CN109776108A - A kind of high rigidity physicochemical property ceramic and preparation method thereof - Google Patents
A kind of high rigidity physicochemical property ceramic and preparation method thereof Download PDFInfo
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- CN109776108A CN109776108A CN201711109197.2A CN201711109197A CN109776108A CN 109776108 A CN109776108 A CN 109776108A CN 201711109197 A CN201711109197 A CN 201711109197A CN 109776108 A CN109776108 A CN 109776108A
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Abstract
The present invention relates to a kind of high rigidity physicochemical property ceramics and preparation method thereof, wherein marble ceramic includes green body layer and surface layer, surface layer is containing the starch adhesive layer for forming multicolour pattern by infiltration ink, it is characterized by: the product surface has length, width, recessed linear slit and/or irregular shape depressed area not of uniform size, the lower recess seam of every square metre of area and/or the quantity of irregular shape depressed area are more than or equal to 10, lower recess seam and/or irregular shape recess section length are more than or equal to 10mm, lower recess seam and/or the width of irregular shape depressed area are less than or equal to 1mm.It realizes on the surface of blank raw material, there is digital spray printing to copy the natural pattern of stone texture and the parian pattern texture ceramics tile product and production method in several fine sink linear slit texture and/or irregular shape recess patterns areas.
Description
Technical field
The present invention relates to building ceramic tiles field, a kind of high rigidity physicochemical property ceramic and its production side are particularly related to
Method.
Background technique
In modern architecture finishing, the ornament materials of top fitting position is ranked, no more than high-grade lithotome, pattern shape
Naturally, especially such as high-grade marble, texture is finely resistance to be seen state.But the attention with people to scarce resource, the attention to environmental protection,
In construction and decoration, people, which are intended to select, to be had environmental protection "dead" and meets modern society's low-carbon green economic development tide
Stream, but the durability ornament materials that can there is the decoration of fine household to enjoy, Ceramic Tiles made of especially being fired by high temperature
Product.
As the current Ceramic Tiles in market copy the prevailing of Natural stone material product, the grade of consumer is also increasingly improved, people
It is not only required from the rich colors of vision more preferable, but also require it that there is the aesthetic effect of three-dimensional concave-convex level,
The marbling effect of careful linear slit texture, or even have the effect requirements of sense of touch.
For this purpose, the developer in building ceramic tiles field, is doing to copy the marble ceramic of fine textures
Effort.
Summary of the invention
Effect in view of the above problem present in the prior art, especially in the fine textures of production marble products
It is difficult to realize, or the not wear-resisting limitation for waiting physicochemical properties of product surface that can be realized but be limited by frit material formation is asked
Topic, the present invention provide a kind of high rigidity physicochemical property ceramic and preparation method thereof, realize and match property with green body
The surface layer starch adhesive floor that pattern is formed by infiltration ink generate finely sagging linear slit texture and/or irregular shape recess patterns area
Artificial marble ceramic glazed tile product because the raw material of surface layer starch adhesive layer is that the green body composition that is matched under it forms high temperature sintering
, surface is not conventional glaze layer, so, product of the present invention has more high abrasion, high rigidity physicochemical property.
In order to solve the above technical problems, the present invention provides a kind of high rigidity physicochemical property ceramics, it is characterised in that
Marble ceramic includes green body layer and surface layer, and surface layer is containing the starch adhesive layer for forming multicolour pattern by infiltration ink, spy
Sign is: the product surface has length, width, recessed linear slit not of uniform size and/or an irregular shape depressed area, and every square
The lower recess seam of rice and flour product and/or the quantity of irregular shape depressed area are more than or equal to 10, and lower recess is stitched and/or irregular shape
Shape is recessed section length more than or equal to 10mm, and lower recess is stitched and/or the width of irregular shape depressed area is less than or equal to 1mm.
Preferably, above-mentioned marble ceramic, it is characterised in that green body layer is formed by different colour porcelain powders
The green body layer of entire body pattern.
Preferably, above-mentioned marble ceramic, it is characterised in that recessed linear slit and/or irregular shape depressed area are recessed
The state of falling into.
Preferably, above-mentioned marble ceramic, it is characterised in that recessed linear slit and/or irregular shape depressed area are portion
Point or be all filled into glaze, clear frit, dry granular, one or more in the colored slurry prepared in advance.
