CN107367878A - A kind of electrochromism vacuum glass - Google Patents
A kind of electrochromism vacuum glass Download PDFInfo
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- CN107367878A CN107367878A CN201710493765.7A CN201710493765A CN107367878A CN 107367878 A CN107367878 A CN 107367878A CN 201710493765 A CN201710493765 A CN 201710493765A CN 107367878 A CN107367878 A CN 107367878A
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/153—Constructional details
- G02F1/1533—Constructional details structural features not otherwise provided for
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/153—Constructional details
- G02F1/1533—Constructional details structural features not otherwise provided for
- G02F2001/1536—Constructional details structural features not otherwise provided for additional, e.g. protective, layer inside the cell
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- Nonlinear Science (AREA)
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- Optics & Photonics (AREA)
- Joining Of Glass To Other Materials (AREA)
- Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
Abstract
The invention provides a kind of electrochromism vacuum glass, it includes being sequentially overlapped the substrate of setting, conductive layer, cathodic electrochromic layer, ion conductive layer, anode electrochromic layer, transparent oxide lower conductiving layer, transparent adhesive-layer, inner layer glass, vacuum layer and glass outer on transparent oxide.The electrochromism vacuum glass of the present invention is a kind of heat-insulated, sound insulation, antiultraviolet, lowers condensation point, the adjustable energy-efficient glass of illuminance；It is fine as architectural glazings soundproof effect and effect of heat insulation, it particularly can change day illuminance according to resident family's oneself requirement, reduce light radiation and radiant heat to indoor and people influence, meet comfort level of the people under certain solar radiation.The present invention preferably resolves electrochomeric glass to be influenceed by external environment impact, and a day illuminance adjustment can not artificially be selected by solving vacuum glass, to the uncontrollable problem of light radiation heat.
Description
Technical field
The present invention relates to glass technology field, more particularly to a kind of electrochromism vacuum glass.
Background technology
Electrochomeric glass (Electrochromism Glass, hereinafter referred to as EC glass) is a kind of new multi-functional
Glass, its application in building, means of transport daylighting meet environmental protection, saved, the glass industry future development that transmitance is variable
Direction.Although the technology end of the sixties in last century is found that WO3EC phenomenons, its application at present in the world still in by into
The developing stage of long-term fast growth phase of progressively marching toward, and still fall within the starting phase as market product at home.
" electrochromism " refers to the optical properties (reflectivity, transmitance, absorptivity etc.) of material in the effect of extra electric field
The lower phenomenon that stable, reversible physical change occurs, shows as the reversible change of color and transparency in appearance, EC glass with
There is wide market capacity and fine development prospect in future by correlation properties.
But electrochomeric glass is not so good as vacuum glass in sound insulation, air-flow thermal resistance (heat-insulated) effect.Between vacuum glass
Interlayer is full glass material sealing vacuum layer, and its general vacuum need to be up to 10-2Pa, its be it is a kind of truly it is heat-insulated, every
The glass of sound, low condensation point, suitable for New Building Materials, means of transport and freezer door etc..In order to ensure vacuum glass vacuum
The long term life of degree, using low-melting glass in 300 DEG C~420 DEG C lower sealing edges, long-acting air-breathing is added with also in vacuum chamber
Agent, make its vacuum life up to more than 20 years.But vacuum glass is to the radiant heat of sunshine, it is impossible to carries out on demand effective
Regulation and control.
Vacuum glass is exactly briefly heat preservation energy-saving, and electrochomeric glass is exactly dimming energy-saving.If it is true to provide a kind of collection
Empty glass and the electrochromism vacuum glass of electrochomeric glass, can greatly expand the application of above two glass
Field, and make electrochromism vacuum glass be it is a kind of integrate insulation, light modulation, ultraviolet radiation preventing with energy-conservation it is most perfect
High-grade glass.
The content of the invention
Present invention solves the technical problem that it is to provide a kind of electrochromism vacuum glass, the electrochromism that the application provides
Vacuum glass has the glass for integrating insulation, light modulation, ultraviolet radiation preventing and sound insulation.
In view of this, this application provides a kind of electrochromism vacuum glass, including：Be sequentially overlapped setting substrate, thoroughly
Conductive layer on bright oxide, cathodic electrochromic layer, ion conductive layer, anode electrochromic layer, transparent oxide lower conductiving layer,
Transparent adhesive-layer, inner layer glass, vacuum layer and glass outer.
