CN1454075A

CN1454075A - Hair care kits and heating devices for warming hair care compositions

Info

Publication number: CN1454075A
Application number: CN00819879.9A
Authority: CN
Inventors: 三松新; 川内昭彦
Original assignee: Procter and Gamble Ltd
Current assignee: Procter and Gamble Ltd; Procter and Gamble Co
Priority date: 2000-09-08
Filing date: 2000-09-08
Publication date: 2003-11-05
Also published as: WO2002019977A1; MXPA03002058A; AU2000273617A1; JP2004508314A; EP1328241A2

Abstract

Disclosed is hair care kits used for warming a hair care composition before the composition is applied to the hair. One of the kits comprises (i) an aqueous hair care composition and (ii) a heat generating agent is isolated from the aqueous care composition, wherein the heat generating agent is isolated from the aqueous hair care composition. One of the heating devices comprises a heating source comprising (i) a heat generating agent which generates a heat by mixing a reacting means, and (ii) a reacting means.

Description

Hair care kits and the heater that is used for warming hair care compositions

Technical field

The heater that the present invention relates to a kind of hair care kits and be used for warming hair care compositions.

Background of invention

Adopted multiple hair care product to come hair conditioning.For instance, adopt hair shampoo to remove excessive dirt and sebum with the cleaning hair; Adopt the hair conditioning product to provide all conditioning effects, as wetness sensation, flexibility and Electrostatic Control for hair; Adopt hair fixing product to fix hair style and/or maintenance coiffure; Adopt the hair-dyeing product to change hair color and/or maintenance hair color; And adopt the natural on-off cycles of hair growth product to promote natural on-off cycles of hair growth.

The effect of hair care product is subjected to influence of various factors, and for example the use amount of hair care product, hair care product are coated in the temperature of time length on the hair, hair care product, hair care product are coated in mode on the hair or the like.Therefore, obtain the effect expected and be not easy from hair care product.

Based on top said, still expect to obtain better effect by hair care product, promptly obtain better effect by hair care product, as obtaining superior cleaning by the hair shampoo product, and by the higher hair conditioning effect of hair conditioning product acquisition, as wetness sensation, flexibility and Electrostatic Control.

Can provide whole advantage of the present invention and benefit without any prior art.

Summary of the invention

The present invention relates to a kind of hair care kits (hereinafter referred to as " box A "), it comprises moisture Haircare composition and heat generating agent, and this heat generating agent produces heat by mixing with this moisture Haircare composition, and wherein heat generating agent separates with moisture Haircare composition.

The invention still further relates to hair care kits (hereinafter referred to as " box B "), it comprises:

(i) Haircare composition;

(ii) heat generating agent, this heat generating agent produces heat by reacting with a kind of reactant; And

(iii) reactant;

Wherein Haircare composition, heat generating agent and reactant separate separately.

The invention still further relates to the heater that is used for warming hair care compositions, it comprises heating source.

To those skilled in the art, by reading the disclosure of the specification, of the present invention those will become apparent with further feature, aspect and advantage.

The heater that the present invention relates to a kind of hair care kits and be used for warming hair care compositions.It is believed that the Haircare composition after the heating can produce better effect, promptly can produce better effect.For instance, hair shampoo compositions after the heating can provide superior cleaning, hair setting composition after the heating can provide better typing effect, Wo 2008069000 after the heating is owing to the better permeability of composition provides better conditioning effect, and the natural on-off cycles of hair growth compositions after hair dyeing composition after the heating and the heating also can provide better effect.

Detailed Description Of The Invention

Though this description with particularly point out and clearly claimed claims of the present invention as ending, should believe by following explanation and can understand the present invention better.

Except as otherwise noted, herein all percentage number averages in the weight of total composition.Except as otherwise noted, all ratios are weight ratio.Except as otherwise noted, the percent of all each compositions, ratio and content are all based on the actual content of composition herein, and being not included in can be with solvent, filler or other material of these compositions in the commercially available prod.

Herein, " comprise or comprise " be meant and can add other step and other composition that does not influence final result.This term comprise " by ... form " and " basically by ... composition ".

The list of references of all references all is incorporated herein in full, for your guidance.Any document quote the decision that is not to recognize that it uses as the availability of prior art of the present invention.

Hair care kits

Hair care kits of the present invention is used for by from the heat of heat generating agent and warming hair care compositions.In hair care kits of the present invention, the heating before applying on the hair of this Wo 2008069000.This Haircare composition preferably be heated to about 25 ℃ to about 80 ℃ temperature, more preferably be heated to about 30 ℃ to about 60 ℃.Amount by selecting heat generating agent, heat generating agent, add can control hot aitiogenic reagent and can attemperation as the material of hair care kits packing.

Box A

Hair care kits of the present invention comprises moisture Haircare composition and heat generating agent, and this heat generating agent produces heat by mixing with moisture Haircare composition, and wherein heat generating agent separates with moisture Haircare composition.

Heat generating agent of the present invention can produce heat when mixing with moisture Haircare composition among the box A.Therefore, before should moisture Haircare composition being coated on the hair, this heat generating agent mixes with the compositions among the box A with the heating said composition.

In box A, this moisture Haircare composition and this heat generating agent can be packed in the same container, also this moisture Haircare composition and this heat generating agent can be packed in the different containers, be about to moisture Haircare composition and pack in first container, heat generating agent is packed in second container.

In the time of in moisture Haircare composition and heat generating agent are packed different containers into, for instance, can be by heat generating agent and moisture Haircare composition be discharged by container separately, and in another container or on hand they are being mixed, perhaps discharge heat generating agent and it is added in first container by second container, perhaps by moisture Haircare composition is discharged by first container, and it is joined in second container, thereby heat generating agent is mixed with moisture Haircare composition.

When in the same container that moisture Haircare composition and heat generating agent are packed into, preferably, this container comprises two compartments, and moisture Haircare composition and heat generating agent are packed in the different compartments, be about to this moisture Haircare composition and pack in first compartment, heat generating agent is packed in second compartment.In the container with two compartments, first compartment and second compartment are preferably with separating by broken spacing body.In the container with two compartments, first compartment and second compartment are with being spaced from each other by broken spacing body, and first compartment is arranged to by first compartment or second compartment or second compartment is surrounded by another compartment.

When employing has the container of two compartments, can be by heat generating agent and moisture Haircare composition be discharged by compartment separately, and in another container or mixing on hand, and the moisture Haircare composition of this heat generating agent and this is mixed.When employing has the container of the compartment that two usefulness can broken spacing body separate, for example can broken spacing body and the moisture Haircare composition of this heat generating agent and this is mixed in same container by breaking this.

Box B

Hair care kits B of the present invention comprises:

(i) Haircare composition;

(ii) heat generating agent, it produces heat by reacting with a kind of reactant; And

(iii) reactant;

Wherein Wo 2008069000, heat generating agent and reactant separate separately.

This heat generating agent by with box B in reaction reaction produce heat.Therefore, before being coated to Haircare composition on the hair, for example beginning and the reaction of this reactant, thereby heat said composition by reactant is mixed with heat generating agent among the box B.

In box B, Haircare composition, heat generating agent and reactant can be packed in the identical container.In box B, Haircare composition, heat generating agent and reactant also can be packed in the different containers separately, are about to Haircare composition and pack in first container, and heat generating agent is packed in second container, and reactant is packed in the 3rd container.

In the time of in Haircare composition, heat generating agent and reactant are packed different containers into, for instance, can be by heat generating agent and reactant be discharged by container separately, and in another container, they are mixed, perhaps discharge heat generating agent, and it is added in the 3rd container, perhaps by reactant is emitted by the 3rd container by second container, and it is joined in second container, thereby this heat generating agent is mixed with these reaction means.When in the different container that Haircare composition, heat generating agent and reactant are packed into separately, for example can contact with heat generating agent and the blended container of reactant by container with Haircare composition, Haircare composition is heated.

In the time of in Haircare composition, heat generating agent and reactant are packed identical container into, preferably, this container comprises three compartments, Haircare composition, heat generating agent and reactant are respectively charged in the different compartments, being about to Haircare composition packs in first compartment, with heat generating agent second compartment of packing into, with reactant the 3rd compartment of packing into.In the container with three compartments, second compartment and the 3rd compartment are preferably with separating by broken spacing body.In container with three compartments, second compartment and the 3rd compartment are with being spaced from each other by broken spacing body, second compartment is arranged to by second compartment or the 3rd compartment or the 3rd compartment is enclosed in by another compartment in the container with three compartments, between preferred first compartment and the second and the 3rd compartment with can not be broken but the spacing body that can conduct heat separate.

When employing has the container of three compartments, can be by heat generating agent and reactant be discharged by compartment separately, and in another container, mix and this heat generating agent is mixed with this reactant.When employing has three compartments and when wherein the second and the 3rd compartment is with the container that can broken spacing body separates, for example can be by can breaking by broken spacing body, and this heat generating agent and this reactant are mixed in same container.When employing has the container of three compartments, can contact with heat generating agent and the blended container of reactant by container Haircare composition, thereby with the heating of this Haircare composition, perhaps this Haircare composition can by can not be broken but the spacing body that can conduct heat heat.

Heater

The invention still further relates to a kind of heater that is used for warming hair care compositions.This Haircare composition preferably is heated to about 25 ℃ to about 80 ℃, more preferably is heated to about 30 ℃ to about 60 ℃.By the amount of selecting heat generating agent, heat generating agent, the material that can control hot aitiogenic reagent and pack that adds, can regulate temperature as heater.

Heater of the present invention heats this Haircare composition before being used in Haircare composition being coated on the hair, heats this Haircare composition after also can being used on being coated to hair.

Heater of the present invention can be the suitable container shapes of holding Haircare composition.This container heats this Haircare composition before being used in and being coated to Haircare composition on the hair.Heater of the present invention can also be the suitable shape that covers hair, for example is the medicated cap shape.This medicated cap heats this Haircare composition after being used in and being coated to Haircare composition on the hair.

Heating source

Heater of the present invention comprises heating source.Be applicable to that heater of the present invention comprises the combining of heat generating agent and reactant, heat-storing material, resistive heating system, electromagnetically induced heating system, and mixed form.

Heat generating agent can be used as heating source of the present invention with combining of reactant.Wherein heat generating agent can be by producing heat with reaction reaction, for example can be by heat generating agent and reaction reaction are started with the reaction of reactant.When adopting heat generating agent and reactant as heating source, this heat generating agent separates with reactant.When with heat generating agent and reactant during as heating source, preferably, heating source also comprises two compartments, and this heat generating agent is packed into reactant in the different compartments, the heat generating agent of promptly packing in first compartment, the reactant of packing in second compartment.In the heating source with two compartments, first compartment and second compartment are preferably with separating by broken spacing body.In the heating source with two compartments, preferably with being spaced from each other by broken spacing body, first compartment is arranged to by first compartment or second compartment or second compartment is surrounded by another compartment for first compartment and second compartment.In heating source with compartment that two usefulness can broken spacing body separate, can broken spacing body and this heat generating agent is mixed in same container with this reactant by breaking this.

Can adopt heat-storing material as heating source of the present invention.Be applicable to heat-storing material of the present invention be can storing energy those materials.This heat-storing material can storing energy, for example by in hot water, boil, by microwave heating and pass through electric heating system.For example this heat-storing material comprises silica gel, carboxymethyl cellulose gel, phase-change material, and composition thereof.

Can adopt resistance heating material as heating source of the present invention.For example, resistance heating material comprises nickel filament, pottery, conducting polymer, and composition thereof.

But heating source of the present invention can with can not be broken but layer heat conduction cover.

Heat generating agent

This hair care kits A and B comprise heat generating agent.Be applicable to heat generating agent among the box A be those by be included in box A in moisture Haircare composition mix the reagent that produces heat.Be applicable to heat generating agent among the box B be those by with box B in reactant react and produce the reagent of heat.

Heater of the present invention comprises heat generating agent.Be applicable to that the thermal agent that adds in the heater of the present invention is that those produce the reagent of heat by reacting with reactant, wherein this reactant is included in this heater with this heat generating agent.

For example, be applicable to that heat generating agent in box A and B and the heater comprises mixture, calcium oxide, magnesium oxide, magnesium sulfate, calcium chloride, magnesium, magnesium chloride, ferrous chloride, ferric chloride, zeolite, the polyhydric alcohol of ferrum and activated carbon and muriatic mixture, ferrum and potassium persulphate, and composition thereof.These reagent can be by producing heat with the water reaction.Be suitable for the chloride that uses with ferrum and activated carbon and for example comprise sodium chloride, potassium chloride, copper chloride, iron chloride, ferrous chloride, and composition thereof.The reagent that comprises ferrum and/or magnesium preferably mixes with water in the presence of oxygen.Be applicable to that polyhydric alcohol of the present invention for example comprises 1,2-propylene glycol or propylene glycol, 1, ammediol, hexanediol, glycerol, diethylene glycol, dipropylene glycol, 1,2-butanediol, 1, the 4-butanediol, and composition thereof.Be applicable to that preferably polyhydric alcohol of the present invention is a glycerol.

Heating agent by solid material is formed as zeolite and magnesium sulfate, can be dispersed in the inert carrier, thus help with box A in Wo 2008069000 and mix with reactant in box B and the heater, and prevent undesirable reaction before use.This inert carrier can be a liquid, can be solid also, as powder.Be applicable to that inert carrier of the present invention comprises as Polyethylene Glycol powder, liquid macrogol, polypropylene glycol powder, liquid polypropylene glycol, and composition thereof.Above-mentioned polyhydric alcohol can also be used as inert carrier.

This inert carrier can contain viscosity modifier.Be applicable to that viscosity modifier of the present invention comprises for example ethene polymers, the crosslinked acrylic acid polymer that is called Carbomer as the CTFA name, carboxylic acid/carboxylate copolymer, acrylic acid/the alkyl acrylate copolymer that is called Acrylates/C10-30 Alkyl Acrylate Crosspolymer as the CTFA name, the cellulosic polymer of cellulose derivative and modification, polyvinylpyrrolidone, polyvinyl alcohol, guar gum, other natural gum, starch-based polymer, the alginic acid based polyalcohol, acrylate polymer, molecular weight surpasses about 1000 poly alkylene glycol, inorganic water-soluble material such as bentonite, Magnesiumaluminumsilicate, laponite (clay particle), Strese Hofmann's hectorite. and anhydrous silicic acid, and composition thereof.

