CN106689178A - Insecticidal composition - Google Patents
Insecticidal composition Download PDFInfo
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- CN106689178A CN106689178A CN201510426608.5A CN201510426608A CN106689178A CN 106689178 A CN106689178 A CN 106689178A CN 201510426608 A CN201510426608 A CN 201510426608A CN 106689178 A CN106689178 A CN 106689178A
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- sulfoxaflor
- ethiprole
- pesticidal combination
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- pesticidal
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Abstract
The present invention relates to an insecticidal composition comprising Sulfoxaflor and Fipronil, and in particular relates to a method for controlling harmful organisms. The insecticidal composition comprises an active component consisting of the Sulfoxaflor and the Fipronil, and the weight ratio of the Sulfoxaflor and the Fipronil ranges from 1:100 to 100:1. Through combination of the Sulfoxaflor and the Fipronil, the insecticidal composition has gain effects in the prevention and treatment effect, an insecticidal spectrum is expanded, rapid effects and long-term effects of pest control can be improved, and drug resistance can be prevented or overcome.
Description
Technical field
The present invention relates to a kind of Pesticidal combination, including sulfoxaflor and ethiprole；More particularly to a kind of method for controlling harmful organism.
Background technology
In agricultural production, chemical agent is to prevent and treat the maximally efficient means of plant pest, but, with the influence of extension, the agricultural chemicals not factor such as scientifical use of agricultural pests chemical prevention medication history, in recent years, agricultural pests resistance is increasingly serious, the pest species of resistance are produced persistently to increase, the Lepidoptera class pest of resistance is particularly easily produced, resistance level is higher, and resistance development speed is relatively fast.The resistance problem of agricultural pests is a global problem.
Sulfoxaflor（Sulfoxaflor）, chemical name is：[1-6- (trifluoromethyl) pyridin-3-yl] ethyl]-λ 4- sulfydryl cyanamides, its molecular structural formula is：
Sulfoxaflor belongs to sulfoximide insecticides, acts on the nervous system of insect, that is, act on binding site unique in nicotinoids acetylcholinergic receptor (nAChR) and play insecticidal function.Can be absorbed through leaf, stem, root and entered in plant.Sulfoxaflor is applied to prevents and treats cotton fleahopper, aphid, aleyrodid, all suckings pest such as plant hopper and coccid；Sulfoxaflor is efficient, the quick and lasting period is long, can effectively prevent and treat to nicotinoids, chrysanthemum esters, and organophosphate and carbamate pesticide produces the suction juice class pest of resistance.Sulfoxaflor is by resistance to insecticides Action Committee（IRAC）Regard as unique Group 4C class brand-new active ingredients.Sulfoxaflor is low to non-target arthropod toxicity, is integrated pest control preferred agents.
Ethiprole (Fipronil), chemical name is：(RS) -5- amino -1- (2,6- bis- chloro- a, a, a- trifluoro-p-tolyl) -4- trifluoromethyl sulfinyl pyrazole -3- nitriles, its molecular structural formula is：
Ethiprole is a kind of Phenylpyrazole insecticides, to insect based on stomach poison function, has concurrently and tags and certain systemic action, and its mechanism of action is the chloride metabolism for hindering the control of insect GABA.Ethiprole has insecticidal activity very high to important pests such as aphid, leafhopper, plant hopper, lepidopterous larvae, flies and coleopteras, to crop without poisoning.The medicament can impose on soil, also can foliar spray.Imposing on soil can effectively prevent and treat corn root leaf A, wireworm and cutworm.During foliage spray, there is high-level preventive effect to diamondback moth, cabbage butterfly, rice thripses etc., and the lasting period is long.
CN102217644A discloses a kind of synergetic pesticide composition containing sulfoxaflor, planted containing one of sulfoxaflor and phenthoate dimephenthoate cidial, chlorfenapyr in composition, the composition has lasting prevention effect, has greater activity to the insect on Cereal, fruit tree, vegetables, ornamental plant, cotton.
CN1799359A discloses a kind of Firponil compounded pesticide, and it contains, and the insect effects such as ethiprole and malathion, described Firponil compounded pesticide preventing and treating striped rice borer, rice leaf roller are good, and the harm to environment and human body is small, and use cost is low.
