal salts. Suitable examples are salts of 4,4'-bis (2-anilino-4-morpholino-1,3,5-tria Zinyl-6-amino) stilbene-2,2'-disulfonic acid or similarly constructed compounds which carry a diethanolamino group, a methylamino group, an anilino group or a 2-methoxyethylamino group instead of the morpholino group. Furthermore, brighteners of the substituted diphenylstyrene type may be present, for example the alkali metal salts of 4,4'-bis (2-sulfostyryl) -diphenyl, 4,4'-bis (4-chloro-3-sulfostyryl) -diphenyl, or (4-chlorostyryl) -4 '- (2-sulfostyryl) -diphenyls. Mixtures of the aforementioned brightener can be used.

color and fragrances, as described above, can be added to the detergent tablets according to the invention be to the aesthetic Improve the impression of the products and the consumer in addition to the Softness performance is a visually and sensory "typical and unmistakable" product available too put.

When Perfume oils or fragrances can preferably to the fragrances already described above individual Fragrance compounds, e.g. the synthetic products of the type the esters, ethers, aldehydes, ketones, alcohols and hydrocarbons used become. Fragrance compounds of the ester type are known e.g. benzyl acetate, Phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, Linalyl acetate, dimethylbenzylcarbinylacetate, phenylethylacetate, Linalyl benzoate, benzyl formate, ethyl methyl phenyl glycinate, allyl cyclohexyl propionate, Styrallyl propionate and Benzylsalicylate. Ethers include, for example, benzyl ethyl ether, to the aldehydes e.g. the linear alkanals with 8-18 carbon atoms, citral, Citronellal, citronellyloxyacetaldehyde, cyclamenaldehyde, hydroxycitronellal, Lilial and Bourgeonal, to the ketones e.g. the Jonone, □ -isomethyl-ionone and methyl cedryl ketone, to the alcohols anethole, citronellol, eugenol, geraniol, Linalool, phenylethyl alcohol and terpineol, to the hydrocarbons belong mainly the Terpenes like limes and pinas. However, mixtures are preferred different fragrances used, which together create an appealing Create a fragrance. Such perfume oils can also natural Contain fragrance mixtures, as they are accessible from plant sources, e.g. Pine, citrus, jasmine, patchouly, rose or ylang-ylang oil. Also suitable Muscat, sage oil, Chamomile oil, Clove oil, Balm oil, Mint oil, cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil and labdanum oil, as well as Orange blossom oil, neroliol, Orange peel oil and Sandalwood oil.

Usually is the content of the detergent tablets according to the invention Dyes below 0.01 wt .-%, while perfumes up to 2% by weight of the total formulation.

The Fragrances can directly into the agents according to the invention incorporated, but it can also be beneficial, the fragrances to apply on carrier, which increase the adhesion of the perfume to the linen and a slower one Fragrance release for long-lasting fragrance of the textiles. As such carrier materials For example, cyclodextrins have proven useful, with the cyclodextrin-perfume complexes additionally can still be coated with other excipients.

Around the aesthetic Impression of the agents according to the invention to improve they are dyed with suitable dyes. Preferred dyes, the selection of which the expert has no difficulty, own a high storage stability and insensitivity to the rest Ingredients of the middle! and against light and no pronounced substantivity to textile fibers, so as not to stain them.

Dishwashing detergent tablets according to the invention can be used for Protection of the dishes or the machine contain corrosion inhibitors, taking particular Silver protection agent in the field of automatic dishwashing have special meaning. In general, especially silver protectants selected from the group of triazoles, benzotriazoles, bisbenzotriazoles, the aminotriazoles, the alkylaminotriazoles and the transition metal salts or complexes are used. Particularly preferable to use are benzotriazole and / or alkylaminotriazole.

you In addition, cleaning agent formulations often contain active chlorine Means that can significantly reduce the corrosion of the silver surface. In Chlorine-free cleaners are especially oxygen- and nitrogen-containing organic redox-active compounds, such as di- and trihydric phenols, z. Hydroquinone, catechol, hydroxyhydroquinone, gallic acid, phloroglucinol, Pyrogallol or derivatives of these classes of compounds. Also salt and complex Inorganic compounds, such as salts of the metals Mn, Ti, Zr, Hf, V, Co and Ce are common Use. Preferred here are the Übergangsmetaflsalze which are selected from the group of manganese and / or cobalt salts and / or complexes, particularly preferably the cobalt (ammin) complexes, the cobalt (acetate) complexes, the cobalt (carbonyl) complexes; the chlorides of cobalt or manganese and manganese sulfate. Also, zinc compounds can help prevent it corrosion on the items to be washed be used.

Particular ingredients that can be used in the invention for machine dishwashing or cleaning hard surfaces are Substan zen, which prevent the re-soiling of surfaces and / or facilitate the soil release after a single application (so-called "soil release compounds").

To The usable soil release compounds all include the prior art known compounds. Particularly suitable are cationic polymers, such as hydroxypropyltrimethylammonium guar; copolymers of aminoethyl methacrylate and acrylamide and copolymers of dimethyldiallylammonium chloride , and acrylamide, polymers with imino groups, cationic cellulose derivatives, cationic homo- and / or copolymers (monomer units: quaternized Ammonium alkyl).

Especially The cationic polymers are preferably selected from cationic polymers of copolymers of monomers such as trialkylammonium alkyl (meth) acrylate or -acrylamide; Dialkyldiallyldiammoniumsalze; polymeranalogous Reaction products of ethers or esters of polysaccharides with Ammonium side groups, in particular guar, cellulose and starch derivatives; Polyadducts of ethylene oxide with ammonium groups; quaternary ethyleneimine polymers and polyesters and polyamides having pendant quaternary groups as soil release compounds. Exceptionally preferred In the context of this application are also natural polyuronic acids and related substances, as well as polyampholytes and hydrophobized polyampholytes, or mixtures of these substances.

In The moldings of the invention can all ingredients described above are used; in addition to the phosphate compounds according to the invention can also other builders in the moldings be included. In the detergent tablets according to the invention, in addition to the phosphate compounds water-soluble and water-insoluble Builder mainly used for binding calcium and magnesium become. Here are for Detergent Tablets water-soluble builder preferred because They usually do less on crockery and hard surfaces tend to be insoluble To form residues. Usual builders, in the context of the invention between 10 and 90 wt .-% based on the Whole preparation may be present, in addition to the already mentioned above Build the low molecular weight polycarboxylic acids and their salts, the carbonates and silicates. To water-insoluble builders counting the zeolites, which can also be used, as well as mixtures the abovementioned builder substances. In addition to the phosphate compounds according to the invention, trisodium citrate is preferred and / or sodium carbonate and / or sodium bicarbonate and / or gluconates and / or silicate builders from the class of disilicates and / or Metasilicates or the layered silicates used.

When other ingredients can alkali carriers are present in the soda-containing particles. To be considered as alkali carriers Alkali metal hydroxides, alkali metal carbonates, alkali metal bicarbonates, Alkali metal sesquicarbonates, alkali silicates, alkali metal silicates, and Mixtures of the abovementioned substances, in the context of this invention preferably the alkali metal carbonates, in particular sodium carbonate, sodium bicarbonate or sodium sesquicarbonate.

In Inventive detergent tablets for machine Cleaning dishes can be also other bleaching agents are used. Preferably, the Bleaching performance of bleach-containing moldings such as detergent tablets, Detergent tablets or bleach tablets through use increased by bleach activators, preferably from the group of polyacylated Alkylenediamines, especially tetraacetylethylenediamine (TAED), the N-acylimides, especially N-nonanoylsuccinimide (NOSI), which are acylated Phenolsulfonates, especially n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), n-methyl-morpholinium acetonitrile-methyl sulfate (MMA) and / or the bleach-enhancing transition metal complexes, in particular with the central atoms Mn, Fe, Co, Cu, Mo, V, Ti and / or Ru, preferably from the group of manganese and / or cobalt salts and / or complexes, particularly preferably the cobalt (ammin) complexes, the cobalt (acetate) complexes, cobalt (carbonyl) complexes, the chlorides of cobalt or Manganese and / or manganese sulfate is mixed.

