CN1899672A - Combined liquid phase catalytic oxidizing and microbial method for simultaneously removing SO2 and nitrogen oxide in smoke - Google Patents

Combined liquid phase catalytic oxidizing and microbial method for simultaneously removing SO2 and nitrogen oxide in smoke Download PDF

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CN1899672A
CN1899672A CNA2006100110134A CN200610011013A CN1899672A CN 1899672 A CN1899672 A CN 1899672A CN A2006100110134 A CNA2006100110134 A CN A2006100110134A CN 200610011013 A CN200610011013 A CN 200610011013A CN 1899672 A CN1899672 A CN 1899672A
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liquid phase
flue gas
phase catalytic
nitrogen oxide
nox
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CN100417431C (en
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孙珮石
黄若华
郑顺生
邓辅唐
王洁
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Yunnan University YNU
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Abstract

The present invention is technological process of eliminating SO2 and NOx from industrial fume in a biomembrane packed tower system with circular catalytically oxidizing sprayed liquid and combined de-sulfurizing bacteria and denitrifying bacteria colony, and belongs to the field of waste gas purifying biochemical technology. The present invention features the addition of special composite metal ion catalyst to the sprayed liquid, and the integrated catalytically oxidizing and biological purification process. The present invention has the mutual promotion of both chemical catalytic process and biological process to reach SO2 and NOx eliminating rate of 50-80 % and high reaction rate, and possesses wide application foreground in controlling pollution of industrial low concentration waste gas.

