CN106750783A - Far-infrared hollow pipe, preparation method and applications - Google Patents
Far-infrared hollow pipe, preparation method and applications Download PDFInfo
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- CN106750783A CN106750783A CN201611142444.4A CN201611142444A CN106750783A CN 106750783 A CN106750783 A CN 106750783A CN 201611142444 A CN201611142444 A CN 201611142444A CN 106750783 A CN106750783 A CN 106750783A
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- far
- hollow pipe
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- infrared hollow
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D23/00—Producing tubular articles
- B29D23/001—Pipes; Pipe joints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Bedding Items (AREA)
Abstract
The present invention relates to furniture cover loose filling material technical field, and in particular to a kind of Far-infrared hollow pipe, preparation method and applications.A kind of Far-infrared hollow pipe, comprising resin Composition：Selected from polyethylene and polypropylene, functional component：Selected from far-infared ceramic powder, antiseptic and negative ion powder；The addition of the functional component is 0.1 10wt%, and the summation of all components percetage by weight is 100%.Functional filler creatively is added in polyethylene and acrylic resin, enables the plastic tube of preparation that far infrared, anion releasing to occur, used as packing material, blood circulation of human body can be improved, improved the health care of sleep；Good permeability, can make the circulation of holding fresh air in pillow, and moisture is excluded in time, keep dry and comfortable；It is antibacterial, anti-mite, it is particularly suitable for allergic rhinitis, breathing problem, asthma crowd and uses；It is easy to clean, can wash repeatedly, its performance is unaffected.
Description
Technical field
The present invention relates to furniture cover loose filling material technical field, and in particular to a kind of Far-infrared hollow pipe, system
Preparation Method and its application.
Background technology
At present, the filler in general pillow, mattress is the materials such as staple fibre, natural fiber, plant species or shell, artificial
Fiber is relatively soft, but poor air permeability；Natural fiber good permeability, but it is easily mouldy, it is difficult to clean；The kind or shell of plant are saturating
Gas is good, but hardness is big, no elastic, easily infested.
The content of the invention
The Far-infrared hollow pipe that filler is used is suitable as it is an object of the invention to provide a kind of, while improving this
The preparation method and application of hollow tube.
The present invention is realized using following technical scheme：
A kind of Far-infrared hollow pipe, comprising resin Composition：Selected from polyethylene and polypropylene, functional component：Selected from remote red
Outer ceramic powder, antiseptic and negative ion powder；The addition of the functional component is 0.1-10wt%, all components weight percent
Several summations is 100%.
Above-mentioned technical proposal, further, the far-infared ceramic powder is nanoscale.
Above-mentioned technical proposal, further, the antiseptic is silver ion antimicrobial agent or bamboo charcoal nano.
Above-mentioned technical proposal, further, the negative ion powder is nano-tourmaline negative ion powder or rare earth element.
Above-mentioned technical proposal, further, the mass ratio of the far-infared ceramic powder, antiseptic and negative ion powder is 3:1:
3。
Above-mentioned technical proposal, further, in the component of the Far-infrared hollow pipe also includes that plastic tube is acceptable and helps
Agent, the acceptable auxiliary agent of plastic tube is selected from：Bulking agent, stabilizer, plasticizer, toughener, pigment, antioxidant, mould inhibitor,
Antistatic additive, slipping agent, the anti-at least one being adhered in agent, hydrolysis agent, processing aid.
Above-mentioned technical proposal, further, the acceptable auxiliary agent of plastic tube is according to 0.01- based on all components
The amount of 5wt% is present, and the level of other components is accordingly reduced so that the summation of all components percetage by weight is 100%.
A kind of preparation method of Far-infrared hollow pipe, comprises the following steps：(1) by functional component and resin Composition according to
Mass ratio is 1：The melting extrusion granulation in comminutor after the ratio blending of (3-5), granulation melt temperature is 120-160 DEG C, will
Gained plastic pellet is dried；(2) remaining resin Composition and plastic tube acceptable auxiliary agent melting extrusion in comminutor are made
Grain, granulation melt temperature is 120-160 DEG C, and gained plastic pellet is dried；(3) it is blended after above two particle is cooled down and is put into
Extruder, the extrusion molding under conditions of the die temperature of extruder is for 125-155 DEG C, is made Far-infrared hollow pipe, then cuts
It is cut into required length.
Above-mentioned technical proposal, further, the equipment that the blending operations are used is high-speed mixer or batch mixer.
Far-infrared hollow pipe described in any of the above-described claim is used to fill pillow, mattress, back cushion.
