CN108560149A - A kind of processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics - Google Patents

A kind of processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics Download PDF

Info

Publication number
CN108560149A
CN108560149A CN201810258619.0A CN201810258619A CN108560149A CN 108560149 A CN108560149 A CN 108560149A CN 201810258619 A CN201810258619 A CN 201810258619A CN 108560149 A CN108560149 A CN 108560149A
Authority
CN
China
Prior art keywords
woven fabrics
polypropylene
spunbond non
polypropylene spunbond
processing technology
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810258619.0A
Other languages
Chinese (zh)
Inventor
关义臣
关建
李鹏
卢辉辉
刘晨阳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jieshou City Shengtong Nonwovens Co Ltd
Original Assignee
Jieshou City Shengtong Nonwovens Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jieshou City Shengtong Nonwovens Co Ltd filed Critical Jieshou City Shengtong Nonwovens Co Ltd
Priority to CN201810258619.0A priority Critical patent/CN108560149A/en
Publication of CN108560149A publication Critical patent/CN108560149A/en
Pending legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/007Addition polymers
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/14Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic System; Zincates; Cadmates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/18Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/20Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups

Abstract

The invention discloses a kind of processing technologys of high-performance antibiosis polypropylene spunbond non-woven fabrics, are related to non-woven fabrics processing technique field, including following operating procedure:(1) preparation of carboxyted polypropylene, (2) are polyacrylic antibacterial modified, the processing of (3) web, (4) nonwoven molding with cloth.The made polypropylene spunbond non-woven fabrics of the present invention not only has significant anti-microbial property, while anti-microbial property is stablized, and antibacterial timeliness is long;And the mechanical strength of made polypropylene spunbond non-woven fabrics is high, and good permeability is non-toxic to humans, suitable for being processed into operation clothing, sheet, diaper, isolation clothes, visiting the medical and hygiene articles such as clothes.

