CN107316510A - A kind of trans-printing type children teaching aid based on electrically conductive ink - Google Patents
A kind of trans-printing type children teaching aid based on electrically conductive ink Download PDFInfo
- Publication number
- CN107316510A CN107316510A CN201710477182.5A CN201710477182A CN107316510A CN 107316510 A CN107316510 A CN 107316510A CN 201710477182 A CN201710477182 A CN 201710477182A CN 107316510 A CN107316510 A CN 107316510A
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- China
- Prior art keywords
- circuit
- ink
- electrically conductive
- teaching aid
- trans
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09B—EDUCATIONAL OR DEMONSTRATION APPLIANCES; APPLIANCES FOR TEACHING, OR COMMUNICATING WITH, THE BLIND, DEAF OR MUTE; MODELS; PLANETARIA; GLOBES; MAPS; DIAGRAMS
- G09B5/00—Electrically-operated educational appliances
- G09B5/06—Electrically-operated educational appliances with both visual and audible presentation of the material to be studied
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/52—Electrically conductive inks
Abstract
The invention provides a kind of trans-printing type children teaching aid based on electrically conductive ink, at least include button cell and sound chip, described trans-printing type children teaching aid is made up of transfer blade and substrate, described button cell and sound chip is fixed on substrate, the circuit A in cartoon pattern shape is printed with electrically conductive ink on substrate, button cell and sound chip are electrically connected in circuit A, and absent region is provided with described circuit A;Described transfer blade is from top to bottom followed successively by transfer paper, transparent abscission layer, ink layer and adhesive layer, and described ink layer is the circuit B in identical cartoon pattern-like printed using electrically conductive ink, and the circuit B matches with the absent region on circuit A.The teaching aid structure is simple, novel, and children can be allowed oneself to be participated in during study, deepens the impression of children, improves study enjoyment, plays the effect taught through lively activities.
Description
Technical field
The invention provides a kind of trans-printing type children teaching aid based on electrically conductive ink, belong to children's early education articles for use technology
Field.
Background technology
At present, the positive every field infiltration of microelectric technique, conductive rendering technique arises at the historic moment as a kind of new and high technology.
Electrically conductive ink can be plotted in PET film by such as film switch circuit version, then by printed film and decorative art face
Plate is formed by combining;Have the advantages that simple in construction, good appearance, environment resistant excellent, service life are long, be widely used in electricity
Sub- toy, teaching aid, measurement apparatus and Medical Instruments etc..Ink protracting circuit plate technique is simple, efficiency high, but also saves metal
Copper, is to reduce an effective way of microelectronic product cost, and other, which also have, is used in contact-sensing panel, draws flat fine
Cable, low-cost solar battery, liquid crystal display electric current and infra-red detection sensing element etc., in microelectronic
Using being diversified.The conventional fabrication method of the said goods is with conductive charcoal slurry or silver paste, only two kinds of black or white
Dull admittance, by the way of half tone is drawn;Mode drawn due to half tone yielded poorly, cost it is high, can not produce in enormous quantities.With
The development of modern science and technology, market needs colorful electrically conductive ink, and water-soluble conducting ink can by the way of various draftings,
Production efficiency can be greatly improved, it will by the most attention of people, because its high conductivity flexibly can should with low conductivity
With improving the flexibility of design, it is adaptable to various new electronic equipment.From RFID tag to " intelligent clothing ", unique chemistry
System maintains the low conductivity under extraneous stress, and wide in range condition of cure and high flexibility has supported many inexpensive pedestals
Application.
At present in children's early education field, it is necessary to teach children to recognize various toys, and children are allowed to be familiar with them
Cry, these current teaching aids are plane pattern print product mostly, or electronic pictures form.By allowing outlook on children
Examine, listen to, to play a part of recognizing these animals.But these children teaching aids can not realize interaction at present, children are in study
During can not participate in person, therefore education effect it is bad, the impressionable quarter of children.If can be by waterborne conductive oil
Ink is combined with children's early education apparatus, then can solve the problem that above technical barrier.
The content of the invention
The invention provides a kind of trans-printing type children teaching aid based on electrically conductive ink, of the prior art ask is solved
Topic, the teaching aid structure is simple, novel, and children can be allowed oneself to be participated in during study, deepens the impression of children, improves and learn
Enjoyment is practised, the effect taught through lively activities is played.