Be applicable to that the heat generating agent in box B and the heater also comprises as hydrogen peroxide, supercool liquid, gasoline, and composition thereof.Hydrogen peroxide, supercool liquid and gasoline produce heat by the differential responses with the differential responses agent.Hydrogen peroxide can be by producing heat with the ascorbic acid reduction.Supercool liquid can produce heat by become solid phase transformation by supercool liquid under motivator.Be applicable to that supercool liquid of the present invention comprises for example sodium acetate salt, as the aqueous solution of sodium acetate, sodium acetate monohydrate, sodium acetate dihydrate, sodium acetate trihydrate and these second sodium salt classes, and composition thereof.Preferred supercool liquid is sodium acetate trihydrate.

Gasoline also can be as the heat generating agent in box B and the heater.Gasoline produces heat by smoulder in the presence of catalyst.

Preferred heat generating agent is calcium oxide, magnesium oxide, magnesium, magnesium sulfate, zeolite among the box A, and composition thereof.

Preferred heat generating agent is calcium oxide, magnesium oxide, magnesium, magnesium sulfate, zeolite, supercool liquid such as sodium acetate trihydrate among the box B, and composition thereof.

Preferred heat generating agent is calcium oxide, magnesium oxide, magnesium, magnesium sulfate, zeolite, supercool liquid such as sodium acetate trihydrate in the heater, and composition thereof.

Reactant

Hair care kits B of the present invention comprises the reactant that can be used for the heat generating agent reaction.When this heat generating agent chosen from Fe, activated carbon and muriatic mixture, the mixture of ferrum and potassium peroxydisulfate, calcium oxide, magnesium oxide, magnesium sulfate, calcium chloride, magnesium, magnesium chloride, dichloride are ferrous, ferric chloride, zeolite, polyhydric alcohol, and composition thereof, be applicable to that reaction means of the present invention are water, aqueous solution or Aquo-composition, wherein heat generating agent starts by this heat generating agent is mixed with this reactant with the reaction of reactant.When adopting hydrogen peroxide as heat generating agent, be applicable to that reactant of the present invention is an ascorbic acid, wherein this heat generating agent starts by this heat generating agent is mixed with this reactant with the reaction of reaction means.When adopting supercool liquid as heat generating agent, be applicable to that reactant of the present invention is the motivator that excitation can be provided to supercool liquid, thus the phase transformation reaction of beginning supercool liquid.Be applicable to motivator of the present invention for example comprise can by mix with supercool liquid form the excitation motivator.These motivators for example comprise the material of the crystal form that is used for supercool liquid, and wherein the reaction of supercool liquid can be started by motivator is mixed with this supercool liquid.Being applicable to that motivator of the present invention also comprises for example provides physical stimulus, as the motivator of pressure and vibration.These motivators for example comprise provides physical stimulus, and as the switch of pressure and vibration, wherein the reaction of supercool liquid is for example started by connecting switch.When adopting gasoline as heat generating agent, be applicable to reactant of the present invention be catalyst, as platinum, wherein heat generating agent starts by this heat generating agent is mixed with this reactant with the reaction of reactant.

The reaction controlling agent

Hair care kits A and B and heater also comprise the reaction controlling agent, and they can be controlled the delivery in hot weather of heat generating agent and give birth to reaction.The reaction controlling agent can slow down reaction or add fast response.This reaction controlling agent can also be controlled the temperature of this Haircare composition heating.

When heat generating agent adopts as calcium oxide, magnesium, magnesium oxide, and composition thereof the time, preferably, adopt and react the reaction that controlling agent promotes this heat generating agent.Can adopt acid as the reaction controlling agent, promoting this heat generating agent such as calcium oxide, magnesium, magnesium oxide, and composition thereof reaction.Be applicable to that acid of the present invention comprises for example citric acid, sodium dihydrogen phosphate, potassium dihydrogen phosphate, l-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, l-glutamic acid hydrochloride, tartaric acid, and composition thereof; Preferably l-glutamic acid, lactic acid, hydrochloric acid, and composition thereof.In these compositions, citric acid is the preferred composition that uses.This sour addition makes this heat generating agent and the mol ratio of acid be about 1: 0.1 to about 1: 10, be preferably 1: 0.5 to about 1: 5.This acid can become to separate with other, as with the box neutralising arrangement in Haircare composition, heat generating agent and reactant separate.Acid can be incorporated in other composition such as Haircare composition, heat generating agent and reactant in box and the device.

When heat generating agent adopts as calcium oxide, magnesium, magnesium oxide, and composition thereof the time, preferably, adopt and react the reaction that controlling agent slows down this heat generating agent.Can adopt water absorbent polymer as the reaction controlling agent, slowing down heat generating agent such as calcium oxide, magnesium, magnesium oxide, and composition thereof reaction.Be applicable to that water absorbent polymer of the present invention comprises for example ethene polymers, the crosslinked acrylic acid polymer that is called Carbomer as the CTFA name, carboxylic acid/carboxylate copolymer, acrylic acid/the alkyl acrylate copolymer that is called Acrylates/C10-30 AlkylAcrylate Crosspolymer as the CTFA name, the cellulosic polymer of cellulose derivative and modification, as hydroxyethyl-cellulose, polyvinylpyrrolidone, polyvinyl alcohol, guar gum, other natural gum, starch-based polymer, the alginic acid based polyalcohol, acrylate polymer, molecular weight surpasses about 1000 poly alkylene glycol, and composition thereof.In above-mentioned water absorbent polymer, hydroxyethyl-cellulose is preferred among the present invention.This water absorbent polymer can with other composition in box and the device, as Haircare composition, heat generating agent and reactant separately.In other composition such as Haircare composition, heat generating agent and reactant during this water absorbent polymer can be incorporated into box and install.

Heat-storing material

Hair care kits A and B and heater can also comprise the heat-storing material that can store heat.For example this heat-storing material comprises silica gel, carboxymethyl cellulose gel, phase-change material, and composition thereof.Be applicable to that phase-change material of the present invention is that fusing point is about 25 ℃ to those about 80 ℃ compositions.Be applicable to that phase-change material of the present invention comprises fatty compound for example aliphatic alcohol and fatty acid; The mixture of hydro carbons and hydrocarbon and expanded polyolefin; And composition thereof.Be applicable to that fatty compound of the present invention is disclosed under following " hard fat chemical compound " title.

In box of the present invention, can adopt heat-storing material to prolong heating.In heater of the present invention, can use this heat-storing material separately, also can with other composition, unite use as the combination of resistive heating system and heat generating agent and reactant.

This heat-storing material can separate with other composition such as Haircare composition, heat generating agent and the reactant in box and the device.For instance, in box A, heat-storing material can be positioned at the place near Haircare composition and heat generating agent.For example, in box B, heat-storing material can be in Haircare composition and heat generating agent and position between reactant combines.For example, heat-storing material can also be positioned at other heating source around.

This heat-storing material can be incorporated in other composition such as Haircare composition, heat generating agent and reactant in box and the device.For instance, in box A, heat-storing material can be incorporated in Haircare composition or the heat generating agent.For instance, in box B, heat-storing material can be incorporated in Haircare composition or heat generating agent or the reactant.For instance, in heater, heat-storing material can be incorporated in heat generating agent or the reactant.

Haircare composition

Hair care kits of the present invention and heater can be used for warming hair care compositions, are preferred for heating Wo 2008069000.Can use multiple Haircare composition in the present invention.In box A, can use moisture Haircare composition.In box B and heater, can use moisture Haircare composition and non-water Haircare composition.Be applicable to of the present invention moisture/non-water Haircare composition comprises that moisture/non-head hair-care shampoo compositions, moisture/non-head send out Hairstyling composition, moisture/non-head and send out that care composition, moisture/non-head are sent out colouring compositions, long compositions takes place moisture/non-head, and composition thereof.

It is believed that, Haircare composition after the heating can produce the effect of reinforcement, for example, hair shampoo compositions after the heating can provide superior cleaning, hair setting composition after the heating can provide better typing effect, Wo 2008069000 after the heating is owing to the better permeability of composition provides better conditioning effect, and the natural on-off cycles of hair growth compositions after hair dyeing composition after the heating and the heating also can provide better effect.

Haircare composition of the present invention can be a rinse-off products, also can be the leave product, and is transparent or opaque.And can be mixed with the multiple product form, including, but not limited to cream, gel, emulsion, mousse and spray.

Wo 2008069000

Heater of the present invention is preferred for heating Wo 2008069000.Hair care kits of the present invention preferably includes Wo 2008069000.In box A, can use moisture Wo 2008069000.In box B, can use moisture Wo 2008069000 and non-head to send out care composition.Be applicable to that Wo 2008069000 of the present invention comprises the compositions (hereinafter being called " compositions A ") that contains following ingredients by weight:

(a) about 0.1% to about 15% hard fat chemical compound;

(b) about 0.1% to about 10% has the amidoamines of following general formula:

R ¹CONH(CH ₂) _mN(R ²) ₂

R in the formula ¹Be C ₁₁-C ₂₄The residue of fatty acid, R ²Be C ₁-C ₄Alkyl, m are 1 to 4 integer;

(c) acid is selected from l-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, l-glutamic acid hydrochloride, tartaric acid, and composition thereof, its amount makes the amidoamines and the mol ratio of acid be about 1: 0.3 to about 1: 1; And

(d) aqueous carrier,

And the compositions (hereinafter being called " compositions B ") that contains following ingredients by weight:

(a) about 0.1% to about 15% hard fat chemical compound, its fusing point is 25 ℃ or higher;

(b) about 0.1% to about 10% cation opsonizing agent;

(c) about 0.1% to about 10% low melting point oil, its fusing point is lower than 25 ℃; With

(d) aqueous carrier.

The hard fat chemical compound

Wo 2008069000 A of the present invention and B comprise the hard fat chemical compound.This hard fat chemical compound and cationic surfactant be amidoamines for example, and aqueous carrier provides the gel network that is suitable for providing various conditioning effects, smooth feeling of sending out as wetting and dried flexibility, wetness sensation and the control of sending out of dispersing together.

Be applicable to that its fusing point of hard fat chemical compound of the present invention is 25 ℃ or higher, and be selected from by aliphatic alcohol, fatty acid, fatty alcohol derivative, derivative of fatty acid, and composition thereof the group formed.This area the professional should be appreciated that, disclosed chemical compound may belong in the more than one classification in some cases in this joint of description, and for example some fatty alcohol derivative can also classify as derivative of fatty acid.But specified class and being not intended to limits particular compound, but for the ease of clssification and designation.In addition, it will be understood by those skilled in the art that some chemical compounds with certain required carbon number may have and are lower than 25 ℃ fusing point according to the number of two keys and the length and the position of position and side chain.This low-melting compound is not included in this joint.The limiting examples of high melting compound is found in International Cosmetic Ingredient Dictionary, Fifth Edition, 1993 and CTFA Cosmetic Ingredient Handbook, Second Edition, 1992.

The content of hard fat chemical compound in compositions A and B be about 0.1% to about 15%, be preferably about 0.25% to about 13% weight.More preferably, the content of this hard fat chemical compound in compositions A is about 1% to about 10% weight, and content is about 0.25% to about 5% weight in compositions B.

Be applicable to that aliphatic alcohol of the present invention is to have about 14 to about 30 carbon atoms, preferred about 16 aliphatic alcohol to about 22 carbon atoms.These aliphatic alcohol are saturated, and can be straight or branched alcohol.Nonlimiting examples of fatty alcohols comprises spermol, stearyl alcohol, docosanol and their mixture.

Be applicable to fatty acid of the present invention be have about 10 to about 30 carbon atoms, preferred about 12 to about 22 carbon atoms, 16 fatty acids more preferably from about to about 22 carbon atoms.These fatty acids are saturated, and can be straight or branched acid.Also comprise the binary acid, ternary acid and other polyprotic acid that satisfy requirement of the present invention.The present invention also comprises the salt of these fatty acids.Nonlimiting examples of fatty acids comprises lauric acid, Palmic acid, behenic acid, decanedioic acid and their mixture.

Be applicable to that but fatty alcohol derivative of the present invention and derivative of fatty acid comprise alkyl ether, alkoxy fatty alcohols, alkyl ether, the aliphatic alcohol ester of alkoxy fatty alcohols, the fatty acid ester with esterified hydroxy groups chemical compound, the fatty acid of hydroxyl replacement and their mixture of aliphatic alcohol.The limiting examples of fatty alcohol derivative and derivative of fatty acid comprises following material, for example the methyl stearyl ether; The ceteth series compound, to ceteth-45, they are glycol ethers of spermol as ceteth-1, wherein numeric character is represented the quantity of existing ethylene glycol part; Stearyl ether (steareth) series compound, to 10, it is the glycol ether of stearic ether alcohol as stearyl ether-1, wherein numeric character is represented the quantity of existing ethylene glycol part; Cetearyl alcohol ether (ceteareth)-1 is to cetearyl alcohol ether-10, and they are glycol ethers of cetearyl alcohol (promptly containing mainly is the fatty alcohol mixture of spermol and stearyl alcohol), and wherein numeric character is represented the quantity of existing ethylene glycol part; The C of above-mentioned ceteth, stearyl ether and cetearyl alcohol ether compound ₁-C ₃₀Alkyl ether; The polyethylene glycol oxide ether of docosanol; Ethyl stearte, the stearic acid cetyl, hexadecane (acid) cetyl ester, the stearic acid stearyl ester, myristic acid tetradecane ester, the polyoxyethylene cetyl ethers stearate, polyethylene glycol oxide stearyl ether stearate, polyethylene glycol oxide lauryl ether stearate, the monostearate glycol ester, monostearate polyethylene glycol oxide ester, distearyl acid polyethylene glycol oxide ester, the monostearate propylene glycol ester, the distearyl acid propylene glycol ester, distearyl acid trihydroxymethylpropanyl ester, the sorbitan stearate, the stearic acid polyglycerin ester, glyceryl monostearate, distearin, glyceryl tristearate, and their mixture.

