CN1947516A - Disinfectant composition with function of deodorization and bleaching effects and its prepn. method - Google Patents
Disinfectant composition with function of deodorization and bleaching effects and its prepn. method Download PDFInfo
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Abstract
A deodoring, bleeching and disintifecting composition in the form of powder, particle, lozenge, tablet, effervescent agent, liquid, colloid, or aerosol for various purposes is prepared from chlorinated isocyanuric acid, bromochloro hydrantoin, dibromo hydrantoin, or hypochlorite for providing hypochlorous acid component through reacting on chlorate, chlorite and tabilizer to obtain stable ClO2 system, and adding the corrosion inhibitor of metal.
Description
Technical field
The present invention relates to a kind of deodorizing, bleaching and sanitizing composition and preparation method, it relates generally to the design that the reaction of the instant prescription of effervesce and corresponding chemical quantizes, and the manufacturing processing method of solid product such as corresponding tablet, pulvis, granule, heavy stone used as an anchor agent and liquid state, colloidal state and aerosol products.
Background technology
Adopt the existing long history of simple substance chlorination sterilization, have the characteristics of broad-spectrum high efficacy, but found afterwards that simple substance chlorine and hypochlorous acid can react with the organic matter in the water, form the chlorohydrocarbon compound, the suspicion of bringing out cancer is arranged.Another is nontoxic so simple substance chlorine and hypochlorination's compound be transformed in water, and the compound that bactericidal activity is high again is a new technical problem.Humphrey Davery successfully made chlorine dioxide in 1811, existing thousands of families water treatment plant and other industry are used chlorine dioxide in the North America at present, mainly be used in except that algae, remove and smell, decolour, sterilize, decompose phenol compound, reduce toxicity, remove iron manganese impurity etc.Use at European chlorine dioxide is more general, because chlorine dioxide can not produce toxic and side effect at disinfecting process, its safety is classified as the A1 level by the World Health Organization, by American-European developed country praise highly be the 4th generation green disinfectant.Yet the liquids and gases of chlorine dioxide are extremely unstable, and concentration only 10% just may be exploded in air, and the stability that solves the chlorine dioxide product also is the emphasis that countries in the world are studied.
Although U.S. Pat 5399288 (1995), US6197215 (2001), US6602442 (2003) adopt chlorate and hypochlorite can make a spot of chlorine dioxide under the effect of acid compound, but product stability is still not good enough, it is permanent to be difficult to preserve, the instant effect of product is also relatively poor in addition, use inconvenient, the corrosivity of product is more serious, influences the scope of application etc.; At present domestic also have some similar products like to occur, but their instant effect and stability have a certain distance in actual use discovery and requirement, in water instant and stable between contradiction do not obtain real solution.
Summary of the invention
Main purpose of the present invention provides a kind of stable in properties, bi-component solid-state instant type, bi-component liquid stable type and deodorizing, bleaching and sanitizing compositions such as one pack system solid-state instant type, single component liquid stable type that dissolving is made of A component and B component fast, poisonous hypochlorous acid, hypochlorite compounds can be changed into chlorine dioxide, wherein the mass percentage content of each component is:
(1) bi-component solid-state composition:
The A component: hypochlorous acid provides agent 0.1%-60%
Fine silica powder 0.01%-3%
Boric acid 0.5%-8%
Benzoate 0.5%-10%
Carbonate 10%-50%
Cellulose 1%-10%
B component: chlorine oxygen hydrochlorate 1%-30%
Per-compound 1%-10%
Disulfate 2%-18%
Zinc sulphate 0.1%-3%
Benzoate 0.5%-10%
Boric acid 0.5%-8%
Cellulosate 1%-10%
Sulphate 25%-45%
Polyphosphate 0.2%-10%
Fine silica powder 0.01%-3%
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, A component hypochlorous acid provides agent, can be chlorinated isocyanuric acid and salt thereof, BCDMH and salt thereof and hypochlorite, can be sodium, potassium or calcium salt, sodium salt preferably, mass percent is 0.1%-60%, preferably 2%-55%.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, the A component contains fine silica powder, and mass percent is 0.01%-3%, preferably 0.5%-1%.Mainly play lubricated, moulding and stability action.
Aforesaid a kind of deodorizing, bleaching and sanitizing composition and preparation method, the A component contains boric acid, mass percent 0.5%-8%, preferably 2%-6%.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, the A component contains benzoate, mass percent 0.5%-8%, preferably 3%-7% can be any salt, preferably a sodium salt in the alkali metal family.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, the A component contains carbonate or acid carbonate, mass percent 10%-50%, preferably 20%-40%; Can be any salt, preferably sodium salt in the alkali metal family.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, A component contain fine little element or its salt, mass percent 1%-10%, and preferably 2%-7% can be any salt, preferably a sodium salt in the alkali metal family.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, B component contain chlorine oxygen hydrochlorate, mass percent 1%-30%, preferably 2%-26%; Can be perchlorate, chlorate or chlorite, preferably chlorite; Can be any salt, preferably sylvite in the alkali metal family.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, the B component contains zinc sulphate, mass percent 0.1%-3%, preferably 0.2%-2%.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, the B component contains a kind of per-compound, shared mass percent example 1%-10%, preferably 3%-8%; Can be perborate, percarbonate, solid-state Peracetic acid or percarbamide, preferably secondly perborate be percarbonate, is any in the alkali metal salt, and preferably secondly sodium salt is sylvite.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, B component contain a kind of disulfate compound, and shared mass percent is 2%-18%, 4%-16% preferably, disulfate can be any in the alkali metal salt, and preferably secondly sodium salt is sylvite.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, the B component contains a kind of sulphate cpd, proportion 25%-45%, 30%-40% preferably, sulphate can be any in the alkali metal salt, preferably secondly sodium salt is sylvite.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, the B component contains boric acid, and shared mass percent is 0.5%-8%, preferably 2%-6%.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, the B component contains benzoate, and shared mass percent is 0.5%-8%, and preferably 3%-7% can be any salt, preferably a sodium salt in the alkali metal family.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, B component contain fine little element or its salt, and mass percent is 1%-10%, and preferably 2%-7% can be any salt, preferably a sodium salt in the alkali metal family.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, B component contain a kind of polyphosphoric acids salt compound, and shared mass percent is 0.2%-10%, 0.5%-8% preferably, polyphosphate.Can be any in the alkali metal salt, preferably secondly sodium salt be sylvite.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, the B component contains a kind of fine silica powder, proportion 0.01%-3%, preferably 0.5%-1%.
