CN109667153A - A kind of fabric anti-flaming dope and the flame retardant fabric using the anti-flaming dope - Google Patents

A kind of fabric anti-flaming dope and the flame retardant fabric using the anti-flaming dope Download PDF

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Publication number
CN109667153A
CN109667153A CN201811369041.2A CN201811369041A CN109667153A CN 109667153 A CN109667153 A CN 109667153A CN 201811369041 A CN201811369041 A CN 201811369041A CN 109667153 A CN109667153 A CN 109667153A
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parts
flaming dope
cloth
fabric
flame retardant
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Inventor
张拥军
吴彤
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NANTONG RURI TEXTILES CO Ltd
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NANTONG RURI TEXTILES CO Ltd
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Priority to CN201811369041.2A priority Critical patent/CN109667153A/en
Publication of CN109667153A publication Critical patent/CN109667153A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35Heterocyclic compounds
    • D06M13/355Heterocyclic compounds having six-membered heterocyclic rings
    • D06M13/358Triazines
    • D06M13/364Cyanuric acid; Isocyanuric acid; Derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/368Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34Polyamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30Flame or heat resistance, fire retardancy properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The present invention relates to the technical fields of textile material, more particularly to a kind of fabric anti-flaming dope, raw material including following parts by weight: 30-60 parts of silicone resin, 5-10 parts of metal hydroxides, 5-15 parts of hexamethylolmelamine, 10-20 parts of polyethylene glycol and 1-5 parts of fatty alcohol polyoxyethylene ether, the silicone resin is by dimethyl silicone polymer and Methyl Hydrogen Polysiloxane Fluid according to silicon mass content than being polymerized for the proportion of 3:1-8:1;To make anti-flaming dope of the invention be suitble to the processing of personal clothing or daily worn cotton or relatively soft clothing cloth, application range and applicability are stronger;A kind of flame retardant fabric of application anti-flaming dope is further related to, it is blended that the cloth is selected from cotton, terylene, polyamide fibre or polyester-cotton blend;Make cloth after using the anti-flaming dope, on the basis of keeping original comfort level and pliability, improves the flame retardant property of cloth.

Description

A kind of fabric anti-flaming dope and the flame retardant fabric using the anti-flaming dope
Technical field
The present invention relates to the technical fields of textile material, and in particular to a kind of fabric anti-flaming dope and applies the fire-retardant painting The flame retardant fabric of material.
Background technique
Fabric is mostly all inflammable since it is at the reason being grouped as through being formed by weaving, even if encountering a little fire Star is also easy kindling, or part is burnt out, gently then surface damage, heavy then burn hole etc., this has seriously affected it using imitating Fruit, if anti-fire is bad, the use of fabric will receive significant limitation.
In order to improve the flame retardant property of fabric or cloth, occur many fire protection flame retarding clothes and fire prevention in the prior art Clothes.In patent CN105220314B, resistance to 320~340 DEG C fire- resistance cloth of one kind and preparation method thereof is disclosed, weaving material is belonged to Material and fireproofing technique field.Warp thread composition are as follows: (by mass percentage) poly- phosphamide fiber 30~70%, aramid fiber 30~ 70%, weft yarn composition are as follows: long-staple cotton 1~30%, poly- phosphamide fiber 29~70%, alginate fibre 29~70%;In this application It is blended at warp yarns with poly- phosphamide fiber and aramid fiber;With long-staple cotton, poly- phosphamide fiber and seaweed fiber blending at Weft yarn;By warp thread in conjunction with weft yarn, using staggeredly weave, it is made into the fire- resistance cloth with certain density;It uses structure strong It spends that the cloth hardness that biggish fiber is staggeredly mutually knitted is larger, and softness is not good enough, is unsuitable for making personal clothing or daily Worn cotton or relatively soft clothing.
