CN110283636A - A method of promoting the calorific value that feces of livestock and poultry prepares biomass carbon - Google Patents
A method of promoting the calorific value that feces of livestock and poultry prepares biomass carbon Download PDFInfo
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- CN110283636A CN110283636A CN201910413489.8A CN201910413489A CN110283636A CN 110283636 A CN110283636 A CN 110283636A CN 201910413489 A CN201910413489 A CN 201910413489A CN 110283636 A CN110283636 A CN 110283636A
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- Prior art keywords
- livestock
- feces
- poultry
- calorific value
- biomass carbon
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/42—Solid fuels essentially based on materials of non-mineral origin on animal substances or products obtained therefrom, e.g. manure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/08—Drying or removing water
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The invention discloses a kind of methods that promotion feces of livestock and poultry prepares the calorific value of biomass carbon, including the following steps: is pulverized into powder the feces of livestock and poultry charcoal that charing is completed;Powder after sieving is mixed with certain density acid, mixes it uniformly, is sufficiently reacted;Mixture after reaction is separated by solid-liquid separation, liquid and solid matter after being separated;Obtained solid substance carries out dehydration and drying processing, finally obtains the feces of livestock and poultry charcoal after calorific value is promoted.The method of the present invention safety and environmental protection, the calorific value of feces of livestock and poultry biomass can be significantly improved, the feces of livestock and poultry charcoal after calorific value is promoted can be used as biomass fuel use, realize the resource utilization of animal faeces wastes, reduce pollution of the feces of livestock and poultry to environment, improves ecological environment.
Description
Technical field
The present invention relates to agricultural solid residue processing technology fields, and in particular to a kind of promotion feces of livestock and poultry preparation biology
The method of the calorific value of matter charcoal.
Background technique
Livestock and poultry cultivation process generates a large amount of discharged waste, and with the fast development of intensive aquaculture industry, feces of livestock and poultry is given
The very big carrying capacity of environment of local agricultural environment band.Feces of livestock and poultry phosphorus content is high, is rich in a large amount of organic carbon.Carbohydrate
It is the base substance composition of biomass, theoretically biomass can be carbonized.China handles feces of livestock and poultry, especially pig at present
Excrement, there are three types of the modes of mainstream: marsh gas power generation, production biological organic fertilizer and vermiculture processing.But each way has it
Respectively different advantage and disadvantage.
And feces of livestock and poultry can carry out charing process, the waste generated in carbonization process is easy to harmless treatment,
Carbonizing the charcoal obtained can be used as biomass fuel use.But problem is feces of livestock and poultry charcoal after charing process,
Its calorific value about 3000 kilocalories/kilogram or so, used as fuel slightly lower, be unfavorable for marketing.If calorific value energy
Effective promotion is accessed, a kind of beneficial method will be provided to the environmental protection treatment of feces of livestock and poultry.
Therefore, it is badly in need of developing a kind of method for promoting feces of livestock and poultry and preparing the calorific value of biomass carbon.
Summary of the invention
The present invention is directed to above-mentioned defect in the prior art, provides a kind of fever for promoting feces of livestock and poultry and preparing biomass carbon
The method of amount, this method safety and environmental protection can significantly improve the calorific value of feces of livestock and poultry biomass, the animal dung after calorific value promotion
Just charcoal can be used as biomass fuel use, realize the resource utilization of animal faeces wastes.
In order to solve the above technical problems, the present invention adopts the following technical scheme:
A method of the calorific value that feces of livestock and poultry prepares biomass carbon is promoted, the difference is that, comprising the following steps:
The feces of livestock and poultry charcoal that charing is completed is pulverized into powder by step 1);
Step 2 mixes powder obtained by step 1) with certain density acid, mixes it uniformly, sufficiently reacts;
Step 3), step 2 is reacted after mixture be separated by solid-liquid separation, liquid and solid matter after being separated;
Step 3) obtained solid substance is carried out dehydration and drying processing by step 4), finally obtains the feces of livestock and poultry after calorific value is promoted
Charcoal.
In the above-mentioned technical solutions, it in the step 1), is crushed by the modes such as breaing up, grinding, makes powder after crushing
The partial size at end is less than 4 mesh.
In the above-mentioned technical solutions, in the step 2, the concentration of workable acid is 0.5 ~ 5mol/L.
In the above-mentioned technical solutions, in the step 2, acid is at least one of hydrochloric acid, nitric acid or sulfuric acid.
In the above-mentioned technical solutions, in the step 2, powder and acid is made mix and can be used stirring, oscillation etc. a variety of
Mode.