Preferably, above-mentioned marble ceramic, it is characterised in that infiltration ink be by or iron ion or cobalt ions or
The mixture of acylate and ester that chromium ion or copper ion are formed.
Preferably, above-mentioned marble ceramic, it is characterised in that starch adhesive layer with a thickness of 0.1mm-1mm.
Preferably, above-mentioned marble ceramic, it is characterised in that in starch adhesive layer raw material containing zinc oxide, titanium dioxide,
At least one of zirconium silicate or nano silica.
Preferably, above-mentioned marble ceramic, it is characterised in that in starch adhesive layer containing white, red, black, yellow,
Two or more in orange, blue or other color slurries.
The present invention also provides the production methods of above-mentioned marble ceramic, it is characterised in that this method includes following step
It is rapid:
(1) it is stitched by the mesh number preparation that design and matching slurry pass through containing length, width, lower recess not of uniform size
And/or the enclosed area of irregular shape depressed area, other regions are the silk screen by area；
(2) routinely technique and raw material prepare green body and are dried；
(3) starch adhesive is prepared；
(4) starch adhesive of step (3) is applied using the silk screen of step (1) by the billet surface for being printed on the drying of step (2)；
(5) adobe after applying starch adhesive carries out second of drying；
(6) ink is permeated by layout spray printing；
(7) enter highest warm area up to firing in 1180 DEG C -1240 DEG C of kiln, obtain infiltration ink marmorean half at
Product；
(8) soft throwing/or full polishing, edging are carried out to semi-finished product, obtains marble ceramic.
It preferably, further include not surpassing by being no less than 10 minutes between step (6) and (7) in above-mentioned production method
Cross the transmission time process on 2 hours pipelines；
Preferably, in above-mentioned production method, in the starch adhesive of step (3) also containing be suitable for silk-screen printing common stamp-pad ink,
Print cream or glue.
Preferably, in above-mentioned production method, after step (4) silk-screen either before step (7) after step (6),
Apply to the lower recess seam of formation and/or irregular shape depressed area glaze, translucent dry granular or the frit of print different color
Raw material forms filling.
Preferably, in above-mentioned production method, step (4) is by layout using digital spray printing, silk-screen printing or roller print
Brush mode prints glue and forms several lower recess seam and/or irregular shape texture of protrusion, then drenches the starch adhesive for applying step (3).
Preferably, in above-mentioned production method, the silk-screen printing is changed to roller printing.
Beneficial effects of the present invention are as described below:
First, the present invention proposes a kind of high rigidity physicochemical property ceramic and preparation method thereof pioneeringly, realizes
On the surface of blank raw material, there is digital spray printing to copy the natural pattern and several finely sagging linear slit textures of stone texture
And/or the parian pattern texture ceramics tile product and production method in irregular shape recess patterns area.
Second, the original prepared due to surface layer starch adhesive of the present invention using the mud sand material for being matched with lower layer's porcelain body recipe
What material was manufactured, the unification being formulated up and down is provided with preferably sintering and vitreous characteristic, breaches existing Ceramic Tiles system
Product all only copy the limitation of the technical method of natural marble using recess connection with production of structures is carried out on transparent glaze, also break through
Not wear-resisting enough the limitation in the surface of traditional glaze process product.
Third, the bulk pattern that the present invention uses are that infiltration ink jet printing is formed, and ink is seeped under billet surface
Base is intracorporal, without applying the processing of glaze protection on surface；This with conventional ceramic ink can only spray printing needed in billet surface
Apply glaze carry out protection be different.The present invention is the pattern formed in the billet surface of vitreous, and texture texture is more aobvious
Naturally, being grown as interior.
4th, present invention employs entire body pattern feed dividing-distributing technologies, so that product is more complete in the structure from face to green body
There is to face the effect of imitated lithotome.
The present invention innovatively uses infiltration ink, spray printing/silk-screen/or roller print based on the slurry of body recipe
The integration of technology realizes and generates on green body quality surface such as the marmorean fine recess linear slit texture of glaze technique and do not advise
The then product and production method of the effect of shaped depressions pattern, this is that the prior art is not all disclosed and proposed, be it is non-aobvious and
It is clear to, there is significant novelty and practicability and creativeness.