Description

Combined liquid phase catalytic oxidizing and microbial removes the method for sulfur dioxide in flue gas and nitrogen oxide simultaneously
Technical field: the present invention adopts a biofilm packing Tower System (single tower cleaning system) that uses catalytic oxidation circulated sprinkling liquid, obtains to have under the liquid phase catalytic oxidation environmental condition to remove sulfur dioxide in flue gas (SO simultaneously by screening and cultivation domestication 2) and the desulfurization bacterium and the denitrifier composite flora of nitrogen oxide (NOx) performance, and make biomembrane filled tower with this composite flora biofilm.Belong to biological-chemical combined method waste gas purification technical field.
Background technology: China is to be the country of main energy sources with coal, is maximum in the world coal production state and country of consumption.Coal in the consumption of the primary energy of China proportion up to about 70%.Because about coal 84% or more is mainly used in direct burning (as the coal-burning power plant etc.), in addition to the low-concentration sulfur dioxide (SO by the fire coal generation 2) and the control measure of atmosphere pollutions such as nitrogen oxide (NOx) and flue dust and act on limited, thereby the atmosphere pollution that has caused China is based on coal smoke type.In recent years, along with the rapid increase of rapid development of economy and consumption of coal, the SO of China 2Discharge capacity is up to more than 2,000 ten thousand tons, by SO 2Be that acid rain contamination hazard area due to main has accounted for the about 40% of area, the therefore annual and economic loss that cause in the whole nation has reached and has exceeded 100 billion.SO 2Harm cause the great attention of countries in the world government and environmental administration as a big problem already of environmental pollution.Aspect flue gas desulfurization technique, various countries have developed many new methods.Yet along with the further understanding that NOx in the flue gas is also caused acid rain and secondary pollution-photochemical fog thereof, people urgently wish to study the technological process that makes new advances, and make SO 2With the disposable synchronous removal of NOx.No matter this class comprehensive process is to having the transformation of desulphurization system now, still to newly-built flue gas purification system investment and the reduction of operating cost and the raising of purification efficiency, all being significant.
Since the eighties in 20th century, technical advanced person, one of rational novel simultanously desulfurizing and denitrification technology new technology forward position research focus that always is the environmental protection field have economically been sought.Why the research work of this respect comes into one's own in many developed countries and China, and partly cause is that the environmental protection legislation of various countries is all to the SO of fume emission 2, pollutant such as NOx and flue dust proposed more strict requirement.At present external flue gas desulfuration and denitrification technical research can be divided into two big classes substantially: while desulfurization removing nitric technology in (1) stove combustion process, (2) burning back flue gas desulfuration and denitrification technology.The former representative art has CFBC method (CFBC), lime stone to inject sectional combustion method (LIMB), sodium matter sorbent injection method etc. in the stove, and the latter's representative art has the wet type metallo-chelate method of purification, NOXSO dry type adsorpting regenerating process, electron beam process for purifying (EBA) etc.Domestic research in this respect is less, still in the starting stage.In recent years there is research such as Ma Shuanchen to adopt researchs employing molybdenum silicic acid chemical absorption methods such as liquid phase catalytic oxidation, Zhao Youcai to remove SO in the flue gas simultaneously 2, NOx experimental study, Chengdu power plant has then carried out the electron beam method of purification demonstration project of desulfurization removing nitric simultaneously.At present generally have the technological process complexity in the simultanously desulfurizing and denitrification technology that test is used, equipment investment is big or operating cost is high, to flue gas in low concentration SO 2, byproduct low with the combined removal rate of NOx disposed technology or economic problems such as utilizing difficulty, be difficult on a large scale mostly in realization apply widely.Therefore, be necessary to research and develop novel simultanously desulfurizing and denitrification new technology in conjunction with the specific national conditions of China.
The biological waste gas purification technology is as an exhaust-gas treatment new technology, with its economy, effectively, pollutant handles thoroughly, is suitable for handling characteristics such as low-concentration industrial waste gas, more and more be subjected to people's extensive attention, therefore it progressively develops into the hot research field, a forward position of industrial waste gas purifying in the world in recent years.The research and the application practice of this technical method show, its solve almost recycle be worth, the purified treatment difficulty is big and expense is high, aspect the purified treatment difficult problem of the low-concentration industrial waste gas that simultaneously harm of health and ecological environment be can not be ignored again (all being one of difficult problem of environmental protection aspect), have special effect at home and abroad.
Summary of the invention: the technology of the present invention method is to adopt one to use the biofilm packing Tower System (single tower cleaning system) of catalytic oxidation circulated sprinkling liquid to remove SO in the flue gas simultaneously 2Industry smoke comprehensive purifying processing method with NOx.It is the advantage and the characteristic of a kind of optimization integrated liquid phase catalytic oxidation (chemistry) method of purification and biological clarification, and " chemical catalysis-biological treatment " that all have novel concept at home and abroad removes SO in the flue gas simultaneously 2Gaseous contaminant new purification method with NOx.
Combined liquid phase catalytic oxidizing and microbial of the present invention removes sulfur dioxide in flue gas (SO simultaneously 2) and the method and technology scheme of nitrogen oxide (NOx) be: adopt proprietary waste gas purification special bacteria gas phase screening breeding apparatus and technology, by screening and cultivate domestication and obtain under the liquid phase catalytic oxidation environmental condition, to have to remove SO in the flue gas simultaneously 2With the desulfurization bacterium and the denitrifier composite flora of NOx performance, and make biomembrane filled tower with these composite flora biofilms.It is characterized in that in the circulated sprinkling liquid of biomembrane filled tower, adding special-purpose metal ion population catalyst, make the sulfur in smoke (SO that enters in the biomembrane filled tower 2) and nitrogen oxide (NOx) molecule can experience liquid phase catalytic oxidation and the biodegradation double purified is handled mechanism.During operation biomembrane filled tower purified treatment industrial waste gas, need to use the biomembrane on circulated sprinkling liquid wetting inner-tower filling material surface, and provide its grow needed nutriment or environment adjusting material to biomembrane.
