The cathode ray tube (CRT) of general information display is under high-voltage state and works, very easily on the glass matter face-plate of a cathode-ray tube, accumulate electrostatic charge, form electrostatic effect, this electrostatic effect will make very easily adsorbs dust and airborne dirt on the panels outside of this cathode ray tube, like this, the quality of this face-plate of a cathode-ray tube video image will be reduced.In addition, when the user touches the panel of this cathode ray tube, the user will produce the uncomfortable sensation that is shocked by electricity because of accumulating the discharge process of electrostatic charge on the panel.If when the discharge process of this electrostatic charge occurs in the production line operation, will have influence on operating personnel's job morale and production quality.In addition, in the out of Memory display on the employed display screen, as: plasma discharge display screen (plasma discharge screen, be called for short PDP), vacuum fluorescent display screen (vacuum florescent screen) and gas panel (gas dischargescreen) etc. are also just like preceding described problem.
On the display screen of general information display, not only, and, cause the video image quality that has reduced this conventional information display floater significantly because this panel is easy to cause the reflection of light because the non-conductive characteristic of its glass matter panel easily causes electrostatic charges accumulatedly.For many years, though the researcher once researched and developed out some solutions at this point, still can't effectively improve these defectives.Traditional anti-static coating material is mainly semiconductor type coating material (as: antimony oozes tin oxide antimony doped tin oxide), a water and an organic solvent (organicsolvent, as ethanol ethanol or isopropyl alcohol isopropanol) mix, yet, unfortunately, be coated with the made information display of this kind anti-static coating material, but face many problems during fabrication, mainly due to this kind anti-static coating material for the dirt on the panel of information display unit (and when cleaning this panel residual brush body dirt) sensitivity as dust, very easily adsorb such dirt, for example, when making and assembling this panel of information display unit, though this panel cleans, the still frequent remaining greasy dirt washmarking (water mark) that has on this panel.Remain in dirt on this panel of information display unit (and when cleaning this panel residual brush body dirt), will reduce the video image quality of this panel as greasy dirt, washmarking, dust.In addition, because the formed coating layer of traditional anti-reflecting layer coating process generally all is porous and comparatively fragile applying structure, so, the mechanical wiping when frequent wiping and manufacturing, very easily make this reflection coating layer destroyed, and then make the antistatic coating layer of its internal layer also therefore destroyed.
In view of accumulating electrostatic charge on the aforementioned conventional information display display screen panel, very easily after cleaning, still frequent residual dirt (and when cleaning this panel residual brush body dirt) as greasy dirt, washmarking, dust, reduce the video image quality of this panel, and in design and making, derive problems, the present invention has been proposed.
The objective of the invention is to propose the coating process of the antistatic and anti-reflecting layer of a kind of video information display pannel, easily adsorb dirt and easy ruined problem to solve traditional antistatic coating layer.
Another object of the present invention is to propose the coating process of the antistatic and anti-reflecting layer of a kind of video information display pannel,, improve the quality of shown image to eliminate catoptrical effect.
For achieving the above object, the antistatic and anti-reflecting layer coating process of a kind of video information display panel of the present invention comprises step: be coated with earlier the first antistatic coating layer on video information display panel thinly; Secondly, this display floater is heated to a suitable high temperature, the coating material of this first antistatic coating layer is infiltrated in this display floater, make the outer surface of this display floater have high conductivity; At last, coating second reflection coating layer on this first antistatic coating layer.
Figure 1 shows that a kind of cathode ray tube, this cathode ray tube 10 mainly comprises a sealed glass body 12, this body 12 is provided with a front panel, or title display screen 14, pars infundibularis 16 in the middle of one tube neck 18 and, the inner surface of this face glass 14 is coated with fluorescence coating 24, but this fluorescence coating 24 comprises the fluorescence picture point of a plurality of difference emitting fluorescences, when the color electric bundle focuses on fluorescence picture point on these face glass 14 inner surfaces, this picture point will have been sent coloured light, with display video frame on this display screen 14, in the tube neck 18 of the seal glass body 12 of this cathode ray tube 10, be provided with a plurality of electron guns 20 that are linear array, to produce a plurality of electron beams 22 that focus on these face glass 12 fluorescence coatings 24, this electron beam 22 along level and vertical direction deflection, and focuses on this fluorescence coating 24 behind magnetic deflection coil (magnetic deflection yoke).
