CN214734561U - Clean hydrogen and renewable energy hydrogen joint production system - Google Patents

Clean hydrogen and renewable energy hydrogen joint production system Download PDF

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Publication number
CN214734561U
CN214734561U CN202120533103.XU CN202120533103U CN214734561U CN 214734561 U CN214734561 U CN 214734561U CN 202120533103 U CN202120533103 U CN 202120533103U CN 214734561 U CN214734561 U CN 214734561U
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hydrogen
oxygen
power generation
hydrogen production
energy
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廖勇
刘清友
王国荣
吴秋伟
刘武
董立臣
丁涛
李俊荣
胡强
李汶颖
张琳东
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Chengdu Jingzhiyi Technology Co ltd
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Chengdu Jingzhiyi Technology Co ltd
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P90/00—Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
    • Y02P90/50—Energy storage in industry with an added climate change mitigation effect

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Abstract

The utility model discloses a clean hydrogen and renewable energy hydrogen joint production system, including photovoltaic power generation system, wind power generation system, outside electric wire netting access system, brineelectrolysis hydrogen manufacturing system, oxygen boosting burning hydrogen manufacturing system, carbon dioxide entrapment and liquefaction system, energy storage system, wherein: the photovoltaic power generation system, the wind power generation system, the external power grid access system and the energy storage system are connected with the water electrolysis hydrogen production system through power buses; the hydrogen production system by water electrolysis is connected with the oxygen-enriched combustion hydrogen production system, and the oxygen-enriched combustion hydrogen production system is connected with the carbon dioxide capture and liquefaction system. The utility model provides an integrate multiple new forms of energy techniques such as photovoltaic, wind-powered electricity generation, hydrogen energy, oxygen boosting burning, carbon entrapment for the first time, finally realize carrying out multipotency complementation, supply coupling, renewable energy system green hydrogen and carbon dioxide entrapment retrieve the energy system of supplying clean hydrogen down, provide a green hydrogen manufacturing factory technical scheme that can implement for realizing in the carbon and the target.

Description

Clean hydrogen and renewable energy hydrogen joint production system
Technical Field
The utility model belongs to the technical field of the new forms of energy technique and specifically relates to a multiple new forms of energy techniques such as integration photovoltaic, wind-powered electricity generation, hydrogen energy, oxygen boosting burning, carbon entrapment finally realize carrying out multipotency complementation, supply coupling, renewable energy system green hydrogen and carbon dioxide entrapment retrieve the energy system of supplying clean hydrogen down, provide a high-efficient green hydrogen manufacturing factory technical scheme that can implement for realizing in the carbon and the target.
Background
Because a large number of green hydrogen electrolysis projects are associated with oxygen utilization and are key points for reducing carbon capture energy consumption in the future, a clean hydrogen and renewable energy source hydrogen combined production system and method are developed, and a low-energy-consumption hydrogen factory is constructed to provide clean energy for the future society.
Photovoltaic power generation is a technology of directly converting light energy into electric energy by using the photovoltaic effect of a semiconductor interface. The solar energy power generation system mainly comprises a solar cell panel (assembly), a controller and an inverter, and the main components are electronic components. The solar cells are connected in series and then are packaged and protected to form a large-area solar cell module, and then the photovoltaic power generation device is formed by matching with components such as a power controller and the like.
Wind power generation converts kinetic energy of wind into mechanical kinetic energy, and then converts the mechanical energy into electrical kinetic energy. The principle of wind power generation is that wind power drives windmill blades to rotate, and then the rotating speed is increased through a speed increaser, so that a generator is promoted to generate electricity. According to current windmill technology, a wind speed of about three meters per second (breeze level) can be used to start generating electricity.
Clean energy resources such as global wind energy, water energy, solar energy and the like are very rich, and the theoretical annual exploitable amount is 38 times of the worldwide exploitable reserve of fossil energy. But they have the fatal defects that the energy output can not be stably provided for a long time, and the energy supplementing and peak shaving system of the existing energy system or the separately configured energy storage and peak shaving system is required.
The process of hydrogen production by water electrolysis is actually an energy conversion process, namely a process of converting primary energy into energy carrier hydrogen energy. At present, two major water electrolysis hydrogen production technologies can be practically applied under low temperature conditions, namely alkaline liquid water electrolysis and solid Polymer (PEM) water electrolysis. The water electrolysis technology of alkaline liquid takes KOH and NaOH aqueous solution as electrolyte, for example, asbestos cloth or the like as a diaphragm, and electrolyzes water under the action of direct current to generate hydrogen and oxygen. The produced gas needs dealkalization fog treatment. The main components of a typical PEM water electrolysis technology comprise an anode gas diffusion layer, a cathode catalyst layer, an anode catalyst layer, a proton exchange membrane and the like. In the PEM technology, hydrogen ions in water pass through a proton exchange membrane to combine with electrons into hydrogen atoms, which combine with each other to form hydrogen molecules. The PEM proton exchange membrane is used as a solid electrolyte, and a perfluorosulfonic acid membrane is generally used to isolate gas generated by a cathode and an anode, prevent the transfer of electrons and transfer protons. The proton exchange membrane replaces the asbestos membrane to isolate the gas at the two sides of the electrode, and avoids the defects caused by using strong alkaline liquid electrolyte in an alkaline liquid electrolyte electrolytic cell. In addition, the PEM water electrolysis cell adopts a zero-gap structure, the volume of the electrolysis cell is more compact and simplified, the ohmic resistance of the electrolysis cell is reduced, and the overall performance of the electrolysis cell is greatly improved.