In patent CN105734958A, a kind of manufacturing method of fireproof cloth is disclosed, comprising the following steps: (1) take Boric acid, zinc borate and aluminium borate, which are dissolved in the water, prepares solution, and woven cloth is placed in configured solution, impregnates 15 Hour or more, it every 5 hours, stirs, swipes cloth back and forth in design on fabric surface with brush;(2) by resulting cloth in temperature It is dried in environment greater than 40 DEG C;(3) step (2) resulting cloth is immersed in pure acrylic latex in closed environment In, 12 hours are impregnated, and take out, in environment of the temperature no more than 25 DEG C, the wind of 5.5m/s is not more than with wind speed, is blown It is dry;(4) step (1) resulting fabric is immersed into water glass solution, impregnates 1.5 hours, after taking-up, entirely spreads out, Three stackings are closed, and are extruded to shape with compression roller, and in gentle breeze, until fabric is dry.The method by soaking cloth three times Bubble processing is affected to fabric itself original performance such as intensity, color fastness etc. to improve its fire protecting performance, and control is improper can Fabric feeling can be made to harden, to influence whether the texture and quality of cloth.
Summary of the invention
In view of the deficienciess of the prior art, the first purpose of this invention is to provide a kind of suitable personal clothing or day The often fabric anti-flaming dope of worn cotton or relatively soft clothing cloth.
The first purpose of this invention is achieved through the following technical solutions:
A kind of fabric anti-flaming dope, the raw material including following parts by weight: 30-60 parts of silicone resin, metal hydroxides 5- 10 parts, 5-15 parts of hexamethylolmelamine, 10-20 parts of polyethylene glycol and 1-5 parts of fatty alcohol polyoxyethylene ether, the silicone tree Rouge is by dimethyl silicone polymer and Methyl Hydrogen Polysiloxane Fluid according to silicon mass content than being polymerized for the proportion of 3:1-8:1.
By using above-mentioned technical proposal, dimethyl silicone polymer is also referred to as dimethicone, colourless or light yellow liquid, Tasteless, transparency is high, and it is small to have many advantages, such as that heat resistance, cold resistance, viscosity vary with temperature small, waterproofness, surface tension.Diformazan Base silicone oil is non-toxic and tasteless, has physiological inertia and good chemical stability, electrical insulating property, weatherability, hydrophobicity are good, and have There is very high anti-shear ability, can be used for a long time at -50 DEG C~200 DEG C.Methyl Hydrogen Polysiloxane Fluid is commonly called as containing hydrogen silicone oil, molecule Formula are as follows: (CH3)3SiO[(CH3)(H)SiO]nSi(CH3)3, Methyl Hydrogen Polysiloxane Fluid is polymerize with linear dimethyl silicone polymer To netted silicone resin, it had not only been able to maintain fabric original gas permeability and flexibility, but also the tearing strength of fabric, friction can be improved Intensity and soil resistance, and have the function of more excellent UV resistance.Hexamethylolmelamine, in without acid aqueous solution A couple of days can be kept to stablize, it can be shared with cation and non-ionic softening agent and bleeding agent.Metal hydroxides plays master Fire-retardant effect is wanted, but needs to cooperate the hexamethylolmelamine in the present invention that can just give full play to it in anti-flaming dope In fire retardation, then by netted silicone resin and metal hydroxides polymeric modification, auxiliary is to emulsify levelling agent fat Alcohol polyoxyethylene ether, antistatic lubricant polyethylene glycol act synergistically between each other, and being formed has preferable flame retardant effect and fit For the anti-flaming dope of soft or soft cloth, so as to be applied to personal clothing or daily worn cotton or relatively soft clothing In the flame retardant treatment of cloth.
Preferably, including the raw material of following parts by weight: 40-50 parts of silicone resin, 6-8 parts of metal hydroxides, six 8-12 parts of melamine methylol, 12-16 parts of polyethylene glycol and 2-4 parts of fatty alcohol polyoxyethylene ether, the silicone resin is by gathering Dimethyl siloxane and Methyl Hydrogen Polysiloxane Fluid are according to silicon mass content than being polymerized for the proportion of 5:1-7:1.
