CN110780504A - Electronic paper display method based on liquid flow control - Google Patents

Electronic paper display method based on liquid flow control Download PDF

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Publication number
CN110780504A
CN110780504A CN201911034044.5A CN201911034044A CN110780504A CN 110780504 A CN110780504 A CN 110780504A CN 201911034044 A CN201911034044 A CN 201911034044A CN 110780504 A CN110780504 A CN 110780504A
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layer
liquid
electronic paper
display
color
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王元庆
殷光军
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Nanjing University
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Nanjing University
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Priority to PCT/CN2019/000217 priority patent/WO2021081684A1/en
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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/165Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
    • G02F1/166Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect
    • G02F1/167Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect by electrophoresis
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/165Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
    • G02F1/1675Constructional details
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/165Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
    • G02F1/1675Constructional details
    • G02F1/1679Gaskets; Spacers; Sealing of cells; Filling or closing of cells
    • G02F1/1681Gaskets; Spacers; Sealing of cells; Filling or closing of cells having two or more microcells partitioned by walls, e.g. of microcup type

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Molecular Biology (AREA)
  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)

Abstract

The invention discloses an electronic paper display method based on liquid flow control, wherein electronic paper forms a one-dimensional or two-dimensional matrix by microstructures, each microstructure can be independently controlled, the deformation of the microstructure is controlled in an electronic mode, the change of pressure distribution inside the microstructure is adjusted, the flowing direction of liquid is controlled, an electronic control deformation microstructure is provided with a display cavity and a storage cavity, liquid in the display cavity can be observed by a viewer, liquid in the storage cavity cannot be observed by the viewer, the liquid flows between the display cavity and the storage cavity under the action of the deformation of the microstructures, the liquid is generally colored liquid, and the capacity of the liquid in the display cavity is adjusted through the deformation of the microstructures, so that the color change of the microstructures is adjusted.

