CN109464297A - A kind of composition of the solid-state structure containing liquid crystal and its application - Google Patents
A kind of composition of the solid-state structure containing liquid crystal and its application Download PDFInfo
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- CN109464297A CN109464297A CN201811383697.XA CN201811383697A CN109464297A CN 109464297 A CN109464297 A CN 109464297A CN 201811383697 A CN201811383697 A CN 201811383697A CN 109464297 A CN109464297 A CN 109464297A
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- composition
- liquid crystal
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0295—Liquid crystals
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Abstract
The present invention relates to daily use chemicals formula technique field, in particular to a kind of cleaning class product suspension system.A kind of composition of the solid-state structure containing liquid crystal, the hair-washing composition contain the following raw material for accounting for composition weight percentage proportion: (A) anionic surfactant 5-30%；(B) hydroxystearin 0.3-10%；(C) nonionic surfactant 0.05-5%；(D) polysaccharide polymer 0.01-3%；And (E) pure water of surplus.The composition by composition framework rationally build, the limitation of the synergy between raw material, raw material key parameter, it is made that mesomorphic state in the product, can suspend effective particulate matter of product, can also retain the washing original technical characteristic of class product as far as possible.Composition composition is mild, is applicable in various people, significant effect is low in cost, and application is simple and direct.
Description
Technical field
The present invention relates to daily use chemicals formula technique field, in particular to a kind of cleaning class product suspension system further relates to it
Using.
Background technique
Two-in-one dandruff control shampoo containing at this stage especially carries polysiloxane particle and anti-dandruff particle with flocculation to heavy
Product brings conditioning and anti-dandruff effect to hair or scalp, has obviously two-in-one anti-dandruff effect in a short time, so
And for suspend the silicone oil particle added and the effective particle of solid such as zpt etc., it needs that pearly-lustre, card wave etc. is added
Suspending agent suspends.
Similar, it is also known in the field for providing the dandruff control shampoo of conditioning effect.Such as Chinese Patent Application No.
00809131.5 and Chinese Patent Application No. 00808517.X discloses a kind of by anionic surfactant and cationic Guar
The flocculate that gum derivative is formed carries silicone oil particle and zpt particle, by for cationic guar derivative parameter
The ability for carrying effective particulate matter is preferably realized；Chinese Patent Application No. 201480045888.9 also disclose it is a kind of by yin from
Sub- surfactant, amphoteric surfactant and cationic guar derivative carry selenium disulfide, zinc pyrithione and silicon
Oxygen alkane realizes the effect of anti-dandruff conditioning, the former uses pearlescent flake and is used as suspending agent, and the latter is using macromolecules such as card waves
As suspension stabilizer.
Both suspension systems are the suspension system widely used at present, but both suspension systems respectively have its limitation
Property, such as pearly-lustre class suspending agent, it will appearance is generated and is directly changed, and changes its wet hair and drying hair effect, and card wave class
Raw material will change the wadding glue state of product, larger change can also be generated to the conditioning effect of product, therefore find other
Approach realizes the stable suspersion of product, will be carried out other effect, provides other selection.
Summary of the invention
Another liquid that pearly-lustre suspends, card wave suspends is different from technical problem to be solved by the invention is to provide a kind of
Crystalline suspension scheme, this liquid crystal suspension scheme can exist in shampoo and have longer netted linear liquid crystal, and this liquid crystal will not
Gluey state of wadding a quilt with cotton is influenced, will not also generate too much influence to foam, additionally it is possible to the largely due appearance of retained product, it can
Other suspension system selection is provided for technical staff on the basis of existing technology；The composition passes through composition framework
It rationally builds, the limitation of the synergy between raw material, raw material key parameter, is made that mesomorphic state in the product, can hang
Effective particulate matter of floating firmly product, can also retain the washing original technical characteristic of class product as far as possible.Composition composition is mild, right
Various people are applicable in, and significant effect is low in cost, and application is simple and direct.Other technical problems to be solved by this invention are to provide this
The application of the composition of liquid crystal solid-state structure.
