CN106758496A - A kind of release tissue paper of Antimicrobial preservative and preparation method thereof - Google Patents
A kind of release tissue paper of Antimicrobial preservative and preparation method thereof Download PDFInfo
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- CN106758496A CN106758496A CN201611144951.1A CN201611144951A CN106758496A CN 106758496 A CN106758496 A CN 106758496A CN 201611144951 A CN201611144951 A CN 201611144951A CN 106758496 A CN106758496 A CN 106758496A
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- slurries
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
- D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
- D21H15/10—Composite fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/02—Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1084—Bleaching ; Apparatus therefor with reducing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/08—Mechanical or thermomechanical pulp
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/10—Phosphorus-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/25—Cellulose
- D21H17/26—Ethers thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
- D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/38—Corrosion-inhibiting agents or anti-oxidants
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/52—Addition to the formed paper by contacting paper with a device carrying the material
- D21H23/64—Addition to the formed paper by contacting paper with a device carrying the material the material being non-fluent at the moment of transfer, e.g. in form of preformed, at least partially hardened coating
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
Abstract
The present invention discloses a kind of release tissue paper of Antimicrobial preservative, it is made up of the raw material of following weight portion, including 200 300 parts of bamboo bar, 130 190 parts of softwood pulp, 100 160 parts of wheat straw, 50 80 parts of organosilicon quaternary phosphonium salt, 40 80 parts of gelatin, modified 20 38 parts of 50 90 parts of tapioca starch, 20 36 parts of carboxymethylcellulose calcium, 30 46 parts of talcum powder, 21 37 parts of paraffin, 40 60 parts of acrylic resin, 12 26 parts of carbonate group, 68 parts of toluene, 30 60 parts of sodium sulfite, 20 38 parts of ammonium hydroxide and potassium hydroxide；This kind of release tissue paper thickness of thin of Antimicrobial preservative and uniform, water absorbing properties are good, not perishable breed bacteria, and pliability is good.
Description
Technical field
The present invention relates to release tissue paper of a kind of Antimicrobial preservative and preparation method thereof.
Background technology
With social development and the raising of living standards of the people, people increasingly pay attention to own health, to living environment
It is required that also improving constantly.However, large-scale outbreak by invasive organism propagates the infectious disease that causes in recent years, such as South Korea
Middle East respiration syndrome (MERS), the Ebola hemorrhagic fever in Africa, the bird flu in Southeast Asia, the SARS in Asia, the EHEC of Germany
Acute intestinal disorders etc., seriously threaten health caused by antibiotic-resistant bacterium, cause great economic loss.Cause
This, the various materials with anti-bacteria and anti-virus function arise at the historic moment, and particularly closely related with people's life is anti-with antibacterial
The research and development of the daily necessities of viral performance are increasingly subject to pay attention to.Face tissue, volume always and everywhere can be all used as people
The life tissue paper such as coil paper, paper for kitchen, the important propagation of pathogenic microorganisms is turned on the way due to the dependence of people's life
Footpath.For example, a cold patients are sealed after mouth sneezes or wipe nasal mucus with face tissue, face tissue is whipped to throw into dustbin, this
When face tissue on be infected with flu germ and virus will widely be propagated by air.And this to be face tissue can turn into
One small aspect of pathogenic microorganisms route of transmission, actually people life in it is all kinds of be various malignant bacterias and virus with paper
Important route of transmission.Therefore, the exploitation of anti-bacteria and anti-virus function paper for daily use is of great significance with application tool.It is anti-at present
Bacterium tissue paper is mainly what the method for being coated with or spraying antiseptic by internal or top sizing, surface was produced.Used
Antiseptic is mainly inorganic antibacterial metal ion such as silver, copper, zinc, and organic antibacterial agent such as organic acid, quaternary ammonium salt, phenolic aldehyde
Class etc..Inorganic antiseptic has security, heat resistance, but price is higher, and easily paper is changed colour；And organic antibacterial agent sterilizing power
By force, wide material sources, but have certain volatility and easily separate out.The antibacterial paper produced by way of physics adds antiseptic,
Due to the dissolution of antiseptic during storage and use, the decline of its anti-microbial property is easily caused.And small molecule antiseptic
Easily in human skin's enrichment, with certain excitant and toxicity.In addition, the loss of antiseptic can also cause environment dirty
Dye.