Description

A kind of processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics
Technical field:
The present invention relates to non-woven fabrics processing technique fields, and in particular to a kind of high-performance antibiosis polypropylene spunbond non-woven fabrics adds Work technique.
Background technology:
Polypropylene spunbond non-woven fabrics is one kind of non-woven fabrics, be with polypropylene is raw material, polymerize networking by high temperature wire drawing, Then reusable heat rolls the one kind of method bonding at cloth.It is wide at present since technological process is simple, yield is big, non-toxic to humans The various fields such as general application hygienic material.
Since polypropylene spunbond non-woven fabrics is chiefly used in the processing of hygienic material, in order to improve the safety in utilization of hygienic material, Need polypropylene spunbond non-woven fabrics that there is anti-microbial property.But rapidoprint polypropylene of polypropylene spunbond non-woven fabrics itself does not have anti- Bacterium acts on, thus antibacterial polypropylene spunbond non-woven fabrics currently on the market largely using chemical mode, photocatalyst or nano silver from Subprocessing technology carries out antibacterial processing, but deficiency is individually present:Though chemical mode can antibacterial, most of chemicals itself is easy Human body is damaged;Though photocatalyst is safe and effective, cost is higher;Though nano silver has bacteriostasis, antibacterial ability weaker.
Invention content:
Technical problem to be solved by the present invention lies in provide one kind to be conducive to improve non-woven fabrics safety in utilization and antibacterial The processing technology for the high-performance antibiosis polypropylene spunbond non-woven fabrics that significant effect, anti-microbial property are stablized.
The technical problems to be solved by the invention are realized using technical solution below:
A kind of processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics, including following operating procedure:
(1) preparation of carboxyted polypropylene:Polypropylene powder and nitric acid are sufficiently mixed, 130 DEG C of heat preservations is again heated to and stirs Reaction is mixed, after reaction by gained mixture cooled to room temperature, and nitric acid is removed through washing, finally vacuum dried, Powder is made to get carboxyted polypropylene in crushing;
(2) polyacrylic antibacterial modified:Chitosan hydrochloride is dissolved in water, made carboxyted polypropylene is added, fills Divide stirring, and dilute sulfuric acid is added dropwise and adjusts pH value to 5, the reaction of reflux state insulated and stirred is again heated to, after reaction by gained Then mixture cooled to room temperature is added dropwise inorganic alkali solution and adjusts pH value to 7, filtering, water-washing desalting is most done through vacuum afterwards Particle is made to get chitin modified polypropylene in dry, crushing;
(3) processing of web:Made chitin modified PP GRANULES is added in screw extruder and is melted, then through spray Silk networking is to get web;
(4) nonwoven molding with cloth:By made web it is hot rolled at cloth to get antibacterial polypropylene spunbond non-woven fabrics.
The mass fraction of nitric acid is 65-70% in the step (1), and the mass ratio of polypropylene powder and nitric acid is 15-30: 1-10。
Chitosan hydrochloride in the step (2), carboxyted polypropylene mass ratio be 5-10:35-50.
In the step (2) inorganic base in sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate one Kind.
The made web of the step (3) has also carried out at secondary antibacterial before entering step (4) non-woven fabrics processing and forming Reason.
The concrete operations of the secondary antimicrobial treatment are:Web is preheated to 125-130 DEG C, and uniformly on web Secondary antimicrobial treatment solution is sprayed, the amount of spraying is 30-50g/m2, it is then transferred to standing 3-5h, 55- in 105-110 DEG C of environment successively It is stood in 2-3h, 5-10 DEG C of environment in 60 DEG C of environment and stands 3-5h.
The secondary antimicrobial treatment solution is made of carrier nano magnesia and Chinese medicine antibacterial extracting solution, and preparation method is: 20g nano magnesias are added in 1kg Chinese medicine antibacterial extracting solutions, 15-30min is stood after being sufficiently stirred, recycle microwave reaction Device microwave return stirring 5min continues microwave return stirring 5min after stopping 5min, stops microwave return stirring again after 5min 5min so repeats, so that microwave return stirring total time is reached 30min, cooled to room temperature is to get secondary antimicrobial treatment Liquid.
The average grain diameter of the nano magnesia is 50nm.
