CN110305245A - A kind of dissaving polymer heavy crude thinner and preparation method thereof - Google Patents
A kind of dissaving polymer heavy crude thinner and preparation method thereof Download PDFInfo
- Publication number
- CN110305245A CN110305245A CN201910610249.7A CN201910610249A CN110305245A CN 110305245 A CN110305245 A CN 110305245A CN 201910610249 A CN201910610249 A CN 201910610249A CN 110305245 A CN110305245 A CN 110305245A
- Authority
- CN
- China
- Prior art keywords
- heavy crude
- dissaving polymer
- crude thinner
- polymer heavy
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17D—PIPE-LINE SYSTEMS; PIPE-LINES
- F17D1/00—Pipe-line systems
- F17D1/08—Pipe-line systems for liquids or viscous products
- F17D1/16—Facilitating the conveyance of liquids or effecting the conveyance of viscous products by modification of their viscosity
- F17D1/17—Facilitating the conveyance of liquids or effecting the conveyance of viscous products by modification of their viscosity by mixing with another liquid, i.e. diluting
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1818—C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Water Supply & Treatment (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Public Health (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention discloses a kind of dissaving polymer heavy crude thinners and preparation method thereof, its technical solution is: octadecyl methacrylate, styrene and ethylene glycol dimethacrylate are dissolved in dimethylbenzene, in nitrogen environment, initiator benzoyl peroxide is added, 6h is reacted under the conditions of 70 DEG C and obtains dissaving polymer heavy crude thinner.The heavy crude thinner viscosity reducing effect is good, preparation is simple, can reduce the defeated temperature of collection of viscous crude, has broad application prospects at the defeated aspect of thickened oil recovery sum aggregate.
Description
Technical field
The present invention relates to a kind of dissaving polymer heavy crude thinners and preparation method thereof, belong to oil field chemical field.
Background technique
China's viscous crude is resourceful.According to statistics, China successively has found a viscous crude field more than 70 in 12 basins, establishes
5 great development production districts, yield have accounted for the 10% of national petroleum total output, and viscous crude positive performer in China's energy resource structure is more next
More important role.But viscous crude molecular structure is complicated, heavy constituent content is high, and viscosity is big, defeated brings to the exploitation sum aggregate of viscous crude
The difficulty that arrives very much.
For a long time, mainly use that heating, viscosity reducing collection is defeated, thin oil blending visbreaking collection is defeated, reducing viscosity by emulsifying collection is defeated to viscous crude both at home and abroad
Etc. modes.Heating, viscosity reducing fuel consumption is big, at high cost；Thin oil blending visbreaking is not only limited by thin oil source, but also mixes viscous crude
Thin oil according to viscous crude calculation of price, it is low in economic efficiency；Thick-oil emulsified adhesive-reducing collection is defeated to be will appear post-processing (as being dehydrated) and asks
Topic, and it is not suitable for low water-bearing crude oil.
Oil-soluble viscosity reducer have many advantages, such as viscosity reduction dosage is few, viscosity reducing effect is good, without post-processing, therefore, receive extensively
Concern.Oil-soluble viscosity reducer viscosity reduction primarily directed to viscous crude component structure and a kind of viscosity reduction method for studying.This method
The oil-soluble viscosity reducer molecular structure of designed synthesis is similar to viscous crude component structure, using nonpolar Long carbon chain as main chain, again
Containing highly polar side-chain radical, nonpolar alkyl chain is soluble in viscous crude, plays infiltration, peptizaiton, and highly polar
Side-chain radical can be formed with the colloid in viscous crude, the polar group in asphalitine than original stronger hydrogen bond, and colloid, pitch are caused
Hydrogen bond in matter original structure destroys；In addition, the benzene ring structure being interspersed in viscosity reduction agent molecule can be with the virtue in colloid, asphalitine
Ring or heteroaromatic form Π-Π conjugation or sedimentation, and regular, the close stratiform packing structure for keeping it original is destroyed, and
And thinner Molecular Adsorption can prevent it from assembling again on scattered asphalitine surface, to significantly reduce the viscosity of viscous crude.
Summary of the invention
Good, simple process that the purpose of the present invention is to provide a kind of viscosity reducing effects and it is low-cost for heavy oil pipeline it is defeated
Send heavy crude thinner and preparation method thereof.
To achieve the goals above, the present invention provides following technical scheme.
A kind of dissaving polymer heavy crude thinner, structural formula are as follows:
Wherein R is positive octadecyl；X, y, z is monomer mole ratio, x ﹢ y ﹢ z=1.