Description

Electronic paper display method based on liquid flow control
Technical Field
The invention relates to the technical field of display electronic products, in particular to an electronic paper display method based on liquid flow control.
Background
With the development of science and technology, people have higher and higher requirements on display equipment, wherein flexible display is a main requirement, and the evolution process of the display equipment of human beings is brought back to the beginning, and people can find that the requirements on the display effect of the display equipment are higher and higher, and the requirements on the volume, the weight and the form of the display equipment are higher and higher. Flexible displays are becoming a hot spot for research in the field of information displays.
Polyvinyl chloride (PVC) gel is an elastic material that is highly transparent, has good flexibility, and has negligible film surface deformation, and is a jelly-like, soft dielectric material that is formed by mixing PVC powder and a plasticizer. With the voltage rise, the PVC gel has obvious deformation effect, and after the voltage is removed, the PVC gel is restored to the initial state.
The prepared electronic paper structure based on liquid flow control can reflect natural light images and can also be matched with backlight images to display the images, and curling can be realized under the condition that a PET material is used as a base material and a protective layer.
Disclosure of Invention
The purpose of the invention is: the electronic paper display method based on liquid flow control is provided, wherein the electronic paper forms a one-dimensional or two-dimensional matrix by microstructures, each microstructure can be independently controlled, the deformation of the microstructures is controlled in an electronic mode, the change of pressure distribution inside the microstructures is adjusted, the flowing direction of liquid is controlled, the electronic control deformation microstructures are provided with a display cavity and a storage cavity, the liquid in the display cavity can be observed by a viewer, the liquid in the storage cavity cannot be observed by the viewer, the liquid flows between the display cavity and the storage cavity under the effect of the deformation of the microstructures, the liquid is generally colored liquid, and the capacity of the liquid in the display cavity is adjusted through the deformation of the microstructures, so that the color change of the microstructures is adjusted.
The electric control deformation microstructure can be formed by using a polyvinyl chloride (PVC) gel film layer to form a micro-cup structure arranged in a matrix, the PVC gel film layer can be an independent micro-structure layer and can also be attached to a base material, electrodes are arranged in the micro-cup structure, driving voltage can be applied to two ends of each electrode, the shape of the micro-cup structure is changed under the action of the voltage, the electronic paper structure comprises four layers which are respectively a base material layer, a control layer, a display layer and a protective layer, and an electric control deformation microstructure is arranged between the control layer and the display layer, namely a micro-cup structure array.
The substrate layer of the electronic paper structure is an ITO film with PET as a substrate, or glass plated with an ITO layer, or a metal thin film (for example, stainless steel).
The control layer is made into a microcup structure by PVC gel, liquid pigment is distributed in each microcup to form a display layer, a leuco matrix is distributed above the microcups (namely the lower surface of the protective layer), the leuco matrix is an opaque area and is used for shielding the pigment entering the lower part of the leuco matrix from being visible, and the color of the leuco matrix can be white, black or other opaque colors.
The control layer of the electronic paper structure is composed of an electric control microstructure, and under the control of voltage, the micro-cup structure deforms to different degrees along with the change of an electric field, so that the gray value electric control change of pixels of the electronic paper is formed, and the aim of displaying gray images is fulfilled.
The electric control microstructure is formed by etching a micro conductive electrode structure on the upper surface of the substrate layer and the lower surface ITO layer of the protective layer and applying different voltages to form a driving electric field.
The display layer comprises liquid color material, and for monochromatic demonstration, the display layer comprises single liquid color material, and for the colored demonstration, the display layer comprises multiple liquid color material to the full-color is constituteed to the mode of space colour mixture, generally adopts 3 ~ 4 kinds of colours.
The protective layer of the electronic paper structure is an ITO film with PET as a base material or glass plated with an ITO layer.
The upper surface of the substrate layer and the lower surface of the protective layer are of electrode structures, each microcup is composed of corresponding driving electrodes, and voltage is applied to two ends of each electrode to form a driving electric field. Under the action of an electric field in the structure of the microcup, the PVC gel deforms. The local deformation of the microcup control layer changes the structure inside the microcups, thereby driving the distribution of the liquid pigment to change. Under the action of voltage, the PVC gel deforms, the liquid pigment is extruded towards the direction of the leuco matrix, the area of the pigment in the area with the same size can be changed under the action of voltage relative to a micro-cup, and the plane area of the micro-cup structure is A 0The color region which can be observed is A 1Then, the duty ratio of the color region is D:
Figure BSA0000193348430000021
the color duty cycle D determines the color saturation SA of the microcup structure:
SA=k(d,t)*D (2)
where k is a color saturation factor, the value of which is related to the thickness d, the transparency t of the pigment.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below.
FIG. 1 is a schematic diagram of a liquid flow control-based electronic paper structure according to the present invention;
FIG. 2 is a schematic diagram of the shape of a PVC gel microcup in a gray state 1 displayed on the electronic paper based on liquid flow control according to the present invention;
FIG. 3 is a schematic diagram of the morphology of a PVC gel microcup in a gray state 2 displayed on the liquid flow control-based electronic paper according to the present invention;
fig. 4 is a schematic view of the morphology of the PVC gel microcups in gray state 3 displayed on the liquid flow control-based electronic paper according to the present invention.
Detailed Description
The technical solution of an embodiment of the present invention will be clearly and completely described below with reference to the accompanying drawings. It should be noted that the following examples are given for illustrative purposes only and are not to be construed as limiting the scope of the present invention, and that the skilled person in the art will be able to make various insubstantial modifications and adaptations of the present invention based on the above disclosure.
The electronic paper display method based on liquid flow control comprises the steps that the electronic paper forms a one-dimensional or two-dimensional matrix by microstructures, each microstructure can be controlled independently, deformation of the microstructures is controlled in an electronic mode, change of pressure distribution inside the microstructures is adjusted, the flowing direction of liquid is controlled, an electronic control deformation microstructure is provided with a display cavity and a storage cavity, liquid in the display cavity can be observed by a viewer, liquid in the storage cavity cannot be observed by the viewer, the liquid flows between the display cavity and the storage cavity under the effect of deformation of the microstructures, the liquid is generally colored liquid, and the capacity of the liquid in the display cavity is adjusted through deformation of the microstructures, so that color change of the microstructures is adjusted.
The electric control deformation microstructure can be formed by using a polyvinyl chloride (PVC) gel film layer to form a micro-cup structure arranged in a matrix, the PVC gel film layer can be an independent micro-structure layer and can also be attached to a base material, electrodes are arranged in the micro-cup structure, driving voltage can be applied to two ends of each electrode, the shape of the micro-cup structure is changed under the action of the voltage, the electronic paper structure comprises four layers, as shown in figure 1, the four layers are respectively a base material layer, a control layer, a display layer and a protective layer, and an electric control deformation microstructure is arranged between the control layer and the display layer, namely, a micro-cup structure array.
Firstly, polyvinyl chloride (PVC) powder and dibutyl adipate (DBA) are mixed into jelly-shaped soft PVC gel according to the mass ratio of 1: 9, and the PVC gel is coated on an IPS electrode in a spinning mode to prepare a PVC gel micro-cup array structure. These microcups are simple and compact in structure, and do not twist due to the effect of gravity when placed vertically, since the film is firmly adhered to the substrate.
The substrate layer 1 of the electronic paper structure is an ITO film with PET as a substrate or glass plated with an ITO layer.
The control layer 2 is a microcup structure made of PVC gel, liquid pigment is distributed in each microcup to form a display layer 3, and a leuco matrix 4 is distributed above the microcups (namely the lower surface of the protective layer 5). The color matrix is an opaque region that blocks the pigment from view below the color matrix, which may be white, black, or other opaque color.
The control layer of the electronic paper structure is composed of an electric control microstructure, and under the control of voltage, the micro-cup structure deforms to different degrees along with the change of an electric field, so that the gray value electric control change of pixels of the electronic paper is formed, and the aim of displaying gray images is fulfilled. The electric control microstructure is formed by etching a micro conductive electrode structure on the upper surface of the substrate layer and the lower surface ITO layer of the protective layer and applying different voltages to form a driving electric field.
The display layer 3 is composed of liquid color materials, and for monochromatic display, the display layer is composed of single liquid color materials, and for color display, the display layer is composed of multiple liquid color materials, and forms full color in a spatial color mixing mode, generally adopting 3-4 colors.
The protective layer 5 of the electronic paper structure is an ITO film with PET as a base material or glass plated with an ITO layer.
The electronic paper display process based on liquid flow control is as follows:
the upper surface of the substrate layer and the lower surface of the protective layer are both of electrode structures carved by an ITO film, each PVC microcup is composed of corresponding driving electrodes, and direct-current voltage is applied to two ends of each electrode to form a driving electric field. Under the action of the driving electric field of the microcup structure, the PVC gel is deformed. The microcups control local deformation of the layer 2, which changes the internal structure of the microcups, thus driving the distribution of the liquid pigment to change, the liquid pigment is uniformly distributed in the microcups in the case of displaying the gray state 1 as shown in fig. 2. In the case of gray state 2 as shown in fig. 3, the liquid pigment is pushed in the direction of the leuco matrix, the area far from the leuco matrix becomes thinner or even completely free of pigment, and the area near the leuco matrix becomes thicker. In the case of display grey state 3 as shown in fig. 4, the liquid pigment is squeezed completely under the leuco matrix.
According to the examples of fig. 2, 3 and 4, the voltage application can change the area of the pigment in the same size area relative to a micro-cup, thereby obtaining better color display effect and higher color saturation.
Although the present invention has been described with reference to the preferred embodiments, it is not intended to be limited thereto. It will be apparent to those skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope of the invention as defined in the appended claims.

Claims (8)

1. The electronic paper display method based on liquid flow control is characterized in that the electronic paper is formed into a one-dimensional or two-dimensional matrix by microstructures, each microstructure can be controlled independently, deformation of the microstructures is controlled in an electronic mode, change of pressure distribution inside the microstructures is adjusted, the flowing direction of liquid is controlled, an electronic control deformation microstructure is provided with a display cavity and a storage cavity, liquid in the display cavity can be observed by a viewer, liquid in the storage cavity cannot be observed by the viewer, the liquid flows between the display cavity and the storage cavity under the effect of deformation of the microstructures, the liquid is generally colored liquid, and the capacity of the liquid in the display cavity is adjusted through deformation of the microstructures, so that color change of the microstructures is adjusted.
2. The electronic paper display method based on liquid flow control of claim 1, wherein the electrically controlled deformable microstructure is formed by a polyvinyl chloride (PVC) gel film layer, forming a matrix-arranged micro-cup structure, the PVC gel film layer can be an independent micro-structural layer or can be attached to a substrate, an electrode is disposed in the micro-cup structure, a driving voltage can be applied to two ends of the electrode, the shape of the micro-cup structure changes under the action of the voltage, the electronic paper structure comprises four layers, which are a substrate layer, a control layer, a display layer and a protective layer, and an electrically controlled deformable microstructure, namely an array of the micro-cup structure, is disposed between the control layer and the display layer.
3. The method as claimed in claim 2, wherein the substrate layer of the electronic paper structure is an ITO film with PET as a substrate, or glass coated with an ITO layer, or a metal film (such as stainless steel).
4. The liquid flow control-based electronic paper display method according to claim 2, wherein the control layer of the electronic paper structure is made of PVC gel to form a microcup structure, liquid pigment is distributed in each microcup to form a display layer, a color matrix is distributed above the microcups (i.e., on the lower surface of the protective layer), the color matrix is an opaque region for blocking the pigment entering below the color matrix from being visible, and the color of the color matrix can be white, black or other opaque colors.
5. The electronic paper display method based on liquid flow control of claim 2, wherein the control layer of the electronic paper structure is composed of an electronic control microstructure, and under voltage control, the microcup structure deforms to different degrees along with the change of an electric field, so that the gray value of the pixels of the electronic paper is changed in an electronic control manner, and the purpose of displaying gray images is achieved.
6. The electronic paper display method based on liquid flow control of claim 5, wherein the electric control microstructure is a micro conductive electrode structure engraved on the ITO layer on the upper surface of the substrate layer and the ITO layer on the lower surface of the protective layer, and a driving electric field is formed by applying different voltages.
7. The electronic paper display method based on liquid flow control of claim 4, wherein the display layer is composed of liquid color materials, for monochrome display, the display layer is composed of a single liquid color material, for color display, the display layer is composed of multiple liquid color materials, and full color is composed by spatial color mixing, and generally 3 to 4 colors are adopted.
8. The electronic paper display method based on liquid flow control as claimed in claim 2, wherein the protective layer of the electronic paper structure is an ITO film with PET as a substrate, or glass coated with an ITO layer.
CN201911034044.5A 2019-10-28 2019-10-28 Electronic paper display method based on liquid flow control Pending CN110780504A (en)

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JP7476718B2 (en) 2020-08-12 2024-05-01 三菱ケミカル株式会社 Light control materials

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