CN113336597A - Slow-release and controlled-release eucalyptus weeding medicinal fertilizer granule and preparation method thereof - Google Patents
Slow-release and controlled-release eucalyptus weeding medicinal fertilizer granule and preparation method thereof Download PDFInfo
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- CN113336597A CN113336597A CN202110733795.7A CN202110733795A CN113336597A CN 113336597 A CN113336597 A CN 113336597A CN 202110733795 A CN202110733795 A CN 202110733795A CN 113336597 A CN113336597 A CN 113336597A
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- Prior art keywords
- fertilizer
- eucalyptus
- release
- pesticide
- controlled
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 210
- 238000013270 controlled release Methods 0.000 title claims abstract description 57
- 239000008187 granular material Substances 0.000 title claims abstract description 53
- 238000009333 weeding Methods 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title abstract description 19
- 244000166124 Eucalyptus globulus Species 0.000 title abstract 4
- 239000002689 soil Substances 0.000 claims abstract description 60
- 230000002363 herbicidal effect Effects 0.000 claims abstract description 46
- 241000196324 Embryophyta Species 0.000 claims abstract description 45
- 239000000575 pesticide Substances 0.000 claims abstract description 44
- 239000004009 herbicide Substances 0.000 claims abstract description 41
- 229920002643 polyglutamic acid Polymers 0.000 claims abstract description 33
- 239000011248 coating agent Substances 0.000 claims abstract description 32
- CAWXEEYDBZRFPE-UHFFFAOYSA-N Hexazinone Chemical compound O=C1N(C)C(N(C)C)=NC(=O)N1C1CCCCC1 CAWXEEYDBZRFPE-UHFFFAOYSA-N 0.000 claims abstract description 28
- 241001474374 Blennius Species 0.000 claims abstract description 27
- 230000000813 microbial effect Effects 0.000 claims abstract description 26
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000004021 humic acid Substances 0.000 claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 22
- 230000006872 improvement Effects 0.000 claims abstract description 21
- 238000000855 fermentation Methods 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 239000010410 layer Substances 0.000 claims abstract description 19
- 230000004151 fermentation Effects 0.000 claims abstract description 18
- 239000011247 coating layer Substances 0.000 claims abstract description 17
- 238000002156 mixing Methods 0.000 claims description 57
- 239000002245 particle Substances 0.000 claims description 52
- 238000001035 drying Methods 0.000 claims description 51
- 238000005507 spraying Methods 0.000 claims description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 31
- 238000009835 boiling Methods 0.000 claims description 28
- 230000001580 bacterial effect Effects 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 17
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 16
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 16
- 241000219927 Eucalyptus Species 0.000 claims description 15
- 239000011230 binding agent Substances 0.000 claims description 14
- 244000063299 Bacillus subtilis Species 0.000 claims description 13
- 235000014469 Bacillus subtilis Nutrition 0.000 claims description 13
- 238000013268 sustained release Methods 0.000 claims description 13
- 239000002202 Polyethylene glycol Substances 0.000 claims description 12
- 229920001223 polyethylene glycol Polymers 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 12
- 241000194108 Bacillus licheniformis Species 0.000 claims description 11
- 229960000892 attapulgite Drugs 0.000 claims description 11
- 239000000440 bentonite Substances 0.000 claims description 11
- 229910000278 bentonite Inorganic materials 0.000 claims description 11
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 11
- 229910052625 palygorskite Inorganic materials 0.000 claims description 11
- 241001465754 Metazoa Species 0.000 claims description 10
- 229920002472 Starch Polymers 0.000 claims description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 10
- 239000004202 carbamide Substances 0.000 claims description 10
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 10
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 10
- 235000011151 potassium sulphates Nutrition 0.000 claims description 10
- 238000007873 sieving Methods 0.000 claims description 10
- 239000012798 spherical particle Substances 0.000 claims description 10
- 239000008107 starch Substances 0.000 claims description 10
- 235000019698 starch Nutrition 0.000 claims description 10
- 230000002459 sustained effect Effects 0.000 claims description 10
- 239000005995 Aluminium silicate Substances 0.000 claims description 9
- 229920001938 Vegetable gum Polymers 0.000 claims description 9
- 235000012211 aluminium silicate Nutrition 0.000 claims description 9
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 9
- 238000010298 pulverizing process Methods 0.000 claims description 9
- 239000005696 Diammonium phosphate Substances 0.000 claims description 8
- 235000019270 ammonium chloride Nutrition 0.000 claims description 8
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 8
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 8
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 8
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 8
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 8
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 8
- 239000006012 monoammonium phosphate Substances 0.000 claims description 8
- 239000001103 potassium chloride Substances 0.000 claims description 8
- 235000011164 potassium chloride Nutrition 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 235000010489 acacia gum Nutrition 0.000 claims description 6
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims description 6
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 6
- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 229920000858 Cyclodextrin Polymers 0.000 claims description 5
- 235000013877 carbamide Nutrition 0.000 claims description 5
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 5
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 4
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 4
- -1 polypropylene carbonate Polymers 0.000 claims description 4
- 229920000379 polypropylene carbonate Polymers 0.000 claims description 4
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 claims description 4
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims description 4
- 241000193744 Bacillus amyloliquefaciens Species 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 15
- 238000000576 coating method Methods 0.000 abstract description 10
- 235000015097 nutrients Nutrition 0.000 abstract description 9
- 230000012010 growth Effects 0.000 abstract description 8
- 241000894006 Bacteria Species 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 239000004480 active ingredient Substances 0.000 abstract description 2
- 238000007789 sealing Methods 0.000 abstract description 2
- 230000003993 interaction Effects 0.000 abstract 1
- 235000021048 nutrient requirements Nutrition 0.000 abstract 1
- 230000008635 plant growth Effects 0.000 abstract 1
- 244000004281 Eucalyptus maculata Species 0.000 description 78
- 239000000047 product Substances 0.000 description 24
- 238000011282 treatment Methods 0.000 description 16
- 235000021049 nutrient content Nutrition 0.000 description 12
- 239000000843 powder Substances 0.000 description 11
- 241000881860 Paenibacillus mucilaginosus Species 0.000 description 9
- 239000007633 bacillus mucilaginosus Substances 0.000 description 9
- 239000004927 clay Substances 0.000 description 8
- 238000001816 cooling Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 230000035558 fertility Effects 0.000 description 6
- 239000003292 glue Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 230000004720 fertilization Effects 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 239000004576 sand Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 108010010803 Gelatin Proteins 0.000 description 4
- 229920000159 gelatin Polymers 0.000 description 4
