CN106889661B - A kind of intelligent color-changing clothes - Google Patents
A kind of intelligent color-changing clothes Download PDFInfo
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- CN106889661B CN106889661B CN201710129286.7A CN201710129286A CN106889661B CN 106889661 B CN106889661 B CN 106889661B CN 201710129286 A CN201710129286 A CN 201710129286A CN 106889661 B CN106889661 B CN 106889661B
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- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 71
- 238000002845 discoloration Methods 0.000 claims abstract description 26
- 210000001015 abdomen Anatomy 0.000 claims abstract description 5
- 230000004224 protection Effects 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims description 59
- 239000000463 material Substances 0.000 claims description 31
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 21
- 238000002360 preparation method Methods 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- 239000004793 Polystyrene Substances 0.000 claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 15
- 239000004411 aluminium Substances 0.000 claims description 15
- 229920002223 polystyrene Polymers 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 14
- 239000000758 substrate Substances 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 12
- 239000004005 microsphere Substances 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 10
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000002775 capsule Substances 0.000 claims description 9
- 235000019441 ethanol Nutrition 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 230000031700 light absorption Effects 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 238000001291 vacuum drying Methods 0.000 claims description 6
- 241000894006 Bacteria Species 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 4
- UJDSDGTZRXTPOF-UHFFFAOYSA-N N1=CC=CC2=CC=CC=C12.C(C)ON1CC(C2=CC=C(C=C12)[N+](=O)[O-])(C)C Chemical compound N1=CC=CC2=CC=CC=C12.C(C)ON1CC(C2=CC=C(C=C12)[N+](=O)[O-])(C)C UJDSDGTZRXTPOF-UHFFFAOYSA-N 0.000 claims description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 238000005119 centrifugation Methods 0.000 claims description 3
- 229910000397 disodium phosphate Inorganic materials 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- 239000011344 liquid material Substances 0.000 claims description 3
- 239000012528 membrane Substances 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- ZYEQKXIEBXGMLG-UHFFFAOYSA-N phenol propane Chemical compound CCC.Oc1ccccc1.Oc1ccccc1.Oc1ccccc1 ZYEQKXIEBXGMLG-UHFFFAOYSA-N 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229940068984 polyvinyl alcohol Drugs 0.000 claims description 3
- 239000003643 water by type Substances 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 3
- 239000011686 zinc sulphate Substances 0.000 claims description 3
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims 3
- 229910004882 Na2S2O8 Inorganic materials 0.000 claims 1
- 230000000903 blocking effect Effects 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims 1
- 235000019800 disodium phosphate Nutrition 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims 1
- 230000001629 suppression Effects 0.000 claims 1
- 230000036413 temperature sense Effects 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims 1
- 235000009529 zinc sulphate Nutrition 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 2
- 238000004134 energy conservation Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000005286 illumination Methods 0.000 abstract description 2
- 230000000007 visual effect Effects 0.000 abstract description 2
- 238000001514 detection method Methods 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- 101710134784 Agnoprotein Proteins 0.000 description 2
- 241001104043 Syringa Species 0.000 description 2
- 235000004338 Syringa vulgaris Nutrition 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000001967 indiganyl group Chemical group [H][In]([H])[*] 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 208000003464 asthenopia Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000011885 synergistic combination Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D1/00—Garments
- A41D1/04—Vests, jerseys, sweaters or the like
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/02—Layered materials
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/30—Antimicrobial, e.g. antibacterial
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0094—Fibrous material being coated on one surface with at least one layer of an inorganic material and at least one layer of a macromolecular material
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2205/00—Condition, form or state of the materials
- D06N2205/08—Microballoons, microcapsules
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/08—Properties of the materials having optical properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1671—Resistance to bacteria, mildew, mould, fungi
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1678—Resistive to light or to UV
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of intelligent color-changing clothes, a kind of intelligent color-changing clothes, including garment body (1), the antibacterial layer of photo-thermal discoloration (8) is coated at the anterior part of chest (2) of the garment body (1), tuck inside the sleeve arm (3) and waist and belly position.Intelligent color-changing clothes of the present invention, shape simplicity generosity, can within take or wear outside.The phototropic layer of thermochromic layer and photoinduction with thermoinduction, the clothes is allow to follow temperature and the strong and weak of illumination that discoloration occurs, its exterior color can be changed with the case where environment temperature and light, with intelligent color-changing effect, improve the ornamental value and attraction of clothes, improve the artistic visual aesthetic feeling of clothes, energy conservation and environmental protection.