The present invention adopts the circulated sprinkling liquid that contains special-purpose metal ion population catalyst, reaches with the compound action environment that makes up " chemical catalysis-biological treatment " to remove SO in the flue gas simultaneously 2Purpose with NOx.
The special-purpose metal ion population catalyst that the present invention adopts is by containing Fe 2+, Mn 2+, Zn 2+, Al 3+The sulfate of four metal ion species is formulated.Contain in the circulated sprinkling liquid of special-purpose metal ion population catalyst Fe 2+, Mn 2+, Zn 2+, Al 3+The concentration of four metal ion species is respectively 0.5%, 0.2%, 0.5%, 1.0%, and its metal ion total concentration is 2.2%.
Biomembrane filled tower used in the present invention is to be made by desulfurization bacterium and denitrifier composite flora biofilm that screening under the liquid phase catalytic oxidation environmental condition is cultivated.
The method that combined liquid phase catalytic oxidizing and microbial of the present invention removes sulfur dioxide in flue gas and nitrogen oxide simultaneously is to adopt one to use the biofilm packing Tower System (single Tower System) of catalytic oxidation circulated sprinkling liquid to purify sulfur dioxide in flue gas (SO 2) and the industrial flue gas cleaning processing method of nitrogen oxide (NOx).
Know-why of the present invention promptly in the biofilm packing Tower System of purified treatment industrial waste gas, adopts the circulated sprinkling liquid that contains special-purpose metal ion population catalyst, makes the SO in the flue gas that enters in the biomembrane filled tower 2Can experience liquid phase catalytic oxidation and biodegradation double purified processing mechanism with the NOx molecule, to reach the optimum efficiency of purified industrial waste gas.
In the operation, contain SO 2Send into biomembrane filled tower [utility model patent, patent No. ZL97211331.2] with the industrial smoke (in case of necessity industrial smoke being done preliminary treatment such as cooling) of NOx by blower fan and carry out purified treatment.Biomembrane filled tower adopts the gas-liquid counter current mode to operate.Flue gas enters at the bottom of tower, contacts SO wherein with wetting biomembrane absorption attached to the solid packing surface in uphill process 2Be recycled metal ion combination catalyst catalytic oxidation in the spray liquid with the one side of NOx, generate sulfuric acid and nitric acid; On the other hand also simultaneously by purifications (owing to constitute biomembranous desulfurization bacterium and the denitrifier composite flora suits to grow in sour environment, so the sour environment that the liquid phase catalytic oxidation effect is produced is understood the enhanced biological catharsis) of catching, degrade of the microorganism in the biomembrane.Purified gas is discharged from the cat head of biomembrane filled tower.Circulation fluid is got to cat head from storage tank by water circulating pump and is sprayed on the biofilm packing downwards, and goes out to enter the circulation fluid storage tank from tower bottom flow and recycle.Because moisture content has evaporation loss in the circulated sprinkling process, therefore to regularly in the circulation fluid storage tank, add supplementing water, nitrogen phosphorus nutrition composition, special-purpose metal ion population catalyst etc.
The purifying property of the technology of the present invention method, cost of investment, operating cost, operability, byproduct etc. all are better than prior art, and PRELIMINARY RESULTS shows that this system is to SO in the experimental gas 2Can reach 50%～80% respectively with the purification efficiency of NOx, the reaction rate ratio increases when adopting biological method purification separately, shows that there are mutual promoting action between the two in chemical catalysis and bioanalysis.The present invention will be in industrial low concentration SO 2Have broad application prospects with NOx exhaust emission controlling party mask.
The process flow diagram of Fig. 1 the inventive method.
Among the figure: 1-preprocessor (using in case of necessity); The 2-air-introduced machine; The 3-biomembrane filled tower; 4-circulation fluid storage tank and pump.
The specific embodiment:
Embodiment 1～4: adopt to remove SO in the flue gas simultaneously 2With liquid phase catalytic oxidation-microorganism combined method of NOx to containing SO 2Carry out the purified treatment experiment with the industrial waste gas of NOx.The technical process schematic diagram of the technology of the present invention method as shown in Figure 1.Adopt proprietary waste gas purification special bacteria gas phase screening breeding apparatus and technology, obtain under the liquid phase catalytic oxidation environmental condition, to have SO in the flue gas of purification by screening and cultivation domestication 2With the desulfurization bacterium and the denitrifier composite flora of NOx performance, and make biomembrane filled tower with this this composite flora biofilm.Wherein biomembrane filled tower is that tower diameter is the small-sized glass biomembrane filled tower of 100mm, divides two sections to load the spherical haydite of class that diameters are 2.5cm, packing volume 3.18L * 2 in the packed tower.Experimental implementation is all carried out under normal temperature and pressure conditions, and gas flow is 0.1～0.3m 3/ h, SO in the flue gas 2And NO XConcentration is respectively 2100～3900mg/m 3, 600～1200mg/m 3The circulated sprinkling flow quantity is 8～10L/h, wherein Fe 2+, Mn 2+, Zn 2+, Al 3+Concentration Deng four metal ion species is respectively 0.5%, 0.2%, 0.5%, 1.0%.Biomembrane filled tower import and export SO 2And NO XGas concentration adopts Britain to produce flue gas analyzer KM900 and measures SO in the liquid phase 2And NO XAmount adopt the conventional chemical method to measure.Experimental result is as shown in table 1.
Table 1 removes SO in the flue gas simultaneously 2Experimental result with NOx
Sequence number Gas flow m 3/h Circulating fluid flow rate L/h SO 2Inlet concentration mg/m 3 NOx mouth concentration mg/m 3 SO 2Exit concentration mg/m 3 SO 2Purifying rate % NOx mouth concentration mg/m 3 NOx purifying rate %
1 0.1 8 2120 598 195 90.8 231 61.4
2 0.2 10 2234 663 131 94.1 225 66.1
3 0.3 10 2514 640 208 91.7 174 72.8
4 0.3 10 3884 1212 675 82.6 462 61.9