- 239000008273 gelatin Substances 0.000 description 4
- 235000019322 gelatine Nutrition 0.000 description 4
- 235000011852 gelatine desserts Nutrition 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000012730 sustained-release form Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 240000005020 Acaciella glauca Species 0.000 description 1
- 101800000263 Acidic protein Proteins 0.000 description 1
- 244000099147 Ananas comosus Species 0.000 description 1
- 235000007119 Ananas comosus Nutrition 0.000 description 1
- 241000512259 Ascophyllum nodosum Species 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 235000018185 Betula X alpestris Nutrition 0.000 description 1
- 235000018212 Betula X uliginosa Nutrition 0.000 description 1
- 241000143476 Bidens Species 0.000 description 1
- 240000009226 Corylus americana Species 0.000 description 1
- 235000001543 Corylus americana Nutrition 0.000 description 1
- 235000007466 Corylus avellana Nutrition 0.000 description 1
- 241000508725 Elymus repens Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 239000005562 Glyphosate Substances 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 241000245240 Lonicera Species 0.000 description 1
- 241000219071 Malvaceae Species 0.000 description 1
- 241000199919 Phaeophyceae Species 0.000 description 1
- 241000218657 Picea Species 0.000 description 1
- 240000007263 Pinus koraiensis Species 0.000 description 1
- 235000011615 Pinus koraiensis Nutrition 0.000 description 1
- 235000011609 Pinus massoniana Nutrition 0.000 description 1
- 241000018650 Pinus massoniana Species 0.000 description 1
- 235000008582 Pinus sylvestris Nutrition 0.000 description 1
- 241000183024 Populus tremula Species 0.000 description 1
- 244000018795 Prunus mume Species 0.000 description 1
- 235000011158 Prunus mume Nutrition 0.000 description 1
- 241000681535 Spiraea salicifolia Species 0.000 description 1
- CKUAXEQHGKSLHN-UHFFFAOYSA-N [C].[N] Chemical compound [C].[N] CKUAXEQHGKSLHN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000010564 aerobic fermentation Methods 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 1
- 229940097068 glyphosate Drugs 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000009332 manuring Methods 0.000 description 1
- 239000002068 microbial inoculum Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000009335 monocropping Methods 0.000 description 1
- 235000015816 nutrient absorption Nutrition 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000001839 pinus sylvestris Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000011076 safety test Methods 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 239000003516 soil conditioner Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/40—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting fertiliser dosage or release rate; for affecting solubility
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
- C05G5/37—Layered or coated, e.g. dust-preventing coatings layered or coated with a polymer
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
- C05G5/38—Layered or coated, e.g. dust-preventing coatings layered or coated with wax or resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Soil Sciences (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a controlled-release eucalyptus weeding pesticide-fertilizer granule and a preparation method thereof, wherein the weeding pesticide-fertilizer granule is prepared from the following raw materials in parts by weight: 0.04-0.21% of hexazinone, 30-65% of fertilizer, 0.02-0.05% of microbial agent (the number of effective viable bacteria is more than or equal to 1000 hundred million cfu/g), 0.2-0.5% of gamma-polyglutamic acid, 10-20% of humic acid, 5-10% of seaweed fermentation product, 0.75-1.2% of coating agent and the balance auxiliary material. The preparation method comprises the steps of preparing the pesticide-fertilizer core, coating the coating layer and coating the soil improvement layer. According to the invention, by utilizing the principle of interaction of pesticide and fertilizer, different types of fertilizers and the herbicide active ingredient hexazinone with a sealing effect are compounded for use according to the characteristics of nutrients required by eucalyptus in different periods of growth, and the coating slow release technology is combined, so that the nutrient requirements of fast-growing eucalyptus plant growth are met, and the effect of weed control is also taken into consideration.
Description
Technical Field
The invention relates to the technical field of pesticides, and particularly relates to a controlled-release eucalyptus weeding pesticide-fertilizer granule and a preparation method thereof.
Background
The eucalyptus has the characteristics of strong adaptability, fast growth, barren resistance, strong stress resistance and the like, and is widely planted in the world. At present, eucalyptus has become the main tree species for afforestation in southern areas of China. However, as the growing area of eucalyptus grows larger and the number of successive planting generations increases, the phenomenon that the fertility of soil is not applied is more and more serious. In some areas, due to insufficient land fertility, the eucalyptus is directly caused to generate physiological diseases, and the sustainable management of the eucalyptus artificial forest is directly influenced. Relevant researches show that reasonable fertilization can improve the growth condition of eucalyptus, and the plant height, the breast diameter and the ground diameter are obviously increased. Therefore, reasonable and effective fertilization is one of effective measures for improving the quality of the artificial forest, promoting the fast growth and high yield of the eucalyptus and preventing the decline of the land fertility, and is also one of important means for realizing the sustainable development of the forest land.
Although fertilizers were used in large quantities in the cultivation and planting of eucalyptus in the early 90 s of the 20 th century. However, in the practical application process, problems such as improper fertilizer selection, low fertilizer utilization rate, unsatisfactory fertilizer efficiency and the like exist. Among them, the problems of low fertilizer utilization rate and unsatisfactory fertilizer efficiency are the most prominent. The main reasons are as follows: (1) eucalyptus is mostly planted in areas with fluctuant topography such as mountainous regions, sloping fields and the like, a large amount of rainfall in a short time can cause leaching loss of fertilizer, and nutrients are lost without being absorbed by the eucalyptus in time; (2) the eucalyptus forest is mostly located on hills or hills, the management is relatively extensive, and weeds, miscellaneous irrigation and various vines are easy to overgrow. If these weeds are not controlled in time, a considerable amount of fertilizer is consumed, resulting in waste of fertilizer. Therefore, the method effectively controls weeds and simultaneously prolongs the fertilizer efficiency duration of the fertilizer as far as possible, and is the key for improving the fertilizer utilization rate in the eucalyptus planting process.
The hexazinone belongs to a biocidal herbicide and has low toxicity to people and livestock. Is suitable for tending evergreen coniferous forests, such as young forests of Korean pine, Pinus sylvestris, spruce, Pinus massoniana and the like. Weeding, irrigating, maintaining forest fire-proof lines, forest stand reconstruction and the like before afforestation, and can prevent and kill most monocotyledonous and dicotyledonous weeds and woody plants such as lonicera caprea, Japanese apricot, hazelnut, spiraea salicifolia, acanthopanax, aspen, birch, basswood, northeast China ash, yellow pineapple, walnut fruit and the like. After the herbicide is applied to soil, the herbicide has stable efficacy, is not easy to decompose and has longer lasting period, so the herbicide has a certain sealing effect on weeds and is an excellent effective component of the long-acting forest herbicide.
