CN110592578A - Composite material - Google Patents

Composite material Download PDF

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Publication number
CN110592578A
CN110592578A CN201910835397.9A CN201910835397A CN110592578A CN 110592578 A CN110592578 A CN 110592578A CN 201910835397 A CN201910835397 A CN 201910835397A CN 110592578 A CN110592578 A CN 110592578A
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CN
China
Prior art keywords
steel pipe
ceramic
composite material
alkaline earth
mass
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Pending
Application number
CN201910835397.9A
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Chinese (zh)
Inventor
刘海波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huageng New Material Technology (jiaxing) Co Ltd
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Huageng New Material Technology (jiaxing) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN201910835397.9A priority Critical patent/CN110592578A/en
Publication of CN110592578A publication Critical patent/CN110592578A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/08Coating starting from inorganic powder by application of heat or pressure and heat
    • C23C24/10Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3409Boron oxide, borates, boric acids, or oxide forming salts thereof, e.g. borax
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite

Abstract

The invention provides a composite material, and a preparation method of the composite material comprises the following steps: 1) providing a ceramic material and a steel pipe; 2) and forming a ceramic layer lining the steel pipe by heating the steel pipe, heating and melting the ceramic material and cooling, wherein the ceramic layer contains diboron trioxide, and the mass percentage of the diboron trioxide is 15-20%. The ceramic layer of the ceramic-lined steel pipe provided by the invention has few bubbles and strong adhesive force.