Preferably, the adduct number of the fatty alcohol polyoxyethylene ether ethylene oxide is 11-16.
By using above-mentioned technical proposal, fatty alcohol polyoxyethylene ether, RO(CH2CH2O)nH, R be generally be saturated or not The C of saturation12~18Alkyl, be straight-chain alkyl, be also possible to branched alkyl;N is the adduct number of ethylene oxide, that is, The number of oxyethylene group in surfactant molecule.N is bigger, and the oxygen on molecule hydrophilic group is more, can be formed more with water Hydrogen bond is water-soluble better.When n=1 ~ 5, product can be dissolved in oil and not soluble in water, often as preparing sulfuric acid ester anionic surface The raw material of activating agent.When n=6 ~ 8, it can be dissolved in water, be commonly used for the detergent and grease emulsifier of textile.When n=10 ~ 20, commonly use Make emulsifier and levelling agent.By experimental results demonstrate cooperate other raw materials at n=11 ~ 16 in the present invention, treated cloth Expect that color is best.
Preferably, the average molecular weight of the polyethylene glycol is 4000-6000.
By using above-mentioned technical proposal, polyethylene glycol, abbreviation PEG, PEG-4000,6000 be used as in textile industry it is anti- Electrostatic agent, lubricant etc. play certain wettability, make silicone resin and metal applied in anti-flaming dope of the invention It is easier to interpenetrate modification between hydroxide, improves the performance of the overall flame air-moisture-permeable of anti-flaming dope.
Preferably, the metal hydroxides is magnesium hydroxide or aluminium hydroxide.
Preferably, the average grain diameter of the metal hydroxides is 1-10 μm.
By using above-mentioned technical proposal, while guaranteeing that fire retardant matter plays a role, fire retardant matter particle is reduced, is reduced Influence to cloth softness, to avoid causing the hardness of clothing to increase because using the anti-flaming dope, degree of comfort decreased The problem of occur.
Preferably, further including 5-15 parts of triethanolamine.
By using above-mentioned technical proposal, triethanolamine, for being good solvent in textile industry, hygroscopic agent is to knit The raw material of object softening agent.The flexibility of cloth processed can further be improved by adding suitable triethanolamine, to improve Comfort level.
A second object of the present invention is to provide a kind of flame retardant fabric processed using above-mentioned fabrics with anti-flaming dope, Make cloth after using the anti-flaming dope, on the basis of keeping original comfort level and pliability, improves the flame retardant property of cloth.
Second object of the present invention is achieved through the following technical solutions:
A kind of flame retardant fabric that fabric is processed with anti-flaming dope, it is blended that the cloth is selected from cotton, terylene, polyamide fibre or polyester-cotton blend.
It is obtained preferably, it is handled as follows:
(1) the two-sided of cloth to be processed is coated with insulating layer, drying obtains cloth germule;
(2) the two-sided of above-mentioned cloth germule is coated with the anti-flaming dope, coating thickness 1-2mm, up to fire-retardant after drying Cloth.
Preferably, drying 20-40min at 80-95 DEG C in the step (1);In the step (2), prior to 100 1-3min is dried at DEG C, then is warming up at 180-195 DEG C and is dried 3-5min.
Fire-retardant painting of the invention is coated with after the surface layer of soft cloth is applied layer of cloth by using above-mentioned technical proposal Material, drying.And the temperature and time of drying is controlled, especially the drying time after coating anti-flaming dope is shorter, drying Temperature is relatively high, makes anti-flaming dope by " dodge dry " and is firmly coated on cloth, will not the property such as hardness to cloth itself It can have adverse effect on, guarantee the soft comfort level of cloth.
In conclusion the invention has the following beneficial effects:
(1) silicone resin is compounded to obtain anti-flaming dope with fire proofing, has both the breathable moisture permeability and fire-retardant material of silicone resin The flame retardant property of material, and other auxiliary agents are assisted, so that anti-flaming dope of the invention is suitable for soft cloth, to be suitble to daily clothing The working process of object cloth, expands application range;
(2) anti-flaming dope of the invention is directly treated to processing cloth to be processed in the way of coating, is had The flame retardant fabric of flame retardant property, limit oxygen index are up to 39.9%, are not affected in performances such as guarantee cloth itself pliabilitys While, improve the flame retardant property of cloth.
Specific embodiment
Each auxiliary agent and raw material used are commercial product in the present invention.Anti-flaming dope in the present invention can be used for cotton, wash In synthetic fibre, polyamide fibre or the blended fire-retardant working process of cloth of polyester-cotton blend, specific processing method is identical, carries out by taking polyamide fibre cloth as an example below Explanation.
Embodiment 1
By silicone resin 60g, average grain diameter be 5 μm magnesium hydroxide 10g, hexamethylolmelamine 10g, average molecular weight be The fatty alcohol polyoxyethylene ether 5g that 4000 polyethylene glycol 10g and the adduct number of ethylene oxide are 11 is thoroughly mixed, and is obtained The anti-flaming dope of embodiment 1.Wherein, silicone resin is by dimethyl silicone polymer and Methyl Hydrogen Polysiloxane Fluid according to silicon mass content ratio It is polymerized for the proportion of 3:1, the conventional technical means that polymerization polymerize with operating procedure for silicone resin is no longer superfluous herein It states.
Embodiment 2
Embodiment 2 the difference from embodiment 1 is that: the anti-flaming dope in embodiment 2 is silicone resin 50g, average grain diameter is 10 μ The aluminium hydroxide 8g of m, hexamethylolmelamine 12g, the polyethylene glycol 16g that average molecular weight is 4000 and ethylene oxide plus It is thoroughly mixed and obtains for 16 fatty alcohol polyoxyethylene ether 4g at number.Wherein, silicone resin by dimethyl silicone polymer with Methyl Hydrogen Polysiloxane Fluid is according to silicon mass content than being polymerized for the proportion of 7:1.
Embodiment 3
Embodiment 3 the difference from embodiment 1 is that: the anti-flaming dope in embodiment 3 is silicone resin 40g, average grain diameter is 1 μm Magnesium hydroxide 6g, hexamethylolmelamine 8g, average molecular weight be 4000 polyethylene glycol 12g and ethylene oxide addition Number is thoroughly mixed and obtains for 14 fatty alcohol polyoxyethylene ether 2g.Wherein, silicone resin is by dimethyl silicone polymer and first Base containing hydrogen silicone oil is according to silicon mass content than being polymerized for the proportion of 5:1.
Embodiment 4
Embodiment 4 the difference from embodiment 1 is that: the anti-flaming dope in embodiment 4 is silicone resin 30g, average grain diameter is 5 μm Magnesium hydroxide 5g, hexamethylolmelamine 5g, average molecular weight be 4000 polyethylene glycol 20g and ethylene oxide addition Number is thoroughly mixed and obtains for 13 fatty alcohol polyoxyethylene ether 1g.Wherein, silicone resin is by dimethyl silicone polymer and first Base containing hydrogen silicone oil is according to silicon mass content than being polymerized for the proportion of 8:1.
Embodiment 5
Embodiment 5 the difference from embodiment 1 is that: the anti-flaming dope in embodiment 5 is silicone resin 45g, average grain diameter is 5 μm Magnesium hydroxide 8g, hexamethylolmelamine 15g, average molecular weight be 4000 polyethylene glycol 15g and ethylene oxide plus It is thoroughly mixed and obtains for 14 fatty alcohol polyoxyethylene ether 3g at number.Wherein, silicone resin by dimethyl silicone polymer with Methyl Hydrogen Polysiloxane Fluid is according to silicon mass content than being polymerized for the proportion of 6:1.
Embodiment 6
Embodiment 6 and the difference of embodiment 5 are: the triethanolamine of 5g is also added into the anti-flaming dope in embodiment 6.
Embodiment 7
Embodiment 7 and the difference of embodiment 5 are: the triethanolamine of 10g is also added into the anti-flaming dope in embodiment 7.
Embodiment 8
Embodiment 8 and the difference of embodiment 5 are: the triethanolamine of 15g is also added into the anti-flaming dope in embodiment 8.
The application examples of anti-flaming dope prepared by the present invention
Application examples 1
It is the double spread insulating layer of the polyamide fibre cloth of 5m by length and width, 40min is dried at 80 DEG C, then double spread is real again Apply the anti-flaming dope of example 7, coating thickness 1-2mm, after coating uniformly, prior to 100 DEG C at dry 3min, then be warming up to 180 DEG C Lower drying 5min, obtains the flame retardant fabric of application examples 1.
Application examples 2
Application examples 2 and the difference of application examples 1 are: the double spread that length and width are the polyamide fibre cloth of 5m insulating in application examples 2 Layer, dries 20min at 90 DEG C, and then the anti-flaming dope of double spread embodiment 7, coating thickness 1-2mm, coating are uniform again Afterwards, prior to 100 DEG C at dry 1min, then be warming up at 195 DEG C and dry 3min, obtain the flame retardant fabric of application examples 2.
Application examples 3
Application examples 3 and the difference of application examples 1 are: the double spread that length and width are the polyamide fibre cloth of 5m insulating in application examples 3 Layer, dries 30min at 95 DEG C, and then the anti-flaming dope of double spread embodiment 7, coating thickness 1-2mm, coating are uniform again Afterwards, prior to 100 DEG C at dry 2min, then be warming up at 190 DEG C and dry 2min, obtain the flame retardant fabric of application examples 3.
Application examples 4-10
Application examples 4-10 is that the anti-flaming dope of embodiment 1-6 and embodiment 8 are successively coated on polyamide cloth with the method for application examples 2 The flame retardant fabric of the application examples 4-10 obtained on material.
Comparative example 1
Comparative example 1 and the difference of application examples 2 are: hexamethylolmelamine is not added in flame retardant fabric.
Comparative example 2
Comparative example 2 and the difference of application examples 2 are: after anti-flaming dope coating uniformly, drying 5min at 100 DEG C, obtain comparative example 2 Flame retardant fabric.
Comparative example 3
Comparative example 3 and the difference of application examples 2 are: without magnesium hydroxide in anti-flaming dope, remaining is identical as application examples 2.
Blank group
The difference of blank group and application examples 2 is: the two-sided uncoated any anti-flaming dope of cloth, remaining is identical as application examples 2.
Performance test
Flame retardant property survey is carried out to the flame retardant fabric of application examples 1-10 and comparative example 1-2 according to the method for GB/T 5454-1997 Examination;Color variation after observing the color situation of each cloth and washing 50 times;And feel degree is detected, test result is shown in Table Shown in 1.Wherein, limit oxygen index refers to the volume point of polymer oxygen when can just support its burning in oxygen and nitrogen mixture gas Particle density.It is the index for characterizing material combustion behavior.It has been generally acknowledged that the substance can fire in air when limit oxygen index is 22 It burns.Limit oxygen index refers under the defined conditions, most hypoxemia needed for material carries out flaming combustion in oxygen-nitrogen mixture stream Concentration.It is indicated with the numerical value of percentage by volume shared by oxygen.Oxygen index (OI) height indicates that material is nonflammable, the low expression material of oxygen index (OI) Material is easy burning, it is considered that oxygen index (OI) < 22% belongs to combustible material, and oxygen index (OI) belongs to combustible material between 22%-27%, and oxygen refers to Number > 27% belongs to nonflammable material.
