CN108660760B - Warm-keeping moisture-resistant self-cleaning scarf and preparation method thereof - Google Patents
Warm-keeping moisture-resistant self-cleaning scarf and preparation method thereof Download PDFInfo
- Publication number
- CN108660760B CN108660760B CN201710213780.1A CN201710213780A CN108660760B CN 108660760 B CN108660760 B CN 108660760B CN 201710213780 A CN201710213780 A CN 201710213780A CN 108660760 B CN108660760 B CN 108660760B
- Authority
- CN
- China
- Prior art keywords
- silk
- scarf
- water
- warm
- cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/01—Stain or soil resistance
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/11—Oleophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention belongs to the technical field of textiles, and particularly relates to a warm-keeping moisture-resistant self-cleaning scarf and a preparation method thereof. The silk scarf is prepared by the hydrophobic oil-conveying antifouling paint through surface treatment of the silk scarf, or the silk scarf is prepared by the hydrophobic oil-conveying antifouling paint through treatment of raw silk. The silk scarf has strong wet-resistant and antifouling performances, cannot cause reduction of heat retention due to wetting of rain and snow in humid, rainy, snowy and other weather, and has good air permeability, antifouling and antibacterial functions, so that the silk scarf can keep dry and breathable and can keep warm retention effect and comfort in cold weather.
Description
Technical Field
The invention belongs to the field of textile application, and particularly relates to a hydrophobic and oleophobic self-cleaning warm-keeping scarf and a preparation method thereof.
Background
Along with the improvement of living standard of people, the requirements of people on wearing comfort and various functions are higher and higher, and the clothes are not only limited on the aspect of clothes shielding bodies, but also develop towards multifunction and diversification. The scarf not only can bring beautiful decorative effect to people, but also can keep warm and keep out cold. When people wear the silk towels, eat meals or drink tea, liquid such as oil stains of food or beverage is easily smeared on the silk towels, most of the oil stains are difficult to wash, and therefore the attractiveness of the silk towels on human bodies is affected, and the silk towels can only be discarded. In cold environment, the silk scarf with good heat retention property is favored, but when the people meet rainy days or weather with high humidity, the silk scarf can become damp due to moisture adsorption, so that the heat retention effect is reduced, and the wearing comfort is reduced.
Disclosure of Invention
The invention aims to overcome the defects and provides a warm-keeping moisture-resistant self-cleaning scarf and a preparation method thereof. The invention adopts the dip coating technology to carry out surface treatment on the scarves, so that the treated scarves are not stained with water and oil, generate a self-cleaning function and have good heat preservation performance and air permeability. The self-cleaning warm-keeping scarf can relieve the environmental problems caused by washing, effectively shield various environmental pollutants such as stains and the like, and prevent the pollutants from causing harm to human bodies through skins.
The technical scheme of the invention is as follows:
the utility model provides a cold-proof moisture-resistant self-cleaning scarf, its characterized in that, the scarf is prepared through silk surface treatment to the silk by hydrophobic and oleophobic antifouling coating, perhaps the scarf is prepared by hydrophobic and oleophobic antifouling coating after to raw and other materials silk processing refabrication.
Further, the hydrophobic and oleophobic antifouling paint consists of nonpolar nano powder, a silane coupling agent and a water-based low surface energy dispersing agent;
the weight percentage composition is as follows: non-polar nano powder: silane coupling agent: the water-based low surface energy dispersant = 2: 0.1-1: 3-5;
the non-polar nano powder is silicon dioxide, the silane coupling agent is siloxane or fluorosilane, and the water-based low-surface-energy dispersing agent is fluorinated polyacrylic acid surfactant.
Further, the diameter of the silicon dioxide is 150-200 nanometers.
The warm-keeping moisture-resistant self-cleaning scarf is prepared by treating the surface of a scarf with a hydrophobic and oleophobic antifouling coating, or the scarf is prepared by treating raw material silk with the hydrophobic and oleophobic antifouling coating, and the thickness of a coating is 0.1-1 mu m.
The invention relates to a warm-keeping moisture-resistant self-cleaning scarf which is prepared by treating the surface of a scarf with a hydrophobic and oleophobic antifouling coating.
The warm-keeping moisture-resistant self-cleaning silk towel is prepared by processing raw material silk with hydrophobic and oleophobic antifouling paint, and specifically comprises the steps of cleaning silk fiber, drying, performing moisture-resistant treatment, uniformly processing the paint on the silk fiber by adopting dipping, plasma and vapor deposition, wherein the processed silk fiber has a good moisture-resistant effect.