Description
Technical field
The present invention relates to garment industry more particularly to a kind of intelligent color-changing clothes.
Background technology
With the increasingly raising of living standard, requirement of the people to clothes is not only in that basic warming function of hushing up a scandal, clothing
The aesthetic appearance of clothes is also paid close attention to by more and more people, and people can especially focus on the color of clothes when buying clothes, at present clothing
Clothes mostly use greatly common cloth, and color is fixed from replacement, will produce visual fatigue over time.Therefore, there is an urgent need for a kind of intelligence
Change colour clothes.Increase the selection of people.
Invention content
The present invention is intended to provide a kind of intelligent color-changing clothes, to solve the above technical problems.
The above-mentioned purpose of the present invention is achieved by the following technical programs：
A kind of intelligent color-changing clothes, including garment body (1), the anterior part of chest (2) of the garment body (1), sleeve arm (3) and
The antibacterial layer of photo-thermal discoloration (8) is coated at waist and belly position.
Further, the antibacterial layer of photo-thermal discoloration (8) from bottom to up successively include substrate layer (10), aluminium layer (11),
Thermochromic layer (12), antibacterial layer (13) and photosensitive layer (14)；The substrate layer (10) supports other each layers, aluminium layer (11) to increase base
The metallic luster of material layer (10), thermochromic layer (12) make fungi-proofing color-changing membrane occur thermochromism, antibacterial layer (13) stop bacterium into
Enter the antibacterial layer of photo-thermal discoloration (8), photosensitive layer (14) makes the antibacterial layer of photo-thermal discoloration (8) that Ultraluminescence discoloration occur.
Further, the preparation process of the antibacterial layer of photo-thermal discoloration (8) is as follows：Aluminium coated (11), aluminium on substrate layer (10)
Thermochromic layer (12) is coated on layer (11), is coated with antibacterial layer (13) on thermochromic layer (12), photosensitive layer is coated on antibacterial layer (13)
(14)。
Further, the preparation method of the antibacterial layer of photo-thermal discoloration (8) is as follows：
Step 1, the preparation of the thermochromatic material for thermochromic layer, includes the following steps：
First, it is 350 according to mass ratio:2.3:4:40:80 to weigh 2- butanone, ultraviolet fluorescence powder, 2,2- respectively bis- to phenol
Propane, CVL, granules of polystyrene；
Second, it sequentially adds in the order described above at 30 DEG C and forms uniform liquid in flask, stir and form within 180 minutes temperature and become
Resin solution, wherein the content of ultraviolet fluorescence powder is the 0.15% of entire warm changing resin, the uniform liquid material of formation；
Step 2, the preparation of the antibacterial material for antibacterial layer, includes the following steps：
1. 500ml deionized waters are added in separatory funnel, 3g (NH are weighed2)2CO and 3.0g PVP are added to above-mentioned liquid separation leakage
In bucket, 1.5g KCl are added, after shaking 10min, AgNO is slowly added dropwise to it using long-neck dropper3Solution, after shaking 10min,
A certain amount of TiO is added dropwise2Solution liquid adds suitable ZnSO45ml is added in solution, 80 DEG C of water-bath 3h postcoolings to room temperature
Na2HPO4Solution shakes 30min；
2. the anhydrous C of 10ml are added2H5OH shakes 30min；With traditional vacuum, precipitation uses distilled water, acid solution, anhydrous successively
C2H5OH is washed；Precipitation is put into electric drying oven with forced convection drying；
3. by dry powder it is ground be made to be put into Muffle furnace after loose powder be calcined, after be down to room naturally
Temperature；Ground after calcination can be prepared by Nano- antibacterial materials；
Step 3, the preparation of light-sensitive material, includes the following steps：
1. a certain amount of styrene monomer is dissolved into anhydrous C2H5OH and H2In O mixed solutions, 60 DEG C are heated to, constant temperature is protected