The hard fat chemical compound of preferably highly purified unification compound.The unification compound that is selected from the pure fat alcohol of pure spermol, stearyl alcohol and tadenan is highly preferred." pure " herein is meant that the purity of chemical compound is at least about 90%, preferably at least about 95%.When consumer washed the present composition off, these high-purity unification compounds can provide good eccysis from hair.

The hard fat chemical compound of the present invention that is applicable to that can buy from the market comprises: derive from Shin-Nihon Rika (Osaka with trade name KONOL series, Japan) and with trade name NAA series derive from NOF (Tokyo, spermol Japan), stearyl alcohol and tadenan; Derive from WAKO (Osaka with trade name 1-DOCOSANOL, Japan) pure tadenan, derive from Akzo (Chicago with trade name NEO-FAT, Illinois, USA), with trade name HYSTRENE derive from Witco Corp. (Dublin, Ohio, USA), and the DERMA (Genova, various fatty acids Italy) that obtain by Vevy.

Amidoamines

Wo 2008069000 of the present invention comprises the amidoamines with following general formula:

R ¹CONH(CH ₂) _mN(R ²) ₂

R in the formula ¹Be C ₁₁-C ₂₄The residue of fatty acid, R ²Be C ₁-C ₄Alkyl, m are 1 to 4 integer.

This amidoamines can be about 0.1% to about 10%, more preferably about 0.25% by weight to about 8%, most preferably is about 0.5% to about 3% content and is included among the compositions A.

Amidoamines also is included among the compositions B as cation opsonizing agent, and its content is about 0.1% to about 10%, more preferably about 0.25% to about 8% by weight, most preferably is about 0.5% to about 3%.

Be applicable to that preferred amidoamines of the present invention comprises the amino amine propyl group of stearoyl dimethylamine, the amino amine diethylamine of stearoyl, the amino amine second of stearoyl dimethylamine, Petiolus Trachycarpi amidoamines propyl group dimethylamine, Petiolus Trachycarpi amidoamines propyl group diethylamine, Petiolus Trachycarpi amidoamines ethyl diethylamine, Petiolus Trachycarpi amidoamines ethyl dimethylamine, the amino amine propyl group of two lauroyls dimethylamine, the amino amine propyl group of two lauroyls diethylamine, the amino amine ethyl of two lauroyls diethylamine, the amino amine ethyl of two lauroyls dimethylamine, 20 amidoamines propyl group dimethylamine, 20 amidoamines propyl group diethylamine, 20 amidoamines ethyl diethylamine, 20 amidoamines ethyl dimethylamine, and composition thereof; The more preferably amino amine propyl group of stearoyl dimethylamine, the amino amine propyl group of stearoyl diethylamine, and composition thereof.

The amidoamines of the present invention that is applicable to that can buy from the market comprises: the commodity that obtain by Inolex by name SAPDMA's and amino third dimethylamine of commodity Amidoamine MPS stearoyl by name that obtains by Nikko.

Acid

Wo 2008069000 A of the present invention comprises and is selected from following acid: l-glutamic acid, lactic acid, hydrochloric acid, maleic acid, succinic acid, acetic acid, fumaric acid, l-glutamic acid hydrochloride, tartaric acid, and composition thereof; Preferably l-glutamic acid, lactic acid, hydrochloric acid, and composition thereof.This sour content makes that the amidoamines and the mol ratio of acid are about 1: 0.3 to about 1: 1, is preferably about 1: 0.5 to about 1: 0.9.

Also comprise this acid in compositions B, its content makes that the amidoamines and the mol ratio of acid are about 1: 0.3 to about 1: 1, is preferably about 1: 0.5 to about 1: 0.9.

The amidoamines of the present invention that is applicable to that can buy from the market comprises: l-glutamic acid: l-glutamic acid (cosmetics-stage) can obtain from Ajinomoto.

Granule

Compositions A of the present invention and B comprise granule.The content of this granule in compositions A and B is about 0.01% to about 10%, is preferably about 0.1% to about 5%, more preferably about 0.1% to about 2%.Be applicable to that particulate mean diameter of the present invention is preferably about 25 μ m to about 1 500 μ m, more preferably about 50 μ m are to about 1000 μ m, even more preferably about 50 μ m are to about 500 μ m.Can adopt organic and inorganic particle.Be applicable to that preferably granule of the present invention comprises organic granular, as cellulose grain and inorganic particle such as Muscovitum, silicon dioxide, mud, clay, zeolite, and composition thereof.Silicon dioxide more preferably.Be applicable to that preferably but granule of the present invention is those granules with disruptiveness, like this, when these granules that comprised in the compositions on hand and/or can be broken when scattering on the hair.

The granule of the present invention that is applicable to that can buy from the market comprises: the silicon dioxide of commodity Neosil series by name, and as the Neosil CBT 60 that obtains by Crosfield.

Aqueous carrier

Compositions A of the present invention and B comprise aqueous carrier.According to selecting the content and the kind of carrier with required other characteristic of the compatibility of other component and product.

Be applicable to that carrier of the present invention comprises the aqueous solution of water and low-grade alkane alcohol and polyhydric alcohol.Be applicable to that low-grade alkane alcohol of the present invention is the monohydric alcohol with 1 to 6 carbon atom, more preferably ethanol and isopropyl alcohol.Be applicable to that polyhydric alcohol of the present invention comprises propylene glycol, hexanediol, glycerol and propylene glycol.

Preferably, this aqueous carrier is water basically.The preferred deionized water that uses.The characteristic required according to product also can be used the water of the natural origin that contains inorganic cation.Compositions of the present invention contains about 20% usually to about 95%, and preferred about 30% to about 92%, more preferably from about 50% to about 90% water.

Cation opsonizing agent

Wo 2008069000 B of the present invention comprises cation opsonizing agent.This cation opsonizing agent provides the gel network that is suitable for providing various conditioning effects with the hard fat chemical compound, as wet smooth feeling of sending out and dried flexibility, wetness sensation and the control of sending out of dispersing.

The content of this cation opsonizing agent in compositions for being 0.1% to about 10%, is preferably about 0.25% to about 8%, more preferably about 0.5% to about 3% by weight.

This cation opsonizing agent is also contained among the compositions A, and its content is 0.1% to about 10%, more preferably about 0.25% to about 8% by weight, most preferably is about 0.5% to about 3%.

This cation opsonizing agent is selected from cationic surfactant, cationic polymer, and composition thereof.

Cationic surfactant

Be applicable to that cationic surfactant of the present invention is that this area professional is known, and the content in said composition is preferably 0.1% to about 10%, more preferably about 0.25% by weight to about 8%, most preferably is about 0.5 to about 3%.

In this cationic surfactant, be applicable to that of the present invention is those cationic surfactants corresponding to following general formula (I):

R in the formula ¹, R ², R ³And R ⁴In at least one is selected from the aliphatic group with 8 to 30 carbon atoms, perhaps have the aromatics, alkoxyl, polyoxyalkylene, alkyl amido, hydroxyalkyl, aryl or the alkaryl that are up to about 22 carbon atoms, remaining R ¹, R ², R ³And R ⁴Be independently selected from and have 1 aliphatic group, perhaps have the aromatics, alkoxyl, polyoxyalkylene, alkyl amido amido, hydroxyalkyl, aryl or the alkaryl that are up to 22 carbon atoms to about 22 carbon atoms; And X is into salt anionic, as is selected from halogen (as chlorine, bromine), acetate, citrate, lactate, ethanol acid group, phosphate radical, nitrate anion, sulfonate radical, sulfate radical, alkyl sulfate and alkyl azochlorosulfonate.Except carbon atom and hydrogen atom, aliphatic group can also contain ehter bond and such as other group of amino.For example about 12 carbon atoms of long-chain aliphatic group or more high-grade those can be saturated or undersaturated.Preferably work as R ¹, R ², R ³And R ⁴Be independently selected from C ₁To about C ₂₂Alkyl.The limiting examples that can be used for cationic surfactant of the present invention comprises the following material of CTFA name: quaternary ammonium-8, quaternary ammonium-14, quaternary ammonium-18, quaternary ammonium-18 dimethyl sulfate, quaternary ammonium-24 and their mixture.

In the middle of general formula (I) cationic surfactant, preferred situation is to comprise the surfactant that at least one has the alkyl of at least 16 carbon atoms in molecule.The limiting examples of described preferred cationic surfactant comprises: INCROQUAT TMC-80 ECONOL TM22; for example obtain by Croda with trade name INCROQUAT TMC-80; and obtain by SanyoKasei with trade name ECONOL TM22; hexadecyltrimethylammonium chloride; for example obtain by NikkoChemicals with trade name CA-2350; the hydrogenated tallow alkyl trimethyl ammonium chloride; dialkyl group (14-18) alkyl dimethyl ammonium chloride; two tallow alkyl alkyl dimethyl ammonium chlorides; dihydro tallow alkyl alkyl dimethyl ammonium chloride; distearyl acyl group alkyl dimethyl ammonium chloride; the dicetyl alkyl dimethyl ammonium chloride; two (docosyl/arachidonic acyl group) alkyl dimethyl ammonium chloride; two docosyl alkyl dimethyl ammonium chlorides; stearyl dimethyl benzene ammonio methacrylate; stearyl propylene glycol phosphate ester alkyl dimethyl ammonium chloride; stearyl acylamino-propyl-dimethyl benzyl ammonium chloride; stearyl acylamino-propyl-dimethyl (tetradecyl acetate) ammonium chloride, and N-(stearyl cholamine base (colamino) formoxyl methyl) pyridine chlorine.

The cationic surfactant that preferably also has hydrophilic replacement, wherein at least one substituent group contains one or more as substituent group or as aromatic series, ether, ester, amide or amino part, the wherein R of linking group in the group chain ¹-R ⁴In the group at least one contains one or more hydrophilic segments, and they are selected from alkoxyl (C preferably ₁-C ₃Alkoxyl), polyoxyalkylene (C preferably ₁-C ₃Polyoxyalkylene), alkyl amido, hydroxyalkyl, Arrcostab and their combination.Preferably, the cationic conditioning surfactant of this hydrophilic replacement contains 2 to about 10 nonionic hydrophilic segments that are positioned at above-mentioned scope.The cationic surfactant of this hydrophilic replacement preferably includes those surfactants with following general formula (II)-(VIII):

N is 8 to about 28 in the formula, and x+y is 2 to about 40, Z ¹Be short-chain alkyl, be preferably C ₁-C ₃Alkyl, more preferably methyl, perhaps (CH ₂CH ₂O) _zH, x+y+z is up to 60 in the formula, and X is aforesaid one-tenth salt anionic;

M is 1 to 5 in the formula, R ⁵, R ⁶And R ⁷In one or more be C independently ₁-C ₃₀Alkyl, remaining is CH ₂CH ₂OH, R ⁸, R ⁹And R ¹⁰In one or two be C independently ₁-C ₃₀Alkyl, and remaining is CH ₂CH ₂OH, and X is aforesaid one-tenth salt anionic;

In the formula, for general formula (IV) and (V), Z2 is alkyl independently, is preferably C ₁-C ₃Alkyl, methyl more preferably, and Z ³Be the short chain hydroxyalkyl, preferred methylol or hydroxyethyl, p and q are 2 to 4 integer (containing 2 and 4) independently, are preferably 2 to 3, more preferably 2, R ¹¹And R ¹²For replacing or unsubstituted alkyl, be preferably C independently ₁₂-C ₂₀Alkyl or alkenyl, and X is aforesaid one-tenth salt anionic;

R in the formula ¹³Be alkyl, be preferably C ₁-C ₃Alkyl, methyl more preferably, Z ⁴And Z ⁵Be short-chain hydrocarbon group, more preferably C independently ₂-C ₄Alkyl or alkenyl, ethyl more preferably, a are 2 to about 40, be preferably about 7 to about 30, and X are aforesaid one-tenth salt anionics;

R in the formula ⁸⁴And R ⁸⁵Be C independently ₁-C ₃Alkyl is preferably methyl; Z ⁶Be C ₁₂-C ₂₂Alkyl, alkyl carboxyl or alkyl amido, and A is protein, is preferably collagen, keratin, milk proem, fibroin, soybean protein, wheat protein or its hydrolysed form; And X is aforesaid one-tenth salt anionic;

B is 2 or 3 in the formula, R ¹⁶And R ¹⁷Be C independently ₁-C ₃Alkyl is preferably methyl, and X is aforesaid one-tenth salt anionic.The limiting examples that can be used for the cationic surfactant of hydrophilic replacement of the present invention comprises the material with following CTFA title: quaternary ammonium-16, quaternary ammonium-26, quaternary ammonium-27, quaternary ammonium-30, quaternary ammonium-33, quaternary ammonium-43, quaternary ammonium-52, quaternary ammonium-53, quaternary ammonium-56, quaternary ammonium-60, quaternary ammonium-61, quaternary ammonium-62, quaternary ammonium-70, quaternary ammonium-71, quaternary ammonium-72, quaternary ammonium-75, the collagen of quaternary ammonium-76 hydrolysis, quaternary ammonium-77, quaternary ammonium-78, the collagen of quaternary ammonium-79 hydrolysis, the keratin of quaternary ammonium-79 hydrolysis, the lactoprotein of quaternary ammonium-79 hydrolysis, the fibroin of quaternary ammonium-79 hydrolysis, the wheat protein of the soybean protein of quaternary ammonium-79 hydrolysis and quaternary ammonium-79 hydrolysis, quaternary ammonium-80, quaternary ammonium-81, quaternary ammonium-82, quaternary ammonium-83, quaternary ammonium-84 and their mixture.

The cationic surfactant of highly preferred hydrophilic replacement comprises dialkyl group acylamino-ethyl-hydroxyethyl ammonium salt, dialkyl group acylamino-ethyl di-ammonium salts, dialkyl group ethyl-hydroxyethyl ammonium salt, two alkanoyl second di-ammonium salts, and composition thereof; For example: can buy from the market with following trade name: VARISOFT 110, VARIQUAT K1215 and 638 (providing) by Witco Chemical, MACKPRO KLP, MACKPRO WLW, MACKPRO MLP, MACKPRO NSP, MACKPRO NLW, MACKPRO WWP, MACKPRO NLP, MACKPRO SLP (providing) by McIntyre, ETHOQUAD 18/25, ETHOQUAD O/12PG, ETHOQUAD C/25, ETHOQUADS/25 and ETHODUOQUAD (providing) by Akzo, DEHYQUAT SP (providing) and ATLAS G265 (providing) by ICI Americas by Henkel.