After the fertilizer is subjected to coating treatment, the nutrient release rate is slower than that of a quick-acting fertilizer or a fertilizer without a coating, the nutrient duration is long, and nutrient loss and waste caused by rainwater, scouring or microbial decomposition due to insufficient absorption of crops after the nutrients are quickly released at one time can be effectively avoided.
Therefore, the controlled-release coating technology is combined with the herbicide and the fertilizer to form the controlled-release herbicide fertilizer, the requirements of eucalyptus forest planting management can be effectively met, and weed prevention and control are achieved while fertilization is carried out. Firstly, the fertilizer utilization rate can be effectively improved, and secondly, the consumption of related manpower, material resources and financial resources caused by weeding can be reduced or avoided. In addition, the microbial agent and the soil conditioner are added into the pesticide-fertilizer particles, so that the effects of effectively improving the soil of the forest land, improving the microbial community structure of the soil and improving the water and fertilizer retention performance of the soil can be achieved.
Disclosure of Invention
The invention overcomes the defects of the existing product, provides the controlled-release eucalyptus weeding medicinal fertilizer granules and the preparation method thereof, and has the advantages of safety, high efficiency, environmental protection, easily obtained raw materials and simple and convenient preparation.
In order to achieve the purpose, the technical scheme of the invention is as follows:
a sustained-release eucalyptus weeding pesticide-fertilizer granule comprises the following components in percentage by mass: 0.04-0.21% of hexazinone, 30-65% of fertilizer, 0.02-0.05% of microbial agent, 0.2-0.5% of gamma-polyglutamic acid, 10-20% of humic acid, 5-10% of seaweed fermentation product, 0.75-1.2% of coating agent and the balance of auxiliary materials.
Further, the herbicide-fertilizer granules comprise a herbicide-fertilizer core, a coating layer and a soil improvement layer which are sequentially arranged from inside to outside, wherein the herbicide-fertilizer core consists of hexazinone, a fertilizer, humic acid, seaweed fermentation products and auxiliary materials; the coating layer comprises a coating agent; the soil improvement layer comprises a microbial agent and gamma-polyglutamic acid.
Further, the fertilizer comprises one or a combination of more of urea, ammonium chloride, ammonium sulfate, monoammonium phosphate, diammonium phosphate, potassium chloride, potassium sulfate, monopotassium phosphate and the like. The selection and the proportion of the fertilizer can be adjusted according to the growth period and the growth condition of the eucalyptus.
Further, the auxiliary material comprises one or a mixture of two of a binder and a filler;
the binder is one or a mixture of more of vegetable gum, animal gum and polyethylene glycol;
the filler is one or a mixture of more of kaolin, bentonite and attapulgite.
Further, the coating agent is one or a mixture of more of Arabic gum, polyvinyl alcohol, cyclodextrin, diphenylmethane diisocyanate and polypropylene carbonate.
Further, the mass ratio of the coating agent to the pesticide fertilizer core is controlled to be 1:80-1: 140.
Further, the microbial agent is one or a mixture of more of bacillus subtilis, bacillus licheniformis and bacillus amyloliquefaciens. The effective viable count of the microbial agent is more than or equal to 1000 hundred million cfu/g.
The preparation method of the controlled-release eucalyptus herbicide fertilizer granules comprises the following steps:
A. preparing a pesticide fertilizer core: pulverizing hexazinone, fertilizer, humic acid, seaweed fermentation product and filler, uniformly mixing, adding binder, fully mixing, and slowly adding the materials into a granulator to prepare spherical particles; drying and sieving to obtain pesticide fertilizer particles with uniform particle size;
B. wrapping the coating layer: dissolving the coating agent by using water or a recyclable volatile organic solvent, uniformly mixing, uniformly spraying the coating agent on the surfaces of the pesticide-fertilizer particles by using a boiling drying spraying device, and drying to obtain coated pesticide-fertilizer particles;
C. wrapping a soil improvement layer: and C, uniformly mixing the microbial agent, the gamma-polyglutamic acid and a proper amount of water, adding a proper amount of starch, uniformly mixing to obtain a mixture bacterial slurry, uniformly spraying the bacterial slurry on the surface of the coated pesticide-fertilizer particles prepared in the step B by using a boiling drying spraying device, and drying to obtain the controlled-release eucalyptus herbicide-fertilizer particles.
The invention also provides application of the controlled-release eucalyptus herbicide fertilizer granules in eucalyptus planting and weeding.
Further, the application specifically comprises that a crescent fertilizing ditch which is 25-35cm long, 15-25cm wide and 5-8cm deep is arranged at a position 20-50cm away from the root of the fast-growing eucalyptus seedling in the upward slope direction, or a fertilizing ditch which is 40-60cm long, 20-40cm wide and 8-10cm deep is arranged between water dripping lines of old plants, the herbicide fertilizer is scattered into the ditch, and soil is covered; the use amount of the controlled-release eucalyptus herbicide fertilizer granules is calculated by the effective component amount of the hexazinone: eucalyptus seedlings (young forest tending period) 0.2-0.5 g/plant, and older plants 0.6-1.3 g/plant.
In view of the above, the present invention has the following remarkable effects:
(1) according to the invention, the enclosed herbicide hexazinone and the fertilizer are scientifically and reasonably combined together, and a sustained-release coating technology is combined, so that the purpose of normally fertilizing eucalyptus is achieved, various forest weeds can be effectively prevented and removed, the fertilizer loss caused by fertilizer competition between weeds and eucalyptus is reduced, and the effective utilization rate of the fertilizer is improved on the premise of ensuring the safety of the pesticide fertilizer to eucalyptus.