30min is held, is again heated to 90 DEG C, constant temperature keeps 30min, so that PVP is fully dissolved, Na is then added2S2O8Solution reacts 5h, instead
It is centrifuged after answering, polystyrene microsphere is obtained after dry；Wherein, anhydrous C2H5OH and H2The volume ratio of O is 55:
45；
2. weighing a certain amount of polystyrene microsphere is added to certain density C8H4O3In solution, N2Protection, while stirring
AlCl is added3, 55 DEG C are reacted 12h, obtain surface-modified polystyrene microspheres；
3. surface-modified polystyrene microspheres are put into N- ethoxy -3,3- dimethyl -6- nitroindoline quinoline spiro-pyrans second
Absorption 12h is carried out in alcoholic solution, is then centrifuged for detaching, and photosensitive microballoon is made through dry, obtained photosensitive microballoon is added to
It is impregnated in certain density poly-vinyl alcohol solution for 24 hours, centrifugation, which is placed in anhydrous C2H5OH, to be disperseed, and is centrifuged, dry；
4. the PVA@polyethylene microballoons after drying are put into SnO248h is impregnated in solution, is then drying to obtain for 80 DEG C；
Step 4, the preparation of the antibacterial tunic of photo-thermal：
According to 2~4:1~2:2~5 mass ratio claims to take respectively in right amount via the thermochromatic material prepared by step 1, step
The light-sensitive material prepared by antibacterial material and step 3 prepared by rapid two；It is molten that thermochromic material is dissolved in methyl ethyl ketone
In liquid, uniform I solution is formed, stirring 90 minutes is spare；Antibacterial material is dissolved in methyl ethyl ketone solution, is formed uniform
II solution, stirring 120 minutes it is spare；Light-sensitive material is dissolved in phenylmethane solution, uniform III solution is formed, stirs
Mix 180 minutes it is spare；It by I solution coatings and forms a film on aluminium layer naturally, dry 8 in negative pressure 0.1~0.5MPa vacuum drying chambers
Hour, obtain the thermochromic layer of appearance uniform；By II solution coatings and form a film on thermochromic layer naturally, negative pressure 0.2~
It is 10 hours dry in 0.3MPa vacuum drying chambers, it is irradiated 2 hours as under 60Co rays after taking-up, obtains the thermotropic of appearance uniform
The antibacterial capsule layer of photochromic layer-；It forms a film III solution coatings and naturally on antibacterial capsule layer, is dried in vacuo 24 hours, obtain outer
See the antibacterial capsule layer of uniform thermochromic layer-- photosensitive microballoon layer, the i.e. antibacterial tunic of photo-thermal.
Further, the thickness of the thermochromic layer (12) is 20~60nm；The thickness of the antibacterial layer (13) is 50nm；
The thickness of the photosensitive layer (14) is 65nm.
Further, the antibacterial tunic of the photo-thermal further includes one layer of light-absorption layer, and the light-absorption layer is painted on the photosensitive layer
(14) top.
Further, the substrate layer (10) is garment body (1).
Compared with the existing technology, beneficial effects of the present invention：
1, intelligent color-changing clothes of the present invention, shape simplicity generosity, can within take or wear outside.
2, intelligent color-changing clothes of the present invention, the phototropic layer of thermochromic layer and photoinduction with thermoinduction, makes
Obtaining the clothes can follow temperature and the strong and weak of illumination that discoloration occurs, and can change outside it with the case where environment temperature and light
Portion's color has intelligent color-changing effect, improves the ornamental value and attraction of clothes, improve the artistic visual aesthetic feeling of clothes,
Energy conservation and environmental protection.
3, the surface of intelligent color-changing clothes of the present invention is also laid with antibacterial layer, contains composite antibacterial in the antibacterial layer
Agent, this complex antimicrobials are by TiO2、Zn2+And Ag+It is combined together, TiO is utilized2Photocatalysis Decomposition, Ag+To light and heat compared with
For sensitive feature so that while the clothes has photic and thermotropic sensitive, have antibacterial action, it is anti-when photic and thermotropic
Bacterium synergistic combinations act on, and enhance the anti-microbial property of clothes.
