CN109692535B - Powdery resource recovery device - Google Patents

Powdery resource recovery device Download PDF

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Publication number
CN109692535B
CN109692535B CN201811551237.3A CN201811551237A CN109692535B CN 109692535 B CN109692535 B CN 109692535B CN 201811551237 A CN201811551237 A CN 201811551237A CN 109692535 B CN109692535 B CN 109692535B
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membrane
wire
powdery
resource
nozzle
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CN109692535A (en
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郭绍华
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Guangdong Fenghe Purification Engineering Co ltd
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Guangdong Fenghe Purification Engineering Co ltd
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Priority to CN201811551237.3A priority Critical patent/CN109692535B/en
Publication of CN109692535A publication Critical patent/CN109692535A/en
Priority to PCT/CN2019/099974 priority patent/WO2020125026A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/54Particle separators, e.g. dust precipitators, using ultra-fine filter sheets or diaphragms
    • B01D46/543Particle separators, e.g. dust precipitators, using ultra-fine filter sheets or diaphragms using membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/0002Casings; Housings; Frame constructions

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Filtering Of Dispersed Particles In Gases (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

A powder resource recovery device uses hollow fiber membrane wires, especially polytetrafluoroethylene hollow fiber membranes, as filtering materials, can obtain more than 1000 times higher filtering precision than the traditional cloth bag dust collector, the spacing distance between the membrane wires is 2-20mm, effectively prevents dust from blocking, and is provided with a back blowing mechanism consisting of a nozzle and a membrane wire nozzle, thereby ensuring long-term stable continuous operation. Can be widely used for extracting metal and metal oxide, separating powdery resource from gas mixed with powdery resource in cement, plastic and pharmaceutical industries, and has high recovery efficiency and low leakage rate.