Preferably, it is impermeable that transparent Indium insulation is provided with the substrate and the transparent oxide between conductive layer
Layer, lower transparent Indium insulation impermeable layer is provided between the transparent adhesive-layer and the transparent oxide lower conductiving layer.
Preferably, it is provided with the transparent oxide between conductive layer and the cathodic electrochromic layer on wire netting bar
Conductive layer, wire netting bar lower conductiving layer is provided between the anode electrochromic layer and the transparent oxide lower conductiving layer.
Preferably, conductive layer on wire netting bar, institute are provided between conductive layer on the substrate and the transparent oxide
State and wire netting bar lower conductiving layer is provided between transparent adhesive-layer and the transparent oxide lower conductiving layer.
Preferably, it is impermeable that transparent Indium insulation is provided with the substrate and the transparent oxide between conductive layer
Layer and conductive layer on wire netting bar, and the upper transparent Indium insulation impermeable layer is arranged at the substrate end, it is described transparent viscous
Wire netting bar lower conductiving layer is provided between glue-line and the transparent oxide lower conductiving layer and the insulation of lower transparent Indium is impermeable
Layer, and the lower transparent Indium insulation impermeable layer is arranged at the transparent adhesive-layer end.
Preferably, conductive layer is set in the following manner on the wire netting bar：
Conductive layer includes the first long side bonding jumper and Duo Gen the second short side bonding jumpers on the wire netting bar, wherein,
The first long side bonding jumper extends in a first direction, and one end is used to connect the second short side bonding jumper,
The other end has the region that is left white of preset length, and the region that is left white is not connected to the second short side bonding jumper；
The more second short side bonding jumpers are connected with the first long side bonding jumper, are extended in a second direction, and from institute
First long side bonding jumper one end is stated to arrange in the first direction；
The first direction is not parallel with the second direction.
Preferably, the first long side bonding jumper is copper or silver, and the second short side bonding jumper is copper, silver or chromium-copper chromium.
Preferably, the thickness of the substrate is 0.1~4mm, on the transparent oxide thickness of conductive layer for 50~
850nm, the thickness of the cathodic electrochromic layer are 200~800nm, and the thickness of the ion conductive layer is 5~650nm, institute
The thickness for stating anode electrochromic layer is 50~400nm, and the thickness of the transparent oxide lower conductiving layer is 50~850nm, institute
The thickness for stating inner layer glass is 4~6mm, 0.1~0.3mm of vacuum gap of the vacuum layer, a diameter of 100 μm of the strong point~
600 μm, the strong point 0.1~0.3mm of height, strong point spacing 10mm~30mm, the thickness of the glass outer is 4~6mm.
Preferably, the thickness of the upper transparent Indium insulation impermeable layer is 5~200nm, the lower transparent Indium insulation
The thickness of impermeable layer is 5~200nm.
Preferably, the thickness of conductive layer is 50nm~5 μm on the wire netting bar, the thickness of the wire netting bar lower conductiving layer
Spend for 50nm~5 μm, the width of second bonding jumper itself is 5 μm~36 μm, and the spacing of adjacent second bonding jumper is 40 μm
~400mm.
This application provides a kind of electrochromism vacuum glass, and it includes being sequentially overlapped the substrate of setting, transparent oxide
Upper conductive layer, cathodic electrochromic layer, ion conductive layer, anode electrochromic layer, transparent oxide lower conductiving layer, transparent viscose glue
Layer, inner layer glass, vacuum layer and glass outer.The internal layer glass that the electrochromism vacuum glass that the application provides is set by it
Glass, vacuum layer and glass outer, enable heat conduction of the electrochromism vacuum glass effectively inside and outside air lock, make it have super
Strong thermal insulation protection performance, finally make the indoor glass surface temperature of electrochromism vacuum glass close with room temperature, be not easy to condense；
Its vacuum Rotating fields has effectively obstructed the transmission of sound simultaneously, makes its soundproof effect preferable；Electrochomeric glass is set simultaneously
Electrochromic layer has stronger iris action to radiant heat, the ultraviolet of light, light can from most secretly to transparent change, because
This, the electrochromism vacuum glass that the application provides has insulation, light modulation line, the function of the pre- ultraviolet radiation preventing of sound insulation simultaneously.
Further, the upper and lower transparent Indium insulation impermeable layer tool set in the electroluminescent glass of vacuum that the application provides
There are impermeable insulation, isolation and increase transmitance.
Further, the upper and lower conductive layer of wire netting bar is additionally provided with the electrochromism vacuum glass that the application provides, can
The discoloration rate of electrochromism vacuum glass is further speeded up, and makes change Color uniformity preferable.