The Chinese medicine antibacterial extracting solution is made of Chinese medicine composition through water extraction, and preparation method is:By 30g the bark of the root or stem of the tree of heaven, 20g Verbena officinalis, 15g Kadsura Root-barks, 15g Siberian elm brak, 10g gold boiling grass, 5g Mongollian Thyme Herbs, 5g berberis poiretiis, 5g Ranunculus sceleratus, 3g Blumea balsamiferas, 2g potentilla chinensis, 0.5g styraxes are added in the water of 5 times of Chinese medicine gross weights, and reflux state insulated and stirred 3h, mistake are heated to after impregnating 12h Filtrate is collected in filter, filter residue is added in the water of 3 times of Chinese medicine gross weights, is again heated to reflux state insulated and stirred 2h, is filtered, and is closed And filtrate is to get Chinese medicine antibacterial extracting solution.
The beneficial effects of the invention are as follows:
(1) present invention introduces carboxyl using nitric acid to polypropylene molecule structure end carboxylated, recycles chitosan Institute's hydroxyl and amino are reacted with amide condensed to be introduced on polypropylene with carboxyl generation esterification respectively in molecular structure Chitosan, to assign polypropylene antibacterial performance using the antibacterial characteristics of chitosan;
(2) present invention is born when prepared by secondary antimicrobial treatment solution using nano magnesia as carrier using its absorption property Chinese medicine antibacterial ingredient is carried, to introduce natural antibacterial ingredient on made non-woven fabrics, to strengthen the anti-microbial property of made non-woven fabrics;
(3) formula of Chinese medicine antibacterial extracting solution preparation Chinese medicine composition used of the present invention follows strictly the compatibility of monarch Relationship, using pathogenic bacteria as controlling object, antimicrobial component directly acts on pathogenic bacteria, to show good anti-microbial property; And the formula of the Chinese medicine composition is obtained by experiment sieving many times, wherein the addition and its dosage per a herb are all By verifying repeatedly, to be the identical or close similar Chinese medicine of pharmacological property can not replace easily;
(4) nano magnesia of the present invention itself has antibacterial action, and because free hydroxyl is contained on its surface after as carrier Base thus can with esterification or amidated carboxyl reacts to Chinese medicine antibacterial ingredient is firmly attached to poly- completely on polypropylene On tacryl, and then significantly improve the anti-microbial property of made non-woven fabrics;
(5) the made polypropylene spunbond non-woven fabrics of the present invention not only has significant anti-microbial property, while anti-microbial property is stablized, and resists Bacterium timeliness is long;And the mechanical strength of made polypropylene spunbond non-woven fabrics is high, and good permeability is non-toxic to humans, is suitable for adding Work is made operation clothing, sheet, diaper, isolation clothes, visits the medical and hygiene articles such as clothes.
Specific implementation mode:
In order to make the technical means, the creative features, the aims and the efficiencies achieved by the present invention be easy to understand, tie below Specific embodiment is closed, the present invention is further explained.
Embodiment 1
(1) preparation of carboxyted polypropylene:The nitric acid of 15g polypropylene powders and 5g mass fractions 70% is sufficiently mixed, 130 DEG C of insulated and stirred reactions are again heated to, after reaction by gained mixture cooled to room temperature, and nitre are removed through washing Powder is made to get carboxyted polypropylene in acid, last vacuum dried, crushing;
(2) polyacrylic antibacterial modified:5g chitosan hydrochlorides are dissolved in water, the made carboxylated of 35g poly- third is added Alkene is sufficiently stirred, and dilute sulfuric acid is added dropwise and adjusts pH value to 5, is again heated to the reaction of reflux state insulated and stirred, after reaction will Then gained mixture cooled to room temperature is added dropwise sodium carbonate liquor and adjusts pH value to 7, filtering, water-washing desalting most passes through true afterwards Sky is dry, particle is made to get chitin modified polypropylene in crushing;
(3) processing of web:Made chitin modified PP GRANULES is added in screw extruder and is melted, then through spray Silk networking is to get web;
(4) nonwoven molding with cloth:By made web it is hot rolled at cloth to get antibacterial polypropylene spunbond non-woven fabrics.
Embodiment 2
(1) preparation of carboxyted polypropylene:The nitric acid of 20g polypropylene powders and 5g mass fractions 70% is sufficiently mixed, 130 DEG C of insulated and stirred reactions are again heated to, after reaction by gained mixture cooled to room temperature, and nitre are removed through washing Powder is made to get carboxyted polypropylene in acid, last vacuum dried, crushing;