The performance test results of each flame retardant fabric of table 1
As shown in Table 1, by anti-flaming dope of the invention treated cloth, excellent flame retardant property is all had, Change it for nonflammable material by combustible material, and limit oxygen index is up to 39.9%, makes the flame retardant property of soft cloth It is greatly improved.By blank group and application examples 1-3 and the Comparative result of application examples 9 and 10 it is found that resistance of the invention Added with after triethanolamine in burning coating material, further improvement is obtained to the feel of cloth, has kept cloth more smooth, it is fine and smooth.
By the testing result of comparative example 1 it is found that flame retardant property of the hexamethylolmelamine to anti-flaming dope in the present invention There is large effect, the flame retardant property of cloth substantially reduces if without hexamethylolmelamine, and becomes flammable from fire retardant.And And comparative example 3 is combined it is found that metal hydroxides plays main fire-retardant effect, if being that the present invention is implemented without metal hydroxides The presence of magnesium hydroxide and aluminium hydroxide in example, then the flame retardant property of resulting cloth substantially reduces, and becomes inflammable from fire retardant. It is proved by comparative example 1 in conjunction with comparative example 3, the metal hydroxides in the present invention needs to cooperate the hexamethylol trimerization in the present invention Cyanamide can just give full play to its fire retardation in anti-flaming dope, then by netted silicone resin and metal hydroxides Polymeric modification, auxiliary is to emulsify levelling agent fatty alcohol polyoxyethylene ether, and antistatic lubricant polyethylene glycol, collaboration is made between each other With, the anti-flaming dope that there is preferable flame retardant effect and be suitable for soft or soft cloth is formed, it is personal so as to be applied to In the flame retardant treatment of clothing or daily worn cotton or relatively soft clothing cloth.
In the present invention, Methyl Hydrogen Polysiloxane Fluid is polymerize to obtain netted silicone resin with linear dimethyl silicone polymer, Not only it had been able to maintain fabric original gas permeability and flexibility, but also the tearing strength, friction intensity and soil resistance of fabric can have been improved, and have There is more excellent UV resistance function.Hexamethylolmelamine can keep a couple of days to stablize in without acid aqueous solution, it It can be shared with cation and non-ionic softening agent and bleeding agent.Metal hydroxides plays main fire-retardant effect, still Its fire retardation in anti-flaming dope can be given full play to by needing to cooperate the hexamethylolmelamine in the present invention, then By netted silicone resin and metal hydroxides polymeric modification, assist resisting quiet to emulsify levelling agent fatty alcohol polyoxyethylene ether Electric lubricant polyethylene glycol acts synergistically between each other, and being formed has preferable flame retardant effect and be suitable for soft or soft cloth The anti-flaming dope of material, so as to be applied to the flame retardant treatment of personal clothing or daily worn cotton or relatively soft clothing cloth In.In addition, PEG-4000,6000 are used as antistatic agent, lubricant etc. in textile industry, applied to anti-flaming dope of the invention In, certain wettability is played, makes to be easier to interpenetrate modification between silicone resin and metal hydroxides, improve fire-retardant The performance of the overall flame air-moisture-permeable of coating.Triethanolamine, for being good solvent in textile industry, hygroscopic agent is to knit The raw material of object softening agent.Suitable triethanolamine is added in the present invention, can further improve the flexibility of cloth processed, To improve comfort level.
This specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art Member can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as at this All by the protection of Patent Law in the scope of the claims of invention.

Claims (10)

1. a kind of fabric anti-flaming dope, which is characterized in that the raw material including following parts by weight: 30-60 parts of silicone resin, gold Hydroxide 5-10 parts of category, 5-15 parts of hexamethylolmelamine, 10-20 parts of polyethylene glycol and fatty alcohol polyoxyethylene ether 1-5 Part, the silicone resin is by dimethyl silicone polymer and Methyl Hydrogen Polysiloxane Fluid according to silicon mass content than the proportion for 3:1-8:1 It is polymerized.
