CN107325402A - A kind of polypropylene electronic tag film - Google Patents

A kind of polypropylene electronic tag film Download PDF

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Publication number
CN107325402A
CN107325402A CN201710554491.8A CN201710554491A CN107325402A CN 107325402 A CN107325402 A CN 107325402A CN 201710554491 A CN201710554491 A CN 201710554491A CN 107325402 A CN107325402 A CN 107325402A
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CN
China
Prior art keywords
parts
polypropylene
electronic tag
tag film
film according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710554491.8A
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Chinese (zh)
Inventor
杨伟帅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Lotte Chemical Technology Co Ltd
Original Assignee
Suzhou Lotte Chemical Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Lotte Chemical Technology Co Ltd filed Critical Suzhou Lotte Chemical Technology Co Ltd
Priority to CN201710554491.8A priority Critical patent/CN107325402A/en
Publication of CN107325402A publication Critical patent/CN107325402A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of polypropylene electronic tag film, it is prepared from by the raw material of following parts by weight:5 12 parts of polystyrene, 1 10 parts of maleic anhydride grafted polyethylene, 15 parts of TPU elastomers, 20 50 parts of HOPP, 15 40 parts of binary copolymerization polypropylene, 10 60 parts of ternary polymerized polypropylene, 15 parts of inorganic particle, 18 parts of PVA alloy, 16 parts of PTEE, 0.5 5 parts of stabilizer, 15 parts of reinforcing fiber, 15 parts of light trigger.By the above-mentioned means, a kind of polypropylene electronic tag film that the present invention is provided, surface transparency is high, hot pressing is combined, without solvent, safety and environmental protection, can be with low temperature and pressure, production efficiency is high, sealing strength is high, and acid-alkali-corrosive-resisting performance is excellent, beneficial to the coil etching process of electronic tag.

Description

A kind of polypropylene electronic tag film
Technical field
The present invention relates to a kind of film, and in particular to a kind of polypropylene electronic tag film.
Background technology
When general film is used in electronic tag at present, because coating layer fit fastness deficiency with basic material, it is easy to fall off or turn Move.Simultaneously traditional film with electronic tag compound tense, be that dry type is combined, dry type is compound to have following shortcoming:One It is to need substantial amounts of volatile solvent, not environmentally, dangerous, environmental pollution is serious, is not permitted in country;Two be high warm Pressure, speed is low, and efficiency is low, and percent defective is high;Three be that sealing strength is low, acid-alkali-corrosive-resisting poor performance.
The content of the invention
The present invention solves the technical problem of a kind of polypropylene electronic tag film is provided, surface transparency is high, hot pressing It is compound, without solvent, safety and environmental protection, can be with low temperature and pressure, production efficiency is high, sealing strength is high, and acid-alkali-corrosive-resisting performance is excellent, profit In the coil etching process of electronic tag.
In order to solve the above technical problems, the present invention provides a kind of polypropylene electronic tag film, it is characterised in that by following heavy The raw material of amount part is prepared from:
5-12 parts of polystyrene
1-10 parts of maleic anhydride grafted polyethylene
1-5 parts of TPU elastomers
20-50 parts of HOPP
15-40 parts of binary copolymerization polypropylene
10-60 parts of ternary polymerized polypropylene
1-5 parts of inorganic particle
1-8 parts of PVA alloy
1-6 parts of PTEE
0.5-5 parts of stabilizer
1-5 parts of reinforcing fiber
1-5 parts of light trigger.
In a preferred embodiments of the invention, the PVA alloy is thermoplastics type's processome.
In a preferred embodiments of the invention, the inorganic particle is calcium carbonate, talcum powder, silicon powder, inorganic salt minerals One or both of powder.
In a preferred embodiments of the invention, stabilizer is 2,6- di-t-butyl cresols.
In a preferred embodiments of the invention, the light trigger aoxidizes for 2,4,6- trimethyl benzoyl diphenyl bases Phosphine.
In a preferred embodiments of the invention, the reinforcing fiber is vinylon fiber, polypropylene fibre, polyimides fibre One kind in dimension.
In a preferred embodiments of the invention, the polyethylene electronic tag film also includes 1-11 parts by weight additives, institute Stating additive includes one kind in antioxidant, lubricant, antistatic additive.
The beneficial effects of the invention are as follows:The present invention provides a kind of polypropylene electronic tag film, and surface transparency is high, and hot pressing is multiple Close, without solvent, safety and environmental protection, can be with low temperature and pressure, production efficiency is high, sealing strength is high, and acid-alkali-corrosive-resisting performance is excellent, is beneficial to The coil etching process of electronic tag.
Embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation Example is only a part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common All other embodiment that technical staff is obtained under the premise of creative work is not made, belongs to the model that the present invention is protected Enclose.
Embodiment 1
A kind of polypropylene electronic tag film, is prepared from by the raw material of following parts by weight:
The kg of polystyrene 5;Maleic anhydride grafted polyethylene 5kg;TPU elastomers 2kg;The kg of HOPP 30;Binary copolymerization The kg of polypropylene 15;The kg of ternary polymerized polypropylene 25;The kg of silicon powder 1;The kg of PVA alloy 3;PTEE2 kg;Stabilizer 2, The kg of 6- di-t-butyls cresols 3.5;Polypropylene fibre 2kg;The kg of 2,4,6- trimethyl benzoyl diphenyl bases phosphine oxide 3;It is anti- The kg of oxygen agent 1.5.
Embodiment 2
A kind of polypropylene electronic tag film, is prepared from by the raw material of following parts by weight:
Polystyrene 6kg;Maleic anhydride grafted polyethylene 8kg;TPU elastomers 3kg;HOPP 35kg;Binary copolymerization gathers The kg of propylene 20;Ternary polymerized polypropylene 40kg;Inorganic salt minerals powder 3kg;The kg of PVA alloy 4;PTEE3kg;2,6- bis- The kg of t-butyltoluene phenol 4.5;Polyimide fiber 3kg;The kg of 2,4,6- trimethyl benzoyl diphenyl bases phosphine oxide 3.5;Profit The kg of lubrication prescription 1.5.
Embodiment 3
A kind of polypropylene electronic tag film, is prepared from by the raw material of following parts by weight:
Polystyrene 12kg;Maleic anhydride grafted polyethylene 8kg;TPU elastomers 4kg;HOPP 45kg;Binary copolymerization gathers The kg of propylene 35;Ternary polymerized polypropylene 45kg;Calcium carbonate 4.5kg;The kg of PVA alloy 5;PTEE4kg;The tertiary fourths of 2,6- bis- The kg of base cresols 5;Polyimide fiber 4kg;The kg of 2,4,6- trimethyl benzoyl diphenyl bases phosphine oxide 4;Antistatic additive 2.5 kg。
Embodiments of the invention are the foregoing is only, are not intended to limit the scope of the invention, it is every to utilize this hair Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks Domain, is included within the scope of the present invention.