Realize technical scheme that above-mentioned purpose of the present invention used for:
A kind of trans-printing type children teaching aid based on electrically conductive ink, it is described at least including button cell and sound chip
Trans-printing type children teaching aid be made up of transfer blade and substrate, described button cell and sound chip is fixed on substrate,
The circuit A in cartoon pattern shape is printed with electrically conductive ink on substrate, button cell and sound chip are electrically connected in circuit A,
Absent region is provided with described circuit A;Described transfer blade is from top to bottom followed successively by transfer paper, transparent abscission layer, ink
Layer and adhesive layer, described ink layer are the circuit B, the circuit B in identical cartoon pattern-like printed using electrically conductive ink
Match, ink layer and adhesive layer tear-off can be got off in described transfer blade, by ink layer with the absent region on circuit A
It is attached to adhesive layer on substrate in corresponding absent region, now circuit A and circuit B compositions loop, sound chip carries out sounding.
Small bulb is additionally provided with described substrate, the small bulb is fixed in circuit A, when circuit A and circuit B is constituted
During loop, small bulb can light.
Described electrically conductive ink is water-soluble conducting ink, and the raw material of the water-soluble conducting ink is composed of the following components, each group
Point and each component shared by mass percent be:Deionized water 30~38%, water-based acrylic resin 15~20%, propane diols
Methyl ether 6~10%, CNT 10~16%, conductive carbon black 5~9%, ethanol 20~30%, sodium p-octadecyl toluene sulfonate 1
~3%, triethanolamine 2~5%, dispersant 0.5~1.5%, wax powder 0.5~1%.
Described water-soluble conducting ink is prepared using following methods:(1) each raw material, is weighed by above-mentioned percentage, will first be gone
In ionized water, sodium p-octadecyl toluene sulfonate, CNT input agitator, stir 30~60 minutes;
(2) and then again by water-based acrylic resin, propylene glycol monomethyl ether, conductive carbon black, ethanol, triethanolamine, dispersant and
In wax powder input agitator, stir 30~60 minutes, then products therefrom is ground 5~10 times with sand mill, that is, is made described
Water-soluble conducting ink.
Described electrically conductive ink can also be colored resistive ink, and the raw material of the colored resistive ink is by following components group
Into the mass percent shared by each component and each component is:Propylene glycol monomethyl ether 30~38%, polyvinyl butyral resin 15~
20%th, polyaniline 6~10%, stannous chloride 10~16%, premetallized dye 5~9%, ethanol 20~30%, surface-active
Agent 1~3%, erucyl amide 2~5%, antistatic additive 0.5~1.5%, wax powder 0.5~1%.
Described colored resistive ink is prepared using following methods:(1) each raw material, is weighed by above-mentioned percentage, first by third
Mixed in glycol methyl ether, polyvinyl butyral resin input agitator, then add polyaniline, be made conductive after mixing and link
Material;
(2) and then again by stannous chloride, premetallized dye, ethanol, surfactant, erucyl amide, antistatic additive with
And mixed in wax powder input agitator, after finally products therefrom is ground with sand mill, that is, the colored resistive ink is made.
The trans-printing type children teaching aid based on electrically conductive ink that the present invention is provided has the advantage that:1st, teaching aid structure letter
It is single, it is made up of transfer blade and substrate two parts.2nd, children's teaching aid can participate when in use, and children need to select correspondence
Pattern matched with the cartoon pattern on substrate, when the match is successful, loop is formed on substrate, can realize it is luminous, and
And sound chip can send the cry of toy, to deepen the impression of children, their manipulative ability is cultivated.
Embodiment
Detailed specific description is done to the present invention with reference to specific embodiment, but protection scope of the present invention not office
It is limited to following examples.
Embodiment 1
The trans-printing type children teaching aid based on electrically conductive ink provided in the present embodiment is made up of transfer blade and substrate,
Described button cell, sound chip and small bulb is fixed on substrate, is printed with and is schemed in doggie with electrically conductive ink on substrate
The circuit A of case, button cell and sound chip are electrically connected in circuit A, and absent region is provided with described circuit A, missing
Region is arranged on the head of doggie pattern.Described transfer blade be from top to bottom followed successively by transfer paper, transparent abscission layer, ink layer and
Adhesive layer, described ink layer is on the circuit B, the circuit B and circuit A of the doggie header pattern printed using electrically conductive ink
Absent region match, ink layer and adhesive layer tear-off can be got off in described transfer blade.
When in use, when the ink layer and adhesive layer that are printed on doggie header pattern are attached to corresponding doggie on substrate by children
During the area of absence of head, now circuit A and circuit B constitutes loop, and sound chip sends the cry of doggie, the hair while lampet is steeped oneself-meeting
Light.When the pattern of other animals is attached on the vacancy position of doggie pattern by children by mistake, due to loop, therefore electricity can not be constituted
Road will not UNICOM.
