CN116285456A - Printable lettering film and preparation method thereof - Google Patents

Printable lettering film and preparation method thereof Download PDF

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Publication number
CN116285456A
CN116285456A CN202310214920.2A CN202310214920A CN116285456A CN 116285456 A CN116285456 A CN 116285456A CN 202310214920 A CN202310214920 A CN 202310214920A CN 116285456 A CN116285456 A CN 116285456A
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ink
layer
water
parts
raw material
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CN202310214920.2A
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CN116285456B (en
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艾敏
贺升
蒋鑫浩
谭心玮
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Hunan Sijiu Technology Co ltd
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Hunan Sijiu Technology Co ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
    • C09D129/02—Homopolymers or copolymers of unsaturated alcohols
    • C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)

Abstract

The application relates to a printable lettering film and a preparation method thereof. The printing ink has the advantages that the cationic polymer, the aluminum oxide and the like in the ink fixing layer form a micropore structure, the dye molecules are fixed, the water resistance of the coating is improved, the silicon dioxide in the ink absorbing layer absorbs the solvent in dye ink, excellent printing effect and drying speed are provided, and the lettering film has the characteristics of clear patterns, high color saturation, high drying speed, strong water washing resistance and the like through the structural arrangement of the sequentially laminated wear-resisting layer, the adhesive layer, the ink absorbing layer and the ink fixing layer.

Description

Printable lettering film and preparation method thereof
Technical Field
The invention relates to the technical field of thermal transfer materials, in particular to a printable lettering film and a preparation method thereof.
Background
With the continuous development of the color inkjet printer market, important consumables capable of printing lettering films are becoming more and more important. The coating technology is the core of the printable lettering film, the quality of the lettering film is directly determined, and the research level of the printable lettering film is marked by the research level of the coating technology, so that the research of the ink-absorbing coating technology of the printable lettering film is particularly important.
The production processes and formulations of ink-receptive coatings for traditional printable lettering films are very diverse and can be basically divided into two types: swelling type and gap type. The swelling type ink-absorbing layer is mainly made of resin (such as gelatin and polyvinyl alcohol), after ink drops are received on the surface of the coating layer, the surface of the coating layer is slightly swelled to form a network, the ink drops are absorbed, the water resistance of the ink-absorbing coating layer is poor, the drying speed after printing is very slow, although the water resistance can be improved by modifying a cross-linking agent, the ink absorption is reduced, namely, the ink absorption and the water resistance are contradictory, so that the type of ink-jet printing can not meet the printing requirement of high quality. The gap type ink-absorbing layer is mainly made of pigment (such as alumina, silica, titanium dioxide, porcelain clay, calcium carbonate, bentonite and the like), the coating contains a network of a large number of gap micropores, the network has adsorption and fixation effects on ink drops, the printing effect and the color saturation are both due to swelling type, but the gap type has poor water resistance due to a micropore structure. Therefore, developing a printable lettering film with high definition, good color saturation, fast drying speed and good water resistance after printing has become a market development direction.
Disclosure of Invention
Based on the above, it is necessary to provide a printable lettering film having a clear print pattern, high color saturation, high ink drying speed, and high water washing resistance.
A printable lettering film comprises a wear-resistant layer, an adhesive layer, an ink absorbing layer and an ink fixing layer which are sequentially laminated;
the ink absorbing layer comprises the following raw materials in parts by weight:
Figure BDA0004114553110000021
the ink fixing layer comprises the following raw materials in parts by weight:
Figure BDA0004114553110000022
Figure BDA0004114553110000031
in one embodiment, the silica is microcrystalline silica, precipitated silica, fumed silica, or silicic acid gel.
In one embodiment, the aluminum oxide is activated aluminum oxide, cationic aluminum oxide, nano aluminum oxide, high pore aluminum oxide, or aluminum oxide gel.
In one embodiment, the cationic polymer in the ink absorbing layer raw material is polyvinyl amine, polyethyleneimine, polydimethyldiallyl ammonium chloride, quaternary ammonium salt cationic fixing agent or polyvinyl benzyl trimethylamine chloride; the cationic polymer in the ink fixing layer raw material is polyvinyl amine, polyethyleneimine, polydimethyl diallyl ammonium chloride, quaternary ammonium salt cationic color fixing agent or polyvinyl benzyl trimethylamine chloride.
In one embodiment, the surfactant in the ink absorbing layer raw material is oleic acid diethanolamide, cetyltrimethylammonium chloride, dodecyl dimethyl betaine or sodium dodecyl diphenyl ether disulfonate; the surfactant in the ink fixing layer raw material is oleic acid diethanolamide, cetyl trimethyl ammonium chloride, dodecyl dimethyl betaine or sodium dodecyl diphenyl ether disulfonate.
In one embodiment, the water repellent agent in the ink absorbing layer raw material is ammonium zirconium carbonate, polyamide polyurea resin, urea resin, melamine formaldehyde resin, modified glyoxal or formaldehyde; the water repellent agent in the ink fixing layer raw material is zirconium ammonium carbonate, polyamide polyurea resin, urea formaldehyde resin, melamine formaldehyde resin, modified glyoxal or formaldehyde.