Preparation of compositions technology:
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method are the mass ratioes according to the ratio and the one pack system of component A and B component, pulverize respectively, cross the 80-100 mesh sieve, put into the thermostatic drying chamber temperature control then respectively 80-110 ℃ of drying, the time is controlled at was advisable in 8-12 hour, measure moisture then, according to the accurate weighing of formula ratio, put into 30 minutes married operations of three-dimensional hybrid device, after mensuration content is accurate, can carry out next step processing again according to different purposes.
A, instant type pulvis: can directly pack, seal and be finished product.
B, instant type granule: can adopt suitable solvent, binder by comminutor, make the effervescence granular of various particle diameters, respectively packing.
C, dissolving tablet and lozenge: by selecting different tablet press machines such as rotary 25,33,40 stamping machines for use, select different punch dies again, adopt dry powder direct tabletting,, make the suitable product of hardness and intensity by adjusting the pressure of machine.Sheet is heavy can be 0.5 gram/sheet, 1.0 gram/sheets, 1.50 gram/sheets, 2 gram/sheets, 3 gram/sheets, 20 gram/sheets, 100 gram/sheets, 150 gram/sheets, 300 gram/sheets etc.
The shaped article of the deodorizing that makes, bleaching and sanitizing composition A part and B part, render in the water simultaneously, different instructions for uses, the dosage that adds entry does not wait, mutual chemical reaction by 5-30 minute, obtain a kind of aqueous solution of chlorine dioxide of limegreen, effectively chlorine dioxide content can reach 20-60000mg/L.The basic principle of preparation is the chemical reaction basic principle of Figure 1A component main chemical reactions mechanism and Fig. 2 A and B component main chemical reactions mechanism realization in the accompanying drawing to specifications.
The present invention can make the higher chlorine dioxide of productive rate by a series of like this chemical reaction; By stabilizing agent in the component and chlorine dioxide reaction fully and combine, finally can obtain the chlorine dioxide of stable state again.
(2) bi-component fluid composition:
The A component: hypochlorous acid provides agent 0.1%-60%
Disulfate 2%-18%
Silicates 0.01%-5%
Tetraborate 0.1%-8%
Benzoate 0.1%-10%
Alkali compounds 1%-50%
Polyphosphate 0.2%-10%
Deionized water 10%-90%
B component: chlorine oxygen hydrochlorate 1%-30%
Per-compound 1%-10%
Zinc sulphate 0.1%-3%
Sulphate 0.5%-45%
Acid compound 0.1%-50%
Deionized water 10%-90%
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, bi-component fluid composition A component wherein, contain a kind of hypochlorous acid agent is provided, can be chlorinated isocyanuric acid and salt thereof, BCDMH and salt thereof and hypochlorite, can be sodium, potassium or calcium salt, sodium salt preferably, mass percent is 0.1%-60%, preferably 2%-55%.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, wherein bi-component fluid composition A component contains a kind of disulfate compound, shared mass percent example 2%-18%, 4%-16% preferably, disulfate can be any in the alkali metal salt, preferably secondly sodium salt is sylvite.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, wherein bi-component fluid composition A component contains silicate, mass percent 0.01%-5%, preferably 0.2%-4% can be any salt, preferably a sodium salt in the alkali metal family.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, wherein bi-component fluid composition A component contains tetraborate, can be sodium, potassium, lithium, magnesium or calcium salt, preferably sodium salt, mass percent is 0.1%-8%, preferably 0.2%-5%.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, wherein bi-component fluid composition A component contains a kind of polyphosphoric acids salt compound, shared mass percent is 0.2%-10%, 0.5%-8% preferably, polyphosphate, can be any in the alkali metal salt, preferably secondly sodium salt be sylvite.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, wherein bi-component fluid composition A component contains benzoate, and shared mass percent is 0.1%-10%, preferably 0.2%-3%, can be any salt, preferably sodium salt in the alkali metal family.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, wherein bi-component fluid composition A component contains a kind of alkali compounds, proportion is 1%-50%, 5%-35% preferably, it can be sodium hydroxide, potassium hydroxide, lithium hydroxide, sodium carbonate, potash, sodium bicarbonate, sodium hydrogen phosphate or their mixture, preferably sodium hydroxide.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, wherein bi-component fluid composition B component contains chlorine oxygen hydrochlorate, mass percent 1%-30%, preferably 2%-26%; Can be perchlorate, chlorate or chlorite, preferably chlorite; Can be any salt, preferably sylvite in the alkali metal family.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, wherein bi-component fluid composition B component contains a kind of per-compound, and shared mass percent example is 1%-10%, preferably 3%-8%; Can be perborate, percarbonate, solid-state Peracetic acid or percarbamide, preferably secondly perborate be percarbonate, is any in the alkali metal salt, and preferably secondly sodium salt is sylvite.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, wherein bi-component fluid composition B component contains zinc sulphate, mass percent 0.1%-3%, preferably 0.2%-2%.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, wherein bi-component fluid composition B component contains a kind of sulphate cpd, shared mass percent example 0.5%-45%, 1%-15% preferably, sulphate can be any in the alkali metal salt, preferably secondly sodium salt is sylvite.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, wherein bi-component fluid composition B component contains a kind of acid compound, proportion is 0.1%-50%, preferably 0.3%-30% can be hydrochloric acid, sulfuric acid, phosphoric acid, formic acid, acetate, citric acid, lactic acid, malic acid, sulfamic acid, tartaric acid etc. or their mixture.
