CN106852337A - A kind of Pesticidal combination of the nitrile of worm containing acetyl and sulfoxaflor - Google Patents
A kind of Pesticidal combination of the nitrile of worm containing acetyl and sulfoxaflor Download PDFInfo
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- CN106852337A CN106852337A CN201510902348.4A CN201510902348A CN106852337A CN 106852337 A CN106852337 A CN 106852337A CN 201510902348 A CN201510902348 A CN 201510902348A CN 106852337 A CN106852337 A CN 106852337A
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- sulfoxaflor
- nitrile
- acetyl
- worm
- worm nitrile
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Abstract
The invention discloses a kind of nitrile of worm containing acetyl and the Pesticidal combination of sulfoxaflor, effective active composition is acetyl worm nitrile and sulfoxaflor, and the weight ratio of acetyl worm nitrile and sulfoxaflor is the ︰ 1 of 1 ︰ 80~80.The present composition has synergistic effect to the various pests for endangering agricultural production, reduces pesticide usage amount, reduces residual quantity of the agricultural chemicals on crop, alleviates environmental pollution, and to person poultry safety, Environmental compatibility is good, and insect is not likely to produce the resistance to the action of a drug.
Description
Technical field
The invention belongs to technical field of pesticide, it is related to a kind of nitrile of worm containing acetyl and sulfoxaflor
Application of the Pesticidal combination on crop pests.
Background technology
Acetyl worm nitrile：Molecular formula：C13H10Cl2F3N3O2S, acetyl worm nitrile is a wide spectrum
Insecticide, its insecticidal mechanism is the chlorine for hindering insect GABA (GABA) control
Compound is metabolized.
Sulfoxaflor：The nervous system of insect is acted on, that is, is acted in choline receptor solely
Special binding site and play insecticidal function.Can be absorbed through leaf, stem, root and enter plant
It is interior.Sulfoxaflor is applied to prevents and treats cotton fleahopper, aphid, aleyrodid, plant hopper and coccid
Deng；Efficiently, the quick and longevity of residure is long, can effectively prevent and treat to nicotinoids, chrysanthemum esters, has
Phosphorus and carbamate chemicals for agriculture generation resistance the suction juice class pest of machine.To non-target segmental appendage
Animal toxicity is low, is integrated pest control preferred agents.
But in the real process of agricultural production, pest control is easiest to generate the problem that
The generation of pest resistance to insecticide.Different cultivars composition is compounded, and is that preventing and treating resistant insect is very normal
The method seen.Heterogeneity is compounded, and judges that certain is answered according to practical application effect
Be synergy, plus and or antagonism.In most cases, the compounding effect of agricultural chemicals
All it is additive effect, really has the compounding of synergistic effect seldom, especially synergistic effect is very
Substantially, co-toxicity coefficient compounding very high is just less.Studied by inventor, found second
The relevant report of acyl worm nitrile and sulfoxaflor compounding is not yet disclosed.
The content of the invention
Have that synergistic function, use cost be low, preventive effect the purpose of the present invention is to propose to one kind
The good nitrile of worm containing acetyl and the Pesticidal combination of sulfoxaflor.
The Pesticidal combination of the nitrile of worm containing acetyl proposed by the present invention and sulfoxaflor, acetyl worm nitrile
It is the ︰ 1 of 1 ︰ 80~80 with sulfoxaflor weight ratio, acetyl worm nitrile and sulfoxaflor are preferred
Weight ratio is the ︰ 1 of 1 ︰ 40~40；The weight ratio of more preferably acetyl worm nitrile and sulfoxaflor is
20:1~1:20.
The Pesticidal combination of the nitrile of worm containing acetyl proposed by the present invention and sulfoxaflor is used to prevent and treat
The purposes of insect on crops, described crops include cereal crops, legume crop, fibre
Dimension crop, sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop,
Root crop, oil crops, flower crop, medicinal crop, crop, green manure herbage
Crop；Described insect be beetle, leafhopper, aphid, aleyrodid, beet armyworm, diamondback moth,
Rice leaf roller, striped rice borer, yellow rice borer, fleahopper, plant hopper or scale insect.