Contains the inventive molding next the soda-containing particles already having the perfume separately Surfactants, so these are in the calculation of a total surfactant content too consider. Usually the surfactant content of detergent tablets is between 10 and 40 wt .-%, preferably between 12.5 and 30 wt .-% and in particular between 15 and 25 wt .-% while Detergent tablets for automatic dishwashing between 0.1 and 10 wt .-%, preferably between 0.5 and 7.5 wt .-% and in particular between 1 and 5 wt .-% surfactants. Bleach tablets and water softener tablets are common free of surfactants.

Above has already been mentioned that in the moldings Other builders may be included. Accordingly, can It may also be preferred within the scope of the invention that these further Builders, preferably at least one aluminosilicate and / or a layered silicate, with the molded body components be mixed.

As already mentioned above, can the washing and detergent molding contain further ingredients of detergents and cleaners. A preferred method in the context of the present invention characterized in that the premix additionally comprises a disintegration aid, preferably a cellulose-based disintegration aid, preferably in granular, cogranulated or compacted form, in amounts of from 0.5 to 10% by weight, preferably from 3 to 7% by weight and in particular from 4 to 6 wt .-%, each based on the weight of the premix, contains, in addition to it it is preferred that the premix additionally one or more substances from the group of enzymes, pH adjusters, fragrances, perfume carriers, fluorescers, Dyes, foam inhibitors, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, color transfer inhibitors, Contains corrosion inhibitors and silver protectants.

In front the compression of the particulate premix to detergent tablets, the premix with finely divided surface treatment agents are "powdered". This can for the Texture and physical properties of both the premix (Storage, compression) and the finished detergent tablets of Be an advantage. Finely divided powdering agents are known in the art well-known, with mostly zeolites, silicates or other inorganic Salts are used. However, the premix is preferred with finely divided zeolite "powdered", wherein zeolites of the faujasite type are preferred. In the context of the present invention features the term "zeolite of faujasite type "all three zeolites containing the faujasite subgroup of the zeolite structure group 4 (Compare Donald W. Breck: "Zeolite Molecular Sieves", John Wiley & Sons, New York, London, Sydney, Toronto, 1974, page 92). In addition to the zeolite X are including zeolite Y and faujasite and mixtures of these compounds can be used, wherein the pure zeolite X is preferred.

Also Mixtures or cocrystallizates of faujasite-type zeolites with other zeolites, not necessarily the zeolite structure group 4 belong have to, are used as Abpude means, it is advantageous if at least 50% by weight of the powdering agent consists of a zeolite consist of faujasite type.

The Production of the shaped body according to the invention takes place preferably first by the dry mixing of the ingredients, in whole or in part can be pre-granulated, and subsequent Informing, in particular compression to tablets, wherein conventional Method used can be. For the preparation of the shaped body according to the invention, the premix is in a so-called matrix between two stamps to a solid Compacted compressed. This process, hereinafter referred to briefly as Tableting is divided into four sections: Dosing, compaction (elastic deformation), plastic deformation and Ejecting.

First, will introduced the premix in the die, wherein the filling amount and thus the weight and the shape of the resulting molded body the position of the lower punch and the shape of the pressing tool be determined. The constant dosage even at high molding throughputs is preferably over reached a volumetric dosage of the premix. In the further Touched the course of tableting the upper stamp the pre-mix and lower in the direction of of the lower punch. In this compression, the particles become closer to the premix pressed together wherein the void volume within the filling between the punches decreases continuously. From a certain position of the upper punch (and thus from a certain pressure on the premix) begins the plastic deformation, in which the particles flow together and it for the formation of the molding comes. Depending on the physical properties of the premix Part of the premix particles is also crushed and it comes at even higher pressures a sintering of the premix. With increasing pressing speed, So high throughput, the phase of elastic deformation ever shorter, so that the resulting mold more or lesser ones cavities can have. In the last step of tabletting the finished molding is through pushed the lower punch out of the die and through subsequent Transportation transported away. At this time, only the weight of the molded article is finally determined, there the compacts due to physical processes (re-expansion, crystallographic Effects, cooling etc.) can change their shape and size.

The Tableting is carried out in commercially available tablet presses, which in principle be equipped with single or double punches can. In the latter case, not only the upper punch for pressure build-up also the lower punch moves during the pressing process on the upper temple too, while the upper punch presses down.

For small production quantities, eccentric tablet presses are preferably used in which the die or punches are attached to an eccentric disc, which in turn is mounted on an axis at a certain rotational speed. The movement of these dies is comparable to the operation of a conventional four-stroke engine. The compression can be done with a respective upper and lower punch, but it can also be attached more stamp on an eccentric disc, the number of Matrizenbohrungen is extended accordingly. The throughputs of eccentric presses vary depending on the type of a few hundred to a maximum of 3000 tablets per hour.

For larger throughputs, choose Rotary tablet presses in which on a so-called die table A larger number of matrices circular is arranged. The number of matrices varies depending on the model 6 and 55, although larger matrices available in the stores are. Each die on the die table is a top and bottom stamp assigned, in turn, the pressing pressure active only by the Upper or lower stamp, but also constructed by both stamps can be. The die table and the stamps move around one common vertical axis, with the stamps with the help rail-like curved tracks during of circulation in the positions for filling, Compression, plastic deformation and ejection are brought. In the places where a particularly serious increase or decrease in the Stamp is required (filling, Compacting, ejecting), These curves are through additional low pressure pieces, Nierderzugschienen and lifting tracks supported. The filling the matrix is over a rigidly arranged supply device, the so-called filling shoe, the one with a reservoir for the Premix is connected. The pressing pressure on the premix is about the compression paths for upper and lower punch individually adjustable, the pressure build-up by advancing the punch shaft heads on adjustable pressure rollers happens.

Rotary presses can to increase the throughput with two filling shoes be provided, wherein for the preparation of a tablet only one Semicircle must be traversed. To produce two-layered and multi-layered shaped bodies, several filling shoes are used arranged one behind the other, without the slightly pressed first Layer before further filling pushed out becomes. By suitable process control are coat and point tablets produced in this way, the have a onion-like structure, wherein in the case of the point tablets not covering the top of the core or core layers and thus remains visible. Also rotary tablet presses are Equipped with single or multiple tools, so that for example an outer circle with 50 and an inner circle with 35 holes at the same time for pressing to be used. The throughputs modern rotary tablet presses amount to over one million moldings per Hour.

in the According to the present invention suitable tabletting machines are available, for example at the companies Apparatebau. Holzwarth GbR, Asperg, Wilhelm Fette GmbH, Schwarzenbek, Hofer GmbH, Weil, KILIAN, Cologne, KOMAGE, Kell am See, KORSCH Press GmbH, Berlin, Mapag Maschinenbau AG, Berne (CH) and Courtoy N.V., Halle (BE / LU). For example, the hydraulic is particularly suitable Double printing press HPF 630 of the company LAEIS, D.

The moldings can manufactured in a predetermined spatial form and predetermined size become. As a form of space virtually all useful manageable Embodiments into consideration, for example, the training as a blackboard, the bar or bar form, cubes, cuboids and the like Room elements with flat side surfaces and in particular cylindrical Embodiments with circular or oval section. This last embodiment detects the presentation form of the tablet to compact cylinder pieces with a relationship of height to diameter above 1.

The portioned compacts can each formed as separate individual elements be that of the predetermined dosage amount of the washing and / or cleaning agents equivalent. But it is also possible compacts form a plurality of such mass units in a compact, in particular by predetermined predetermined breaking points, the light Separability portioned smaller units is provided. For the Use of laundry detergents in machines common in Europe Type with horizontally arranged mechanics can be the training of the portioned compacts be useful as tablets, in cylindrical or cuboidal form, being a diameter / height ratio in the Range of about 0.5: 2 to 2: 0.5 is preferred. Commercial hydraulic presses, Eccentric presses or rotary presses are suitable devices, in particular for the production of such dies.

The Room shape of another embodiment the molded body is in its dimensions of the dispenser of commercial Household washing machines adapted, so that the moldings without Dosing aid directly into the dispenser can be metered in, where they are during the flushing process dissolves. Of course but is also a use of detergent tablets via a dosing easily possible and preferred in the context of the present invention.

Another preferred molded article which can be produced has a plate-like or tabular structure with alternately thick long and thin short segments, so that individual segments of this "bar" at the predetermined breaking points, which represent the short thin segments, can be broken off and entered into the machine. This principle of the "bar-shaped" shaped body wash can also be realized in other geometric shapes, for example vertical triangles, which are joined together only on one side thereof.