Technical scheme is as follows:
A kind of composition of the solid-state structure containing liquid crystal, the hair-washing composition contain the following original for accounting for composition weight percentage proportion
Material:
(A) anionic surfactant 5-30%；
(B) hydroxystearin 0.3-10%；
(C) nonionic surfactant 0.05-5%；
(D) polysaccharide polymer 0.01-3%；
And surplus
(E) pure water.
The anionic surfactant is selected from ethoxylated dodecyl alcohol sulfate, glycerine monofatty ester sulfuric acid
Salt, fatty alcohol ether sulfosuccinate ester salt, N- fatty acyl amino-acid salt, fatty acyl methyl tauride, monoalkyl sulfate are single
Alkyl carboxylate, one or more of alkylphosphonate.Wherein preferred ethoxylated dodecyl alcohol sulfate, monoalkyl
Sulfate, fatty acyl methyl tauride.The emulsifying ability of this surfactant is moderate, can be well in high temperature solubilising hydroxyl
Tristerin contacts it sufficiently with the micella of surfactant, forms Van der Waals force, and keep phase uniform.
The hydroxystearin is obtained with glycerine esterification by hydroxy stearic acid, it is sweet to can be hydroxy stearic acid
Oily monoesters, hydroxystearin diester, one of three ester of hydroxystearin or three kinds or more are arranged in pairs or groups, wherein most preferably
Three ester of hydroxystearin.Main component as liquid crystal is participated in the formation of entire liquid crystal by hydroxystearin.Liquid
Brilliant formation is to first have to guarantee that hydroxystearin is solubilized enough in high temperature, and then as the reduction of temperature, hydroxyl is hard
Glycerol fusing point itself is higher, and then solid states can gradually be precipitated into the suitable situation of surfactant, but
It is due to Van der Waals force, hydroxystearin exists with surfactant always to interact, and then, one kind depends on
The solid matter of the surfactant micellar of system is formed, this is a kind of state between solid-state and liquid, can
It is seen using petrographic microscope, referred to as mesomorphic state.
The nonionic surfactant is selected from fatty acyl single ethanol amide, fatty acyl diglycollic amide, fatty acyl methyl
Single ethanol amide, one of alkyl glycosides or a variety of collocation, preferred fat acyl single ethanol amide, fatty acyl diglycollic amide；
The effect of nonionic surfactant is to assist solubilized hydroxystearin, and assists its precipitation, wherein with fatty acyl
The auxiliaring effect of single ethanol amide, fatty acyl diglycollic amide is more obvious, the mixture energy with hydroxystearin
The processing difficulty for enough reducing hydroxystearin, improves technological feasibility.
The polysaccharide polymer includes anionic polysaccharide polymers, Cationic polysaccharide polymer, nonionic polysaccharide polymerization
Object, amphoteric polysaccharide polymer, the collocation of one or more of hydrophobically modified polysaccharide polymer.
Anionic polysaccharide polymers are selected from alginic acid and its derivative, pectin and its derivative, and angle pitches (dish) glue and its spreads out
Biology, xanthan gum and its derivative, hyaluronic acid and its derivative, Arabic gum and its derivative, karaya gum and its spread out
Biology, bassora gum and its derivative, carboxymethyl cellulose and its derivative, one of carboxymethyl chitosan and its derivative or
Several collocation.
Cationic polysaccharide polymer is selected from chitosan and its derivative, cationic cellulose derivative, cation
The collocation of one or more of guar derivative.
Cationic cellulose derivative meets general formula:
Wherein, R1It is glucoside residue；
Wherein R2Selected from hydroxy alkylidene, alkylene oxide alkylidene, polyoxalkylene and their combination；
Wherein, R3、R4And R5Independently selected from long alkyl chain, each group contains up to 20 carbon atoms；
Wherein, X—Selected from one or more of halogen family anion, sulfate ion, methyl sulfate；
It is preferred that the cationic cellulose derivative for meeting above-mentioned general formula is Polyquaternium-10, there is following ideal structure formula:
And the cationic cellulose derivative nitrogen content is about 0.8% to about 3.1%, while the viscosity of its 2% pure water solution is
About 10000 cps to about 400000 cps.