The weight ratio of acetyl worm nitrile and sulfoxaflor is the ︰ 1 of 1 ︰ 80~80.In usual composition
The weight percentage of active component for gross weight 0.5%~90%, preferably 5%~
80%.According to different preparation types, active component content scope is different.Generally, liquid
Body preparation contains by weight 1%~70% active material, preferably 5%~50%；Gu
Body preparation contains by weight 5%~80% active material, preferably 10%~80%.
At least contain a kind of surfactant in Pesticidal combination of the invention, be beneficial to when applying
Dispersion of the active component in water.Surface-active contents are the 5%~30% of total formulation weight,
Balance of solid or liquid diluent.
Pesticidal combination of the invention can by user using it is preceding through dilute or directly use.
Its preparation can be prepared by common processing method known in those skilled in the art, will activity
After material mixes with liquid flux or solid carrier, surfactant such as dispersant, steady is added
Determine one or more in agent, wetting agent, binding agent, defoamer, disintegrant, antifreeze etc..
Pesticidal combination of the invention, can be processed into acceptable dose on any agricultural chemicals on demand
Type, wherein more preferably formulation be wettable powder, water dispersible granules, suspending agent, suspension emulsion,
Aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, can also be made effervesce
Tablet, seed coat agent, ultra-low-volume formulation, aqua, soluble liquid, soluble powder, hot mist
Agent.
Composition is when being made wettable powder comprising following constituent content：Acetyl worm nitrile 0.1%~
80%th, sulfoxaflor 0.1%~80%, dispersant 2%~10%, wetting agent 2%~10%,
Filler surplus.
Composition includes following constituent content when being made water dispersible granules：Acetyl worm nitrile 0.1%~
80%th, sulfoxaflor 0.1%~80%, dispersant 3%~12%, wetting agent 1%~8%, collapse
Solution agent 1%~10%, binding agent 0~8%, filler surplus.
Composition includes following constituent content when being made suspending agent：Acetyl worm nitrile 0.1%~50%,
Sulfoxaflor 0.1%~50%, dispersant 2%~10%, wetting agent 2%~10%, defoamer
0.01%~2%, thickener 0~2%, antifreeze 0~8%, deionized water add to 100%.
Composition includes following constituent content when being made suspension emulsion：Acetyl worm nitrile 0.1%~50%,
Sulfoxaflor 0.1%~50%, dispersant 2%~10%, defoamer 0.01%~2%, solvent
1%~15%, thickener 0~2%, emulsifying agent 2%~12%, antifreeze 0~8%, deionized water
Add to 100%.
Composition is when being made aqueous emulsion comprising following constituent content：Acetyl worm nitrile 0.1%~50%,
Sulfoxaflor 0.1%~50%, solvent 1%~30%, emulsifying agent 1%~15%, antifreeze 0~8%,
Thickener 0~2%, defoamer 0.01%~2%, deionized water supply surplus.
Composition includes following constituent content when being made microcapsule suspending agent：Acetyl worm nitrile
0.1%~50%, sulfoxaflor 0.1%~50%, macromolecule cyst material 2%~10%, dispersion
Agent 1%~10%, organic solvent 1%~10%, defoamer 0.01%~2%, emulsifying agent 1%~7%,
PH adjusting agent 0.01%~5%, deionized water adds to 100%.
Composition includes following constituent content when being made microcapsule suspension-suspendinagent agent：Acetyl worm nitrile
0.1%~50%, sulfoxaflor 0.1%~50%, macromolecule cyst material 2%~10%, dispersion
Agent 1%~12%, wetting agent 1%~8%, organic solvent 1%~15%, emulsifying agent 1%~6%,
Defoamer 0.01%~2%, thickener 0~2%, pH adjusting agent 0.01%~5%, deionized water
Add to 100%.