Therefore, in sum, existing antibacterial tissue paper has that in uneven thickness, water absorbing properties are poor, perishable grow thin
Bacterium, and the poor problem of pliability.
The content of the invention
In view of this, it is an object of the present invention to provide a kind of thickness of thin and uniform, water absorbing properties are good, not perishable grow thin
Bacterium, and the release tissue paper of the good Antimicrobial preservative of pliability.
In order to solve the above-mentioned technical problem, the technical scheme is that：A kind of release tissue paper of Antimicrobial preservative, by following
The raw material of weight portion is made, including 200-300 parts of bamboo bar, softwood pulp 130-190 parts, wheat straw 100-160 parts, organosilicon season phosphine
Salt 50-80 parts, gelatin 40-80 parts, modified 50-90 parts of tapioca starch, carboxymethylcellulose calcium 20-36 parts, talcum powder 30-46 parts, stone
Wax 21-37 parts, acrylic resin 40-60 parts, carbonate group 12-26 parts, toluene 6-8 parts, sodium sulfite 30-60 parts, hydroxide
Ammonium 20-38 parts and potassium hydroxide 20-38 parts.
Further, the release tissue paper of the Antimicrobial preservative is made up of the raw material of following weight portion, including 300 parts of bamboo bar,
130 parts of softwood pulp, 100 parts of wheat straw, 50 parts of organosilicon quaternary phosphonium salt, 40 parts of gelatin, modified 50 parts of tapioca starch, carboxymethylcellulose calcium
20 parts, 30 parts of talcum powder, 21 parts of paraffin, 40 parts of acrylic resin, 12 parts of carbonate group, 6 parts of toluene, 30 parts of sodium sulfite, hydrogen
20 parts of 20 parts of amine-oxides and potassium hydroxide.
Further, the release tissue paper of the Antimicrobial preservative is made up of the raw material of following weight portion, including 200 parts of bamboo bar,
190 parts of softwood pulp, 160 parts of wheat straw, 80 parts of organosilicon quaternary phosphonium salt, 80 parts of gelatin, modified 90 parts of tapioca starch, carboxymethylcellulose calcium
36 parts, 46 parts of talcum powder, 37 parts of paraffin, 60 parts of acrylic resin, 26 parts of carbonate group, 8 parts of toluene, 60 parts of sodium sulfite, hydrogen
38 parts of 38 parts of amine-oxides and potassium hydroxide.
Further, the release tissue paper of the Antimicrobial preservative is made up of the raw material of following weight portion, including 250 parts of bamboo bar,
160 parts of softwood pulp, 130 parts of wheat straw, 65 parts of organosilicon quaternary phosphonium salt, 60 parts of gelatin, modified 70 parts of tapioca starch, carboxymethylcellulose calcium
28 parts, 38 parts of talcum powder, 29 parts of paraffin, 50 parts of acrylic resin, 19 parts of carbonate group, 7 parts of toluene, 45 parts of sodium sulfite, hydrogen
29 parts of 29 parts of amine-oxides and potassium hydroxide.
The invention solves the problems that another technical problem be that a kind of preparation method of the release tissue paper of Antimicrobial preservative is provided, including
Following steps：
1) take 200-300 parts and wheat straw 100-160 parts of bamboo bar to be crushed by Material disintegrator, particle is obtained, then take pin
130-190 parts of leaf wood pulp is put into pulper in the lump with particle, is run at high speed by pulper, and particle is carried out with softwood pulp
Mashing, is obtained mixed serum, standby；
2) by step 1) obtained in mixed serum pour into steam stove, then take ammonium hydroxide 20-38 parts and potassium hydroxide 20-
38 parts, stirred with the rotating speed of 45r/min by mixer so that ammonium hydroxide and potassium hydroxide are well mixed with mixed serum,
Then by heating so that the temperature of steam stove is increased to 260-380 DEG C so that slurries boil, high rigidity slurries are obtained, it is standby；
3) by step 2) obtained in high rigidity slurries pour into Bellmer, addition 30-60 parts of sodium sulfite bleached, hold
