CN113287609A - Preparation method of medicament suitable for swimming pool - Google Patents

Preparation method of medicament suitable for swimming pool Download PDF

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Publication number
CN113287609A
CN113287609A CN202110279557.3A CN202110279557A CN113287609A CN 113287609 A CN113287609 A CN 113287609A CN 202110279557 A CN202110279557 A CN 202110279557A CN 113287609 A CN113287609 A CN 113287609A
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Prior art keywords
mass
parts
mixture
mixing
sodium
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CN202110279557.3A
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Chinese (zh)
Inventor
陶波
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Chongqing Zhonglanyou Water Treatment Co ltd
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Chongqing Zhonglanyou Water Treatment Co ltd
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Priority to CN202110279557.3A priority Critical patent/CN113287609A/en
Publication of CN113287609A publication Critical patent/CN113287609A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12Powders or granules
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/32Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/501,3-Diazoles; Hydrogenated 1,3-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/02Sulfur; Selenium; Tellurium; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/42Nature of the water, waste water, sewage or sludge to be treated from bathing facilities, e.g. swimming pools
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/02Specific form of oxidant

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Cosmetics (AREA)

Abstract

The invention discloses a method for preparing a medicament suitable for a swimming pool, which relates to the field of chemical disinfectants and comprises the following specific steps: step (1): the raw materials are prepared according to the following mass portions: 20-25 parts of sodium chlorite and 3-5 parts of nano magnesium carbonate by mass; 10-15 parts by mass of dichloroisocyanuric acid; 25-30 parts by mass of sodium bicarbonate; 2-5 parts by mass of boric acid; 13-15 parts by mass of dibromohydantoin; 2-5 parts by mass of sodium molybdate; 10-15 parts by mass of cobalt salt and 15-25 parts by mass of monoperoxybisulfate; step (2): adding dichloroisocyanuric acid and sodium carbonate into a mixing device in proportion, and mixing to obtain an effervescent mixture for later use. The anti-irritant is obtained by mixing boric acid and sodium molybdate during the preparation, and a film can be formed on the surface of the skin by adding the anti-irritant, so that the disinfectant is effectively prevented from contacting the skin of a human body, and the irritation of the disinfected swimming pool water to the skin is effectively reduced.