The hydrocarbon steam conversion hydrogen production process is a chemical process which is widely applied in China. The raw materials suitable for hydrocarbon conversion hydrogen production are various, and include natural gas, liquefied petroleum gas, various refinery gases, synthesis gas, straight run naphtha, raffinate oil, topping oil, secondary processing oil and the like. Wherein the natural gas with the lightest molecular weight and the minimum hydrocarbon ratio is used for producing hydrogen. The patent description mainly exemplifies natural gas: natural gas hydrogen production, namely, reforming gas prepared by natural gas steam reforming and hydrogen (H) purified by Pressure Swing Adsorption (PSA)2) The method comprises the steps of compressing and desulfurizing natural gas, mixing the natural gas with water vapor, and converting the natural gas into hydrogen (H) under the action of a nickel catalyst at the temperature of 750-850 DEG C2) Carbon monoxide (CO) and carbon dioxide (CO)2) The reformed gas of (3) can convert carbon monoxide (CO) into hydrogen (H) by conversion2) To a shifted gas, and then the shifted gas or the shifted gas is passed through a Pressure Swing Adsorption (PSA) process to obtain high-purity hydrogen (H)2). The relevant reaction is endothermic and requires combustion of fuel for heat replenishment.
The CCUS technology is a key solution for reducing emission in the energy industry, and plays an important role in promoting low-carbon transformation of an energy system and realizing global climate targets. According to classification in reports of CCUS (role of CCUS in low-carbon power generation system) of International Energy Agency (IEA), carbon capture modes are mainly divided into three research directions of post-combustion capture, pre-combustion capture and oxygen-enriched combustion carbon capture systems. The oxygen-enriched combustion trapping technology is a trapping technology in combustion. Different from the traditional combustion technology of directly using air to support combustion, the oxygen-enriched combustion uses oxygen with very high purity to support combustion, and uses CO generated by combustion2Replacing N in air2Repeatedly recycled, and the ratio of combustion air and circulating flue gas is adjusted to control O2/CO2The mixture ratio is suitable for different combustion requirements. Rich in high concentration CO in the exhaust smoke of oxygen-enriched combustion2Is convenient for the subsequent implementation of low-cost carbon dioxide capture。
The micro-grid is a concept relative to a traditional large power grid, and refers to a network formed by a plurality of distributed power sources and related loads according to a certain topological structure, and is related to a conventional power grid through a static switch. The development and extension of the micro-grid can fully promote the large-scale access of distributed power sources and renewable energy sources, realize the high-reliability supply of various energy source types of loads, and is an effective mode for realizing an active power distribution network, so that the traditional power grid is transited to a smart power grid. The direct current microgrid and the alternating current microgrid are typical microgrid modes, and the mode of the microgrid is mainly different from the mode of the direct current microgrid and the alternating current microgrid which are used as energy transmission carriers.
According to the standard and evaluation of low hydrocarbon, clean hydrogen and renewable energy hydrogen proposed by the Chinese hydrogen energy alliance, in the aspect of unit hydrogen carbon emission, the threshold value of the low hydrocarbon is 14.51 kgCO2e/kgH2, the threshold value of the clean hydrogen and the renewable hydrogen is 4.9 kgCO2e/kgH2, and the renewable hydrogen simultaneously requires hydrogen production energy to be renewable energy.
Disclosure of Invention
In order to develop the technique of effectively utilizing in carbonaceous fuel's improvement combustion efficiency and reduction petrochemical industry fuel decarbonization cost, the utility model provides a clean hydrogen and renewable energy hydrogen joint production system aims at realizing that renewable energy combines down to produce clean hydrogen and renewable energy hydrogen with the CCUS technique, accords with the social demand of following carbon neutralization, and application prospect is wide.
The utility model provides a technical scheme that its technical problem adopted is: the utility model provides a clean hydrogen and renewable energy source hydrogen joint production system, includes photovoltaic power generation system, wind power generation system, outside electric wire netting access system, electrolytic water hydrogen production system, oxygen boosting burning hydrogen production system, carbon dioxide entrapment and liquefaction system, energy storage system, wherein: the photovoltaic power generation system, the wind power generation system, the external power grid access system and the energy storage system are connected with the water electrolysis hydrogen production system through power buses; the hydrogen production system by water electrolysis is connected with the oxygen-enriched combustion hydrogen production system, and the oxygen-enriched combustion hydrogen production system is connected with the carbon dioxide capture and liquefaction system.