It is prepared the following steps are included: octadecyl methacrylate, styrene and ethylene glycol dimethacrylate is molten
In dimethylbenzene, in nitrogen environment, initiator benzoyl peroxide is added, reaction 6h is obtained hyperbranched under the conditions of 70 DEG C
Polymer heavy crude thinner.
The molar ratio of octadecyl methacrylate and styrene is 3~5:1.
The dosage of ethylene glycol dimethacrylate is 0.02~0.05%.
The present invention compared with the prior art, the beneficial effect is that:
(1) heavy crude thinner of the invention is adaptable, is suitble to the viscous crude of different water cut and different compositions；
(2) heavy crude thinner dosage of the invention is small, viscosity reducing effect is good；
(3) heavy crude thinner site construction technology of the invention is simple, does not need to post-process.
Specific embodiment
Below by embodiment, the present invention will be further described:
Embodiment 1
Octadecyl methacrylate, styrene and ethylene glycol dimethacrylate are dissolved in dimethylbenzene, wherein methyl
Octadecyl acrylate, styrene molar ratio are 3:1, and ethylene glycol dimethacrylate dosage is 0.02%, in nitrogen environment,
Initiator benzoyl peroxide is added, 6h is reacted under the conditions of 70 DEG C and obtains dissaving polymer heavy crude thinner 1.
Embodiment 2
Octadecyl methacrylate, styrene and ethylene glycol dimethacrylate are dissolved in dimethylbenzene, wherein methyl
Octadecyl acrylate, styrene molar ratio are 4:1, and ethylene glycol dimethacrylate dosage is 0.03%, in nitrogen environment,
Initiator benzoyl peroxide is added, 6h is reacted under the conditions of 70 DEG C and obtains dissaving polymer heavy crude thinner 2.
Embodiment 3
Octadecyl methacrylate, styrene and ethylene glycol dimethacrylate are dissolved in dimethylbenzene, wherein methyl
Octadecyl acrylate, styrene molar ratio are 5:1, and ethylene glycol dimethacrylate dosage is 0.05%, in nitrogen environment,
Initiator benzoyl peroxide is added, 6h is reacted under the conditions of 70 DEG C and obtains dissaving polymer heavy crude thinner 3.
1 heavy crude thinner viscosity break ratio of table
Claims (4)
1. a kind of dissaving polymer heavy crude thinner, structural formula are as follows:
Wherein R is positive octadecyl；X, y, z is monomer mole ratio, x ﹢ y ﹢ z=1.
2. a kind of dissaving polymer heavy crude thinner as described in claim 1, prepares the following steps are included: by metering system
Sour octadecyl ester, styrene and ethylene glycol dimethacrylate are dissolved in dimethylbenzene, and in nitrogen environment, initiator peroxide is added
Change benzoyl, 6h is reacted under the conditions of 70 DEG C and obtains dissaving polymer heavy crude thinner.
3. a kind of dissaving polymer heavy crude thinner as described in claim 1, it is characterised in that: octadecyl methacrylate with
The molar ratio of styrene is 3~5:1.
4. a kind of dissaving polymer heavy crude thinner as described in claim 1, it is characterised in that: ethyleneglycol dimethacrylate
The dosage of ester is 0.02~0.05%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910610249.7A CN110305245A (en) | 2019-07-06 | 2019-07-06 | A kind of dissaving polymer heavy crude thinner and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910610249.7A CN110305245A (en) | 2019-07-06 | 2019-07-06 | A kind of dissaving polymer heavy crude thinner and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110305245A true CN110305245A (en) | 2019-10-08 |
Family
ID=68079157
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910610249.7A Pending CN110305245A (en) | 2019-07-06 | 2019-07-06 | A kind of dissaving polymer heavy crude thinner and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110305245A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112299681A (en) * | 2020-09-03 | 2021-02-02 | 西南石油大学 | Preparation method of water-based mud/drilling cuttings drying agent |
| CN112898468A (en) * | 2021-01-21 | 2021-06-04 | 西南石油大学 | Asphaltene inhibitor and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4906547A (en) * | 1987-11-24 | 1990-03-06 | Agfa-Gevaert N.V. | Triboelectrically chargeable magnetic carrier particles having magnetic powder dispersed in acidic resin basic amino resin reaction product binder |
| CN101824314A (en) * | 2010-03-10 | 2010-09-08 | 中国地质大学（武汉） | Terpolymer oil soluble viscosity reducer for thick oil exploration and transportation and preparation method thereof |
| CN102977254A (en) * | 2012-11-27 | 2013-03-20 | 山东大学 | Thick oil nano viscosity reducer and preparation method thereof |