(2) The invention is also provided with a soil improvement layer outside the coating layer. The reasonable addition of the microbial agent, especially bacillus microbe, to the fertilizer can effectively improve the unbalance of soil microbial flora caused by continuous cropping or single planting structure, inhibit soil-borne diseases, activate soil nutrients, and increase the content of effective components in soil, especially the content of medium and trace nutrients. Thereby achieving the soil improvement effects of improving soil flora, increasing soil fertility and the like. The gamma-polyglutamic acid has the characteristics of excellent film forming property, plasticity, cohesiveness, moisture retention, biodegradability and the like, and can be used as a soil humectant and a fertility intensifier, so that the water-storing capacity of soil can be effectively enhanced, the nutrient absorption of crops is promoted, the fertilizer utilization rate is increased, the yield is increased, the quality is improved, and the stress resistance of the crops is improved. The organic combination of the microbial inoculum and the gamma-polyglutamic acid can effectively improve the soil microbial community structure of the eucalyptus woodland and improve the water and fertilizer retention performance of the soil. The microbial agent and the gamma-polyglutamic acid are coated on the outer layer of the pesticide fertilizer, so that the pesticide fertilizer is quickly and fully released, and the application effect is further improved. In addition, the coating layer can effectively isolate the pesticide-fertilizer core from the microbial agent, so that the potential influence of the fertilizer or the active ingredients of the herbicide in the pesticide-fertilizer core on the microbial activity is avoided.
(3) The invention takes the microorganisms, the gamma-polyglutamic acid, the humic acid and the seaweed fermentation product added in the herbicide fertilizer granules as soil conditioners, can effectively improve the soil of the forest land, improve the microbial community structure of the soil and improve the water and fertilizer retention performance of the soil, thereby realizing the effect of one fertilizer with multiple purposes.
(4) Because the herbicide fertilizer granules have better weed control effect and longer weed control time, the management cost of eucalyptus planting managers in the aspect of weeding can be effectively reduced, the purpose of reducing the use amount of pesticide and fertilizer is achieved, and the management of eucalyptus planting, quality improvement and efficiency improvement are effectively assisted.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more concise and clear, the present invention is described with reference to the following specific examples, but the present invention is by no means limited to these examples. The following are only preferred embodiments of the present invention, which are intended to illustrate the present invention and should not be construed as limiting the scope of the present invention. It should be understood that any modification, equivalent replacement, and improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
The specific preparation method of the seaweed fermentation product used in this example was: mixing kelp, brown algae, gulfweed and other large-scale seaweeds or leftover materials after deep processing with cellulose decomposition bacteria and acidic protein decomposition bacteria, adjusting the carbon-nitrogen ratio to be within the range of 25: 1-30: 1, stacking the materials into a stack, covering a plastic film for anaerobic fermentation, and controlling the stack temperature to be 55-60 ℃ (stack temperature is larger than 60 ℃ and stack turning treatment is carried out). Anaerobic fermentation for about 30-40 days, uncovering the plastic film, exposing the material to air, and performing facultative aerobic fermentation for 10-15 days. After fermentation, drying, dehydrating and crushing the fermented product for later use.
And (3) other raw materials:
the effective viable count of the bacillus subtilis is more than or equal to 1000 hundred million cfu/g; the effective viable count of the bacillus licheniformis is more than or equal to 1000 hundred million cfu/g; the effective viable count of the bacillus mucilaginosus is more than or equal to 1000 hundred million cfu/g;
gamma-polyglutamic acid with molecular weight of 20000.
Example 1
The controlled-release eucalyptus herbicide fertilizer granule comprises the following components in percentage by mass:
component name | Mass percent (%) |
Hexazinones | 0.04 |
Urea | 10 |
Potassium dihydrogen phosphate | 20 |
Humic acid | 10 |
Fermented product of seaweed | 5 |
Vegetable gum | 2 |
Bentonite clay | 51.74 |
Arabic gum | 1.0 |
Bacillus subtilis | 0.02 |
Gamma-polyglutamic acid | 0.2 |
The preparation method of the controlled-release eucalyptus herbicide fertilizer granule comprises the following steps:
A. preparing a pesticide fertilizer core: the hexazinone, the urea, the monopotassium phosphate, the humic acid, the seaweed fermentation product and the bentonite are crushed and uniformly mixed, then the vegetable gum is added to be used as a binder, and after the mixture is fully mixed, the material is slowly added into a granulator to prepare spherical particles. Boiling, drying and sieving to obtain pesticide fertilizer particles with uniform particle size;
B. wrapping the coating layer: dissolving Arabic gum with a certain amount of water, uniformly mixing, uniformly spraying the coating agent on the surfaces of the pesticide-fertilizer particles by using a boiling drying spraying device, and drying to obtain coated pesticide-fertilizer particles;
C. wrapping a soil improvement layer: mixing a small amount of starch and water according to the weight ratio of 1: and (4) mixing according to the proportion of 25, heating to boil, uniformly stirring, cooling the mixture to room temperature, uniformly mixing the bacillus subtilis and the gamma-polyglutamic acid with the mixture to obtain mixture bacterial slurry, and uniformly spraying the bacterial slurry on the surface of the particle prepared in the step (B) by utilizing boiling drying spraying equipment. Drying to obtain the controlled-release eucalyptus weeding pesticide-fertilizer granules.
The nutrient content of the sustained and controlled release fertilizer obtained in the embodiment is N: P2O5:K2O =4:11:7, can be used as a base fertilizer for seedling planting, and the using method comprises the following steps: a crescent fertilizing ditch which is 30cm long, 20cm wide and 5-8cm deep is formed at a position 30cm away from the upward slope direction of the roots of the fast-growing eucalyptus seedlings, the weeding pesticide fertilizer is spread in the ditch, the dosage and the fertilizing amount of the hexazinone are comprehensively considered, the dosage of the pesticide fertilizer is 500g per plant, and soil covering is carried out.
Example 2
The controlled-release eucalyptus herbicide fertilizer granule comprises the following components in percentage by mass:
component name | Mass percent (%) |
Hexazinones | 0.08 |
Ammonium chloride | 13 |
Monoammonium phosphate | 9 |
Potassium sulfate | 13 |
Humic acid | 12 |
Fermented product of seaweed | 6 |
Animal glue | 1.5 |
Bentonite clay | 44.3 |
Gelatin | 0.8 |
Bacillus licheniformis | 0.03 |
Gamma-polyglutamic acid | 0.3 |
The preparation method of the controlled-release eucalyptus herbicide fertilizer granule comprises the following steps:
A. preparing a pesticide fertilizer core: pulverizing hexazinone, ammonium chloride, monoammonium phosphate, potassium sulfate, humic acid, seaweed fermentation product and bentonite, uniformly mixing, adding animal glue as a binder, fully mixing, slowly adding the materials into a granulator to prepare spherical particles, boiling, drying and sieving to obtain medicinal fertilizer particles with uniform particle size;
B. wrapping the coating layer: dissolving gelatin in a certain amount of water, uniformly mixing, uniformly spraying the coating agent on the surfaces of the pesticide-fertilizer granules by using a boiling drying spraying device, and drying to obtain coated pesticide-fertilizer granules;
C. wrapping a soil improvement layer: mixing a small amount of starch and water according to the weight ratio of 1: and (4) mixing according to the proportion of 25, heating to boil, uniformly stirring, cooling the mixture to room temperature, uniformly mixing the bacillus licheniformis and the gamma-polyglutamic acid to obtain mixture bacterial slurry, and uniformly spraying the bacterial slurry on the surface of the particle prepared in the step (B) by utilizing boiling drying spraying equipment. Drying to obtain the controlled-release eucalyptus weeding pesticide-fertilizer granules.