Is possible but it also does not make the various components uniform Tablet pressed be, but that shaped body be obtained, the several layers, so at least two layers, exhibit. It is also possible the different dissolution rates of these different layers exhibit. From this you can advantageous performance properties of the molded articles result. For example, if components are contained in the moldings that are mutually negatively affect, so it is possible the one component in the faster soluble Layer and integrate the other component into a slower one soluble Incorporate layer so that the first component already reacted has, if the second in solution goes. The layer structure of the molded body can be both stacked take place, being a solution process the inner layer (s) already takes place at the edges of the shaped body, if the outer layers are still not completely solved but it can also be a complete wrapping of the inner layer (s) each further out lying (s) layer (s) are achieved, resulting in a prevention the early one solution of constituents of the inner layer (s).

In a further preferred embodiment The invention consists of a molded body from at least three layers, so two outer and at least one inner layer, wherein at least in one of the inner layers a peroxy bleach is contained, while in the stacked shaped body the both outer layers and the envelope-shaped body the outermost However, layers are free of peroxy bleach. Furthermore is it also possible Peroxy bleach and optionally present bleach activators and / or enzymes spatially in a shaped body separate from each other. Such multilayer moldings have the Advantage that they not only about a Einspülkammer or over a metering device, which is added to the wash liquor, can be used; rather, it is in such cases also possible, the shaped body in direct contact with the textiles in the machine without giving the stains by bleach and the like would be feared.

Similar Effects can also be achieved by coating ("coating") individual components of the material to be pressed Achieve detergent and cleaner composition or the entire molding. You can do this for example, the body to be coated with aqueous solutions or Emulsions be, or over the process of melt coating obtained a coating.

To the pressing, the detergent tablets have a high stability. The breaking strength of cylindrical Shaped body can over the Measured variable of the diametrical Breaking stress detected become. This can be determined by σ = 2PπDt.

Here in σ stands for the diametrical one Diametral fracture stress (DFS) in Pa, P is the force in N, which leads to the pressure exerted on the molded body, the causing the breakage of the molding, D is the shaped body diameter in meters and t is the height the molded body.

The perfume of the invention containing soda-containing particles can be post-treated, for example, by the respective soda-containing and / or soda-containing Particles of the direct spray-drying product rounded.

The Rounding of the direct spray-drying product can in a usual Run rounder. Preferably, the rounding time is included no longer than 4 minutes, especially not more than 3.5 minutes. rounding of not more than 1.5 minutes or less are particularly preferred. The rounding becomes a further standardization of the grain spectrum achieved, since any resulting coarse particles zerklei nert be.

Especially can be particles according to the invention and / or finished product subsequently with solids, preferably in amounts of up to 15 wt .-%, in particular in amounts of 2 to 15 wt .-%, each based on the total weight the post-treated particles or finished product, nachbehanden.

When Components for the aftertreatment can be solids, preferably bicarbonate, Carbonate, zeolite, silicic acid, Citrate, urea or mixtures thereof, in particular in quantities from 2 to 15 wt .-%, based on the total weight of the aftertreated Products, use. The aftertreatment can be advantageously in a mixer and / or by means of mills.

In the post-treatment step, it is therefore possible to use particles according to the invention with a solid, for example silicic acids, zeolites, carbonates, bicarbonates and / or sulfates, citrates, urea or mixtures thereof, as is well known in the art. It is preferred to use solids, in particular bicarbonate and soda, in amounts of up to 15% by weight and in particular in amounts of from 2 to 15% by weight, based in each case on the after-treated product.

In a preferred embodiment of the invention is the finished product with nonionic surfactants, which contain, for example, optical brighteners and / or hydrotropes can, Perfume, a solution of optical brighteners and / or foam inhibitors or preparation forms, which may contain these ingredients, aftertreated. Preferably These ingredients or formulations containing these Contain ingredients in liquid, melted or pasty Form applied to particles of the finished product.

advantageously, are particles of the finished product according to the invention with up to 20% by weight, advantageously with 2 to 18% by weight and in particular with 5 to 15 wt .-% of active ingredient of the ingredients mentioned treated. The quantities are in each case based on the aftertreated product. It is preferred that the aftertreatment with the here mentioned Substances in a usual Mixer, for example only in a 2-wave mixer within a maximum 1 minute, preferably within 30 seconds and for example within 20 seconds, whereby the time and mixing time stands.

Yet An object of the present invention relates to a method for the production of soda-containing particles.

Advantageous is that one to carry out the inventive method Can use free-fall mixers.

When Free-fall mixers are in the context of the present invention Designates mixer in which the mix picked up by wall friction and then due to its own gravity falls freely through the mixer room. Particularly according to the invention suitable is the use of a Doppelwellen discount mixer.

such Free fall mixers have a moving mixing tank. Suitable as a container those with simple geometric shapes (cylinders, simple or double cone, cube etc.). Preferred mixing containers also have as obtuse an angle as possible Inner corners on, as this both the free movement of the mix as well as the emptying and cleaning of the container after completion of the process is relieved. The movement of the container must be so on the mix transferred inside, so that one possible irregular clutter and loosening the reaction mixture takes place. Furthermore must be at the continuous invention Procedures a directed motion component occur around the continuous To ensure mass transfer. When Movement types for the free-fall mixer is particularly suitable for rotating around a container axis (Drum or rotary tube mixer) or axes that are not geometric Axes of the container match or to whose symmetry planes are perpendicular (tumble mixers), or vibrating, preferably with high amplitude and low frequency as well as changing directions of the rashes, leaving irregular shaking or staggering movements occur.

in the Under the present invention preferred free-fall mixer are Drum mixer, tumble mixer, cone mixer, double cone mixer or V-mixer.

The used according to the invention Free-fall mixers provide for rotating or tumbling movements alternating with the good carried up inside and falling again inclined walls and thus redirecting, widening or narrowing the space, shifting and division of the good flow. Such mixers can be fixed installations for the better Loosening of the mix, e.g. Liftlists, exhibit.

According to the invention preferred However, usable mixers have different from those customary in the prior art High or low speed mixer no mixing or cutting tools on.

at the invention used Free fall mixers are mixers, which are characterized by a movable or rotating reactor housing, or a moving mixing vessel, distinguished. Such reactors can furthermore static and / or mobile mixing and / or cutting tools exhibit. However, preference is given to rotating reactors, in which the mix is lifted by wall friction and then due your own gravity falls freely through the mixer room. When container such a free fall mixer are those with simple geometric shapes, such as cylinders, single or double cone, cube, etc.

In addition, preferred mixing containers have as far as possible obtuse-angled inner corners, since this facilitates both the free movement of the mixed material and the emptying and cleaning of the container after the end of the process. The movement of the container is vorzugswei se so on the mix inside, so that the most irregular possible confusion and loosening of the reaction mixture. In addition, in preferred continuous processes according to the invention, a directional component of motion occurs in order to ensure the continuous transport of the current. As types of movement for the tumbler mixer is particularly suitable rotating about a container axis, such as drum or rotary tube mixer, or about axes that do not coincide with geometric axes of the container or to its Symmetrieebenen are perpendicular, such as tumble mixer, or vibrating, preferably high-amplitude, low-frequency and alternating directions of rashes, so that irregularly shaking or tumbling movements occur.

In a preferred embodiment the method according to the invention forms the solid support material moved in the tumbler mixer, especially soda, a falling powder curtain on which the Fragrances or perfume sprayed on become.

Especially preference is given to processes according to the invention, in which as a free fall mixer double cone mixer with rotatable container be used without mixing tools, the double cone mixer are divided into a mixing zone and a post-mixing zone and a Have tee bar, which is attached to a face plate and from there traverses the entire mixing zone and optionally extends into the post-mixing zone. In the invention especially preferably used double-cone mixers is the ratio of the length of the mixing zone to the length of Post-mixing zone preferably at least 1: 1.

The Abschlagleiste can have a width of 50 mm to 150 mm, preferably from 75 mm to 130 mm. The upper edge of the tee bar points a distance to the inner mixer wall, which preferably maximum 10% of the drum diameter of the narrowest part of the rotatable container preferably at most 5% of the narrowest point of the rotatable container and in particular less than 2.5% of the narrowest point of the rotatable container makes. In the post-mixing zone, the distance to the nearest internal mixer wall may well to be taller as in the mixing zone; Values between 100 and 300 mm are quite common.