Claims (5)

1, a kind of combined liquid phase catalytic oxidizing and microbial removes sulfur dioxide in flue gas (SO simultaneously 2) and the method for nitrogen oxide (NOx), adopt proprietary waste gas purification special bacteria gas phase screening breeding apparatus and technology, by screening and cultivate domestication and obtain under the liquid phase catalytic oxidation environmental condition, to have SO in the flue gas of purification 2, the NOx performance desulfurization bacterium and denitrifier composite flora, and make biomembrane filled tower with these composite flora biofilms, it is characterized in that in the circulated sprinkling liquid of biomembrane filled tower, adding special-purpose metal ion population catalyst, make the sulfur in smoke (SO that enters in the biomembrane filled tower 2) and nitrogen oxide (NOx) molecule can experience liquid phase catalytic oxidation and the biodegradation double purified is handled mechanism.
2, a kind of combined liquid phase catalytic oxidizing and microbial according to claim 1 removes the method for sulfur dioxide in flue gas and nitrogen oxide simultaneously, it is characterized in that special-purpose metal ion population catalyst is by containing Fe 2+, Mn 2+, Zn 2+, Al 3+The sulfate of four metal ion species is formulated.
3, combined liquid phase catalytic oxidizing and microbial according to claim 1 and 2 removes the method for sulfur dioxide in flue gas and nitrogen oxide simultaneously, it is characterized in that containing in the circulated sprinkling liquid of special-purpose metal ion population catalyst Fe 2+, Mn 2+, Zn 2+, Al 3+The concentration of four metal ion species is respectively 0.5%, 0.2%, 0.5%, 1.0%, and its metal ion total concentration is 2.2%.
4, combined liquid phase catalytic oxidizing and microbial according to claim 1 removes the method for sulfur dioxide in flue gas and nitrogen oxide simultaneously, it is characterized in that employed biomembrane filled tower is to be made by desulfurization bacterium and denitrifier composite flora biofilm that screening under the liquid phase catalytic oxidation environmental condition is cultivated.
5, combined liquid phase catalytic oxidizing and microbial according to claim 1 removes the method for sulfur dioxide in flue gas and nitrogen oxide simultaneously, it is characterized in that described is to adopt one to use the biofilm packing Tower System (single Tower System) of catalytic oxidation circulated sprinkling liquid to purify sulfur dioxide in flue gas (SO 2) and the industrial flue gas cleaning processing method of nitrogen oxide (NOx).
CNB2006100110134A 2006-07-03 2006-07-03 Combined liquid phase catalytic oxidizing and microbial method for simultaneously removing SO2 and nitrogen oxide in smoke Expired - Fee Related CN100417431C (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102050516A (en) * 2009-10-27 2011-05-11 中国石油化工股份有限公司 Method for preparing selective microbial packing
CN102179166A (en) * 2011-04-08 2011-09-14 云南大学 Method for increasing synchronous flue gas desulfuration and denitrification efficiency of bio-membrane packed tower by using external carbon source
CN102228789A (en) * 2011-05-13 2011-11-02 云南大学 Method for improving desulfurization and denitrification efficiencies of flue gas in biomembrane packing tower by using artificial compound functional bacteria simultaneously
CN103721561A (en) * 2013-01-10 2014-04-16 华南理工大学 Biologic filtering method for simultaneously desorbing NOX (Nitric Oxide), SO2 and PM2.5 in aerobic environment
CN103933855A (en) * 2014-04-26 2014-07-23 南京宇行环保科技有限公司 Double-tower serially-connected device and method for removing SO2 and NOx from smoke by using biological method
CN104043329A (en) * 2014-07-09 2014-09-17 云南大学 Method for improving denitrification efficiency of biological membrane packed tower for simultaneously removing sulfur and nitrogen from smoke by externally adding rare earth enhancer
CN105413354A (en) * 2015-12-21 2016-03-23 天津欧盼科技开发有限公司 Method for reducing environmental pollution
CN109569270A (en) * 2019-02-01 2019-04-05 南京大学 Method that is a kind of while removing high load capacity sulfur dioxide and nitrogen oxides in exhaust gas
CN110499262A (en) * 2018-05-17 2019-11-26 卢松 Purification absorbs the compound of slurry-spraying pelletizing flue gas
CN113828141A (en) * 2021-11-11 2021-12-24 昆明理工大学 Method for efficiently desulfurizing and recycling sulfur resources by combining manganese ion aqueous solution with NOx

