CN113495383A - Variable three-color module adjusted through microsphere liquid crystal and preparation process thereof - Google Patents

Variable three-color module adjusted through microsphere liquid crystal and preparation process thereof Download PDF

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Publication number
CN113495383A
CN113495383A CN202110854437.1A CN202110854437A CN113495383A CN 113495383 A CN113495383 A CN 113495383A CN 202110854437 A CN202110854437 A CN 202110854437A CN 113495383 A CN113495383 A CN 113495383A
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China
Prior art keywords
layer
flim
liquid crystal
lens
ito
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CN202110854437.1A
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Chinese (zh)
Inventor
刘华
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Dongguan Jingbo Photoelectric Co Ltd
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Dongguan Jingbo Photoelectric Co Ltd
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Priority to CN202110854437.1A priority Critical patent/CN113495383A/en
Publication of CN113495383A publication Critical patent/CN113495383A/en
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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133514Colour filters
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1341Filling or closing of cells

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Liquid Crystal (AREA)

Abstract

The invention relates to the technical field of colored display, in particular to a variable three-color module regulated by microsphere liquid crystal and a preparation process thereof, which comprises a first color coating layer, a first ITO layer, a first flim layer or a lens layer, a second color coating layer, a second ITO layer, a second flim layer or a lens layer, a third color coating layer, a third ITO layer and a third flim layer or a lens layer which are sequentially arranged from top to bottom, wherein the first flim layer or the lens layer and the second color coating layer are packaged with microsphere liquid crystal, the second flim layer or the lens layer and the third color coating layer are packaged with microsphere liquid crystal, the colors of the first color coating layer, the second color coating layer and the third color coating layer are different, the invention combines liquid crystal microspheres with three different color coating layers, controls the transmittance of the microsphere liquid crystal in a packaging material layer under the conditions of applying an electric field and not applying the electric field to realize the color regulation and control, a multi-color variation can be achieved.