For the continuous Operation, in particular those free-fall mixers are particularly suitable, the to rotate about their horizontal, preferably about their little inclined axis. Due to the inclination of the axis of rotation, the mix due one's own gravity, a directed movement, which one continuous discharge of the mix from the mixer allows. Such a directed movement can except by the inclination of the axis of rotation Of course also by a continuous entry of solid support material, like soda, are produced.

For the product properties, especially for the adjustment of the bulk density and the solubility the reaction products, it has proved to be advantageous if the angle of inclination of the axis of rotation of a preferably used rotatable container correlated with a certain number of revolutions. It will therefore such inventive method especially preferred in which the rotatable container of the tumbler mixer a Inclination angle of ≥ 0 ° to 20 °, in particular from 0 ° to 15 °, whole more preferably from 1 ° to 15 ° and the movement of the rotatable container of the tumbler over the Drive at the same time to 20 to 70 revolutions per minute and in particular is set to 30 to 60 revolutions per minute. The number of revolutions should preferably be set so that the Froude number is between ≥ 0 and ≤ 3.

The Residence time of the reaction mixture in the rotatable container is in preferred embodiments the present inventive method preferably less than 20 minutes, preferably 1 minute to 10 minutes, more preferably between 2 minutes to 8 minutes and in particular 3 minutes to 6 minutes.

To passing through the post-mixing zone, the finished product can either directly above discharged or over a conveyor be further processed, with further additions or Components, in particular surface modifiers the well-known kind, about a solids feed can be added. The aftertreatment of the process products after discharge from the Free fall mixer on a reaction line is a hallmark especially preferred embodiments the present inventive method, again, such process variants are especially preferred be, in which it is the reaction path to a pneumatic Fluidized bed and / or a conveyor belt and / or a mixer is. Leads these subsidies and metering screw into the post-mixing zone, is possible also a direct connection of the conveyor to the discharge unit, so it is preferred that the screw only a maximum in the second Half of the length of Post-mixing zone and thus does not protrude into the part of the post-mixing zone, which still contains the tee bar.

• – ≥ 0 Gew.-% bis 20 Gew.-% Silikat, besonders bevorzugt 1 Gew.-% bis 15 Gew.-% Silikat und am meisten bevorzugt 5 Gew.-% bis 10 Gew.-% Silikat; und/oder
• – 1 Gew.-% bis 40 Gew.-% Polymer, besonders bevorzugt 5 Gew.-% bis 30 Gew.-% Polymer und am meisten bevorzugt 10 Gew.-% bis 20 Gew.-% Polymer; und/oder
• – ≥ 0 Gew.-% bis 5 Gew.-% Phosphonat, besonders bevorzugt 0,01 Gew.-% bis 2 Gew.-% Phosphonat und am meisten bevorzugt 0,5 Gew.-% bis 1 Gew.-% Phosphonat; und/oder
• – ≥ 0 Gew.-% bis 30 Gew.-% Phosphat, besonders bevorzugt 5 Gew.-% bis 25 Gew.-% Phosphat und am meisten bevorzugt 10 Gew.-% bis 20 Gew.-% Phosphat; und/oder
• – ≥ 0 Gew.-% bis 50 Gew.-% Sulfat, besonders bevorzugt 5 Gew.-% bis 35 Gew.-% Sulfat und am meisten bevorzugt 10 Gew.-% bis 25 Gew.-% Sulfat; und/oder
• – ≥ 0 Gew.-% bis 5 Gew.-% Seife, besonders bevorzugt 0,01 Gew.-% bis 3 Gew.-% Seife und am meisten bevorzugt 0,05 Gew.-% bis 1 Gew.-% Seife; enthalten, wobei

die Gewichtsgehalte der Trägermaterialien der sodahaltigen Partikel einschließlich der Gewichtsgehalte von Parfum sowie gegebenenfalls weiterer Zusätze so gewählt sind, dass diese 100 Gew.-% nicht übersteigen.For example, for the preparation of the fragrance-laden particles containing soda-containing particles of the carrier soda, and given if further excipients are added, which are preferably selected from the group comprising:

• - ≥ 0 wt .-% to 20 wt .-% silicate, particularly preferably 1 wt .-% to 15 wt .-% silicate and most preferably 5 wt .-% to 10 wt .-% silicate; and or
• From 1% to 40% by weight of polymer, more preferably from 5% to 30% by weight of polymer, and most preferably from 10% to 20% by weight of polymer; and or
• - ≥ 0 wt .-% to 5 wt .-% phosphonate, particularly preferably 0.01 wt .-% to 2 wt .-% phosphonate and most preferably 0.5 wt .-% to 1 wt .-% phosphonate; and or
• - ≥ 0 wt .-% to 30 wt .-% phosphate, particularly preferably 5 wt .-% to 25 wt .-% of phosphate and most preferably 10 wt .-% to 20 wt .-% of phosphate; and or
• - ≥ 0 wt .-% to 50 wt .-% sulfate, more preferably 5 wt .-% to 35 wt .-% sulfate, and most preferably 10 wt .-% to 25 wt .-% sulfate; and or
• - ≥ 0 wt .-% to 5 wt .-% soap, particularly preferably 0.01 wt .-% to 3 wt .-% soap and most preferably 0.05 wt .-% to 1 wt .-% soap; contain, where

the weight contents of the carrier materials of the soda-containing particles, including the weight contents of perfume and, if appropriate, further additives are chosen such that they do not exceed 100% by weight.

The Residence time of the reaction mixture comprising carrier / e in the rotatable Mixer or container is preferably less than 20 minutes, preferably 1 minute to 10 minutes, more preferably between 2 minutes to 8 minutes and in particular 3 minutes to 6 minutes.

During the Residence time of the reaction mixture in the mixer become perfumes or perfume added. Preferably, perfume or perfume in the mixer or container sprayed. The spraying time is maximum 90%, preferably less than 70%, preferably less than 50%, further preferably less than 30%, and more preferably less than 10% the residence time of the reaction mixture in the mixer. The spraying time can 1 second to 60 seconds, 10 seconds to 50 seconds and preferred 20 seconds to 40 seconds.

Around a good absorption capacity the carrier particles according to the invention for perfume or to ensure perfume, it is preferred that the water content of the soda-containing carrier particles within a certain weight.

Advantageous is when the soda-containing according to the invention Particles 0.2 mole to 4 moles of water per mole of soda, preferably 0.5 Mol to 3.5 moles of water per mole of soda, more preferably 1 mole to 3 Mol of water per mole of soda, more preferably 1.5 moles to 2.75 moles of water per mole of soda and most preferably 2 moles to 2.5 moles of water each Contain mol soda, or if the soda-containing particles silicate contain such soda-containing particles from 0.2 mol to 2 moles of water per mole of soda, preferably 0.5 mole to 1.5 moles of water per mole of soda and most preferably from 0.75 moles to 1 mole of water per mole of soda.

The soda-containing particles can for example, while and / or after the inclusion of fragrance or perfume a water content of ≥ 0% by weight and ≤ 30 Wt .-%, preferably ≥ 5 Wt .-% and ≤ 25 Wt .-%, more preferably ≥ 10 Wt .-% and ≤ 15 Wt .-%, and most preferably ≥ 4 Wt .-% and ≤ 6 % By weight, based on the total weight of the soda-containing particles, exhibit.

Support materials such as polymers, in particular Sokalan, Sulfatein and / or silicate, can preferably in the form of a solution, for example, aqueous Solution, on the carrier material Soda, applied, in particular sprayed or gedust.

In the cases in which the water content of the so-treated soda-containing particles the inventively provided Exceeds water content, must be dried to ensure sufficient application or absorption of fragrance or Perfume on the soda-containing according to the invention carrier particles to ensure.

The inventive soda-containing carrier particles absorb the perfume or perfume practically, leaving the particles just a few seconds to minutes after perfume or perfume treatment palpable dry surface exhibit.

The according to the invention Perfume or perfume loaded soda-containing particles can further additions or components are added.

Preferably, are the invention with Fragrance or perfume loaded soda-containing particles later other additives or components mixed. In such mixtures in particular Finished products are the invention with perfume or perfume loaded soda-containing particles at least partially, preferably substantially, i.e. > 50 wt .-% based on the total weight of the particles according to the invention, as primary particles in front. At this primary Particles can optionally further additives or components loosely resting on the surface.

• – Herstellung feinteiliger sodahaltiger Partikel enthaltend gegebenenfalls weitere Trägerstoffe, wobei die sodahaltigen Partikel 0,2 Mol bis 4 Mol Wasser je Mol Soda, vorzugsweise 0,5 Mol bis 3,5 Mol Wasser je Mol Soda, weiter bevorzugt 1 Mol bis 3 Mol Wasser je Mol Soda, weiter bevorzugt 1,5 Mol bis 2,75 Mol Wasser je Mol Soda und am meisten bevorzugt 2 Mol bis 2,5 Mol Wasser je Mol Soda enthalten;
• – Aufbringung von wenigstens einem Parfum auf die sodahaltigen Partikel; wobei die sodahaltigen Partikel das Parfum aufsaugen; und

die erhaltenen Partikel 30 Gew.-% bis 70 Gew.-% Soda und 0,5 Gew.-% bis 20 Gew.-% Parfum aufweisen.A method of making perfume-laden soda-containing particles according to the invention may comprise the steps of:

• - Production of finely divided soda-containing particles containing optionally further excipients, wherein the soda-containing particles 0.2 mole to 4 moles of water per mole of soda, preferably 0.5 mole to 3.5 moles of water per mole of soda, more preferably 1 mole to 3 moles of water each Moles of soda, more preferably 1.5 moles to 2.75 moles of water per mole of soda and most preferably 2 moles to 2.5 moles of water per mole of soda;
• - applying at least one perfume to the soda-containing particles; wherein the soda-containing particles absorb the perfume; and

the particles obtained have 30% by weight to 70% by weight of sodium carbonate and 0.5% by weight to 20% by weight of perfume.

The Process for the preparation of soda-containing particles according to the invention preferably comprises the application of further additives to the soda-containing particles, with additives and / or carriers the soda-containing particles can be added, wherein liquid additives and / or solutions of additives and / or carriers, especially aqueous solutions thereof, be absorbed by the soda-containing particles, so this additions without post-treatment by drying the particles under training a dry particle surface are orderable.

For example you can get higher Proportions of fragrances, additives and / or carriers in the form of solutions, especially aqueous Solutions, on Apply the particles by adding these at previous, simultaneous and / or subsequent drying the soda-containing particles applied.

Of the The present invention is based on the following Examples 1 to 3 further explained.

example 1

In a double-shaft discount type Forberg was reduced to 60% by weight Soda with mixing 40 wt .-% of a 45 wt .-% Sokalan PA 30th solution (Sodium polyacrylate, aqueous solution, ex BASF) non-sprayed added within 30 seconds. Since the soda is the water immediately after setting, a final mixing time of 15 seconds was sufficient. Subsequently 1% by weight of perfume, based on the total weight of the particles added. That at first slight on the surface moist product was after a residence time of 5 to 10 minutes dry and storable.

The bulk weight was 570 g / l.

A change the perfume note after storage in a usual closed opaque Detergent packaging at 35 ° C for 4 weeks at a room humidity of 80% did not occur.

The review of Scent note was performed by 10 adult human subjects none of the 10 subjects noticed a change in the scent compared to an instant fresh detergent sample and a sample stored as described above.

Example 2

In a continuously operated free fall mixer, i. Drum with Demounting bar, were added to 60 parts by weight of soda 40 parts by weight a 45 wt .-% Sokalan PA 30 solution gedüst. The contained in the drum Granules were dried in the subsequent fluidized bed to 20% by weight of residual water (based on the total weight of the particles) with additional 20 parts by weight of a 45% strength by weight Sokalan PA 30 solution. Subsequently were 5% by weight of perfume, based on the total weight of the particles added. At a average residence time of the product of 3 minutes in the fluidized bed became a bulk density of 360 g / l.

at a residence time of 6 minutes, the bulk density was 570 g / l.

A change the perfume note after storage in a usual closed opaque Detergent packaging at 35 ° C for 4 weeks at a room humidity of 80% did not occur.

The review of Scent note was performed by 10 adult human subjects none of the 10 subjects noticed a change in the scent compared to an instant fresh detergent sample and a sample stored as described above.

Example 3

In a continuously operated free-fall mixer, ie drum with tee bar, 47.9 parts by weight of soda and 27.4 parts by weight of sulfate were admixed with a mixture of 11.1 parts by weight of a 45 wt .-% Sokalanlösung PA 30 and 8.14 parts by weight of a 40 wt .-% Silicate 2.0 solution. The granules contained in the drum was in the subsequent fluidized bed under Drying to 11.62 wt .-% residual water with an additional 5.6 parts by weight of a 45 wt .-% Sokalan PA 30 solution and 4.1 parts by weight of a 40 wt .-% strength Silicate 2.0 solution. Subsequently, 5% by weight of perfume, based on the total weight of the particles, was added. With an average residence time of the product of 3 minutes in the fluidized bed, a bulk density of 450 g / l was obtained.

at a residence time of 6 minutes, the bulk density was 630 g / l.

A change the perfume note after storage in a usual closed opaque Detergent packaging at 35 ° C for 4 weeks at a room humidity of 80% did not occur.

The review of Scent note was performed by 10 adult human subjects none of the 10 subjects noticed a change in the scent compared to an instant fresh detergent sample and a sample stored as described above.

below are the measuring methods stated

Principle of Dust valuation

It each 50g of a respective sample were examined in which one the respective sample on a vibrating trough has applied, wherein the frequency of the vibrating trough was 50 Hz and the opening gap so was adjusted so that the sample through the Schüttelrinne in 1 minute so that the sample through the funnel and the filler pipe in the cylinder falls and collect in the vessel, while the dust is outside of this vessel the bottom plate collects. Any remaining sample in the funnel By carefully knocking the funnel into the cylinder over the Transfer tube transferred. To a settling time of 2 minutes was on the polished bare Ground plate settled dust with a spatula transferred to a weighing dish and weighed.

Of the Construction of the experimental apparatus for determining the dust value was such that the sample over a vibrating trough and funnel into a sealed cylinder, centered over one filler pipe was dropped, with the drop height measured from the filler pipe outlet opening to to the upper outer bottom plate 50 cm made. While so coarse portions of the sample are perpendicular to the bottom of the cylinder, Centrally located under the funnel collecting vessel with a Height of 10 cm and a diameter of 18 cm collected, distributed the fines - dust - on the entire bottom plate of the cylinder. After settling leave the Dust in the cylinder was the dust with a spatula on the base plate of the cylinder pushed together, collected in a vessel and weighed.

Equipment:

It became a laboratory standard Shake trough used, Manufacturer AEG type DR 50 220 V, 50 Hz, 0.15 A.

Of the used funnels made of sheet iron with a wall thickness of 2 mm had a top diameter of 15 cm and the diameter the spout was 1.8 cm. The length of the funnel tube was 8 cm.

The used filler pipe made of brass with a wall thickness of 1 mm had a length of 30 cm and a diameter of 2.5 cm. The immersion depth of the Pipe in the outer cylinder was 20 cm. The immersion depth of the tube is by a on the outer wall of the filler pipe brazed Brass disc with a diameter of 15 cm and a thickness of 1 mm constant,

Of the used cylinder had a height of 70 cm, diameter 40 cm, closed at the top, open at the bottom. The cover plate the cylinder was in the middle with a circular opening, diameter about 3 cm, provided for receiving the funnel outlet tube. The bottom edge The cylinder was crimped outwards to eliminate the sharp edge soldered. The cylinder was made of galvanized sheet steel with a wall thickness of 1 mm.

The had used vessel a height of 10 cm and a diameter of 18 cm. The vessel was up open and closed down. The lower edge of the vessel was crimped to the outside and soldered to eliminate the sharp edge. The vessel was off Galvanized steel sheet with a wall thickness of 1 mm.

The used base plate made of bright aluminum with a thickness of 1 mm had a round shape with a diameter of 48 cm.

Of the used 2 mm thick sheet iron spatula had a worktop width of 11 cm.

The The analytical balance used had an accuracy of 0.01 g.

to Weight determination of the dust content became a laboratory standard Used weighing dishes.

Of the Dust content was in% based on the weight of each sample specified.

aggregation test

at the also carried out Klumpptest 15 ml of each sample to be examined in transferred a hollow cylinder with an inner diameter of 25 mm and by means of a stamp, in addition is loaded with 500 g while Pressed for 30 minutes. The under appropriate precautions knocked-out cylindrical compact is subsequently in vertical position under defined conditions until breakage loaded. The applied load in grams is a measure of the lumping tendency.

The Values of the clumping test were given in g.

solution behavior

The Determination of the solution behavior was carried out as follows. In a beaker (volume 500 ml) are added for each sample to be examined 200 ml each at 30 ° C and 10 ° C tempered tap water (15 ° d) with the help of a motor driven stirrer, with 4 at an angle from 30 ° to equipped below curved impellers is stirred with a constant number of revolutions of 700 rpm. Of the Distance of the stirring blades to Bottom of the vessel is 2.5 cm. 1 g of each sample is carefully and while avoiding from lumping into a stirring cone poured. After 90 seconds, the solution becomes through a tared sieve with a mesh size of 0.1 mm and a 7 cm diameter cast and sucked off with a suction bottle. Remains of substance in the beaker are by means of possible little injected water transferred to the sieve. The sieve is after a drying time re-weighed in the air for 24 hours.

The residue formation and the dissolved sample portion at 30 ° C and 10 ° C was given in%.

sedimentation test

In a beaker, 90 ml of tap water at 16 ° d were introduced and added with vigorous stirring 10 g of each sample to be examined in small portions. Thereafter, it is stirred for 15 minutes at room temperature. The solution is then filled into a graduated cylinder and allowed to stand. During the service life, the measuring cylinder is covered with a foil. After 20 h, the quotient of the sediment volume V _S and total volume V is determined.

Equipment:

• Cups:
• 250 ml, diameter 70 mm
• stirrer:
• Three-bladed propeller stirrer, diameter 50 mm, speed 700-1000 min ^-1
• measuring cylinder:
• 100 ml glass measuring cylinder according to DIN

The Values of the sedimentation test were expressed in ml.

migration test

It were the efflux time of 1000 ml of each sample from a standardized funnel measured and against the discharge speed from standard test sand compared. The flow time of the dry test sand from the Rieselapparatur was set at 100%. The flow time of the sample from the Rieselapparatur were in proportion set and expressed as% flow time compared to the test sand.

Characteristics of the test sand: bulk weight 1460 g / l Particle size distribution: > 1.6 mm = 0.2%> 0.8 mm and ≤ 1.6 mm = 11.6> 0.4 mm and ≤ 0.8 mm = 56.2%> 0.2 mm and ≤ 0, 4 mm = 26.6%> 0.1 mm and ≤ 0.2 mm = 4.8% <0.1 mm = 0.6%

The Grain spectrum of the test sand is weighed out from fractionated building sand and is an average distribution a washing powder modeled.

Of the Test Sand is before the calibration of the Rieseltrichters by Probeteilung from a larger storage bottle to divide to a volume of 1000 ml.

equipment

• Bulk density apparatus with 1000 ml beaker
• Rieseltestapparatur (consisting of trickle funnel and tripod)
• stopwatch
• Powder funnel (for filling the apparatus)
• 2 liter plastic can (to collect the spilled material)
• execution

Calibration of the trickle test apparatus

For the trickle test apparatus becomes the flow time of the test sand determined by the flow time of 1000 ml of test sand 5 determined. The average runtime is set as 100%. It is important to pay attention to the flow time of the test sand 50 seconds. Otherwise, the outlet opening of the Correct funnel.

Measurement of a sample according to the invention

1000 ml of each sample are transferred to the trickle test apparatus. to lighter filling the Rieseltrichters was the particles of the invention using a huge Pulvertrichters filled in the apparatus. While the sample from the top of the vertical standing Rieselapparatur is filled, is the lower outlet opening of the Funnel of the trickle test apparatus to close (finger). After release the outlet opening the funnel of the Rieselapparatur became the time with a stopwatch in seconds measured in the particle sample completely off runs out of the trickle funnel.

The Outflow time of 1000 ml sample according to the invention was determined 5 times and the mean is calculated.

The Flow time of the test sand in seconds multiplied by 100 and divided by the flow time 1000 ml of sample according to the invention in seconds, the trickle test results in%.

determination the oil number

Corresponding DIN ISO 787/5 became the oil numbers for samples same composition of the soda-containing particles according to the invention without Perfume determined by adding 0.5 g each of the respective particle sample weighed on a rectangular glass plate and then dropwise from a 50ml burette n-octane on the fine particulate Gave funds. While The addition of the octane, powder and liquid were carefully with a spatula mixed. Once the sample is not a liquid took more and a soft paste was formed, was the addition terminated by octane and the respective octane consumption was at the burette read. From each sample, a duplicate determination was performed, wherein the respective oil number indicates the average determined.

Claims (42)

Perfume containing soda-containing particles, characterized in that the soda-containing particles 0.2 mole to 6 moles of water per mole of soda, preferably 0.5 mole to 3.5 moles of water per mole of soda, more preferably 1 mole to 3 moles of water per mole of soda more preferably 1.5 moles to 2.75 moles of water per mole of soda and most preferably 2 moles to 2.5 moles of water per mole of soda. Soot-containing particles according to claim 1, characterized in that the soda-containing particles comprise: From 35% to 65% by weight of soda, more preferably from 40% to 60% by weight of soda, and most preferably From 45% to 55% by weight of soda; and or From 1% to 15% by weight of perfume, more preferably from 2% to 10% by weight of perfume and most preferably from 3% by weight to 5% by weight of perfume, based on the total weight the soda-containing particles. Soda-containing particles according to claim 1 or 2, characterized characterized in that the soda-containing particles additional support materials selected from the group comprising: - ≥ 0% by weight up to 20% by weight of silicate, particularly preferably 1% by weight to 15% by weight Silicate and most preferably 5% to 10% by weight of silicate; and or - 1% by weight up to 40% by weight of polymer, more preferably 5% by weight to 30% by weight Polymer and most preferably 10% to 20% by weight polymer; and or - ≥ 0% by weight up to 5% by weight of phosphonate, particularly preferably 0.01% by weight to 2% by weight Phosphonate and most preferably from 0.5% to 1% by weight of phosphonate; and or - ≥ 0% by weight up to 30% by weight of phosphate, particularly preferably 5% by weight to 25% by weight Phosphate, and most preferably from 10% to 20% by weight of phosphate; and or - ≥ 0% by weight up to 50% by weight of sulphate, particularly preferably 5% by weight to 35% by weight Sulfate, and most preferably 10% to 25% by weight sulfate; and or - ≥ 0% by weight up to 5% by weight of soap, particularly preferably from 0.01% by weight to 3% by weight Soap, and most preferably from 0.05% to 1% by weight soap; contain, wherein the weight contents of the carrier materials the soda-containing particles including the weight contents of Perfume and optionally other additives are chosen so that these 100 wt .-% do not exceed. Soda-containing particles according to any one of claims 1 to 3, characterized in that the soda-containing particles have as further additives: - linear alkylbenzenesulfonate / e (LAS), preferably the weight fraction of linear alkylbenzenesulfonates ≥ 0 wt .-% and ≤ 25 wt .-% , preferably ≥ 5 wt .-% and ≤ 15 wt .-%, more preferably ≥ 5 wt .-% and ≤ 10 wt .-%; and / or - nonionic surfactant, preferably the content of nonionic surfactant 1 wt .-% to 30 wt .-% of nonionic surfactant, preferably 5 wt% to 20 wt% nonionic surfactant, more preferably 10 wt% to 18 wt% nonionic surfactant, and most preferably 14 wt% to 17 wt% nonionic surfactant; based on the total weight of the soda-containing particles, wherein the weight contents of the carrier materials of the soda-containing particles, including the weight contents of perfume and other additives are chosen so that they do not exceed 100 wt .-%. Soot-containing particles according to one of claims 1 to 4, characterized in that the soda-containing particles have a Water content of ≥ 0 Wt .-% and ≤ 30 Wt .-%, preferably ≥ 5 Wt .-% and ≤ 25 Wt .-%, more preferably ≥ 10 Wt% and ≤ 15 wt% and most preferably ≥ 4 Wt .-% and ≤ 6 % By weight, based on the total weight of the soda-containing particles, exhibit. Sodahaltige particles according to any one of claims 1 to 5, characterized in that the soda-containing particles have a particle diameter d ₅₀ of 0.01 mm to 2 mm, preferably 0.02 mm to 1 mm and more preferably from 0.05 to 0.4 mm exhibit. Soot-containing particles according to one of claims 1 to 6, characterized in that the soda-containing particles have a bulk density from 300 g / l to 1000 g / l, preferably 400 g / l to 700 g / l and preferred 450 g / l to 600 g / l. Soot-containing particles according to one of claims 1 to 7, characterized in that the soda-containing particles a Dust value of ≥ 0.001 % and ≤ 0.05 %, preferably ≥ 0.003 % and ≤ 0.02 % and more preferably ≥ 0.007 % and ≤ 0.01 % exhibit. Soot-containing particles according to one of claims 1 to 8, characterized in that the soda-containing particles before the perfume loading an oil number in ml / 100g of 50 to 150, preferably 60 to 140, preferably of 70 to 130, more preferably from 80 to 120 and more preferably from 90 to 110. Soot-containing particles according to one of claims 1 to 9, characterized in that the soda-containing particles have a Klumptestwert based on 500g soda-containing particles of ≥ 0 g and ≤ 7 g, preferably ≤ 5 g, preferably ≤ 3 g and especially preferably ≦ 1 g have. Soot-containing particles according to one of claims 1 to 10, characterized in that the soda-containing particles with a Content of 30 wt .-% to 60 wt .-% soda, a silicate content of at least 9 wt% to 25 wt%, and a nonionic surfactant of Up to 5 wt .-% of a Klumptestwert based on 500g soda-containing Particles of ≥ 0 g and ≤ 1 g. Soot-containing particles according to one of claims 1 to 11, characterized in that the soda-containing particles with a Content of 30 wt .-% to 60 wt .-% soda, a silicate content of at least 9 wt% to 25 wt%, and a nonionic surfactant of Up to 10 wt .-% of a Klumptestwert based on 500g soda-containing Particles of ≥ 2 g and ≤ 3 g. Soot-containing particles according to one of claims 1 to 12, characterized in that the soda-containing particles with a Content of 30 wt .-% to 60 wt .-% soda, a silicate content of at least 9 wt% to 25 wt%, and a nonionic surfactant of Up to 15 wt .-% of a Klumptestwert based on 500g soda-containing Particles of ≥ 6 g and ≤ 9 g. Soot-containing particles according to one of claims 1 to 13, characterized in that the soda-containing particles with a Content of 30 wt .-% to 60 wt .-% soda, a silicate content of at least 9 wt% to 25 wt%, and a nonionic surfactant of Up to 20 wt .-% of a Klumptestwert based on 500g soda-containing Particles of ≥ 8 g and ≤ 14 g. Soot-containing particles according to one of claims 1 to 14, characterized in that the soda-containing particles with a Content of 30 wt .-% to 60 wt .-% soda, a silicate content of at least 9 wt% to 25 wt%, and a nonionic surfactant of up to 25 wt .-% of a Klumptestwert based on 500g soda-containing Particles of ≥ 28 g and ≤ 52 g. Soot-containing particles according to one of claims 1 to 15, characterized in that for the soda-containing particles the sedimentation test has a value of ≥ 0 ml and ≤ 5 ml, preferably ≥ 0.01 ml and ≤ 3 ml, and preferably ≥ 0.05 ml and ≤ 2 ml. Soot-containing particles according to one of claims 1 to 16, characterized in that at least 10 wt .-%, preferably at least 30% by weight, preferably at least 50% by weight, more preferably at least 70% by weight and more preferably at least 90% by weight the soda-containing particles as primary soda-containing particles, based on the total weight of the soda-containing particles. Sodahaltige particles according to one of claims 1 to 17, characterized in that the soda-containing particles have a flowability of little at least 40%, in particular of at least 50%, preferably at least 70% and preferably 90% to ≤ 100%. Soot-containing particles according to one of claims 1 to 18, characterized in that the soda-containing particles in a Water temperature of 10 ° C a release time of a maximum of 3.5 minutes and / or at a water temperature of 30 ° C a dissolution time of for a maximum of 1.5 minutes. Soot-containing particles according to one of claims 1 to 19, characterized in that 1 g of the soda-containing particles residue behavior in 200 ml at 10 ° C tempered tap water with 15 ° d H of ≥ 0% and ≤ 5%, preferably ≥ 0.001% and ≤ 4%, preferably ≥ 0.01% and ≤ 3% and more preferably of ≥ 0.1 % and ≤ 2 % exhibit. Soot-containing particles according to one of claims 1 to 20, characterized in that 1 g of the soda-containing particles residue behavior in 200 ml at 30 ° C tempered tap water with 15 ° d H of ≥ 0% and ≤ 5%, preferably ≥ 0.001% and ≤ 4%, preferably ≥ 0.01% and ≤ 2% and more preferably of ≥ 0.1 % and ≤ 1 % exhibit. Soot-containing particles according to one of claims 1 to 21, characterized in that - ≥ 0 to 30 wt .-% of soda-containing Particles have a particle diameter of ≥ 1.6 mm, - 2 to 5.5% by weight of the soda-containing particles have a particle diameter of <1.6 mm to 1.25 mm, - 1 up to 3.5% by weight of the soda-containing particles have a particle diameter from <1.25 mm to 1.0 mm, - 1 up to 3.5% by weight of the soda-containing particles have a particle diameter from <1.0 mm to 0.8 mm, - 1 to 4.5 wt .-% of soda-containing particles a particle diameter from <0.8 mm to 0.63 mm, - 2 to 28% by weight of the soda-containing particles have a particle diameter from <0.63 mm to 0.4 mm, - 22 to 57% by weight of the soda-containing particles have a particle diameter from <0.4 mm to 0.2 mm, - 2 to 34 wt .-% of soda-containing particles a particle diameter from <0.2 mm to 0.1 mm, -> 0 to 10 wt .-% of soda-containing particles have a particle diameter of <0.1 mm to 0.63 mm, based on the total weight of the soda-containing particles, have, wherein the respective weight proportions of the soda-containing Particles so chosen are that together make up a maximum of 100 wt .-%. Soot-containing particles according to one of claims 1 to 22, characterized in that - ≥ 0 to 20 wt .-% of the soda-containing Particles have a particle diameter of ≥ 1.6 mm, - 2 to 4.5 wt .-% of soda-containing particles have a particle diameter of <1.6 mm to 1.25 mm, - 1 to 3.0% by weight of the soda-containing particles have a particle diameter from <1.25 mm to 1.0 mm, - 1 up to 3.5% by weight of the soda-containing particles have a particle diameter from <1.0 mm to 0.8 mm, - 1 to 4.5 wt .-% of soda-containing particles a particle diameter from <0.8 mm to 0.63 mm, - 2 to 28% by weight of the soda-containing particles have a particle diameter from <0.63 mm to 0.4 mm, - 45 to 56% by weight of the soda-containing particles have a particle diameter from <0.4 mm to 0.2 mm, - 2 to 28% by weight of the soda-containing particles have a particle diameter from <0.2 mm to 0.1 mm, -> 0.1 to 2 wt .-% of soda-containing particles have a particle diameter of <0.1 mm to 0.63 mm, based on the total weight of the soda-containing particles, have, wherein the respective weight proportions of the soda-containing Particles so chosen are that together make up a maximum of 100 wt .-%. Soot-containing particles according to one of claims 1 to 23, characterized in that - ≥ 7 to 9 wt .-% of the soda-containing Particles have a particle diameter of ≥ 1.6 mm, - 2 to 3 wt .-% of soda-containing particles have a particle diameter of <1.6 mm to 1.25 mm, - 1,2 to 2.5 wt .-% of soda-containing particles a particle diameter from <1.25 mm to 1.0 mm, - 1 to 3.2% by weight of the soda-containing particles have a particle diameter from <1.0 mm to 0.8 mm, - 1 to 4.5 wt .-% of soda-containing particles a particle diameter from <0.8 mm to 0.63 mm, - 2 to 28% by weight of the soda-containing particles have a particle diameter from <0.63 mm to 0.4 mm, - 50 to 56% by weight of the soda-containing particles have a particle diameter from <0.4 mm to 0.2 mm, - 2 to 28% by weight of the soda-containing particles have a particle diameter from <0.2 mm to 0.1 mm, -> 0.2 to 1.5 wt .-% the soda-containing particles have a particle diameter of <0.1 mm to 0.63 mm, based on the total weight of the soda-containing particles, have, wherein the respective weight proportions of the soda-containing Particles so chosen are that together make up a maximum of 100 wt .-%. Soot-containing particles according to one of claims 1 to 24, characterized in that at least one silicate of the carrier material selected is from the group comprising amorphous sodium silicates, aluminosilicates, in particular zeolites, preferably zeolite A, zeolite P and / or Zeolite X, swellable phyllosilicates, preferably montmorillonite, in particular bentonite. Sodahaltige particles according to any one of claims 1 to 25, characterized in that at least one polymer of the carrier material is a polycarboxylate, preferably a polyacrylate, wherein the polyacrylate is preferably a copolymer selected from the group comprising acrylic acid with Me thacrylic acid, acrylic acid or methacrylic acid with maleic acid. Soot-containing particles according to one of claims 1 to 26, characterized in that at least one phosphonate of the carrier material is selected from the group comprising trimethylenephosphonic acid, hydroxyethylidene-1,1-diphosphonic acid, ethylenediaminetetramethylenephosphonic acid, hexamethylenediamine tetramethylenephosphonic acid, diethylenetriaminepentamethylenephosphonic acid, polyaminomethylenephosphonic acid, hexamethylenetriaminepentamethylenephosphonic acid, phosphonobutane tricarboxylic acid, and / or Neutral salts of the aforementioned phosphonates. Soot-containing particles according to one of claims 1 to 27, characterized in that at least one phosphate of the carrier material is selected from the group comprising tripolyphosphates, pentasodium triphosphate, Pyrophosphates, orthophosphates, alkali metal phosphates, in particular Sodium and potassium salts of various phosphoric acids. Soot-containing particles according to one of claims 1 to 28, characterized in that at least one soap of the carrier material selected is from the group comprising saturated Fatty acid soaps, in particular salts of lauric acid, myristic, palmitic acid, stearic acid, hydrogenated erucic acid, behenic and / or the natural one Fatty acids. Soot-containing particles according to one of claims 1 to 29, characterized in that at least one sulfate of the carrier material selected is selected from the group comprising alkali metal sulphate / s, in particular sodium sulphate. Soot-containing particles according to one of claims 1 to 30, characterized in that at least one nonionic surfactant is selected from the group comprising alkoxylated fatty alcohols, alkyl glycosides, fatty acid alkyl esters and / or amine oxides, wherein alkoxylated fatty acid alkyl esters, ethoxylated fatty acid alkyl ester or ethoxylated and propoxylated fatty acid alkyl esters are preferred. Soot-containing particles according to one of claims 1 to 31, characterized in that at least one perfume is selected from the group comprising perfume (s) with green note notes, Citrus notes, Lavender notes, Flowery notes, Aldehyde notes, Chypre notes, Fougere notes, spice notes, Oriental notes, wood notes, tobacco notes, leather notes and / or metal notes. Soot-containing particles according to one of claims 1 to 32, characterized in that at least one perfume is selected from the group comprising: - essences from fruits, Fruit parts and / or other parts of plants, preferably herbs, drugs, essential oils derived therefrom, preferred terpene-free oils; and or - artificial Essences, preferably of synthetic odorants and / or flavorings, particularly preferably vanillin, menthol, biacetyl and / or eucalyptol; and or - flavors, preferably essential oils, aniseed oil, star aniseed oil, bitter almond oil, eucalyptus oil, fennel oil, peppermint oil, lemon oil, wintergreen oil, clove oil, menthol and / or caraway oil; and or - synthetic Fragrance compounds of the ester type, preferably benzyl acetate, Phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinyl acetate, Phenylethyl acetate, linalyl benzoate, benzyl formate, ethylmethylphenyl glycinate, Allyl cyclohexyl propionate, styrallyl propionate and / or benzyl salicylate; and or - synthetic Fragrance compounds of the ether type, preferably benzyl ethyl ether; and or - synthetic Fragrance compounds of the aldehyde type, preferably linear Alkanals with 8-18 C atoms, citral, citronellal, citronellyloxyacetaldehyde, Cyclamenaldehyde, hydroxycitronellal, lilial and / or bourgeonal; and or - synthetic Fragrance compounds of the ketone type, preferably Jonone, Isomethylionone and / or methyl cedryl ketone; and or - synthetic Fragrance compounds of the alcohol type, preferably anethole, Citronellol, eugenol, geraniol, linalool, phenylethyl alcohol and / or terpineol; and or - synthetic Fragrance compounds of the hydrocarbon type, preferably Terpenes, preferably limonene and pine trees; and or - natural fragrance mixtures from vegetable sources, preferably pine, citrus, jasmine, patchouli, Rose or Ylang-ylang oil, Muscat, sage oil, Chamomile oil, Clove oil, Balm oil, mint oil, Cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil, labdanum oil, orange blossom oil, neroliol, Orange peel oil and / or sandalwood; and or - metallic Perfume compounds comprising oxacyclododecan-2-one, 4,5-decamethyleneoxazole, sclarenes, Derivatives thereof and / or precursors thereof, wherein the derivatives are preferably in the form of esters and / or ethers. Sodahaltige particles according to any one of claims 1 to 33, characterized in that the soda-containing particles have at least one, preferably a plurality of additives selected from the group comprising washing, care and / or cleaning active substances, in particular anionic surfactants, cationic surfactants, amphoteric surfactants , Builders, bleaches, bleach activators, Bleach stabilizers, bleach catalysts, enzymes, polymers, cobuilders, alkalizers, acidifiers, anti-redeposition agents, silver protectants, colorants, optical brighteners, UV protectants, fabric softeners, foam inhibitors and / or rinse aids, and optionally other admixed additives. Finished product comprising soda-containing particles after one of the claims 1 to 34. The finished product of claim 35, wherein the finished product a detergent, a cleaner for hard and / or soft surfaces, a Stainless steel cleaner, a household cleaner, an oven cleaner, a conditioner, a laundry detergent, a laundry care product, a fragrance, a hair treatment composition, a hair dye, a conditioner, a fabric softener, a conditioning substrate, a drug, a pesticide, a food, a cosmetic, a fertilizer, a building material, a Glue, a bleach, a disinfectant and / or a Preproduct of the aforementioned finished products. A finished product according to claim 35 or 36, wherein said Finished product additionally to the soda-containing particles and separately at least one, preferably several additives has selected from the group comprising as washing, care and / or cleaning active Substances anionic surfactants, cationic surfactants, amphoteric surfactants, builders, Bleaching agents, bleach activators, bleach stabilizers, bleach catalysts, Enzymes, polymers, cobuilders, alkalizers, acidifiers, Anti redeposition agents, silver protectants, colorants, optical brighteners, UV protection substances, fabric softeners, Foam inhibitors and / or rinse aid, and optionally further admixed additives. Finished product according to one of claims 35 to 37, characterized in that the finished product at least 1 Wt .-% and at most 70 wt .-%, preferably at most 50 wt .-%, preferably at most 30% by weight, more preferably at most 20% by weight, still further preferably from 3% to 15% and most preferably 5% by weight to 10 wt .-% soda-containing particles according to any one of claims 1 to 35, based on the total weight of the finished product, wherein the respective weight fractions are chosen so that these together maximally Make up 100% by weight. Process for the preparation of soda-containing particles according to one the claims 1 to 34, comprising the steps: - Production of finely divided soda-containing particles optionally containing further excipients, wherein the soda-containing particles from 0.2 mol to 4 moles of water per mole of soda, preferably 0.5 mole to 3.5 moles of water per mole of soda, more preferably 1 mole to 3 moles of water per mole of soda, more preferably 1.5 moles to 2.75 moles of water per mole of soda and most preferably 2 moles to 2.5 Moles of water per mole of soda; - Application of at least a perfume on the soda-containing particles; the soda-containing Particles absorb the perfume; and the particles obtained 30% by weight to 70% by weight of soda and 0.5% by weight to 20% by weight of perfume exhibit. Process for the preparation of soda-containing particles according to claim 39, wherein additives and / or carriers the soda-containing particles are added, wherein liquid additives and / or Solutions from additives and / or carriers, especially aqueous solutions from being absorbed by the soda-containing particles, so that these additives without After treatment by drying the particles to form a dry particle surface applicable are. Process for the preparation of soda-containing particles according to claim 39 or 40, wherein higher proportions of fragrances, additives and / or carriers in the form of solutions, especially aqueous Solutions, can be applied to the particles by placing them at previous, simultaneous and / or afterthought Drying of the particles applies. Soot-containing particles according to one of claims 1 to 34, producible according to one of the methods of claims 40 to 42nd