Description

Powdery resource recovery device
Technical Field
A device for recovering powdery resources. In particular to a recovery device for recovering powdery resources loaded in flue gas.
Background
Many resources exist in a powder state, particularly in the manufacturing process, dry preparation is a simpler way, but the microparticle dust state resources are loaded in smoke and are difficult to capture, because the microparticle dust state resources are easy to escape and lose and even form pollutants, particularly resources such as beryllium, lead, tin, cadmium, zinc, manganese, nickel and the like, and in the smelting process, the microparticles are extremely small, the value is high, the toxicity is high, and the contradiction between resource collection and pollution control is particularly outstanding. The same problems are faced by plastics, pharmaceutical and cement manufacturing industries. To avoid this contradiction, more complex processes often have to be used, which greatly increases the cost and reduces the resource utilization.
The core problem is to separate these resources from the flue gas carrying them, and the core difficulty is the technical performance problems of the filter for separating flue gas from the fine particulate resources, such as efficiency, wind resistance, dust holding capacity, corrosion resistance, high temperature resistance, etc.
For example, the current common dust removal and recovery technology is electrostatic dust removal and cloth bag dust removal, the highest reported treatment level is a film-covered cloth bag dust remover, and the filtering effect of the cloth bag dust remover can reach 5-7mg/m, and although the value is high, the technology is not enough in terms of resource recovery and pollution control. Particularly, the metal dust such as beryllium, lead and the like has quite high toxicity and must be thoroughly treated, the optimal leakage index is at the level of below 1-30 ug/m, the most strict standard in reality is 5-7mg/m, and the gap is thousands of times from the ideal target. This index can only be achieved up to what is known as an "absolute filter" level in the row, and so the powdery resource recovery means in this sense can be referred to as "powdery resource absolute recovery means".
Conventional 13-14 stage high efficiency filters (hape), commonly used to make "absolute filters" in standard filtration devices, have extremely high hape windage; the energy consumption is very high; the dust holding capacity is very small and can be easily blocked, so that the dust holding capacity needs to be replaced frequently, and the operation cost is very high, and the defects make the traditional hape unsuitable for manufacturing the recovery and filtration equipment of the powdery resources in the mass production process.
The 2018 national intellectual property agency accepted the Guo Shaohua application for a hollow fiber membrane module for treating high dust gas and its application structure (2018209712467). Numerous experiments and field applications have shown that this technique can reach levels of 1-10 ug/m, which would be possible to solve the above-mentioned problems if it could be used for powdery resource recovery.
The gas purification and the resource recovery are seemingly the same problems, but the difference between the two is quite clear, the former focuses on the purity of the gas, and the latter pursues the recovery of powdery resources. With respect to the differences, the device configurations involved will vary. For example, in the conventional membrane modules, the spacing between membrane wires is very small in order to pursue packing rate, but the membrane modules for resource recovery must appropriately increase the spacing between membrane wires to avoid dust accumulation, which also puts new demands on the structure.
Therefore, the absolute recovery device of powdery resources which can reach the microgram level is a new design which needs innovation.
Disclosure of Invention
The present invention aims to provide a solution for efficiently separating powdery resources from mixed flue gas of gas and powdery resources, and provides a powdery resource recovery device, which is characterized in that: using plastic hollow fiber membrane wires as a recovery filter material, forming a membrane assembly by using the membrane wires, and forming a recovery array by using the membrane assembly; the recovery array is arranged in a cabinet, the cabinet is divided into an upper layer and a lower layer, the air outlet end of the membrane component is arranged on the upper layer of the cabinet, the membrane wire is arranged on the lower layer of the cabinet, the upper layer of the cabinet is provided with negative pressure air, the negative pressure air flows through the central hole of the membrane wire, namely the wall of the membrane wire, and the gas carrying metal, metal oxide, cement, plastic and medicine powder resources to be recovered is attracted, and the metal, metal oxide, cement, plastic and medicine powder resources carried by the gas are adsorbed on the outer wall of the membrane wire; the high-pressure back blowing device is arranged at the position of the air outlet port of the membrane wire, high-pressure air pulses are intermittently blown into the center of the membrane wire, metal oxide, cement, plastic and medicine powder resources adsorbed on the outer wall of the membrane wire are blown down, and the powder resources fall at the funnel port at the bottom of the lower layer of the cabinet and are recovered through the funnel port.
Further, the plastic hollow fiber membrane wires are polytetrafluoroethylene hollow fiber membrane wires, the diameter of the membrane wires is 3-20 mm, the length of the membrane wires is 0.3-2 m, and the membrane wires are subjected to hydrophilic treatment to prevent static electricity accumulation.
Further, the diameter of the membrane component is 50 mm-300 mm, the number of membrane wires of each membrane component is 30-1000, and the distance between the membrane wires is 2 mm-20 mm.
Further, two modes of forming the membrane assembly by using the membrane wires are adopted, one mode is a high-temperature membrane assembly which is resistant to powdery resource gas with the height of 300 ℃ at most, the high-temperature membrane assembly is formed by arranging a membrane wire nozzle array on a flower plate made of metal, ceramic or plastic, one end of each membrane wire nozzle is fixed on the flower plate in a threaded or press-connection mode, each membrane wire corresponds to one membrane wire nozzle, and the other end of each membrane wire is fixed with the membrane wire nozzle in a press-connection or adhesive mode; the distance between each two membrane wires is 2-20 mm;
the other is a low-temperature membrane component which can resist the low-temperature powdery resource-containing gas with the temperature of up to 200 ℃, wherein the membrane wires are cast into the membrane component by a plastic casting method, and the distance between each two membrane wires is 2-20 mm.
Further, the high-temperature membrane component is structurally characterized by comprising membrane wires, a shell, a pattern plate, a nozzle plate, membrane wire nozzles, a sealing ring and dust sensors, wherein the membrane wire nozzles are hollow tubes, all the membrane wire nozzles penetrate through the pattern plate, the membrane wires are fixed at one end of the membrane wire nozzles one by one, and the other end of the membrane wire nozzles are fixed on the pattern plate in a threaded or press-connection mode to form an array; a nozzle plate is arranged at a distance of 3-30 mm away from the upward side of the flower plate, a nozzle array is fixed on the nozzle plate, and the nozzles are downward and face each central hole of the film yarn nozzle penetrating through the flower plate one by one; the pattern plate and the nozzle plate are arranged in the shell, the nozzle plate divides the shell into a high-pressure bin and a low-pressure bin, a high-pressure air inlet is distributed on the outer wall of the high-pressure bin of the shell, and a low-pressure air outlet is distributed on the outer wall of the low-pressure bin of the shell; the sealing ring is arranged at the combining position of the lower part of the flower plate and the cabinet.
Furthermore, the air outlet end of each high-temperature membrane module or each low-temperature membrane module in the recovery array is respectively provided with one dust sensor, and the working state and the effect of each membrane module are monitored on line.
Drawings
FIG. 1 is an expanded schematic view of an example of a high temperature membrane module used in the powdery resource recovery apparatus according to the present invention.
Fig. 2 is a schematic diagram of a cabinet used in the powdery resource recycling apparatus according to the present invention.
FIG. 3 is a photograph of a small laboratory bench of the powdery resource recovery device of the present invention on-line experiment on a zinc oxide production line.
Description of the embodiments
An example of an embodiment of a high temperature membrane module used in a powdery resource recovery device according to the present invention is given in fig. 1. But this is not the only design.
Wherein the method comprises the steps of
2 is the upper half of the housing for forming the high pressure chamber.
And 1 is a high-pressure air inlet arranged on the high-pressure bin and used for being connected with a high-pressure back-blowing compressed air source and receiving pulsed high-pressure back-blowing air through a control valve.
And 3 is a nozzle array formed by nozzles, and each nozzle is opposite to the upper half part of one film wire nozzle.
And 4, a pattern plate, wherein a film wire nozzle array is arranged on the pattern plate.
And 5 is the lower half part of the shell and is used for forming a low-pressure bin, and a low-pressure air outlet 6 is distributed on the bin wall of the low-pressure bin.
And 6 is a low pressure vent.
And 7, a film wire nozzle is a hollow pipe, the upper end of the film wire nozzle is provided with threads, the film wire nozzle is screwed on the flower plate, the other end of the film wire nozzle is fixedly provided with film wires, and each film wire can be unscrewed together with the film wire nozzle for replacement.
And 8, a sealing ring is used for sealing the joint of the membrane assembly and the cabinet.
9 is a protective steel cage.
10 is a membrane filament.
01 is a dust sensor, each membrane module is separately provided with a dust sensor for monitoring the working state of the membrane module.
Fig. 2 is a perspective schematic view of one cabinet design employed in the powdery resource recovery device according to the present invention, but this is not the only design.
Wherein the method comprises the steps of
11 is the cabinet body of the cabinet.
12 is the upper layer of the cabinet, in which the upper half of the array of membrane modules is located, with air at negative pressure.
13 is the funnel opening
14 is the upper layer of the cabinet, in which the lower half of the membrane module array, mainly the membrane wire array, is mounted.
A small experimental device manufactured according to the aim of the invention performs on-line experiments on a zinc oxide production line, and experiments prove that the upper limit of the working temperature of the high-temperature membrane component can reach 300 ℃, can work for a long time under the condition of 210 ℃ and can not generate blockage phenomenon after long-term operation. The dust collection rate can reach more than 99.99%, the leaked dust PM2.5 is below 20ug/m, and as can be seen from the field photo figure 3, the leaked dust data on the field is PM2.5 of 6ug/m, PM10 of 12ug/m, and wind resistance is less than 900pa.
The powdery resource recovery device provided by the invention can work under the high-temperature condition of below 300 ℃; the wind resistance is only half of that of a common bag-type dust collector; the interception index is improved by 1000-10000 times, and the method can be widely used in powder resource recovery occasions in industries such as metal, metal oxide, cement, plastic, pharmacy and the like, can completely recover resources, and can thoroughly avoid pollution caused by dust leakage. Has great economic and social values.