Electrically conductive ink described in the present embodiment is water-soluble conducting ink, and water-soluble conducting ink is made using following methods:
(1), by deionized water 31%, water-based acrylic resin 16%, propylene glycol monomethyl ether 8%, CNT 12%, conductive carbon black 7%,
Ethanol 20%, sodium p-octadecyl toluene sulfonate 2%, triethanolamine 3%, dispersant 0.5%, the mass percent of wax powder 0.5%
Each raw material is weighed, first deionized water, sodium p-octadecyl toluene sulfonate, CNT are put into agitator, stirred 45 minutes;
(2) and then again by water-based acrylic resin, propylene glycol monomethyl ether, conductive carbon black, ethanol, triethanolamine, dispersant and
In wax powder input agitator, stir 50 minutes, then grind products therefrom with sand mill 8 times, that is, the waterborne conductive oil is made
Ink.
Water-soluble conducting ink properties testing result obtained by the present embodiment is as follows:
Project | Technical indicator | Examination criteria |
Viscosity (applies -4 glasss) | > 50 seconds | GB/T1723-1993 |
Fineness | 8~15 μm | GB/T1724-1989 |
Hardness | ≥2H | GB/T6739-1996 |
Attachment fastness | >=95% | GB/T13217.7-1991 |
Drying time | ≤5 | Min |
Volume conduction (Ω .cm) | ≤1×10-2 | Ink film thickness (6 μm) |
Embodiment 2
The trans-printing type children teaching aid based on electrically conductive ink provided in the present embodiment is made up of transfer blade and substrate,
Described button cell, sound chip and small bulb is fixed on substrate, is printed with substrate with electrically conductive ink in duckling
The circuit A of pattern, button cell and sound chip are electrically connected in circuit A, and absent region is provided with described circuit A, are lacked
Lose the head that region is arranged on duckling sub-pattern.Described transfer blade is from top to bottom followed successively by transfer paper, transparent abscission layer, ink
Layer and adhesive layer, described ink layer be the duckling header pattern printed using electrically conductive ink circuit B, the circuit B with
Absent region on circuit A matches, and ink layer and adhesive layer tear-off can get off in described transfer blade.
When in use, when children the ink layer and adhesive layer that are printed on duckling header pattern are attached to it is corresponding small on substrate
During the area of absence of duck head, now circuit A and circuit B constitutes loop, and sound chip sends the cry of duckling, while lampet
Steep oneself-meeting luminous.When the pattern of other animals is attached on the vacancy position of duckling sub-pattern by children by mistake, due to that can not constitute back
Road, therefore circuit will not UNICOM.
Electrically conductive ink described in the present embodiment is colored resistive ink, and the colored resistive ink uses following methods system
:(1), by formula measure 32% propylene glycol monomethyl ether, 15% polyvinyl butyral resin, 8% polyaniline, 12% chlorination
Cuprous, 6% orchil, 22% ethanol, 1% surfactant, 3% erucyl amide, 0.5% antistatic additive and
0.5% wax powder, propylene glycol monomethyl ether, polyvinyl butyral resin are first put into agitator and mixed, then add polyaniline, mix
Conduction link stuff is made after conjunction;
(2) and then again by stannous chloride, orchil, ethanol, surfactant, erucyl amide, antistatic additive and wax
Mixed in powder input agitator, after finally products therefrom is ground with sand mill, that is, the colored resistive ink is made.
Colored resistive ink properties testing result obtained by the present embodiment is as follows:
Claims (6)
1. a kind of trans-printing type children teaching aid based on electrically conductive ink, at least including button cell and sound chip, its feature
It is:Described trans-printing type children teaching aid is made up of transfer blade and substrate, and described button cell and sound chip is fixed
The circuit A in cartoon pattern shape is printed with electrically conductive ink on substrate, on substrate, button cell and sound chip are electrically connected to
In circuit A, absent region is provided with described circuit A;Described transfer blade is from top to bottom followed successively by transfer paper, transparent disengaging
Layer, ink layer and adhesive layer, described ink layer are the circuit B in identical cartoon pattern-like printed using electrically conductive ink, institute
State circuit B to match with the absent region on circuit A, ink layer and adhesive layer tear-off can be got off in described transfer blade,
Ink layer and adhesive layer are attached on substrate in corresponding absent region, now circuit A and circuit B compositions loop, sound chip
Carry out sounding.
2. trans-printing type children teaching aid according to claim 1, it is characterised in that:It is additionally provided with described substrate small
Bulb, the small bulb is fixed in circuit A, and when circuit A and circuit B composition loops, small bulb can light.