The primary, the salt of the second month in a season and uncle's fatty amine also is suitable cationic surfactants.The alkyl of this class amine preferably has about 12 to about 22 carbon atoms, and can be substituted or not replacement.The acylamino-amine salt of particularly suitable is selected from front disclosed material in the title " amidoamines " and " acid ".Preferred situation is that the acylamino-amine salt is used as cation opsonizing agent in compositions B.

Cationic polymer

Describe below and be applicable to cationic polymer of the present invention.Term " polymer " used herein " should both comprise the material that produces by a kind of monomer polymerization, also comprise material (being copolymer) that produces by two kinds of monomer polymerizations or the material that produces by multiple monomer polymerization.

Cationic polymer is preferably water-soluble cationic polymer.Term " water-soluble cationic polymer " be meant in water, have enough dissolubility, being to form naked eyes under 0.1% aqueous solution (distilled water or the equivalent) condition to look it is the polymer of settled solution basically 25 ℃ and concentration.Preferred polymer should fully dissolve, and forms clear solutions basically, and concentration is 0.5%, and more preferably 1.0%.

Cationic polymer among the present invention has at least about 5,000 usually, is typically at least about 10,000, and is less than about 10,000,000 weight average molecular weight.Preferably, its molecular weight is about 100,000 to about 2,000,000.This cationic polymer has the cationic nitrogenous part usually, as quaternary ammonium or cation amino part and combination thereof.

This cationic charge density preferably is at least about 0.1meq/ gram, more preferably is at least about 1.5meq/ gram, more more preferably is at least about 1.1meq/ gram, most preferably is at least about 1.2meq/ gram.The cationic charge density of this cationic polymer can be measured according to the Kieldahl method.It will be appreciated by those skilled in the art that the charge density that contains amino polymer will become with pH and amino isoelectric point, IP.Charge density should be in the above-mentioned pH limited field that will use.

Any anionic counter-ion can be used for this cationic polymer, as long as it can satisfy the water solubility standard.Suitable counter ion counterionsl gegenions comprise halogen ion (for example CI, Br, I or F, preferably CI, Br or I), sulfate radical and methylsulfate.Should not exclusive for example, therefore can also use other counter ion counterionsl gegenions.

The cation nitrogen moiety is present on a part of monomeric unit of cationic hair conditioning polymer as substituent group usually.Therefore, this cationic polymer can comprise the copolymer, terpolymer of monomeric unit that quaternary ammonium or cationic amine replace and other non-cationic unit (being referred to herein as the spacer monomers unit) etc.These polymer are known in the art, and at CTFA Cosmetic IngredientDictionary, the third edition, editor Estrin, Crosley and Haynes, (The Cosmetic, Toiletry, and Fragrance Association, Inc., Washington, D.C., 1982) in can find its multiple variant.

Suitable cationic polymers comprises the vinyl monomer that for example has cationic amine or quaternary ammonium functional group and the copolymer of water solublity spacer monomers, and described water solublity spacer monomers is for example acrylamide, Methacrylamide, alkyl and dialkyl group acrylamide, alkyl and dialkyl methyl acrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone and vinyl pyrrolidone.The monomer that this alkyl and dialkyl group replace preferably has C ₁-C ₇Alkyl, more preferably C ₁-C ₃Alkyl.Other suitable interval monomer comprises vinyl esters, vinyl alcohol (being made by the polyvinyl acetate hydrolysis), maleic anhydride, propylene glycol and ethylene glycol.

According to the concrete kind and the pH value of compositions, cationic amine can be primary, the second month in a season or tertiary amine.Usually, preferred secondary amine and tertiary amine, especially preferred is tertiary amine.

The vinyl monomer that amine replaces can then randomly can change into ammonium by quaterisation with the form polymerization of amine.Amine also can be quaternized similarly, forms polymer afterwards.For instance, the tertiary amine degree of functionality can react and quaternized by the salt with general formula R ' X, and R ' is a short-chain alkyl in the formula, is preferably C ₁-C ₇Alkyl, more preferably C ₁-C ₃Alkyl, and X is anion, and it and quaternised ammonium form water-soluble salt.

Suitable cation amino and quaternary ammonium monomer comprise for example by propenoic acid dialkyl aminoalkyl ester, the methacrylate dialkyl aminoalkyl ester, acrylic acid one alkylaminoalkyl, methacrylate one alkylaminoalkyl, trialkyl isobutene. acyl-oxygen base alkylammonium salt, trialkyl acryloxyalkyl ammonium salt, the vinyl compound that the diallyl quaternary ammonium salt replaces, with have the ring-type cation and contain for example pyridine of azo-cycle, the vinyl quaternary ammonium monomer of imidazoles and quaternized ketopyrrolidine, for example alkyl vinyl imidazoles, alkylvinylpyridines, alkyl vinyl ketopyrrolidine salt.These monomeric moieties are preferably low alkyl group, as C ₁-C ₃Alkyl, more preferably C ₁And C ₂Alkyl.Be applicable to that the vinyl monomer that amine of the present invention replaces comprises propenoic acid dialkyl ammonia alkane ester, methacrylate dialkyl amino Arrcostab, dialkyl amino alkyl acrylamide and dialkyl amino alkyl MAAm, wherein this alkyl group is preferred for C ₁-C ₇Alkyl, more preferably C ₁-C ₃Alkyl.

Cationic polymers hereof can comprise the mixture by the monomeric unit of the monomer of amine and/or quaternary ammonium-substituted and/or compatible spacer monomer derived.

Suitable cationic hair conditioning polymer for example comprises: the copolymer of l-vinyl-2-pyrrolidone and 1-vinyl-3-methylimidazole salt (for example hydrochlorate) is (according to Cosmetic, Toiletry, andFragrance Association, " CTFA ", in industry, be called Onamer M 6), for example with trade name LUVIQUAT (for example LUVIQUAT FC 370) available from BASF Wyandotte Corp. (Parsippany, NJ, USA); The copolymer of l-vinyl-2-pyrrolidone and methacrylate dimethylamino ethyl ester (being referred to as Polyquaternium-11 by CTFA) in this area, for example with trade name GAFQUAT (as GAFQUAT 755N) by Gaf Corporation (Wayne, NJ, USA) those raw materials of Huo Deing; The polymer that contains cation diallyl quaternary ammonium comprises for example copolymer ((CTFA) is referred to as Polyquaternium 6 and Polyquaternium 7 in this area) of dimethyl diallyl ammonium chloride homopolymer and acrylamide and dimethyl diallyl ammonium chloride; And, having 3 inorganic acid salts described in No. 256 to the amino alkane ester of the homopolymer of the unsaturated carboxylic acid of about 5 carbon atoms and copolymer as United States Patent (USP) the 4th, 009, the document is incorporated herein by reference.

Other cationic polymer that is suitable for comprises polysaccharide polymer, for example cationic cellulose derivative and cationic starch derivative.

Be applicable to that cationic polysaccharide polymer of the present invention comprises the polymer of following formula:

In the formula: A is the anhydroglucose residue, for example starch or cellulose anhydroglucose residue, and R is alkylidene alkylidene oxide, polyoxyalkylene or hydroxyl alkylidene or its combination, R ¹, R ²And R ³Be alkyl, aryl, alkaryl, aralkyl, alkoxyalkyl or alkoxy aryl independently, each group contains and is up to 18 carbon atoms, and the total number of carbon atoms in each cationic moiety (is R ¹, R ²And R ³In the total number of carbon atoms) be preferably about 20 or still less, and X is as above said anionic counter-ion.

Cationic cellulose can (Edison, NJ USA), be their Polymer JR available from Amerchol Corp. ^And LR ^Series polymer is the epoxide reaction that replaces with trimethyl ammonium and the salt of the hydroxyethyl-cellulose that obtains, and (CTFA) is called polyquaternary amine 10 in industry.Another kind of cationic cellulose comprises the epoxide reaction that hydroxyethyl-cellulose and lauryl dimethyl ammonium replace and the polymeric quaternary ammonium salts ((CTFA) is called polyquaternary amine 24 in industry) that forms.These materials are with trade name Polymer LM-200 ^Available from Amerchol Corp. (Edison, NJ, USA).

Operable other cationic polymer comprises the cationic guar gum derivant, as guar gum hydroxypropyl three ammoniums (hydroxypropyltrimonium) chloride (with Jaguar R series title available from CelaneseCorp.).Other material comprises that the cellulose ether that contains quaternary nitrogen is (as United States Patent (USP) the 3rd, 962, described in No. 418, the document is incorporated herein by reference) and the copolymer of etherified cellulose and starch (as United States Patent (USP) the 3rd, described in 958, No. 581, the document is incorporated herein by reference).

Low melting point oil

Wo 2008069000 B of the present invention comprises low melting point oil, and this oily fusing point is lower than 25 ℃, and the low melting point oil that is included in the said composition is preferably about 0.1% to about 10%, more preferably about 0.25% to about 6% by weight.

Compositions A also comprises low melting point oil, and this oily fusing point is lower than 25 ℃, and is included in low melting point oil in the said composition and is preferably about 0.1% to about 10%, more preferably about 0.25% by weight to about 6%, most preferably is about 0.3% to about 3%.

Be applicable to that low melting point grease separation of the present invention has about 10 hydrocarbon to about 40 carbon atoms certainly, has about 10 unsaturated fatty alcohols to about 30 carbon atoms, has about 10 unsaturated fatty acids to about 30 carbon atoms, derivative of fatty acid, fatty alcohol derivative, ester oil, poly ﹠ Alpha ,-olefin oil, and composition thereof.

Be applicable to aliphatic alcohol of the present invention be have about 10 to about 30 carbon atoms, preferred about 12 to about 22 carbon atoms, 16 aliphatic alcohol more preferably from about to about 22 carbon atoms.These aliphatic alcohol are undersaturated, and can be straight or branched alcohol.Suitable aliphatic alcohol for example comprises oleyl alcohol, isooctadecanol, tridecanol, decyl tetradecyl alchohol and octyl group dodecyl alcohol.These alcohol for example can be obtained by Shinnihon Rika.

Be applicable to that low melting point oil of the present invention comprises pentaerythritol ester oil, trihydroxy methyl ester oil, poly ﹠ Alpha ,-olefin oil, citric acid ester oil, glyceride oil, and composition thereof, and be applicable to that the ester oil among the present invention is water-fast.The term " water-insoluble " that this paper adopts is meant that chemical compound is gone up water insoluble substantially in the time of 25 ℃; When with chemical compound being higher than 1.0% (weight), when preferably mixing with water with the concentration that is higher than 0.5% (weight), this chemical compound temporarily is scattered in and forms unsettled colloid in the water, then rapidly and separated form water be biphase.

Those chemical compounds that to can be used for pentaerythritol ester oil of the present invention be following formula:

R in the formula ¹, R ², R ³And R ⁴Independently for having 1 side chain, straight chain, saturated or unsaturated alkyl, aryl and alkaryl to about 30 carbon atoms.Preferably, R ¹, R ², R ³And R ⁴Independently for having 8 side chains, straight chain, saturated or unsaturated alkyl to about 22 carbon atoms.More preferably, R ¹, R ², R ³And R ⁴Be defined as and make that the molecular weight of this chemical compound is about 800 to about 1200.

Those chemical compounds that to can be used for trihydroxy methyl ester oil of the present invention be following formula:

R in the formula ¹¹Be to have 1 alkyl to about 30 carbon atoms, and R ¹², R ¹³And R ¹⁴Independently for having 1 side chain, straight chain, saturated or unsaturated alkyl, aryl and alkaryl to about 30 carbon atoms.Preferably, R ¹¹, R ¹², R ¹³And R ¹⁴Independently for having 8 side chains, straight chain, saturated or unsaturated alkyl to about 22 carbon atoms.More preferably, R ¹¹, R ¹², R ¹³And R ¹⁴Be defined as and make that the molecular weight of this chemical compound is about 800 to about 1200.

Useful especially pentaerythritol ester oil of the present invention and trihydroxy methyl ester oil comprise pentaerythritol tetraoctyl stearate, tetramethylolmethane four oleates, trimethylolpropane tris isostearate, trimethylolpropane tris oleate and their mixture.Such chemical compound be can trade name KAKPTI and KAKTTI available from Kokyo Alcohol, and with trade name PTO and ENUJERUBU TP3SO product available from Shin-nihon Rika.

Can be used for poly ﹠ Alpha ,-olefin oil of the present invention and be derived from having about 6 to about 16 carbon atoms, preferred about 6 poly ﹠ Alpha ,-olefin oils to the 1-olefinic monomer of about 12 carbon atoms.The limiting examples that can be used for preparing the 1-olefinic monomer of poly ﹠ Alpha ,-olefin oil comprises 1-hexene, 1-octene, 1-decene, 1-dodecylene, tetradecene, cetene, branched chain isomer for example 4-methyl-1-pentene and their mixture.The preferred 1-olefinic monomer that can be used for preparing poly ﹠ Alpha ,-olefin oil is 1-octene, 1-decene, 1-dodecylene, tetradecene, 1 hexadecene and their mixture.Be applicable to that its viscosity of poly ﹠ Alpha ,-olefin oil of the present invention is about 1 to about 35,000cst, molecular weight are about 200 to about 60,000, and poly-dispersion is no more than about 3.

Molecular weight is at least about 800 poly ﹠ Alpha ,-olefin oil and is applicable to the present invention.This high-molecular weight poly ﹠ Alpha ,-olefin oil is considered to and can provides more permanent wetness sensation for hair.Molecular weight is lower than about 800 poly ﹠ Alpha ,-olefin oil and is applicable to the present invention.This low-molecular-weight poly ﹠ Alpha ,-olefin oil is considered to make hair to have smooth, shinny and clean sensation.