The invention also provides a preparation method of the warm-keeping moisture-resistant self-cleaning scarf,
treating the surface of the scarves fabric needing self-cleaning treatment, soaking the scarves fabric in an ethanol-water solution (preferably, the water content is less than 5 percent, and the temperature is room temperature), washing the scarves fabric with water, and drying the scarves fabric; preparing a hydrophobic and oleophobic antifouling paint by using water: mixing 0.5-3.0% of nonpolar powder silicon dioxide, 0.2-2% of fluorosilane and 3211-10% of water-based dispersant Zonyl according to mass percent, adding water, and stirring to obtain the stable hydrophobic and oleophobic antifouling paint;
immersing the scarves in the hydrophobic and oleophobic antifouling paint for 0.5-1 min (room temperature), taking out, removing excessive solution, and placing in an oven 100oAnd C, drying for 10 minutes to obtain the warm-keeping moisture-resistant self-cleaning scarf.
The invention also provides a preparation method of the warm-keeping moisture-resistant self-cleaning scarf,
firstly, silk is treated, the surface of the silk is treated, the silk is soaked in an ethanol-water solution (preferably, the water content is less than 5 percent, and the room temperature is selected), then the silk is washed by water, and then the silk is dried;
preparing a hydrophobic and oleophobic antifouling paint by using water: mixing fluorosilane or siloxane with a water-based dispersing agent according to the mass ratio of 1:3, adding water, and stirring to obtain a stable hydrophobic and oleophobic antifouling paint, wherein the mass percent of the solution is 1-10% wt/v; soaking silk in the coating for about 0.5-1 min (room temperature), placing in an oven 60oC-100oC, drying, wherein the treated silk has good hydrophobic, oleophobic and antifouling effects; different weaving methods can be used for preparing the finished product of the warm-keeping moisture-resistant self-cleaning scarf according to the requirements.
Detailed description of the invention:
a water-based coating solution comprises nonpolar nano powder, a silane coupling agent and a water-based low-surface-energy dispersing agent, the silk towel is subjected to dip coating and drying treatment, the treated silk towel has good hydrophobic and oleophobic effects, and the silk towel can keep the original air permeability by controlling the thickness of the coating. In addition, due to the low heat-conducting property of the hydrophobic and oleophobic coating material on the surface of the scarf, the scarf can keep a good warm-keeping effect.
The purpose of the invention is realized as follows: a wet-resistant, antifouling and warm-keeping scarf is characterized in that a silane coupling agent with hydrophobic and oleophobic effects, such as siloxane or fluorosilane, is treated on the surface of each fiber in the scarf by using a plasma technology, and the scarf after drying treatment has good wet-resistant and antifouling effects.
The purpose of the invention is realized as follows: a wet-resistant antifouling warm-keeping scarf is characterized in that a coating is uniformly treated on the surface of the scarf by a vapor deposition method, and the dried scarf has good wet-resistant antifouling effects. But also can keep the original performance of the scarves. Such as color ventilation, hand feel, etc.
The purpose of the invention is realized as follows: a wet-proof, anti-fouling and warm-keeping scarf is realized by a method of firstly processing silk. And (3) treating the cleaned silk to obtain the silk fiber with moisture resistance and antifouling effects. The treatment method can adopt immersion method, plasma, vapor deposition and other methods. The treated silk can keep the original silk fiber performance. The treated silk is post-processed into a silk towel finished product, so that the silk towel has good moisture resistance, antifouling and warm keeping performances.
The moisture-resistant, breathable and self-cleaning warm-keeping scarf disclosed by the invention has good moisture-resistant and antifouling performances, and can firmly lock an air layer between internal fibers under a wet state due to no moisture absorption, so that the scarf has a good warm-keeping effect. The silk scarf has good moisture resistance, so that the silk scarf has good antifouling capacity and can resist contamination of milk, coffee, beverages and the like, thereby reducing daily washing times and prolonging the service life of the silk scarf.
The processing method adopted by the moisture-resistant breathable self-cleaning warm-keeping scarf does not influence the appearance and the original performance of the scarf, such as color, breathability, comfort, hand feeling and the like.