Specific embodiment
Embodiment
(1) the muds sand plain material such as kaolin, feldspar, quartz are selected, routinely ceramic process prepares green body porcelain powder, formula
Weight percent group become silica 67%, aluminium oxide 21%, potassium oxide+sodium oxide molybdena 6%, calcium oxide+magnesia 1.5%,
It is other be igloss and trace impurity, it is spare；
(2) by the recipe requirements for being matched with above-mentioned blank raw material, formulation weight percentage group becomes silica 70%, oxygen
Change aluminium 20%, potassium oxide+sodium oxide molybdena 8%, calcium oxide+magnesia 0.5%, it is other be igloss and trace impurity, in this slurry
In promote ink by least one of proper ratio addition zinc oxide, titanium dioxide, zirconium silicate or nano silica again
The requirement of water color development pressed 200 mesh screen residues within 0.5%, and specific gravity prepares starch adhesive in 1.80g/cm3, what the present embodiment used
It is the mode of silk-screen printing, so, it is furthermore preferred that being deployed into the common stamp-pad ink used as medium again in starch adhesive, it has been allowed to
Certain viscosity, it is spare in favor of silk-screen printing or the control of roller printing；
It (3) is enclosed area, Qi Tawei by contain several length, width, the irregular shape not of uniform size of design
Mesh number is 100 purposes by area, and it is stand-by to prepare silk screen；
(4) ceramic tile blank of above-mentioned blank raw material is produced in conventional fashion and is dried, drying temperature is at 80 DEG C -250
DEG C, it is transmitted after drying out to subsequent processing；
(5) when the drying base that transmission comes cools to 50 DEG C -80 DEG C, the present embodiment is at 60 DEG C -70 DEG C, using step
(3) silk screen, which applies the starch adhesive of step (2), to be printed on step (4) base temperature is on 60 DEG C -70 DEG C of dry base substrate surface afterwards, to be formed
By the fine recess linear slit texture of design and irregular shape recess patterns areas on pulp noodle floor, starch adhesive weight is about
1.3kg/m2；
(6) adobe after applying starch adhesive is input into dry into second；Here the temperature of redrying is carried out at 40 DEG C -180
DEG C, it is highly preferred that control is kept for about 35 minutes at 130 DEG C -160 DEG C, redrying is utilized using the waste heat of kiln, with more
Save the consumption of the energy, if without the step for drying, can be easy to generate facial cleft, side in actual production and the matter such as split
Amount problem；
(7) the adobe transmission of starch adhesive that is to be applied and foring fine recess texture reaches ink jet printer and base temperature 40
Under conditions of DEG C -50 DEG C or so, ink and penetration-assisting agent are permeated by layout spray printing, and enters in the glaze line of a distance and reaches
To about 40 minutes time courses, so as to be seeped into base under infiltration ink；
(8) the pattern green body Jing Guo about 40 minutes times of penetration enters highest warm area up to 1180 DEG C -1240 DEG C of kiln
Middle firing, obtain the infiltration ink marmorean half with fine recess linear slit and/or irregular shape pattern area texture at
Product.
(9) to semi-finished product carry out it is soft throw/or full polishing, edging, obtain high rigidity physicochemical property of the invention or soft
The product of light or light.
Claims (1)
1. a kind of high rigidity physicochemical property ceramic, it is characterised in that marble ceramic includes green body layer and surface layer, table
Layer be containing the starch adhesive layer for forming multicolour pattern by infiltration ink, it is characterised in that: the product surface have length, width, greatly
Small different recessed linear slit and/or irregular shape depressed area, the lower recess seam and/or irregular shape of every square metre of area are recessed
The quantity for falling into area is more than or equal to 10, and lower recess seam and/or irregular shape recess section length are more than or equal to 10mm, lower recess seam
And/or the width of irregular shape depressed area is less than or equal to 1mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201711109197.2A CN109776108A (en) | 2017-11-11 | 2017-11-11 | A kind of high rigidity physicochemical property ceramic and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711109197.2A CN109776108A (en) | 2017-11-11 | 2017-11-11 | A kind of high rigidity physicochemical property ceramic and preparation method thereof |
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| CN109776108A true CN109776108A (en) | 2019-05-21 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110202994A (en) * | 2019-05-29 | 2019-09-06 | 广东必图新材料科技股份有限公司 | A kind of artificial stone's preparation method of natural-like stone |
-
2017
- 2017-11-11 CN CN201711109197.2A patent/CN109776108A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110202994A (en) * | 2019-05-29 | 2019-09-06 | 广东必图新材料科技股份有限公司 | A kind of artificial stone's preparation method of natural-like stone |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190521 |