Continuous 2-4 days, then washing and starching machine by pressurized screen and vacuum carries out washing and screening, obtains the cleaning slurries that concentration is 6~8%, standby
With；
4) 50-80 parts of organosilicon quaternary phosphonium salt, gelatin 40-80 parts, modified 50-90 parts of tapioca starch, carboxymethylcellulose calcium 20- are taken
36 parts and talcum powder 30-46 parts are added in agitator, by weight 1:3 ratio addition water, then start mixer with
The rotating speed of 50r/min mixes above-mentioned material with water, and filler is obtained, standby；
5) by step 4) obtained in slurries be added to step 3) in it is obtained cleaning slurries in, then by mixer will starch
Liquid is stirred with mixed pulp with the rotating speed of 45r/min, and body paper slurries are obtained, and is then held with boiler, and be heated to 180-
230 DEG C so that standby because modified tapioca starch is heated retrogradation in body paper slurries；
6) by step 5) obtained in body paper slurries pour into pressure cooker, and by the pressure set of pressure cooker be 50KPa, then
Paper pulp raw material is heated to 170-250 DEG C in the pressure of setting so that body paper slurries react with ingredients at high temperature, increase
The function of strong body paper slurries, it is standby；
7) by step 6) obtained in body paper slurries carry out copy paper, paper pulp is scooped up by scooping oar, and by control scoop oar with
The frequency for swinging 30 times per minute uniformly spreads paper pulp out on gauze, can effectively control the copy paper that paper pulp is spread out to reach thickness
The requirement of uniform good toughness, is then extruded the copy paper on gauze by extruder so that the moisture extrusion in copy paper
And be molded, the copy paper after finally extruding is placed into low temp dryer is dried with 12-26 DEG C of low temperature, standby；
8) paraffin 21-37 parts, acrylic resin 40-60 parts, carbonate group 12-26 parts and toluene 6-8 parts input smelting furnace is taken
It is interior, and glue is obtained by high-temperature fusion, glue is then obtained film by inflation film manufacturing machine, it is standby；
9) by step 8) obtained in film be covered in step 7) obtained in copy paper, be heated to 70 DEG C by hot press
Afterwards so that film is extruded under the pressure of 17MPa, and the surface of copy paper is heated, thin film melt and the surface of copy paper is sticked to so that
Two surfaces of copy paper are smooth, obtain final product.
The technology of the present invention effect major embodiment is in the following areas：By with bamboo bar, softwood pulp and wheat straw as main material,
With reference to the filler such as organosilicon quaternary phosphonium salt, gelatin, modified tapioca starch, carboxymethylcellulose calcium and talcum powder, and by paraffin, acrylic acid tree
Fat, carbonate group and toluene add ammonium hydroxide and potassium hydroxide boiling as release glued membrane in bamboo bar, softwood pulp and wheat straw
Afterwards, then by sodium sulfite rinse, then thin paper obtained in mixed fillers, mould release membrance is covered on thin paper, is obtained through hot pressing
Tissue paper, not only thickness of thin and uniform, water absorbing properties are good, not perishable breed bacteria, and pliability is good.
Specific embodiment
Embodiment 1
A kind of release tissue paper of Antimicrobial preservative, is made up of the raw material of following weight portion, including 300 parts of bamboo bar, softwood pulp
130 parts, it is 100 parts of wheat straw, 50 parts of organosilicon quaternary phosphonium salt, 40 parts of gelatin, modified 50 parts of tapioca starch, 20 parts of carboxymethylcellulose calcium, sliding
30 parts of stone flour, 21 parts of paraffin, 40 parts of acrylic resin, 12 parts of carbonate group, 6 parts of toluene, 30 parts of sodium sulfite, ammonium hydroxide 20
20 parts of part and potassium hydroxide.