(2) polyacrylic antibacterial modified:8g chitosan hydrochlorides are dissolved in water, the made carboxylated of 50g poly- third is added Alkene is sufficiently stirred, and dilute sulfuric acid is added dropwise and adjusts pH value to 5, is again heated to the reaction of reflux state insulated and stirred, after reaction will Then gained mixture cooled to room temperature is added dropwise sodium carbonate liquor and adjusts pH value to 7, filtering, water-washing desalting most passes through true afterwards Sky is dry, particle is made to get chitin modified polypropylene in crushing;
(3) processing of web:Made chitin modified PP GRANULES is added in screw extruder and is melted, then through spray Silk networking is to get web;
(4) nonwoven molding with cloth:By made web it is hot rolled at cloth to get antibacterial polypropylene spunbond non-woven fabrics.
Embodiment 3
(1) preparation of carboxyted polypropylene:The nitric acid of 20g polypropylene powders and 5g mass fractions 70% is sufficiently mixed, 130 DEG C of insulated and stirred reactions are again heated to, after reaction by gained mixture cooled to room temperature, and nitre are removed through washing Powder is made to get carboxyted polypropylene in acid, last vacuum dried, crushing;
(2) polyacrylic antibacterial modified:8g chitosan hydrochlorides are dissolved in water, the made carboxylated of 50g poly- third is added Alkene is sufficiently stirred, and dilute sulfuric acid is added dropwise and adjusts pH value to 5, is again heated to the reaction of reflux state insulated and stirred, after reaction will Then gained mixture cooled to room temperature is added dropwise sodium carbonate liquor and adjusts pH value to 7, filtering, water-washing desalting most passes through true afterwards Sky is dry, particle is made to get chitin modified polypropylene in crushing;
(3) processing of web:Made chitin modified PP GRANULES is added in screw extruder and is melted, then through spray Silk networking is to get web;
(4) secondary antimicrobial treatment:Web is preheated to 125-130 DEG C, and uniformly sprays secondary antibacterial on web Treatment fluid, the amount of spraying are 50g/m2, then it is transferred to successively in 105-110 DEG C of environment and stands 2- in 3-5h, 55-60 DEG C of environment of standing 3-5h is stood in 3h, 5-10 DEG C of environment;
(5) nonwoven molding with cloth:By the web after secondary antimicrobial treatment it is hot rolled at cloth to get antibacterial polypropylene spunbond nonwoven Cloth.
The preparation of secondary antimicrobial treatment solution:The extraction of 1kg Chinese medicine antibacterials is added in the nano magnesia of 20g average grain diameters 50nm In liquid, 30min is stood after being sufficiently stirred, recycles microwave reactor microwave return stirring 5min, continues microwave after stopping 5min Microwave return stirring 5min, such repetition make microwave return stirring total time reach again after return stirring 5min, stopping 5min 30min, cooled to room temperature is to get secondary antimicrobial treatment solution.
The preparation of Chinese medicine antibacterial extracting solution:By 30g the bark of the root or stem of the tree of heaven, 20g Verbena officinalis, 15g Kadsura Root-barks, 15g Siberian elm brak, 10g gold Boil grass, 5g Mongollian Thyme Herbs, 5g berberis poiretiis, 5g Ranunculus sceleratus, 3g Blumea balsamiferas, 2g potentilla chinensis, 0.5g styraxes 5 times of Chinese medicine gross weights of addition In water, it is heated to reflux state insulated and stirred 3h after impregnating 12h, is filtered, filtrate is collected, by filter residue 3 times of Chinese medicine gross weights of addition In water, it is again heated to reflux state insulated and stirred 2h, is filtered, merging filtrate is to get Chinese medicine antibacterial extracting solution.
Reference examples
With reference to patent CN201410077137.7 embodiments 1.
Embodiment 4
Be utilized respectively embodiment 1-3 processing and prepare antibacterial polypropylene spunbond non-woven fabrics, wherein screw extruder melting, spinneret at Net, the process condition for being rolled into cloth are identical, and test the anti-microbial property (dialogue of made antibacterial polypropylene spunbond non-woven fabrics The 1h sterilizing rates of color candida albicans, staphylococcus aureus, Escherichia coli), test result is as shown in table 1.
The anti-microbial property of the 1 made antibacterial polypropylene spunbond non-woven fabrics of the present invention of table
Strain name Embodiment 1 Embodiment 2 Embodiment 3 Reference examples
Candida albicans 95-98% 95-98% > 99.9% < 90%
Staphylococcus aureus 95-98% 95-98% > 99.9% < 90%
Escherichia coli 95-98% 95-98% > 99.9% < 90%
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (9)