Claims (7)

1. a kind of polypropylene electronic tag film, it is characterised in that be prepared from by the raw material of following parts by weight:
5-12 parts of polystyrene
1-10 parts of maleic anhydride grafted polyethylene
1-5 parts of TPU elastomers
20-50 parts of HOPP
15-40 parts of binary copolymerization polypropylene
10-60 parts of ternary polymerized polypropylene
1-5 parts of inorganic particle
1-8 parts of PVA alloy
1-6 parts of PTEE
0.5-5 parts of stabilizer
1-5 parts of reinforcing fiber
1-5 parts of light trigger.
2. polypropylene electronic tag film according to claim 1, it is characterised in that the PVA alloy is thermoplastics type Processome.
3. polypropylene electronic tag film according to claim 1, it is characterised in that the inorganic particle is calcium carbonate, cunning One or both of stone flour, silicon powder, inorganic salt minerals powder.
4. polypropylene electronic tag film according to claim 1, it is characterised in that the stabilizer is 2,6- di-t-butyls Cresols.
5. polypropylene electronic tag film according to claim 1, it is characterised in that, the light trigger be 2,4,6- front threes Base benzoyl diphenyl phosphine oxide.
6. polypropylene electronic tag film according to claim 1, it is characterised in that the reinforcing fiber is that vinylon is fine One kind in dimension, polypropylene fibre, polyimide fiber.
7. polypropylene electronic tag film according to claim 1, it is characterised in that the polyethylene electronic tag film is also Including 1-11 parts by weight additives, the additive includes one kind in antioxidant, lubricant, antistatic additive.
CN201710554491.8A 2017-07-10 2017-07-10 A kind of polypropylene electronic tag film Pending CN107325402A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710554491.8A CN107325402A (en) 2017-07-10 2017-07-10 A kind of polypropylene electronic tag film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710554491.8A CN107325402A (en) 2017-07-10 2017-07-10 A kind of polypropylene electronic tag film

Publications (1)

Publication Number Publication Date
CN107325402A true CN107325402A (en) 2017-11-07

Family

ID=60196668

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710554491.8A Pending CN107325402A (en) 2017-07-10 2017-07-10 A kind of polypropylene electronic tag film

Country Status (1)

Country Link
CN (1) CN107325402A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1659030A (en) * 2002-06-26 2005-08-24 艾利丹尼森公司 Oriented films comprising polypropylene/olefin elastomer blends
CN103265755A (en) * 2013-05-08 2013-08-28 上海纳米技术及应用国家工程研究中心有限公司 Multiple composite modified polypropylene plastic and preparation method thereof
CN104231178A (en) * 2014-08-22 2014-12-24 青岛文晟汽车零部件有限公司 High-toughness plastic film

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1659030A (en) * 2002-06-26 2005-08-24 艾利丹尼森公司 Oriented films comprising polypropylene/olefin elastomer blends
CN103265755A (en) * 2013-05-08 2013-08-28 上海纳米技术及应用国家工程研究中心有限公司 Multiple composite modified polypropylene plastic and preparation method thereof
CN104231178A (en) * 2014-08-22 2014-12-24 青岛文晟汽车零部件有限公司 High-toughness plastic film

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Application publication date: 20171107