Wettable powder the key technical indexes of the invention：
Water dispersible granules the key technical indexes of the invention：
Suspending agent the key technical indexes of the invention：
Suspension emulsion the key technical indexes of the invention：
Aqueous emulsion the key technical indexes of the invention：
Microcapsule suspending agent the key technical indexes of the invention：
Microcapsule suspension-suspendinagent agent the key technical indexes of the invention：
The advantage of the invention is that：
(1) after acetyl worm nitrile is compounded with sulfoxaflor, with obvious synergy and lasting effect；
(2) to cereal crops, legume crop, fibre crops, sugar crop, melon crop, water
Orchard crop, dry fruit crop, hobby crop, root crop, oil crops, flowers make
Thing, medicinal crop, crop, green manure pasture crop insect have greater activity；(3) subtract
Lack pesticide usage amount, reduced residual quantity of the agricultural chemicals on crop, alleviate environmental pollution；
(4) to person poultry safety, Environmental compatibility is good；And preparation adhesion strength strengthens, resistance to rainwater punching
Brush.
Specific embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is
Percentage by weight, but the invention is not limited in this.
Application Example one
The wettable powder of embodiment 1~4
Acetyl worm nitrile, sulfoxaflor, dispersant, wetting agent, filler are mixed in mixed cylinder
Close uniform, remixed after being crushed through airslide disintegrating mill uniform, you can be obtained it is of the present invention can
WP product, is specifically shown in Table 1.
The each component of 1 embodiment of table 1~4 and weight portion
The water dispersible granules of embodiment 5~8
By acetyl worm nitrile, sulfoxaflor, dispersant, wetting agent, disintegrant, filler etc.
Play the particle diameter that is needed through air-flow crushing, add binding agent (can add to be not added with) etc. other
Auxiliary agent, obtains materials of pelletizing.Item is quantitatively sent into fluidized bed granulating dryer by granulation
And after drying, you can water dispersible granules product of the present invention is obtained, 2 are specifically shown in Table.
The each component of 2 embodiment of table 5~8 and weight portion
The suspending agent of embodiment 9~12
By dispersant, wetting agent, defoamer, thickener (can add to be not added with), antifreeze (can
Plus can be not added with), it is well mixed by high speed shear, acetyl worm nitrile, sulfoxaflor are added,
Ball milling 2~3 hours in ball mill, make diameter of particle all below 5 μm, and surplus spends
Ionized water is supplied, you can suspending agent product of the present invention is obtained, 3 are specifically shown in Table.
The each component of 3 embodiment of table 9~12 and weight portion
The suspension emulsion of embodiment 13~15
By dispersant, defoamer, thickener (can add to be not added with), (can add can for antifreeze
It is not added with) it is well mixed by high speed shear, add sulfoxaflor, the ball milling in ball mill
2~3 hours, make diameter of particle all below 5 μm, sulfoxaflor suspending agent is obtained, so
Afterwards by acetyl worm nitrile, solvent (can add to be not added with), emulsifying agent and various auxiliary agent high-speed stirrings
Mix device directly to emulsify in suspending agent, surplus is supplied with deionized water, be obtained of the present invention
Suspension emulsion product, be specifically shown in Table 4.
The each component of 4 embodiment of table 13~15 and weight portion
The aqueous emulsion of embodiment 16~18
Acetyl worm nitrile, sulfoxaflor, solvent, emulsifying agent are added together, make to be dissolved into
Even oil phase；By deionized water, antifreeze (can add to be not added with), thickener (can add to be not added with),
Defoamer is mixed, into homogeneous water phase.Under high velocity agitation, water is added to oil phase,
Surplus is supplied with deionized water；Aqueous emulsion product of the present invention is can be prepared by, is specifically shown in Table
5。
The each component of 5 embodiment of table 16~18 and weight portion
The microemulsion of embodiment 19~21
Acetyl worm nitrile, sulfoxaflor are dissolved in the homogenizer equipped with solvent, by emulsifying agent,
Antifreeze (can add to be not added with), defoamer are added in the homogenizer equipped with above-mentioned solution, remaining
Amount deionized water mixes and homogenizes strongly after supplying, and finally obtains clear appearance transparent
Microemulsion product of the present invention, is specifically shown in Table 6.
The each component of 6 embodiment of table 19~21 and content
Embodiment 22,23 microcapsule suspending agents
Acetyl worm nitrile, sulfoxaflor, macromolecule cyst material, solvent, defoamer are mixed,
Make to be dissolved into homogeneous oil phase, in a shear condition, oil phase is added to and contains emulsifying agent, pH
In conditioning agent, the aqueous phase solution of dispersant, surplus is supplied with deionized water, and two kinds of materials are in oil
Water termination reacts, and forms high score ascus wall, is made well dispersed micro- of the present composition
Capsule suspending agent product, is specifically shown in Table 7.
The embodiment 22 of table 7,23 each components and weight portion
Embodiment 24,25 microcapsule suspension-suspendinagent agents
Acetyl worm nitrile, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase,
During oil phase is added in a shear condition containing emulsifying agent, the aqueous phase solution of pH adjusting agent,
It is made well dispersed microcapsule suspending agent.By dispersant, wetting agent, defoamer, thickener (can
Plus can be not added with) well mixed by high speed shear, add sulfoxaflor, the ball in ball mill
Mill 2~3 hours, makes diameter of particle all below 5 μm, and suspending agent is obtained, then will be outstanding
Floating agent is added in the aqueous phase solution of micro-capsule suspension, and deionized water supplies surplus, is made this
The well dispersed microcapsule suspension-suspendinagent agent product of inventive composition, is specifically shown in Table 8.
The embodiment 24 of table 8,25 each components and weight portion
The embodiment of the present invention is the method being combined using Toxicity Determination and field test.First
By Toxicity Determination, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient
(CTC), CTC ＜ 80 are antagonism, and 80≤CTC≤120 are summation action, CTC
＞ 120 is synergistic effect, on this basis, then carries out field test.
Test method：The mother liquor of each mixed agent is diluted to five series concentrations respectively during experiment,
It is respectively placed in standby in beaker.Using the method that first leaching leaf is followed by worm, will be not in contact with any medicament
Blade of the same size 5s is soaked in the liquid for having configured after take out, dry naturally, put
Enter in insect box, then connect for examination larva, raised under the conditions of 25 DEG C, often process 3 times
Repeat, often repeat test worm number used for 50, while setting blank, check dead in 72h
Borer population, calculates the death rate and corrected mortality, tries to achieve virulence regression equation and calculates LC50Value.
If the control death rate is more than 10%, it is considered as invalid experiment.Computing formula is as follows：
Insect corrected mortality is converted into probit value (y), concentration for the treatment of (μ g/ml) is converted into
Logarithm value (x), virulence regression equation is drawn with least square method, and thus calculates every kind of medicine
The value of agent, co-toxicity coefficient CTC is calculated according to the abundant equations of Sun Yun.Computing formula it is following (with
Acetyl worm nitrile is standard agent, and its toxicity index is for 100)：
TI × the P of the theoretical toxicity index (TTI) of M=acetyl worm nitrileAcetyl worm nitrile+Sulfoxaflor
TI × PSulfoxaflor
In formula：M is the mixture of different ratio
PSulfoxaflorIt is sulfoxaflor ratio shared in the composition
PAcetyl worm nitrileIt is acetyl worm nitrile ratio shared in the composition
Application Example two：
For examination insect：Cotton aphid
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：By pilot study determine acetyl worm nitrile and sulfoxaflor active compound and the two
Effective lethasl concentration scope of different ratio mixture.
Toxicity test result
The acetyl worm nitrile of table 9 compounds the toxicity test analysis of results table to cotton aphid with sulfoxaflor
As shown in Table 9, acetyl worm nitrile is matched in 1 ︰ 80~80 with sulfoxaflor to cotton aphid
During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of the ︰ 1 of 1 ︰ 80~80
Synergistic effect is shown, when the proportioning of acetyl worm nitrile and sulfoxaflor is 1：20~20：1
When, synergistic effect becomes apparent protruding, and co-toxicity coefficient is all higher than 230.Tested through applicant and sent out
Existing acetyl worm nitrile is 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ with the optimum ratio of sulfoxaflor
1st, 16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8
︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,2:3rd, 1 ︰ 2,1
︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,
1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein
When acetyl worm nitrile and sulfoxaflor weight ratio are 2：Co-toxicity coefficient is maximum when 3, synergistic effect
The most substantially, to the beetle in various crop, leafhopper, aphid, aleyrodid, beet armyworm, small
The preventing and treating of diamond-back moth, rice leaf roller, striped rice borer, yellow rice borer, fleahopper, plant hopper or scale insect
There is obvious synergistic effect, co-toxicity coefficient is more than 120.
Effect experiment part：Test medicine is researched and developed by Shaanxi Welch Crop Protection Co., Ltd., carried
For acetyl worm nitrile suspending agent (autogamy) of comparison medicament 10%, 50% sulfoxaflor moisture dissipate
Granula (purchased in market).
Application Example triacetyl worm nitrile and sulfoxaflor and its compounding preventing and treating cabbage aphid drug effect
Experiment
This test arrangement is investigated cabbage aphid insect pest and is referred in Shaanxi Province Weinan City Dali County, before medicine
Number, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest index in 10 days, 20 days
And calculate preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 10 and sulfoxaflor and its compounding preventing and treating cabbage aphid test of pesticide effectiveness
As can be seen from Table 10, can effectively prevent and treat sweet after acetyl worm nitrile and sulfoxaflor compounding
Blue aphid, proves that acetyl worm nitrile can also be effective after being compounded with sulfoxaflor through inventor's experiment
Preventing and treating cabbage flea beetle, diamondback moth, prevention effect is above 96%, better than the preventive effect of single dose,
And preventive effect phase is long.Target crop is had no adverse effects in experiment scope of medication.
The acetyl worm nitrile of Application Example four prevents and treats rice hoppers medicine with sulfoxaflor and its compounding
Effect experiment
This test arrangement is investigated rice hoppers insect pest and is referred in Shaanxi Province Hanzhong suburban area, before medicine
Number, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest index in 10 days, 20 days
And calculate preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 11 prevents and treats the rice hoppers test of pesticide effectiveness with sulfoxaflor and its compounding
As can be seen from Table 11, can effectively prevent harnessing the river after acetyl worm nitrile and sulfoxaflor compounding
Rice planthopper, proves that acetyl worm nitrile can also have after being compounded with sulfoxaflor through inventor's experiment
Effect preventing and treating rice-stem borer, yellow rice borer, rice leaf roller, prevention effect are above 96%,
Better than the preventive effect of single dose, and preventive effect phase is long.To target crop without bad in experiment scope of medication
Influence.
The acetyl worm nitrile of Application Example five and sulfoxaflor and its compounding preventing and treating brassicaceous vegetable
The diamondback moth test of pesticide effectiveness
This test arrangement investigates brassicaceous vegetable pickles in Shaanxi Province Hanzhong suburban area before medicine
Moth insect pest index, in insect pest early period of origination dispenser, 3 days after dispenser, investigates for 10 days, 20 days
Insect pest index simultaneously calculates preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 12 and sulfoxaflor and its compounding preventing and treating brassicaceous vegetable diamondback moth test of pesticide effectiveness
As can be seen from Table 12, ten can effectively be prevented and treated after acetyl worm nitrile and sulfoxaflor compounding
Zi Hua sections vegetables diamondback moth, after proving that acetyl worm nitrile is compounded with sulfoxaflor through inventor's experiment
Brassicaceous vegetable aphid can also be effectively prevented and treated, prevention effect is above 96%, better than list
The preventive effect of agent, and preventive effect phase is long.Target crop is had no adverse effects in experiment scope of medication.