Further, the transparent adhesive-layer that also sets up of electrochromism vacuum glass that the application provides make electrochromic layer and
Vacuum layer organically combines, and prevents ultraviolet radiation.
Brief description of the drawings
Fig. 1 is the electrochromism vacuum glass schematic diagram that the embodiment of the present invention 1 provides；
Fig. 2 is the electrochromism vacuum glass schematic diagram that the embodiment of the present invention 2 provides；
Fig. 3 is the electrochromism vacuum glass schematic diagram that the embodiment of the present invention 3 provides；
Fig. 4 is the electrochromism vacuum glass schematic diagram that the embodiment of the present invention 4 provides；
Fig. 5 is the electrochromism vacuum glass schematic diagram that the embodiment of the present invention 5 provides；
Fig. 6 is the electrochromism vacuum glass schematic diagram that the embodiment of the present invention 6 provides；
Fig. 7 is the structural representation of wire netting bar conductive layer plate of the present invention；
Fig. 8 is the structural representation of wire netting bar conductive layer lower panel of the present invention.
Embodiment
For a further understanding of the present invention, the preferred embodiment of the invention is described with reference to embodiment, still
It should be appreciated that these descriptions are simply further explanation the features and advantages of the present invention, rather than to the claims in the present invention
Limitation.
The embodiment of the invention discloses a kind of electrochromism vacuum glass, including：It is sequentially overlapped the substrate of setting, transparent oxygen
It is conductive layer in compound, cathodic electrochromic layer, ion conductive layer, anode electrochromic layer, transparent oxide lower conductiving layer, transparent
Adhesive-layer, inner layer glass, vacuum layer and glass outer.
This application provides a kind of electrochromism vacuum glass, the advantages of it has electrochomeric glass and vacuum glass concurrently,
And the defects of effectively compensate for electrochomeric glass and vacuum glass.
Specifically, the substrate in herein described electrochromism vacuum glass is material well known to those skilled in the art,
Example, the substrate can be glass or Low-E glass, or PET film, its thickness are 0.1~4mm.
Conductive layer has transparent and conductive effect concurrently on the transparent oxide, is added between upper and lower transparency conducting layer
Certain voltage, forms uniform electric field between the two layers, the electrochromism layer material between two layers is occurred under electric field action
Redox reaction, its color and transmitance is set to change；Therefore transparent oxide conductive layer can also be referred to as electroluminescent change
Chromatograph discoloration electric field driven layer.The conductive of conductive layer is needed with higher light transmission rate and good on transparent oxide
Electric conductivity, common used material has ITO, FTO, AZO etc.；Example, it is specially ito film, and its thickness is 50~850nm, is being had
In body embodiment, the thickness of conductive layer is 100~500nm on the transparent oxide.
The ion conductive layer is also known as dielectric substrate, and ion conductive layer has high ionic conductance, to guarantee in electricity
Ion is quickly conducted between mutagens color and ion storage；Its material is material well known to those skilled in the art, example,
The ion conductive layer is lithium ion conductor layer, and more specifically, the material of the ion conductive layer is all solid state inorganic electrolyte
Or organic-inorganic compoiste polymer (PEO-LiCIO (LiPON)4), more specifically, the material of the electrode layer is
LiWOx+NixVyOz、LiTaO3Or Li+LiTaO3.The thickness of the ion conductive layer is 5~650nm, in a particular embodiment,
The thickness of the ion conductive layer is 20~500nm.
The anode electrochromic layer typically uses transition metal oxide and its derivative, oxidizing process coloured material,
It is the certain voltage applied between upper and lower transparency conducting layer, and under the electric field action of formation, anode electrochromic layer loses
The anion migrated in electronics or dielectric substrate realizes discoloration；Its material is material well known to those skilled in the art, is shown
Example, the anode electrochromic layer is NiOx、IrO2Deng more specifically, the material of the anode electrochromic layer is NiO.Institute
The thickness for stating anode electrochromic layer is 50~400nm, and in a particular embodiment, the thickness of the anode electrochromic layer is
100~300nm.
The cathodic electrochromic layer, general to use transition metal oxide and its derivative, reduction process coloured material,
It is certain voltage for applying between upper and lower transparency conducting layer that it, which is acted on, under the electric field action of formation, cathodic electrochromic layer
The cation for obtaining migrating in electronics or dielectric substrate realizes discoloration, can have WO with materialX、MO3.The cathodic electrochromic becomes
The thickness of chromatograph is 200~800nm, and in a particular embodiment, the thickness of the cathodic electrochromic layer is 250~500nm.