In addition, the application also provides a preparation method of the printable lettering film, which comprises the following specific scheme:
the preparation method of the printable lettering film, which comprises the following steps:
providing a wear-resistant layer and an adhesive layer which are sequentially laminated;
providing the ink absorbing layer raw material and the ink fixing layer raw material;
uniformly mixing the raw materials of the ink absorption layer, then coating the raw materials on the surface of the adhesion layer far away from the wear-resistant layer, and drying to obtain the wear-resistant layer, the adhesion layer and the ink absorption layer which are sequentially laminated;
and uniformly mixing the raw materials of the ink fixing layer, then coating the raw materials on the surface of the ink absorbing layer, which is far away from the adhesive layer, and drying to obtain the wear-resisting layer, the adhesive layer, the ink absorbing layer and the ink fixing layer which are sequentially laminated.
In one embodiment, the step of uniformly mixing the raw materials of the ink absorbing layer specifically includes: mixing the dispersing agent, the wetting agent, the surfactant and the deionized water in the raw materials of the ink absorbing layer, stirring for 2-3 min at the speed of 300-500 r/min, adding the water-based acrylic ester and the water-based polyurethane, stirring for 5-10 min at the speed of 500-800 r/min, adding the silicon dioxide and the coupling agent, stirring for 20-30 min at the speed of 1200-1600 r/min, adding the cationic polymer, the water-insoluble plasticizer and the water-insoluble antioxidant, stirring for 5-10 min at the speed of 500-800 r/min, finally adding the water-resistant agent, and stirring for 3-5 min at the speed of 300-500 r/min.
In one embodiment, the step of uniformly mixing the ink fixing layer raw materials specifically includes: mixing the dispersing agent, the wetting agent, the surfactant and the deionized water in the ink fixing layer raw material, stirring for 2-3 min at the speed of 300-500 r/min, adding the vinyl modified polyvinyl alcohol and the cationic styrene-acrylic emulsion, stirring for 5-10 min at the speed of 500-800 r/min, adding the aluminum oxide and the coupling agent, stirring for 20-30 min at the speed of 1200-1600 r/min, adding the cationic polymer, the water-insoluble plasticizer and the water-insoluble antioxidant, stirring for 5-10 min at the speed of 500-800 r/min, finally adding the water-resistant agent, and stirring for 3-5 min at the speed of 300-500 r/min.
In one embodiment, the coating thickness of the ink absorbing layer raw material is 60-120 μm; the coating thickness of the ink fixing layer raw material is 20-80 mu m.
According to the printable lettering film, the solid fillers such as aluminum oxide in the ink fixing layer form a micropore structure, meanwhile, the anionic dye is fixed under the action of the cationic color fixing agent and other additives, the water resistance of the coating is improved while the excellent printing effect is provided, the silicon dioxide in the ink absorbing layer absorbs the solvent in dye ink, higher color saturation and drying speed are provided, and the lettering film has the characteristics of clear pattern, high color saturation, high drying speed, strong water washing resistance and the like through the structural arrangement of the sequentially laminated wear-resisting layer, the adhesive layer, the ink absorbing layer and the ink fixing layer.
Detailed Description
The present invention will be described more fully hereinafter in order to facilitate an understanding of the present invention, and preferred embodiments of the present invention are set forth. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used herein in the description of the invention is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. The term "and/or" as used herein includes any and all combinations of one or more of the associated listed items.
The printable lettering film of an embodiment comprises a wear-resistant layer, an adhesive layer, an ink absorbing layer and an ink fixing layer which are sequentially laminated.
The ink absorbing layer is prepared from the following raw materials: 20-25 parts by mass of aqueous acrylic ester, 20-25 parts by mass of aqueous polyurethane, 15-25 parts by mass of silicon dioxide, 1-5 parts by mass of cationic polymer, 10-15 parts by mass of deionized water, 1-3 parts by mass of water-insoluble plasticizer, 1-3 parts by mass of water-insoluble antioxidant, 1-2 parts by mass of dispersing agent, 1-2 parts by mass of wetting agent, 1-2 parts by mass of surfactant, 1-2 parts by mass of coupling agent and 1-2 parts by mass of water-repellent agent.
Further, the silica in the ink absorbing layer raw material is microcrystalline silica, precipitated silica, fumed silica or silicic acid gel.
Further, the cationic polymer in the ink absorbing layer raw material is polyvinyl amine, polyethyleneimine, polydimethyl diallyl ammonium chloride, quaternary ammonium salt cationic color fixing agent or polyvinyl benzyl trimethylamine chloride.
Further, the surfactant in the ink absorbing layer raw material is oleic acid diethanolamide, cetyltrimethylammonium chloride, dodecyl dimethyl betaine or sodium dodecyl diphenyl ether disulfonate.
Further, the water repellent agent in the raw material of the ink absorbing layer is zirconium ammonium carbonate, polyamide polyurea resin, urea formaldehyde resin, melamine formaldehyde resin, modified glyoxal or formaldehyde.