The activity of the individual compounds is good；However, in low rate of application or when being used for single insect, they are not that can meet the high request that insecticide, acaricide or nematicide must are fulfilled for.
The typical demand occurred in field of pest control is to need to reduce the close rate of preventing and treating active component and reduction or avoid unfavorable environment or toxicological effects, while still allowing for the control of insect of effect.Also need to combine the pest control agent for knocking down activity and extension preventing and treating time, i.e. snap action and long-acting.
The use of another difficulty of insecticide is to repeat to cause to produce the reactive compound quick selection that is natural or adapting to drug-fast insect in many cases using single Pesticidal compound with uniquely.Accordingly, it would be desirable to help to prevent or overcome drug-fast pest control agent.
The content of the invention
The invention aims to solve above-mentioned technical problem, a kind of Pesticidal combination is provided, said composition is combined by by sulfoxaflor and ethiprole, so that the composition for obtaining has gain effect in prevention effect, and expand insecticidal spectrum, the snap action and long-acting of control of insect are improve, helps to prevent and treat or overcome the generation of drug resistance.
Therefore, it is an object of the present invention to provide a kind of reduction close rate, expansion activity profile, with reference to the Pesticidal combination knocked down activity and dauer effect, overcome drug resistance.
It has been found that compared with the possible control rate of each compound, meanwhile, i.e., jointly or separately obtain enhanced control of insect using reactive compound sulfoxaflor and ethiprole or successively using sulfoxaflor and ethiprole.
The technical solution adopted for the present invention to solve the technical problems is：
A kind of Pesticidal combination, active component is made up of sulfoxaflor and ethiprole, and sulfoxaflor and ethiprole are 1 by weight ratio:100-100:1.
As a further improvement on the present invention, the sulfoxaflor and ethiprole are 1 by weight ratio:50-50:1.
As a further improvement on the present invention, the sulfoxaflor and ethiprole are 1 by weight ratio:25-25:1.
As a further improvement on the present invention, the sulfoxaflor and ethiprole are 1 by weight ratio:10-10:1.
As a further improvement on the present invention, the sulfoxaflor and ethiprole are 1 by weight ratio:5-5:1.
A kind of Pesticidal combination, active component is made up of sulfoxaflor and ethiprole, and the weight of the sulfoxaflor and ethiprole accounts for composition 5%-90% by weight altogether.
A kind of Pesticidal combination, active component is made up of sulfoxaflor and ethiprole, and the weight of the sulfoxaflor and ethiprole accounts for composition 10%-80% by weight altogether.
A kind of Pesticidal combination, active component is made up of sulfoxaflor and ethiprole, and the weight of the sulfoxaflor and ethiprole accounts for composition 20%-60% by weight altogether.
Pesticidal combination of the invention, also comprising surfactant and/or extender.
Pesticidal combination of the invention, the Pesticidal combination can be configured to any formulation for agriculturally allowing.
Pesticidal combination of the invention, the formulation of the Pesticidal combination is missible oil, suspending agent, seed treatment, water dispersible granules, wettable powder, suspension emulsion, smoke agent, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, ultra low volume liquids, microemulsion.
On the other hand, present invention also offers a kind of purposes that Pesticidal combination of the invention is used to prevent or control harmful organism.
Preferably, the Pesticidal combination is used to prevent and treat fleahopper silk worm, aphid, aleyrodid, plant hopper, scale insect, thrips, rice leaf roller, yellow rice borer, pachydiplosis oryzae, base of a fruit moth, red spider, prodenia litura, cabbage caterpillar, diamondback moth, beet armyworm, powder mosquito diamond-back moth, anthonomus grandis, striped flea-beetle, smaller green leaf hopper, root maggot, mythimna separata, nematode, wireworm, cutworm.
On the other hand, present invention also offers a kind of method prevented or control harmful organism, Pesticidal combination of the invention is acted on into target useful plant, object noxious livings or its environment, the propagating materials of target useful plant.The plant propagation material is seedling, rhizome, garden seedling, cutting or seed.
A kind of cover crop is in case the method for pest infestation, including crop is contacted with Pesticidal combination of the invention with target useful plant, object noxious livings or its environment, the propagating materials of target useful plant.
A kind of cover crop is in case the method for pest infestation, including jointly or separately applies reactive compound sulfoxaflor and ethiprole or apply sulfoxaflor and ethiprole successively and separate.