The transparent oxide lower conductiving layer has transparent and conductive effect concurrently, is added between upper and lower transparency conducting layer
Certain voltage, forms uniform electric field between the two layers, the electrochromism layer material between two layers is occurred under electric field action
Redox reaction, its color and transmitance is set to change.Electrically conducting transparent layer material need with higher light transmission rate and
Good electric conductivity, common used material have ITO, FTO, AZO etc.；Its material is material well known to those skilled in the art, example,
The transparent oxide lower conductiving layer is ito film, and its thickness is 50~850nm, in a particular embodiment, the transparent oxide
The thickness of lower conductiving layer is 100~500nm.
The transparent adhesive-layer is used to glue transparent oxide conductive layer and inner layer glass, specifically, described transparent viscous
Glue-line uses optical clear adhesive (SGP doublings layer), to realize the adhesion of transparent oxide lower conductiving layer and inner layer glass, and
It prevents ultraviolet radiation.
The material of the inner layer glass is glass or Low-E glass, and its thickness is 4~6mm.The vacuum layer is also known as vacuum
Layer branch bed course, 0.1~0.3mm of its vacuum gap, a diameter of 100 μm~600 μm of the strong point, the strong point 0.1~0.3mm of height,
Strong point spacing 10mm~30mm.The thickness of the glass outer is 4~6mm.
The transparent oxide conductive layer side's of hope resistance in design is the smaller the better, but due to transparent Indium object space
The reduction of resistance, it, which will deposit the thickness of (sputtering, evaporation, chemistry) transparent oxide layer (ITO), to increase.Therefore in transparent oxygen
In the case that compound layer (ITO) thickness is certain, can wire netting bar conductive layer be set in electrochromism vacuum glass to improve
The electric conductivity of bright oxide conducting layer, ensure certain vision transmitance.
Preferably, it is provided with metal between conductive layer and the cathodic electrochromic layer on the transparent oxide
Conductive layer on net bar, it is provided with wire netting bar and leads between the transparent oxide lower conductiving layer and the anode electrochromic layer
Electric layer；
The setting of above-mentioned wire netting bar conductive layer can ensure the certain transmitance of form, and transparent oxide conductive layer is being set
Timing side's resistance can not be made small, and square resistance is smaller, and the thickness of transparent oxide will increase, with transparent oxide
Thickness increase, transmitance just necessarily reduces, but in the case where ensureing the certain transmitance of form, with electrochomeric glass area
Increase, due to the effect of its internal resistance, the electric field between upper and lower transparent oxide conductive layer dies down, uniformity is deteriorated, discoloration rate
Slack-off and uniformity is deteriorated, and sets the wire netting bar conductive layer of this specific setting in electrochromism vacuum glass, in auxiliary,
Electric conductivity of the lower transparent oxide conductive layer under certain square resistance, strengthens electric field, and can lead upper and lower transparent oxide
Electric Field Distribution is uniform between electric layer, under conditions of the certain vision transmitance of form is ensured, accelerates discoloration rate and improves
Become Color uniformity.
Or, conductive layer on wire netting bar is provided between conductive layer on the substrate and the transparent oxide, it is described
Wire netting bar lower conductiving layer is provided between bright oxide lower conductiving layer and the transparent adhesive-layer.
Under conditions of the setting of such a wire netting bar conductive layer can ensure the certain vision transmitance of the form of large area,
Accelerate the discoloration rate of form and improve form change Color uniformity.
The upper and lower conductive layer of wire netting bar presses Fig. 7, Fig. 8 structure design so that upper and lower transparent oxide conductive layer electric field increases
Strong uniformity improves, and which raises the technology discoloration rate quickening of full sputtering (evaporation) plated film inorganic full-solid, and uniformity is good,
The problem of bigger coloring fading rate of inorganic full-solid electric driven color-changing glass, area is slower, and uniformity is deteriorated is improved, is improved
The discoloration rate uniformity and uniformity of large scale electrochomeric glass；Change the electricity of existing electrochomeric glass internal structure
Field distribution uniformity and the electric-field intensity for improving application part；So that the ion in ion storage passes through ionic conduction
Layer when penetrating into cathodic electrochromic layer, with the lifting of electric-field intensity accelerate by diffusion velocity, electrochromic discoloration speed
Rate is accelerated, and this structural metal net bar conductive layer causes the Electric Field Distribution uniformity of electrochomeric glass internal structure to become more
Good, the Electric Field Distribution uniformity of electrochomeric glass internal structure improves, and electrochromism discoloration uniformity, uniformity improve.