Far-infrared hollow pipe disclosed by the invention, feature is added creatively in polyethylene and acrylic resin and is filled out
Material, enables the plastic tube of preparation that far infrared, anion releasing to occur, and is used as packing material, can improve human body blood
Liquid is circulated, and is improved the health care of sleep；Good permeability, can make the circulation of holding fresh air in pillow, and moisture is excluded in time, keep dry
It is refreshing；It is antibacterial, anti-mite, it is particularly suitable for allergic rhinitis, breathing problem, asthma crowd and uses；It is easy to clean, can water repeatedly
Wash, its performance is unaffected.
Specific embodiment
In order to be more clearly understood from the above objects, features and advantages of the present invention, with reference to embodiment to this
Invention is described further.
Many details are elaborated in the following description in order to fully understand the present invention, but, the present invention may be used also
To be implemented using other modes described here are different from, therefore, the present invention is not limited to following public specific embodiment.
A kind of Far-infrared hollow pipe, including
Resin Composition：By weight, the polyethylene of 60-99.9%, preferably 70-98%, more preferably 80-90% or poly-
Allyl resin；
Functional component：By weight, the far-infared ceramic powder of 0.1-10%, preferably 1-8%, more preferably 2-5%, anti-
Microbial inoculum or negative ion powder；Mass ratio between infrared ceramic powder, antiseptic or negative ion powder is preferably (1-3):1:It is (1-3), more excellent
Select 3:1:3；
Condition is that the summation of the percetage by weight of above-mentioned all components is 100%.
The preparation method of Far-infrared hollow pipe of the invention is：The first step, above-mentioned functions component and resin Composition are pressed
It is 1 according to mass ratio：(3-5), preferably 1:The melting extrusion granulation in comminutor after 4 ratio blending, granulating melt temperature is
120-160 DEG C, gained plastic pellet is dried；Second step, remaining resin Composition and the acceptable auxiliary agent of plastic tube are being made
Melting extrusion granulation in grain machine, granulation melt temperature is 120-160 DEG C, and gained plastic pellet is dried；3rd step, by above-mentioned two
Blending is put into extruder after planting particle cooling, the extrusion molding under conditions of the die temperature of extruder is for 125-155 DEG C, is made
Far-infrared hollow pipe, is then cut into required length.
In one embodiment, also include in addition to resin Composition and functional component in the component of Far-infrared hollow pipe
The acceptable auxiliary agent of plastic tube based on all compositions preferably 0.01-5%, 0.05-3%, 1-2% by weight, at this
In the case of kind, the level of other components is accordingly reduced, and the percetage by weight summation for making all components is 100%.
Resin Composition
Comprising polyethylene and/or polypropylene, the present invention is also contained in based on polyethylene and/or polyacrylic modified copolymer
Theme in.
Functional component
At least one in far-infared ceramic powder, antiseptic and negative ion powder.It is preferred that nano-scale far infrared ceramic powder；It is preferred that
Antiseptic is silver ion antimicrobial agent；It is preferred that nano-tourmaline negative ion powder.Said components are commercially available.
The acceptable auxiliary agent of plastic tube
Selected from bulking agent, stabilizer, plasticizer, toughener, pigment, antioxidant, mould inhibitor, antistatic additive, slipping agent, anti-
It is adhered at least one in agent, hydrolysis agent, processing aid.Above-mentioned auxiliary agent is commercially available plastic additive, including but not limited to upper
State auxiliary agent.
Method
The invention further relates to a kind of method for preparing Far-infrared hollow pipe, the present invention is used by using melting extrusion method
Composition, produce plastic products, preferably plastic tube, more preferably plastic flexible pipe.
Production method is：The first step, functional component is mixed with the small part in resin Composition in blend tool,
Then melting extrusion granulation in input comminutor；Second step, remaining resin Composition is mixed with auxiliary agent in blend tool, so
Melting extrusion granulation in input comminutor afterwards；3rd step, squeezes being blended in tube extruding equipment after the cooling of above-mentioned particle, drying
Go out, cool down, draw, cut.
For the component mixture that the present invention is used, blend tool selects high speed mixer.
In the context of the present invention, the preferred single screw extrusion machine of extrusion equipment.
In granulation, granulation melt temperature is 120-160 DEG C, mixes 20-30min.
Extruder feed section temperature is 100-110 DEG C, and extruder compression section temperature is 110-130 DEG C, extruder metering section
Temperature is 130-150 DEG C, and extruder die temperature is 120-155 DEG C, and the screw speed of extruder is 20-35r/min；
Using
Present invention also offers a kind of purposes of Far-infrared hollow pipe, as filler in pillow, mattress, bedding, back cushion
In use.It is also used as filling in support tube inner chamber body after the compositions such as spices, energy stone and is re-used as filler and uses.