The acetyl worm nitrile of Application Example six and sulfoxaflor and its compounding preventing and treating cucumber aleyrodid drug effect
Experiment
This test arrangement is investigated cucumber powder mite evil in Shaanxi Province Weinan City Dali County, before medicine and is referred to
Number, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest index in 10 days, 20 days
And calculate preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 13 and sulfoxaflor and its compounding preventing and treating cucumber aleyrodid test of pesticide effectiveness
As can be seen from Table 13, can effectively anti-Yellow River harnessing after acetyl worm nitrile and sulfoxaflor compounding
Melon aleyrodid, proves that acetyl worm nitrile can also be effective after being compounded with sulfoxaflor through inventor's experiment
Preventing and treating Cucumber blight, prevention effect is above 96%, better than the preventive effect of single dose, and preventive effect phase
It is long.Target crop is had no adverse effects in experiment scope of medication.
Drawn by the experiment of different places throughout the country afterwards, acetyl worm nitrile and sulfoxaflor
After compounding to the beetle in various crop, leafhopper, aphid, aleyrodid, beet armyworm, diamondback moth,
The common insect pests such as rice leaf roller, striped rice borer, yellow rice borer, fleahopper, plant hopper or scale insect it is anti-
More than 96%, better than single dose preventive effect, synergistic effect is obvious for effect.
Claims (6)
1. the Pesticidal combination of a kind of nitrile of worm containing acetyl and sulfoxaflor, it is characterised in that：
Active ingredient is the weight ratio of acetyl worm nitrile and sulfoxaflor, acetyl worm nitrile and sulfoxaflor
It is the ︰ 1 of 1 ︰ 80~80.
2. Insecticidal combinations of the nitrile of worm containing acetyl according to claim 1 and sulfoxaflor
Thing, it is characterised in that：The weight ratio of acetyl worm nitrile and sulfoxaflor is the ︰ 1 of 1 ︰ 40~40.
3. Insecticidal combinations of the nitrile of worm containing acetyl according to claim 2 and sulfoxaflor
Thing, it is characterised in that：The weight ratio of acetyl worm nitrile and sulfoxaflor is 20:1~1:20.
4. the nitrile of worm containing acetyl according to any one of claim 1 to 3 and flonicamid
The Pesticidal combination of nitrile, it is characterised in that：Composition be made wettable powder, water dispersible granules,
Suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent,
Thermal fog, ultra-low-volume formulation.
5. Insecticidal combinations of the nitrile of worm containing acetyl according to claim 4 and sulfoxaflor
Thing is used to prevent and treat the purposes of insect on crops.
6. purposes according to claim 5, it is characterised in that：Described insect is first
Worm, leafhopper, aphid, aleyrodid, beet armyworm, diamondback moth, rice leaf roller, striped rice borer,
Yellow rice borer, fleahopper, plant hopper or scale insect.
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| CN201510902348.4A CN106852337A (en) | 2015-12-09 | 2015-12-09 | A kind of Pesticidal combination of the nitrile of worm containing acetyl and sulfoxaflor |
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Citations (3)
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| CN102017978A (en) * | 2011-01-07 | 2011-04-20 | 陕西上格之路生物科学有限公司 | Pesticidal composition containing Sulfoxaflor and butene-fipronil |
| CN102271512A (en) * | 2008-12-29 | 2011-12-07 | 拜耳作物科学公司 | Treatment of transgenic crops with mixtures of fiproles and chloronicotinyls |
| CN103755487A (en) * | 2013-12-31 | 2014-04-30 | 灵川县金田农资经营部 | Biogas slurry compound insecticide for preventing and treating aphid |
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- 2015-12-09 CN CN201510902348.4A patent/CN106852337A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102271512A (en) * | 2008-12-29 | 2011-12-07 | 拜耳作物科学公司 | Treatment of transgenic crops with mixtures of fiproles and chloronicotinyls |
| CN102017978A (en) * | 2011-01-07 | 2011-04-20 | 陕西上格之路生物科学有限公司 | Pesticidal composition containing Sulfoxaflor and butene-fipronil |
| CN103755487A (en) * | 2013-12-31 | 2014-04-30 | 灵川县金田农资经营部 | Biogas slurry compound insecticide for preventing and treating aphid |
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Application publication date: 20170616 |
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