Compared with the prior art, the utility model has the positive effects that:
the utility model provides an one set of scheme that adopts renewable energy + carbon dioxide entrapment technique to supply with clean hydrogen and renewable energy hydrogen has proposed for the first time a plurality of new energy techniques such as integration photovoltaic, wind-powered electricity generation, hydrogen energy, oxygen boosting burning, carbon entrapment, finally realize carrying out multipotency complementation, supply coupling, renewable energy system green hydrogen and carbon dioxide entrapment retrieve down the energy system of supply clean hydrogen, propose a green hydrogen manufacturing factory technical scheme that can implement for realizing in the carbon and the target.
Drawings
The invention will now be described, by way of example, with reference to the accompanying drawings, in which:
FIG. 1 is a schematic diagram of a clean hydrogen and renewable energy hydrogen cogeneration system framework;
FIG. 2 is a schematic diagram of a clean hydrogen and renewable energy hydrogen cogeneration system (DC microgrid system);
FIG. 3 is a schematic diagram of a clean hydrogen and renewable energy hydrogen cogeneration system (AC microgrid system);
the reference numbers in the figures include: the system comprises a grid power access device 1, a first AC/DC converter 2, a solar cell matrix 3, a combiner box 4, a first DC/DC converter 5, a wind driven generator 6, a second AC/DC converter 7, a second DC/DC converter 8, a storage battery pack 9, a super capacitor bank 10, a direct current microgrid bus 11, a third DC/DC converter 12, an electrolytic water device 13, a hydrogen purification device 14, a hydrogen storage device 15, an oxygen storage device 16, a liquid hydrocarbon storage tank 17, a BOG compressor 18, a liquid hydrocarbon pressure boost gasifier 19, a liquid hydrocarbon booster pump 20, a liquid hydrocarbon main gasifier 21, an oxygen-enriched combustion hydrogen production converter 22, a steam generator 23, a shift reactor 24, a steam preheater 25, a cooling separator 26, a PSA separation device 27, a tail gas heat exchanger 28, a primary compressor 29, a CO pre-heater 25, a cooling separator 26, a PSA separation device 27, a tail gas heat exchanger 28, a primary compressor 29, a CO gas2 A dewatering device 30, a condensate pump 31, a secondary compressor 32, CO2Liquefied cooling tank 33, refrigerating device 34, and liquid CO2Storage tank 35, CO2Buffer tank 36, intelligent energy management system 37.
Detailed Description
A clean hydrogen and renewable energy hydrogen cogeneration system, as shown in figure 1, comprising: photovoltaic power generation system, wind power generation system, external power grid access system, electrolytic water hydrogen production system, oxygen boosting burning hydrogen production system, liquid hydrocarbon storage and supply system, carbon dioxide entrapment and liquefaction system, energy storage system etc. wherein:
the photovoltaic power generation system, the wind power generation system, the external power grid access system and the energy storage system supply power to the water electrolysis hydrogen production system through the power bus, and surplus power is supplied to the energy storage system through the power bus for storage; the liquid hydrocarbon storage and supply system supplies the feed gas and the fuel gas to the oxygen-enriched combustion hydrogen production system, and the oxygen-enriched combustion hydrogen production system supplies the generated hydrogen to the water electrolysis hydrogen production system; the water electrolysis hydrogen production system supplies the generated hydrogen to the outside and supplies the generated oxygen to the oxygen-enriched combustion hydrogen production system; tail gas generated by the oxygen-enriched combustion hydrogen production system enters a carbon dioxide capture and liquefaction system for carbon capture, and liquid CO generated by the carbon dioxide capture and liquefaction system2The produced condensed water is transported outside for steam production and reuse.
Embodiment I, based on multi-energy complementary green hydrogen production and oxygen-enriched combustion CO of direct-current micro-grid2Clean hydrogen was supplied under the trapping technique, as shown in fig. 2:
1) the external power grid access system is composed of the power grid access device 1 and the first AC/DC converter 2.
The grid power access arrangement 1 is connected by means of cables to the first AC/DC converter 2 and finally to the direct current microgrid bus 11.
2) A photovoltaic power generation system is composed of a solar cell array 3, a combiner box 4 and a first DC/DC converter 5.
The solar cell array 3 is connected with the combiner box 4 through a cable to collect electric power generated by the solar cell group, and the electric power collected by the combiner box 4 is regulated to reference voltage through the cable and the first DC/DC converter 5 and finally connected to the direct-current micro-grid bus 11.
3) The wind power generator 6 and the second AC/DC converter 7 constitute a wind power generation system.
The wind generator 6 produces electricity and is regulated to a reference voltage by a cable and a second AC/DC converter 7 and finally connected to a DC microgrid bus 11.
4) An energy storage system is composed of a second DC/DC converter 8, a storage battery pack 9, a super capacitor pack 10 and a direct current micro-grid bus 11.
The photovoltaic power generation system, the wind power generation system and the external power grid access system are adjusted to reference voltage through various converters and are finally connected to the direct-current micro-grid bus 11, the direct-current micro-grid bus 11 is a junction of the joint production system, and all energy is collected to the direct-current micro-grid bus 11 in a direct-current mode and then distributed.