Be specially adapted to poly ﹠ Alpha ,-olefin oil of the present invention and comprise poly decene, its commodity are called PURESYN6, and number-average molecular weight is about 500; Commodity are called PURESYN 100, and number-average molecular weight is about 3,000; And commodity PURESYN 300 by name, number-average molecular weight is about 6,000, is obtained by Mobil Chemical Co..

Can be used for citric acid ester oil of the present invention is that molecular weight is at least about 500 following formula: compound:

R in the formula ²¹Be OH or CH ₃COO, and R ²², R ²³And R ²⁴Independently for having 1 side chain, straight chain, saturated or unsaturated alkyl, aryl and alkaryl to about 30 carbon atoms.Preferably, R ²¹Be OH and R ²², R ²³And R ²⁴Independently for having 8 side chains, straight chain, saturated or unsaturated alkyl, aryl and alkaryl to about 22 carbon atoms.More preferably, R ²¹, R ²², R ²³And R ²⁴Be defined as and make the molecular weight of this chemical compound be at least about 800.

The useful especially citric acid ester oil of the present invention comprises: the citric acid three different cetyl esters that derive from the commodity CITMOL316 by name of Bernel, derive from Phoenix commodity PELEMOL TISC by name citric acid three iso stearyl esters and derive from the citric acid trioctylphosphine dodecyl ester of the commodity CITMOL 320 by name of Bernel.

Can be used for glyceride oil of the present invention is that molecular weight is at least about 500 following formula: compound:

R in the formula ⁴¹, R ⁴²And R ⁴³Independently for having 1 side chain, straight chain, saturated or unsaturated alkyl, aryl and alkaryl to about 30 carbon atoms.Preferably, R ⁴¹, R ⁴²And R ⁴³Independently for having 8 side chains, straight chain, saturated or unsaturated alkyl, aryl, alkaryl to about 22 carbon atoms.More preferably, R ⁴¹, R ⁴²And R ⁴³Be defined as and make the molecular weight of this chemical compound be at least about 800.

The useful especially glyceride oil of the present invention comprises: the glycerol tristearate that derives from the commodity SUNESPOL G-318 by name of Taiyo Kagaku; Derive from the triolein of the commodity CITHROL GTO by name of Croda Surfactants Ltd.; Derive from the commodity EFADERMA-F by name of Vevy, or derive from the linolein of the commodity EFA-GLYCERIDES by name of Brooks.

Polysiloxane compound

Present composition A preferably contains polysiloxane compound.Can comprise polysiloxane compound in said composition A, its content is preferably about 0.1% to about 10%, more preferably about 0.25% by weight to about 8%, most preferably is about 0.5% to about 3%.

Also can comprise polysiloxane compound in compositions B, its content is preferably about 0.1% to about 10%, more preferably about 0.25% by weight to about 8%, most preferably is about 0.5% to about 3%.

Polysiloxane compound of the present invention can comprise volatile soluble or insoluble, or non-volatile soluble or insoluble polysiloxanes conditioner.Solubility is meant that polysiloxane compound can be miscible to form part homophase mutually with the carrier of compositions.Insoluble be meant polysiloxanes form separate with carrier, mutually discontinuous, for example be the emulsion or the form of suspension of polysiloxanes droplet.Polysiloxane compound among the present invention can make by conventional polyreaction or emulsion polymerization.

Be applicable to that polysiloxane compound of the present invention preferably has about 1,000 to about 2,000,000 centistoke at 25 ℃, more preferably from about 10,000 to about 1,800,000, even more preferably from about 25,000 to about viscosity of 1,500,000.This viscosity can be by at Dow Corning Corporate Test MethodCTM0004, said glass capillary tube viscometer method among the July 20,1970 and measuring, and the document is incorporated herein as a reference and in full.Can prepare high-molecular weight silicone compounds by emulsion polymerization.

Be applicable to that polysiloxane compound of the present invention comprises poly-alkyl poly aromatic radical siloxane, polyalkylene oxides-modified siloxane, polyorganosiloxane resin, the amino siloxanes that replaces, and composition thereof.This polysiloxane compound is preferably selected from the poly-aryl siloxanes of poly-alkyl, polyalkylene oxides-modified siloxane, polyorganosiloxane resin, and composition thereof, more preferably be selected from the poly-aryl siloxanes of one or more poly-alkyl.

Be applicable to that the poly-aryl siloxanes of poly-alkyl of the present invention comprises those materials with following array structure (I)

R is an alkyl or aryl in the formula, and x is about 7 to about 8000 integer.The group of " A " representative sealing polysiloxanes chain end.Can have any structure at the alkyl or aryl (R) of siloxanes chain substitution or the alkyl or aryl (A) that on the siloxane chain end, replaces, as long as the polysiloxanes that is obtained at room temperature keeps mobile, be dispersible, be non-stimulated, nontoxic, harmless in the time of on being applied to hair, can be compatible with other composition in the said composition, under regular service conditions and storage requirement, be chemically stable, and can be deposited on the hair and conditioning hair.The non-limiting examples of suitable group comprises hydroxyl, methyl, methoxyl group, ethyoxyl, propoxyl group and aryloxy group.Two R groups on silicon atom can be represented identical or different group.Preferably, two identical groups of R group representative.The suitable R group comprises methyl, ethyl, propyl group, phenyl, aminomethyl phenyl and phenyl methyl.Preferred polysiloxane compound is polydimethylsiloxane, poly-di-ethyl siloxane and PSI.The polydimethylsiloxane that also is called simethicone is especially preferred.Spendable poly-alkylsiloxane comprises for example polydimethylsiloxane.For instance, these polysiloxane compounds can be bought with its ViscasilR and SF 96 series by General Electric Company, and are bought with its Dow Corning 200 series by DowCorning.For example, as SF 1075 aminomethyl phenyl fluids, perhaps be applicable to the present invention as the fluidic PSI of 556 cosmetics-stages from General Electric Company from Dow Corning.

What preferably be used to improve the hair gloss characteristic is that index of refraction is about 1.46 or higher, particularly is about 1.52 or the polysiloxane compound of higher height arylation, for example many ethyl polysiloxanes of height benzeneization.When using these high refractive index polysiloxane compounds, should with its with the smears for example surfactant or polyorganosiloxane resin as described below mixes, to reduce surface tension and its film forming ability of raising.

The poly-aryl siloxanes of the poly-alkyl of the another kind of particularly suitable is a polysiloxanes natural gum.Term " polysiloxanes natural gum " is meant in the time of 25 ℃ its viscosity more than or equal to 1,000, the polysiloxane of 000 centistoke.Will be appreciated that polysiloxanes natural gum as herein described also can have some overlapping with above-mentioned polysiloxane compound.This is overlapping not to be restriction to any of these material.Petrarch and other document, be included in the people's such as Spitzer that published on May 1st, 1979 United States Patent (USP) the 4th, 152, No. 416, and Noll, Walter, Chemistry and Technology of Silicones, New York:AcademicPress, 1968 have described polysiloxanes natural gum.That other describes polysiloxanes natural gum is GeneralElectric Silicone Rubber Product Data Sheets SE 30, and SE 33, SE 54 and SE 76.The document of all these descriptions all is incorporated into herein as a reference and all.The mass molecular weight of " polysiloxanes natural gum " is typically about more than 200,000, usually 200,000 to about 1,000, between 000.Concrete example comprises polydimethylsiloxane, poly-(dimethyl siloxane ethylene methacrylic radical siloxane) copolymer, poly-(dimethyl siloxane-diphenyl siloxane-ethylene methacrylic radical siloxane) copolymer, and composition thereof.

For instance, be applicable to that polyalkylene oxides-modified siloxane of the present invention comprises the polypropylene oxide modification and the polydimethylsiloxane polyethylene glycol oxide modification.The content of oxirane and expoxy propane should be enough low, not influence the allocability of polysiloxanes.These materials also are called the simethicone copolyol.

The polyorganosiloxane resin of highly cross-linked polymer siloxane system also is applicable to the present invention.Described crosslinkedly introduce by trifunctional and four functional silanes being mixed with simple function or difunctional silane or the two at the polyorganosiloxane resin production period.As well known in the art, will change according to the specific silane moiety that mixes in the polyorganosiloxane resin in order to obtain the required crosslinking degree of polyorganosiloxane resin.Generally speaking, thus have the trifunctional of enough content and four functional silane monomeric units, and the crosslinked silicone materials that makes that they can form hard or firm film when becoming dry that therefore has enough levels can be considered polyorganosiloxane resin.The ratio of oxygen atom and silicon atom is the indication of the crosslinked level of concrete polysiloxanes material.Each silicon atom has at least about the polysiloxanes material of 1.1 oxygen atoms polyorganosiloxane resin normally of the present invention.Preferably, the ratio of oxygen and silicon atom was at least about 1.2: 1.0.The silane that is used for making polyorganosiloxane resin comprise monomethyl-, dimethyl-, trimethyl-, a phenyl-, biphenyl-Ji, aminomethyl phenyl-, a vinyl-and methyl chloride vinyl silanes and tetrachloro silicane, wherein methyl substituted silane is the most frequently used.Preferred resin is GE SS4230 and the SS4267 by General Electric supply.Commercially available polyorganosiloxane resin normally provides with the dissolved form in low viscosity volatility or non-volatile siloxane liquid.Can be used for polyorganosiloxane resin of the present invention should provide with such dissolved form and be incorporated in the present composition, and this it will be apparent to those skilled in the art that.Be not bound by theory, it is believed that polyorganosiloxane resin can strengthen the sedimentation of other polysiloxane compound on hair, and strengthen the gloss of hair with high refractive index volume.

Spendable other polyorganosiloxane resin is the polyorganosiloxane resin powder, and for example the CTFA name is called the material of polymethylsilsequioxane, and this material is by the commercially available Tospearl of Toshiba Silicones ^TM

According to the known abbreviation naming system of those skilled in the art (" MDTQ " nomenclature), can discern polyorganosiloxane resin more conveniently.Under this naming system, be to describe polysiloxanes according to the various siloxanyl monomers of the formation polysiloxanes that exists.In brief, symbol M is represented simple function unit (CH ₃) ₃SiO) _.5D represents difunctionality unit (CH ₃) ₂SiO; T represents trifunctional units (CH ₃) SiO _1.5Q represents four functional unit SiO ₂Major part in the unit symbol as M ', D ', T ' and the substituent group of Q ' expression except that methyl, and defines especially to each situation.Typical other substituent group comprises the group such as vinyl, phenyl, amino, hydroxyl etc.Under the MDTQ system, according to the symbol subscript of various unitary total numbers in the expression polysiloxanes, or according to its meansigma methods, or as represent with molecular weight concrete shown in the mol ratio of different units of ratio finished the description of silicone materials.In polyorganosiloxane resin, with respect to D, D ', M and/or M ', the T of higher molar amounts, Q, T ' and/or Q ' mean the crosslinked of higher level.Yet as mentioned above, total crosslinked level can also be represented by the ratio of oxygen and silicon.

Can be used for preferred polyorganosiloxane resin of the present invention is MQ, MT, MTQ, MQ and MDTQ resin.Therefore, preferred polysiloxanes substituent group is a methyl.Especially preferred is MQ resin, wherein M: the Q ratio is about 0.5: 1.0 to about 1.5: 1.0, and the mean molecule quantity of this resin is about 1000 to about 10,000.

Be applicable to that the amino siloxanes that replaces of the present invention comprises those chemical compounds by following array structure (II) expression:

R is CH in the formula ₃Or OH, x and y are the integers that depends on molecular weight, mean molecule quantity is about 5,000 to 10,000.Known this polymer is also called " amino dimethyl polysiloxane ".

The siloxanes fluids that the amino that is suitable for replaces comprises those chemical compounds by general formula (III) expression:

(R ₁) _aG _3-a-Si-(-OSiG ₂) _n-(-OSiG _b(R ₁) _2-b)m-O-SiG _3-a(R ₁) _a(III)

G is selected from hydrogen, benzene, OH, C in the formula ₁-C ₈Alkyl, and methyl preferably; A represents 0 or 1 to 3 integer, and is preferably 0; B represents 0 or 1, and is preferably 1; N+m is 1 to 2,000 and is preferably 50 to 150, and n can represent 0 to 1,999 and be preferably 49 to 149 integer, and m can be 1 to 2,000, and is preferably 1 to 10 integer; R ₁Be that general formula is C _qH _2qThe monoradical of L, q is that 2 to 8 integer and L are selected from following groups in the formula

-N(R ₂)CH ₂-CH ₂-N(R ₂) ₂

-N(R ₂) ₂

-N(R ₂) ₃A ^-

-N(R ₂)CH ₂-CH ₂-NR ₂H ₂A ^-

R in the formula ₂Be selected from hydrogen, phenyl, benzyl, saturated hydrocarbyl, be preferably the alkyl that contains 1 to 20 carbon atom, and A ^-The expression halogen atom.

Particularly preferred amino substituted silicone corresponding to general formula (III) be have general formula (IV), be the known polymer of people with " trimethyl silyl amino dimethyl polysiloxane ": In this general formula, n and m select according to the molecular weight of required chemical compound.Operable other amino siloxanes that replaces is represented with logical formula V:

R in the formula ³Expression has the monovalence alkyl of 1 to 18 carbon atom, is preferably alkyl or alkenyl, as methyl; R ₄The expression alkyl is preferably C ₁-C ₁₈Alkylidene or C ₁-C ₁₈, more preferably C ₁-C ₈Alkylidene oxygen base; Q ^-Be halogen atom, be preferably chlorine; R is expressed as the average statistics value, is 2 to 20, is preferably 2 to 8; S represents the average statistics value, is 20 to 200, is preferably 20 to 50.Preferred this base polymer can be by Union Carbide with trade name " UCAR SILICONE ALE 56." obtain.

Polypropylene glycol

Present composition A preferably also contains polypropylene glycol.Polypropylene glycol can about 0.1% to about 10%, more preferably from about 0.25% to about 6% by weight content be included among the compositions A.

Polypropylene glycol can also about 0.1% to about 10%, more preferably from about 0.25% to about 6% by weight amount be included among the compositions B.