Description of the drawings
The drawings herein are incorporated into the specification and forms part of this specification, and shows the implementation for meeting the present invention
Example, and be used to explain the principle of the present invention together with specification.
Fig. 1 is the structural schematic diagram of the present invention.
Fig. 2 is the structural schematic diagram of the antibacterial tunic of the photo-thermal in Fig. 1.
Specific implementation mode
The invention will be further described with the following Examples.
As shown in Figure 1, a kind of intelligent color-changing clothes, including garment body 1, anterior part of chest 2, the sleeve arm 3 of the garment body 1
With the antibacterial layer of photo-thermal discoloration 8 is coated at waist and belly position.
Further, the antibacterial layer of the photo-thermal discoloration 8 includes substrate layer 10 as shown in Figure 2, aluminium successively from bottom to up
Layer 11, thermochromic layer 12, antibacterial layer 13 and photosensitive layer 14；The substrate layer 10 supports other each layers, aluminium layer 11 to increase substrate layer
10 metallic luster, thermochromic layer 12 make fungi-proofing color-changing membrane that thermochromism occur, and antibacterial layer 13 stops that bacterium enters photo-thermal discoloration
Antibacterial layer 8, photosensitive layer 14 make the antibacterial layer 8 of photo-thermal discoloration that Ultraluminescence discoloration occur.
Further, the preparation process of the antibacterial layer of photo-thermal discoloration 8 is as follows：The aluminium coated 11 on substrate layer 10, on aluminium layer 11
Thermochromic layer 12 is coated, antibacterial layer 13 is coated on thermochromic layer 12, photosensitive layer 14 is coated on antibacterial layer 13.
Further, the preparation method of the antibacterial layer of the photo-thermal discoloration 8 is as follows：
Step 1, the preparation of the thermochromatic material for thermochromic layer, includes the following steps：
First, it is 350 according to mass ratio:2.3:4:40:80 to weigh 2- butanone, ultraviolet fluorescence powder, 2,2- respectively bis- to phenol
Propane, CVL, granules of polystyrene；
Second, it sequentially adds in the order described above at 30 DEG C and forms uniform liquid in flask, stir and form within 180 minutes temperature and become
Resin solution, wherein the content of ultraviolet fluorescence powder is the 0.15% of entire warm changing resin, the uniform liquid material of formation；
Step 2, the preparation of the antibacterial material for antibacterial layer, includes the following steps：
1. 500ml deionized waters are added in separatory funnel, 3g (NH are weighed2)2CO and 3.0g PVP are added to above-mentioned liquid separation leakage
In bucket, 1.5g KCl are added, after shaking 10min, AgNO is slowly added dropwise to it using long-neck dropper3Solution, after shaking 10min,
A certain amount of TiO is added dropwise2Solution liquid adds suitable ZnSO45ml is added in solution, 80 DEG C of water-bath 3h postcoolings to room temperature
Na2HPO4Solution shakes 30min；
2. the anhydrous C of 10ml are added2H5OH shakes 30min；With traditional vacuum, precipitation uses distilled water, acid solution, anhydrous successively
C2H5OH is washed；Precipitation is put into electric drying oven with forced convection drying；
3. by dry powder it is ground be made to be put into Muffle furnace after loose powder be calcined, after be down to room naturally
Temperature；Ground after calcination can be prepared by Nano- antibacterial materials；
Step 3, the preparation of light-sensitive material, includes the following steps：
1. a certain amount of styrene monomer is dissolved into anhydrous C2H5OH and H2In O mixed solutions, 60 DEG C are heated to, constant temperature is protected
30min is held, is again heated to 90 DEG C, constant temperature keeps 30min, so that PVP is fully dissolved, Na is then added2S2O8Solution reacts 5h, instead
It is centrifuged after answering, polystyrene microsphere is obtained after dry；Wherein, anhydrous C2H5OH and H2The volume ratio of O is 55:
45；
2. weighing a certain amount of polystyrene microsphere is added to certain density C8H4O3In solution, N2Protection, while stirring
AlCl is added3, 55 DEG C are reacted 12h, obtain surface-modified polystyrene microspheres；
3. surface-modified polystyrene microspheres are put into N- ethoxy -3,3- dimethyl -6- nitroindoline quinoline spiro-pyrans second
Absorption 12h is carried out in alcoholic solution, is then centrifuged for detaching, and photosensitive microballoon is made through dry, obtained photosensitive microballoon is added to