The charge density of the cationic guar derivative is about 0.2 ~ 1.0 meq/g；And molecular weight is about
100000~2200000 g/mol。
The composition of the above-mentioned solid-state structure containing liquid crystal can also contain following component other than above-mentioned necessary ingredient
One or more of:
Assist suspending agent: 0.01-5%；
Preservative: 0.01-1%；
Essence: 0.01-3%；
Viscosity modifier: 0.01-4%；
Chelating agent: 0.005-0.2%；
Ultraviolet absorbing agent: 0.01-2%；
Plant extracts and its derivative: 0.0001-5%.
A kind of composition of above-mentioned solid-state structure containing liquid crystal, configuration method are the configuration and hybrid technology of routine, herein
It does not elaborate.
The composition of the above-mentioned solid-state structure containing liquid crystal, can arbitrary proportion and common base-material cleaning class product is made, such as wash
Hair product, washes one's hands and uses product at shower product.Dosage form can be solution, suspension, lotion, paste, one in solid-like
Kind.
The invention has the following beneficial effects:
1, composition of the invention, the fusing point containing liquid crystal structure, and this liquid crystal structure can reach 50 ~ 65 DEG C, tolerance
Performance is stablized, and is widely used.
2, composition of the invention has extremely strong suspendability, has suspension to make the particle of big partial size small particle
With；This suspendability is to pass through performance brought by the liquid crystal structure that collocation is formed as composition.
3, composition of the invention, does not influence the foaming properties of product, is not directly changed the appearance of product, if addition is being sent out
The conditioning effect of product is not directly affected among product yet；Such performance gains are able to achieve in its liquid crystal structure and liquid crystal structure
Transparent performance, hydroxystearin will exist not as the form of grease.
4, the compounding synergistic effect between composition of the invention is obvious, by the synergistic effect between raw material, so that liquid
Crystal structure is more easier to be formed, and also reduces whole fusing point, is also exactly the difficulty for improving technique.
Specific embodiment
The present invention will now be described in detail with reference to examples, and the examples are only preferred embodiments of the present invention,
It is not limitation of the invention.
The following table 1 embodiment 1-3 is the shampoo containing liquid crystal structure composition of the present invention, and comparative example 1-3 is three kinds other
The shampoo of formula.Wherein, comparative example 3 selects a kind of pin on the market is measured to be gone with what cationic guar derivative was made into
Consider shampoo to be worth doing.
Table 1: embodiment and comparative example (unit: %)
The observation Testing index of each embodiment and comparative example is as follows:
It can find out in above test, form liquid crystal using hydroxystearin, the steady of product will be greatly improved
Qualitative, and will not substantially change its foam state, gluey state of wadding a quilt with cotton, to the stability of system, there is no existing common suspended substances
System is big.
Following example 4-7 is four additional preferred embodiment of the present invention.
Common base-material is added respectively with 10% weight percent in embodiment 4 and 5, shower cream is made, by embodiment 6 and 7
Common base-material is added with 20% weight percent respectively, hand cleanser is made.The observation Testing index of final products is as follows:
Claims (10)
1. a kind of composition of solid-state structure containing liquid crystal, it is characterised in that contain the following original for accounting for composition weight percentage proportion
Material:
(A) anionic surfactant 5-30%；
(B) hydroxystearin 0.3-10%；
(C) nonionic surfactant 0.05-5%；
(D) polysaccharide polymer 0.01-3%；
And surplus
(E) pure water.
2. the composition of the solid-state structure according to claim 1 containing liquid crystal, it is characterised in that: the anionic surface is living
Property agent be selected from ethoxylated dodecyl alcohol sulfate, glycerine monofatty ester sulfate, fatty alcohol ether sulfosuccinate ester salt, N-
Fatty acyl amino-acid salt, fatty acyl methyl tauride, monoalkyl sulfate, monoalkyl carboxylate, in alkylphosphonate
At least one.