Description

Composite material
Technical Field
The invention relates to a composite material, in particular to a steel pipe lined with ceramic.
Background
The current compounding methods of metal materials and inorganic non-metal materials mainly comprise a self-propagating high-temperature synthesis method, a thermal spraying method, physical vapor deposition, chemical vapor deposition, enamel and the like.
The self-propagating high-temperature synthesis method is a new process for preparing boride, carbide, nitride, silicide and intermetallic compound materials by maintaining self-propagation of combustion waves by using an exothermic reaction between raw materials, and was originally invented by a.g. merzhanov et al, russian chemico-physical research institute. Since the self-propagating high-temperature synthesis technology is generated, the foreign countries have made great progress on material preparation processes and equipment, and materials such as TiB2, TiC, MoSi2 and the like are successfully produced in large quantities by adopting the technology, and the technology is the most advanced in Russia and the technology level in the United states. However, the synthesis process has serious environmental pollution, the technological process is difficult to control, the product porosity is high, the inorganic non-metallic material layer is always cracked, and the potential cracking risk exists. Therefore, the product can be used for wear resistance, but is difficult to be used for corrosion prevention.
The thermal spraying method of inorganic nonmetallic materials refers to a series of processes in which finely dispersed inorganic nonmetallic coating materials are deposited in a molten or semi-molten state on a prepared substrate surface to form a certain sprayed deposition layer. It is a technique that inorganic non-metal powder or inorganic non-metal material is heated to molten or semi-molten state by using a certain heat source (such as electric arc, plasma spraying or combustion flame, etc.), and then sprayed onto the surface of the pretreated substrate at a certain speed by means of flame flow itself or compressed air, and deposited to form surface coatings with various functions. This technique has no potential risk of cracking relative to self-propagating high temperature synthesis, but has higher porosity and very low bond strength. The corrosion resistance and the wear resistance of the material are general, and the characteristic of stronger performance of inorganic non-metallic materials is difficult to develop.
Physical vapor deposition and chemical vapor deposition can form a layer of dense inorganic non-metallic material film on the surface of the substrate, but the cost is very high, and the method is not suitable for mass production.
The enamel is inorganic glass enamel coated on the surface of a metal base blank. The enamel coating on the metal surface can prevent the metal from rusting, so that the metal can not form an oxide layer on the surface when being heated and can resist the corrosion of various liquids. The enamel product is safe, non-toxic, easy to wash and clean, and may be used widely as diet utensil and washing utensil in daily life. The enamel layer can also endow the product with beautiful appearance and serve people's life. Therefore, the enamel product has both the strength of metal, the gorgeous appearance of the enamel and the performance of chemical erosion resistance. However, enamel products are becoming more and more rare in recent years, mainly because the surface enamel layer is easily broken, cracks are easily generated when products with larger volume are made, and the like, especially when the thermal expansion coefficient of the enamel is far from that of the metal material of the base layer.
How to overcome the defects of the various schemes can form a layer of compact and uniform inorganic non-metallic material layer with high toughness and strength, particularly a ceramic layer, an enamel layer, a glass layer, a glaze layer and the like on the surface of metal, so that the inorganic non-metallic material layer has wear resistance, corrosion resistance and certain thermal shock resistance and shock resistance, and is a problem to be solved urgently.
The present application thus proposes a completely new, very economical and high-quality solution for depositing a layer of inorganic, non-metallic material, such as ceramic, on metal pipes and sheets.
Disclosure of Invention
In view of the above-mentioned drawbacks of the prior art, the present invention provides a new composite material, and aims to solve the technical problem of lining a ceramic layer on a metal pipe.
In order to solve the problems, the invention adopts the technical scheme that: a composite material, the method of making the composite material comprising the steps of:
1) providing a ceramic material and a steel pipe;
2) forming a ceramic layer lining the steel pipe by heating the steel pipe, heating to melt the ceramic material, and cooling,
the ceramic layer contains diboron trioxide, and the mass percentage of the diboron trioxide is 15% -20%.
Preferably, the mass percentage of the diboron trioxide is 17-18%.
Preferably, the ceramic layer comprises kaolin and an alkaline earth.
Preferably, the ratio of the kaolin to the alkaline earth in percentage by mass is: 0.8 to 1.2.
Preferably, the alkaline earth contains aluminum oxide, and the mass percentage of the aluminum oxide in the alkaline earth is 35-50%.
Preferably, the mass percentage content of the aluminum oxide in the alkaline earth is 38-42%.
Preferably, the alkaline earth contains silica, and the mass content of silica in the alkaline earth is 30% or more.
Preferably, the ceramic material is provided in the form of a ceramic powder.
Preferably, the method for manufacturing the ceramic-lined steel pipe comprises the following steps: mixing ceramic powder with liquid to obtain a mixture, coating the mixture on the surface of the steel tube substrate, and drying to make the ceramic powder adhere to the surface of the steel tube substrate.
The invention has the beneficial effects that: the ceramic layer of the steel pipe lined with the ceramic prepared by the invention has less bubbles and strong adhesive force.
The conception, the specific structure, and the technical effects produced by the present invention will be further described below to fully understand the objects, the features, and the effects of the present invention.
Detailed Description
The invention is further illustrated below with reference to specific examples.