The nutrient content of the sustained and controlled release fertilizer obtained in the embodiment is N: P2O5:K2O =4:5:7, and the using method comprises the following steps: a crescent fertilizing ditch which is 30cm long, 20cm wide and 5-8cm deep is formed at the position 30cm away from the upward slope direction of the root of the fast-growing eucalyptus seedling, the weeding pesticide fertilizer is scattered in the ditch, the dosage and the fertilizing amount of the hexazinone are comprehensively considered, the dosage of the pesticide fertilizer in the embodiment is 500g per plant, and the soil is covered.
Example 3
The controlled-release eucalyptus herbicide fertilizer granule comprises the following components in percentage by mass:
component name | Mass percent (%) |
Hexazinones | 0.12 |
Ammonium sulfate | 11 |
Diammonium phosphate | 19 |
Potassium chloride | 10 |
Humic acid | 14 |
Fermented product of seaweed | 7 |
Polyethylene glycol | 3 |
Attapulgite powder | 34.24 |
Polyvinyl alcohol | 1.2 |
Bacillus mucilaginosus | 0.04 |
Gamma-polyglutamic acid | 0.4 |
The preparation method of the controlled-release eucalyptus herbicide fertilizer granule comprises the following steps:
A. preparing a pesticide fertilizer core: pulverizing hexazinone, ammonium sulfate, diammonium phosphate, potassium chloride, humic acid, seaweed fermentation product and attapulgite powder, uniformly mixing, adding polyethylene glycol as a binder, fully mixing, slowly adding the materials into a granulator to prepare spherical particles, and sieving after boiling drying to obtain pesticide-fertilizer particles with uniform particle size;
B. wrapping the coating layer: dissolving polyvinyl alcohol with a certain amount of hot water, uniformly mixing, uniformly spraying the coating agent on the surfaces of the pesticide-fertilizer particles by using a boiling drying spraying device, and drying to obtain coated pesticide-fertilizer particles;
C. wrapping a soil improvement layer: mixing a small amount of starch and water according to the weight ratio of 1: and (4) mixing according to a ratio of 25, heating to boil, uniformly stirring, cooling the mixture to room temperature, uniformly mixing the bacillus mucilaginosus, the gamma-polyglutamic acid and a proper amount of water to obtain mixture bacterial pulp, and uniformly spraying the bacterial pulp on the surfaces of the particles prepared in the step (B) by using a boiling drying spraying device. Drying to obtain the controlled-release eucalyptus weeding pesticide-fertilizer granules.
The nutrient content of the sustained and controlled release fertilizer obtained in the embodiment is N: P2O5:K2O =6:10:6, can be used as a base fertilizer for seedling planting, and the using method comprises the following steps: a crescent fertilizing ditch which is 30cm long, 20cm wide and 5-8cm deep is formed at the position 30cm away from the upward slope direction of the root of the fast-growing eucalyptus seedling, the weeding pesticide fertilizer is scattered in the ditch, the dosage and the fertilizing amount of the hexazinone are comprehensively considered, the dosage of the pesticide fertilizer in the embodiment is 400g per plant, and the fast-growing eucalyptus seedling is covered with soil.
Example 4
The controlled-release eucalyptus herbicide fertilizer granule comprises the following components in percentage by mass:
component name | Mass percent (%) |
Hexazinones | 0.16 |
Urea | 28 |
Potassium sulfate | 7 |
Potassium dihydrogen phosphate | 10 |
Humic acid | 16 |
Fermented product of seaweed | 8 |
Vegetable gum | 1.5 |
Animal glue | 0.5 |
Kaolin clay | 20 |
Bentonite clay | Make up the balance |
Cyclodextrin | 0.75 |
Bacillus subtilis | 0.05 |
Gamma-polyglutamic acid | 0.5 |
The preparation method of the controlled-release eucalyptus herbicide fertilizer granule comprises the following steps:
A. preparing a pesticide fertilizer core: pulverizing hexazinone, urea, potassium sulfate, monopotassium phosphate, humic acid, seaweed fermentation product, kaolin and bentonite, uniformly mixing, adding plant gum and animal gum as binders, slowly adding the materials into a granulator after fully mixing to prepare spherical particles, and sieving after boiling drying to obtain medicinal fertilizer particles with uniform particle size;
B. wrapping the coating layer: dissolving cyclodextrin with a certain amount of water, mixing uniformly, and spraying the coating agent on the surface of the pesticide fertilizer particles uniformly by using a boiling drying spraying device. Drying to obtain coated pesticide-fertilizer granules;
C. wrapping a soil improvement layer: mixing a small amount of starch and water according to the weight ratio of 1: and (4) mixing at a ratio of 25, heating to boil, uniformly stirring, cooling the mixture to room temperature, uniformly mixing the bacillus subtilis, the gamma-polyglutamic acid and a proper amount of water to obtain mixture bacterial slurry, and uniformly spraying the bacterial slurry on the surfaces of the particles prepared in the step (B) by using boiling drying spraying equipment. Drying to obtain the controlled-release eucalyptus weeding pesticide-fertilizer granules.
The nutrient content of the sustained and controlled release fertilizer obtained in the embodiment is N: P2O5:K2O =13:5:7, can be used in eucalyptus forests with low fertility, and the using method comprises the following steps: a crescent fertilizing ditch which is 30cm long, 20cm wide and 5-8cm deep is formed at the position 30cm away from the upward slope direction of the root of the fast-growing eucalyptus seedling, the weeding pesticide fertilizer is scattered in the ditch, the dosage and the fertilizing amount of the hexazinone are comprehensively considered, the dosage of the pesticide fertilizer in the embodiment is 250 and 300g per plant, and the soil is covered.