A kind of method prevented or control harmful organism, wherein sulfoxaflor and ethiprole is individually the form of formulated composition.
The present invention also provides a kind of protection seed in case soil insect and protection seedling root and branch are in case the method for soil and foliar insect, it is included in before sowing and/or seed is contacted with the Pesticidal combination of the invention of insecticidal effective dose after vernalization.
A kind of method for protecting vegetable seeds, it includes making seed prior to seeding and/or is contacted with the Pesticidal combination of the invention of effective dose after vernalization.
The invention further relates to purposes of the Pesticidal combination of the invention in harmful organism is resisted.
The invention further relates to purposes of the Pesticidal combination of the invention in confrontation insect, acarid or nematode.
Purposes of the Pesticidal combination of the invention in the veterinary drug of confrontation parazoon.
The invention further relates to a kind of protection animal in case parasite infestation or the method for invasion and attack, its animal for including delivering medicine to the Pesticidal combination of effective dose of the present invention needs.
A kind of seed for applying Pesticidal combination of the invention treatment.
Detailed description of the invention
Present invention discover that：Sulfoxaflor and ethiprole combination can not only be brought and improved for the additive property of insecticidal spectrum, but also realize amazing synergy.
Term " synergy " used herein refers to inventive compound combination insecticidal effect more than each active component effect sum, and in other words, its effect is superadditivity.
The invention provides a kind of Pesticidal combination, active component is made up of sulfoxaflor and ethiprole, and sulfoxaflor and ethiprole are 1 by weight ratio:100-100:1, preferably 1:50-50:1, more preferably 1:25-25:1, further preferably 1:10-10:1, further preferably 1:5-5:1.
The total amount of active component can be selected according to material elements in the present composition, to realize desired effect.The factor is for example, formulation, object to be administered, application process etc..Sulfoxaflor and ethiprole account for 5% to 90% by weight of the composition, preferably 10% to 80%, more preferably 20% to 60% altogether.
Composition of the invention optionally includes agronomically acceptable surfactant and/or extender.
According to the present invention, term " filler " refers to can be combined with active component or combines to make it easier for being administered to object（Such as plant, crop or careless class）Natural or synthetic organic or inorganic compound.Therefore, the filler is preferably inert, at least should be agricultural acceptable.The filler can be solid or liquid.
Applicable solid carrier is：Such as phyteral powdery type（Such as particle of soy meal, starch, grain dust, wood powder, bark powder, sawdust, walnut shell powder, wheat bran, cellulose powder, coconut husk, corncob and tobacco stem, extracts residue after plant essence etc.）, clay class（Such as kaolin, bentonite, acid china clay etc.）, talcum powder class.Silica（Such as diatomite, silica sand, mica, aqueous silicic acid, calcium silicates）, activated carbon, natural mineral matter class（Float stone, attapulgite and zeolite etc.）, fire diatomite, sand, plastics medium etc.（Such as polyethylene, polypropylene, polyvinylidene chloride etc.）, potassium chloride, calcium carbonate, chemical fertilizer, the clay fertilizer of inorganic mineral powder, ammonium sulfate, ammonium phosphate, urea, the ammonium chloride of calcium phosphate etc. etc., these materials can be used alone or two or more is mixed.
Applicable liquid-carrier can be selected in llowing group of materials, such as water, alcohol type（Such as methyl alcohol, ethanol, isopropanol, butanol, ethylene glycol etc.）, ketone（Such as acetone, methyl ethyl ketone, isobutyrone, cyclohexanone etc.）, ethers（Such as ether, dioxs, methylcellulose, tetrahydrofuran etc.）, aliphatic hydrocarbon class（Such as kerosene, mineral oil etc.）, aromatic hydrocarbons class（Such as benzene,toluene,xylene, solvent naphtha, alkylnaphthalene, chlorinated aromatic hydrocarbons, chlorinated aliphatic hydrocarbon, chlorobenzene etc.）, halogenated hydrocarbon class, amide-type, sulfone class, dimethyl sulfoxide (DMSO), mineral and vegetable oil, animal oil etc..
Applicable surfactant has the emulsifying agent with ion or non-ionic nature, dispersant or a wetting agent, or these surfactants mixture.