The weight average molecular weight normally about 200 that is applicable to polypropylene glycol of the present invention to about 100,000 gram/moles, preferred about 1,000 to about 60,000 gram/moles.Be not bound by theory, it is believed that polypropylene glycol of the present invention is deposited on or is adsorbed in hair, with as wetting agent, and/or provide one or more other desired hair conditioning effect.The term " polypropylene glycol " that this paper adopts comprises list-polypropylene glycol-segmented polymer and multi-polypropylene glycol-chain section polymer.For example, in " polymeric principle ", pp.17-19, G.Odian, (John Wiley ﹠amp; Sons, Inc., 3 ^RdThe general structure of branch polymer, for example poly propylene glycol-segmented polymer has been described ed., 1991).

Can be used for polypropylene glycol of the present invention generally is the polydispersion polymer.Can be used for polypropylene glycol of the present invention and have about 1 to about 2.5, preferred about 1 to about polydispersity of 2, more preferably from about 1 to about 1.5.Term used herein " polydispersity " is meant the molecular weight distribution degree of polymer sample.Particularly, polydispersity is a weight average molecular weight divided by the ratio of number-average molecular weight greater than 1.About the further argumentation of polydispersity referring to " polymeric principle ", pp.20-24, G.Odian, (John Wiley ﹠amp; Sons, Inc., 3 ^RdEd., 1991).

According to extent of polymerization and whether be connected with other group, to can be used for polypropylene glycol of the present invention can be water solublity, water-insoluble or have limited solubility in water.The required dissolubility of polypropylene glycol in water depends on the type (for example leave or washing-off type) of Haircare composition to a great extent.The dissolubility of polypropylene glycol herein of the present invention in water can be selected according to multiple factor by those skilled in the art.Therefore, for the leave Haircare composition, polypropylene glycol is the water-soluble poly propylene glycol preferably.Solubility data can be easily from for example Sanyo Kasei (Osaka, Japan) acquisition of polypropylene glycol supplier.Yet the present invention can also be the form of rinse-off hair care composition.Be not bound by theory, it is believed that in such compositions, the water-soluble poly propylene glycol may deposit on the hair effectively and is highly susceptible to before required beneficial effect is provided being washed off at it.Therefore for such compositions, weak water solublity or or even the water-insoluble polypropylene glycol be preferred.So for rinse-off hair care composition, polypropylene glycol dissolubility in 25 ℃ in water is lower than about 1 gram/100 gram water, more preferably less than about 0.5 gram/100 gram water, even more preferably less than about 0.1 gram/100 gram water.

Polypropylene glycol is preferably selected from list-polypropylene glycol-segmented polymer, multi-polypropylene glycol-chain section polymer and their mixture, more preferably is selected from following formula I list-polypropylene glycol-segmented polymer, following formula II multi-polypropylene glycol-chain section polymer and their mixture.

List-polypropylene glycol-segmented polymer

Therefore, list-polypropylene glycol very preferably-segmented polymer has following structural formula:

HO-(C ₃H ₆O) _aH?????????(III)，

A is about 4 to about 400 in the formula, and preferred about 20 to about 100, more preferably from about 20 to about 40 value.

It is normally more cheap to be used for list-polypropylene glycol of the present invention-segmented polymer, can be easily available from, for example Sanyo Kasei (Osaka, Japan), Dow Chemicals (Midland, Michigan, USA), Calgon Chemical, Inc. (Skokie, Illinois, USA), and Arco Chemical Co. (Newton Square Pennsylvania, USA), Witco Chemicals Corp. (Greenwich, Connecticut, USA) and PPG Specialty Chemicals (Gurnee, Illinois, USA).

Multi-polypropylene glycol-chain section polymer

Highly preferred multi-polypropylene glycol-chain section polymer has the following formula structure:

N is 0 to about 10 number in the formula, is preferably 0 to about 7, more preferably is about 1 to about 4.In general formula I V, each R " is independently selected from H and C ₁-C ₃₀Alkyl, preferably each R " is independently selected from H and C ₁-C ₄Alkyl.In general formula I V, each b is about 0 to about 2 value independently, is preferably 0 to about 1 value, more preferably b=0.Similarly, c and d are 0 to about 2 value independently, are preferably 0 to about 1 value.It is about 2 that but the b+c+d summation is at least, and preferably the b+c+d summation is about 2 to about 3.Each e is 0 or 1 value independently, if n is about 1 to about 4, then e is preferably 1.In general formula I V, x, y and z are about 1 to about 120 value independently in addition, are preferably about 7 to about 100, more preferably about 7 to about 100, and x+y+z is greater than about 20 in the formula.

The example that is particularly preferred for many-polypropylene glycol chain segment copolymer of formula II of the present invention comprises polypropylene oxide glycerin ether (n=1, R '=H, b=0, c and d=1, e=1, and x, y and z represent their polypropylene glycol-segmental degree of polymerization separately respectively; Can New Pol GP-4000 trade name available from SanyoKasei (Osaka, Japan), polypropylene trimethylolpropane (n=1, R '=C ₂H ₅B=1, c and d=1, e=1, and x, y and z represent their polypropylene glycol-segmental degree of polymerization separately respectively), polypropylene oxide sorbitol (n=4, each R '=H, b=0, c and d=1, each e=1, and y, z and each x represent their polypropylene glycol-segmental degree of polymerization separately respectively); Can New Pol SP-4000 trade name available from Sanyo Kasei, Osaka, Japan) and PPG-10 butanediol (n=0, the d=2 of c, and y+z=10; Can Probutyl DB-10 trade name available from Croda, Inc., Parsippany, NewJersey, U.S.A.).

In preferred specific embodiments, the one or more propylene recurring groups in polypropylene glycol are isopropyl oxygen recurring groups.More preferably, one or more propylene oxide recurring groups of formula III polypropylene glycol and/or formula IV polypropylene glycol are oxidation isopropyl recurring groups.Even more preferably, all propylene oxide recurring groups of formula III polypropylene glycol and/or formula IV polypropylene glycol all are the oxidation isopropyl group basically.Therefore, list-polypropylene glycol very preferably-segmented polymer has following structural formula:

The definition of a is as above described to formula III in the formula.Similarly, multi-polypropylene glycol-chain section polymer has following formula:

N, R in the formula ", b, c, d, e, x, y and z as above define formula IV.Can think that this isopropyl oxygen recurring group can also represent alone or with group recited above:

Be applicable to that polypropylene glycol of the present invention for example can buy from following company: from Sanyo Kasei (Osaka, Japan) as New pol PP-2000, New pol PP-4000, New pol GP-4000 and New pol SP-4000, from Dow Chemicals (Midland, Michigan, USA), from CalgonChemical, Inc. (Skokie, Illinois, USA), from Arco Chemical Co. (Newton SquarePennsylvania, USA), from Witco Chemicals Corp. (Newton Square Pennsylvania, USA), from Witco Chemicals Corp. (Greenwich, Connecticut, USA), and from PPG Specialty Chemicals (Gurnee, Illinois USA) buys.

Polyethylene Glycol

Preferably, compositions B of the present invention can also comprise the Polyethylene Glycol with following general formula:

H(OCH ₂CH ₂) _n-OH

The meansigma methods of n is about 2 in the formula, 000-14, and 000, be preferably about 5,000 to about 9,000, more preferably about 6,000 to about 8,000.

The content of Polyethylene Glycol in compositions B can be about 0.1% to about 10%, more preferably from about 0.25% to about 6% weight.

The content of Polyethylene Glycol in compositions A can be about 0.1% to about 10%, more preferably from about 0.25% to about 6% weight.

Known polyethylene glycol oxide and the polyoxyethylene of being also called of Polyethylene Glycol recited above.Particularly preferredly be applicable to that Polyethylene Glycol of the present invention is PEG-2M, wherein the meansigma methods of n is about 2,000 (PEG-2M is also with the Polyox WSR from Union Carbide ^N-10 and with PEG-2,000 is known); PEG-5M, wherein the meansigma methods of n is about 5,000 (PEG-5M is also with Polyox WSR ^N-35 and Polyox WSR ^N-80 is known, and these two kinds of products are all from Union Carbide, and as PEG-5, and 000 and Polyethylene Glycol300,000 is known); PEG-7M, wherein the meansigma methods of n is about 7,000 (PEG-7M is also with Polyox WSR ^N-750 is known, and it is from Union Carbide); PEG-9M, wherein the meansigma methods of n is about 9,000 (PEG-9M is also with Polyox WSR ^N-3,333 is known, it is from Union Carbide); And PEG-14M, wherein the meansigma methods of n is about 14,000 (PEG-14M is also with Polyox WSR ^N-3,000 is known, it is from Union Carbide).

Preferred Wo 2008069000

Compositions of the present invention can be rinse-off products or leave product, and can be the product of emulsion, cream, gel, spray or mousse form.

Compositions of the present invention has suitable viscosity, be preferably about 1,000mm ²s ^-1To about 100,000mm ²s ^-1, more preferably be about 2,000mm ²s ^-1To about 50,000mm ²s ^-1Said herein viscosity can be passed through after rotating one minute at 2.0s ^-1Measure under the shear rate.

In a preferred version of the present invention, Wo 2008069000 comprises by weight:

(a) about 0.1% to about hard fat chemical compound of 15%, preferred about 1% to about 10%, and preferably, this hard fat chemical compound is selected from spermol, stearyl alcohol, docosanol, and composition thereof;

(b) about 0.1% to about 10%, preferred about 0.5% to about 3% has the amidoamines of following general formula:

R ¹CONH(CH ₂) _mN(R ²) ₂

R in the formula ¹Be C ₁₁-C ₂₄Fatty acid residue, R ²Be C ₁-C ₄Alkyl, m are 1 to 4 integers, and preferably this amidoamines is selected from the amino propyl group dimethylamine of stearoyl, the amino ethyl diethylamine of stearoyl, and composition thereof;

(c) acid, be selected from l-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, l-glutamic acid hydrochloride, tartaric acid, and composition thereof, its amount makes that the amidoamines and the mol ratio of acid are about 1: 0.3 to about 1: 1, preferred l-glutamic acid, its amount make that the amidoamines and the mol ratio of acid are about 1: 0.5 to about 1: 0.9; And

(d) aqueous carrier.

Said composition also comprises polysiloxane compound, and its content is about 0.1% to about 10% weight.

In another preferred version of the present invention, Wo 2008069000 comprises by weight:

(a) about 0.1% to about 15%, preferred about 1% to about 10% fusing point be 25 ℃ or higher hard fat chemical compound;

(b) about 0.1% to about cation opsonizing agent of 10%, preferred about 0.25% to about 5%;

(c) aqueous carrier; And

(d) about 0.1% to about polypropylene glycol of 10%, preferred about 0.25% to about 6%.

Said composition can also comprise low melting point oil, and this oily fusing point is lower than 25 ℃, and the content of low melting point oil is preferably about 0.1% to about 10%, more preferably about 0.25% to about 6%, more preferably about 0.3% to about 3% by weight in said composition.

(a) about 0.1% to about 15%, preferred about 0.25% to about 5% fusing point be 25 ℃ or higher hard fat chemical compound;

(c) about 0.1% to about low melting point oil of 10%, preferred about 0.25% to about 6%, and its fusing point is lower than 25 ℃, and preferably this low melting point oil is unsaturated oils;

(d) aqueous carrier; And

(e) about 0.1% to about Polyethylene Glycol of 10%, preferred about 0.25% to about 6%.

Supplementary element

Compositions of the present invention can comprise other supplementary element, they can be selected by the person in the art according to the required characteristic of end product, and they are suitable to make said composition in beauty treatment or aestheticly can be accepted more, perhaps makes them have additional result of use.The common independent consumption of these annexing ingredients be compositions by weight about 0.001% to about 10%, preferably up to about 5%.

Wide variety of other additional components can be formulated in the present composition.These compositions comprise: other conditioner such as hydrolytic collagen, obtain by Hormel with trade name Peptein 2000, vitamin E, Emix-d is obtained by Eisai with trade name, and pantothenylol derives from Roche, pan-ethyl ether, derive from Roche, the mixture of polysorbate60 and cetearyl alcohol derives from Croda Chemicals with trade name Polawax NF, glyceryl monostearate, derive from Stepan Chemicals, hydroxyethyl-cellulose derives from Aqualon and gets, 3-pyridine carboxylic acid amide (nicotiamide), hydrolysis of keratin, protein, plant extraction liquid and nutrient; Hair fixing copolymer, as the both sexes styling polymer, cationic styling polymers, anionic shaped polymer, nonionic styling polymer and silicone-grafted copolymers; Antiseptic, as benzyl alcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate and imidazolidinyl urea; The pH regulator agent, as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; Salt is usually as potassium acetate and sodium chloride; Coloring agent is as any FD﹠amp; C or D﹠amp; The C dyestuff; Hair oxidation (bleaching) agent, as hydrogen peroxide, perborate and persulfate; The hair Reducing agent is as mercaptoacetate; Spice; And chelating agen, as disodiumedetate; Ultraviolet and infrared shielding and absorption examination, as ethylhexyl salicylate, dandruff removing agent is as Zinc Pyrithione and salicylic acid; And fluorescent whitening agent, as the polystyrene stilbene, the triazine stilbene, Hydroxycoumarin, aminocoumarin, triazole, pyrazoline, oxazole, pyrene, porphyrin, imidazoles, and composition thereof.

Embodiment

The following example has further described and has proved the specific embodiments in the scope of the invention.These embodiment only are illustrative, but not limit the scope of the invention, because can carry out multiple change under the condition that does not deviate from spirit and scope of the invention.Except as otherwise noted, each composition all provides with chemical name or CTFA title.