The moisture-resistant, breathable, self-cleaning and warm-keeping scarf is prepared by performing surface treatment on a hydrophobic and oleophobic material. Various methods of preparation may be employed such as water-based coatings, plasma, vapor deposition, and the like.
The treatment process of the moisture-resistant, breathable, self-cleaning and warm-keeping scarf comprises an after-finishing technology, namely treating the finished scarf fabric. The water-based hydrophobic and oil-conveying paint can be uniformly coated on the whole fabric by using a dipping or spraying technology, and other treatment technologies such as plasma and vapor deposition can also uniformly treat the paint on each fiber in the silk scarf, so that the treated silk scarf has a good moisture resistance effect.
The treatment process of the anti-wet breathable self-cleaning warm-keeping scarf comprises a treatment process and also can comprise the step of treating silk fibers firstly. And (3) cleaning the silk fiber, and drying and then carrying out moisture resistance treatment. The treatment method may employ dipping, plasma, vapor deposition, or the like. The treated silk fiber has good moisture resistance. The scarf processed by the moisture-resistant silk fiber has good moisture-resistant effect.
The treatment process of the moisture-resistant, breathable, self-cleaning and warm-keeping scarf comprises the step of treating the whole three-dimensional structure, so that the whole scarf presents good water and oil delivery performance from inside to outside.
The wet-resistant, breathable, self-cleaning and warm-keeping scarf disclosed by the invention has good durability due to the strong adhesion between the coating and the base material. The hydrophobic, oil-transfer and stain-resistant properties of the washed scarves remained unchanged after 50-200 wash tests according to AATCC standard. After the treated fabric is subjected to 1000 times of wear resistance tests according to the DMTC standard, the worn scarves still have good hydrophobic, oil-conveying and antifouling properties.
The whole three-dimensional structure of the moisture-resistant breathable self-cleaning warm-keeping scarf is treated, and finally each fiber in the scarf fabric has a uniform coating, so that the whole scarf has good moisture-resistant and antifouling performance from inside to outside. Under the wet state, the fibers can firmly lock the air layer between the internal fibers because the fibers do not absorb moisture, so that the scarf has a good warm-keeping effect.
The preparation of the warm-keeping moisture-resistant self-cleaning scarf is a nontoxic and environment-friendly preparation process, and only water is used as a solvent in the whole treatment process, so that an organic solvent is not used at all. The preparation method has no environmental pollution and can save cost.
The invention has the beneficial effects that: the hydrophobic and oleophobic self-cleaning warm-keeping scarf disclosed by the invention is simple in treatment method, the treated scarf has good water and oil transportation performance from inside to outside, has good self-cleaning and warm-keeping effects, has a good moisture-resistant effect and good air permeability, and the functionality and the service life of the scarf are improved.
FIG. 1 is a coating treatment flow chart of the hydrophobic and oleophobic self-cleaning warm-keeping silk scarf fabric, and a silk scarf finished product is treated.
Drawings
FIG. 2 is a coating treatment flow chart of the hydrophobic and oleophobic self-cleaning warm-keeping silk scarf fabric, and the silk treatment method is firstly adopted.
FIG. 3 shows the hydrophobic and oleophobic properties of the silk scarf fabric after and after treatment, wherein yellow is water, transparent is paraffin oil, red is edible olive oil, blue is hexadecane, and the size of each liquid drop is 5-20 μ L.
Fig. 4 shows the change in air permeability of the scarves before and after treatment, with little change in air permeability of the scarves after treatment.
Fig. 5 is a graph of the change in contact angle to water and olive oil after 200 washes of a scarf treated with the invention.
Fig. 6 is a graph of the change in contact angle against water and olive oil after 2000 abrasions of a scarf treated with the invention.
Detailed Description
The present invention will be further illustrated by the following detailed description, with the preferred embodiment being example 2, but the invention is not limited to these embodiments. For a brief description of the various embodiments, reference is made to FIG. 1.
Example 1
The surface of the silk scarf fabric needing self-cleaning treatment is treated, the silk scarf fabric is soaked in an ethanol solution for 10 minutes, then the silk scarf fabric is washed by water to remove dust, grease and impurities on the surface, and then the silk scarf fabric is dried to ensure that the surface of the silk scarf fabric is clean and dry.
The invention adopts water as solvent to keep the original self-cleaning effect.