The direct current microgrid bus 11 is connected with the second DC/DC converter 8 through a cable, and the second DC/DC converter 8 is respectively connected with an electric energy storage device such as a storage battery pack 9 and a super capacitor pack 10 through a cable.
5) The third DC/DC converter 12, the water electrolysis device 13, the hydrogen purification device 14, the hydrogen storage device 15 and the oxygen storage device 16 form a water electrolysis hydrogen production system.
The third DC/DC converter 12, the water electrolysis device 13, the hydrogen purification device 14, and the hydrogen storage device 15 are connected in sequence, and the crude hydrogen generated by the water electrolysis device 13 passes through the hydrogen purification device 14 to be a high-purity product hydrogen, and enters the hydrogen storage device 15 to be supplied as the product hydrogen. The water electrolysis device 13 is connected with an oxygen storage device 16, and hydrogen generated by the water electrolysis device 13 enters the oxygen storage device 16.
The water electrolysis device 13 can be an alkaline liquid water electrolysis tank, a solid Polymer (PEM) water electrolysis tank or a Solid Oxide (SOEC) electrolysis tank, and different water electrolysis processes can be determined according to different construction scales and project construction conditions.
The hydrogen purification device 14 comprises a series of hydrogen drying and deoxidizing devices such as a gas-liquid analyzer, a desalted water scrubber, a cooler, a steam-water separator, a deoxidizing tower, a TSV drying tower and the like. And the requirement for hydrogen impurities generated along with the utilization object of the prepared hydrogen gas is different, and the flow of reasonable equipment collocation can be increased or decreased.
6) The liquid hydrocarbon storage and supply system is composed of a liquid hydrocarbon storage tank 17, a BOG compressor 18, a liquid hydrocarbon pressurization gasifier 19, a liquid hydrocarbon booster pump 20 and a liquid hydrocarbon main gasifier 21.
The LNG fuel is stored in a liquid hydrocarbon storage tank 17. The liquid phase outlet of the liquid hydrocarbon storage tank 17 is connected to the inlet of the liquid hydrocarbon booster pump 20 through a pipeline, the outlet of the liquid hydrocarbon booster pump 20 is connected with the inlet of the liquid hydrocarbon pressurization gasifier 19 through a pipeline, and the outlet of the liquid hydrocarbon pressurization gasifier 19 returns to the liquid hydrocarbon storage tank 17 to realize self pressurization. The LNG fuel reaching 0.3-0.4 MPa is connected to the inlet of the main liquid hydrocarbon gasifier 21 from the other liquid phase outlet of the liquid hydrocarbon storage tank 17 through a pipeline, and is gasified to normal temperature; the Gas phase outlet of the liquid hydrocarbon storage tank 17 is connected to the BOG compressor 18 through a pipeline, and the BOG (Boil Off Gas flash Gas, static evaporation generated during static storage of liquid hydrocarbon) pressurized by the BOG compressor 18 is communicated and mixed with the gaseous hydrocarbon at the outlet of the liquid hydrocarbon main gasifier 21, and then the gaseous hydrocarbon is sent to the oxygen-enriched combustion hydrogen production converter 22 of the oxygen-enriched combustion hydrogen production system through a raw material pipeline and a fuel pipeline to participate in the reaction. Wherein:
the liquid hydrocarbon storage tank 17 may be a vacuum powder heat insulation tank or a high vacuum dewar when storing low-temperature materials such as LNG, ethane, etc., and may be a carbon steel horizontal tank when storing normal-temperature materials such as LPG, etc.; the BOG compressor 18 may be a screw compressor, a labyrinth compressor, a balanced reciprocating compressor; the liquid hydrocarbon booster pump 20 can be a barrel bag immersed pump or an external centrifugal pump; the main gasifier 21 for liquid hydrocarbons may be an air-temperature gasifier, a water-bath gasifier, or a steam heat-exchange gasifier.
7) The oxygen-enriched combustion hydrogen production system consists of an oxygen-enriched combustion hydrogen production converter 22, a steam generator 23, a shift reactor 24, a steam preheater 25, a cooling separator 26, a PSA separator 27 and a tail gas heat exchanger 28.
The oxygen-enriched combustion hydrogen production converter 22, the steam generator 23, the shift reactor 24, the steam preheater 25, the cooling separator 26 and the PSA separation device 27 are sequentially connected, and high-purity product hydrogen generated after separation by the PSA separation device 27 enters the hydrogen storage device 15. Oxygen from the oxygen storage device 16 enters the oxygen-enriched combustion hydrogen production converter 22, the oxygen-enriched combustion hydrogen production converter 22 is connected with a tail gas heat exchanger 28, and tail gas generated by the oxygen-enriched combustion hydrogen production converter 22 passes through the tail gas heat exchanger 28 and then enters a primary compressor 29 of a carbon dioxide capture and liquefaction system.