3. the composition of the solid-state structure according to claim 1 containing liquid crystal, it is characterised in that: the anionic surface is living
Property agent be ethoxylated dodecyl alcohol sulfate, monoalkyl sulfate, at least one of fatty acyl methyl tauride.
4. the composition of the solid-state structure according to claim 1 containing liquid crystal, it is characterised in that: the hydroxy stearic acid is sweet
Grease is hydroxystearin monoesters, hydroxystearin diester, at least one of three ester of hydroxystearin.
5. the composition of the solid-state structure according to claim 1 containing liquid crystal, it is characterised in that: the non-ionic surface is living
Property agent in fatty acyl single ethanol amide, fatty acyl diglycollic amide, fatty acyl methyl single ethanol amide, alkyl glycosides extremely
Few one kind.
6. the composition of the solid-state structure according to claim 1 containing liquid crystal, it is characterised in that: the polysaccharide polymer packet
Include anionic polysaccharide polymers, Cationic polysaccharide polymer, nonionic polysaccharide polymer, amphoteric polysaccharide polymer, hydrophobically modified
At least one of polysaccharide polymer.
7. the composition of the solid-state structure according to claim 1 containing liquid crystal, feature is also containing one in following component
Kind is several:
Assist suspending agent: 0.01-5%；
Preservative: 0.01-1%；
Essence: 0.01-3%；
Viscosity modifier: 0.01-4%；
Chelating agent: 0.005-0.2%；
Ultraviolet absorbing agent: 0.01-2%；
Plant extracts and its derivative: 0.0001-5%.
8. a kind of cleaning class product of the composition containing the solid-state structure containing liquid crystal described in claim 1-7 any one.
9. cleaning class product according to claim 8, it is characterised in that: the cleaning class product includes washing hair product, washing one's hair
Bath product washes one's hands and uses product.
10. cleaning class product according to claim 8, which is characterized in that dosage form is solution, suspension, lotion, paste, consolidates
One of body shape.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811383697.XA CN109464297A (en) | 2018-11-20 | 2018-11-20 | A kind of composition of the solid-state structure containing liquid crystal and its application |
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| CN201811383697.XA CN109464297A (en) | 2018-11-20 | 2018-11-20 | A kind of composition of the solid-state structure containing liquid crystal and its application |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111135103A (en) * | 2020-02-17 | 2020-05-12 | 澳宝化妆品（惠州）有限公司 | Sulfate-free scalp care composition containing liquid crystal solid structure |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101039723A (en) * | 2004-10-15 | 2007-09-19 | 宝洁公司 | Personal care compositions comprising visible beads, cationic polymer, and surfactant |
| CN102186449A (en) * | 2008-08-07 | 2011-09-14 | 荷兰联合利华有限公司 | Liquid personal cleansing composition |
| CN107375035A (en) * | 2007-03-30 | 2017-11-24 | 宝洁公司 | Include the multi phase personal care composition of the structuring system containing association polymer, low hlb emulsifying agent and electrolyte |
| CN107753319A (en) * | 2017-10-27 | 2018-03-06 | 澳宝化妆品（惠州）有限公司 | A kind of hair Cleasing compositions and preparation method thereof |
-
2018
- 2018-11-20 CN CN201811383697.XA patent/CN109464297A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101039723A (en) * | 2004-10-15 | 2007-09-19 | 宝洁公司 | Personal care compositions comprising visible beads, cationic polymer, and surfactant |
| CN107375035A (en) * | 2007-03-30 | 2017-11-24 | 宝洁公司 | Include the multi phase personal care composition of the structuring system containing association polymer, low hlb emulsifying agent and electrolyte |
| CN102186449A (en) * | 2008-08-07 | 2011-09-14 | 荷兰联合利华有限公司 | Liquid personal cleansing composition |
| CN107753319A (en) * | 2017-10-27 | 2018-03-06 | 澳宝化妆品（惠州）有限公司 | A kind of hair Cleasing compositions and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111135103A (en) * | 2020-02-17 | 2020-05-12 | 澳宝化妆品（惠州）有限公司 | Sulfate-free scalp care composition containing liquid crystal solid structure |
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