Example 5
The controlled-release eucalyptus herbicide fertilizer granule comprises the following components in percentage by mass:
component name | Mass percent (%) |
Hexazinones | 0.21 |
Urea | 22 |
Diammonium phosphate | 15 |
Potassium sulfate | 13 |
Humic acid | 18 |
Fermented product of seaweed | 9 |
Vegetable gum | 0.5 |
Polyethylene glycol | 2 |
Kaolin clay | 15 |
Attapulgite powder | Make up the balance |
Diphenylmethane diisocyanate | 0.9 |
Bacillus subtilis | 0.01 |
Bacillus licheniformis | 0.01 |
Gamma-polyglutamic acid | 0.5 |
The preparation method of the controlled-release eucalyptus herbicide fertilizer granule comprises the following steps:
A. preparing a pesticide fertilizer core: pulverizing and uniformly mixing hexazinone, urea, diammonium phosphate, potassium sulfate, humic acid, seaweed fermentation product, kaolin and attapulgite powder, adding vegetable gum and polyethylene glycol as binders, slowly adding the materials into a granulator after fully mixing to prepare spherical particles, and sieving after boiling drying to obtain pesticide-fertilizer particles with uniform particle size;
B. wrapping the coating layer: dissolving diphenylmethane diisocyanate by using a certain amount of soybean polyol, uniformly mixing, uniformly spraying the coating agent on the surfaces of the pesticide-fertilizer particles by using a boiling drying spraying device, and drying to obtain coated pesticide-fertilizer particles;
C. wrapping a soil improvement layer: mixing a small amount of starch and water according to the weight ratio of 1: and B, mixing the components according to a ratio of 25, heating to boil, uniformly stirring, cooling the mixture to room temperature, uniformly mixing the bacillus subtilis, the bacillus licheniformis and the gamma-polyglutamic acid with a proper amount of water to obtain mixture bacterial slurry, uniformly spraying the bacterial slurry on the surface of the particle prepared in the step B by using a boiling drying spraying device, and drying to obtain the controlled-release eucalyptus herbicide fertilizer particle.
The nutrient content of the sustained and controlled release fertilizer obtained in the embodiment is N: P2O5:K2O =13:8:7, can be used in the eucalyptus additional manuring, and the using method comprises the following steps: a crescent fertilizing ditch with the length of 30cm, the width of 20cm and the depth of 5-8cm or a fertilizing ditch with the length of 50cm, the width of 30cm and the depth of 8-10cm is arranged at a position 30cm away from the upward slope direction of the root of the seedling of the fast-growing eucalyptus, and the herbicide fertilizer is scattered in the ditchThe dosage and the fertilizing amount of the hexazinone are comprehensively considered, and the dosage of the pesticide fertilizer in the embodiment is as follows: the nursery period of the young forest is 200-.
Example 6
The controlled-release eucalyptus herbicide fertilizer granule comprises the following components in percentage by mass:
component name | Mass percent (%) |
Hexazinones | 0.12 |
Ammonium chloride | 21 |
Monoammonium phosphate | 18 |
Potassium chloride | 16 |
Humic acid | 20 |
Fermented product of seaweed | 10 |
Animal glue | 0.5 |
Polyethylene glycol | 1.5 |
Bentonite clay | 10 |
Attapulgite powder | Make up the balance |
Polypropylene carbonate | 1.1 |
Bacillus subtilis | 0.02 |
Bacillus mucilaginosus | 0.01 |
Gamma-polyglutamic acid | 0.4 |
The preparation method of the controlled-release eucalyptus herbicide fertilizer granule comprises the following steps:
A. preparing a pesticide fertilizer core: pulverizing hexazinone, ammonium chloride, monoammonium phosphate, potassium chloride, humic acid, seaweed fermentation product, bentonite and attapulgite powder, uniformly mixing, adding animal glue and polyethylene glycol as binders, slowly adding the materials into a granulator after fully mixing to prepare spherical particles, and sieving after boiling drying to obtain medicinal fertilizer particles with uniform particle size;
B. wrapping the coating layer: dissolving polypropylene carbonate by using a certain amount of ethyl acetate, uniformly mixing, uniformly spraying the coating agent on the surfaces of the pesticide-fertilizer particles by using a boiling drying spraying device, and drying to obtain coated pesticide-fertilizer particles;
C. wrapping a soil improvement layer: mixing a small amount of starch and water according to the weight ratio of 1: and (4) mixing according to the proportion of 25, heating to boil, uniformly stirring, cooling the mixture to room temperature, uniformly mixing the bacillus subtilis, the bacillus mucilaginosus, the gamma-polyglutamic acid and a proper amount of water to obtain mixture bacterial pulp, and uniformly spraying the bacterial pulp on the surfaces of the particles prepared in the step (B) by utilizing a boiling drying spraying device. Drying to obtain the controlled-release eucalyptus weeding pesticide-fertilizer granules.
The nutrient content of the sustained and controlled release fertilizer obtained in the embodiment is N: P2O5:K2O =8:11:10, can be used in top dressing of eucalyptus, and can effectively promote the height of eucalyptus plants. The using method comprises the following steps: fertilizing furrows with the length of 50cm, the width of 30cm and the depth of 8-10cm are arranged between water dripping lines of the old plants, weeding pesticide fertilizer is scattered in the furrows, the dosage and the fertilizing amount of the hexazinone are comprehensively considered, the dosage of the pesticide fertilizer is 750 plus 1000 g/plant, and then the plants are covered with soil.
Example 7
The controlled-release eucalyptus herbicide fertilizer granule comprises the following components in percentage by mass:
component name | Mass percent (%) |
Hexazinones | 0.21 |
Urea | 31 |
Diammonium phosphate | 9 |
Potassium sulfate | 20 |
Humic acid | 10 |
Fermented product of seaweed | 5 |
Polyethylene glycol | 2 |
Attapulgite powder | 20.25 |
Polyvinyl alcohol | 1.0 |
Cyclodextrin | 1.2 |
Bacillus licheniformis | 0.02 |
Bacillus mucilaginosus | 0.02 |
Gamma-polyglutamic acid | 0.3 |
The preparation method of the controlled-release eucalyptus herbicide fertilizer granule comprises the following steps:
A. preparing a pesticide fertilizer core: pulverizing hexazinone, urea, diammonium phosphate, potassium sulfate, humic acid, seaweed fermentation product and attapulgite powder, uniformly mixing, adding polyethylene glycol as a binder, fully mixing, slowly adding the materials into a granulator to prepare spherical particles, and sieving after boiling drying to obtain pesticide-fertilizer particles with uniform particle size;
B. wrapping the coating layer: dissolving polyvinyl alcohol with a certain amount of hot water, uniformly mixing, uniformly spraying the coating agent on the surfaces of the pesticide-fertilizer particles by using a boiling drying spraying device, and drying to obtain coated pesticide-fertilizer particles;
C. wrapping a soil improvement layer: mixing a small amount of starch and water according to the weight ratio of 1: and (4) mixing according to the proportion of 25, heating to boil, uniformly stirring, cooling the mixture to room temperature, uniformly mixing the bacillus licheniformis, the bacillus mucilaginosus, the gamma-polyglutamic acid and a proper amount of water to obtain mixture bacterial pulp, and uniformly spraying the bacterial pulp on the surfaces of the particles prepared in the step (B) by utilizing a boiling drying spraying device. Drying to obtain the controlled-release eucalyptus weeding pesticide-fertilizer granules.