(3) one pack system solid-state composition:
Hypochlorous acid provides agent 0.1%-60%
Fine silica powder 0.01%-3%
Boric acid 0.5%-8%
Benzoate 0.5%-10%
Per-compound 10%-60%
Cellulosate 1%-10%
Chlorine oxygen hydrochlorate 2%-30%
Sulphate 10%-40%
Zinc sulphate 0.1%-3%
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, monobasic packing list component solid-state composition wherein, contain a kind of hypochlorous acid agent is provided, proportion 0.1%-60%, preferably 10%-55% can be TCCA (Trichloroisocyanuric acid), DCCA salt, BCDMH class, C5H6Br2N2O2 class, clorox or calcium hypochlorite etc.; Contain a kind of fine silica powder, proportion is 0.01%-3%, preferably 0.1%-2%; Contain a kind of boric acid, proportion is 0.5%-8%, preferably 1%-40%; Contain a kind of per-compound, proportion is 10%-60%, and preferably 15%-40% can be perborate, percarbonate, solid-state Peracetic acid, percarbamide; Contain a kind of cellulosate, proportion is 1%-10%, preferably 3%-8%; Contain a kind of benzoate, proportion is 0.5%-10%, 3%-8% preferably, and it can be sodium, sylvite; Contain a kind of chlorine oxygen hydrochlorate, proportion is 2%-30%, and preferably 3%-25% can be sodium perchlorate, potassium hyperchlorate, potassium chlorate, sodium chlorate, potassium chlorite, sodium chlorite, magnesium chlorite or calcium chlorite; Contain a kind of sulphate, proportion is 10%-40%, and preferably 15%-35% can be lithium, potassium or sodium salt; Contain a kind of zinc sulphate, proportion is 0.1%-3%, preferably 0.5%-2%.
The above a kind of deodorizing, bleaching and sanitizing composition and preparation method, monobasic packaged solid state single-component composition wherein, mainly realize by being prepared as follows method, ratio according to prescription is pulverized respectively, sieves, is dried, adopt dry powder package, dry powder direct tabletting or process for granulating, make the production method of monobasic packing shaped article; During use, render in a certain amount of water, by the stabilizing chlorine dioxide aqueous solution that reaction makes, this shaped article is meant tablet, pulvis, granule or lozenge.
(4) single component liquid composition:
Hypochlorous acid provides agent 0.1%-60%
Silicate 0.01%-8%
Boric acid and salt 0.1%-8%
Benzoate 0.05%-10%
Per-compound 5%-60%
Chlorine oxygen hydrochlorate 2%-30%
Zinc sulphate 0.1%-3%
Polyphosphate 0.05%-5%
Edetate 0.01%-4%
Compound 0.5%-25% such as phosphoric acid
N, two (3-aminopropyl) the alkanamine 0.01%-8% of N-
Macromolecular compound 0.1%-10%
Propellant 10%-60%
Deionized water 10%-90%
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, monobasic packing list component fluid composition wherein, contain a kind of hypochlorous acid agent is provided, proportion 0.1%-60%, 3%-55% preferably, can be TCCA (Trichloroisocyanuric acid), DCCA salt, BCDMH class, C5H6Br2N2O2 class, clorox or calcium hypochlorite etc., preferably clorox; Contain a kind of boric acid and salt, proportion is 0.1%-8%, and preferably 0.2%-6% can be boric acid, Boratex, potassium borate, sodium tetraborate, dipotassium tetraborate or their mixture, preferably boric acid; Contain a kind of silicate, proportion is 0.01%-8%, and preferably 0.1%-4% can be silicon potash fertilizer, sodium silicate, sodium metasilicate, calcium silicates or their mixture, preferably sodium metasilicate; Contain a kind of benzoate, proportion is 0.05%-10%, and preferably 0.1%-5% can be Potassium Benzoate, Sodium Benzoate, magnesium benzoate, calcium benzoate or their mixture, preferably Sodium Benzoate; Contain a kind of per-compound, proportion is 5%-60%, and preferably 8%-40% can be sodium perborate, SODIUM PERCARBONATE, potassium percarbonate, Peracetic acid, peroxy-disulfuric acid or percarbamide, preferably SODIUM PERCARBONATE; Contain a kind of chlorine oxygen hydrochlorate, proportion is 2%-30%, and preferably 3%-25% can be sodium perchlorate, potassium hyperchlorate, potassium chlorate, sodium chlorate, potassium chlorite, sodium chlorite, magnesium chlorite or calcium chlorite, preferably sodium chlorite; Contain a kind of zinc sulphate compound, proportion is 0.1%-3%, preferably 0.3%-2%; Contain a kind of polyphosphate, proportion is 0.05%-5%, and preferably 0.5%-3% can be tripolyphosphate, five Quadrafos, and its salt can be potassium, sodium, magnesium or calcium salt, preferably tripolyphosphate; Contain a kind of edetate, proportion is 0.01%-4%, 0.1%-3% preferably, and its salt can be potassium, sodium, magnesium or calcium salt or their mixture, preferably sodium salt; Contain compounds such as a kind of phosphoric acid, proportion is 0.5%-25%, preferably 2%-20%; Contain a kind of N, two (3-aminopropyl) the alkanamine proportions of N-are 0.01%-8%, 0.1%-6% preferably, and alkyl is that to contain carbon number be C in its molecule
3-C
22Alkane or their mixture, preferably C
6-C
15Alkane; Contain a kind of macromolecular compound, proportion is 0.1%-10%, 0.3%-8% preferably, can be carbomer 934-943, agar, acrylic resin, gelatin, hydroxymethyl-propyl cellulose, POLYPROPYLENE GLYCOL, polyvinylpyrrolidone, PVP-acrylate copolymer, vinyl acetate-butenoic acid copolymer or their mixture, preferably gelatin; Contain a kind of propellant, proportion is 10%-60%, and preferably 15%-45% can be fluorochloroparaffins, dimethyl ether, propane hydrocarbon, normal butane hydrocarbon, isobutyl alkane, nitrogen, carbonic acid gas, nitrogen oxide, liquefied natural gas or their mixture.