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CN101708415B (en) * 2009-12-09 2015-08-19 云南大学 Double-column in series formula catalysis-biofilm packing Tower System removes the method for sulfur dioxide in flue gas and nitrogen oxide simultaneously
CN102989272A (en) * 2012-12-04 2013-03-27 天津大学 Method and device for synchronously removing sulfur dioxide and nitric oxide by flue gas biological method

Cited By (14)

* Cited by examiner, † Cited by third party
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CN102050516A (en) * 2009-10-27 2011-05-11 中国石油化工股份有限公司 Method for preparing selective microbial packing
CN102179166A (en) * 2011-04-08 2011-09-14 云南大学 Method for increasing synchronous flue gas desulfuration and denitrification efficiency of bio-membrane packed tower by using external carbon source
CN102228789A (en) * 2011-05-13 2011-11-02 云南大学 Method for improving desulfurization and denitrification efficiencies of flue gas in biomembrane packing tower by using artificial compound functional bacteria simultaneously
CN103721561B (en) * 2013-01-10 2015-12-02 华南理工大学 Remove NO under a kind of aerobic environment simultaneously x, SO 2and PM 2.5biologic filtration method
CN103721561A (en) * 2013-01-10 2014-04-16 华南理工大学 Biologic filtering method for simultaneously desorbing NOX (Nitric Oxide), SO2 and PM2.5 in aerobic environment
CN103933855A (en) * 2014-04-26 2014-07-23 南京宇行环保科技有限公司 Double-tower serially-connected device and method for removing SO2 and NOx from smoke by using biological method
CN103933855B (en) * 2014-04-26 2016-09-14 南京宇行环保科技有限公司 SO in bioanalysis removing flue gas2and NOxdouble-column in series device and method
CN104043329A (en) * 2014-07-09 2014-09-17 云南大学 Method for improving denitrification efficiency of biological membrane packed tower for simultaneously removing sulfur and nitrogen from smoke by externally adding rare earth enhancer
CN104043329B (en) * 2014-07-09 2016-06-15 云南大学 A kind of additional rare earth reinforced agent improves the method for simultanously desulfurizing and denitrification biomembrane filled tower nitric efficiency
CN105413354A (en) * 2015-12-21 2016-03-23 天津欧盼科技开发有限公司 Method for reducing environmental pollution
CN110499262A (en) * 2018-05-17 2019-11-26 卢松 Purification absorbs the compound of slurry-spraying pelletizing flue gas
CN109569270A (en) * 2019-02-01 2019-04-05 南京大学 Method that is a kind of while removing high load capacity sulfur dioxide and nitrogen oxides in exhaust gas
CN109569270B (en) * 2019-02-01 2020-01-14 南京大学 Method for simultaneously removing high-load sulfur dioxide and nitrogen oxide in waste gas
CN113828141A (en) * 2021-11-11 2021-12-24 昆明理工大学 Method for efficiently desulfurizing and recycling sulfur resources by combining manganese ion aqueous solution with NOx

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