The emulsifying agent can be selected：Lauryl sodium sulfate,Neopelex,Calcium dodecyl benzene sulfonate,Thermally coupled distillation columns,Thermally coupled distillation columns amine salt,Castor oil polyoxyethylene ether phosphate amine salt,Phenyl phenol polyoxyethanyl ether phosphate,Styrene polyoxyethylene ether ammonium sulfate salt,Alkyl biphenyl ether disulfonic acid magnesium salts,Three phenethyl phenol polyoxy ether phosphate amine salts,Polyoxyethylene fatty acid amides fatty acid ester,Fixanol,Alkyl isoquinolinium salt,Dialkylmorpholinum salts,Oleamide sulfonate,Diisopropyl naphthalene sulfonate,Lignosulfonates,Naphthalenesulfonate formaldehyde condensation compound,Benzyl dimethyl phenol polyoxyethyl ether,Styryl phenyl APEO,Phenethyl phenol polyoxyethylene poly-oxygen propylene aether,Castor oil polyoxyethylene ether NPE,AEO,Polyoxyethylene alkyl ether,Polyoxyethylene polyoxypropylene block polymer,Alkyl phenol formaldehyde resin polyoxyethylene ether,Polyoxyethylene Sorbitol Fatty Acid Esters,Sorbitan monostearate,Sorbitan monostearate APEO,Sorbitan fatty acid ester APEO,One or more in polyoxypropylene glycol mono fatty acid ester etc..
The dispersant can be selected：Lignosulfonates, p-hydroxyphenyl sodium lignin sulfonate, fatty alcohol polyoxyethylene ether sulfate, alkylnaphthalene sulfonate, naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, APES formaldehyde condensation product, dodecyl trimethyl ammonium salt, alkyl dimethyl benzyl ammonium salt, two polyoxyethylene lauryl ether phosphate, styrene-maleic acid salt copolymer, to methoxyl group fatty acyl anilinesulfonic acid, to methoxyl group fatty acyl amido benzene sulfonate, AEO, aliphatic alcohol polyoxyvinethene phosphate, NPE, glycerine fatty acid APEO, polyoxyethylene alkylaryl ether, polyoxyethylene lanolin alcohol, Polyoxyethylene Sorbitan acid esters, polyoxyethylene glyceryl mono fatty acid ester, one or more in alkylolamides and polyoxyethylene alkyl amine etc..
The wetting agent can be selected：Lauryl sodium sulfate, calcium dodecyl benzene sulfonate, isooctanol Disodium sulfosuccinate, oleoyl methyl sodium taurocholate, polyoxyethylene lauryl ether carboxylic acid sodium, sodium N-lauroyl sarcosinate, N- sodium lauroyl glutamates, dioctyl sulfosuccinate, polyoxyethylene alkylaryl ether phosphate ester salt, trisiloxanes APEO, triphenoethyl benzene phenol polyethenoxy ether, castor oil polyoxyethylene ether, AEO, the poly- base ether formaldehyde condensation products of alkylphenol-polyethenoxy, alkylphenol-polyethenoxy base ether phosphate, polyoxyethylene fatty acid ester, higher fatty acid ester, one or more in sorbitan aliphatic ester etc..
When a kind of water insoluble in one kind and/or inert carrier in reactive compound and when being applied in water, it is necessary to there is surfactant.The ratio of surfactant is 5% to 40% weight of composition of the invention.
Composition of the invention can also include additional other components, such as adhesive, disintegrant, thickener, defoamer, antifreezing agent, stabilizer, preservative, pH adjusting agent.
Described adhesive can be selected：One or more in sucrose, starch, dextrin, polyvinylpyrrolidone, carboxymethylcellulose calcium, carboxyethyl cellulose, gelatin, Arabic gum, xanthans etc..
The disintegrant can be selected：One or more in sodium carboxymethyl starch, Ac-Di-Sol, urea, sodium sulphate, calcium sulfate, sodium acid carbonate, ammonium sulfate, magnesium chloride, sodium chloride, bentonite etc..
The thickener can be selected：One or more in Arabic gum, xanthans, gelatin, polyvinyl alcohol, polyvinyl acetate, aluminium-magnesium silicate, sodium alginate, sodium carboxymethylcellulose etc..
The defoamer can be selected：One or more in butylphosphoric acid ester, phosphoric acid isobutyl ester, n- octanol, silicone etc..