A kind of as mentioned above deodorizing, bleaching and sanitizing composition and preparation method, monobasic packages for liquid single-component composition wherein, mainly realize by being prepared as follows method, ratio according to prescription joins in the pure water of certain mass number in order, by heating 20 ℃-65 ℃ and suitable mechanical agitation, form the aqueous solution of clear, again by compounds such as a certain amount of phosphoric acid of interpolation, the pH value that makes solution system is between 2-14, obtain solution dosage composition of the present invention, also can add a certain amount of inertia propellant by professional equipment again and obtain aerosol combination of the present invention; Can finish colloidal composition of the present invention by adding a small amount of macromolecular compound.
Main feature of the present invention is that the effervesce dissolving is quick, reaction velocity fast productive rate height, particularly dyad packaging product, and stability is high, safety easy to use, metering easily.Because component has the preferred metal corrosion inhibition through the anticorrosion design, to test under 20 ℃ of conditions, maximum working concentration is when 1000mg/L, and the quality that the immersion metal is measured after 72 hours before and after the metal reduces, thereby determines the metal erosion degree, and the result shows:
Stainless steel does not have corrosion, and carbon steel does not have corrosion substantially, the corrosion of copper moderate, and aluminium base is not had corrosion.
Stability test: 37 ℃ of constant temperature, under the lasting 90 days conditions, measure decline percentage≤8.7% of working substance content in the component, meet the requirement of the countries concerned's disinfecting product, the shelf-life of product is 2 years.
Description of drawings
Fig. 1 is A component main chemical reactions mechanism figure;
Fig. 2 is A and B component main chemical reactions mechanism figure.
Embodiment
Embodiment 1
A kind of deodorizing, bleaching and sterilization bi-component solid-state composition and preparation method, wherein the mass percent of each component is:
A component: DCCNa 35%-55%
Fine silica powder 0.5%-1%
Boric acid 2%-6%
Sodium Benzoate 3%-7%
Sodium carbonate 20%-30%
Cellulose 1%-8%
B component: sodium chlorite 2%-18%
Sodium perborate 2%-9%
Niter cake 2%-18%
Zinc sulphate 0.5%-2%
Sodium Benzoate 2%-8%
Boric acid 2%-6%
Cellulosate 2%-8%
Sodium sulphate 30%-40%
Sodium polyphosphate 1%-10%
Fine silica powder 0.5%-2%
Adopt and pulverize the back drying, cross 100 mesh sieves, direct tablet compressing, adopt 25 or 33 towards rotary tablet machine, select suitable punch die, adjust machine pressure, work continuously, can make 3 gram/sheets, smooth in appearance, pure white, immaculate, no sticking phenomenon have suitable hardness, and molten water test shows: dissolving in 5-8 minute, form lurid clarification aqueous solution of chlorine dioxide, prove and to realize the purpose that designs.