The preparation method of the hydrophobic and oleophobic antifouling paint comprises the following steps: 2 g of nonpolar components (silicon dioxide, the diameter of which is about 150-200 nm), 0.5-1 g of fluorosilane and a water-based dispersant (Zonyl 321 fluorinated polyacrylic acid surfactant) are mixed, 100 ml of water is added, and the mixture is stirred to obtain the stable hydrophobic and oleophobic coating.
The scarves are soaked in the coating for about 30 seconds to 1 minute, taken out, the excess solution is removed, and the scarves are placed in an oven to be dried for 10 minutes at 100 ℃. The surface of the treated scarf has good hydrophobic, oleophobic and antifouling effects, and the durability of the coating is very good and can withstand more than 100 times of repeated washing.
Example 2
Firstly, silk is treated, the surface of the silk which needs to be subjected to moisture-resistant and self-cleaning treatment is treated, the silk is soaked in an ethanol solution for half an hour, then the silk is washed by water, surface dust, grease and impurities are removed, and the silk is dried to ensure that each silk fiber is clean and dry.
The hydrophobic and oleophobic antifouling paint is prepared by adopting water as a solvent, and the preparation method comprises the following steps: mixing fluorosilane or siloxane with water-based dispersant, adding water, and stirring to obtain the stable hydrophobic and oleophobic coating. The final mass percent of the solution is controlled to be 1-5% (wt/v). Soaking silk in the coating for about 30 seconds to 1 minute, taking out, removing the redundant solution, and drying at 60-100 deg.C in an oven. The treated silk has good hydrophobic and oleophobic antifouling effect. And then the final scarf finished product can be manufactured by different weaving methods according to requirements. Due to the strong adhesion between the coating and the silk scarf fiber base material, the processing effect of the silk cannot be influenced in the weaving process. The prepared silk towel finished product has good durability, can endure repeated washing for more than 100 times, or can still keep the original self-cleaning effect after 2000 times of repeated abrasion.
The above description is only exemplary of the present invention and should not be taken as limiting the invention, as any modifications, equivalents, improvements and the like within the spirit and principle of the present invention should be included in the scope of the present invention.
Claims (3)
1. The warm-keeping moisture-resistant self-cleaning silk scarf is characterized in that the silk scarf is prepared by processing raw material silk with hydrophobic, oleophobic and antifouling paint;
the hydrophobic and oleophobic antifouling paint consists of a silane coupling agent and a water-based low-surface-energy dispersing agent in a mass ratio of 1: 3;
the silane coupling agent is siloxane or fluorosilane, and the water-based low-surface-energy dispersing agent is Zonyl321 fluorinated polyacrylic acid surfactant;
the silk scarf is formed by hydrophobic oleophobic antifouling coating through the refabrication after handling raw and other materials silk, specifically does, with silk fibre sanitization, carries out anti wet-processing after the stoving, and the processing mode is for adopting the flooding will coating even processing is on the fibre of silk, and the silk fibre after the processing has fine anti wet effect.
2. A method for preparing the warm-keeping moisture-resistant self-cleaning scarf according to claim 1,
firstly, silk is treated, the surface of the silk is treated, the silk is soaked in an ethanol-water solution and then washed by water, and then the silk is dried;
preparing a hydrophobic and oleophobic antifouling paint by using water: mixing fluorosilane or siloxane with a water-based low-surface-energy dispersing agent according to the mass ratio of 1:3, adding water, and stirring to obtain a stable hydrophobic and oleophobic antifouling paint, wherein the mass percent of the prepared paint is 1-10% wt/v; soaking silk in the coating for 0.5-1 min, and placing in oven 60oC-100oC, drying, wherein the treated silk has good hydrophobic, oleophobic and antifouling effects; different weaving methods can be used for preparing the finished product of the warm-keeping moisture-resistant self-cleaning scarf according to the requirements.