The oxygen-enriched combustion hydrogen production converter 22 is a device which uses hydrocarbons as raw materials and adopts a steam conversion gas-making process. The raw materials suitable for hydrocarbon conversion to produce hydrogen include natural gas, liquefied petroleum gas, various refinery gases, synthetic gas, straight run naphtha, raffinate oil, topping oil, secondary processing oil and the like. Wherein the natural gas with the lightest molecular weight and the minimum hydrocarbon ratio is used for producing hydrogen. This patent primarily exemplifies liquefied natural gas.
The basic principle is that water vapor is used as oxidant, and natural gas is converted under the action of nickel catalyst to obtain raw material gas for preparing hydrogen. The process is endothermic, so it needs external heat supply, and the heat needed by conversion is provided by oxygen-enriched combustion chemical reaction of fuel gas or desorbed gas. The natural gas is used as a raw material, firstly enters a tail gas convection section of the oxygen-enriched combustion hydrogen production converter to be preheated to 500-520 ℃, then is sent to the top of a radiation section of the hydrogen production converter, is distributed to enter each reaction tube, and flows through a catalyst layer from top to bottom. The reforming reaction condition is that the temperature is maintained at 750-920 ℃. The gas is subjected to steam reforming reaction in the reforming tubes, and the reformed gas from each reforming tube is collected to the gas collecting tube from the bottom.
The main reaction under the action of the nickel catalyst is as follows:
CH4+H2O----CO+3H2–Q
CO+H2O----CO2+H2+Q
the nitrogen which accounts for 4/5 in the case of ordinary air combustion does not participate in the combustion reaction, carries a large amount of heat in the combustion process, and generates nitrogen oxides. The utility model provides a carbon dioxide + pure oxygen replaces air combustion-supporting, multiplicable combustion efficiency to the final product only has carbon dioxide and water, will greatly do benefit to the cost that reduces follow-up carbon entrapment.
The reformed gas produced by the oxygen-enriched combustion hydrogen production converter 22 exchanges heat through the steam generator 23 to produce steam, and then enters the conversion reactor 24, and under the action of the medium-temperature catalyst, carbon monoxide and steam react as follows:
CO+H2O----CO2+H2+Q
the CO transformation reaction is exothermic reaction, the temperature of about 300 ℃ is favorable for transformation balance, higher CO transformation rate can be obtained, and further the hydrogen yield of unit raw material can be improved. In order to simplify the process flow and save the investment, only one stage of conversion is adopted for small-scale hydrogen production by natural gas conversion. And in a larger scale mode, a two-section heat exchange type conversion technology can be adopted, so that the yield of the product hydrogen is increased.
8) From the first compressor 29, CO2 A dewatering device 30, a condensate pump 31, a secondary compressor 32, CO2 Liquefied cooling tank 33, refrigerating device 34, and liquid CO2Storage tank 35, CO2The buffer tank 36 constitutes a carbon dioxide capture and liquefaction system.
The primary compressor 29, CO2Dehydration plant 30, secondary compressor 32, CO2Liquefied cold box 33, liquid CO2The storage tanks 35 are connected in sequence; the primary compressor 29 and CO2Buffer tank 36, the liquid CO2CO in the storage tank 352The evaporated gas enters CO from gas phase2A buffer tank 36; the CO is2The dehydration device 30 is connected with a condensate pump 31, and the outlet water of the condensate pump 31 is recovered as condensate water; the liquid CO2Liquid CO at the liquid phase outlet of the storage tank 352Loading and outputting; the CO is2The liquid cooling tank 33 is connected to a refrigeration device 34.
The primary compressor 29 and the secondary compressor 32 may be a reciprocating compressor, a screw compressor, or the like.
The CO is2The dehydration device 30 is a method for removing carbon dioxide by adsorbing water molecules of gas into pores of a desiccant by using the adsorption tension of the desiccant. The commonly used drying agent comprises silica gel, molecular sieve and the like, the technology is mature and reliable, and the water content of the dehydrated dry gas can be as low as 1 x 10-6The dew point of the dry natural gas water dehydrated by the molecular sieve can be as low as-100 ℃, so that the dew point requirement of subsequent carbon dioxide liquefaction can be met, and the phenomenon that the cold box flow channel is blocked by icing is avoided.
The CO is2Liquefied cold box 33 is due to CO2The optimal liquefaction point is about-30 ℃, the cooling temperature requirement is not high, and therefore, a plurality of strands of aluminum can be adoptedA cold box, or an evaporative heat exchanger, etc.
The refrigerating device 34 is composed of CO2The optimum liquefaction point of the refrigerant is about-30 ℃, so the refrigeration device can be one of a plurality of refrigeration cycles such as an R134a refrigeration cycle, an R410a refrigeration cycle, an R290 (propane) refrigeration cycle, an R600a refrigeration cycle and the like.
The liquid CO2The storage tank 35 is a metal storage tank having a cold insulation function, and can be designed to achieve cold insulation by vacuum powder heat insulation, perlite accumulation heat insulation, polyurethane coating heat insulation, or the like.