The structural representation of herein described wire netting bar conductive layer on the wire netting bar as shown in fig. 7, specifically, lead
Electric layer is set in the following manner：
Conductive layer includes the first long side bonding jumper and Duo Gen the second short side bonding jumpers on the wire netting bar, wherein,
The first long side bonding jumper extends in a first direction, and one end is used to connect the second short side bonding jumper,
The other end has the region that is left white of preset length, and the region that is left white is not connected to the second short side bonding jumper；
The more second short side bonding jumpers are connected with the first long side bonding jumper, are extended in a second direction, and from institute
First long side bonding jumper one end is stated to arrange in the first direction；
The first direction is not parallel with the second direction.
The first direction of the upper wire netting bar conductive layer can be understood as the long side side of wire netting bar conductive layer in Fig. 7
To the second direction can be understood as the short side direction of wire netting bar conductive layer in Fig. 7, the first direction and described second
The span of direction angulation is 90 ° ± 1 °, including endpoint value；The first direction is preferably with the second direction
90°.110 be the first long side bonding jumper in Fig. 7, and 120 be the second short side bonding jumper；L in Fig. 7 is wire netting bar conductive layer
The long edge lengths of plate or the wire netting bar conductive layer lower panel in Fig. 8, W are the length of wire netting bar conductive layer plate, and X is phase
Spacing between the adjacent second short side bonding jumper 120, X1 are the width of the second short side bonding jumper, and X2 is the length for being left white region
Degree, it is equal to the half of spacing and the second short side strip width X1 sums between the adjacent second short side bonding jumper, and Y1 is
The width of first long side bonding jumper, Y2 are the length of the second short side bonding jumper, and Y1 is much smaller than Y2.
The value of X, X1, X2, Y1, Y2, L and W in herein described wire netting bar conductive layer can be according to actual electroluminescent changes
The performance of color vacuum glass is adjusted, and in a particular embodiment, X span is 40 μm~600mm, X1 span
For 5 μm~36 μm, X2 span is 20 μm~300mm, and Y1 span is 2mm~20mm, W=Y1+Y2.Described
The radical of two short side bonding jumpers 120 is set to n, then L=(n-1) * X+n*X1+X2.
The formation material of the wire netting bar conductive layer can be chromium-copper chromium, copper, silver, copper alloy or silver alloy, more specifically
, the first long side bonding jumper is copper or silver, and the second short side bonding jumper is copper, silver or chromium-copper chromium.
In order to further improve the light penetration of electrochromism vacuum glass, the application also the substrate with it is described
Be provided with bright oxide between conductive layer transparent Indium insulation impermeable layer, the transparent oxide lower conductiving layer with it is described
Lower transparent Indium insulation impermeable layer is provided between transparent adhesive-layer；Upper and lower transparent Indium insulation impermeable layer mainly rises absolutely
The impermeable effect of edge, or buffer action.
The material of the upper transparent Indium insulation impermeable layer is with SiO2Exemplified by filling, its thickness is 5~200nm, in reality
Apply in example, the thickness of the upper transparent Indium insulation impermeable layer is 30~180nm；The lower transparent Indium insulation impermeable layer
Material with SiO2Exemplified by filling, its thickness is 5~200nm, in embodiment, the lower transparent Indium insulation impermeable layer
Thickness is 30~180nm.
In the case of the impermeable layer that insulated including upper and lower transparent Indium, conductive layer and gold on also settable wire netting bar
Belong to net bar lower conductiving layer, and conductive layer is arranged at conductive layer and cathodic electrochromic layer on transparent oxide on the wire netting bar
Between, the wire netting bar lower conductiving layer be arranged at the transparent oxide lower conductiving layer and the anode electrochromic layer it
Between；
Or, conductive layer is arranged on the substrate and the transparent oxide between conductive layer on wire netting bar, and it is described
Away from the substrate end, the wire netting bar lower conductiving layer is arranged under the transparent oxide conductive conductive layer on wire netting bar
Between layer and the transparent adhesive-layer, and the wire netting bar lower conductiving layer is away from the transparent adhesive-layer.