Example 1
(1) One embodiment of a steel pipe made in accordance with the principles of the present invention
(a) Selection of materials
The steel pipe substrate is made of steel pipe with the inner diameter of 60mm, the steel pipe is made of high-quality carbon structural steel with the steel grade of 45, and the length of the steel pipe is about 1 m.
The anti-corrosion material is ceramic powder, the size of the ceramic powder is more than 300 meshes, the components comprise 50 parts of kaolin clay and 50 parts of alkaline earth in parts by mass, the kaolin clay comprises 40% of aluminum oxide and 45% of silicon dioxide in parts by weight, and a small amount of potassium oxide, calcium oxide and silicate materials. Then adding diboron trioxide into the ceramic powder, so that the mass percent of the diboron trioxide is 17% of the whole anticorrosive material. The amount of the anticorrosive material is 0.75g/cm2A meter (comprising the spool mentioned in step (c)).
(b) Rust and dust removal
And carrying out internal rust removal and dust removal treatment on the steel pipe. The methods of removing rust (e.g., removing rust with an iron brush) and removing dust (e.g., air blowing treatment) employed in the prior art are both applicable to this embodiment. After the rust removal treatment, the quality of the iron oxide on the inner wall of the steel pipe is not higher than 1 gram per square meter.
(c) Pipeline port pretreatment
Short pipes made of corrosion-resistant nickel-based alloy and having the same diameter and thickness as the steel pipe are provided, and the two short pipes are welded to the two ends of the steel pipe respectively. The welding methods used in the prior art are all suitable for this embodiment. The short pipes at the two ends of the steel pipe are used for welding the two steel pipes when the pipeline is laid.
(d) Coating of corrosion-resistant materials
And (3) pouring the anticorrosive material on the inner wall of the steel pipe uniformly, and scraping the anticorrosive material off the short pipe (for example, reserving 2mm) which does not need to be lined partially.
(e) Heating and cooling
Rotating the steel pipe (rotating speed is proper for promoting the anticorrosive material to be uniformly distributed on the inner wall of the steel pipe by the centrifugal force of the steel pipe), enabling the steel pipe to pass through a medium-frequency heater at a constant speed (heating the steel pipe to about 1100 ℃, moving speed is proper for melting the intermediate material and uniformly attaching the intermediate material on the pipe wall), and then naturally cooling.
(2) Comparative examples of the above examples
(a) Selection of materials
The steel pipe substrate is made of steel pipe with the inner diameter of 60mm, the steel pipe is made of high-quality carbon structural steel with the steel grade of 45, and the length of the steel pipe is about 1 m.
The anti-corrosion material is ceramic powder, the size of the ceramic powder is more than 300 meshes, the components comprise 50 parts of kaolin clay and 50 parts of alkaline earth in parts by mass, the kaolin clay comprises 40% of aluminum oxide and 45% of silicon dioxide in parts by weight, and a small amount of potassium oxide, calcium oxide and silicate materials. The amount of the anticorrosive material is 0.75g/cm2A meter (comprising the spool mentioned in step (c)).
(b) Rust and dust removal
And carrying out internal rust removal and dust removal treatment on the steel pipe. The methods of removing rust (e.g., removing rust with an iron brush) and removing dust (e.g., air blowing treatment) employed in the prior art are both applicable to this embodiment. After the rust removal treatment, the quality of the iron oxide on the inner wall of the steel pipe is not higher than 1 gram per square meter.
(c) Pipeline port pretreatment
Short pipes made of corrosion-resistant nickel-based alloy and having the same diameter and thickness as the steel pipe are provided, and the two short pipes are welded to the two ends of the steel pipe respectively. The welding methods used in the prior art are all suitable for this embodiment. The short pipes at the two ends of the steel pipe are used for welding the two steel pipes when the pipeline is laid.
(d) Coating of corrosion-resistant materials
And (3) pouring the anticorrosive material on the inner wall of the steel pipe uniformly, and scraping the anticorrosive material off the short pipe (for example, reserving 2mm) which does not need to be lined partially.
(e) Heating and cooling
Rotating the steel pipe (rotating speed is proper for promoting the anticorrosive material to be uniformly distributed on the inner wall of the steel pipe by the centrifugal force of the steel pipe), enabling the steel pipe to pass through a medium-frequency heater at a constant speed (heating the steel pipe to about 1100 ℃, moving speed is proper for melting the intermediate material and uniformly attaching the intermediate material on the pipe wall), and then naturally cooling.
(3) Comparison of the Performance of the products of the examples of the invention with that of the products of the comparative examples
The products of the examples of the invention and the products of the comparative examples are cut into small sections of about 10cm, and performance detection is carried out.
(a) Thickness of the layer of corrosion-resistant material
The thickness of the anticorrosive material layer was about 3mm for both the products of examples of the present invention and the products of comparative examples.
(b) Anticorrosive material layer detection
The anticorrosive material layer of the product of the comparative example is observed by naked eyes and detected by electric sparks (1-2 ten thousand volts) to find a large amount of bubbles or cracks, and a plurality of cracks appear.
The number of bubbles in the anticorrosive material layer of the product of the comparative example is slightly reduced, and the crack is greatly reduced.
(c) Adhesion test
The impact of the example product and the example product of the invention shows that the ceramic layer of the example product of the invention is kept intact when the ceramic layer of the example product begins to peel off.
Example 2
(1) One embodiment of a steel pipe made in accordance with the principles of the present invention
(a) Selection of materials
The steel pipe substrate is made of steel pipe with the inner diameter of 60mm, the steel pipe is made of high-quality carbon structural steel with the steel grade of 45, and the length of the steel pipe is about 1 m.
The anti-corrosion material is ceramic powder, the size of the ceramic powder is more than 300 meshes, the components comprise 50 parts of kaolin clay and 50 parts of alkaline earth in parts by mass, the kaolin clay comprises 40% of aluminum oxide and 45% of silicon dioxide in parts by weight, and a small amount of potassium oxide, calcium oxide and silicate materials. Then adding diboron trioxide into the ceramic powder, so that the mass percent of the diboron trioxide is 18 percent of the whole anticorrosive material. The amount of the anticorrosive material is 0.75g/cm2A meter (comprising the spool mentioned in step (c)).
(b) Rust and dust removal
And carrying out internal rust removal and dust removal treatment on the steel pipe. The methods of removing rust (e.g., removing rust with an iron brush) and removing dust (e.g., air blowing treatment) employed in the prior art are both applicable to this embodiment. After the rust removal treatment, the quality of the iron oxide on the inner wall of the steel pipe is not higher than 1 gram per square meter.
(c) Pipeline port pretreatment
Short pipes made of corrosion-resistant nickel-based alloy and having the same diameter and thickness as the steel pipe are provided, and the two short pipes are welded to the two ends of the steel pipe respectively. The welding methods used in the prior art are all suitable for this embodiment. The short pipes at the two ends of the steel pipe are used for welding the two steel pipes when the pipeline is laid.
(d) Coating of corrosion-resistant materials
And (3) pouring the anticorrosive material on the inner wall of the steel pipe uniformly, and scraping the anticorrosive material off the short pipe (for example, reserving 2mm) which does not need to be lined partially.
(e) Heating and cooling
Rotating the steel pipe (rotating speed is proper for promoting the anticorrosive material to be uniformly distributed on the inner wall of the steel pipe by the centrifugal force of the steel pipe), enabling the steel pipe to pass through a medium-frequency heater at a constant speed (heating the steel pipe to about 1100 ℃, moving speed is proper for melting the intermediate material and uniformly attaching the intermediate material on the pipe wall), and then naturally cooling.
(2) Comparative examples of the above examples
(a) Selection of materials
The steel pipe substrate is made of steel pipe with the inner diameter of 60mm, the steel pipe is made of high-quality carbon structural steel with the steel grade of 45, and the length of the steel pipe is about 1 m.
The anti-corrosion material is ceramic powder, the size of the ceramic powder is more than 300 meshes, the components comprise 50 parts of kaolin clay and 50 parts of alkaline earth in parts by mass, the kaolin clay comprises 40% of aluminum oxide and 45% of silicon dioxide in parts by weight, and a small amount of potassium oxide, calcium oxide and silicate materials. The amount of the anticorrosive material is 0.75g/cm2A meter (comprising the spool mentioned in step (c)).
(b) Rust and dust removal
And carrying out internal rust removal and dust removal treatment on the steel pipe. The methods of removing rust (e.g., removing rust with an iron brush) and removing dust (e.g., air blowing treatment) employed in the prior art are both applicable to this embodiment. After the rust removal treatment, the quality of the iron oxide on the inner wall of the steel pipe is not higher than 1 gram per square meter.
(c) Pipeline port pretreatment
Short pipes made of corrosion-resistant nickel-based alloy and having the same diameter and thickness as the steel pipe are provided, and the two short pipes are welded to the two ends of the steel pipe respectively. The welding methods used in the prior art are all suitable for this embodiment. The short pipes at the two ends of the steel pipe are used for welding the two steel pipes when the pipeline is laid.
(d) Coating of corrosion-resistant materials
And (3) pouring the anticorrosive material on the inner wall of the steel pipe uniformly, and scraping the anticorrosive material off the short pipe (for example, reserving 2mm) which does not need to be lined partially.
(e) Heating and cooling
Rotating the steel pipe (rotating speed is proper for promoting the anticorrosive material to be uniformly distributed on the inner wall of the steel pipe by the centrifugal force of the steel pipe), enabling the steel pipe to pass through a medium-frequency heater at a constant speed (heating the steel pipe to about 1100 ℃, moving speed is proper for melting the intermediate material and uniformly attaching the intermediate material on the pipe wall), and then naturally cooling.
(3) Comparison of the Performance of the products of the examples of the invention with that of the products of the comparative examples
The products of the examples of the invention and the products of the comparative examples are cut into small sections of about 10cm, and performance detection is carried out.
(a) Thickness of the layer of corrosion-resistant material
The thickness of the anticorrosive material layer was about 3mm for both the products of examples of the present invention and the products of comparative examples.
(b) Anticorrosive material layer detection
The anticorrosive material layer of the product of the comparative example is observed by naked eyes and detected by electric sparks (1-2 ten thousand volts) to find a large amount of bubbles or cracks, and a plurality of cracks appear.
The number of bubbles in the anticorrosive material layer of the product of the comparative example is slightly reduced, and the crack is greatly reduced.
(c) Adhesion test
The impact of the example product and the example product of the invention shows that the ceramic layer of the example product of the invention is kept intact when the ceramic layer of the example product begins to peel off.
The foregoing detailed description of the preferred embodiments of the invention has been presented. It should be understood that numerous modifications and variations could be devised by those skilled in the art in light of the present teachings without departing from the inventive concepts. Therefore, the technical solutions available to those skilled in the art through logic analysis, reasoning and limited experiments based on the prior art according to the concept of the present invention should be within the scope of protection defined by the claims.

Claims (9)

1. A composite material, characterized in that the preparation method of the composite material comprises the following steps:
1) providing a ceramic material and a steel pipe;
2) forming a ceramic layer lining the steel pipe by heating the steel pipe, heating to melt the ceramic material, and cooling,
the ceramic layer contains diboron trioxide, and the mass percentage of the diboron trioxide is 15% -20%.
2. The composite material of claim 1, wherein the boron trioxide is present in an amount of 17 to 18% by weight.
3. The composite material of claim 1, wherein the ceramic layer comprises kaolin and an alkaline earth.
4. The composite material according to claim 3, wherein the kaolin and the alkaline earth are present in a ratio of mass percent: 0.8 to 1.2.
5. The composite material of claim 3, wherein the alkaline earth comprises alumina, and the alumina accounts for 35 to 50 percent of the alkaline earth by mass.
6. The composite material according to claim 5, wherein the alumina is present in an amount of 38 to 42% by weight in the alkaline earth.
7. The composite material according to claim 3, wherein the alkaline earth contains silica, and the mass content of silica in the alkaline earth is 30% or more.
8. The composite material of claim 1, wherein the ceramic material is provided in the form of a ceramic powder.
9. The ceramic lined steel pipe of claim 5, wherein the method of making the ceramic lined steel pipe comprises: mixing ceramic powder with liquid to obtain a mixture, coating the mixture on the surface of the steel tube substrate, and drying to make the ceramic powder adhere to the surface of the steel tube substrate.
CN201910835397.9A 2019-09-05 2019-09-05 Composite material Pending CN110592578A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201910835397.9A CN110592578A (en) 2019-09-05 2019-09-05 Composite material

Publications (1)

Publication Number Publication Date
CN110592578A true CN110592578A (en) 2019-12-20

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Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB901126A (en) * 1959-06-18 1962-07-18 Shoichiro Tanaka Metallic pipes lined with glass
GB1467459A (en) * 1975-10-10 1977-03-16 English Electric Co Ltd Glass ceramics and to the coating of metal articles with glass-ceramic
US4145764A (en) * 1975-07-23 1979-03-27 Sumitomo Chemical Co., Ltd. Endosseous implants
EP0885606A2 (en) * 1997-06-12 1998-12-23 Ivoclar Ag Alkali-silicate glass
CN1873278A (en) * 2005-05-30 2006-12-06 四平市东海石化设备有限公司 Glass products for inner lining of steel tube, and preparation method
CN203209286U (en) * 2013-05-03 2013-09-25 胜利油田金岛工程安装有限责任公司 Lining glass corrosion prevention production line for steel pipes
CN103822031A (en) * 2013-05-03 2014-05-28 胜利油田金岛工程安装有限责任公司 Glass-lined anti-corrosion steel pipe producing and welding processes
WO2015045595A1 (en) * 2013-09-30 2015-04-02 三菱重工業株式会社 Method for producing member for fluid machines, and member for fluid machines
CN105392923A (en) * 2013-07-19 2016-03-09 格尔丹柏·帕特尔 Fast and economical methods and apparatus for manufacturing glass lined metal objects by induction heating
CN107377337A (en) * 2017-06-22 2017-11-24 陕西宇阳石油科技工程有限公司 Epoxy powder coating process inside and outside a kind of steel pipe
CN108019569A (en) * 2016-11-04 2018-05-11 王双喜 A kind of glass undercoating composite metal pipe and its preparation process

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB901126A (en) * 1959-06-18 1962-07-18 Shoichiro Tanaka Metallic pipes lined with glass
US4145764A (en) * 1975-07-23 1979-03-27 Sumitomo Chemical Co., Ltd. Endosseous implants
GB1467459A (en) * 1975-10-10 1977-03-16 English Electric Co Ltd Glass ceramics and to the coating of metal articles with glass-ceramic
EP0885606A2 (en) * 1997-06-12 1998-12-23 Ivoclar Ag Alkali-silicate glass
CN1873278A (en) * 2005-05-30 2006-12-06 四平市东海石化设备有限公司 Glass products for inner lining of steel tube, and preparation method
CN203209286U (en) * 2013-05-03 2013-09-25 胜利油田金岛工程安装有限责任公司 Lining glass corrosion prevention production line for steel pipes
CN103822031A (en) * 2013-05-03 2014-05-28 胜利油田金岛工程安装有限责任公司 Glass-lined anti-corrosion steel pipe producing and welding processes
CN105392923A (en) * 2013-07-19 2016-03-09 格尔丹柏·帕特尔 Fast and economical methods and apparatus for manufacturing glass lined metal objects by induction heating
WO2015045595A1 (en) * 2013-09-30 2015-04-02 三菱重工業株式会社 Method for producing member for fluid machines, and member for fluid machines
CN108019569A (en) * 2016-11-04 2018-05-11 王双喜 A kind of glass undercoating composite metal pipe and its preparation process
CN107377337A (en) * 2017-06-22 2017-11-24 陕西宇阳石油科技工程有限公司 Epoxy powder coating process inside and outside a kind of steel pipe

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