Figure 2 shows that the partial cutaway schematic on the information display display floater, the section of this glass display panel 40 is planar-shaped (or can be arc surfaced), the fluorescence coating 42 that is coated with on the inner surface of this glass display panel 40, for a plurality of each intervals and be point-like (dots) or fluorescence coating that banded (stripes) distributes, then be coated with the antistatic and reflection coating layer 44 of multilayer on the outer surface of this glass display panel 40.Antistatic and reflection coating layer of the present invention is not limited to be applied on the display screen of cathode ray tube, also can be applied in the out of Memory display on the employed display screen, as: field effect emission display screen (fieldemission display, between claim FED), LCDs (liquid crystaldisplay, be called for short LCD), plasma discharge display screen (plasma dischargescreen is called for short PDP), on the outer surface of vacuum fluorescent display screen (vacuum florescent screen) and gas panel (gas discharge screen) etc.Antistatic and the reflection coating layer 44 of this multilayer comprises the first antistatic coating layer 46 of an internal layer, this coating layer 46 mainly is to be heated to Celsius 500~600 when spending at this glass display panel 40, to comprise phosphorus oozes tin oxide (coating material that P (Phosphor)-doped) or fluorine ooze tin oxide compositions such as (F (Fluorine)-doped tin oxide) directly is coated on the outer surface of this glass display panel 40, form the antistatic coating layer 46 of skim, and heat the antistatic coating layer 46 of this glass display panel 40 and outer surface thereof with the temperature of 500~600 degree Celsius, this anti-static coating material is infiltrated through in the outer surface of this glass display panel 40, form the antistatic permeable formation 46a of skim (as shown in phantom in Figure 2), the thickness of this permeable formation 46a is about 0.5~1 μ m, also have antistatic property, the electrical conductivity of these glass display panel 40 outer surfaces through permeating can be up to being about 10~10
3Ohm-cm on it and be equipped with a conducting element 52, is connected to earth terminal by this conducting element with this glass display panel 40, makes this glass display panel 40 have the characteristic of antistatic and electromagnetic shielding.
In addition; the present invention makes this glass display panel 40 have the characteristic of antireflection protection simultaneously; antistatic and the reflection coating layer 44 of this multilayer also comprises second reflection coating layer 48 in an intermediate layer; this coating layer 48 is mainly and will comprises as tin oxide (tin oxide); tantalum stannum oxide (tantalum oxide); titanium (titanium); antimony oozes tin oxide (antimony-doped tin oxide) etc. and has high index of refraction (light refraction; as: antireflection material 1.8~2.2); directly coat on first antistatic coating layer 46 outer surfaces of this internal layer; form second reflection coating layer 48 in this intermediate layer; the thickness of this second reflection coating layer 48 is main according to deciding suppressing the ray refraction rate; for example; for the light that will make wavelength 550nm produces minimal reflection; the thickness of this second reflection coating layer 48 is about 1/4 of this optical wavelength, or is about 137~138nm.
In addition; the present invention is for strengthening the antireflection protective feature of this glass display panel 40; antistatic and the reflection coating layer 44 of this multilayer also comprises outer field the 3rd reflection coating layer 50; this coating layer 50 is mainly and will has low refraction coefficient (light refraction; as: antireflection material 1.2~1.45); as silica (silicon oxide); magnesium fluoride (mag-nesium fluoride) and other antireflecting optics coating material etc.; directly be coated on these second antistatic coating layer 48 outer surfaces; form this outer field the 3rd reflection coating layer 50; the thickness of the 3rd reflection coating layer 50 mainly is that foundation is decided suppressing the ray refraction rate, and its thickness is about will suppress 1/4 of wavelength of light.