The intelligent energy management system 37 is a neural center and an energy management center of the system, performs acquisition management and coordination control on the devices in the region, and guarantees safe, stable and efficient operation of the system. The management system can comprehensively sense the operation, environmental state and personnel management of various devices (such as photovoltaic devices, converters, switches, electrolysis devices, hydrogen storage/oxygen devices, hydrocarbon conversion hydrogen production devices, carbon capture devices and the like), realize real-time monitoring, coordination control, peak clipping and valley filling and economic operation management, and can support the functions of load tracking, photovoltaic power generation prediction, demand side management, energy selling and the like.
In this embodiment, hydrogen is produced by using a multi-energy complementary direct-current microgrid:
the solar cell matrix 3 of the photovoltaic power generation system is connected with the combiner box 4 through a cable, and the combiner box 4 is connected with the first DC/DC converter 5 through a cable and finally connected to the direct current micro-grid bus 11. The system can realize the effective power generation time of about 1500-2000 hours per year by depending on the solar cell matrix power generation in the area with sunlight resources, and supplies the power to the microgrid.
The wind generator 6 of the wind power generation system is connected by a cable to the second AC/DC converter 7 and finally to the direct current microgrid bus 11. The system can realize that the effective power generation time is about 2000-3500 hours per year by relying on the wind driven generator to generate power in the area with wind resources, and the power is supplied to the micro-grid.
The second DC/DC converter 8 is connected with a direct current micro-grid bus 11 through a cable, and meanwhile, the second DC/DC converter 8 is respectively connected with a storage battery pack 9 and a super capacitor pack 10 through cables; the photovoltaic power generation and the wind power generation of the system can be stored and released by the storage battery pack and the super capacitor in a short time (the storage scale of 24 hours of self-electricity utilization of the matching system can be stored according to actual requirements), and the power supply of the microgrid is guaranteed.
A water electrolysis hydrogen production system: the abundance of photovoltaic and wind power generation can be made into hydrogen gas by the water electrolysis hydrogen production system and enter the hydrogen storage device 15.
Second embodiment, based on the multi-energy complementary green hydrogen production and oxygen-enriched combustion CO of the AC micro-grid2Clean hydrogen was supplied under the trapping technique, as shown in fig. 3:
as long as the equipment in the direct current micro-grid system of the utility model is slightly changed, the direct current micro-grid system can be changed into an alternating current micro-grid system to electrolyze water to produce hydrogen.
The first AC/DC converter 2 is regulated into a first transformer 102; the first DC/DC converter 5 is regulated as a DC/AC inverter 105; the second AC/DC converter 7 is regulated as a second transformer 107; the second DC/DC converter 8 is regulated as an AC/DC bidirectional converter 108; the third DC/DC converter 12 is regulated as an AC/DC converter 112.
After the final transformation, a schematic diagram (alternating current micro-grid system) of a clean hydrogen and renewable energy hydrogen joint production system is shown in fig. 3.
The solar cell matrix 103 of the photovoltaic power generation unit is connected by a cable to a combiner box 104, and the combiner box 104 is connected by a cable to a DC/AC inverter 105 and finally to an AC microgrid bus 111. The system can realize the effective power generation time of about 1500 hours per year by depending on the solar cell matrix power generation in the area with sunlight resources, and supplies the power to the micro-grid.
The wind generators of the wind power units are connected to the ac microgrid bus via cables and a second transformer 107. The system can realize the effective annual power generation time of about 2500 hours by relying on a wind driven generator to generate power in the area with wind power resources, and supplies the power to a micro-grid.
The AC/DC bidirectional converter 108 is connected with an alternating current micro-grid bus 111 through a cable, and meanwhile, the AC/DC bidirectional converter 108 is respectively connected with a storage battery pack 109 and a super capacitor pack 110 through cables; the photovoltaic power generation and the wind power generation of the system can be stored and released by the storage battery pack and the super capacitor in a short time (the storage scale of 1-12 hours can be matched according to actual requirements), and the power supply of a micro-grid is guaranteed.
In the water electrolysis hydrogen production system, the abundance of photovoltaic and wind power generation can be converted into direct current through the AC/DC converter and then hydrogen is produced by the water electrolysis hydrogen production system and enters the hydrogen storage device 115.
The oxygen-enriched combustion hydrogen production system and the carbon dioxide capture and liquefaction system are completely consistent with the first embodiment.
The utility model discloses a theory of operation is:
the utility model discloses a photoelectricity, wind-powered electricity generation, electric wire netting millet electricity system hydrogen, oxygen: the electric power generated by the solar cell array and the wind driven generator can be made into hydrogen and oxygen by the water electrolysis hydrogen production system and then enters the storage device for storage; at night without sunlight, cheap valley electricity can be taken from the power grid through the grid electricity access device and is made into hydrogen and oxygen through the electrolytic water system to enter the storage device for storage.
Hydrogen and oxygen generated by hydrogen production of the water electrolysis system are respectively stored in corresponding storage devices, wherein the hydrogen can be pressurized or liquefied and then is sent to a consumption terminal; the oxygen is mainly sent to the oxygen-enriched combustion hydrogen production converter 22 for oxygen-enriched combustion to provide heat for steam conversion hydrogen production, the prepared hydrogen is sent to a hydrogen storage tank after being purified to meet the product requirement, and finally is sent to a consumption terminal after being pressurized or liquefied.