Embodiment 2
A kind of deodorizing, bleaching and sterilization bi-component solid-state composition and preparation method, the mass percent of its each component is:
A component: TCCA (Trichloroisocyanuric acid) 3%-55%
Fine silica powder 0.2%-1%
Boric acid 2%-6%
Sodium Benzoate 1%-8%
Sodium carbonate 20%-50%
Cellulosate 1%-18%
B component: sodium chlorate 2%-18%
SODIUM PERCARBONATE 2%-9%
Niter cake 2%-8%
Zinc sulphate 0.5%-2%
Sodium Benzoate 2%-8%
Boric acid 2%-8%
Cellulose 2%-8%
Sodium sulphate 30%-40%
Sodium polyphosphate 1%-10%
Fine silica powder 0.5%-2%
Embodiment 3
A kind of deodorizing, bleaching and sterilization bi-component solid-state composition and preparation method, the mass percent of its each component is:
A component: calcium hypochlorite 5%-55%
Fine silica powder 0.2%-1%
Boric acid 2%-6%
Sodium Benzoate 1%-8%
Sodium bicarbonate 20%-40%
Cellulose 1%-8%
B component: sodium chlorate 2%-18%
SODIUM PERCARBONATE 2%-9%
Niter cake 2%-18%
Zinc sulphate 0.5%-2%
Sodium Benzoate 2%-8%
Boric acid 2%-8%
Cellulosate 2%-8%
Sodium sulphate 30%-40%
Sodium polyphosphate 1%-10%
Fine silica powder 0.5%-2%
A kind of deodorizing of embodiment 4 (optimization embodiment), bleaching and sterilization bi-component solid-state composition, the mass percent of its each component is:
A component: TCCA (Trichloroisocyanuric acid) 5%-55%
Fine silica powder 0.5%-1%
Boric acid 2%-6%
Sodium Benzoate 3%-7%
Sodium bicarbonate 15%-40%
Cellulose 2%-7%
B component: sodium chlorite 6%-18%
Sodium perborate 4%-8%
Niter cake 2%-8%
Zinc sulphate 0.5%-2%
Sodium Benzoate 2%-8%
Boric acid 2%-8%
Sodium cellulosate 2%-7%
Sodium sulphate 30%-40%
Sodium polyphosphate 4%-8%
Fine silica powder 0.5%-1%
Embodiment 5
A kind of deodorizing, bleaching and sterilization bi-component solid-state composition, the mass percent of its each component is:
A component: BCDMH 5%-55%
Fine silica powder 0.5%-1%
Boric acid 2%-6%
Sodium Benzoate 2%-8%
Sodium bicarbonate 20%-40%
Sodium cellulosate 1%-8%
B component: sodium chlorate 2%-18%
SODIUM PERCARBONATE 2%-9%
Niter cake 2%-8%
Zinc sulphate 0.5%-2%
Sodium Benzoate 2%-8%
Boric acid 2%-8%
Cellulose 2%-8%
Sodium sulphate 30%-40%
Sodium polyphosphate 1%-10%
Fine silica powder 0.5%-2%
Embodiment 6
A kind of deodorizing, bleaching and sterilization bi-component solid-state composition monobasic one pack system solid-state composition, the mass percent of its each component is:
BCDMH 5%-55%
Fine silica powder 0.5%-1%
Boric acid 2%-6%
Sodium Benzoate 2%-8%
SODIUM PERCARBONATE 25%-50%
Sodium cellulosate 1%-8%
Sodium chlorite 2%-18%
Zinc sulphate 0.2%-2%
Sodium sulphate 20%-40%
Embodiment 7 (optimization embodiment)
Bromine glycolylurea 5%-55%
Fine silica powder 0.5%-1%
Boric acid 2%-6%
Sodium Benzoate 2%-8%
SODIUM PERCARBONATE 25%-50%
Sodium cellulosate 1%-8%
Sodium chlorite 2%-18%
Zinc sulphate 0.2%-2%
Sodium sulphate 20%-40%
Adopt and pulverize the back drying, cross 80 mesh sieves, direct tablet compressing, adopt 33 towards rotary tablet machine, select suitable punch die, adjust machine pressure, work continuously, can make 1.5 gram/sheets, smooth in appearance, pure white, immaculate, no sticking phenomenon have suitable hardness, and molten water test shows: dissolving in 3-8 minute, form lurid clarification aqueous solution of chlorine dioxide, prove and to realize the purpose that designs.
8 one kinds of deodorizing of embodiment, bleaching and sterilization single component liquid composition, the mass percent of its each component is:
Calcium hypochlorite 5%-45%
Sodium silicate 0.5%-4%
Boratex 0.6%-6%
Sodium Benzoate 0.1%-8%
Peroxidating Boratex 8%-40%
Potassium chlorite 3%-23%
Zinc sulphate 1%-2%
Five polyphosphate sodium 0.9%-4%
Disodium ethylene diamine tetraacetate 0.01%-4%
Compound 0.8%-8% such as phosphoric acid
N, two (3-aminopropyl) the alkanamine 0.5%-5% of N-
Carbomer 934 0.2%-3%
15%-50% such as normal butane hydrocarbon
Deionized water 5%-80%
A kind of deodorizing of embodiment 9 (optimization embodiment), bleaching and sterilization single component liquid composition, the mass percent of its each component is:
Clorox 6%-40%
Sodium silicate 0.5%-5%
Boratex 0.5%-6%
Potassium Benzoate 0.1%-8%
Sodium carbonate peroxide 9%-40%
Sodium chlorite 3%-25%
Zinc sulphate 0.5%-2%
Sodium phosphate trimer 0.8%-3%
Disodium ethylene diamine tetraacetate 0.01%-4%
Compound 0.8%-8% such as phosphoric acid
N, two (3-aminopropyl) the ten alkanamine 0.5%-5% of N-
Carbomer 934 0.2%-3%
15%-50% such as normal butane hydrocarbon
Deionized water 5%-80%
Present composition bactericidal assay result:
Bacterial classification: withered grass brood cell black mutation bacillus neutralizer: 1% tween+1%Na
2S
2O
3
| Valid density (mg/l) | Action time (min) | Killing rate (Δ lg) |
| 125 250 400 800 1000 | 5 10 20 30 5 10 20 30 5 10 20 30 5 10 20 30 5 10 20 30 | 3 3 4 4 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 |
Invention is summed up
The chlorine dioxide that deodorizing of the present invention, bleaching and the sanitizing composition design chemical reaction by science successfully changes into environment-friendly type with organochlorine and the inorganic chlorine of toxic side effect; Effervesce A component and B component bi-component solid-state composition have fast dissolving and reaction in 3-8 minute, form the aqueous solution of clarification; One pack system solid bodies cording has preferably faster characteristics of stability and dissolution velocity, the metal inhibitor system in the component, make its with the Metal Contact process in have good compatibility, make it have in actual applications wider scope. The bi-component liquid form product has good stability, can directly use, and is very convenient; The single component liquid product has the convenient characteristics of using than the bi-component product. The stabilizing agent of the formula Design of this formulation products, the comprehensive function of auxiliary agent, make it have good stability, accumulating is convenient, safety, the characteristics such as easy metering, in addition, the microbiological test result demonstrates the bactericidal activity of the high-efficiency broad spectrum of product, makes the present invention have wide actual application prospect. Single-component composition of the present invention is upper more convenient from using, and make also to realize, but the two component compositions that form not as A and B is more reliable and more stable. Therefore the present composition can be applied to Living Water processing, environment disinfected, hospital, domestic utensils, fruit and vegetable sterilization and deodorizing, decolouring processing etc. safer and more effectively.