Description

Variable three-color module adjusted through microsphere liquid crystal and preparation process thereof
Technical Field
The invention relates to the technical field of colored display, in particular to a variable three-color module regulated by microsphere liquid crystal and a preparation process thereof.
Background
At present, in order to meet the requirements of consumer groups on visual aesthetics, almost all industrial finished products are subjected to certain appearance design and matched with various color patterns, so that the aesthetic requirements of consumers are met, the consumer approval is obtained to a certain extent, the product competitiveness is promoted, and the product sales volume is increased.
The existing industrial finished products usually realize the decoration of the products by arranging a layer with fixed colors on the surface of the industrial finished products, but because the colors of the layer are fixed, consumers are easy to generate visual fatigue after using for a period of time. This is particularly wasteful for some consumer groups that have extremely high requirements for appearance, even if they are interested in changing different colored products because they are weary of the appearance of the finished industrial product.
Particularly, the color of the back cover glass of the mobile phone on the market is basically single, and the change of the color cannot be realized.
Disclosure of Invention
In order to overcome the defects and shortcomings in the prior art, the invention aims to provide a variable three-color module regulated by microsphere liquid crystals and a preparation process thereof.
The purpose of the invention is realized by the following technical scheme: the utility model provides a variable tristimulus module through microballon liquid crystal regulation, includes first colour coating film layer, first ITO layer, first flim layer or lens layer, second colour coating film layer, second ITO layer that from top to bottom set gradually, second flim layer or lens layer, third colour coating film layer, third ITO layer, third flim layer or lens layer, first flim layer or lens layer and second colour coating film layer are packaged with microballon liquid crystal, and second flim layer or lens layer and third colour coating film layer are packaged with microballon liquid crystal, the colour on first colour coating film layer, second colour coating film layer and third colour coating film layer is different.
Preferably, the sheet resistance of the first ITO layer is less than 800 ohm/square resistance;
the material transmission T of the first flim layer or the lens layer is more than 70 percent.
Preferably, the sheet resistance of the second ITO layer is less than 800 ohm/square resistance;
the material transmission T of the second flim layer or the lens layer is more than 70 percent.
Preferably, the sheet resistance of the third ITO layer is less than 800 ohm/square resistance;
the third flim or lens layer has a material transmission T > 70%.
Preferably, the pore diameter of the micropores of the liquid crystal microspheres ranges from a few nanometers to a few hundred nanometers.
A preparation process of a variable three-color module regulated by microsphere liquid crystal comprises the following steps: it comprises the following steps:
step 1, plating a first ITO layer on the upper surface of the first flim layer or the lens layer, and plating a first color coating layer on the first ITO layer to obtain an upper substrate layer;
step 2, plating a second ITO layer on the upper surface of the second flim layer or the lens layer, and plating a second color coating layer on the second ITO layer to obtain a middle substrate layer;
step 3, plating a third ITO layer on the upper surface of the third flim layer or the lens layer, and plating a third color coating layer on the third ITO layer to obtain a lower substrate layer;
step 4, coating liquid crystal microspheres on the lower surface of the first flim layer or the lens layer of the upper base layer, and coating liquid crystal microspheres on the lower surface of the second flim layer or the lens layer of the middle base layer;
and 5, attaching the upper substrate layer, the middle substrate layer and the lower substrate layer coated with the liquid crystal microspheres, and packaging the liquid crystal microspheres by adopting a packaging material layer.
The invention has the beneficial effects that: the color-changing film comprises a first color film coating layer, a first ITO layer, a first flim layer or a lens layer, a second color film coating layer, a second ITO layer, a second flim layer or a lens layer, a third color film coating layer, a third ITO layer and a third flim layer or a lens layer which are sequentially arranged from top to bottom, wherein microsphere liquid crystals are packaged in the first flim layer or the lens layer and the second color film coating layer, microsphere liquid crystals are packaged in the second flim layer or the lens layer and the third color film coating layer, and the first color film coating layer, the second color film coating layer and the third color film coating layer are different in color.
Drawings
FIG. 1 is a schematic structural view of the present invention;
FIG. 2 is a schematic illustration of the present invention with no electric field applied;
FIG. 3 is a schematic illustration of the present invention applying an electric field;
the reference signs are: 1 a first color film coating layer, 2 a first ITO layer, 3 a first flim layer or a lens layer, 4 packaging material layers, 5 a second color film coating layer, 6 a second ITO layer, 7 a second flim layer or a lens layer, 8 a third color film coating layer, 9 a third ITO layer, 10 a third flim layer or a lens layer and 11 microsphere liquid crystals.
Detailed Description
For the understanding of those skilled in the art, the present invention will be further described with reference to the following examples and accompanying fig. 1-3, which are not intended to limit the present invention.
Example 1
The utility model provides a variable tristimulus module through adjustment of microballon liquid crystal 11, includes first colour coating film layer 1, first ITO layer 2, first flim layer or lens layer 3, second colour coating film layer 5, second ITO layer 6 that from top to bottom set gradually, second flim layer or lens layer 7, third colour coating film layer 8, third ITO layer 9, third flim layer or lens layer 10, first flim layer or lens layer 3 and second colour coating film layer 5 are packaged with microballon liquid crystal 11, and second flim layer or lens layer 7 and third colour coating film layer 8 are packaged with microballon liquid crystal 11, first colour coating film layer 1, second colour coating film layer 5 and third colour coating film layer 8's colour is different.