The oxycombustion hydrogen production converter 22 is based on reforming of hydrocarbon steam by reforming of steam, and is a mature technology in the direction of hydrogen production from fossil energy, and comprises an endothermic reaction and an exothermic reaction. The raw materials suitable for hydrogen production by hydrocarbon conversion include natural gas, liquefied petroleum gas, various refinery gases, synthetic gas and the like. Wherein the natural gas with the lightest molecular weight and the minimum hydrocarbon ratio is used for producing hydrogen. This patent primarily exemplifies liquefied natural gas.
The basic principle is that water vapor is used as oxidant, and natural gas is converted under the action of nickel catalyst to obtain raw material gas for preparing hydrogen. The main reaction under the action of the nickel catalyst is as follows:
CH4+H2O----CO+3H2–Q
CO+H2O----CO2+H2+Q
the process of methane in the steam reforming conversion reaction is an endothermic process, the reaction temperature is up to 750-920 ℃, and the heat required by the conversion is provided by the oxygen-enriched combustion chemical reaction of the fuel gas.
After the reformed gas produced by the oxygen-enriched combustion hydrogen production converter 22 exchanges heat through the steam generator 23 to produce steam, the reformed gas enters the shift reactor 24 at the temperature of about 300 ℃, and carbon monoxide and steam react under the action of the shift catalyst as follows:
CO+H2O----CO2+H2+Q
the CO transformation reaction is exothermic reaction, the reaction temperature is 300 ℃ which is favorable for transformation balance, higher CO transformation rate can be obtained, and further the hydrogen yield of unit raw material can be improved. In order to simplify the process flow and save the investment, only one stage of conversion is adopted for small-scale hydrogen production by natural gas conversion. And in a larger scale mode, a two-section heat exchange type conversion technology can be adopted, so that the yield of the product hydrogen is increased.
The hydrogen produced by natural gas is purified by pressure swing adsorption. The pressure swing adsorption purification process is achieved due to two properties of the adsorbent in this physical adsorption: the adsorption capacity of the adsorbate on the adsorbent increases with the partial pressure of the adsorbate and decreases with the increase of the adsorption temperature. By utilizing the first property of the adsorbent, the aim of purifying hydrogen by preferentially adsorbing impurity components in a hydrogen-containing gas source can be fulfilled; by utilizing the second property of the adsorbent, the adsorbent can be adsorbed at low temperature and high pressure and desorbed and regenerated at high temperature and low pressure, so that the adsorption and regeneration cycle of the adsorbent is formed, and the aim of continuously extracting hydrogen is fulfilled. And the desorbed gas of the PSA separation device is sent to a reformer as fuel after being subjected to pressure stabilization.
The nitrogen which accounts for 4/5 in the case of ordinary air combustion does not participate in the combustion reaction, carries a large amount of heat in the combustion process, and generates nitrogen oxides. The utility model provides a carbon dioxide + pure oxygen replaces air combustion-supporting, multiplicable combustion efficiency to the final product only carbon dioxide will greatly do benefit to the cost that reduces follow-up carbon entrapment with water.
In CO2Under the condition of certain concentration, the reduction of the liquefaction temperature and the improvement of the liquefaction pressure are both beneficial to CO2Liquefaction, in the embodiment of the utility model, the selection of-30 ℃ and 3MPa is more beneficial to the capture of tail gas components.
CO we adopt2The dehydration device is a method for removing carbon dioxide by adsorbing water molecules of gas into pores of a desiccant by using the adsorption tension of the desiccant. The commonly used drying agent comprises silica gel, molecular sieve and the like, the technology is mature and reliable, and the water content of the dehydrated dry gas can be as low as 1 x 10-6The dew point of the dry natural gas water dehydrated by the molecular sieve can be as low as-100 ℃, so that the dew point requirement of subsequent carbon dioxide liquefaction can be met, and the phenomenon that the cold box flow channel is blocked by icing is avoided.
CO2Liquefied cold box due to CO2The optimal liquefaction point is about-30 ℃, the cooling temperature requirement is not high, and therefore a plurality of flow cold boxes or evaporative heat exchangers and the like can be adopted.
CO is used as refrigerating unit2The optimal liquefaction point of the refrigerant is about-30 ℃, so that the refrigerating device can select a most appropriate process according to field conditions from various refrigerating cycles such as an R134a refrigerating cycle, an R410a refrigerating cycle, an R290 (propane) refrigerating cycle, an R600a refrigerating cycle and the like.
Pertaining liquid CO2The storage tank is a metal storage tank with a cold insulation function, and can realize cold insulation and heat insulation by adopting schemes such as vacuum powder heat insulation, perlite accumulation insulation, polyurethane coating heat insulation and the like.