A kind of preparation method of the release tissue paper of Antimicrobial preservative, comprises the following steps：
1) take 300 parts of bamboo bar and 100 parts of wheat straw is crushed by Material disintegrator, particle is obtained, then take softwood pulp 130
Part is put into pulper in the lump with particle, is run at high speed by pulper, and particle is beaten with softwood pulp, and mixing is obtained
Slurries, it is standby；
2) by step 1) obtained in mixed serum pour into steam stove, then take 20 parts of 20 parts of ammonium hydroxide and potassium hydroxide,
Stirred with the rotating speed of 45r/min by mixer so that ammonium hydroxide and potassium hydroxide are well mixed with mixed serum, Ran Houtong
Cross heating so that the temperature of steam stove is increased to 260 DEG C so that slurries boil, high rigidity slurries are obtained, it is standby；
3) by step 2) obtained in high rigidity slurries pour into Bellmer, addition 30 parts of sodium sulfite bleached, continue 2
My god, then washing and starching machine by pressurized screen and vacuum carries out washing and screening, obtains the cleaning slurries that concentration is 6%, standby；
4) 50 parts of organosilicon quaternary phosphonium salt, 40 parts of gelatin, modified 50 parts of tapioca starch, 20 parts of carboxymethylcellulose calcium and talcum powder are taken
30 parts are added in agitator, by weight 1:3 ratio addition water, then starting mixer will be upper with the rotating speed of 50r/min
State material to mix with water, filler is obtained, it is standby；
5) by step 4) obtained in slurries be added to step 3) in it is obtained cleaning slurries in, then by mixer will starch
Liquid is stirred with mixed pulp with the rotating speed of 45r/min, and body paper slurries are obtained, and is then held with boiler, and be heated to 180
DEG C so that it is standby because modified tapioca starch is heated retrogradation in body paper slurries；
6) by step 5) obtained in body paper slurries pour into pressure cooker, and by the pressure set of pressure cooker be 50KPa, then
Paper pulp raw material is heated to 170 DEG C in the pressure of setting so that body paper slurries react with ingredients at high temperature, and enhancing is former
The function of pulp liquor, it is standby；
7) by step 6) obtained in body paper slurries carry out copy paper, paper pulp is scooped up by scooping oar, and by control scoop oar with
The frequency for swinging 30 times per minute uniformly spreads paper pulp out on gauze, can effectively control the copy paper that paper pulp is spread out to reach thickness
The requirement of uniform good toughness, is then extruded the copy paper on gauze by extruder so that the moisture extrusion in copy paper
And be molded, the copy paper after finally extruding is placed into low temp dryer is dried with 12-26 DEG C of low temperature, standby；
8) take in 21 parts of paraffin, 40 parts of acrylic resin, 6 parts of input smelting furnaces of 12 parts of carbonate group and toluene, and by height
Temperature melting is obtained glue, and glue then is obtained into film by inflation film manufacturing machine, standby；
9) by step 8) obtained in film be covered in step 7) obtained in copy paper, be heated to 70 DEG C by hot press
Afterwards so that film is extruded under the pressure of 17MPa, and the surface of copy paper is heated, thin film melt and the surface of copy paper is sticked to so that
Two surfaces of copy paper are smooth, obtain final product.
Embodiment 2
A kind of release tissue paper of Antimicrobial preservative, is made up of the raw material of following weight portion, including 200 parts of bamboo bar, softwood pulp
190 parts, it is 160 parts of wheat straw, 80 parts of organosilicon quaternary phosphonium salt, 80 parts of gelatin, modified 90 parts of tapioca starch, 36 parts of carboxymethylcellulose calcium, sliding
46 parts of stone flour, 37 parts of paraffin, 60 parts of acrylic resin, 26 parts of carbonate group, 8 parts of toluene, 60 parts of sodium sulfite, ammonium hydroxide 38
38 parts of part and potassium hydroxide.
A kind of preparation method of the release tissue paper of Antimicrobial preservative, comprises the following steps：
1) take 200 parts of bamboo bar and 160 parts of wheat straw is crushed by Material disintegrator, particle is obtained, then take softwood pulp 190
Part is put into pulper in the lump with particle, is run at high speed by pulper, and particle is beaten with softwood pulp, and mixing is obtained
Slurries, it is standby；
2) by step 1) obtained in mixed serum pour into steam stove, then take 38 parts of 38 parts of ammonium hydroxide and potassium hydroxide,
Stirred with the rotating speed of 45r/min by mixer so that ammonium hydroxide and potassium hydroxide are well mixed with mixed serum, Ran Houtong
Cross heating so that the temperature of steam stove is increased to 380 DEG C so that slurries boil, high rigidity slurries are obtained, it is standby；
3) by step 2) obtained in high rigidity slurries pour into Bellmer, addition 60 parts of sodium sulfite bleached, continue 4
My god, then washing and starching machine by pressurized screen and vacuum carries out washing and screening, obtains the cleaning slurries that concentration is 8%, standby；
4) 80 parts of organosilicon quaternary phosphonium salt, 80 parts of gelatin, modified 90 parts of tapioca starch, 36 parts of carboxymethylcellulose calcium and talcum powder are taken
46 parts are added in agitator, by weight 1:3 ratio addition water, then starting mixer will be upper with the rotating speed of 50r/min
State material to mix with water, filler is obtained, it is standby；
5) by step 4) obtained in slurries be added to step 3) in it is obtained cleaning slurries in, then by mixer will starch
Liquid is stirred with mixed pulp with the rotating speed of 45r/min, and body paper slurries are obtained, and is then held with boiler, and be heated to 230
DEG C so that it is standby because modified tapioca starch is heated retrogradation in body paper slurries；
6) by step 5) obtained in body paper slurries pour into pressure cooker, and by the pressure set of pressure cooker be 50KPa, then
Paper pulp raw material is heated to 250 DEG C in the pressure of setting so that body paper slurries react with ingredients at high temperature, and enhancing is former
The function of pulp liquor, it is standby；
7) by step 6) obtained in body paper slurries carry out copy paper, paper pulp is scooped up by scooping oar, and by control scoop oar with
The frequency for swinging 30 times per minute uniformly spreads paper pulp out on gauze, can effectively control the copy paper that paper pulp is spread out to reach thickness
The requirement of uniform good toughness, is then extruded the copy paper on gauze by extruder so that the moisture extrusion in copy paper
And be molded, the copy paper after finally extruding is placed into low temp dryer is dried with 26 DEG C of low temperature, standby；
8) take in 37 parts of paraffin, 60 parts of acrylic resin, 8 parts of input smelting furnaces of 26 parts of carbonate group and toluene, and by height
Temperature melting is obtained glue, and glue then is obtained into film by inflation film manufacturing machine, standby；
9) by step 8) obtained in film be covered in step 7) obtained in copy paper, be heated to 70 DEG C by hot press
Afterwards so that film is extruded under the pressure of 17MPa, and the surface of copy paper is heated, thin film melt and the surface of copy paper is sticked to so that
Two surfaces of copy paper are smooth, obtain final product.
Embodiment 3
A kind of release tissue paper of Antimicrobial preservative, is made up of the raw material of following weight portion, including 250 parts of bamboo bar, softwood pulp
160 parts, it is 130 parts of wheat straw, 65 parts of organosilicon quaternary phosphonium salt, 60 parts of gelatin, modified 70 parts of tapioca starch, 28 parts of carboxymethylcellulose calcium, sliding
38 parts of stone flour, 29 parts of paraffin, 50 parts of acrylic resin, 19 parts of carbonate group, 7 parts of toluene, 45 parts of sodium sulfite, ammonium hydroxide 29
29 parts of part and potassium hydroxide.
A kind of preparation method of the release tissue paper of Antimicrobial preservative, comprises the following steps：
1) take 250 parts of bamboo bar and 130 parts of wheat straw is crushed by Material disintegrator, particle is obtained, then take softwood pulp 160
Part is put into pulper in the lump with particle, is run at high speed by pulper, and particle is beaten with softwood pulp, and mixing is obtained
Slurries, it is standby；
2) by step 1) obtained in mixed serum pour into steam stove, then take 29 parts of 29 parts of ammonium hydroxide and potassium hydroxide,
Stirred with the rotating speed of 45r/min by mixer so that ammonium hydroxide and potassium hydroxide are well mixed with mixed serum, Ran Houtong
Cross heating so that the temperature of steam stove is increased to 320 DEG C so that slurries boil, high rigidity slurries are obtained, it is standby；
3) by step 2) obtained in high rigidity slurries pour into Bellmer, addition 30-60 parts of sodium sulfite bleached, hold
Continuous 3 days, then washing and starching machine by pressurized screen and vacuum carries out washing and screening, obtains the cleaning slurries that concentration is 7%, standby；
4) 65 parts of organosilicon quaternary phosphonium salt, 60 parts of gelatin, modified 70 parts of tapioca starch, 28 parts of carboxymethylcellulose calcium and talcum powder are taken
38 parts are added in agitator, by weight 1:3 ratio addition water, then starting mixer will be upper with the rotating speed of 50r/min
State material to mix with water, filler is obtained, it is standby；
5) by step 4) obtained in slurries be added to step 3) in it is obtained cleaning slurries in, then by mixer will starch
Liquid is stirred with mixed pulp with the rotating speed of 45r/min, and body paper slurries are obtained, and is then held with boiler, and be heated to 205
DEG C so that it is standby because modified tapioca starch is heated retrogradation in body paper slurries；
6) by step 5) obtained in body paper slurries pour into pressure cooker, and by the pressure set of pressure cooker be 50KPa, then
Paper pulp raw material is heated to 210 DEG C in the pressure of setting so that body paper slurries react with ingredients at high temperature, and enhancing is former
The function of pulp liquor, it is standby；
7) by step 6) obtained in body paper slurries carry out copy paper, paper pulp is scooped up by scooping oar, and by control scoop oar with
The frequency for swinging 30 times per minute uniformly spreads paper pulp out on gauze, can effectively control the copy paper that paper pulp is spread out to reach thickness
The requirement of uniform good toughness, is then extruded the copy paper on gauze by extruder so that the moisture extrusion in copy paper
And be molded, the copy paper after finally extruding is placed into low temp dryer is dried with 19 DEG C of low temperature, standby；
8) take in 29 parts of paraffin, 50 parts of acrylic resin, 7 parts of input smelting furnaces of 19 parts of carbonate group and toluene, and by height
Temperature melting is obtained glue, and glue then is obtained into film by inflation film manufacturing machine, standby；
9) by step 8) obtained in film be covered in step 7) obtained in copy paper, be heated to 70 DEG C by hot press
Afterwards so that film is extruded under the pressure of 17MPa, and the surface of copy paper is heated, thin film melt and the surface of copy paper is sticked to so that
Two surfaces of copy paper are smooth, obtain final product.
Experimental example
Following table is the technical indicator of tissue paper：
Above table is the technical requirements of tissue paper, according to the data of upper table, Antimicrobial preservative of the invention is release thin
Page paper is contrasted with other tissue papers, and record data.
Experimental products：Made using the release tissue paper of the Antimicrobial preservative of common tissue paper, special tissue paper and the application
Contrast, and concrete numerical value is recorded, it is as shown in the table：
With reference to upper table, the release tissue paper of Antimicrobial preservative of common tissue paper, special tissue paper and the application is contrasted, only
There is the release tissue paper all technical of Antimicrobial preservative of the invention to reach the standard of high-class product, therefore, compared to common thin page
Paper, special tissue paper, the release tissue paper of Antimicrobial preservative of the invention can more protrude thickness of thin and uniform, water absorbing properties are good, no
Perishable breed bacteria, and pliability it is good the characteristics of.
The technology of the present invention effect major embodiment is in the following areas：By with bamboo bar, softwood pulp and wheat straw as main material,
With reference to the filler such as organosilicon quaternary phosphonium salt, gelatin, modified tapioca starch, carboxymethylcellulose calcium and talcum powder, and by paraffin, acrylic acid tree
Fat, carbonate group and toluene add ammonium hydroxide and potassium hydroxide boiling as release glued membrane in bamboo bar, softwood pulp and wheat straw
Afterwards, then by sodium sulfite rinse, then thin paper obtained in mixed fillers, mould release membrance is covered on thin paper, is obtained through hot pressing
Tissue paper, not only thickness of thin and uniform, water absorbing properties are good, not perishable breed bacteria, and pliability is good.
Certainly, it is more than representative instance of the invention, in addition, the present invention can also have other various specific implementations
The technical scheme that mode, all use equivalents or equivalent transformation are formed, all falls within the scope of protection of present invention.
Claims (4)
1. the release tissue paper of a kind of Antimicrobial preservative, it is characterised in that：It is made up of the raw material of following weight portion, including bamboo bar 200-
300 parts, softwood pulp 130-190 parts, wheat straw 100-160 parts, 50-80 parts of organosilicon quaternary phosphonium salt, gelatin 40-80 parts, innovation wood
50-90 parts of potato powder, carboxymethylcellulose calcium 20-36 parts, talcum powder 30-46 parts, paraffin 21-37 parts, acrylic resin 40-60 parts,
Carbonate group 12-26 parts, toluene 6-8 parts, sodium sulfite 30-60 parts, ammonium hydroxide 20-38 parts and potassium hydroxide 20-38 parts.
2. a kind of release tissue paper of Antimicrobial preservative as claimed in claim 1, it is characterised in that：By the raw material system of following weight portion
Into, including 300 parts of bamboo bar, 130 parts of softwood pulp, 100 parts of wheat straw, 50 parts of organosilicon quaternary phosphonium salt, 40 parts of gelatin, modified tapioca starch
50 parts, 20 parts of carboxymethylcellulose calcium, 30 parts of talcum powder, 21 parts of paraffin, 40 parts of acrylic resin, 12 parts of carbonate group, toluene 6
Part, 30 parts of sodium sulfite, 20 parts of ammonium hydroxide and 20 parts of potassium hydroxide.
3. a kind of release tissue paper of Antimicrobial preservative as claimed in claim 1, it is characterised in that：By the raw material system of following weight portion
Into, including 200 parts of bamboo bar, 190 parts of softwood pulp, 160 parts of wheat straw, 80 parts of organosilicon quaternary phosphonium salt, 80 parts of gelatin, modified tapioca starch
90 parts, 36 parts of carboxymethylcellulose calcium, 46 parts of talcum powder, 37 parts of paraffin, 60 parts of acrylic resin, 26 parts of carbonate group, toluene 8
Part, 60 parts of sodium sulfite, 38 parts of ammonium hydroxide and 38 parts of potassium hydroxide.
4. a kind of release tissue paper of Antimicrobial preservative as claimed in claim 1, it is characterised in that：By the raw material system of following weight portion
Into, including 250 parts of bamboo bar, 160 parts of softwood pulp, 130 parts of wheat straw, 65 parts of organosilicon quaternary phosphonium salt, 60 parts of gelatin, modified tapioca starch
70 parts, 28 parts of carboxymethylcellulose calcium, 38 parts of talcum powder, 29 parts of paraffin, 50 parts of acrylic resin, 19 parts of carbonate group, toluene 7
Part, 45 parts of sodium sulfite, 29 parts of ammonium hydroxide and 29 parts of potassium hydroxide.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611144951.1A CN106758496A (en) | 2016-12-13 | 2016-12-13 | A kind of release tissue paper of Antimicrobial preservative and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611144951.1A CN106758496A (en) | 2016-12-13 | 2016-12-13 | A kind of release tissue paper of Antimicrobial preservative and preparation method thereof |
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| CN106758496A true CN106758496A (en) | 2017-05-31 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611144951.1A Pending CN106758496A (en) | 2016-12-13 | 2016-12-13 | A kind of release tissue paper of Antimicrobial preservative and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110055759A (en) * | 2019-05-24 | 2019-07-26 | 刘群英 | Comfortable protective garment of antibacterial and preparation method thereof |
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| CN1271795A (en) * | 1999-07-14 | 2000-11-01 | 方力平 | Antibacterial paper and its paper-making technology |
| CN1594730A (en) * | 2003-09-12 | 2005-03-16 | 昆山钞票纸厂 | Production process for antibacterial banknote paper and banknote paper thereof |
| CN104018387A (en) * | 2014-04-25 | 2014-09-03 | 江阴比图特种纸板有限公司 | Manufacturing method of mould-proof packaging lining paperboard |
| CN105386362A (en) * | 2015-11-05 | 2016-03-09 | 义乌市义南纸业有限公司 | Anti-corrosion and insect-resistant corrugated paper and preparation method thereof |
| CN105568771A (en) * | 2015-12-24 | 2016-05-11 | 浙江华川实业集团有限公司 | Strong antibacterial ability medical packaging raw paper and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1271795A (en) * | 1999-07-14 | 2000-11-01 | 方力平 | Antibacterial paper and its paper-making technology |
| CN1594730A (en) * | 2003-09-12 | 2005-03-16 | 昆山钞票纸厂 | Production process for antibacterial banknote paper and banknote paper thereof |
| CN104018387A (en) * | 2014-04-25 | 2014-09-03 | 江阴比图特种纸板有限公司 | Manufacturing method of mould-proof packaging lining paperboard |
| CN105386362A (en) * | 2015-11-05 | 2016-03-09 | 义乌市义南纸业有限公司 | Anti-corrosion and insect-resistant corrugated paper and preparation method thereof |
| CN105568771A (en) * | 2015-12-24 | 2016-05-11 | 浙江华川实业集团有限公司 | Strong antibacterial ability medical packaging raw paper and preparation method thereof |
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| CN110055759A (en) * | 2019-05-24 | 2019-07-26 | 刘群英 | Comfortable protective garment of antibacterial and preparation method thereof |
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Application publication date: 20170531 |