In the ink-absorbing layer raw material, the aqueous acrylic ester and the aqueous polyurethane can form a copolymer, good printing quality is provided, the silicon dioxide can absorb a solvent in dye ink, good printing effect and drying speed are provided, the cationic polymer can form a micropore structure and can form a water-insoluble complex with anionic dye ink, dye molecules are fixed, the water-insoluble plasticizer and the water-insoluble antioxidant can improve the weather resistance of the coating, one end of the coupling agent is connected with the silicon dioxide, the other end of the coupling agent is in chemical reaction or physical winding with an organic group, the firmness of the silicon dioxide is enhanced, the washing fastness of the silicon dioxide is enhanced, the water-resisting agent can enhance the washing resistance of the coating, and the raw materials cooperate, so that the ink-absorbing layer has good quick-drying effect and printing quality.
The ink fixing layer is prepared from the following raw materials: 20 to 30 parts by mass of vinyl modified polyvinyl alcohol, 15 to 25 parts by mass of cationic styrene-acrylic emulsion, 10 to 15 parts by mass of aluminum oxide, 1 to 5 parts by mass of cationic polymer, 10 to 15 parts by mass of deionized water, 1 to 3 parts by mass of water-insoluble plasticizer, 1 to 3 parts by mass of water-insoluble antioxidant, 1 to 2 parts by mass of dispersing agent, 1 to 2 parts by mass of wetting agent, 1 to 2 parts by mass of surfactant, 1 to 2 parts by mass of coupling agent and 1 to 5 parts by mass of water-repellent agent.
Further, the aluminum oxide is active aluminum oxide, cationic aluminum oxide, nano aluminum oxide, high-pore aluminum oxide or aluminum oxide gel.
Further, the cationic polymer is polyvinyl amine, polyethyleneimine, polydimethyldiallyl ammonium chloride, a high-polymerization-degree polyamine cationic color fixing agent or polyvinyl benzyl trimethylamine chloride.
Further, the surfactant is diethanolamide oleate, cetyltrimethylammonium chloride, dodecyl dimethyl betaine or sodium dodecyl diphenyl ether disulfonate.
Further, the water repellent agent is zirconium ammonium carbonate, polyamide polyurea resin, urea resin, melamine formaldehyde resin, modified glyoxal or formaldehyde.
In the raw materials of the ink fixing layer, the vinyl modified polyvinyl alcohol and the cationic propyl benzene emulsion can form a copolymer to provide excellent water resistance, the aluminum oxide has strong positive charges, dye molecules can be firmly adsorbed, the cationic polymer can form a water-insoluble complex with anionic dye ink, the water-insoluble plasticizer and the water-insoluble antioxidant can improve the weather resistance of the coating, the coupling agent can connect the dye molecules with the aluminum oxide, so that the dye is adsorbed on the aluminum oxide, the water-resistant agent can enhance the water washing resistance of the coating, and the raw materials cooperate to ensure that the ink fixing layer has excellent water resistance.
The dispersing agent in the ink-absorbing layer raw material and the ink-fixing layer raw material may be dispersing agents conventionally used in the art, and in this embodiment, the dispersing agent in the ink-absorbing layer raw material and the ink-fixing layer raw material is a non-silicon dispersing agent.
The wetting agent in the ink-absorbing layer raw material and the ink-fixing layer raw material can be wetting agents conventionally used in the field, and in the embodiment, the wetting agents in the ink-absorbing layer raw material and the ink-fixing layer raw material are sodium diisooctyl succinate.
The coupling agent in the ink-absorbing layer raw material and the ink-fixing layer raw material may be a coupling agent conventionally used in the art, and in this embodiment, the coupling agent in the ink-absorbing layer raw material and the ink-fixing layer raw material is an aluminum-zirconium coupling agent.
The water-insoluble plasticizer in the ink-absorbing layer raw material and the ink-fixing layer raw material may be water-insoluble plasticizers conventionally used in the art, and in the present embodiment, the water-insoluble plasticizer in the ink-absorbing layer raw material and the ink-fixing layer raw material is acetylated glyceride.
The water-insoluble antioxidants in the ink-absorbing layer raw material and the ink-fixing layer raw material may be water-insoluble antioxidants conventionally used in the art, and in the present embodiment, the water-insoluble antioxidants in the ink-absorbing layer raw material and the ink-fixing layer raw material are BASF (BASF) antioxidant B900.
In addition, the abrasion-resistant layer is an abrasion-resistant layer conventionally used in the art such as a PET (polyethylene terephthalate) layer or the like, and the adhesive layer is an adhesive layer conventionally used in the art such as a TPU (thermoplastic polyurethane) layer or the like.
The thickness of the PET layer and TPU layer are conventional in the art, in this embodiment, the thickness of the PET layer is 1mm and the thickness of the TPU layer is 50um.
The printable lettering film has the advantages of clear printed patterns, high color saturation, high ink drying speed, strong water washing resistance and the like, has a wide application range, and can be used on a large scale.
The preparation method of the printable lettering film in one embodiment comprises the following steps S110 to S140:
and S110, providing a wear-resistant layer and an adhesive layer which are sequentially laminated.
In this embodiment, the abrasion-resistant layer and the adhesive layer are laminated in this order to realize a structural arrangement in which the abrasion-resistant layer and the adhesive layer are laminated in this order.
Further, the wear-resistant layer is a PET layer, and the adhesive layer is a TPU layer.
S120, providing ink absorbing layer raw materials and ink fixing layer raw materials.
In this embodiment, the ink-absorbing layer raw material composition is as follows: 20-25 parts by mass of aqueous acrylic ester, 20-25 parts by mass of aqueous polyurethane, 15-25 parts by mass of silicon dioxide, 1-5 parts by mass of cationic polymer, 10-15 parts by mass of deionized water, 1-3 parts by mass of water-insoluble plasticizer, 1-3 parts by mass of water-insoluble antioxidant, 1-2 parts by mass of dispersing agent, 1-2 parts by mass of wetting agent, 1-2 parts by mass of surfactant, 1-2 parts by mass of coupling agent and 1-2 parts by mass of water-repellent agent.
The ink fixing layer comprises the following raw materials: 20 to 30 parts by mass of vinyl modified polyvinyl alcohol, 15 to 25 parts by mass of cationic styrene-acrylic emulsion, 10 to 15 parts by mass of aluminum oxide, 1 to 5 parts by mass of cationic polymer, 10 to 15 parts by mass of deionized water, 1 to 3 parts by mass of water-insoluble plasticizer, 1 to 3 parts by mass of water-insoluble antioxidant, 1 to 2 parts by mass of dispersing agent, 1 to 2 parts by mass of wetting agent, 1 to 2 parts by mass of surfactant, 1 to 2 parts by mass of coupling agent and 1 to 5 parts by mass of water-repellent agent.
It should be noted that, steps S110 and S120 are only for convenience of description, and are not meant to limit the sequence of the two steps, and the two steps may be performed simultaneously or sequentially.
And S130, uniformly mixing the raw materials of the ink absorbing layer, then coating the raw materials on the surface of the adhesive layer, which is far away from the wear-resistant layer, and drying to obtain the wear-resistant layer, the adhesive layer and the ink absorbing layer which are sequentially laminated.
In this embodiment, the step of uniformly mixing the raw materials of the ink-absorbing layer specifically includes: mixing the dispersing agent, the wetting agent, the surfactant and the deionized water in the raw materials of the ink absorbing layer, stirring for 2-3 min at the speed of 300-500 r/min, adding the water-based acrylic ester and the water-based polyurethane, stirring for 5-10 min at the speed of 500-800 r/min, adding the silicon dioxide and the coupling agent, stirring for 20-30 min at the speed of 1200-1600 r/min, adding the cationic polymer, the water-insoluble plasticizer and the water-insoluble antioxidant, stirring for 5-10 min at the speed of 500-800 r/min, finally adding the water-resistant agent, and stirring for 3-5 min at the speed of 300-500 r/min.
Furthermore, the coating thickness of the ink absorbing layer raw material is more than or equal to 60 mu m.
Further, the temperature of the drying in the step S130 is 60-100 ℃ and the time is about 20 min.
And S140, uniformly mixing the raw materials of the ink fixing layer, then coating the raw materials on the surface of the ink absorbing layer, which is far away from the adhesive layer, and drying to obtain the wear-resisting layer, the adhesive layer, the ink absorbing layer and the ink fixing layer which are sequentially laminated, thus printing the lettering film.
In this embodiment, the step of uniformly mixing the raw materials of the ink fixing layer specifically includes: the step of uniformly mixing the raw materials of the ink fixing layer comprises the following steps: mixing the dispersing agent, the wetting agent, the surfactant and the deionized water in the ink fixing layer raw material, stirring for 2-3 min at the speed of 300-500 r/min, adding the vinyl modified polyvinyl alcohol and the cationic styrene-acrylic emulsion, stirring for 5-10 min at the speed of 500-800 r/min, adding the aluminum oxide and the coupling agent, stirring for 20-30 min at the speed of 1200-1600 r/min, adding the cationic polymer, the water-insoluble plasticizer and the water-insoluble antioxidant, stirring for 5-10 min at the speed of 500-800 r/min, finally adding the water-resistant agent, and stirring for 3-5 min at the speed of 300-500 r/min.
Further, the coating thickness of the ink fixing layer raw material is 20-80 μm.
Further, the temperature of the drying in the step S140 is 60-100 ℃ and the time is about 20 min.
The preparation method of the printable lettering film is simple and controllable, and the prepared printable lettering film has the advantages of clear printing patterns, high color saturation, high ink drying speed, strong water washing resistance and the like.
The following are specific examples.
Example 1
The ink absorbing layer comprises the following raw materials: 20 parts of aqueous acrylic ester, 20 parts of aqueous polyurethane, 15 parts of silicon dioxide, 1 part of cationic polymer, 10 parts of deionized water, 1 part of water-insoluble plasticizer, 1 part of water-insoluble antioxidant, 1 part of dispersing agent, 1 part of wetting agent, 1 part of surfactant, 1 part of coupling agent and 1 part of water repellent agent.
The ink fixing layer comprises the following raw materials: 20 parts of vinyl modified polyvinyl alcohol, 15 parts of cationic styrene-acrylic emulsion, 10 parts of aluminum oxide, 1 part of cationic polymer, 10 parts of deionized water, 1 part of water-insoluble plasticizer, 1 part of water-insoluble antioxidant, 1 part of dispersing agent, 1 part of wetting agent, 1 part of surfactant, 1 part of coupling agent and 1 part of water repellent agent.
The preparation method adopts the preparation method as in the steps S110 to S140.
The printable lettering film prepared in the embodiment 1 has the advantages of clear printing pattern, high color saturation, high ink drying speed, strong water washing resistance and the like through detection.
Example 2
The ink absorbing layer comprises the following raw materials: 25 parts of water-based acrylic ester, 25 parts of water-based polyurethane, 25 parts of silicon dioxide, 5 parts of cationic polymer, 15 parts of deionized water, 3 parts of water-insoluble plasticizer, 3 parts of water-insoluble antioxidant, 2 parts of dispersing agent, 2 parts of wetting agent, 2 parts of surfactant, 2 parts of coupling agent and 2 parts of water repellent agent.
The ink fixing layer comprises the following raw materials: 30 parts of vinyl modified polyvinyl alcohol, 25 parts of cationic styrene-acrylic emulsion, 15 parts of aluminum oxide, 5 parts of cationic polymer, 15 parts of deionized water, 3 parts of water-insoluble plasticizer, 3 parts of water-insoluble antioxidant, 2 parts of dispersing agent, 2 parts of wetting agent, 2 parts of surfactant, 2 parts of coupling agent and 5 parts of water repellent agent.
The preparation method adopts the preparation method as in the steps S110 to S140.
The printable lettering film prepared in the embodiment 2 has the advantages of clear printing pattern, high color saturation, high ink drying speed, strong water washing resistance and the like through detection.
Example 3
The ink absorbing layer comprises the following raw materials: 23 parts of aqueous acrylic ester, 23 parts of aqueous polyurethane, 20 parts of silicon dioxide, 3 parts of cationic polymer, 13 parts of deionized water, 2 parts of water-insoluble plasticizer, 2 parts of water-insoluble antioxidant, 1.5 parts of dispersing agent, 1.5 parts of wetting agent, 1.5 parts of surfactant, 1.5 parts of coupling agent and 1.5 parts of water repellent agent.
The ink fixing layer comprises the following raw materials: 25 parts of vinyl modified polyvinyl alcohol, 20 parts of cationic styrene-acrylic emulsion, 13 parts of aluminum oxide, 2.5 parts of cationic polymer, 12.5 parts of deionized water, 2 parts of water-insoluble plasticizer, 2 parts of water-insoluble antioxidant, 1.5 parts of dispersing agent, 1.5 parts of wetting agent, 1.5 parts of surfactant, 1.5 parts of coupling agent and 2.5 parts of water repellent agent.
The preparation method adopts the preparation method as in the steps S110 to S140.
The printable lettering film prepared in the embodiment 3 has the advantages of clear printing pattern, high color saturation, high ink drying speed, strong water washing resistance and the like.
Comparative example 1
The ink absorbing layer comprises the following raw materials: 18 parts of aqueous acrylic ester, 18 parts of aqueous polyurethane, 13 parts of silicon dioxide, 0.8 part of cationic polymer, 8 parts of deionized water, 0.8 part of water-insoluble plasticizer, 0.8 part of water-insoluble antioxidant, 0.8 part of dispersing agent, 0.8 part of wetting agent, 0.8 part of surfactant, 0.8 part of coupling agent and 0.8 part of water repellent agent.
The ink fixing layer comprises the following raw materials: 18 parts of vinyl modified polyvinyl alcohol, 13 parts of cationic styrene-acrylic emulsion, 8 parts of aluminum oxide, 0.8 part of cationic polymer, 8 parts of deionized water, 0.8 part of water-insoluble plasticizer, 0.8 part of water-insoluble antioxidant, 0.8 part of dispersing agent, 0.8 part of wetting agent, 0.8 part of surfactant, 0.8 part of coupling agent and 0.8 part of water-resistant agent.
The preparation method adopts the preparation method as in the steps S110 to S140.
Through detection, the printable lettering film prepared in the comparative example 1 has the defects that the adhesive force between the ink absorbing layer and the adhesive layer is insufficient due to the too low resin content of the ink absorbing layer, the ink absorbing layer is easy to fall off in the washing process, the ink fixing layer has poor waterproof performance and uneven hole rate due to the too small proportion of raw materials.
Comparative example 2
The ink absorbing layer comprises the following raw materials: 30 parts of aqueous acrylic ester, 30 parts of aqueous polyurethane, 28 parts of silicon dioxide, 6 parts of cationic polymer, 17 parts of deionized water, 4 parts of water-insoluble plasticizer, 4 parts of water-insoluble antioxidant, 2.3 parts of dispersing agent, 2.3 parts of wetting agent, 2.3 parts of surfactant, 2.3 parts of coupling agent and 2.3 parts of water repellent agent.
The ink fixing layer comprises the following raw materials: 33 parts of vinyl modified polyvinyl alcohol, 28 parts of cationic styrene-acrylic emulsion, 16 parts of aluminum oxide, 6 parts of cationic polymer, 20 parts of deionized water, 4 parts of water-insoluble plasticizer, 4 parts of water-insoluble antioxidant, 2.3 parts of dispersing agent, 2.3 parts of wetting agent, 2.3 parts of surfactant, 2.3 parts of coupling agent and 6 parts of water repellent.
The preparation method adopts the preparation method as in the steps S110 to S140.
Through detection, the printable lettering film prepared in the comparative example 2 has the advantages that the printing definition can be greatly reduced due to the fact that the proportion of the raw materials of the ink absorption layer is too large, the viscosity of the system is too high, the workability is poor, and the printing color rendering degree can be affected due to the fact that the proportion of the raw materials of the ink fixing layer is too large.
The foregoing examples illustrate only a few embodiments of the invention and are described in detail herein without thereby limiting the scope of the invention. It should be noted that it will be apparent to those skilled in the art that several variations and modifications can be made without departing from the spirit of the invention, which are all within the scope of the invention. Accordingly, the scope of protection of the present invention is to be determined by the appended claims.

Claims (10)

1. The printable lettering film is characterized by comprising a wear-resistant layer, an adhesive layer, an ink absorbing layer and an ink fixing layer which are sequentially laminated;
the ink absorbing layer comprises the following raw materials in parts by weight:
Figure FDA0004114553100000011
the ink fixing layer comprises the following raw materials in parts by weight:
Figure FDA0004114553100000012
Figure FDA0004114553100000021
2. the printable lettering film according to claim 1, wherein said silica is microcrystalline silica, precipitated silica, fumed silica or silicic acid gel.
3. The printable lettering film according to claim 1, wherein said aluminium oxide is activated aluminium oxide, cationic aluminium oxide, nano aluminium oxide, highly porous aluminium oxide or aluminium oxide gel.
4. The printable lettering film according to claim 1, wherein the cationic polymer in the ink-absorbing layer raw material is polyvinyl amine, polyethylenimine, polydimethyldiallyl ammonium chloride, quaternary ammonium salt type cationic fixing agent or polyvinyl benzyl trimethylamine chloride; the cationic polymer in the ink fixing layer raw material is polyvinyl amine, polyethyleneimine, polydimethyl diallyl ammonium chloride, quaternary ammonium salt cationic color fixing agent or polyvinyl benzyl trimethylamine chloride.
5. The printable lettering film according to claim 1, wherein the surfactant in the ink absorbing layer raw material is diethanolamide oleate, cetyltrimethylammonium chloride, dodecyl dimethyl betaine or sodium dodecyl diphenyl ether disulfonate; the surfactant in the ink fixing layer raw material is oleic acid diethanolamide, cetyl trimethyl ammonium chloride, dodecyl dimethyl betaine or sodium dodecyl diphenyl ether disulfonate.
6. The printable lettering film according to claim 1, wherein the water-repellent agent in the ink-absorbing layer raw material is zirconium ammonium carbonate, polyamide polyurea resin, urea resin, melamine formaldehyde resin, modified glyoxal or formaldehyde; the water repellent agent in the ink fixing layer raw material is zirconium ammonium carbonate, polyamide polyurea resin, urea formaldehyde resin, melamine formaldehyde resin, modified glyoxal or formaldehyde.
7. A method of producing a printable lettering film according to any one of claims 1 to 6, comprising the steps of:
providing a wear-resistant layer and an adhesive layer which are sequentially laminated;
providing the ink absorbing layer raw material and the ink fixing layer raw material;
uniformly mixing the raw materials of the ink absorption layer, then coating the raw materials on the surface of the adhesion layer far away from the wear-resistant layer, and drying to obtain the wear-resistant layer, the adhesion layer and the ink absorption layer which are sequentially laminated;
and uniformly mixing the raw materials of the ink fixing layer, then coating the raw materials on the surface of the ink absorbing layer, which is far away from the adhesive layer, and drying to obtain the wear-resisting layer, the adhesive layer, the ink absorbing layer and the ink fixing layer which are sequentially laminated.
8. The method for preparing a printable lettering film according to claim 7, wherein the step of uniformly mixing the raw materials of the ink-absorbing layer is specifically as follows: mixing the dispersing agent, the wetting agent, the surfactant and the deionized water in the raw materials of the ink absorbing layer, stirring for 2-3 min at the speed of 300-500 r/min, adding the water-based acrylic ester and the water-based polyurethane, stirring for 5-10 min at the speed of 500-800 r/min, adding the silicon dioxide and the coupling agent, stirring for 20-30 min at the speed of 1200-1600 r/min, adding the cationic polymer, the water-insoluble plasticizer and the water-insoluble antioxidant, stirring for 5-10 min at the speed of 500-800 r/min, finally adding the water-resistant agent, and stirring for 3-5 min at the speed of 300-500 r/min.
9. The method for preparing a printable lettering film according to claim 7, wherein the step of uniformly mixing the raw materials of the ink fixing layer is specifically as follows: mixing the dispersing agent, the wetting agent, the surfactant and the deionized water in the ink fixing layer raw material, stirring for 2-3 min at the speed of 300-500 r/min, adding the vinyl modified polyvinyl alcohol and the cationic styrene-acrylic emulsion, stirring for 5-10 min at the speed of 500-800 r/min, adding the aluminum oxide and the coupling agent, stirring for 20-30 min at the speed of 1200-1600 r/min, adding the cationic polymer, the water-insoluble plasticizer and the water-insoluble antioxidant, stirring for 5-10 min at the speed of 500-800 r/min, finally adding the water-resistant agent, and stirring for 3-5 min at the speed of 300-500 r/min.
10. The method for producing a printable lettering film according to claim 7, wherein the ink absorbing layer raw material is applied in a thickness of 60 μm to 120 μm; the coating thickness of the ink fixing layer raw material is 20-80 mu m.
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Citations (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1119989A (en) * 1994-02-24 1996-04-10 佳能株式会社 Printing medium, production process thereof, and ink jet printing method using the same
EP0819546A1 (en) * 1996-07-18 1998-01-21 Canon Kabushiki Kaisha Recording medium, and ink-jet printing process and image forming process using the same
KR20000007698A (en) * 1998-07-06 2000-02-07 차동천 Film for ink jet printer having its light resistance improved
CN1593935A (en) * 2004-06-30 2005-03-16 乐凯集团第二胶片厂 Ink-ejecting acceptance material and back jetting lamp house sheet using the same
US20060205840A1 (en) * 2005-03-14 2006-09-14 Konica Minolta Holdings, Inc. Ink-jet ink and ink jet recording method
CN1970308A (en) * 2006-11-30 2007-05-30 中国乐凯胶片集团公司 Front-spraying film for water-proof ink jetting
WO2008035797A1 (en) * 2006-09-19 2008-03-27 Ricoh Company, Ltd. Ink, ink cartridge, ink jet recording apparatus, and ink jet recording method
CA2671327A1 (en) * 2006-12-01 2008-06-12 Avery Dennison Corporation Ink-receptive coating composition
CN101875253A (en) * 2009-04-28 2010-11-03 大连路明发光科技股份有限公司 Water-proof self-luminous printing film
CN101879820A (en) * 2010-06-24 2010-11-10 中国乐凯胶片集团公司 Ink-jet recording material used for full-face spray light box film
CN101927631A (en) * 2010-06-03 2010-12-29 哈尔滨工业大学 Ink jet recording ink-absorption layer material and preparation method thereof
CN102092209A (en) * 2010-10-29 2011-06-15 哈尔滨工业大学 Ink-jet recording material and preparation method thereof as well as method for preparing ink absorption layer coating liquid
CN102909982A (en) * 2012-09-12 2013-02-06 浙江欧丽数码喷绘材料有限公司 Waterproof PP(propene polymer) synthesized paper for ink-jet printing and preparation method thereof
CN103395337A (en) * 2013-08-01 2013-11-20 江苏格美高科技发展有限公司 Water-borne matte water-proof ink jet canvas and preparation method thereof
CN104371411A (en) * 2014-11-21 2015-02-25 广东高璐美数码科技有限公司 Water-based color ink-jet printing medium and production method thereof
CN104936996A (en) * 2013-01-21 2015-09-23 日本合成化学工业株式会社 Silyl group-containing poly(vinyl alcohol)-based resin and use thereof
CN105415911A (en) * 2015-12-25 2016-03-23 天津美迪亚影像材料有限公司 Gold card for ink-jet printing
CN105693938A (en) * 2014-11-28 2016-06-22 合众（佛山）化工有限公司 Preparation method of imidized SMA modified cationic styrene-acrylic emulsion
WO2016178402A1 (en) * 2015-05-01 2016-11-10 富士フイルム株式会社 Method for manufacturing lenticular printed matter and lenticular printed matter
CN106555364A (en) * 2016-11-28 2017-04-05 江苏格美高科技发展有限公司 A kind of high glaze is water-fast printing paper and preparation method thereof
CN106758510A (en) * 2016-11-28 2017-05-31 江苏格美高科技发展有限公司 A kind of ink absorbing layer masking liquid of the water-fast printing paper of high glaze and preparation method thereof
CN210283660U (en) * 2019-05-17 2020-04-10 江苏天之印数码打印材料有限公司 High-gloss photographic paper for color ink-jet printing
CN113429625A (en) * 2021-07-08 2021-09-24 湖南肆玖科技有限公司 Liquid candle dye and preparation method thereof
CN113605138A (en) * 2021-08-16 2021-11-05 海南必凯水性新材料有限公司 Aqueous coating liquid for photographic paper, preparation method thereof and printing photographic paper
CN114426621A (en) * 2020-10-14 2022-05-03 中国石油化工股份有限公司 Nonionic modified polyvinyl alcohol and preparation method thereof
CN114671700A (en) * 2022-02-25 2022-06-28 广东省福美材料科学技术有限公司 Modified inorganic powder composite facing sheet with decorative pattern and preparation method thereof
CN114872471A (en) * 2022-05-17 2022-08-09 广东冠豪新材料研发有限公司 High-transparency thermosensitive recording material and preparation method thereof
CN114953801A (en) * 2022-06-15 2022-08-30 乐凯胶片股份有限公司 Ink-jet printing material and preparation method thereof
CN115522405A (en) * 2022-09-28 2022-12-27 广东冠豪高新技术股份有限公司 Thermal sublimation transfer printing paper coating and preparation method and application thereof

Patent Citations (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1119989A (en) * 1994-02-24 1996-04-10 佳能株式会社 Printing medium, production process thereof, and ink jet printing method using the same
EP0819546A1 (en) * 1996-07-18 1998-01-21 Canon Kabushiki Kaisha Recording medium, and ink-jet printing process and image forming process using the same
KR20000007698A (en) * 1998-07-06 2000-02-07 차동천 Film for ink jet printer having its light resistance improved
CN1593935A (en) * 2004-06-30 2005-03-16 乐凯集团第二胶片厂 Ink-ejecting acceptance material and back jetting lamp house sheet using the same
US20060205840A1 (en) * 2005-03-14 2006-09-14 Konica Minolta Holdings, Inc. Ink-jet ink and ink jet recording method
WO2008035797A1 (en) * 2006-09-19 2008-03-27 Ricoh Company, Ltd. Ink, ink cartridge, ink jet recording apparatus, and ink jet recording method
CN1970308A (en) * 2006-11-30 2007-05-30 中国乐凯胶片集团公司 Front-spraying film for water-proof ink jetting
CA2671327A1 (en) * 2006-12-01 2008-06-12 Avery Dennison Corporation Ink-receptive coating composition
CN101875253A (en) * 2009-04-28 2010-11-03 大连路明发光科技股份有限公司 Water-proof self-luminous printing film
CN101927631A (en) * 2010-06-03 2010-12-29 哈尔滨工业大学 Ink jet recording ink-absorption layer material and preparation method thereof
CN101879820A (en) * 2010-06-24 2010-11-10 中国乐凯胶片集团公司 Ink-jet recording material used for full-face spray light box film
CN102092209A (en) * 2010-10-29 2011-06-15 哈尔滨工业大学 Ink-jet recording material and preparation method thereof as well as method for preparing ink absorption layer coating liquid
CN102909982A (en) * 2012-09-12 2013-02-06 浙江欧丽数码喷绘材料有限公司 Waterproof PP(propene polymer) synthesized paper for ink-jet printing and preparation method thereof
CN104936996A (en) * 2013-01-21 2015-09-23 日本合成化学工业株式会社 Silyl group-containing poly(vinyl alcohol)-based resin and use thereof
CN103395337A (en) * 2013-08-01 2013-11-20 江苏格美高科技发展有限公司 Water-borne matte water-proof ink jet canvas and preparation method thereof
CN104371411A (en) * 2014-11-21 2015-02-25 广东高璐美数码科技有限公司 Water-based color ink-jet printing medium and production method thereof
CN105693938A (en) * 2014-11-28 2016-06-22 合众（佛山）化工有限公司 Preparation method of imidized SMA modified cationic styrene-acrylic emulsion
WO2016178402A1 (en) * 2015-05-01 2016-11-10 富士フイルム株式会社 Method for manufacturing lenticular printed matter and lenticular printed matter
CN105415911A (en) * 2015-12-25 2016-03-23 天津美迪亚影像材料有限公司 Gold card for ink-jet printing
CN106555364A (en) * 2016-11-28 2017-04-05 江苏格美高科技发展有限公司 A kind of high glaze is water-fast printing paper and preparation method thereof
CN106758510A (en) * 2016-11-28 2017-05-31 江苏格美高科技发展有限公司 A kind of ink absorbing layer masking liquid of the water-fast printing paper of high glaze and preparation method thereof
CN210283660U (en) * 2019-05-17 2020-04-10 江苏天之印数码打印材料有限公司 High-gloss photographic paper for color ink-jet printing
CN114426621A (en) * 2020-10-14 2022-05-03 中国石油化工股份有限公司 Nonionic modified polyvinyl alcohol and preparation method thereof
CN113429625A (en) * 2021-07-08 2021-09-24 湖南肆玖科技有限公司 Liquid candle dye and preparation method thereof
CN113605138A (en) * 2021-08-16 2021-11-05 海南必凯水性新材料有限公司 Aqueous coating liquid for photographic paper, preparation method thereof and printing photographic paper
CN114671700A (en) * 2022-02-25 2022-06-28 广东省福美材料科学技术有限公司 Modified inorganic powder composite facing sheet with decorative pattern and preparation method thereof
CN114872471A (en) * 2022-05-17 2022-08-09 广东冠豪新材料研发有限公司 High-transparency thermosensitive recording material and preparation method thereof
CN114953801A (en) * 2022-06-15 2022-08-30 乐凯胶片股份有限公司 Ink-jet printing material and preparation method thereof
CN115522405A (en) * 2022-09-28 2022-12-27 广东冠豪高新技术股份有限公司 Thermal sublimation transfer printing paper coating and preparation method and application thereof

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
CHI-JUNG CHANG等: "Improving mechanical properties and chemical resistance of ink-jet printer color filter by using diblock polymeric dispersants", JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, vol. 43, no. 22, 5 November 2005 (2005-11-05) *
唐小君;李路海;何君勇;辛智青;赵文;杜鹏;: "喷墨打印纸结构及其打印画面保存性研究进展", 信息记录材料, no. 06, 15 November 2009 (2009-11-15), pages 32 - 36 *
杨宝红;白永平;: "聚氯乙烯膜喷绘性能的影响因素研究", 塑料科技, no. 03, 10 March 2010 (2010-03-10), pages 58 - 60 *
马吉峰, 戴红旗: "阳离子苯丙乳液在彩喷纸中的应用研究", 造纸化学品, no. 05, 30 October 2005 (2005-10-30), pages 8 - 11 *

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