Wo 2008069000

Component	Component 1	Component 2	Component 3
Component	Component 1	Component 2	Component 3	Spermol ^*1	????2.0	????2.5	????2.0
Stearyl alcohol ^*2	????3.6	????4.5	????3.6	Spermol ^*1	????2.0	????2.5	????2.0
Stearyl alcohol ^*2	????3.6	????4.5	????3.6	The amino propyl-dimethyl amine of stearoyl ^*3	????1.6	????2.0	????1.6
L-glutamic acid ^*4	????0.412	????0.64	????0.412	The amino propyl-dimethyl amine of stearoyl ^*3	????1.6	????2.0	????1.6
L-glutamic acid ^*4	????0.412	????0.64	????0.412	Muscovitum ^*5	?????-	?????-	????0.5
Silicon dioxide ^*6	?????-	????1.0	????1.0	Muscovitum ^*5	?????-	?????-	????0.5
Silicon dioxide ^*6	?????-	????1.0	????1.0	Mixture of siloxanes ^*7	????3.36	????4.37	????3.36
Spice	????0.4	????0.4	????0.4	Mixture of siloxanes ^*7	????3.36	????4.37	????3.36
Spice	????0.4	????0.4	????0.4	Benzyl alcohol	????0.4	????0.4	????0.4
EDTA	????0.1	????0.1	????0.1	Benzyl alcohol	????0.4	????0.4	????0.4
EDTA	????0.1	????0.1	????0.1	Kathon?CG ^*8	????0.0005	????0.0005	????0.0005
Sodium chloride	????0.01	????0.01	????0.01	Kathon?CG ^*8	????0.0005	????0.0005	????0.0005
Sodium chloride	????0.01	????0.01	????0.01	3-picolinic acid amidoamines	????0.05	????0.05	????0.05
Dl-alpha tocopherol acetas	????0.05	????0.05	????0.05	3-picolinic acid amidoamines	????0.05	????0.05	????0.05
Dl-alpha tocopherol acetas	????0.05	????0.05	????0.05	Hydrolytic collagen ^*9	????0.01	????0.01	????0.01
Pantothenylol ^*10	????0.05	????0.05	????0.05	Hydrolytic collagen ^*9	????0.01	????0.01	????0.01
Pantothenylol ^*10	????0.05	????0.05	????0.05	Pan-ethyl ether ^*11	????0.05	????0.05	????0.05
Methoxy cinnamic acid octyl group ester	????0.09	????0.09	????0.09	Pan-ethyl ether ^*11	????0.05	????0.05	????0.05
Methoxy cinnamic acid octyl group ester	????0.09	????0.09	????0.09	Benzophenone-3	????0.09	????0.09	????0.09
Citric acid	Regulate the required amount of pH3-7			Benzophenone-3	????0.09	????0.09	????0.09
Citric acid	Regulate the required amount of pH3-7			Deionized water	Add to 100%

Wo 2008069000

Component	Component 4	Component 5
Component	Component 4	Component 5	Spermol ^*1	????2.6	????2.0
Stearyl alcohol ^*2	????4.6	????3.6	Spermol ^*1	????2.6	????2.0
Stearyl alcohol ^*2	????4.6	????3.6	The amino propyl-dimethyl amine of stearoyl ^*3	????1.8	????1.6
L-glutamic acid ^*4	????0.6	????0.5	The amino propyl-dimethyl amine of stearoyl ^*3	????1.8	????1.6
L-glutamic acid ^*4	????0.6	????0.5	Pentaerythritol tetraoctyl stearate ^*13	????1.0	????0.5
Polypropylene glycol ^*20	????4.5	????4.0	Pentaerythritol tetraoctyl stearate ^*13	????1.0	????0.5
Polypropylene glycol ^*20	????4.5	????4.0	Silicon dioxide ^*6	?????-	????1.0
Mixture of siloxanes ^*7	????2.5	????4.2	Silicon dioxide ^*6	?????-	????1.0
Mixture of siloxanes ^*7	????2.5	????4.2	Spice	????0.4	????0.4
Benzyl alcohol	????0.4	????0.4	Spice	????0.4	????0.4
Benzyl alcohol	????0.4	????0.4	EDTA	????0.1	????0.1
Kathon?CG ^*8	????0.0005	????0.0005	EDTA	????0.1	????0.1
Kathon?CG ^*8	????0.0005	????0.0005	Sodium chloride	????0.01	????0.01
3-picolinic acid amidoamines	????0.05	????0.05	Sodium chloride	????0.01	????0.01
3-picolinic acid amidoamines	????0.05	????0.05	Dl-alpha tocopherol acetas	????0.05	????0.05
Hydrolytic collagen ^*9	????0.01	????0.01	Dl-alpha tocopherol acetas	????0.05	????0.05
Hydrolytic collagen ^*9	????0.01	????0.01	Pantothenylol ^*10	????0.05	????0.05
Pan-ethyl ether ^*11	????0.05	????0.05	Pantothenylol ^*10	????0.05	????0.05
Pan-ethyl ether ^*11	????0.05	????0.05	Methoxy cinnamic acid octyl group ester	????0.09	????0.09
Benzophenone-3	????0.09	????0.09	Methoxy cinnamic acid octyl group ester	????0.09	????0.09
Benzophenone-3	????0.09	????0.09	Citric acid	Regulate the required amount of pH3-7
Deionized water	Add to 100%		Citric acid	Regulate the required amount of pH3-7

Wo 2008069000

Component	Component 6	Component 7
Component	Component 6	Component 7	Spermol ^*1	????0.96	????1.2
Stearyl alcohol ^*2	????0.64	????0.8	Spermol ^*1	????0.96	????1.2
Stearyl alcohol ^*2	????0.64	????0.8	The amino propyl-dimethyl amine of stearoyl ^*3	????1.0
Two Adeps Bovis seu Bubali ammonio methacrylates ^*12	????0.75	????0.64	The amino propyl-dimethyl amine of stearoyl ^*3	????1.0
Two Adeps Bovis seu Bubali ammonio methacrylates ^*12	????0.75	????0.64	Pentaerythritol tetraoctyl stearate ^*13	????0.5
Four pentaerythritol oleates ^*14		????0.2	Pentaerythritol tetraoctyl stearate ^*13	????0.5
Four pentaerythritol oleates ^*14		????0.2	Oleyl alcohol * 15		????0.25
Three isostearic acid trihydroxy methyl propyl ester ^*16		????0.25	Oleyl alcohol * 15		????0.25
Three isostearic acid trihydroxy methyl propyl ester ^*16		????0.25	PEG?2M ^*17	????0.5	????0.5
Polysorbate60 ^*18	????0.25	????0.25	PEG?2M ^*17	????0.5	????0.5
Polysorbate60 ^*18	????0.25	????0.25	Cetearyl alcohol ^*18	????0.25	????0.25
Glyceryl monostearate ^*19	????0.25	????0.25	Cetearyl alcohol ^*18	????0.25	????0.25
Glyceryl monostearate ^*19	????0.25	????0.25	Silicon dioxide ^*6	????1.0	????1.0
Polysiloxane mixture ^*7	????4.2	????4.2	Silicon dioxide ^*6	????1.0	????1.0
Polysiloxane mixture ^*7	????4.2	????4.2	Spice	????0.4	????0.4
Benzylalcohol	????0.4	????0.4	Spice	????0.4	????0.4
Benzylalcohol	????0.4	????0.4	EDTA	????0.1	????0.1
Kathon?CG ^*8	????0.0005	????0.0005	EDTA	????0.1	????0.1
Kathon?CG ^*8	????0.0005	????0.0005	Sodium chloride	????0.01	????0.01
3-pyridine carboxylic acid amidoamines	????0.05	????0.05	Sodium chloride	????0.01	????0.01
3-pyridine carboxylic acid amidoamines	????0.05	????0.05	Dl-α tocopherol acetate	????0.05	????0.05
Hydrolytic collagen ^*9	????0.01	????0.01	Dl-α tocopherol acetate	????0.05	????0.05
Hydrolytic collagen ^*9	????0.01	????0.01	Pantothenylol ^*10	????0.05	????0.05
The pantothenylol benzyl ethyl ether ^*11	????0.05	????0.05	Pantothenylol ^*10	????0.05	????0.05
The pantothenylol benzyl ethyl ether ^*11	????0.05	????0.05	Methoxy cinnamic acid octyl group ester	????0.09	????0.09
Benzophenone-3	????0.09	????0.09	Methoxy cinnamic acid octyl group ester	????0.09	????0.09
Benzophenone-3	????0.09	????0.09	Citric acid	Be adjusted to the required amount of pH3-7
Deionized water	Add to 100%		Citric acid	Be adjusted to the required amount of pH3-7

The definition of component

^*1 spermol: Konol series, from Shin Nihon Rika.

^*2 stearyl alcohols: Konol series, from Shin Nihon Rika.

^*Amino propyl-dimethyl amine: the SAPDMA of 3 stearoyls is from Inolex.

^*4 l-glutamic acid: l-glutamic acid (cosmetics-stage) can obtain from Ajinomoto.

^*5 Muscovitums: Mearlmica CF, from Mearl.

^*6 silicon dioxide: Neosil CBT 60, its mean diameter is 250-400 μ m.

^*7 polysiloxane mixtures: SE76 is from General Electric Co. Limited.

^*8 Kathon CG: methylchloroisothiazandnone and Methylisothiazolinone, from Rohm ﹠amp; Haas.

^*9 hydrolytic collagens: Peptein 2000 is from Hormel.

^*10 pantothenylol: from Roche.

^*11 pantothenylol benzyl ethyl ethers: from Roche.

^*12 2 Adeps Bovis seu Bubali ammonio methacrylates: from Witco Chemicals.

^*13 pentaerythritol tetraoctyl stearates: KAK PTI is obtained by Kokyu alcohol.

^*14 4 pentaerythritol oleates: from Shin NihonRika.

^*15 oleyl alcohol: from New Japan Chemical.

^*16 3 isostearic acid trihydroxy methyl propyl ester: KAK TTI is obtained by Kokyu alcohol.

^*17 PEG-2M:Polyox are obtained by Union Carbide.

^*18 polysorbate60s, cetearyl alcohol:, obtain by CrodaChemicals with Polawax NF mixture sold.

^*19 glyceryl monostearates: from Stepan Chemicals.

^*20 polypropylene glycols: PP2000 is from Sanyo Kasei.

Preparation method

Prepare as said Wo 2008069000 in embodiment 1 and 7 by any conventional method known in the art.They suitably make according to following manner: if comprise polymeric material in the said composition, then at room temperature with this polymeric material, be dispersed in the water as polypropylene glycol, form polymer solution, and be heated up to 70 ℃.Under agitation, the ester oil that in this solution, adds amidoamines and acid or other cationic surfactant (if present) and low melting point oil.Under agitation then, in this solution, add hard fat chemical compound and other low melting point oil and benzylalcohol (if present).Thus obtained mixture is cooled to be lower than 60 ℃, and, adds wherein as polysiloxane compound and menthol, and further be cooled to about 30 ℃ under agitation with remaining composition.If comprise Muscovitum and silicon dioxide, then these granules are added wherein and mix.

Need, can in each step, adopt three-roller and/or ball mill, with raw material dispersion.

Embodiment 1

Hair care kits A comprises 20 gram Wo 2008069000s and restrains calcium oxide as heat generating agent as Haircare composition 1 and 1.3.By this Wo 2008069000 is mixed with calcium oxide, this Wo 2008069000 can be heated to the highest about 55 ℃.

Embodiment 2

Hair care kits A comprises 50 gram Wo 2008069000s 2 and restrains magnesium sulfate as heat generating agent as Haircare composition and 7.By this Wo 2008069000 is mixed with magnesium sulfate, this Wo 2008069000 can be heated to the highest about 57 ℃.

Embodiment 3

Hair care kits A comprises 20 gram Wo 2008069000s 4 and restrains citric acids as the reaction controlling agent as Haircare composition and 1.3 gram magnesium as heat generating agent and 2.6.By this Wo 2008069000 is mixed with calcium oxide and citric acid, this Wo 2008069000 can be heated to the highest about 65 ℃.

Embodiment 4

Hair care kits A comprise 50 the gram Wo 2008069000s 7 as Haircare composition and 3.3 the gram calcium oxide and 3.3 the gram magnesium as heat generating agent and 6.66 the gram citric acids as the reaction controlling agent.By this Wo 2008069000 is mixed with calcium oxide, magnesium and citric acid, this Wo 2008069000 can be heated to the highest about 80 ℃.

Embodiment 5

Hair care kits B comprises that 50 gram Wo 2008069000s 1 restrain citric acids as reacting control reagent and water as reactant as Haircare composition, 3.3 gram calcium oxide and 3.3 gram magnesium as heat generating agent and 13.3, and wherein calcium oxide, magnesium and citric acid are dispersed in the glycerol.By calcium oxide, magnesium and citric acid are mixed with water, the starting delivery in hot weather is given birth to reaction, and the conduction of heat that is produced by this reaction is heated to about 55 ℃ maximum temperature in this Wo 2008069000 and with this Wo 2008069000.

Embodiment 6

Hair care kits B among the embodiment 5 adopt Wo 2008069000 3 as Haircare composition to replace Wo 2008069000 1.By calcium oxide, magnesium and citric acid are mixed with water, the starting delivery in hot weather is given birth to reaction, and the conduction of heat that is produced by this reaction is heated to about 55 ℃ maximum temperature in this Wo 2008069000 and with this Wo 2008069000.

Embodiment 7

Hair care kits B adopts 50 gram Wo 2008069000s 5 as Haircare composition, sodium acetate trihydrate as heat generating agent and a kind of energizing switch as the reaction means.By connecting this energizing switch, the starting delivery in hot weather is given birth to reaction, and the conduction of heat that is produced by this reaction and is heated to about 43 ℃ maximum temperature with this Wo 2008069000 in this Wo 2008069000.

Embodiment 8

Hair care kits B among the embodiment 7 adopt Wo 2008069000 6 as Haircare composition to replace Wo 2008069000 5.By connecting energizing switch, the starting delivery in hot weather is given birth to reaction, and the conduction of heat that is produced by this reaction and is heated to about 43 ℃ maximum temperature with this Wo 2008069000 in this Wo 2008069000.

Embodiment 9

The heater that is shaped as container comprises that 3.3 gram calcium oxide and 3.3 gram magnesium restrain citric acids as reaction control reagent as heat generating agent and 13.3, and wherein calcium oxide, magnesium and citric acid are dispersed in the glycerol.By being mixed with calcium oxide, magnesium and citric acid, water starts the living reaction of this delivery in hot weather.The maximum temperature that this device provides is more than 55 ℃, and keeps the temperature more than 40 ℃ to reach more than 20 minutes.

Embodiment 10

The heater that is shaped as hat comprise sodium acetate trihydrate as heat generating agent and energizing switch as the reaction means.Start the living reaction of this delivery in hot weather by connecting energizing switch.The maximum temperature that this device provides is more than 55 ℃, and the temperature that remains on more than 40 ℃ reached more than 20 minutes.