In the above-mentioned technical solutions, it in the step 3), is separated by solid-liquid separation using the modes such as centrifugation or filtering.
In the above-mentioned technical solutions, liquid isolated in the step 3), which may continue as the acid in step 2, makes
With.
In the above-mentioned technical solutions, in the step 4), the modes such as centrifugation, drying, ray can be used and dehydrated
Processing.
Compared with prior art, pass through the feces of livestock and poultry that will carbonize and complete the beneficial effects of the present invention are: the present invention to give birth to
Object powdered carbon is sufficiently mixed with certain density acid react after be separated by solid-liquid separation, the solid matter after separation is dehydrated
Processing, can significantly improve the calorific value of feces of livestock and poultry biomass, and the feces of livestock and poultry charcoal after calorific value is promoted can be used as biology
Matter fuel uses, and realizes the resource utilization of animal faeces wastes, reduces pollution of the feces of livestock and poultry to environment, improve
Ecological environment.
Specific embodiment
Below with reference to embodiment, specific embodiments of the present invention will be described in further detail.Following embodiment is for saying
The bright present invention, but be not used in and limit the scope of the invention.
The fresh pig manure in Hua Zhong Agriculture University pig farm is taken, air-dries and is packed into porcelain crucible after breaking into pieces, close the lid, be placed in certain temperature
It is pyrolyzed 2 hours and carbonizes in degree (450 DEG C) Muffle furnace, taken out after being cooled to room temperature spare.Its high calorific power is detected through detecting
For 3107 kilocalories/kilogram.
Embodiment 1
A method of promoting the calorific value that feces of livestock and poultry prepares biomass carbon, comprising the following steps:
Step 1) crushes the charcoal after pyrolysis by the modes such as breaing up, grinding, and feces of livestock and poultry is made to prepare biomass carbon
Powder diameter is stored in wide-mouth bottle less than 4 mesh, and by smashed powder;
Step 2 takes 20 grams of above-mentioned samples, adds it in 200 mL0.5mol/L sulfuric acid, using oscillator to mixture
Divide 4 washings;
Mixture after reaction is centrifuged step 3), and supernatant is collected after centrifugation every time, finally with 50 mL go from
Son is washed to weakly acidic pH, and deionization wash water is collected into supernatant together;
The wet solid being centrifugally separating to obtain is placed on wide-mouth bottle in 80 DEG C of drying by step 4), the biomass after obtaining dedusting
Charcoal.
Through detecting, the high calorific power of the present embodiment biomass carbon is 4573 kilocalories/kilogram.
Embodiment 2
0.5mol/L sulfuric acid in 1 step 2 of embodiment is changed to 0.5mol/L hydrochloric acid, other steps are same as Example 1.
Through detecting, the high calorific power of the present embodiment biomass carbon is 4481 kilocalories/kilogram.
Embodiment 3
0.5mol/L sulfuric acid in 1 step 2 of embodiment is changed to 0.5mol/L nitric acid, other steps are same as Example 1.
Through detecting, the high calorific power of the present embodiment biomass carbon is 4602 kilocalories/kilogram.
Embodiment 4
A method of promoting the calorific value that feces of livestock and poultry prepares biomass carbon, comprising the following steps:
Step 1) crushes the charcoal after pyrolysis by the modes such as breaing up, grinding, and feces of livestock and poultry is made to prepare biomass carbon
Powder diameter is stored in wide-mouth bottle less than 4 mesh, and by smashed powder;
Step 2 takes 20 grams of above-mentioned samples, adds it in 200 mL 2mol/L sulfuric acid, using oscillator to mixture
Divide 4 washings;
Mixture after reaction is centrifuged step 3), and supernatant is collected after centrifugation every time, finally with 50 mL go from
Son is washed to weakly acidic pH, and deionization wash water is collected into supernatant together;
The wet solid being centrifugally separating to obtain is placed on wide-mouth bottle in 80 DEG C of drying by step 4), the biomass after obtaining dedusting
Charcoal.
Through detecting, the high calorific power of the present embodiment biomass carbon is 5196 kilocalories/kilogram.
Embodiment 5
2mol/L sulfuric acid in 4 step 2 of embodiment is changed to 2mol/L hydrochloric acid, other steps are same as Example 4.
Through detecting, the high calorific power of the present embodiment biomass carbon is 4971 kilocalories/kilogram.
Embodiment 6
2mol/L sulfuric acid in 4 step 2 of embodiment is changed to 2mol/L nitric acid, other steps are same as Example 4.