A kind of preparation method of Far-infrared hollow pipe, it is characterised in that comprise the following steps：(1) by functional component with
Resin Composition is 1 according to mass ratio：Melting extrusion granulation in an extruder after the ratio blending of (3-5), granulating melt temperature is
120-160 DEG C, gained plastic pellet is dried；(2) by remaining resin Composition and the acceptable auxiliary agent of plastic tube in extruder
Middle melting extrusion granulation, granulation melt temperature is 120-160 DEG C, and gained plastic pellet is dried；(3) it is above two particle is cold
But blending is put into extruder afterwards, the extrusion molding under conditions of the die temperature of extruder is for 125-155 DEG C, is made in far infrared
Blank pipe, is then cut into required length.
The preparation method of Far-infrared hollow pipe according to claim 8, it is characterised in that the blending operations are used
Equipment be high-speed mixer or batch mixer.
Embodiment
Proportioning according to the embodiment 1-3 of table 1 weighs each component, and Far-infrared hollow pipe is obtained according to the method described above.According to table 1
The proportioning of comparative example weighs each component, and common plastics tube is obtained according to the method for production plastic tube.
Following components has been used in embodiment：
Polyvinyl resin：Yangtze petrochemical industry HDPE5306J
Acrylic resin：Magnificent brocade chemical industry EP2S12B
Nano far infrared ceramic powder：Shandong Origine Nanomaterial Engineering Co., Ltd.'s product
Silver ion antimicrobial agent：BASF IRGAGUARD B 7000
Nano-tourmaline negative ion powder：Shijiazhuang Dong Ze mineral products Co., Ltd nano-scaled electric stone flour
Auxiliary agent：Antioxidant 1098, bulking agent, antistatic additive, mould inhibitor.
Table 1
| Component (wt%) | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example |
| Polyvinyl resin | 89 | 45 | 50 | |
| Acrylic resin | 92.5 | 45 | 48 | |
| Far-infared ceramic powder | 6 | 3 | 5 | |
| Antiseptic | 2 | 1 | 2 | |
| Negative ion powder | 2 | 3 | 1 | |
| Auxiliary agent | 1 | 0.5 | 2 | 2 |
Plastic tube obtained in embodiment 1-3 and comparative example is detected respectively, far infrared obtained in embodiment 1-3 is found
The normal direction total emissivity of hollow tube is significantly larger than comparative example.In antibacterial experiment, embodiment 1-3 is obtained Far-infrared hollow pipe antibacterial
Performance is better than comparative example.
Embodiment 1-3 is obtained Far-infrared hollow pipe and plastic tube obtained in comparative example is filled into four kinds of pillows respectively, entered
Row sleep test.By using, it is found that tester's sleep quality of the pillow using filling Far-infrared hollow pipe is improved, after wakeing up
The state of mind is good, and the pillow and the tester's sleep quality using common pillow and spiritual shape filled using comparative example plastic tube
State is all without significant change.
Embodiment described above is only that the preferred embodiment of the present invention is described, not to the scope of the present invention
It is defined, on the premise of design spirit of the present invention is not departed from, those of ordinary skill in the art are to technical scheme
The various modifications made and improvement, all should fall into the protection domain of claims of the present invention determination.
Claims (10)
1. a kind of Far-infrared hollow pipe, it is characterised in that comprising resin Composition：Selected from polyethylene and polypropylene, functional component：
Selected from far-infared ceramic powder, antiseptic and negative ion powder；The addition of the functional component is 0.1-10wt%, all components
The summation of percetage by weight is 100%.
2. Far-infrared hollow pipe according to claim 1, it is characterised in that the far-infared ceramic powder is nanoscale.
3. Far-infrared hollow pipe according to claim 2, it is characterised in that the antiseptic be silver ion antimicrobial agent or
Bamboo charcoal nano.
4. Far-infrared hollow pipe according to claim 3, it is characterised in that the negative ion powder for nano-tourmaline bear from
Sub- powder or rare earth element.
5. the Far-infrared hollow pipe according to claim any one of 1-4, it is characterised in that the far-infared ceramic powder, anti-
The mass ratio of microbial inoculum and negative ion powder is 3:1:3.
6. Far-infrared hollow pipe according to claim 5, it is characterised in that also wrapped in the component of the Far-infrared hollow pipe
The acceptable auxiliary agent of plastic tube is included, the acceptable auxiliary agent of plastic tube is selected from：Bulking agent, stabilizer, plasticizer, toughener,
Pigment, antioxidant, mould inhibitor, antistatic additive, slipping agent, the anti-at least one being adhered in agent, hydrolysis agent, processing aid.
7. Far-infrared hollow pipe according to claim 6, it is characterised in that the acceptable auxiliary agent of plastic tube is to be based on
All components exist according to the amount of 0.01-5wt%, and the level of other components is accordingly reduced so that all components weight hundred
The summation of fraction is 100%.