It is impregnated in certain density poly-vinyl alcohol solution for 24 hours, centrifugation, which is placed in anhydrous C2H5OH, to be disperseed, and is centrifuged, dry；
4. the PVA@polyethylene microballoons after drying are put into SnO248h is impregnated in solution, is then drying to obtain for 80 DEG C；
Step 4, the preparation of the antibacterial tunic of photo-thermal：
According to 2~4:1~2:2~5 mass ratio claims to take respectively in right amount via the thermochromatic material prepared by step 1, step
The light-sensitive material prepared by antibacterial material and step 3 prepared by rapid two；It is molten that thermochromic material is dissolved in methyl ethyl ketone
In liquid, uniform I solution is formed, stirring 90 minutes is spare；Antibacterial material is dissolved in methyl ethyl ketone solution, is formed uniform
II solution, stirring 120 minutes it is spare；Light-sensitive material is dissolved in phenylmethane solution, uniform III solution is formed, stirs
Mix 180 minutes it is spare；It by I solution coatings and forms a film on aluminium layer naturally, dry 8 in negative pressure 0.1~0.5MPa vacuum drying chambers
Hour, obtain the thermochromic layer of appearance uniform；By II solution coatings and form a film on thermochromic layer naturally, negative pressure 0.2~
It is 10 hours dry in 0.3MPa vacuum drying chambers, it is irradiated 2 hours as under 60Co rays after taking-up, obtains the thermotropic of appearance uniform
The antibacterial capsule layer of photochromic layer-；It forms a film III solution coatings and naturally on antibacterial capsule layer, is dried in vacuo 24 hours, obtain outer
See the antibacterial capsule layer of uniform thermochromic layer-- photosensitive microballoon layer, the i.e. antibacterial tunic of photo-thermal.
Further, the thickness of the thermochromic layer 12 is 20~60nm；The thickness of the antibacterial layer 13 is 50nm；It is described
The thickness of photosensitive layer 14 is 65nm.
Further, the antibacterial tunic of the photo-thermal further includes one layer of light-absorption layer, and the light-absorption layer is painted on the photosensitive layer
14 tops.
Further, the substrate layer 10 is garment body 1.
The photic phenomenon of intelligent color-changing clothes of the present invention is detected：The detection for carrying out Ultraluminescence, is adopted
It is detected with the ultraviolet lamp on cash inspecting machine；Using sunlight irradiation, Indoor Natural light.
1 experimental result of table
| Type of wavelength | Color |
| Dark condition | Pink |
| Sunlight | Purple |
| Indoor conditions | Lilac |
| Ultraviolet lamp | It is red |
Intelligent color-changing clothes of the present invention shows pink under the conditions of darkness, the photosensitive microballoon under sunlight
Layer color changes, and shows purple, shows lilac in room conditions.Under ultra violet lamp, color is red.
Further, the denaturation of the Reversible temperature of intelligent color-changing clothes of the present invention is detected：It directly will be certain
The hot water of temperature is splashed on the intelligent color-changing clothes of the present invention, and the color of intelligent color-changing clothes of the present invention is vertical
Quarter changes, and becomes very shallow blue or almost colourless from navy blue, is then then restored to initial navy blue quickly.This
Kind detection method is very convenient, as long as splashing not only fast with hot water at one's side but also intuitively detecting, significantly facilitates this
The detection of the invention intelligent color-changing clothes, has widened its application range.
2 thermotropic experimental result of table
In 65 DEG C~68 DEG C of temperature, color change is most apparent, intelligent color-changing clothes from blue become very shallow blue or
Almost colourless, it is very high to become chromatic sensitivity, encounters temperature and reaches the hot water of minimum temperature or more and changes colour at once, recovery time section, about
4s is then restored to priming color.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected
The limitation of range is protected, although being explained in detail to the present invention with reference to preferred embodiment, those skilled in the art answer
Work as understanding, technical scheme of the present invention can be modified or replaced equivalently, without departing from the reality of technical solution of the present invention
Matter and range.
Claims (3)
1. a kind of intelligent color-changing clothes, including garment body (1), which is characterized in that the anterior part of chest (2) of the garment body (1),
The antibacterial layer of photo-thermal discoloration (8) is coated at sleeve arm (3) and waist and belly position；
Temperature sense discoloration layer；Photoinduction discoloration layer (8) is coated at the waist and belly (8) of the garment body (1)；
The antibacterial layer of photo-thermal discoloration (8) from bottom to up successively include substrate layer (10), aluminium layer (11), thermochromic layer (12),
Antibacterial layer (13) and photosensitive layer (14)；The substrate layer (10) supports other each layers, aluminium layer (11) to increase the gold of substrate layer (10)
Belong to gloss, thermochromic layer (12) makes fungi-proofing color-changing membrane that thermochromism occur, and antibacterial layer (13) blocking bacterium enters the suppression of photo-thermal discoloration
Bacterium layer (8), photosensitive layer (14) make the antibacterial layer of photo-thermal discoloration (8) that Ultraluminescence discoloration occur；
The preparation process of the antibacterial layer of photo-thermal discoloration (8) is as follows：The aluminium coated (11) on substrate layer (10) coats heat on aluminium layer (11)
Photochromic layer (12), is coated with antibacterial layer (13) on thermochromic layer (12), coating photosensitive layer (14) on antibacterial layer (13)；
The preparation method of the antibacterial layer of photo-thermal discoloration (8) is as follows：
Step 1, the preparation of the thermochromatic material for thermochromic layer, includes the following steps：
First, it is 350 according to mass ratio:2.3:4:40:80 weigh respectively 2- butanone, ultraviolet fluorescence powder, 2,2- it is bis- to phenol propane,
CVL, granules of polystyrene；
Second, it sequentially adds in the order described above at 30 DEG C and forms uniform liquid in flask, stir and form within 180 minutes warm changing resin
Solution, wherein the content of ultraviolet fluorescence powder is the 0.15% of entire warm changing resin, the uniform liquid material of formation；
Step 2, the preparation of the antibacterial material for antibacterial layer, includes the following steps：
1. 500ml deionized waters are added in separatory funnel, weigh 3g (NH2) 2CO and 3.0g PVP and be added to above-mentioned separatory funnel
In, 1.5g KCl are added, after shaking 10min, AgNO3 solution is slowly added dropwise to it using long-neck dropper, after shaking 10min, drop
Add a certain amount of TiO2 solution liquid, add suitable ZnSO4 solution, 5ml is added in 80 DEG C of water-bath 3h postcoolings to room temperature
Na2HPO4 solution shakes 30min；
2. the anhydrous C2H5OH of 10ml, which are added, shakes 30min；With traditional vacuum, precipitation uses distilled water, acid solution, anhydrous C2H5OH successively
Washing；Precipitation is put into electric drying oven with forced convection drying；
3. by dry powder it is ground be made to be put into Muffle furnace after loose powder be calcined, after be down to room temperature naturally；
Ground after calcination can be prepared by Nano- antibacterial materials；
Step 3, the preparation of light-sensitive material, includes the following steps：
1. a certain amount of styrene monomer is dissolved into anhydrous C2H5OH and H2O mixed solutions, 60 DEG C are heated to, constant temperature is kept
30min is again heated to 90 DEG C, and constant temperature keeps 30min, and PVP is made fully to dissolve, and Na2S2O8 solution is then added, and reacts 5h, instead
It is centrifuged after answering, polystyrene microsphere is obtained after dry；Wherein, the volume ratio of anhydrous C2H5OH and H2O is 55:
45；
2. weighing a certain amount of polystyrene microsphere to be added in certain density C8H4O3 solution, N2 protections add while stirring
Enter AlCl3,55 DEG C of reaction 12h obtain surface-modified polystyrene microspheres；
3. it is molten that surface-modified polystyrene microspheres are put into N- ethoxy -3,3- dimethyl -6- nitroindoline quinoline spiro-pyrans ethyl alcohol
Absorption 12h is carried out in liquid, is then centrifuged for detaching, and photosensitive microballoon is made through dry, obtained photosensitive microballoon is added to centainly
It is impregnated in the poly-vinyl alcohol solution of concentration for 24 hours, centrifugation, which is placed in anhydrous C2H5OH, to be disperseed, and is centrifuged, dry；
4. the PVA@polyethylene microballoons after drying are put into SnO2 solution and impregnate 48h, then it is drying to obtain for 80 DEG C；
Step 4, the preparation of the antibacterial tunic of photo-thermal：
According to 2~4:1~2:2~5 mass ratio claims to take respectively in right amount via the thermochromatic material prepared by step 1, step 2
Light-sensitive material prepared by prepared antibacterial material and step 3；Thermochromic material is dissolved in methyl ethyl ketone solution
In, form uniform I solution, stirring 90 minutes is spare；Antibacterial material is dissolved in methyl ethyl ketone solution, is formed uniform
II solution, stirring 120 minutes it is spare；Light-sensitive material is dissolved in phenylmethane solution, uniform III solution is formed, is stirred
180 minutes spare；It by I solution coatings and forms a film on aluminium layer naturally, dry 8 is small in negative pressure 0.1~0.5MPa vacuum drying chambers
When, obtain the thermochromic layer of appearance uniform；By II solution coatings and form a film on thermochromic layer naturally, negative pressure 0.2~
It is 10 hours dry in 0.3MPa vacuum drying chambers, it is irradiated 2 hours as under 60Co rays after taking-up, obtains the thermotropic of appearance uniform
The antibacterial capsule layer of photochromic layer-；It forms a film III solution coatings and naturally on antibacterial capsule layer, is dried in vacuo 24 hours, obtain outer
See the antibacterial capsule layer of uniform thermochromic layer-- photosensitive microballoon layer, the i.e. antibacterial tunic of photo-thermal.
2. a kind of intelligent color-changing clothes according to claim 1, which is characterized in that the thickness of the thermochromic layer (12) is
20~60nm；The thickness of the antibacterial layer (13) is 50nm；The thickness of the photosensitive layer (14) is 65nm.
3. a kind of intelligent color-changing clothes according to claim 2, which is characterized in that the antibacterial tunic of photo-thermal (8) is also wrapped
One layer of light-absorption layer is included, the light-absorption layer is painted on above the photosensitive layer (14).
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0645489A1 (en) * | 1993-09-16 | 1995-03-29 | Matsui Shikiso Chemical Co., Ltd | Multiple-colored textile products |
| CN101779834A (en) * | 2010-03-12 | 2010-07-21 | 上海工程技术大学 | Environment-friendly garment |
| CN103859665A (en) * | 2012-12-13 | 2014-06-18 | 天津市涵基商贸有限公司 | Novel clothes fabric |
| CN205018317U (en) * | 2015-06-23 | 2016-02-10 | 徐任飞 | Clothing with pattern discolours |
| CN105876952A (en) * | 2014-10-13 | 2016-08-24 | 宁波六艺服饰设计有限公司 | Color changing garment |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10112122C1 (en) * | 2001-03-14 | 2002-10-24 | Deotexis Inc | Textile material for clothing |
-
2017
- 2017-03-06 CN CN201710129286.7A patent/CN106889661B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0645489A1 (en) * | 1993-09-16 | 1995-03-29 | Matsui Shikiso Chemical Co., Ltd | Multiple-colored textile products |
| CN101779834A (en) * | 2010-03-12 | 2010-07-21 | 上海工程技术大学 | Environment-friendly garment |
| CN103859665A (en) * | 2012-12-13 | 2014-06-18 | 天津市涵基商贸有限公司 | Novel clothes fabric |
| CN105876952A (en) * | 2014-10-13 | 2016-08-24 | 宁波六艺服饰设计有限公司 | Color changing garment |
| CN205018317U (en) * | 2015-06-23 | 2016-02-10 | 徐任飞 | Clothing with pattern discolours |
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