The invention provides a kind of electrochromism vacuum glass, and it includes being sequentially overlapped the substrate of setting, transparent oxide
Upper conductive layer, cathodic electrochromic layer, ion conductive layer, anode electrochromic layer, transparent oxide lower conductiving layer, transparent viscose glue
Layer, inner layer glass, vacuum layer and glass outer.The electrochromism vacuum glass of the present invention is a kind of heat-insulated, sound insulation, UV resistance
Line, lower condensation point, the adjustable energy-efficient glass of illuminance；Best as architectural glazings soundproof effect, effect of heat insulation is most
It is good, it particularly can change day illuminance according to resident family's oneself requirement, reduce the influence of light radiation and radiant heat to interior and people,
Meet comfort level of the people under certain solar radiation.The present invention preferably resolves what electrochomeric glass was impacted by external environment
Influence, a day illuminance adjustment can not artificially be selected by solving vacuum glass, to the uncontrollable problem of light radiation heat.
For a further understanding of the present invention, electrochromism vacuum glass provided by the invention is carried out with reference to embodiment
Describe in detail, protection scope of the present invention is not limited by the following examples.
Embodiment 1
A kind of electrochromism vacuum glass, including it is sequentially overlapped the substrate 1 of setting, conductive layer 2, negative electrode on transparent oxide
Electrochromic layer 3, ion conductive layer 4, anode electrochromic layer 5, transparent oxide lower conductiving layer 6, transparent adhesive-layer 7, internal layer
Glass 8, vacuum layer 9 and glass outer 10.The structural representation of the electrochromism vacuum glass of the present embodiment is as shown in Figure 1.
Every layer of specific material and thickness are specifically as shown in table 1 in above layers,
The parametric data table of the present embodiment electrochromism vacuum glass of table 1
The performance of the present embodiment electrochromism vacuum glass is detected, is specially：Heat-insulating property K=0.56W/ (m2·K)；Dew
- 60 DEG C of experimental tests temperature stickup times 4min, no frosting, without condensation；The propagation of sound needs medium, composite vacuum glass every
Acoustic performance amount testing inspection is up to 39dB；Visible light transmissivity can adjust from 1%~60%, and radiant heat only has 0.4%~
33%；Service life was up to more than 20 years.
Embodiment 2
A kind of electrochromism vacuum glass, including it is sequentially overlapped the substrate 1 of setting, upper transparent Indium insulation impermeable layer
11st, conductive layer 2, cathodic electrochromic layer 3, ion conductive layer 4, anode electrochromic layer 5, transparent oxide on transparent oxide
Lower conductiving layer 6, lower transparent Indium insulation impermeable layer 12, transparent adhesive-layer 7, inner layer glass 8, vacuum layer 9 and glass outer 10.
The structural representation of the electrochromism vacuum glass of the present embodiment is as shown in Figure 2.
Embodiment 3
A kind of electrochromism vacuum glass, including it is sequentially overlapped the substrate 1 of setting, conductive layer 2, metal on transparent oxide
Conductive layer 13 on net bar, cathodic electrochromic layer 3, ion conductive layer 4, positive electrochromic layer 5, wire netting bar lower conductiving layer 14,
Transparent oxide lower conductiving layer 6, transparent adhesive-layer 7, inner layer glass 8, vacuum layer 9 and glass outer 10.The present embodiment it is electroluminescent
The structural representation of discoloration vacuum glass is as shown in Figure 3.
Embodiment 4
A kind of electrochromism vacuum glass, including it is sequentially overlapped the substrate 1 of setting, upper transparent Indium insulation impermeable layer
11st, conductive layer 2 on transparent oxide, conductive layer 13, cathodic electrochromic layer 3, ion conductive layer 4, anode electricity on wire netting bar
Mutagens chromatograph 5, wire netting bar lower conductiving layer 14, transparent oxide lower conductiving layer 6, lower transparent Indium insulation impermeable layer 12, thoroughly
Bright adhesive-layer 7, inner layer glass 8, vacuum layer 9 and glass outer 10.The structural representation of the electrochromism vacuum glass of the present embodiment
Figure is as shown in Figure 4.
Every layer of specific material and thickness are specifically as shown in table 2 in above layers,
The parametric data table of the present embodiment electrochromism vacuum glass of table 2
The performance of the present embodiment electrochromism vacuum glass is detected, is specially：Heat-insulating property K=0.56W/ (m2·K)；Dew
- 60 DEG C of experimental tests temperature stickup times 4min, no frosting, without condensation；The propagation of sound needs medium, composite vacuum glass every
Acoustic performance amount testing inspection is up to 39dB；Visible light transmissivity can adjust from 1%~60%, and radiant heat only has 0.4%~
33%, ultraviolet penetrates almost nil；Service life was up to more than 20 years.
Embodiment 5
A kind of electrochromism vacuum glass, including it is sequentially overlapped the substrate 1 of setting, conductive layer 13 on wire netting bar, transparent
It is conductive under conductive layer 2, cathodic electrochromic layer 3, ion conductive layer 4, anode electrochromic layer 5, transparent oxide on oxide
Layer 6, wire netting bar lower conductiving layer 14, transparent adhesive-layer 7, inner layer glass 8, vacuum layer 9 and glass outer 10.The electricity of the present embodiment
The structural representation of mutagens color vacuum glass is as shown in Figure 5.
Every layer of specific material and thickness are specifically as shown in table 3 in above layers,
The parametric data table of the present embodiment electrochromism vacuum glass of table 3
Embodiment 6
A kind of electrochromism vacuum glass, including it is sequentially overlapped the substrate 1 of setting, upper transparent Indium insulation impermeable layer
11st, conductive layer 13 on wire netting bar, conductive layer 2, cathodic electrochromic layer 3, ion conductive layer 4, anode electricity on transparent oxide
Mutagens chromatograph 5, transparent oxide lower conductiving layer 6, wire netting bar lower conductiving layer 14, lower transparent Indium insulation impermeable layer 12, thoroughly
Bright adhesive-layer 7, inner layer glass 8, vacuum layer 9 and glass outer 10.The structural representation of the electrochromism vacuum glass of the present embodiment
Figure is as shown in Figure 5.
Every layer of specific material and thickness are specifically as shown in table 4 in above layers,
The parametric data table of the present embodiment electrochromism vacuum glass of table 4
The performance of above example electrochromism vacuum glass is detected, can reach：Heat-insulating property K≤0.6W/ (m2·K)；
- 60 DEG C of dew-point test temperature stickup time >=4min, no frosting, without condensation；The propagation of sound needs medium, composite vacuum glass
Sound insulation property energy testing inspection up to 39dB；Visible light transmissivity can adjust from 1%~60%, and radiant heat only has 0.4%
~33%, ultraviolet penetrates almost nil；Service life was up to more than 20 years.
The explanation of above example is only intended to help the method and its core concept for understanding the present invention.It should be pointed out that pair
For those skilled in the art, under the premise without departing from the principles of the invention, the present invention can also be carried out
Some improvement and modification, these are improved and modification is also fallen into the protection domain of the claims in the present invention.
The foregoing description of the disclosed embodiments, professional and technical personnel in the field are enable to realize or using the present invention.
A variety of modifications to these embodiments will be apparent for those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, it is of the invention
The embodiments shown herein is not intended to be limited to, and is to fit to and principles disclosed herein and features of novelty phase one
The most wide scope caused.
Claims (10)
1. a kind of electrochromism vacuum glass, including：It is sequentially overlapped the substrate of setting, conductive layer, negative electrode electricity on transparent oxide
It is mutagens chromatograph, ion conductive layer, anode electrochromic layer, transparent oxide lower conductiving layer, transparent adhesive-layer, inner layer glass, true
Dead level and glass outer.
2. electrochromism vacuum glass according to claim 1, it is characterised in that the substrate and the transparent oxide
Transparent Indium insulation impermeable layer, the transparent adhesive-layer and conduction under the transparent oxide are provided between upper conductive layer
Lower transparent Indium insulation impermeable layer is provided between layer.
3. electrochromism vacuum glass according to claim 1 or 2, it is characterised in that conductive on the transparent oxide
Be provided with conductive layer on wire netting bar between layer and the cathodic electrochromic layer, the anode electrochromic layer with it is described transparent
Wire netting bar lower conductiving layer is provided between oxide lower conductiving layer.
4. electrochromism vacuum glass according to claim 1, it is characterised in that the substrate and the transparent oxide
Conductive layer on wire netting bar is provided between upper conductive layer, between the transparent adhesive-layer and the transparent oxide lower conductiving layer
It is provided with wire netting bar lower conductiving layer.
5. electrochromism vacuum glass according to claim 1, it is characterised in that the substrate and the transparent oxide
Transparent Indium insulation impermeable layer and conductive layer on wire netting bar are provided between upper conductive layer, and the upper transparent Indium is exhausted
Edge impermeable layer is arranged at the substrate end, and gold is provided between the transparent adhesive-layer and the transparent oxide lower conductiving layer
Belong to net bar lower conductiving layer and lower transparent Indium insulation impermeable layer, and the lower transparent Indium insulation impermeable layer be arranged at it is described
Transparent adhesive-layer end.