Description

Preparation method of medicament suitable for swimming pool
Technical Field
The invention relates to the field of chemical disinfectants, in particular to a preparation method of a medicament suitable for a swimming pool.
Background
At present, the most applied swimming pools are generally chlorine disinfectants, and the common chlorine disinfectants comprise: (1) liquid chlorine (2) calcium hypochlorite (bleaching powder) (3) sodium hypochlorite (high-efficiency bleaching powder, bleaching water) (4) sodium dichloroisocyanurate (sodium perchlorate) (5) trichloroisocyanuric acid (strong chlorine concentrate) (6) bromochlorohydantoin (bromine tablet) (7) chlorine dioxide.
However, these chlorine-based chemical agents have significant disadvantages in that chlorine-based chemical agents are products which are highly irritating to the skin, so that many people are allergic to skin irritation after swimming, and secondly, the existing agents for swimming pools are inconvenient to store and transport after being manufactured.
Disclosure of Invention
The invention aims to: in order to solve the problems of large irritation to human bodies and inconvenient storage and transportation, a preparation method of a medicament suitable for a swimming pool is provided.
In order to achieve the purpose, the invention provides the following technical scheme: a preparation method of a medicament suitable for a swimming pool comprises the following specific steps:
step (1): the raw materials are prepared according to the following mass portions: 20-25 parts of sodium chlorite and 3-5 parts of nano magnesium carbonate by mass; 10-15 parts by mass of dichloroisocyanuric acid; 25-30 parts by mass of sodium bicarbonate; 2-5 parts by mass of boric acid; 13-15 parts by mass of dibromohydantoin; 2-5 parts by mass of sodium molybdate; 10-15 parts by mass of cobalt salt and 15-25 parts by mass of monoperoxybisulfate;
step (2): adding dichloroisocyanuric acid and sodium carbonate into a mixing device in proportion, and mixing to obtain an effervescent mixture for later use;
and (3): adding the effervescent mixture obtained in the step (2), sodium chlorite and 1/2 nanometer magnesium carbonate into a mixing device in proportion for mixing to obtain a mixture A for later use;
and (4): putting the rest 1/2 of nano magnesium carbonate, dibromohydantoin, cobalt salt and monoperoxybisulfate into a mixing device in proportion for mixing to obtain a mixture B for later use;
and (5): proportionally putting boric acid and sodium molybdate into a mixing device for mixing to obtain a mixture C for later use;
and (6): putting the mixture A, the mixture B and the mixture C into a mixing device for mixing to obtain a disinfectant mixture;
and (7): and (4) putting the disinfectant mixture obtained in the step (5) into granulation equipment to prepare granules, and then packaging to obtain the disinfectant for the swimming pool.
Preferably, the mesh number of the particles obtained in the step (7) is 20-25 meshes.
Preferably, the humidity of the production environment in step (7) is controlled to be less than 35% r.h.
Preferably, the mixing time in the step (6) is 25-30 min.
Preferably, in the step (7), the particles of the disinfectant are packaged by using a waterproof and lightproof material or container, and the weight of each packet is 200 g.
Compared with the prior art, the invention has the beneficial effects that: according to the invention, boric acid and sodium molybdate are mixed during production to obtain the anti-irritant, and a film can be formed on the surface of the skin by adding the anti-irritant, so that the disinfectant is effectively prevented from contacting the skin of a human body, and the irritation of the disinfected swimming pool water to the skin is effectively reduced; meanwhile, monoperoxybisulfate is catalyzed by cobalt ions in cobalt salt to generate high-activity free radicals of sulfuric acid, the free radicals of sulfuric acid have high oxidation activity and can react with microorganisms in swimming pool water to destroy substances such as cell membrane lipid layer, protein, carbohydrate, DNA and the like of organisms, so that the aim of killing bacteria and algae organisms is fulfilled, wastes such as urea, ammonia, creatinine, arginine and the like discharged by a human body in the swimming pool can be degraded, harmful disinfection byproducts are not generated at the same time, and the swimming pool is friendly to the human body and the environment; secondly, the invention packages the medicament into small bags, avoids the problem that the medicament is affected with damp or polluted because the packaging bag or the container is repeatedly opened when the traditional big bag is used, so that the storage and the transportation are more convenient, and when the novel large bag is used, the granular medicament is dispersed into water, can be uniformly and rapidly contacted and dissolved with the water, thereby improving the disinfection efficiency and the disinfection effect.
Detailed Description
The first embodiment is as follows:
a preparation method of a medicament suitable for a swimming pool comprises the following specific steps:
step (1): the raw materials are prepared according to the following mass portions: 20 parts by mass of sodium chlorite and 3 parts by mass of nano magnesium carbonate; 10 parts by mass of dichloroisocyanuric acid; 25 parts by mass of sodium bicarbonate; 2 parts by mass of boric acid; 13 parts by mass of dibromohydantoin; 2 parts by mass of sodium molybdate; 10 parts by mass of a cobalt salt and 15 parts by mass of a monoperoxybisulfate salt;
step (2): adding dichloroisocyanuric acid and sodium carbonate into a mixing device in proportion, and mixing to obtain an effervescent mixture for later use;
and (3): adding the effervescent mixture obtained in the step (2), sodium chlorite and 1/2 nanometer magnesium carbonate into a mixing device in proportion for mixing to obtain a mixture A for later use;
and (4): putting the rest 1/2 of nano magnesium carbonate, dibromohydantoin, cobalt salt and monoperoxybisulfate into a mixing device in proportion for mixing to obtain a mixture B for later use;
and (5): proportionally putting boric acid and sodium molybdate into a mixing device for mixing to obtain a mixture C for later use;
and (6): putting the mixture A, the mixture B and the mixture C into a mixing device for mixing to obtain a disinfectant mixture;
and (7): and (4) putting the disinfectant mixture obtained in the step (5) into granulation equipment to prepare granules, and then packaging to obtain the disinfectant for the swimming pool.
In the present invention, the particle size obtained in the step (7) is 20 mesh.
In the invention, the humidity of the production environment in the step (7) is controlled to be less than 35% R.H.
In the present invention, the mixing time in the step (6) is 25 min.
In the invention, in the step (7), the sterilizing medicament particles are packaged by adopting a waterproof and lightproof material or container, and the quantitative amount of each packet is 200 g.
Example two:
step (1): the raw materials are prepared according to the following mass portions: 25 parts by mass of sodium chlorite and 5 parts by mass of nano magnesium carbonate; 15 parts by mass of dichloroisocyanuric acid; 30 parts by mass of sodium bicarbonate; 5 parts by mass of boric acid; 15 parts by mass of dibromohydantoin; 5 parts by mass of sodium molybdate; 15 parts by mass of a cobalt salt and 25 parts by mass of a monoperoxybisulfate salt;
step (2): adding dichloroisocyanuric acid and sodium carbonate into a mixing device in proportion, and mixing to obtain an effervescent mixture for later use;
and (3): adding the effervescent mixture obtained in the step (2), sodium chlorite and 1/2 nanometer magnesium carbonate into a mixing device in proportion for mixing to obtain a mixture A for later use;
and (4): putting the rest 1/2 of nano magnesium carbonate, dibromohydantoin, cobalt salt and monoperoxybisulfate into a mixing device in proportion for mixing to obtain a mixture B for later use;
and (5): proportionally putting boric acid and sodium molybdate into a mixing device for mixing to obtain a mixture C for later use;
and (6): putting the mixture A, the mixture B and the mixture C into a mixing device for mixing to obtain a disinfectant mixture;
and (7): and (4) putting the disinfectant mixture obtained in the step (5) into granulation equipment to prepare granules, and then packaging to obtain the disinfectant for the swimming pool.
In the present invention, the number of the particles obtained in the step (7) is 25.
In the invention, the humidity of the production environment in the step (7) is controlled to be less than 35% R.H.
In the present invention, the mixing time in the step (6) is 30 min.
In the invention, in the step (7), the sterilizing medicament particles are packaged by adopting a waterproof and lightproof material or container, and the quantitative amount of each packet is 200 g.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.