The antifreezing agent can be selected：Selected from one or more in ethylene glycol, propane diols, glycerine etc..
The stabilizer can be selected：One or more in triphenyl phosphite, N- soybean oleyl trimethylene diamine, dialkyl group succinate sulfonate, epoxychloropropane, butyl glycidyl ether etc..
The preservative can be selected：One or more in benzoic acid, Sodium Benzoate etc..
The pH adjusting agent can be selected：One or more in hydrochloric acid, calgon, sodium citrate, sodium acid carbonate, NaOH, hydrogen-oxygen agent, triethanolamine etc..
The preparation of the invention can be mixed the active component with least one in following material by known way：Solvent or diluent, emulsifying agent, dispersant, and/or adhesive or fixative, wetting agent, waterproofing agent, if it is desired, drier and colouring agent, stabilizer, pigment, defoamer, preservative, thickener, water and other processing aids can also be included.
Pesticidal combination of the invention can be used with itself, or can be used with its dosage form or type of service prepared therefrom according to its respective physically and/or chemically property.The Exemplary dosage forms of premix composition are：
GR：Granule
WP：Wettable powder
SP：Soluble powder
WG：Water dispersibles granula
SG：Soluble granule
SL：Soluble concentrate
EC：Missible oil
EW：Emulsion, aqueous emulsion
ME：Microemulsion
SC：Suspending agent
CS：Microcapsule suspending agent
OD：Oil-based suspension
SE：Suspension emulsion
FS：Seed coat agent
The Exemplary dosage forms for being adapted to bucket mixing composition are solution, dilution emulsion, suspending agent or its mixing and pulvis.Generally, bucket mixing composition is to use solvent（Such as water）Dilution containing different agricultural chemicals, and optionally further auxiliary agent one or more premix composition.
Composition of the invention not only includes can use what suitable device was applied to plant or seed to use composition, and including the commercially available concentrate of necessary dilute with water before administration.
Composition of the invention can also be applied with other active ingredient combinations, described other active components such as fungicide, bactericide, attractant, insecticide, acaricide, nematicide, growth regulator, herbicide, safener, fertilizer or semiochemical etc..
Present invention also offers a kind of purposes that Pesticidal combination of the invention is used to prevent or control harmful organism.
Pesticidal combination of the invention, with good plant compatibility and favourable homeothermal animal toxicity, is suitable to the harmful organism that preventing and treating runs into agricultural, forestry, protection Stored Product and material and health field, especially insect, acarid, nematode.They are active for the species of generally sensitive and resistance, and are respectively provided with activity for all or single stage of development.
Term " harmful organism " used herein means can any organism damnous to the normal condition of plant.Including：
Lepidoptera pest, it is such as Egyptian to bore noctuid (Earias insulana), cabbage butterfly (Pierisrapae Linnaeus), grey snout moth's larva (Herpetogramma
Licarsisalis Walker), Spodopterafrugiperda (Spodoptera
Fugiperda), meadow mythimna separata (Spodoptera frugiperda), looper (Rachiplusia nu), soybean noctuid (Pseudoplusia
Includens), Sesamia inferens (Sesamia inferens), rice leaf roller (Cnaphalocrocis medinalis Guenee), beanpod open country snout moth's larva (Maruca testulalis), striped rice borer (Cirphis
Unipuncta), Liriomyza brponiae (Tuta absoluta), cabbage looper (Trichoplusia ni), powder stem snout moth's larva (Sesamia
Nonagrioides), cabbage looper (Trichoplusia ni), pears beans noctuid (Anticarsia gemmatalis), oriental fruit months (Grapholitha
Molesta), Lee's Grapholita spp (Cydia funebrana), Lee's Grapholita spp (Grapholitha funebrana), phthorimaea operculella (Phthorimaea