3. The method for preparing the warm-keeping moisture-resistant self-cleaning scarf according to claim 2, characterized in that the ethanol-water solution has a water content of less than 5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710213780.1A CN108660760B (en) | 2017-04-01 | 2017-04-01 | Warm-keeping moisture-resistant self-cleaning scarf and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710213780.1A CN108660760B (en) | 2017-04-01 | 2017-04-01 | Warm-keeping moisture-resistant self-cleaning scarf and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108660760A CN108660760A (en) | 2018-10-16 |
| CN108660760B true CN108660760B (en) | 2020-10-20 |
Family
ID=63784679
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710213780.1A Active CN108660760B (en) | 2017-04-01 | 2017-04-01 | Warm-keeping moisture-resistant self-cleaning scarf and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108660760B (en) |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS584873A (en) * | 1981-06-30 | 1983-01-12 | カネボウ株式会社 | Processing of fiber structure |
| WO1997048774A1 (en) * | 1996-06-19 | 1997-12-24 | Daikin Industries, Ltd. | Coating composition, coating film, and process for the production of the film |
| TW494125B (en) * | 1997-07-11 | 2002-07-11 | Rohm And Haas Compary | Preparation of fluorinated polymers |
| US6979711B2 (en) * | 2003-11-18 | 2005-12-27 | E. I. Du Pont De Nemours And Company | Fluorine efficient finishes for textiles |
| DE102004002499A1 (en) * | 2004-01-17 | 2005-08-11 | Degussa Ag | Method for preventing start-up effects in the impregnation of substrates |
| CN1277019C (en) * | 2004-03-17 | 2006-09-27 | 韦钧千 | Nano self cleaning silk broadcloth and products |
| CN101018903B (en) * | 2004-07-20 | 2011-02-16 | 舍勒纺织股份公司 | Finishings for textile fibres and fabrics to give hydrophobic oleophobic and self-cleaning surfaces |
| AU2014203168B2 (en) * | 2007-05-18 | 2016-04-21 | Invista Technologies S.A R.L. | Method and composition for treating fibrous substrates |
| CN101161916A (en) * | 2007-10-09 | 2008-04-16 | 北京首创纳米科技有限公司 | Nano protective liquid for weaving and preparation method thereof |
| US9364859B2 (en) * | 2011-07-28 | 2016-06-14 | Kimberly-Clark Worldwide, Inc. | Superhydrophobic surfaces |
-
2017
- 2017-04-01 CN CN201710213780.1A patent/CN108660760B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN108660760A (en) | 2018-10-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100334291C (en) | Production of feather dress fabric with self-cleaning function | |
| Mahltig et al. | Functionalisation of textiles by inorganic sol–gel coatings | |
| CN101250597B (en) | Preparation method of nano self-cleaning leather or product | |
| CN105623326B (en) | A kind of nanometer oyster shell whiting ecological functions bullet applies coating | |
| CN101161916A (en) | Nano protective liquid for weaving and preparation method thereof | |
| CN105603724B (en) | The method for sorting of easy to operate high-performance three proofings antibiotic facing material | |
| CN111270514B (en) | Preparation method of stable superhydrophobic antibacterial cotton fabric based on glutaraldehyde crosslinking | |
| CN109322144A (en) | A kind of durability super-hydrophobic textile finishing agent and its method for sorting | |
| CN111485422A (en) | Anti-mite antibacterial finishing agent and finishing method and application thereof | |
| Lv et al. | Robust, infrared-reflective, superhydrophobic and breathable coatings on polyester fabrics | |
| CN111534650B (en) | Durable antibacterial soft leather for leather bags and preparation method thereof | |
| CN106182241A (en) | A kind of wicker for braiding does old antique imitation process | |
| CN108660760B (en) | Warm-keeping moisture-resistant self-cleaning scarf and preparation method thereof | |
| CN101250596A (en) | Preparation method of self-cleaning leather or product containing nano functional material | |
| CN109440443B (en) | Preparation method of super-hydrophobic fabric | |
| CN106192420B (en) | The production method and ZnO nano material fabric of ZnO nano material fabric | |
| CN106217556A (en) | Low temperature resistant, the damp-proof treatment agent of a kind of wicker plaiting article rattan | |
| JP5506265B2 (en) | Textile treatment agent, antibacterial and antifungal fiber product manufacturing method | |
| CN203807860U (en) | Waterproof and moisture permeable grid printed fabric | |
| CN110055359A (en) | A kind of anti-mite cow leather mat of mosquito repellent and its production method | |
| CN110592959B (en) | Self-cleaning textile material for automotive interior and preparation method thereof | |
| CN104588299B (en) | Diamond is bright to dodge effect spraying coating process | |
| CN108184822A (en) | A kind of working fluid that can retain camellia Fresh Cutting flower natural primary color and its application | |
| CN110004703B (en) | Preparation method of multifunctional colored real silk or wool fabric | |
| CN114438787B (en) | Dustproof, hydrophobic and color-retaining microporous coating for fabric and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |