CN114641452A - Cogeneration turbine for power generation and seawater desalination - Google Patents

Cogeneration turbine for power generation and seawater desalination Download PDF

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Publication number
CN114641452A
CN114641452A CN202080070800.4A CN202080070800A CN114641452A CN 114641452 A CN114641452 A CN 114641452A CN 202080070800 A CN202080070800 A CN 202080070800A CN 114641452 A CN114641452 A CN 114641452A
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Prior art keywords
air
turbine
chamber
seawater
heat
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CN202080070800.4A
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Chinese (zh)
Inventor
S·阿塔
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S Ata
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S Ata
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/16Treatment of water, waste water, or sewage by heating by distillation or evaporation using waste heat from other processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/043Details
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/048Purification of waste water by evaporation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K13/00General layout or general methods of operation of complete plants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K15/00Adaptations of plants for special use
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02CGAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C1/00Gas-turbine plants characterised by the use of hot gases or unheated pressurised gases, as the working fluid
    • F02C1/04Gas-turbine plants characterised by the use of hot gases or unheated pressurised gases, as the working fluid the working fluid being heated indirectly
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02CGAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C1/00Gas-turbine plants characterised by the use of hot gases or unheated pressurised gases, as the working fluid
    • F02C1/04Gas-turbine plants characterised by the use of hot gases or unheated pressurised gases, as the working fluid the working fluid being heated indirectly
    • F02C1/10Closed cycles
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02CGAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C6/00Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use
    • F02C6/18Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24SSOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S20/00Solar heat collectors specially adapted for particular uses or environments
    • F24S20/40Solar heat collectors combined with other heat sources, e.g. using electrical heating or heat from ambient air
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/10Energy recovery
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05DINDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2260/00Function
    • F05D2260/20Heat transfer, e.g. cooling
    • F05D2260/213Heat transfer, e.g. cooling by the provision of a heat exchanger within the cooling circuit
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/138Water desalination using renewable energy
    • Y02A20/142Solar thermal; Photovoltaics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/40Solar thermal energy, e.g. solar towers
    • Y02E10/46Conversion of thermal power into mechanical power, e.g. Rankine, Stirling or solar thermal engines
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/14Combined heat and power generation [CHP]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Physics & Mathematics (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Thermal Sciences (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

By using a gas turbine and a closed cycle gas/(air or nitrogen) turbine in a cascaded manner, the heat required by the heat exchanger chambers (for heat addition) in the closed cycle gas turbine can be obtained by using the heat transferred from the exhaust gas of the open cycle gas turbine. Instead of an open cycle gas turbine, we can also obtain heat from a nuclear power plant, if any. When we send very hot air to the heat exchanger compartment (for cooling air) after leaving the turbine from the closed cycle gas/air turbine, we use seawater in multiple heat exchangers to cool the air and use the heat to desalinate the seawater, so finally we can produce both fresh water and electricity through both open and closed gas turbines.