Claims (4)

1. Powdery resource recovery unit, its characterized in that: using plastic hollow fiber membrane wires as a recovery filter material, forming a membrane assembly by using the membrane wires, and forming a recovery array by using the membrane assembly; the recovery array is arranged in a cabinet, the cabinet is divided into an upper layer and a lower layer, the air outlet end of the membrane component is arranged on the upper layer of the cabinet, the membrane wire is arranged on the lower layer of the cabinet, the upper layer of the cabinet is negative pressure air, the negative pressure air flows through the central hole of the membrane wire, namely the wall of the membrane wire, and attracts gas carrying powdery resource substances to be recovered, and the powdery resource substances carried by the gas are adsorbed on the outer wall of the membrane wire; a high-pressure back blowing device is arranged at the position of the air outlet port of the membrane wire, high-pressure air pulses are intermittently blown into the center of the membrane wire, powdery resource substances adsorbed on the outer wall of the membrane wire are blown down, and the powdery resource substances fall at a funnel port at the bottom of the lower layer of the cabinet and are recovered through the funnel port;
the membrane assembly consisting of the membrane wires can tolerate the powdery resource gas with the maximum height of 300 ℃, the membrane assembly is characterized in that a pattern plate made of metal, ceramic or plastic is provided with a membrane wire nozzle array, one end of each membrane wire is fixed on the pattern plate in a threaded or press-connection mode, each membrane wire corresponds to one membrane wire nozzle, and the other end of each membrane wire is fixed with the membrane wire nozzle in a press-connection or adhesive mode;
the membrane assembly is structurally characterized by comprising membrane wires, a shell, a pattern plate, a nozzle plate, membrane wire nozzles, sealing rings and dust sensors, wherein the membrane wire nozzles are hollow tubes, all the membrane wire nozzles penetrate through the pattern plate, the membrane wires are fixed at one end of the membrane wire nozzles one by one, and the other end of the membrane wire nozzles are fixed on the pattern plate in a threaded or press-connection mode to form an array; a nozzle plate is arranged at a distance of 3-30 mm away from the upward side of the flower plate, a nozzle array is fixed on the nozzle plate, and the nozzles are downward and face each central hole of the film yarn nozzle penetrating through the flower plate one by one; the pattern plate and the nozzle plate are arranged in the shell, the nozzle plate divides the shell into a high-pressure bin and a low-pressure bin, a high-pressure air inlet is distributed on the outer wall of the high-pressure bin of the shell, and a low-pressure air outlet is distributed on the outer wall of the low-pressure bin of the shell; the sealing ring is arranged at the combining position of the lower part of the flower plate and the cabinet.
2. The powder resource recycling apparatus according to claim 1, wherein the plastic hollow fiber membrane filaments are polytetrafluoroethylene hollow fiber membrane filaments having a diameter of 3mm to 20mm and a length of 0.3m to 2m, and the membrane filaments are subjected to hydrophilic treatment.
3. A powdery resource recovery device according to claim 1, wherein the diameter of the membrane modules is 50mm to 300mm, the number of membrane filaments per membrane module is 30 to 1000, and the distance between the membrane filaments is 2mm to 20mm.
4. The powder resource recycling apparatus according to claim 1, wherein the gas outlet end of each membrane module in the recycling array is provided with a dust sensor, and the working state and effect of each membrane module are monitored on line.
CN201811551237.3A 2018-12-18 2018-12-18 Powdery resource recovery device Active CN109692535B (en)