1. a kind of processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics, which is characterized in that including following operating procedure:
(1) preparation of carboxyted polypropylene:Polypropylene powder and nitric acid are sufficiently mixed, it is anti-to be again heated to 130 DEG C of insulated and stirreds It answers, after reaction by gained mixture cooled to room temperature, and nitric acid, last vacuum dried, crushing is removed through washing Powder is made to get carboxyted polypropylene;
(2) polyacrylic antibacterial modified:Chitosan hydrochloride is dissolved in water, made carboxyted polypropylene is added, fully stirs It mixes, and dilute sulfuric acid is added dropwise and adjusts pH value to 5, be again heated to the reaction of reflux state insulated and stirred, after reaction mix gained Then object cooled to room temperature is added dropwise inorganic alkali solution and adjusts pH value to 7, filters, water-washing desalting, finally vacuum dried, Particle is made to get chitin modified polypropylene in crushing;
(3) processing of web:Made chitin modified PP GRANULES is added in screw extruder and is melted, then through spinneret at Net is to get web;
(4) nonwoven molding with cloth:By made web it is hot rolled at cloth to get antibacterial polypropylene spunbond non-woven fabrics.
2. the processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics according to claim 1, it is characterised in that:The step Suddenly the mass fraction of nitric acid is 65-70% in (1), and the mass ratio of polypropylene powder and nitric acid is 15-30:1-10.
3. the processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics according to claim 1, it is characterised in that:The step Suddenly chitosan hydrochloride in (2), carboxyted polypropylene mass ratio be 5-10:35-50.
4. the processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics according to claim 1, it is characterised in that:The step Suddenly the one kind of inorganic base in sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate in (2).
5. the processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics according to claim 1, it is characterised in that:The step Suddenly (3) made web has also carried out secondary antimicrobial treatment before entering step (4) non-woven fabrics processing and forming.
6. the processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics according to claim 5, which is characterized in that described two The concrete operations of secondary antimicrobial treatment are:Web is preheated to 125-130 DEG C, and is uniformly sprayed at secondary antibacterial on web Liquid is managed, the amount of spraying is 30-50g/m2, then it is transferred in 105-110 DEG C of environment and is stood in 3-5h, 55-60 DEG C of environment of standing successively 3-5h is stood in 2-3h, 5-10 DEG C of environment.
7. the processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics according to claim 6, it is characterised in that:Described two Secondary antimicrobial treatment solution is made of carrier nano magnesia and Chinese medicine antibacterial extracting solution, and preparation method is:By 20g nano magnesias It is added in 1kg Chinese medicine antibacterial extracting solutions, 15-30min is stood after being sufficiently stirred, recycle microwave reactor microwave return stirring 5min continues microwave return stirring 5min after stopping 5min, stops microwave return stirring 5min again after 5min, so repeats, Microwave return stirring total time is set to reach 30min, cooled to room temperature is to get secondary antimicrobial treatment solution.
8. the processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics according to claim 7, it is characterised in that:It is described to receive The average grain diameter of rice magnesia is 50nm.
9. the processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics according to claim 7, it is characterised in that:In described Medicine antibacterial extracting solution is made of Chinese medicine composition through water extraction, and preparation method is:30g the bark of the root or stem of the tree of heaven, 20g Verbena officinalis, 15g is purple Chaste tree skin, 15g Siberian elm brak, 10g gold boiling grass, 5g Mongollian Thyme Herbs, 5g berberis poiretiis, 5g Ranunculus sceleratus, 3g Blumea balsamiferas, 2g potentilla chinensis, 0.5g peaces Breath is fragrant to be added in the water of 5 times of Chinese medicine gross weights, is heated to reflux state insulated and stirred 3h after impregnating 12h, is filtered, collects filtrate, will Filter residue is added in the water of 3 times of Chinese medicine gross weights, is again heated to reflux state insulated and stirred 2h, filters, merging filtrate is to get Chinese medicine Antibacterial extracting solution.
CN201810258619.0A 2018-03-27 2018-03-27 A kind of processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics Pending CN108560149A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810258619.0A CN108560149A (en) 2018-03-27 2018-03-27 A kind of processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810258619.0A CN108560149A (en) 2018-03-27 2018-03-27 A kind of processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics

Publications (1)

Publication Number Publication Date
CN108560149A true CN108560149A (en) 2018-09-21

Family

ID=63533490

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810258619.0A Pending CN108560149A (en) 2018-03-27 2018-03-27 A kind of processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics

Country Status (1)

Country Link
CN (1) CN108560149A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109594196A (en) * 2018-11-07 2019-04-09 桐城市鸿江包装有限公司 The preparation method of antimicrobial form wall paper non-woven fabrics
CN110592808A (en) * 2019-09-02 2019-12-20 中科纺织研究院(青岛)有限公司 Alga modified PP spunbonded non-woven fabric
CN110894642A (en) * 2019-12-16 2020-03-20 中科纺织研究院(青岛)有限公司 Chitin modified PP spunbonded non-woven fabric
CN112376167A (en) * 2020-10-22 2021-02-19 江阴市中兴无纺布有限公司 Low-impedance electrostatic functional non-woven fabric and production process thereof
EP3786329A1 (en) 2019-09-02 2021-03-03 Bestee Material (Tsingtao) Co., Ltd. Plant-based functional polypropylene spunbond non-woven fabric and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04272273A (en) * 1991-02-26 1992-09-29 Unitika Ltd Antimicrobial, antifungal and deodorizing nonwoven fabric having hydrophilicity
CN101057874A (en) * 2006-04-18 2007-10-24 北京未名宝生物科技有限公司 Method for comprehensively producing and utilizing nanometer biological active material
CN101138648A (en) * 2006-09-07 2008-03-12 电子科技大学中山学院 Method of preparing antimicrobial hemostasis Chinese medicine-containing biological dressings
PL393698A1 (en) * 2011-01-20 2012-07-30 Instytut Włókiennictwa Composite nonwoven cloth for air filtration with antimicrobial properties and method for manufacturing the composite nonwoven cloth for air filtration with antimicrobial properties
CN107011488A (en) * 2017-05-16 2017-08-04 马嘉 A kind of preparation and application of NEW TYPE OF COMPOSITE antiseptic and its master batch
CN107099934A (en) * 2017-05-09 2017-08-29 南昌萃诗贸易有限公司 A kind of facial mask special non-woven fabric
CN107447279A (en) * 2016-05-30 2017-12-08 上海九意日用品有限公司 A kind of long-acting biological antibacterial nonwoven cloth and preparation method thereof
CN107744189A (en) * 2017-10-17 2018-03-02 钟婷婷 A kind of Traditional Chinese medicine bacteriostatic mouth mask and preparation method

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04272273A (en) * 1991-02-26 1992-09-29 Unitika Ltd Antimicrobial, antifungal and deodorizing nonwoven fabric having hydrophilicity
CN101057874A (en) * 2006-04-18 2007-10-24 北京未名宝生物科技有限公司 Method for comprehensively producing and utilizing nanometer biological active material
CN101138648A (en) * 2006-09-07 2008-03-12 电子科技大学中山学院 Method of preparing antimicrobial hemostasis Chinese medicine-containing biological dressings
PL393698A1 (en) * 2011-01-20 2012-07-30 Instytut Włókiennictwa Composite nonwoven cloth for air filtration with antimicrobial properties and method for manufacturing the composite nonwoven cloth for air filtration with antimicrobial properties
CN107447279A (en) * 2016-05-30 2017-12-08 上海九意日用品有限公司 A kind of long-acting biological antibacterial nonwoven cloth and preparation method thereof
CN107099934A (en) * 2017-05-09 2017-08-29 南昌萃诗贸易有限公司 A kind of facial mask special non-woven fabric
CN107011488A (en) * 2017-05-16 2017-08-04 马嘉 A kind of preparation and application of NEW TYPE OF COMPOSITE antiseptic and its master batch
CN107744189A (en) * 2017-10-17 2018-03-02 钟婷婷 A kind of Traditional Chinese medicine bacteriostatic mouth mask and preparation method