Description

Cogeneration turbine for power generation and seawater desalination
Background
There are several inventions relating to desalination of sea water. All of these inventions focus on extracting heat from the sun (solar energy). These inventions do not produce a large amount of fresh water and cannot stably supply energy due to the limited time of the heat source (influence of night and cloudy day).
In my invention, it is proposed to use an open cycle gas turbine as the heat source and present it to a closed cycle gas/air turbine which requires heat from one stage of the closed cycle (heat exchangers B2, B3).
After leaving the turbine (B4), the very hot air needs to be cooled before entering the compressor (B1). This is typically accomplished by the gas flow in the second heat exchanger.
I propose to desalinate seawater by passing it through a number of heat exchangers (B6, B7, B8) and to cool the closed-cycle air before it enters the compressor (B1).
In this way, the cogeneration of open and closed cycle gas turbines can generate electricity together, and the closed cycle turbine can produce fresh water from seawater at the same time.
I have added a method of combining solar heat with heat from an open cycle gas turbine, the combined heat being used as a secondary heat source in the heat exchanger of (B3), which can save some energy for the open cycle gas turbine.
Detailed Description
In an open cycle gas turbine (a), air enters the compressor (a1), then enters the combustion chamber (a2), and then the very hot, high pressure gas from (a2) impinges on the turbine (A3), which leaves the turbine as a very hot exhaust gas.
These gases enter the first heat exchanger (B2) and lead to iron pipes which are divided in the heat exchange chamber into 2, 3 or more pipes, each pipe being surrounded by a layer of insulation.
The multiple conduits leave the chamber and become one conduit again, going to (B3).
Warm compressed air (or nitrogen) entering the chamber (B2) from (B3) is directed to the copper tube divided within the chamber to the coil within one of the iron tubes. The coil should be in the middle of the iron pipe and not touch the pipe wall.
At the end of the tube, the coils are again connected to form a tube, B2, and very hot compressed air enters the turbine (B4).
Air and very hot gases move in opposite directions to each other.
In chamber (B3), its design is similar to chamber (B2), except that in the copper tube as compressed warm or hot air from compressor (B1) to (B3) and out (B2) air, part of the hot gas enters the middle of each tube of chamber (B3) from the copper coil of (B2), exits from the other side, reconnects to one tube and enters the exhaust.
There is no direct insulation on the pipe, but a material that can be made very hot by solar heat is installed and transferred to the pipe where the air flows. These materials may be (lava rock or coal).
The outer wall of the chamber is made of glass on the top and both sides so that sunlight is absorbed in the morning and introduced into the chamber through the mirrors. These glass panels can be covered with insulating material after the sun has fallen on the hill until the sun rises again. The bottom of the chamber is made of iron and has a support for the pipe which has supports for the coils inside, as shown in (B3).
After the air leaves the turbine (B4), it enters a multi-pass heat exchanger for cooling, absorbing (B6, B8) the heat in the air with seawater, and the cold air enters the compressor (B1), starting the cycle again.
As shown, the chamber (B6) has multiple sets of coils, passing the very hot air obtained (B4) to several coils of the chamber (B6) and exiting from one of the formed tubes, passing the warm air in (B8).
The pipes feed the partially warm seawater from (B8) to several atomizers on the wall of the chamber (B6) atomizing the water into droplets which drop on top of several sets of pipes with hot air in the pipes in the chamber.
Most of the water droplets evaporate by absorbing heat from the air in the duct and evaporate in the form of gas, rise to the curved roof of the chamber (B6) and are directed by the suction fan to the duct out of the chamber (B7). The remaining water droplets fall, collect at the bottom of (B6) and rejoin the atomizer with warm water from (B7 and B8) via the water droplets leading to the pipe.
In chamber (B8), there is a coil set immersed in seawater, which completely fills the chamber (B8) and is driven from the sea by a water pump to enter the chamber from the bottom, exit from the top of the chamber after warming, and extract the rest of the heat in the air before entering (B6). The air leaving the chamber cools, entering the compressor (B1).
In (B7), the hot water vapor enters the chamber in the form of a gas from the sidewall above the level of the fresh water formed. The hot gas rises from several sets of pipes horizontally suspended in the chamber and is directly fed into the seawater under the push of a water pump.
The warm sea water after the exchange of heat leaves the chamber in a pipe (B7) and the water vapour cools during its rise, causing a large amount of water vapour to condense, falling under gravity into the bottom of the chamber, becoming fresh water and being pumped out.
The remaining steam exits the pipes at the top side of the chamber, enters the hot water steam pipe, and enters the chamber again for repeated circulation.
Reference numerals
1, A: open cycle gas turbine
A1: compressor with a compressor housing having a plurality of compressor blades
A2: combustion chamber
A3: turbine engine
A4: generator
2, B: closed cycle gas/air turbine
B1: compressor with a compressor housing having a plurality of compressor blades
B2: heat converter (for increasing heat)
B3: preheat heat exchanger (for added heat) B4: turbine B5: generator
B6: heat converter (for extracting heat)
B7: heat converter (seawater desalination)
B8: preheating heat exchanger (for drawing heat)

Claims (10)