2. fabric anti-flaming dope according to claim 1, which is characterized in that the raw material including following parts by weight: silicon 40-50 parts of ketone resin, 6-8 parts of metal hydroxides, 8-12 parts of hexamethylolmelamine, 12-16 parts of polyethylene glycol and fat 2-4 parts of alcohol polyoxyethylene ether, the silicone resin is by dimethyl silicone polymer and Methyl Hydrogen Polysiloxane Fluid according to silicon mass content ratio It is polymerized for the proportion of 5:1-7:1.
3. fabric anti-flaming dope according to claim 1, it is characterised in that: epoxy in the fatty alcohol polyoxyethylene ether The adduct number of ethane is 11-16.
4. fabric anti-flaming dope according to claim 1, it is characterised in that: the average molecular weight of the polyethylene glycol is 4000-6000。
5. fabric anti-flaming dope according to claim 1, it is characterised in that: the metal hydroxides is magnesium hydroxide Or aluminium hydroxide.
6. fabric anti-flaming dope according to claim 1, it is characterised in that: the average grain diameter of the metal hydroxides It is 1-10 μm.
7. fabric anti-flaming dope according to claim 1, it is characterised in that: further include 5-15 parts of triethanolamine.
8. a kind of flame retardant fabric processed with the described in any item fabrics of claim 1-7 with anti-flaming dope, feature exist In: it is blended that the cloth is selected from cotton, terylene, polyamide fibre or polyester-cotton blend.
9. flame retardant fabric according to claim 8, which is characterized in that it handles obtain as follows:
(1) the two-sided of cloth to be processed is coated with insulating layer, drying obtains cloth germule;
(2) the two-sided of above-mentioned cloth germule is coated with the anti-flaming dope, coating thickness 1-2mm, up to fire-retardant after drying Cloth.
10. flame retardant fabric according to claim 9, it is characterised in that: in the step (1), dried at 80-95 DEG C 20-40min;In the step (2), prior to 100 DEG C at dry 1-3min, then be warming up at 180-195 DEG C and dry 3-5min.
CN201811369041.2A 2018-11-16 2018-11-16 A kind of fabric anti-flaming dope and the flame retardant fabric using the anti-flaming dope Pending CN109667153A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113308878A (en) * 2021-06-24 2021-08-27 天津市花儿正红仿真花卉有限公司 Preparation method of fabric flame-retardant flower subjected to fireproof treatment

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US20090258182A1 (en) * 2005-07-08 2009-10-15 Daikyo Chemical Co., Ltd., Artificial sueded leather being excellent in flame retardance and method of producing the same
CN103225215A (en) * 2013-04-28 2013-07-31 百利合化工(中山)有限公司 Environmental protection fire retardation type textile printing coating material and preparation method thereof
CN103321052A (en) * 2012-03-23 2013-09-25 东丽纤维研究所(中国)有限公司 Coated fabric for safety airbag and production method thereof
CN103835131A (en) * 2012-11-24 2014-06-04 无锡市银泰纺织品有限公司 Production technology of flame-retardant textile

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090258182A1 (en) * 2005-07-08 2009-10-15 Daikyo Chemical Co., Ltd., Artificial sueded leather being excellent in flame retardance and method of producing the same
CN103321052A (en) * 2012-03-23 2013-09-25 东丽纤维研究所(中国)有限公司 Coated fabric for safety airbag and production method thereof
CN103835131A (en) * 2012-11-24 2014-06-04 无锡市银泰纺织品有限公司 Production technology of flame-retardant textile
CN103225215A (en) * 2013-04-28 2013-07-31 百利合化工(中山)有限公司 Environmental protection fire retardation type textile printing coating material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113308878A (en) * 2021-06-24 2021-08-27 天津市花儿正红仿真花卉有限公司 Preparation method of fabric flame-retardant flower subjected to fireproof treatment

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