The sheet resistance of the first ITO layer 2 is less than 800 ohm/square resistance;
the material transmission T of the first flim layer or the lens layer 3 is more than 70 percent;
the sheet resistance of the second ITO layer 6 is less than 800 ohm/square resistance;
the material transmission T of the second flim layer or the lens layer 7 is more than 70 percent;
the sheet resistance of the third ITO layer 9 is less than 800 ohm/square resistance;
the third flim or lens layer 10 has a material transmission T > 70%.
The pore diameter range of the micropores of the liquid crystal microspheres is from a few nanometers to a few hundred nanometers.
A preparation process of a variable three-color module regulated by microsphere liquid crystal 11 comprises the following steps: it comprises the following steps:
step 1, plating a first ITO layer 2 on the upper surface of a first flim layer or a lens layer 3, and plating a first color coating layer 1 on the first ITO layer 2 to obtain an upper substrate layer;
step 2, plating a second ITO layer 6 on the upper surface of the second flim layer or the lens layer 7, and plating a second color coating layer 5 on the second ITO layer 6 to obtain a middle substrate layer;
step 3, plating a third ITO layer 9 on the upper surface of the third flim layer or the lens layer 10, and plating a third color coating layer 8 on the third ITO layer 9 to obtain a lower substrate layer;
step 4, coating liquid crystal microspheres on the lower surface of the first flim layer or the lens layer 3 of the upper base layer, and coating liquid crystal microspheres on the lower surface of the second flim layer or the lens layer 7 of the middle base layer;
and 5, attaching the upper substrate layer, the middle substrate layer and the lower substrate layer coated with the liquid crystal microspheres, and packaging the liquid crystal microspheres by adopting a packaging material layer 4.
Example 2
This example differs from example 1 in that the present example uses liquid crystal microspheres imported from kyushu, and the encapsulating material uses transparent polystyrene.
Example 3
The difference between this example and example 1 is that the packaging material is transparent polystyrene, and the preparation method of the liquid crystal microsphere of the present invention is:
firstly, the method comprises the following steps: uniformly dispersing 0.01g of silica microspheres with the size of 600nm in 10mL of ethanol and 80mL of deionized water, adding 0.05g of NaOH and 0.3g of formaldehyde solution, stirring for 10 minutes at room temperature, adding 0.3g of resorcinol, stirring for 6 hours at room temperature to obtain the silica microspheres with the surfaces coated with a layer of phenolic resin, washing the product with a mixed solution of ethanol and water, and drying the washed product at room temperature for later use.
Secondly, the method comprises the following steps: 0.1g of silica microspheres coated with a layer of phenolic resin on the surface thereof was ultrasonically dispersed in 80mL of deionized water in which 0.4g of cetylammonium bromide (CTAB) and 0.8g of strong ammonia were dissolved, and 30mL of n-hexane in which 2mL of Tetraethylorthosilicate (TEOS) was dissolved was added dropwise thereto. Stirring in 30 deg.C water bath for 12 hr, washing with ethanol and water repeatedly, and oven drying at 30 deg.C. And (3) putting the dried sample into 80mL of n-propanol solution, performing reflux extraction at 90 ℃ for 12h, and fully removing the surfactant in the mesoporous pore channel to obtain the liquid crystal microsphere material required by the invention.
The principle of realizing color change by the structure is as follows:
the reflectivity of the first color coating layer 1 is R1, and the transmittance is T1; the reflectivity of the second color coating layer 5 is R2, and the transmittance is T2; the reflectivity of the third color coating layer 8 is R3, and the transmittance is T3;
the microsphere liquid crystal 11 allows light to pass through under the action of an electric field, and the light passing rate is t. When no electric field exists, the liquid crystal microspheres 11 completely do not allow light to pass through or have low passing rate, and can be ignored;
the first ITO layer 2, the second ITO layer 6, and the third ITO layer 9 are conductive layers that enable application of an electric field E;
in the absence of the applied electric field E, the liquid crystal microspheres 11 will not allow visible light to pass through, and the light entering the human eyes is only the reflected light of the first color coating layer 1 (for convenience of explanation, the reflection of the first ITO layer 2, the first flim layer or the lens layer 3 is not considered, and the transmittance of the first ITO layer 2, the first flim layer or the lens layer 3 is assumed to be 100%), the color is of course the reflected spectrum color of the first color coating layer 1, and the light path diagram is shown in fig. 2.
Under the condition of applying an electric field E, visible light is allowed to pass through the liquid crystal microspheres 11, and then light rays entering human eyes are mixed light rays after light rays entering human eyes are reflected by the first color coating layer 1 and the second color coating layer 5 and transmitted through the first color coating layer 1, the first ITO layer 2, the first flim layer or the lens layer 3 and mixed light rays reflected by the third color coating layer 8 and transmitted through the first color coating layer 1, the first ITO layer 2, the first flim layer or the lens layer 3, the second color coating layer 5, the second ITO layer 6 and the second flim layer or the lens layer 7; at this time, the color perceived by human eyes is the color of the mixed first color film coating layer 1, the second color film coating layer 5 and the third color film coating layer 8, and the three lights are mixed according to different intensities to present different colors, and the schematic light path diagram is shown in fig. 3.
The above-described embodiments are preferred implementations of the present invention, and the present invention may be implemented in other ways without departing from the spirit of the present invention.