6. according to the electrochromism vacuum glass described in claim 3,4 or 5, it is characterised in that conductive on the wire netting bar
Layer is set in the following manner：
Conductive layer includes the first long side bonding jumper and Duo Gen the second short side bonding jumpers on the wire netting bar, wherein,
The first long side bonding jumper extends in a first direction, and one end is used to connect the second short side bonding jumper, another
End is left white region with preset length, and the region that is left white is not connected to the second short side bonding jumper；
The more second short side bonding jumpers are connected with the first long side bonding jumper, are extended in a second direction, and from described
Rise and arrange in the first direction in one long side bonding jumper one end；
The first direction is not parallel with the second direction.
7. electrochromism vacuum glass according to claim 6, it is characterised in that the first long side bonding jumper be copper or
Silver, the second short side bonding jumper are copper, silver or chromium-copper chromium.
8. the electrochromism vacuum glass according to any one of Claims 1 to 5, it is characterised in that the thickness of the substrate
For 0.1~4mm, the thickness of conductive layer is 50~850nm on the transparent oxide, and the thickness of the cathodic electrochromic layer is
200~800nm, the thickness of the ion conductive layer are 5~650nm, the thickness of the anode electrochromic layer for 50~
400nm, the thickness of the transparent oxide lower conductiving layer is 50~850nm, and the thickness of the inner layer glass is 4~6mm, described
0.1~0.3mm of vacuum gap of vacuum layer, a diameter of 100 μm~600 μm of the strong point, the strong point 0.1~0.3mm of height, support
Point spacing 10mm~30mm, the thickness of the glass outer is 4~6mm.
9. the electrochromism vacuum glass according to claim 2 or 5, it is characterised in that the upper transparent Indium insulation is anti-
The thickness of permeable formation is 5~200nm, and the thickness of the lower transparent Indium insulation impermeable layer is 5~200nm.
10. according to the electrochromism vacuum glass described in claim 3,4 or 5, it is characterised in that conductive on the wire netting bar
The thickness of layer is 50nm~5 μm, and the thickness of the wire netting bar lower conductiving layer is 50nm~5 μm, second bonding jumper itself
Width be 5 μm~36 μm, the spacing of adjacent second bonding jumper is 40 μm~400mm.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710493765.7A CN107367878A (en) | 2017-06-26 | 2017-06-26 | A kind of electrochromism vacuum glass |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710493765.7A CN107367878A (en) | 2017-06-26 | 2017-06-26 | A kind of electrochromism vacuum glass |
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| CN107367878A true CN107367878A (en) | 2017-11-21 |
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ID=60305672
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| CN201710493765.7A Pending CN107367878A (en) | 2017-06-26 | 2017-06-26 | A kind of electrochromism vacuum glass |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111562705A (en) * | 2020-05-25 | 2020-08-21 | 广东省雅众幕墙科技有限公司 | Electrochromic glass light modulation window assembly |
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| US5657149A (en) * | 1992-05-21 | 1997-08-12 | Saint-Gobain Recherche | Architectural electrochromic pane |
| CN1571940A (en) * | 2001-10-16 | 2005-01-26 | Ppg工业俄亥俄公司 | Polymeric electrochromic devices |
| CN205080345U (en) * | 2015-10-16 | 2016-03-09 | 巴中市华盛玻璃有限责任公司 | Novel electrochromic glass |
| CN205581464U (en) * | 2016-04-07 | 2016-09-14 | 位元奈米科技股份有限公司 | Transparent optical device |
| CN106873281A (en) * | 2017-04-21 | 2017-06-20 | 安徽鑫昊等离子显示器件有限公司 | Electrochromic device component, electrochromic device and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5657149A (en) * | 1992-05-21 | 1997-08-12 | Saint-Gobain Recherche | Architectural electrochromic pane |
| CN1571940A (en) * | 2001-10-16 | 2005-01-26 | Ppg工业俄亥俄公司 | Polymeric electrochromic devices |
| CN205080345U (en) * | 2015-10-16 | 2016-03-09 | 巴中市华盛玻璃有限责任公司 | Novel electrochromic glass |
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| CN111562705A (en) * | 2020-05-25 | 2020-08-21 | 广东省雅众幕墙科技有限公司 | Electrochromic glass light modulation window assembly |
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Application publication date: 20171121 |