Through detecting, the high calorific power of the present embodiment biomass carbon is 5435 kilocalories/kilogram.
Embodiment 7
A method of promoting the calorific value that feces of livestock and poultry prepares biomass carbon, comprising the following steps:
Step 1) crushes the charcoal after pyrolysis by the modes such as breaing up, grinding, and feces of livestock and poultry is made to prepare biomass carbon
Powder diameter is stored in wide-mouth bottle less than 4 mesh, and by smashed powder;
Step 2 takes 20 grams of above-mentioned samples, adds it in 200 mL 5mol/L sulfuric acid, using oscillator to mixture
Divide 4 washings;
Mixture after reaction is centrifuged step 3), and supernatant is collected after centrifugation every time, finally with 50 mL go from
Son is washed to weakly acidic pH, and deionization wash water is collected into supernatant together;
The wet solid being centrifugally separating to obtain is placed on wide-mouth bottle in 80 DEG C of drying by step 4), the biomass after obtaining dedusting
Charcoal.
Through detecting, the high calorific power of the present embodiment biomass carbon is 5996 kilocalories/kilogram.
Embodiment 8
5mol/L sulfuric acid in 7 step 2 of embodiment is changed to 5mol/L hydrochloric acid, other steps are same as Example 7.
Through detecting, the high calorific power of the present embodiment biomass carbon is 5579 kilocalories/kilogram.
Embodiment 9
5mol/L sulfuric acid in 7 step 2 of embodiment is changed to 5mol/L nitric acid, other steps are same as Example 7.
Through detecting, the high calorific power of the present embodiment biomass carbon is 6182 kilocalories/kilogram.
The present invention provides a kind of beneficial method for the environmental protection treatment of feces of livestock and poultry, can significantly improve feces of livestock and poultry biology
The calorific value of matter, the feces of livestock and poultry charcoal after calorific value is promoted can be used as biomass fuel use, it is useless to realize feces of livestock and poultry
The resource utilization of gurry can promote feces of livestock and poultry charing to promote the use of.
Finally, it should be noted that above embodiments are merely to illustrate the protection scope that the present invention is not intended to limit the present invention.
In addition, after reading the technical contents of the present invention, those skilled in the art the present invention can be made various changes, modification or
Modification, all these equivalent forms also belong within the required protection scope limited of the application.
Claims (8)
1. a kind of method for promoting feces of livestock and poultry and preparing the calorific value of biomass carbon, it is characterised in that: the following steps are included:
The feces of livestock and poultry charcoal that charing is completed is pulverized into powder by step 1);
Step 2 mixes powder obtained by step 1) with certain density acid, mixes it uniformly, sufficiently reacts;
Step 3), step 2 is reacted after mixture be separated by solid-liquid separation, liquid and solid matter after being separated;
Step 3) obtained solid substance is carried out dehydration and drying processing by step 4), finally obtains the feces of livestock and poultry after calorific value is promoted
Charcoal.
2. the method according to claim 1 for promoting feces of livestock and poultry and preparing the calorific value of biomass carbon, it is characterised in that: institute
It states in step 1), is crushed by the modes such as breaing up, grinding, make the partial size of powder after crushing less than 4 mesh.
3. the method according to claim 1 for promoting feces of livestock and poultry and preparing the calorific value of biomass carbon, it is characterised in that: institute
It states in step 2, the concentration of workable acid is 0.5 ~ 5mol/L.
4. the method according to claim 1 for promoting feces of livestock and poultry and preparing the calorific value of biomass carbon, it is characterised in that: institute
It states in step 2, acid is at least one of hydrochloric acid, nitric acid or sulfuric acid.
5. the method according to claim 1 for promoting feces of livestock and poultry and preparing the calorific value of biomass carbon, it is characterised in that: institute
It states in step 2, powder is made to carry out mixing the various ways such as usable stirring, oscillation with acid.
6. the method according to claim 1 for promoting feces of livestock and poultry and preparing the calorific value of biomass carbon, it is characterised in that: institute
It states in step 3), is separated by solid-liquid separation using the modes such as centrifugation or filtering.
7. the method according to claim 1 for promoting feces of livestock and poultry and preparing the calorific value of biomass carbon, it is characterised in that: institute
The acid that stating liquid isolated in step 3) may continue as in step 2 uses.
8. the method according to claim 1 for promoting feces of livestock and poultry and preparing the calorific value of biomass carbon, it is characterised in that: institute
It states in step 4), the modes such as centrifugation, drying, ray can be used and carry out dehydration and drying processing.
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Application publication date: 20190927 |