Claims (7)

1. The utility model provides a but through variable three-colour module that microballon liquid crystal was adjusted which characterized in that: including the first colour coating film layer, first ITO layer, first flim layer or lens layer, second colour coating film layer, the second ITO layer that from top to bottom set gradually, second flim layer or lens layer, third colour coating film layer, third ITO layer, third flim layer or lens layer, first flim layer or lens layer and second colour coating film layer are packaged with microballon liquid crystal, and second flim layer or lens layer and third colour coating film layer are packaged with microballon liquid crystal, the colour on first colour coating film layer, second colour coating film layer and third colour coating film layer is different.
2. The variable tristimulus module of claim 1 tuned by microspherical liquid crystals, wherein: the sheet resistance of the first ITO layer is less than 800 ohm/square resistance; the material transmission T of the first flim layer or the lens layer is more than 70 percent.
3. The variable tristimulus module of claim 1 tuned by microspherical liquid crystals, wherein: the sheet resistance of the second ITO layer is less than 800 ohm/square resistance; the material transmission T of the second flim layer or the lens layer is more than 70 percent.
4. The variable tristimulus module of claim 1 tuned by microspherical liquid crystals, wherein: the sheet resistance of the third ITO layer is less than 800 ohm/square resistance; the third flim or lens layer has a material transmission T > 70%.
5. The variable tristimulus module of claim 1 tuned by microspherical liquid crystals, wherein: the pore diameter range of the micropores of the liquid crystal microspheres is from a few nanometers to a few hundred nanometers.
6. A preparation process of a variable three-color module adjusted by microsphere liquid crystal is characterized in that: it comprises the following steps:
step 1, plating a first ITO layer on the upper surface of the first flim layer or the lens layer, and plating a first color coating layer on the first ITO layer to obtain an upper substrate layer;
step 2, plating a second ITO layer on the upper surface of the second flim layer or the lens layer, and plating a second color coating layer on the second ITO layer to obtain a middle substrate layer;
step 3, plating a third ITO layer on the upper surface of the third flim layer or the lens layer, and plating a third color coating layer on the third ITO layer to obtain a lower substrate layer;
step 4, coating liquid crystal microspheres on the lower surface of the first flim layer or the lens layer of the upper base layer, and coating liquid crystal microspheres on the lower surface of the second flim layer or the lens layer of the middle base layer;
and 5, attaching the upper substrate layer, the middle substrate layer and the lower substrate layer, and packaging the liquid crystal microspheres by adopting a packaging material layer.
7. The process of claim 6 for preparing a variable three-color module tuned by microspherical liquid crystals, wherein: and 5, adopting a transparent material with the optical refractive index close to that of the liquid crystal microspheres for the packaging material layer in the step 5.
CN202110854437.1A 2021-07-28 2021-07-28 Variable three-color module adjusted through microsphere liquid crystal and preparation process thereof Pending CN113495383A (en)

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1031210A (en) * 1996-07-12 1998-02-03 Fuji Xerox Co Ltd Reflection type color display device
TW201033713A (en) * 2009-03-03 2010-09-16 Wintek Corp Reflective color-changing liquid crystal display
CN102385188A (en) * 2010-09-06 2012-03-21 北京众智同辉科技有限公司 Plastic liquid crystal film and making method thereof
CN103963711A (en) * 2013-02-01 2014-08-06 宁波昊达汽车科技有限公司 Semi-transmittance and semi-reflection type anti-dazzling electronic rearview mirror lens
CN104428740A (en) * 2014-10-14 2015-03-18 华为技术有限公司 Terminal with variable color
CN105487157A (en) * 2014-08-13 2016-04-13 南京晶多新材料科技有限公司 Construction and application of electric control light modulation film serving as scattering polaroid
CN207114957U (en) * 2017-08-18 2018-03-16 深圳市柔宇科技有限公司 Light modulation film and light modulating device
CN109581777A (en) * 2019-01-12 2019-04-05 Oppo广东移动通信有限公司 Electronic equipment, housing unit, electrochromism mould group and preparation method thereof
CN110780503A (en) * 2019-11-19 2020-02-11 华南师范大学 Color-changeable intelligent window
CN112888201A (en) * 2019-11-29 2021-06-01 北京小米移动软件有限公司 Back cover of electronic equipment, electronic equipment and back cover control method

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1031210A (en) * 1996-07-12 1998-02-03 Fuji Xerox Co Ltd Reflection type color display device
TW201033713A (en) * 2009-03-03 2010-09-16 Wintek Corp Reflective color-changing liquid crystal display
CN102385188A (en) * 2010-09-06 2012-03-21 北京众智同辉科技有限公司 Plastic liquid crystal film and making method thereof
CN103963711A (en) * 2013-02-01 2014-08-06 宁波昊达汽车科技有限公司 Semi-transmittance and semi-reflection type anti-dazzling electronic rearview mirror lens
CN105487157A (en) * 2014-08-13 2016-04-13 南京晶多新材料科技有限公司 Construction and application of electric control light modulation film serving as scattering polaroid
CN104428740A (en) * 2014-10-14 2015-03-18 华为技术有限公司 Terminal with variable color
CN207114957U (en) * 2017-08-18 2018-03-16 深圳市柔宇科技有限公司 Light modulation film and light modulating device
CN109581777A (en) * 2019-01-12 2019-04-05 Oppo广东移动通信有限公司 Electronic equipment, housing unit, electrochromism mould group and preparation method thereof
CN110780503A (en) * 2019-11-19 2020-02-11 华南师范大学 Color-changeable intelligent window
CN112888201A (en) * 2019-11-29 2021-06-01 北京小米移动软件有限公司 Back cover of electronic equipment, electronic equipment and back cover control method

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Application publication date: 20211012