From using function, practical effect two-component composition A of the present invention component itself to consist of a kind of hypochlorous high-efficiency broad spectrum disinfectant that contains, can directly apply to the sterilization of sewage disposal, environment disinfected, hospital surgical equipment etc. in addition. Therefore the present invention can have different several functions and effect according to different objects and purposes, possesses multiple selection function and actual effect.
Claims (10)
1. a deodorizing, bleaching and sanitizing composition and preparation method, it is characterized in that, solid-state effervesce quick-dissolving agent and liquid preparation that it is made up of chlorine-containing compound such as chlorinated isocyanurates, BCDMH and salt, hypochlorite etc. provide the agent component as hypochlorous acid, again by obtaining the application of method in formulation preparation such as pulvis, granule, tablet and liquid of stable chlorine dioxide disinfectant disinfectant with reactions such as chlorine oxygen hydrochlorates; The medicament system that the hypochlorous acid that the present composition contains provides agent, peracid salt compound, carbonate, chlorine oxygen hydrochlorate, corrosion inhibiter, acidity or alkali compounds etc. to make by following mass percent, it both can be solid-state or liquid two-component packaging bi-component, also can be monobasic packaged solid state or liquid state, colloidal state and aerosol single-component composition:
(1) bi-component solid-state composition:
The A component: hypochlorous acid provides agent 0.1%-60%
Fine silica powder 0.01%-3%
Boric acid 0.5%-8%
Benzoate 0.5%-10%
Carbonate 10%-50%
Cellulose 1%-10%
B component: chlorine oxygen hydrochlorate 1%-30%
Per-compound 1%-10%
Disulfate 2%-10%
Zinc sulphate 0.1%-3%
Benzoate 0.5%-10%
Boric acid 0.5%-8%
Cellulosate 1%-10%
Sulfuric acid 25%-45%
Polyphosphate 0.2%-10%
Fine silica powder 0.01%-3%
2. according to the described a kind of deodorizing of claim 1, bleaching and sanitizing composition and preparation method, bi-component solid-state composition A component wherein, it is characterized in that, contain a kind of hypochlorous acid agent is provided, its proportion is 0.1%-60%, can be TCCA (Trichloroisocyanuric acid), DCCA salt, BCDMH class, C5H6Br2N2O2 class, chlorine water, clorox or calcium hypochlorite etc.; It is characterized in that contain a kind of fine silica powder, proportion is 0.01%-3%; Contain a kind of boric acid crystalline compounds, proportion is 0.5%-10%; Contain a kind of benzoate crystalline compounds, proportion is 0.5%-8%, and it can be sodium, potassium or calcium salt; Contain a kind of carbonate or bicarbonate crystalline compounds, proportion is 10%-50%, and it can be sodium, potassium or calcium salt; Contain a kind of cellulose or cellulosate compound, proportion is 1%-10%; Contain a kind of zinc sulphate crystalline compounds, proportion is 0.1%-3%.
3. according to the described a kind of deodorizing of claim 1, bleaching and sanitizing composition and preparation method, bi-component solid-state composition B component wherein, it is characterized in that, contain a kind of chlorine oxygen hydrochlorate, proportion is 1%-30%, can be sodium perchlorate, potassium hyperchlorate, potassium chlorate, sodium chlorate, potassium chlorite, sodium chlorite, magnesium chlorite or calcium chlorite; Contain a kind of per-compound, proportion is 1%-10%, can be sodium perborate, SODIUM PERCARBONATE, potassium percarbonate, Peracetic acid or percarbamide; Contain a kind of disulfate compound, proportion is 2%-10%, can be potassium, sodium, magnesium or calcium salt; Contain a kind of benzoate crystalline compounds, proportion is 0.5%-8%, can be potassium, sodium, magnesium or calcium salt; Contain a kind of boric acid crystalline compounds, proportion is 0.5%-8%; Containing a kind of sulphate cpd, can be potassium, sodium, magnesium or calcium salt, and proportion is 25%-45%; Contain a kind of polyphosphoric acids salt compound, proportion is 0.2%-10%, can be tripolyphosphate, five Quadrafos, and its salt can be potassium, sodium, magnesium or calcium salt; Contain a kind of fine silica powder, proportion is 0.01%-3%.