Disclosed embodiment has many advantages in this article.For instance, the Haircare composition that is heated by hair care kits of the present invention and heater can produce better effect, promptly can provide better effect.For example, because composition has higher permeability, the Wo 2008069000 after the heating can provide better hair conditioning effect, as wetness sensation, softness and Electrostatic Control.

Should be appreciated that embodiment of the present invention and specific embodiments only are illustrative, under the condition that does not deviate from spirit and scope of the invention, this area professional can carry out various changes or variation to it.

Claims

1. hair care kits that comprises moisture Haircare composition and a kind of heat generating agent, this heat generating agent produces heat by mixing with this moisture Haircare composition, wherein this heat generating agent with should moisture Haircare composition isolation.

2. according to the hair care kits of claim 1, in first container of wherein moisture Haircare composition being packed into, heat generating agent is packed in second container, and first container and second container are spaced from each other.

3. according to the hair care kits of claim 1, wherein moisture Haircare composition and heat generating agent are packed into and are contained in the same container of two compartments, and moisture Haircare composition is packed in first compartment, and heat generating agent is packed in second compartment.

4. according to the hair care kits of claim 3, wherein first compartment and second compartment are with separating by broken spacing body.

5. according to the hair care kits of claim 3, wherein first compartment and second compartment are with being spaced from each other by broken spacing body, and first compartment is arranged to by first compartment and second compartment or second compartment is surrounded by another compartment.

6. according to the hair care kits of claim 1, wherein ferrous, the ferric chloride of mixture, calcium oxide, magnesium oxide, magnesium sulfate, calcium chloride, magnesium, magnesium chloride, the dichloride of heat generating agent chosen from Fe and activated carbon and muriatic mixture, ferrum and potassium persulphate, zeolite, polyhydric alcohol, and composition thereof.

7. according to the hair care kits of claim 6, wherein heat generating agent is dispersed in the inert carrier.

8. according to the hair care kits of claim 1, further comprise a kind of reaction controlling agent.

9. according to the hair care kits of claim 1, further comprise a kind of heat-storing material.

10. according to the hair care kits of claim 1, wherein before should moisture Haircare composition being coated on the hair, heat generating agent be mixed with moisture Haircare composition.

11. according to the hair care kits of claim 1, it is used for should moisture Haircare composition heating before being coated to moisture Haircare composition on the hair.

12. according to the hair care kits of claim 11, wherein moisture Haircare composition is heated to about 25 ℃ to about 80 ℃ temperature.

13. according to claim 1 hair care kits, wherein moisture Haircare composition is selected from moisture hair shampoo compositions, aqueous hair setting composition, moisture Wo 2008069000, moisture hair dyeing composition, moisture natural on-off cycles of hair growth compositions, and composition thereof.

14. according to the hair care kits of claim 13, wherein moisture Haircare composition is moisture Wo 2008069000.

15. according to the hair care kits of claim 14, wherein moisture Wo 2008069000 comprises by weight:

(a) about 0.1% to about 15% hard fat chemical compound;

(b) about 0.1% to about 10% amidoamines with following general formula:

R ¹CONH(CH ₂) _mN(R ²) ₂

R in the formula ¹Be C ₁₁-C ₂₄Fatty acid residue, R ²Be C ₁-C ₄Alkyl, m are 1 to 4 integer;

(c) acid is selected from l-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, l-glutamic acid hydrochloride, tartaric acid, and composition thereof, its amount makes that the amidoamines and the mol ratio of acid are about 1: 0.3 to about 1: 1; And

(d) aqueous carrier.

16. according to the hair care kits of claim 15, wherein moisture Wo 2008069000 also comprises about 0.1% polysiloxane compound to about 10% weight.

17. according to the hair care kits of claim 15, wherein moisture Wo 2008069000 also comprises about 0.1% polypropylene glycol to about 10% weight.

18. according to the hair care kits of claim 15, wherein moisture Wo 2008069000 also comprises about 0.01% granule to about 10% weight.

19. according to the hair care kits of claim 15, wherein moisture Wo 2008069000 comprises by weight:

(a) about 1% to about 10% hard fat chemical compound is selected from spermol, stearyl alcohol, docosyl alcohol, and composition thereof;

(b) about 0.5% to about 3% amidoamines is selected from the amino propyl group dimethylamine of stearoyl, the amino ethyl diethylamine of stearoyl, and composition thereof;

(c) l-glutamic acid, its content make that the amidoamines and the mol ratio of acid are about 1: 0.5 to about 1: 0.9; And

(d) aqueous carrier.

20. according to the hair care kits of claim 14, wherein moisture Wo 2008069000 comprises by weight:

(b) about 0.1% to about 10% cation opsonizing agent;

(d) aqueous carrier.

21. according to the hair care kits of claim 20, wherein low melting point oil is unsaturated fatty alcohol.

22. according to the hair care kits of claim 20, wherein low melting point grease separation is certainly: (a) molecular weight is at least about 800 pentaerythritol ester oil, and it has following general formula:

R in the formula ¹, R ², R ³And R ⁴Independently for having 1 side chain, straight chain, saturated or unsaturated alkyl, aryl and alkaryl to about 30 carbon atoms;

(b) molecular weight is at least about 800 trihydroxy methyl ester oil, and it has following general formula:

R in the formula ¹¹Be to have 1 alkyl to about 30 carbon atoms, and R ¹², R ¹³And R ¹⁴Independently of one another for having 1 side chain, straight chain, saturated or unsaturated alkyl, aryl and alkaryl to about 30 carbon atoms;

(c) poly ﹠ Alpha ,-olefin oil, derived from having the about 6 1-olefinic monomers to about 16 carbon atoms, this poly alpha olefin oil viscosity is about 1 to about 35,000cst, molecular weight are about 200 to about 60,000, and poly-dispersion is no more than about 3;

(d) molecular weight is at least about 500 citric acid ester oil, and it has following general formula:

R in the formula ²¹Be OH or CH ₃COO, and R ²², R ²³And R ²⁴Independently for having 1 side chain, straight chain, saturated or undersaturated alkyl, aryl and alkaryl to about 30 carbon atoms;

(e) molecular weight is at least about 500 glyceride oil, and it has following general formula:

R in the formula ⁴¹, R ⁴²And R ⁴³Independently for having 1 side chain, straight chain, saturated or unsaturated alkyl, aryl and alkaryl to about 30 carbon atoms;

And composition thereof.

23. according to the hair care kits of claim 20, wherein moisture Wo 2008069000 also comprises about 0.1% Polyethylene Glycol with following general formula to about 10% weight:

H(OCH ₂CH ₂) _n-OH

The meansigma methods of n is 2,000 to 14,000 in the formula.

24. according to the hair care kits of claim 20, wherein moisture Wo 2008069000 also comprises about 0.01% granule to about 10% weight.

25. hair care kits comprises:

(i) Haircare composition;

(iii) reactant;

Wherein Haircare composition, heat generating agent and living hot auxiliary agent separate separately.

26. according to the hair care kits of claim 25, wherein Haircare composition, heat generating agent and reactant are packed into and had in the same container of three compartments, Haircare composition is packed in first compartment, and heat generating agent is packed in second compartment, and reactant is packed in the 3rd compartment.

27. according to the hair care kits of claim 26, wherein second compartment and the 3rd compartment are with separating by broken spacing body.

28. according to the hair care kits of claim 26, wherein second compartment and the 3rd compartment are with being spaced from each other by broken spacing body, second compartment or the 3rd compartment are arranged to second compartment and are surrounded by the 3rd compartment.

29. according to the hair care kits of claim 26, wherein second compartment and the 3rd compartment are with being spaced from each other by broken spacing body, second compartment and the 3rd compartment are arranged to the 3rd compartment and are surrounded by second compartment.

30. according to the hair care kits of claim 25, wherein between first compartment and the second and the 3rd compartment with can not be broken but the spacing body that conducts heat separate.

31. hair care kits according to claim 25, wherein ferrous, the ferric chloride of mixture, calcium oxide, magnesium oxide, magnesium sulfate, calcium chloride, magnesium, magnesium chloride, the dichloride of heat generating agent chosen from Fe and activated carbon and muriatic mixture, ferrum and potassium persulphate, zeolite, polyhydric alcohol, supercool liquid, and composition thereof.

32. according to the hair care kits of claim 31, wherein heat generating agent is dispersed in the inert carrier.

33. according to the hair care kits of claim 25, wherein reactant is selected from water, aqueous solution, Aquo-composition, and composition thereof.

34., further comprise the reaction controlling agent according to the hair care kits of claim 25.

35., further comprise heat-storing material according to the hair care kits of claim 25.

36., wherein before being coated to Haircare composition on the hair, heat generating agent is mixed with reactant according to the hair care kits of claim 25.

37. according to the hair care kits of claim 25, it is used for warming hair care compositions before being coated to Haircare composition on the hair.

38. according to the hair care kits of claim 25, wherein Haircare composition be heated to about 25 ℃ to about 80 ℃ temperature.

39. according to claim 25 hair care kits, wherein Wo 2008069000 is selected from hair shampoo compositions, hair setting composition, Wo 2008069000, hair dyeing composition, natural on-off cycles of hair growth compositions, and composition thereof.

40. according to the hair care kits of claim 39, wherein said Wo 2008069000 is a Wo 2008069000.

41. according to the hair care kits of claim 40, wherein Wo 2008069000 comprises by weight:

(a) about 0.1% to about 15% hard fat chemical compound;

(b) about 0.1% to about 10% amidoamines with following general formula:

R ¹CONH(CH ₂) _mN(R ²) ₂

(d) aqueous carrier.

42. according to the hair care kits of claim 41, wherein said Wo 2008069000 also comprises about 0.1% polysiloxane compound to about 10% weight.

43. according to the hair care kits of claim 41, wherein this Wo 2008069000 also comprises about 0.1% polypropylene glycol to about 10% weight.

44. according to the hair care kits of claim 41, wherein Wo 2008069000 also comprises about 0.01% granule to about 10% weight.

45. according to the hair care kits of claim 41, wherein Wo 2008069000 comprises by weight:

(d) aqueous carrier.

46. according to the hair care kits of claim 40, wherein said Haircare composition is a Wo 2008069000, by weight, it comprises:

(b) about 0.1% to about 10% cation opsonizing agent;

(d) aqueous carrier.

47. according to the hair care kits of claim 46, wherein low melting point oil is unsaturated fatty alcohol.

48. according to the hair care kits of claim 46, wherein this low melting point grease separation is certainly:

(a) molecular weight is at least about 800 pentaerythritol ester oil, and it has following general formula:

R in the formula ¹¹Be to have 1 alkyl to about 30 carbon atoms, and R ¹², R ¹³And R ¹⁴Independently for having 1 side chain, straight chain, saturated or unsaturated alkyl, aryl and alkaryl to about 30 carbon atoms;

R in the formula ²¹Be OH or CH ₃COO, and R ²², R ²³And R ²⁴Independently for having 1 side chain, straight chain, saturated or unsaturated alkyl, aryl and alkaryl to about 30 carbon atoms;

And composition thereof.

49. according to the hair care kits of claim 46, wherein said Wo 2008069000 also comprises about 0.1% Polyethylene Glycol with following general formula to about 10% weight:

H(OCH ₂CH ₂) _n-OH

The meansigma methods of n is 2,000 to 14,000 in the formula.

50. according to the hair care kits of claim 46, wherein said Wo 2008069000 also comprises about 0.01% granule to about 10% weight.

51. heater is used for warming hair care compositions, this device comprises heating source.

52. according to the heater of claim 51, also comprise cover this heating source can not be broken but the layer that conducts heat.

53. according to the heater of claim 51, wherein the shape of heater is the container shapes of suitable splendid attire Haircare composition.

54. according to the heater of claim 51, wherein heater is used for before being coated to Haircare composition on the hair Haircare composition being heated.

55. according to the heater of claim 51, wherein the shape of heater is the suitable shape that covers hair.

56. according to the heater of claim 55, wherein the shape of heater is a hat-shaped.

57. according to the heater of claim 51, wherein this heater after being used for being coated to Haircare composition on the hair heats Haircare composition.

58. according to the heater of claim 51, wherein Haircare composition is selected from hair shampoo compositions, hair setting composition, Wo 2008069000, hair dyeing composition, natural on-off cycles of hair growth compositions, and composition thereof.

59. according to the heater of claim 51, wherein Haircare composition be heated to about 25 ℃ to about 80 ℃ temperature.

60. according to the heater of claim 51, wherein heating source is selected from:

(i) heat generating agent and reactant, wherein heat generating agent is by producing heat with reaction reaction, and wherein heat generating agent separates with reactant;

(ii) heat-storing material;

(iii) resistive heating system;

(iv) electromagnetically induced heating system; And

(v) its mixed form.

61. heater according to claim 60, wherein heating source comprises heat generating agent and reactant, heating source also comprises first compartment that this heat generating agent wherein is housed and second compartment that this reactant wherein is housed, and this first and second compartment is with separating by broken spacing body.

62. according to the heater of claim 61, wherein first compartment and second compartment are with being spaced from each other by broken spacing body, first compartment is arranged to by first compartment and second compartment or second compartment is surrounded by another compartment.

63. heater according to claim 60, wherein ferrous, the ferric chloride of mixture, calcium oxide, magnesium oxide, magnesium sulfate, calcium chloride, magnesium, magnesium chloride, the dichloride of heat generating agent chosen from Fe and activated carbon and muriatic mixture, ferrum and potassium persulphate, zeolite, polyhydric alcohol, supercool liquid, and composition thereof.

64. according to the heater of claim 63, wherein heat generating agent is dispersed in the inert carrier.

65. according to the heater of claim 60, wherein reactant is selected from water, aqueous solution, Aquo-composition, and composition thereof.

66. according to the heater of claim 60, wherein heating source comprises heat generating agent and reactant, and comprises the reaction controlling agent.

67. according to the heater of claim 60, wherein heat-storing material is selected from silica gel, carboxymethyl cellulose gel, phase-change material, and composition thereof.

68. according to the heater of claim 60, wherein resistive heating system is selected from nickel filament, pottery, conducting polymer, and mixed form.