8. a kind of preparation method of Far-infrared hollow pipe, it is characterised in that comprise the following steps：(1) by functional component and tree
Fat component is 1 according to mass ratio：The melting extrusion granulation in comminutor after the ratio blending of (3-5), granulating melt temperature is
120-160 DEG C, gained plastic pellet is dried；(2) by remaining resin Composition and the acceptable auxiliary agent of plastic tube in comminutor
Middle melting extrusion granulation, granulation melt temperature is 120-160 DEG C, and gained plastic pellet is dried；(3) it is above two particle is cold
But blending is put into extruder afterwards, the extrusion molding under conditions of the die temperature of extruder is for 125-155 DEG C, is made in far infrared
Blank pipe, is then cut into required length.
9. the preparation method of Far-infrared hollow pipe according to claim 8, it is characterised in that what the blending operations were used
Equipment is high-speed mixer or batch mixer.
10. the Far-infrared hollow pipe described in any of the above-described claim is used to fill pillow, mattress, back cushion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611142444.4A CN106750783A (en) | 2016-12-13 | 2016-12-13 | Far-infrared hollow pipe, preparation method and applications |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611142444.4A CN106750783A (en) | 2016-12-13 | 2016-12-13 | Far-infrared hollow pipe, preparation method and applications |
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| Publication Number | Publication Date |
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| CN106750783A true CN106750783A (en) | 2017-05-31 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611142444.4A Pending CN106750783A (en) | 2016-12-13 | 2016-12-13 | Far-infrared hollow pipe, preparation method and applications |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163294A (en) * | 2017-06-07 | 2017-09-15 | 深圳市创艺工业技术有限公司 | A kind of far infrared composite powder |
| CN109594140A (en) * | 2018-12-24 | 2019-04-09 | 广东蒙泰高新纤维股份有限公司 | A kind of functional hollow polypropylene fiber and preparation method thereof |
| CN110724345A (en) * | 2019-09-03 | 2020-01-24 | 会通新材料股份有限公司 | Antistatic negative ion high-release polypropylene composite material and preparation method and application thereof |
| CN112076352A (en) * | 2020-08-25 | 2020-12-15 | 云南科威液态金属谷研发有限公司 | Medical liquid metal thermoplastic functional composite material and preparation method and application thereof |
| CN115521523A (en) * | 2022-09-15 | 2022-12-27 | 青岛上雅家居用品股份有限公司 | Hose with blue light prevention function and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2215866Y (en) * | 1994-06-02 | 1995-12-27 | 卢金铨 | Health pillow made of plastic hollow cylinder |
| CN1978514A (en) * | 2005-11-17 | 2007-06-13 | 李豪荣 | Plastic caviar bead for filling of pillow having function of anti-bacteria |
| CN104356477A (en) * | 2014-11-02 | 2015-02-18 | 石海波 | Hollow tube pillow filler with bamboo charcoal adsorption and far-infrared functions and preparation method |
-
2016
- 2016-12-13 CN CN201611142444.4A patent/CN106750783A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2215866Y (en) * | 1994-06-02 | 1995-12-27 | 卢金铨 | Health pillow made of plastic hollow cylinder |
| CN1978514A (en) * | 2005-11-17 | 2007-06-13 | 李豪荣 | Plastic caviar bead for filling of pillow having function of anti-bacteria |
| CN104356477A (en) * | 2014-11-02 | 2015-02-18 | 石海波 | Hollow tube pillow filler with bamboo charcoal adsorption and far-infrared functions and preparation method |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163294A (en) * | 2017-06-07 | 2017-09-15 | 深圳市创艺工业技术有限公司 | A kind of far infrared composite powder |
| CN109594140A (en) * | 2018-12-24 | 2019-04-09 | 广东蒙泰高新纤维股份有限公司 | A kind of functional hollow polypropylene fiber and preparation method thereof |
| CN110724345A (en) * | 2019-09-03 | 2020-01-24 | 会通新材料股份有限公司 | Antistatic negative ion high-release polypropylene composite material and preparation method and application thereof |
| CN112076352A (en) * | 2020-08-25 | 2020-12-15 | 云南科威液态金属谷研发有限公司 | Medical liquid metal thermoplastic functional composite material and preparation method and application thereof |
| CN112076352B (en) * | 2020-08-25 | 2022-03-29 | 云南迈特力医疗技术有限公司 | Medical liquid metal thermoplastic functional composite material and preparation method and application thereof |
| CN115521523A (en) * | 2022-09-15 | 2022-12-27 | 青岛上雅家居用品股份有限公司 | Hose with blue light prevention function and preparation method thereof |
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