| CN104232050A (en) * | 2014-09-05 | 2014-12-24 | 纳百科创(北京)技术开发有限公司 | Compound oil-soluble viscosity reducer for reducing viscosity of thickened oil and preparation method of compound oil-soluble viscosity reducer |
-
2019
- 2019-07-06 CN CN201910610249.7A patent/CN110305245A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4906547A (en) * | 1987-11-24 | 1990-03-06 | Agfa-Gevaert N.V. | Triboelectrically chargeable magnetic carrier particles having magnetic powder dispersed in acidic resin basic amino resin reaction product binder |
| CN101824314A (en) * | 2010-03-10 | 2010-09-08 | 中国地质大学（武汉） | Terpolymer oil soluble viscosity reducer for thick oil exploration and transportation and preparation method thereof |
| CN102977254A (en) * | 2012-11-27 | 2013-03-20 | 山东大学 | Thick oil nano viscosity reducer and preparation method thereof |
| CN104232050A (en) * | 2014-09-05 | 2014-12-24 | 纳百科创(北京)技术开发有限公司 | Compound oil-soluble viscosity reducer for reducing viscosity of thickened oil and preparation method of compound oil-soluble viscosity reducer |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112299681A (en) * | 2020-09-03 | 2021-02-02 | 西南石油大学 | Preparation method of water-based mud/drilling cuttings drying agent |
| CN112299681B (en) * | 2020-09-03 | 2022-06-17 | 西南石油大学 | Preparation method of water-based mud/drilling cuttings drying agent |
| CN112898468A (en) * | 2021-01-21 | 2021-06-04 | 西南石油大学 | Asphaltene inhibitor and preparation method thereof |
| CN112898468B (en) * | 2021-01-21 | 2022-01-14 | 西南石油大学 | Asphaltene inhibitor and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102719234B (en) | Thickened oil viscosity depressant as well as preparation method and application thereof | |
| CN103613306B (en) | A kind of poly carboxylic acid series water reducer containing hyperbranched polyamine-ester structure and preparation method thereof | |
| CN100595220C (en) | Method for manufacturing oil solubility thick oil thinner for thick oil pipe-line transportation | |
| CN105387347A (en) | Oil field crude oil pour point depressant and preparing method thereof | |
| CN110229654B (en) | High-molecular surfactant type thick oil viscosity reducer and preparation method thereof | |
| CN104402740B (en) | Acidification diversion agent octadecylbutyldihydroxyethyl ammonium bromide and its preparation method and use | |
| CN110305245A (en) | A kind of dissaving polymer heavy crude thinner and preparation method thereof | |
| CN102492410A (en) | Thick oil-soluble viscosity reducer and preparation method thereof | |
| CN103193936A (en) | Alcohol amine-carboxylic acid polymer as well as preparation method and application thereof | |
| CN104371081A (en) | Preparation method of rapid dispersion viscosity reduction type polycarboxylic acid cement dispersant | |
| CN105440276A (en) | Preparation method and application of polymer containing phosphorous acid group | |
| CN105001847B (en) | Anti-salt type viscous crude dispersing drag reducer and preparation method | |
| CN105199699B (en) | A kind of inexpensive oil-soluble viscosity reducer and preparation method for reducing thick oil viscosity | |
| CN102399547A (en) | Application of rhamnolipid as crude oil pipeline drag reducer and viscosity reducer | |
| CN101531744A (en) | Method for synthesizing polycarboxylic acid series concrete hyper-dispersant | |
| CN102274701A (en) | Surfactant and preparation and application thereof | |
| EP2738190A1 (en) | Amphiphilic macromolecule and use | |
| CN112342005B (en) | Environment-friendly efficient thick oil viscosity reducer | |
| CN101497814A (en) | Organosilicon reinforced composite type oil phase dispersed demulsifying agent | |
| CN102250296A (en) | Water reducing agent as well as preparation method and application thereof | |
| CN105482848A (en) | Crude oil desalting complex agent and preparation method thereof | |
| CN102585792A (en) | Low-cost environment-friendly oil-soluble viscosity reducing agent for super heavy oil | |
| CN102863473A (en) | Hexatomic-ring alkylsiloxane-phosphate natural gas pipeline corrosion-inhibition drag reducer and preparation method thereof | |
| CN102453252A (en) | Acrylamide macromonomer and comb type copolymer and preparation method and application thereof | |
| CN102604621B (en) | Novel high-efficiency composite viscosity reducer for super heavy oil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191008 |
|
| RJ01 | Rejection of invention patent application after publication |