The device can be used as a joint production system of clean hydrogen and renewable energy hydrogen, and can also be used as a peak shaving energy storage facility of a power grid. The power of the electrolyzed water is reduced to output electric power outwards at the peak of electricity utilization in the daytime, the power of the electrolyzed water can be increased to absorb valley electricity at the valley of electricity utilization such as at night, and meanwhile, the fluctuation of the scale of hydrocarbon hydrogen production can be adjusted by adjusting the supply of the hydrogen production oxygen, so that the stable operation of the downstream hydrogen utilization terminal is ensured.

Claims (10)

1. A clean hydrogen and renewable energy source hydrogen joint production system is characterized in that: including photovoltaic power generation system, wind power generation system, outside electric wire netting access system, electrolytic water hydrogen production system, oxygen boosting burning hydrogen production system, carbon dioxide entrapment and liquefaction system, energy storage system, wherein: the photovoltaic power generation system, the wind power generation system, the external power grid access system and the energy storage system are connected with the water electrolysis hydrogen production system through power buses; the hydrogen production system by water electrolysis is connected with the oxygen-enriched combustion hydrogen production system, and the oxygen-enriched combustion hydrogen production system is connected with the carbon dioxide capture and liquefaction system.
2. The clean hydrogen and renewable energy hydrogen cogeneration system of claim 1, wherein: the water electrolysis hydrogen production system comprises a water electrolysis device, a hydrogen purification device and a hydrogen storage device which are connected in sequence, wherein the water electrolysis device is connected with the oxygen storage device.
3. The clean hydrogen and renewable energy hydrogen cogeneration system of claim 1, wherein: the oxygen-enriched combustion hydrogen production system comprises an oxygen-enriched combustion hydrogen production converter, a steam generator, a shift reactor, a steam preheater, a cooling separator and a PSA (pressure swing adsorption) separation device which are connected in sequence, wherein the oxygen-enriched combustion hydrogen production converter is connected with a tail gas heat exchanger.
4. The clean hydrogen and renewable energy hydrogen cogeneration system of claim 1, wherein: the carbon dioxide capture and liquefaction system comprises a primary compressor and CO which are sequentially connected2Dehydration device, two-stage compressor, CO2Liquefied cold box, liquid CO2Storage tank, said primary compressor and CO2Buffer tank connection, said liquid CO2Gas phase and CO of storage tank2The buffer storage tank is connected.
5. The clean hydrogen and renewable energy hydrogen cogeneration system of claim 4, wherein: the CO is2The dewatering device is connected with the condensate pump.
6. The clean hydrogen and renewable energy hydrogen cogeneration system of claim 4, wherein: the CO is2The liquefaction cold box is connected with a refrigerating device.
7. The clean hydrogen and renewable energy hydrogen cogeneration system of claim 1, wherein: the oxygen-enriched combustion hydrogen production system is connected with the liquid hydrocarbon storage and supply system.
8. The clean hydrogen and renewable energy hydrogen cogeneration system of claim 7, wherein: the liquid hydrocarbon storage and supply system comprises a liquid hydrocarbon storage tank, and a BOG compressor, a liquid hydrocarbon booster pump and a main liquid hydrocarbon gasifier which are respectively connected with the liquid hydrocarbon storage tank, wherein the outlet of the liquid hydrocarbon booster pump is connected with the inlet of the liquid hydrocarbon booster gasifier through a pipeline, and the outlet of the liquid hydrocarbon booster gasifier returns to the liquid hydrocarbon storage tank.
9. The clean hydrogen and renewable energy hydrogen cogeneration system of claim 1, wherein: the power bus is a direct-current micro-grid bus, the external power grid access system and the wind power generation system are respectively connected with the direct-current micro-grid bus through a first AC/DC converter and a second AC/DC converter, and the photovoltaic power generation system, the energy storage system and the water electrolysis hydrogen production system are respectively connected with the direct-current micro-grid bus through the first DC/DC converter, the second DC/DC converter and a third DC/DC converter.
10. The clean hydrogen and renewable energy hydrogen cogeneration system of claim 1, wherein: the power bus is an alternating current micro-grid bus, the external power grid access system and the wind power generation system are respectively connected with the alternating current micro-grid bus through a first transformer and a second transformer, and the photovoltaic power generation system, the energy storage system and the water electrolysis hydrogen production system are respectively connected with the alternating current micro-grid bus through a DC/AC inverter, an AC/DC bidirectional converter and an AC/DC converter.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115200025A (en) * 2022-07-06 2022-10-18 中国华能集团清洁能源技术研究院有限公司 System and method for incinerating household garbage by utilizing renewable energy
CN115200025B (en) * 2022-07-06 2024-05-31 中国华能集团清洁能源技术研究院有限公司 System and method for incinerating household garbage by using renewable energy

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115200025A (en) * 2022-07-06 2022-10-18 中国华能集团清洁能源技术研究院有限公司 System and method for incinerating household garbage by utilizing renewable energy
CN115200025B (en) * 2022-07-06 2024-05-31 中国华能集团清洁能源技术研究院有限公司 System and method for incinerating household garbage by using renewable energy

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