Another embodiment of the present invention, be to omit aforementioned this outer field the 3rd reflection coating layer 50, the meaning i.e. antistatic and reflection coating layer 44 of this multilayer only comprises the first antistatic coating layer 46 of an internal layer and second reflection coating layer 48 in intermediate layer, this first antistatic coating layer 46 mainly comprises phosphorus and oozes that (P (Phosphor)-doped) tin oxide or fluorine ooze the coating material of tin oxide compositions such as (F (Fluo-rine)-doped tin oxide), and this material must have the antireflective properties greater than 1.8 refraction coefficient, as silica (silicon oxide), magnesium fluoride (magnesium fluoride) and other antireflective optical coating material etc.
Shown in Figure 3, for the present invention is antistatic and reflection coating layer are applied to operation process chart on the glass matter display floater, the first step 58 of this coating operation, be to be coated with thinly on video information display panel earlier that one deck is phosphorous and to ooze that (P (Phosphor)-doped) tin oxide or fluorine ooze the antistatic coating layer of tin oxide compositions such as (F (Fluorine)-doped tin oxide), and the thickness of this antistatic coating layer is the best with 0.3 μ m.Second step 60, be when this antistatic coating layer of coating, this display floater is heated to the high temperature of 500~600 degree Celsius approximately, described tin oxide (the doped tin oxide) coating material that oozes can be penetrated in (diffuse into) this display floater, make the outer surface tool high conductivity (highly conductive) of this display floater, at this moment, again with the edge ground connection of this display floater, can make it have the characteristic of antistatic and electromagnetic shielding.In the third step 62 of this coating operation, with one embodiment of the invention is example, be on the antistatic coating layer 46 of this display floater, to be coated with one deck again to have the low refraction coefficient antireflection material of (being about 1.2~1.4), as silica (silicon oxide), magnesium fluoride (magnesium fluoride) etc., form second reflection coating layer 48, this moment, the coating material of this first antistatic coating layer 46 must have antireflective properties greater than 1.8 refraction coefficient, and the thickness of this second reflection coating layer 48 need satisfy the antireflection standard of 1/4 wavelength.To suppress the most serious situation of light reflection, make this panel possess high-caliber video image quality and antistatic effect.
In another embodiment of the present invention, the third step 64 of this coating operation, be on the antistatic coating layer of the ground floor of this display floater, to be coated with one deck again to have the high index of refraction antireflection material of (being about 1.8~2.2), as: tin oxide (tin oxide), tantalum oxide (tantalum oxide), titanium (titanium), antimony oozes tin oxide (antimony-dopedtin oxide) etc., form second reflection coating layer 48, the final step 66 of this coating operation, be that coating one deck has the low refraction coefficient antireflection material of (being about 1.2~1.45) on second reflection coating layer 48 of this display floater, as: silica (siliconoxide), magnesium fluoride (magnesium fluoride) etc., form the 3rd reflection coating layer 50, the essential antireflection standard that satisfies 1/4 wavelength of thickness relationship between this second and the 3rd reflection coating layer, to suppress the most serious situation of light reflection, make this panel possess high-caliber video image quality and antistatic effect.
This anti-static coating material of the present invention is behind the outer surface that infiltrates through this glass display panel 40, the antistatic permeable formation 46a (as shown in phantom in Figure 2) of skim will be formed, the thickness of this permeable formation 46a is 0.5~1 μ m, have antistatic property, and the electrical conductivity (conductivity) of these glass display panel 40 outer surfaces through permeating is because can be up to 10~10
3Ohm-cm; so not only provide good antistatic protection for this glass display panel 40; and provide static and electromagnetic shielding (electrostatic and electromagnetic shielding) protection; in addition; this antistatic permeable formation 46a infiltrates through the osmosis (penetration) of these glass display panel 40 outer surfaces; also make this antistatic coating layer when being cleared up, have higher anti-scratch anti-wear (the scratchand wear resistance) characteristic that undermines in the wiping mode.After reflection coating layer of the present invention is coated on the display floater, owing to satisfy 1/4 wavelength antireflection standard, so have anti-reflection effect preferably.
The above only is preferred embodiment of the present invention, claim scope proposed by the invention; be not limited thereto, allly be familiar with the person skilled in art, according to the disclosed technology contents of the present invention; other equivalence that can expect easily changes, and all should belong to and not break away from protection category of the present invention.