3. trans-printing type children teaching aid according to claim 1, it is characterised in that:Described electrically conductive ink is led to be aqueous
Electric ink, the raw material of the water-soluble conducting ink is composed of the following components, and the mass percent shared by each component and each component is:
Deionized water 30~38%, water-based acrylic resin 15~20%, propylene glycol monomethyl ether 6~10%, CNT 10~16%, lead
Electrical carbon black 5~9%, ethanol 20~30%, sodium p-octadecyl toluene sulfonate 1~3%, triethanolamine 2~5%, dispersant 0.5~
1.5%th, wax powder 0.5~1%.
4. trans-printing type children teaching aid according to claim 3, it is characterised in that:Described water-soluble conducting ink is used
It is prepared by following methods:(1) each raw material, is weighed by percentage described in claim 3, first by deionized water, octadecyl toluene
In sodium sulfonate, CNT input agitator, stir 30~60 minutes;
(2) and then again by water-based acrylic resin, propylene glycol monomethyl ether, conductive carbon black, ethanol, triethanolamine, dispersant and wax powder
Put into agitator, stir 30~60 minutes, then products therefrom is ground 5~10 times with sand mill, that is, is made described aqueous
Electrically conductive ink.
5. trans-printing type children teaching aid according to claim 1, it is characterised in that:Described electrically conductive ink is technicolo
Ink is hindered, the raw material of the colored resistive ink is composed of the following components, and the mass percent shared by each component and each component is:
Propylene glycol monomethyl ether 30~38%, polyvinyl butyral resin 15~20%, polyaniline 6~10%, stannous chloride 10~16%, metal
Complex dyestuff 5~9%, ethanol 20~30%, surfactant 1~3%, erucyl amide 2~5%, antistatic additive 0.5~
1.5%th, wax powder 0.5~1%.
6. trans-printing type children teaching aid according to claim 5, it is characterised in that:Described colored resistive ink is used
It is prepared by following methods:(1) each raw material, is weighed by percentage described in claim 5, first propylene glycol monomethyl ether, polyvinyl alcohol contract
Mixed in butyraldehyde input agitator, then add polyaniline, conduction link stuff is made after mixing;
(2) and then again by stannous chloride, premetallized dye, ethanol, surfactant, erucyl amide, antistatic additive and wax
Mixed in powder input agitator, after finally products therefrom is ground with sand mill, that is, the colored resistive ink is made.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710477182.5A CN107316510A (en) | 2017-06-21 | 2017-06-21 | A kind of trans-printing type children teaching aid based on electrically conductive ink |
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CN201710477182.5A CN107316510A (en) | 2017-06-21 | 2017-06-21 | A kind of trans-printing type children teaching aid based on electrically conductive ink |
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CN201710477182.5A Pending CN107316510A (en) | 2017-06-21 | 2017-06-21 | A kind of trans-printing type children teaching aid based on electrically conductive ink |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108538092A (en) * | 2018-04-17 | 2018-09-14 | 武汉世帝牧文化传媒有限公司 | A kind of interactive teaching material of flexibility based on printed form circuit |
CN113421477A (en) * | 2021-06-25 | 2021-09-21 | 苏州润易尚文化科技有限公司 | Circuit based on carbon-based water-based conductive ink and interaction method |
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CN2710707Y (en) * | 2004-06-22 | 2005-07-20 | 许荻萱 | Picture arrangement toy |
CN1912023A (en) * | 2006-08-18 | 2007-02-14 | 徐若谷 | Coloured conductive ink and printing matter using said coloured conductive ink |
CN2872506Y (en) * | 2006-02-14 | 2007-02-21 | 林彬 | Toy book with intelligence-strengthening and teaching functions |
CN102402895A (en) * | 2010-09-17 | 2012-04-04 | 深圳市普天文科技有限公司 | Capacitance type touch sounding globe |
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US5609488A (en) * | 1989-08-21 | 1997-03-11 | Mctaggart; Stephen I. | Method of combining audio and visual indicia |
CN2116514U (en) * | 1992-03-07 | 1992-09-23 | 童严 | Jig-saw puzzle |
CN2255297Y (en) * | 1996-06-19 | 1997-06-04 | 曾军 | Sounding photo-electric-magnetic picture-arrangement toy |
CN2306043Y (en) * | 1997-07-04 | 1999-02-03 | 许荻萱 | Picture arrangement sounding toy |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108538092A (en) * | 2018-04-17 | 2018-09-14 | 武汉世帝牧文化传媒有限公司 | A kind of interactive teaching material of flexibility based on printed form circuit |
CN108538092B (en) * | 2018-04-17 | 2020-08-04 | 武汉世帝牧文化传媒有限公司 | Flexible interactive teaching material based on printed circuit |
CN113421477A (en) * | 2021-06-25 | 2021-09-21 | 苏州润易尚文化科技有限公司 | Circuit based on carbon-based water-based conductive ink and interaction method |
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