4. according to the described a kind of deodorizing of claim 1, bleaching and sanitizing composition and preparation method, Solid Double components composition wherein, it is characterized in that, it is ratio according to component A and B component, pulverize respectively, sieve, dry, adopt dry powder package, dry powder direct tabletting or process for granulating, make the production technology of A part and B part two-component packaging product.
5. according to the described a kind of deodorizing of claim 1, bleaching and sanitizing composition and preparation method, it is characterized in that, it is ratio according to component A and B component, make various two-component packaging shaped articles respectively, put into a certain amount of water during use simultaneously, by the aqueous solution of chlorine dioxide that reaction makes, this shaped article is meant tablet, pulvis, granule or lozenge.
(2) bi-component fluid composition:
The A component:
Hypochlorous acid provides agent 0.1%-60%
Disulfate 2%-18%
Silicates 0.01%-5%
Tetraborate 0.1%-8%
Benzoate 0.1%-10%
Alkali compounds 1%-50%
Polyphosphate 0.2%-10%
Deionized water 10%-90%
B component: chlorine oxygen hydrochlorate 1%-30%
Per-compound 1%-10%
Zinc sulphate 0.1%-3%
Sulphate 0.5%-15%
Acid compound 0.1%-50%
Deionized water 10%-90%
6. according to the described a kind of deodorizing of claim 1, bleaching and sanitizing composition and preparation method, bi-component fluid composition A component wherein, it is characterized in that, contain hypochlorous acid agent is provided, its proportion is 0.1%-60%, can be TCCA (Trichloroisocyanuric acid), DCCA salt, BCDMH class, C5H6Br2N2O2 class, chlorine water, clorox or calcium hypochlorite etc.; Contain a kind of disulfate compound, proportion is 2%-50%, can be lithium, potassium or sodium salt; Contain a kind of silicate, shared example is 0.01%-5%, can be potassium, sodium, magnesium or calcium salt; Contain a kind of tetraborate crystalline compounds, proportion is 0.1%-8%, can be potassium, sodium or calcium salt; Contain a kind of benzoate crystalline compounds, proportion is 0.1%-10%, and it can be sodium, sylvite; Contain a kind of polyphosphoric acids salt compound, proportion is 0.2%-10%, can be tripolyphosphate, five Quadrafos, and its salt can be potassium, sodium, magnesium or calcium salt.
7. according to the described a kind of deodorizing of claim 1, bleaching and sanitizing composition and preparation method, B component in the bi-component fluid composition, it is characterized in that, contain a kind of chlorine oxygen hydrochlorate, proportion is 1%-30%, can be sodium perchlorate, potassium hyperchlorate, potassium chlorate, sodium chlorate, potassium chlorite, sodium chlorite, magnesium chlorite or calcium chlorite; Contain a kind of per-compound, proportion is 1%-10%, can be sodium perborate, SODIUM PERCARBONATE, potassium percarbonate, Peracetic acid, peroxy-disulfuric acid or percarbamide or their mixture; Contain a kind of zinc sulphate compound, proportion 0.1%-3%; Contain a kind of sulphate cpd, proportion is 0.5%-15%, can be lithium, potassium or sodium salt; Contain a kind of acid compound, proportion is 0.1%-50%, can be hydrochloric acid, sulfuric acid, phosphoric acid, formic acid, acetate, citric acid, lactic acid, malic acid, sulfamic acid, tartaric acid etc. or their mixture.
(3) one pack system solid-state composition:
Hypochlorous acid provides agent 0.1%-60%
Fine silica powder 0.01%-3%
Boric acid 0.5%-8%
Benzoate 0.5%-10%
Per-compound 10%-60%
Cellulosate 1%-10%
Chlorine oxygen hydrochlorate 2%-30%
Sulphate 10%-40%
Zinc sulphate 0.1%-3%
8. according to the described a kind of deodorizing of claim 1, bleaching and sanitizing composition and preparation method, monobasic packing list component solid-state composition wherein, it is characterized in that, provide agent for containing a kind of hypochlorous acid, proportion 0.1%-60% can be TCCA (Trichloroisocyanuric acid), DCCA salt, BCDMH class, C5H6Br2N2O2 class, clorox or calcium hypochlorite etc.; Contain a kind of fine silica powder, proportion is 0.01%-3%; Contain a kind of boric acid, proportion is 0.5%-8%; Contain a kind of per-compound, proportion is 10%-60%, can be perborate, percarbonate, solid-state Peracetic acid, percarbamide; Contain a kind of cellulosate, proportion is 1%-10%; Contain a kind of benzoate, proportion is 0.5%-10%, and it can be sodium, sylvite; Contain a kind of chlorine oxygen hydrochlorate, proportion is 2%-30%, can be sodium perchlorate, potassium hyperchlorate, potassium chlorate, sodium chlorate, potassium chlorite, sodium chlorite, magnesium chlorite or calcium chlorite; Contain a kind of sulphate, proportion is 10%-40%, can be lithium, potassium or sodium salt; Contain a kind of zinc sulphate, proportion is 0.1%-3%.