Claims (5)

1. A preparation method of a medicament suitable for a swimming pool comprises the following specific steps:
step (1): the raw materials are prepared according to the following mass portions: 20-25 parts of sodium chlorite and 3-5 parts of nano magnesium carbonate by mass; 10-15 parts by mass of dichloroisocyanuric acid; 25-30 parts by mass of sodium bicarbonate; 2-5 parts by mass of boric acid; 13-15 parts by mass of dibromohydantoin; 2-5 parts by mass of sodium molybdate; 10-15 parts by mass of cobalt salt and 15-25 parts by mass of monoperoxybisulfate;
step (2): adding dichloroisocyanuric acid and sodium carbonate into a mixing device in proportion, and mixing to obtain an effervescent mixture for later use;
and (3): adding the effervescent mixture obtained in the step (2), sodium chlorite and 1/2 nanometer magnesium carbonate into a mixing device in proportion for mixing to obtain a mixture A for later use;
and (4): putting the rest 1/2 of nano magnesium carbonate, dibromohydantoin, cobalt salt and monoperoxybisulfate into a mixing device in proportion for mixing to obtain a mixture B for later use;
and (5): proportionally putting boric acid and sodium molybdate into a mixing device for mixing to obtain a mixture C for later use;
and (6): putting the mixture A, the mixture B and the mixture C into a mixing device for mixing to obtain a disinfectant mixture;
and (7): and (4) putting the disinfectant mixture obtained in the step (5) into granulation equipment to prepare granules, and then packaging to obtain the disinfectant for the swimming pool.
2. The method as claimed in claim 1, wherein the medicament is prepared by the steps of: the mesh number of the particles obtained in the step (7) is 20-25 meshes.
3. The method as claimed in claim 1, wherein the medicament is prepared by the steps of: and (3) controlling the humidity of the production environment in the step (7) to be less than 35% R.H.
4. The method as claimed in claim 1, wherein the medicament is prepared by the steps of: and (3) mixing time in the step (6) is 25-30 min.
5. The method as claimed in claim 1, wherein the medicament is prepared by the steps of: in the step (7), the disinfection medicament particles are packaged by adopting a waterproof and lightproof material or container, and the quantitative amount of each packet is 200 g.
CN202110279557.3A 2021-03-16 2021-03-16 Preparation method of medicament suitable for swimming pool Pending CN113287609A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110279557.3A CN113287609A (en) 2021-03-16 2021-03-16 Preparation method of medicament suitable for swimming pool

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Application Number Priority Date Filing Date Title
CN202110279557.3A CN113287609A (en) 2021-03-16 2021-03-16 Preparation method of medicament suitable for swimming pool

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Publication Number Publication Date
CN113287609A true CN113287609A (en) 2021-08-24

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101475245A (en) * 2008-10-22 2009-07-08 大连海事大学 Swimming pool water disinfection method
CN104115837A (en) * 2013-04-25 2014-10-29 江苏三仪胜意药业有限公司 Preparation method of ready-to-use disinfection algicide for swimming pools
CN107306973A (en) * 2017-08-17 2017-11-03 山东大明消毒科技有限公司 A kind of swimming pool disinfectant and its preparation method and application
CN107593720A (en) * 2017-09-22 2018-01-19 河北冀衡化学股份有限公司 A kind of compound disinfecting tablet and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101475245A (en) * 2008-10-22 2009-07-08 大连海事大学 Swimming pool water disinfection method
CN104115837A (en) * 2013-04-25 2014-10-29 江苏三仪胜意药业有限公司 Preparation method of ready-to-use disinfection algicide for swimming pools
CN107306973A (en) * 2017-08-17 2017-11-03 山东大明消毒科技有限公司 A kind of swimming pool disinfectant and its preparation method and application
CN107593720A (en) * 2017-09-22 2018-01-19 河北冀衡化学股份有限公司 A kind of compound disinfecting tablet and preparation method thereof

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Application publication date: 20210824