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Application Number Priority Date Filing Date Title
CN201811551237.3A CN109692535B (en) 2018-12-18 2018-12-18 Powdery resource recovery device
PCT/CN2019/099974 WO2020125026A1 (en) 2018-12-18 2019-08-09 Powdery resource recovery device

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Application Number Priority Date Filing Date Title
CN201811551237.3A CN109692535B (en) 2018-12-18 2018-12-18 Powdery resource recovery device

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CN109692535B true CN109692535B (en) 2024-03-22

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109692535B (en) * 2018-12-18 2024-03-22 广东风和洁净工程有限公司 Powdery resource recovery device
CN110064261A (en) * 2019-06-08 2019-07-30 郭绍华 It is a kind of processing high humility, high temperature, high-dust flue gas high-precision deduster
CN113441726B (en) * 2021-06-03 2023-03-24 西北稀有金属材料研究院宁夏有限公司 Method for recovering low-temperature sintered beryllium scraps

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JPS6068027A (en) * 1983-09-22 1985-04-18 Nippon Atom Ind Group Co Ltd Apparatus for removing minute grain contained in gas
CN202212107U (en) * 2011-07-21 2012-05-09 曾国明 Air purifier
CN103118766A (en) * 2010-09-24 2013-05-22 西门子工业公司 Fluid control manifold for membrane filtration system
CN108211573A (en) * 2018-03-24 2018-06-29 郭绍华 A kind of hollow-fibre membrane dusty gas cleaning plant
CN211189524U (en) * 2018-12-18 2020-08-07 广东风和洁净工程有限公司 Powdery resource recovery device

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CN201996463U (en) * 2011-04-12 2011-10-05 江苏净威环保有限公司 Industrial high-negative pressure dust collector
CN103463896B (en) * 2013-09-09 2016-01-27 佛山市人居环保工程有限公司 A kind of long-pending rack-layer thickness is controlled, sorting, continuous print deduster method of operating
CN103752104B (en) * 2014-01-28 2016-06-29 浙江吉天环保科技有限公司 High-temperature cartridge deduster
CN206642497U (en) * 2017-04-18 2017-11-17 安徽省金建工程技术有限公司 A kind of microporous barrier chimney filter filtration dust catcher
CN109692535B (en) * 2018-12-18 2024-03-22 广东风和洁净工程有限公司 Powdery resource recovery device
CN109433006A (en) * 2019-01-02 2019-03-08 郭绍华 A kind of flue gas treating process process and its equipment configurations

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6068027A (en) * 1983-09-22 1985-04-18 Nippon Atom Ind Group Co Ltd Apparatus for removing minute grain contained in gas
CN103118766A (en) * 2010-09-24 2013-05-22 西门子工业公司 Fluid control manifold for membrane filtration system
CN202212107U (en) * 2011-07-21 2012-05-09 曾国明 Air purifier
CN108211573A (en) * 2018-03-24 2018-06-29 郭绍华 A kind of hollow-fibre membrane dusty gas cleaning plant
CN211189524U (en) * 2018-12-18 2020-08-07 广东风和洁净工程有限公司 Powdery resource recovery device

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Effective date of registration: 20190711

Address after: Room 309, Meisheng Chuanggu Summer Valley, No. 10 Longchang Road, Xin'an Street, Baoan District, Shenzhen City, Guangdong Province

Applicant after: GUANGDONG FENGHE PURIFICATION ENGINEERING Co.,Ltd.

Address before: 518000 Building C 1001, Xiamengyuan, 2075 Lianhua West Road, Futian District, Shenzhen City, Guangdong Province

Applicant before: Guo Shaohua

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