(3) single component liquid composition:
Hypochlorous acid provides agent 0.1%-60%
Silicate 0.01%-8%
Borate 0.1%-8%
Benzoate 0.05%-10%
Per-compound 5%-60%
Chlorine oxygen hydrochlorate 2%-30%
Zinc sulphate 0.1%-3%
Polyphosphate 0.05%-5%
Edetate 0.01%-4%
Compound 0.5%-25% such as phosphoric acid
N, two (3-aminopropyl) the alkanamine 0.01%-8% of N-
Macromolecular compound 0.1%-10%
Propellant 10%-60%
9. according to the described a kind of deodorizing of claim 1, bleaching and sanitizing composition and preparation method, monobasic packages for liquid single-component composition wherein, it is characterized in that, be to contain a kind of hypochlorous acid agent is provided, proportion is 0.1%-60%, can be TCCA (Trichloroisocyanuric acid), DCCA salt, BCDMH class, C5H6Br2N2O2 class, clorox or calcium hypochlorite etc.; Contain a kind of borate, proportion is 0.1%-8%, can be Boratex, potassium borate, sodium tetraborate, dipotassium tetraborate or their mixture; Contain a kind of silicate, proportion is 0.01%-8%, can be silicon potash fertilizer, sodium silicate, sodium metasilicate, calcium silicates or their mixture; Contain a kind of benzoate, proportion is 0.05%-10%, can be Potassium Benzoate, Sodium Benzoate, magnesium benzoate, calcium benzoate or their mixture; Contain a kind of per-compound, proportion is 5%-60%, can be sodium perborate, SODIUM PERCARBONATE, potassium percarbonate, Peracetic acid, peroxy-disulfuric acid or percarbamide; Contain a kind of chlorine oxygen hydrochlorate, proportion is 2%-30%, can be sodium perchlorate, potassium hyperchlorate, potassium chlorate, sodium chlorate, potassium chlorite, sodium chlorite, magnesium chlorite or calcium chlorite; Contain a kind of zinc sulphate compound, proportion is 0.1%-3%; Contain a kind of polyphosphate, proportion is 0.05%-5%, can be tripolyphosphate, five Quadrafos, and its salt can be potassium, sodium, magnesium or calcium salt; Contain a kind of edetate, proportion is 0.01%-4%, and its salt can be potassium, sodium, magnesium or calcium salt or their mixture; Contain compounds such as a kind of phosphoric acid, proportion is 0.5%-25%; Contain a kind of macromolecular compound, proportion is 0.1%-10%, can be carbomer 390-943, agar, acrylic resin, gelatin, hydroxymethyl-propyl cellulose, POLYPROPYLENE GLYCOL, polyvinylpyrrolidone, PVP-acrylate copolymer, vinyl acetate-butenoic acid copolymer; Contain a kind of N, two (3-aminopropyl) alkanamines of N-, proportion is 0.01%-8%, alkyl is that to contain carbon number be C in its molecule
3-C
22Alkane, or their mixture; Contain a kind of propellant, proportion is 10%-60%, can be fluorochloroparaffins, dimethyl ether, propane hydrocarbon, normal butane hydrocarbon, isobutyl alkane, nitrogen, carbonic acid gas, nitrogen oxide, liquefied natural gas or their mixture.
10. according to the described a kind of deodorizing of claim 1, bleaching and sanitizing composition and preparation method, monobasic packaged solid state single-component composition wherein, it is characterized in that, ratio according to prescription is pulverized respectively, sieves, is dried, adopt dry powder package, dry powder direct tabletting or process for granulating, make the production method of monobasic packing shaped article; During use, render in a certain amount of water, by the stabilizing chlorine dioxide aqueous solution that reaction makes, this shaped article is meant tablet, pulvis, granule or lozenge.Monobasic packages for liquid single-component composition wherein, it is characterized in that, ratio according to prescription joins in the pure water of certain mass number in order, by heating 20 ℃-65 ℃ and suitable mechanical agitation, form the aqueous solution of clear, by compounds such as a certain amount of phosphoric acid of interpolation, the pH value that makes solution system is between 3-12 again, obtain solution dosage composition of the present invention, also can add a certain amount of inertia propellant by professional equipment again and obtain aerosol combination of the present invention; Can finish colloidal composition of the present invention by adding a small amount of macromolecular compound.
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| CN101947237A (en) * | 2010-03-13 | 2011-01-19 | 沙建民 | Externally-applied hypochlorous acid liquid with functions of oxidizing, disinfecting, expelling and removing toxins |
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| CN103052316A (en) * | 2010-08-31 | 2013-04-17 | 荷兰联合利华有限公司 | A novel biocide composition |
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| CN102634423A (en) * | 2012-03-21 | 2012-08-15 | 王春玲 | Deodorizing and passivating cleaning agent for oil refining devices |
| CN102626104B (en) * | 2012-03-22 | 2014-01-08 | 广东环凯微生物科技有限公司 | Stabilized chlorine dioxide disinfection solution and preparation method thereof |
| CN102626104A (en) * | 2012-03-22 | 2012-08-08 | 广东环凯微生物科技有限公司 | Stabilized chlorine dioxide disinfection solution and its preparation method |
| CN103505749A (en) * | 2013-09-25 | 2014-01-15 | 张跃杰 | Air sterilization freshener |
| CN104886412A (en) * | 2015-04-17 | 2015-09-09 | 周希潭 | Antidote potion as well as making method and application |
| CN106994298A (en) * | 2017-04-10 | 2017-08-01 | 北京雅迪力特航空新材料股份公司 | A kind of aircraft toilet deodorant |
| CN111226921A (en) * | 2020-03-18 | 2020-06-05 | 湖南化工研究院有限公司 | Stabilizer for preventing sodium hypochlorite from decomposing and stable sodium hypochlorite aqueous solution |
| CN111481723A (en) * | 2020-04-17 | 2020-08-04 | 重庆有艾生物科技有限公司 | Integrated technology and method for dynamically disinfecting air in gathering place by using weak-acid hypochlorous acid disinfectant |
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