The nutrient content of the sustained and controlled release fertilizer obtained in the embodiment is N: P2O5:K2O =15:5:11, can be used in top dressing of eucalyptus, and can effectively promote thickening of eucalyptus. The using method comprises the following steps: fertilizing furrows with the length of 50cm, the width of 30cm and the depth of 8-10cm are arranged between water dripping lines of the old plants, weeding pesticide fertilizer is scattered in the furrows, the dosage and the fertilizing amount of the hexazinone are comprehensively considered, the dosage of the pesticide fertilizer in the embodiment is 500-600 g/plant, and then the plants are covered with soil.
Example 8
The controlled-release eucalyptus herbicide fertilizer granule comprises the following components in percentage by mass:
component name | Mass percent (%) |
Hexazinones | 0.2 |
Ammonium chloride | 46 |
Monoammonium phosphate | 8 |
Potassium chloride | 11 |
Humic acid | 20 |
Fermented product of seaweed | 10 |
Vegetable gum | 0.5 |
Animal glue | 0.5 |
Polyethylene glycol | 1.0 |
Kaolin clay | 1.25 |
Arabic gum | 0.6 |
Gelatin | 0.4 |
Bacillus subtilis | 0.01 |
Bacillus licheniformis | 0.02 |
Bacillus mucilaginosus | 0.02 |
Gamma-polyglutamic acid | 0.5 |
The preparation method of the controlled-release eucalyptus herbicide fertilizer granule comprises the following steps:
A. preparing a pesticide fertilizer core: pulverizing hexazinone, ammonium chloride, monoammonium phosphate, potassium chloride, humic acid, seaweed fermentation product and kaolin, uniformly mixing, adding vegetable gum, animal gum and polyethylene glycol as binders, slowly adding the materials into a granulator after fully mixing to prepare spherical particles, and sieving after boiling drying to obtain pesticide-fertilizer particles with uniform particle size;
B. wrapping the coating layer: dissolving arabic gum and gelatin with a certain amount of water, uniformly mixing, uniformly spraying the coating agent on the surfaces of the pesticide-fertilizer granules by using a boiling drying spraying device, and drying to obtain coated pesticide-fertilizer granules;
C. wrapping a soil improvement layer: mixing a small amount of starch and water according to the weight ratio of 1: and (4) mixing according to the proportion of 25, heating to boil, uniformly stirring, cooling the mixture to room temperature, uniformly mixing the bacillus subtilis, the bacillus licheniformis, the bacillus mucilaginosus, the gamma-polyglutamic acid and a proper amount of water to obtain mixture bacterial pulp, and uniformly spraying the bacterial pulp on the surfaces of the particles prepared in the step (B) by using a boiling drying spraying device. Drying to obtain the controlled-release eucalyptus weeding pesticide-fertilizer granules;
the nutrient content of the sustained and controlled release fertilizer obtained in the embodiment is N: P2O5:K2O =13:5:7, can be used in top dressing of eucalyptus, and can effectively promote thickening of eucalyptus. Can be used as a base fertilizer for seedling planting, and the using method comprises the following steps: a crescent fertilizing ditch which is 30cm long, 20cm wide and 5-8cm deep is formed at the position 30cm away from the upward slope direction of the root of the fast-growing eucalyptus seedling, the weeding pesticide fertilizer is scattered in the ditch, the dosage and the fertilizing amount of the hexazinone are comprehensively considered, the dosage of the pesticide fertilizer in the embodiment is 200 and 250g per plant, and the soil is covered.
Example 9
The nitrogen release rate of the sustained and controlled release fertilizer in some embodiments of the invention is determined by referring to the national standard (GB/T) 23348-2009 sustained release fertilizer.
The samples of examples 1, 4, 6, 7 and 8 were used as test samples, and were used as ordinary fertilizers having nutrient contents equivalent to those of the test samples (no gamma-polyglutamic acid, humic acid, seaweed fermentation product, microbial agent and coating agent were added during granulation, and the balance of the excess was made up with an inert filler such as kaolin, bentonite or attapulgite powder, and no coating treatment was performed).
The proportion of the general fertilizer remarks is N: P2O5:K2And (4) proportioning of O.
TABLE 1 comparison of nitrogen nutrient release rates of slow/controlled release fertilizers and general fertilizers according to some examples of the present invention
Example 10
The samples of examples 1, 2, 3, 5 and 6 were used as samples, and the common fertilizer with corresponding nutrient content was used as a sample control (the preparation method of the common fertilizer is shown in example 9, and the ratio of the notes of the common fertilizer is N: P2O5:K2O proportion) and a blank control is additionally arranged, and the control effect of the test sample on weeds and the safety of the test sample on eucalyptus plants under corresponding application conditions are measured.
(1) The method for testing the control effect on weeds comprises the following steps: three replicates were set for each sample treatment and control treatment, each replicate containing two eucalyptus plants. Dividing each eucalyptus into 1 × 1m areas around each eucalyptus, and cleaning weeds around the plants by using a solution of acid and glyphosate. After the cleaning work is finished, the pesticide fertilizer or the contrast common fertilizer is applied to the ground according to the use method. After soil covering, uniformly spreading a mixture of bidens triphylla and couch grass seeds (25 seeds of each weed) in an area of 1 square meter around each eucalyptus plant, and covering a layer of fine soil. Finally, quantitative water is poured. The germination of each treated weed was observed 7 days, 15 days and 30 days after the treatment.
(2) And (3) safety test: and (4) observation.
TABLE 2 controlling effect of the controlled release fertilizer of some examples of the present invention on weeds and safety to eucalyptus
Example 11
2 treatments are set according to different fertilizer varieties, namely treatment of a base fertilizer in one embodiment 8 and treatment of an additional fertilizer in another embodiment 6, and treatment of a common fertilizer in another embodiment 8 and treatment of a base fertilizer in another embodiment 6, wherein the preparation method of the common fertilizer is shown in the embodiment 9, afforestation measures are carried out according to a conventional mode, the base fertilizer is applied during field planting, and the fertilizing amount ensures that the total nutrient content of the fertilizers applied in each treatment is the same. Applying additional fertilizer once at 1.0a of tree age, making crescent fertilization ditch 30cm long, 20cm wide and 5-8cm deep at 30cm upward slope of fast-growing eucalyptus seedling root, spreading quantitative herbicide fertilizer in the ditch, and covering with soil. The plant height and diameter are measured 3 months (0.2 a) after planting, and then the growth index of each eucalyptus treatment is investigated every 0.5 a.
TABLE 3 Effect of different treatments on Eucalyptus Tree height and Tree diameter growth
Example 12
The application amount of the fertilizer is calculated by 1000 g/strain by taking example 6 as a test sample, and comparing the effects of the two fertilizers on soil improvement by taking a common fertilizer (without coating, the microbial agent is directly mixed and granulated with a pesticide fertilizer) containing the same nutrient content, microbial agent dosage and gamma-polyglutamic acid content as a reference. Repeating the treatment for 3 times, taking a soil sample 60 days after the additional fertilization, and detecting the pH value, the EC value and the soil particle size of the soil. Wherein the soil particle size is measured to identify the soil texture. The dividing method of the soil texture refers to the classification standard of soil made in the United states: 1000-2000 μm is extra coarse sand; 500-1000 μm coarse sand; 250-500 mu m is medium sand; 100-250 is fine sand; 50-100 μm is superfine sand; 2-50 μm is powder; less than 2 μm is a sticky particle.
TABLE 4 Effect of different fertiliser treatments on the physicochemical Properties of the soil
The data show that the addition of the microbial agent and the gamma-polyglutamic acid into the pesticide fertilizer or the fertilizer can stabilize the pH value of the soil to a certain extent, slow down the acidification process of the soil, increase the content of clay grains and powder grains of the soil and improve the air permeability, water retention and fertilizer retention performance of the soil to a certain extent. And the microbial agent, the gamma-polyglutamic acid and the pesticide fertilizer core are separated by the coating material, so that the influence of the pesticide fertilizer core on the microbial activity can be effectively avoided, and meanwhile, the gamma-polyglutamic acid can exert the effect on the outer layer of the fertilizer more quickly.
Claims (10)
1. A sustained and controlled release eucalyptus weeding medicinal fertilizer granule is characterized in that,
the herbicide fertilizer granules comprise the following components in percentage by mass: 0.04-0.21% of hexazinone, 30-65% of fertilizer, 0.02-0.05% of microbial agent, 0.2-0.5% of gamma-polyglutamic acid, 10-20% of humic acid, 5-10% of seaweed fermentation product, 0.75-1.2% of coating agent and the balance of auxiliary materials.
2. The controlled-release eucalyptus herbicidal fertilizer granule as set forth in claim 1,
the herbicide fertilizer granules comprise a pesticide fertilizer core, a coating layer and a soil improvement layer which are sequentially arranged from inside to outside, wherein the pesticide fertilizer core consists of hexazinone, a fertilizer, humic acid, seaweed leavening and auxiliary materials; the coating layer comprises a coating agent; the soil improvement layer comprises a microbial agent and gamma-polyglutamic acid.
3. The controlled-release eucalyptus herbicidal fertilizer granule as set forth in claim 1,
the fertilizer comprises one or a combination of more of urea, ammonium chloride, ammonium sulfate, monoammonium phosphate, diammonium phosphate, potassium chloride, potassium sulfate, monopotassium phosphate and the like.
4. The controlled-release eucalyptus herbicide fertilizer granule as claimed in claim 1, wherein the auxiliary material comprises one or a mixture of two of a binder and a filler;
the binder is one or a mixture of more of vegetable gum, animal gum and polyethylene glycol;
the filler is one or a mixture of more of kaolin, bentonite and attapulgite.
5. The controlled-release eucalyptus herbicidal fertilizer granule as set forth in claim 1,
the coating agent is one or a mixture of more of Arabic gum, polyvinyl alcohol, cyclodextrin, diphenylmethane diisocyanate and polypropylene carbonate.
6. The controlled release eucalyptus herbicidal fertilizer granule as set forth in claim 2,
the mass ratio of the coating agent to the pesticide fertilizer core is controlled to be 1:80-1: 140.
7. The controlled-release eucalyptus herbicidal fertilizer granule as set forth in claim 1,
the microbial agent is one or a mixture of more of bacillus subtilis, bacillus licheniformis and bacillus amyloliquefaciens.
8. The method for preparing the controlled-release eucalyptus herbicide fertilizer granule as claimed in any one of claims 1 to 7,
the method comprises the following steps:
A. preparing a pesticide fertilizer core: pulverizing hexazinone, fertilizer, humic acid, seaweed fermentation product and filler, uniformly mixing, adding binder, fully mixing, and slowly adding the materials into a granulator to prepare spherical particles; drying and sieving to obtain pesticide fertilizer particles with uniform particle size;
B. wrapping the coating layer: dissolving the coating agent by using water or a recyclable volatile organic solvent, uniformly mixing, uniformly spraying the coating agent on the surfaces of the pesticide-fertilizer particles by using a boiling drying spraying device, and drying to obtain coated pesticide-fertilizer particles;
C. wrapping a soil improvement layer: and C, uniformly mixing the microbial agent, the gamma-polyglutamic acid and a proper amount of water, adding a proper amount of starch, uniformly mixing to obtain a mixture bacterial slurry, uniformly spraying the bacterial slurry on the surface of the coated pesticide-fertilizer particles prepared in the step B by using a boiling drying spraying device, and drying to obtain the controlled-release eucalyptus herbicide-fertilizer particles.
9. The application of the controlled-release eucalyptus herbicide-fertilizer granules as claimed in any one of claims 1 to 7 in eucalyptus planting and weeding.
10. The application of claim 9, wherein a crescent fertilizing ditch 25-35cm long, 15-25cm wide and 5-8cm deep is opened 20-50cm up-slope from the root of the fast-growing eucalyptus seedling or a fertilizing ditch 40-60cm long, 20-40cm wide and 8-10cm deep is opened between the water dripping lines of the old plant, the herbicide fertilizer is scattered into the ditches, and soil is covered; the use amount of the controlled-release eucalyptus herbicide fertilizer granules is calculated by the effective component amount of the hexazinone: eucalyptus seedlings (young forest tending period) 0.2-0.5 g/plant, and older plants 0.6-1.3 g/plant.
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