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
何小维等: "《碳水化合物功能材料》", 31 January 2007, 中国轻工业出版社 *
何银地等: "C6位选择性氧化竹浆纤维的壳聚糖改性处理", 《高分子材料科学与工程》 *
周红军: "硝酸氧化法制备末端羧基化聚丙烯", 《仲恺农业工程学院学报》 *
邹训重等: "纳米抗菌剂的研究进展", 《广东微量元素科学》 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109594196A (en) * 2018-11-07 2019-04-09 桐城市鸿江包装有限公司 The preparation method of antimicrobial form wall paper non-woven fabrics
CN110592808A (en) * 2019-09-02 2019-12-20 中科纺织研究院(青岛)有限公司 Alga modified PP spunbonded non-woven fabric
EP3786329A1 (en) 2019-09-02 2021-03-03 Bestee Material (Tsingtao) Co., Ltd. Plant-based functional polypropylene spunbond non-woven fabric and preparation method thereof
CN110894642A (en) * 2019-12-16 2020-03-20 中科纺织研究院(青岛)有限公司 Chitin modified PP spunbonded non-woven fabric
US20210180213A1 (en) * 2019-12-16 2021-06-17 Sinotech Academy Of Textile (Qingdao) Co., Ltd. Chitin-modified polypropylene spunbond non-woven fabric and preparation method thereof
WO2021120446A1 (en) * 2019-12-16 2021-06-24 中科纺织研究院(青岛)有限公司 Chitin-modified pp spunbonded non-woven fabric
JP2021107606A (en) * 2019-12-16 2021-07-29 中科紡織研究院(青島)有限公司Sinotech Academy of Textile (Qingdao) Co., Ltd. Chitin-modified pp spun-bonded nonwoven fabric, and production method of the same
US11767614B2 (en) * 2019-12-16 2023-09-26 Sinotech Academy Of Textile (Qingdao) Co., Ltd. Preparation method of chitin-modified polypropylene spunbond non-woven fabric
CN112376167A (en) * 2020-10-22 2021-02-19 江阴市中兴无纺布有限公司 Low-impedance electrostatic functional non-woven fabric and production process thereof
CN112376167B (en) * 2020-10-22 2022-04-12 江阴市中兴无纺布有限公司 Low-impedance electrostatic functional non-woven fabric and production process thereof

Similar Documents

Publication Publication Date Title
CN108560149A (en) A kind of processing technology of high-performance antibiosis polypropylene spunbond non-woven fabrics
CN108286132A (en) A kind of degradable method for processing nonwoven fabrics with antibacterial functions
KR20190087959A (en) Process for the production of regenerated cellulose fibers having antibacterial, antitermic and antifungal functions and uses thereof
CN107761183B (en) It is a kind of with antibacterial, health care, the vegetative fiber cellulose fiber of skin-protecting function and preparation method thereof
CN107362680A (en) A kind of cleanser for air purifier and preparation method thereof
CN102330167A (en) Curcumin antibacterial fiber and preparation method thereof
CN107099167A (en) A kind of wormwood dyestuff and its production and use
CN109457474A (en) A kind of high-efficiency antimicrobial deodorant socks and preparation method thereof
US6156817A (en) Functional form and process for the production of the same
CN103741245A (en) Viscose fiber with antibacterial function of ginkgo leaves and preparation method of viscose fiber
CN106564222A (en) Multifunctional non-woven fabric
CN110230112A (en) A kind of antibiosis anti-acarien smelly eliminating viscose fiber and preparation method thereof
CN113279146A (en) Preparation process and application of spunbonded non-woven fabric containing honeysuckle antipyretic extract
CN105754751A (en) Anti-bacteria and water-saving detergent prepared from pure natural Chinese herbal medicines and plants and preparation method of detergent
CN107789662A (en) A kind of diaper and preparation method thereof
CN107312642A (en) A kind of preparation method of the Traditional Chinese medicine laundry detergent containing licorice
CN106719901A (en) Plant immune inducer prepared by a kind of utilization shrimp and crab shells and preparation method thereof
CN101974796A (en) Method for preparing medical stone cellulose fiber
CN108042460A (en) A kind of Traditional Chinese medicinal hand lotion and preparation method thereof
CN105726415A (en) Bacteriostasis wet tissue containing pure natural traditional Chinese herbal medicine ingredients and preparing method thereof
CN108744016A (en) A kind of preparation method of the medical adhesive-bonded fabric dressing of moisture absorption anti-inflammatory
CN106106588A (en) A kind of bactericide and preparation method thereof
CN102058898B (en) Powder with antibacterial and haemostatic effects and preparation method and applications thereof
CN102165958A (en) Pesticide composite containing bifenazate and triazophos
CN108904380A (en) A kind of hygenic towelette and its manufacturing method with bacteria resistance function

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180921