1.A cogeneration turbine for power generation and seawater desalination comprising an open cycle gas turbine and a closed cycle gas/air turbine, wherein the very hot gas released from the open cycle gas turbine or the heat from a nuclear power plant is to be directed to heat exchangers (B2 and B3) as described in the drawing for the closed cycle gas/air turbine, which are added as a heat source to the air of the closed cycle gas/air turbine.
Wherein the very hot air, after leaving the turbine (B4 in the figure), enters heat exchangers (B6 and B8 in the figure) where it is cooled by seawater (B6 and B8).
Wherein the seawater is evaporated and its vapour is led to (B7 in the drawing), cooled, condensed and formed into fresh water by the seawater.
Wherein the air is cooled in heat exchangers (B6 and B8 in the drawing) and directed to a compressor (B1 in the drawing) to complete the cycle of the closed cycle gas/air turbine.
2. The cogeneration turbine for power generation and desalination of sea water of claim 1, wherein said very hot gases produced by the open cycle gas turbine are directed to a heat exchanger (B2) to provide the required heat to the air of the closed cycle gas turbine.
3. The cogeneration turbine for power generation and seawater desalination of claim 2, wherein said heat exchanger (B2) is an insulated chamber comprising a plurality of pipes, each pipe having very hot gas from an open cycle gas turbine into the chamber of (B2) and then out to (B3), said air from the pipes in the chamber of (B3) to (B2) into a cup-shaped coil in each pipe and then out to go as very hot compressed air to the turbine (B4).
4. The cogeneration turbine for power generation and seawater desalination of claim 1, wherein said hot gas leaves (B2) to (B3) a chamber, said (B3) chamber being a preheated heat exchanger, said hot gas entering (B3) a coil within each of a plurality of tubes of a chamber.
Wherein the air is passed from the compressor (B1) to the chamber (B3), the direction of the air in the duct being opposite to the direction of the hot gas in the coil, the air being discharged from (B3) to the exhaust, the air in the duct entering the coil of (B2).
5. The cogeneration turbine for power generation and desalination of sea water of claim 4, wherein instead of insulation around pipes like (B2), a chamber filled with material around said pipes (such as B3) is able to transfer solar heat to the air in the pipes in (B3), the walls and roof of said chamber B3 being glass, by providing mirrors to direct sunlight to the glass to the chamber, more heat is added to the air in the pipes by using the solar heat.
6. Cogeneration turbine for power generation and seawater desalination according to claim 1, wherein in heat exchanger (B6), very hot air from (B4) is passed to the pipes inside chamber (B6), said very hot air is cooled down by warm seawater, said very hot air from (B8) leaves (B6) to be recycled and re-enters (B6).
7. Cogeneration turbine for power generation and seawater desalination according to claim 6, wherein said seawater in chamber (B6) is atomized by atomizers on the walls of chamber (B6), said seawater falls on very hot air pipes, part of the water evaporates and rises, collecting from the top of (B6), said steam gas is extracted by suction fan (B6), said steam gas is directed to (B7).
8. A cogeneration turbine for power generation and seawater desalination according to claim 1 wherein said hot air is passed from (B6) into chamber (B8) to a set of coils, said cooling air coming out from (B8) to compressor (B1), said chamber (B8) comprising a set of coils, said air being passed into it, said pipes being immersed in seawater, said seawater being pumped directly from the sea to the bottom of chamber (B8), exiting from the top of chamber (B8) to (B6).
9. Cogeneration turbine for power generation and seawater desalination according to claim 1, wherein said heat exchanger (B7) comprises a set of pipes carrying seawater pumped directly from the sea by a pump, said seawater exiting (B7) to (B8).
10. The cogeneration turbine for power generation and desalination of sea water of claim 9, wherein said hot water vapor enters the chamber (B7) as from the lower side wall of the group of pipes of sea water, said vapor rising from the pipes, said majority of vapor should condense and fall as fresh water, falling at the bottom of (B7), said fresh water being collected from (B7), said remaining vapor being redirected to the bottom of the chamber (B7).
CN202080070800.4A 2019-10-11 2020-10-06 Cogeneration turbine for power generation and seawater desalination Withdrawn CN114641452A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CA3,058,596 2019-10-11
CA3058596A CA3058596A1 (en) 2019-10-11 2019-10-11 Cogeneration turbines for power and desalination of sea water
PCT/IB2020/059359 WO2021070041A1 (en) 2019-10-11 2020-10-06 Cogeneration turbines for power and desalination of sea water

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CN114641452A true CN114641452A (en) 2022-06-17

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EP (1) EP4041686A4 (en)
JP (1) JP2022551715A (en)
KR (1) KR20220097880A (en)
CN (1) CN114641452A (en)
AU (1) AU2020362987A1 (en)
CA (1) CA3058596A1 (en)
WO (1) WO2021070041A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115405390B (en) * 2022-08-24 2024-05-07 西安热工研究院有限公司 Pressurized water reactor power generation, energy storage, sea water desalination and refrigeration coupling operation system and method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1572728A (en) * 2003-05-30 2005-02-02 通用电气公司 Combined power generation and desalinization apparatus and related method
EP1701006A2 (en) * 2005-02-22 2006-09-13 Kabushiki Kaisha Toshiba Electric power-generating and desalination combined plant and operation method of the same
CN203582533U (en) * 2013-12-16 2014-05-07 湖南创化低碳环保科技有限公司 Sea water desalting device
CN104847428A (en) * 2015-06-01 2015-08-19 国家电网公司 External-combustion type Britten combined cycle power generation device
CN108658157A (en) * 2018-05-14 2018-10-16 广州航海学院 A kind of seawater desalination system

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10221775B2 (en) * 2016-12-29 2019-03-05 Malta Inc. Use of external air for closed cycle inventory control

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1572728A (en) * 2003-05-30 2005-02-02 通用电气公司 Combined power generation and desalinization apparatus and related method
EP1701006A2 (en) * 2005-02-22 2006-09-13 Kabushiki Kaisha Toshiba Electric power-generating and desalination combined plant and operation method of the same
CN203582533U (en) * 2013-12-16 2014-05-07 湖南创化低碳环保科技有限公司 Sea water desalting device
CN104847428A (en) * 2015-06-01 2015-08-19 国家电网公司 External-combustion type Britten combined cycle power generation device
CN108658157A (en) * 2018-05-14 2018-10-16 广州航海学院 A kind of seawater desalination system

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WO2021070041A8 (en) 2021-11-25
EP4041686A4 (en) 2024-01-03
WO2021070041A1 (en) 2021-04-15
AU2020362987A1 (en) 2022-05-26
EP4041686A1 (en) 2022-08-17
JP2022551715A (en) 2022-12-13
CA3058596A1 (en) 2021-04-11
KR20220097880A (en) 2022-07-08

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