Operculella), gelechiid (Sitotroga cerealella), cotton spot reality moth (Earias vittella Fabricius), adoxophyes moth (Adoxophyes
Orana), pink bollworm (Pectinophoragossypiella Saunders), bollworm (Helicoverpaarmigera H ü bner), bollworm (Heliothis armigera), cotton leaf ripple noctuid (Alabama
Argillacea), lymantria monacha (Lymantria monacha), codling moth (Cydia pomonella), apple brown bortrix (Pandemis
Heparana), grape olethreutid (Lobesia botrana), pilleriana (Sparganothis pilleriana), grape-berry moth (Endopiza
ViteanaClemens), yellow rice borer (Scirpophaga
Incertulas), beet armyworm (Spodopteraexigua H ü bner), prodenia litura (Spodoptera
Litura), pear leaf blister moth (Leucoptera scitella), tobacco powder sp (Ephestia elutella), tobacco budworm (Heliothis
Virescens), night steinernema (Epinotia aporema), casemaking clothes moth (Tineola bisselliella), India paddy spot moth (Plodia
Interpunctella), corn borer (Ostrinianubilalis
Hübner)；
Diptera pest, such as Aedes aegypti (Aedes aegypti), dish latent fly (Liriomyza brassicae), Sarcophaga haemorrhoidalis (Sarcophaga
Haemorrhoidalis), glossina morsitans (Glossina
Morsitans), onion fly (Phorbia antiqua), Mediterranean fruitfly (Ceratitis capitata), wild cabbage ground Hylemyia Platura Meigen (Delia
Radicum), melon fly (Dacus cucurbitae), red original horsefly (Tabanus lineola), calliphora erythrocephala (Calliphora
Vicina), carrot fly (Psila rosae), citrus fruit fly (Bactrocera dorsalis), furious Storehouse midge (Culicoides furens), perverse disturb yellow-fever mosquito (Aedes
Vexans), blue tangerine is around trypetid (Rhagoletis mendax), calliphorid (Chrysomya spp., deer horsefly (Chrysops
Spp.), deerfly (Chrysops discalis), radish fly (Phorbia brassicae), wheat midge (Sitodiplosis
Mosellana), wheat cecidomyiia (Mayetiola destructor), matchmaker's spot mosquito (Culex tarsalis), U.S. Liriomyza (Liriomyza trifolii), Rhagoletis pomonella (Rhagoletis
Pomonella), Hippelates (Hippelates), peach trypetid (Bactrocera zonata), henbane seed spring fly (Pegomya
Hysocyami), beet spring fly (Pegomya betae), lucilia cuprina (Lucilia cuprina), Culex quinquefasciatus (Culex
Quinquefasciatus), the latent fly (Agromyza of alfalfa
frontella)；
Semiptera and homoptera pest, such as white backed planthopper (Sogatellafurcifera Horvath), trialeurodes vaporariorum (Trialeurodes vaporariorum), icerya purchasi (Ieryapurchasi
Maskell cotton a red-spotted lizard (Icerya purchasi), big Leptocorisa spp (Leptocorisa oratorius), soybean aphid (Aphis), are blown
Glycines), root of Beijing euphorbia Macrosiphus spp (Macrosiphum euphorbiae), planthopper (Nilaparvata lugens), brown plant-hopper (Nilaparvata
Lugens), brevicoryne brassicae (Brevicoryne brassicae), sweet potato whitefly (Bemisia tabaci), citrus psylla (Diaphorina
Citri), rice green leafhopper (Nephotettix nigropictus), ceroplastes rubens (Ceroplastes rubens), California red scale (Aonidiella
Aurantii), phorodon aphid (Phorodon humuli), small brown rice planthopper (Laodelphax striatellus), cowpea aphid (Aphis
Craccivora Koch), potato person of outstanding talent fleahopper (Calocoris
Norvegicus), grain aphid (Sitobion avenae Fabricius), grain aphid (Macrosiphum avenae), green bugs (Schizaphis
Graminum), wheat two branches off aphid (Schizaphis graminum Rondani), Diuraphis noxia (Diuraphis noxia), wheat without net aphid (Metopolophium
Dirhodum), red cotton bug (Dysdercus cingulatus), cotten aphid (Aphis gossypiiGlover), clover acyrthosiphum pisim (Acyrthosiphon
Pisum), eriosoma lanigerum (Eriosoma lanigerum), apple aphid (Aphis pomi), apple sucker (Psylla
Mali), peach short-tail aphid (Brachycaudus persicae), black peach aphid (Myzuspersicae Sulzer), acyrthosiphum pisim (Acyrthisiphon
Pisum Harris), Trialeurodes vaporariorum Westwood (Trialeurodes vaporariorum), lettuce aphid (Nasonovia ribisnigri Mosley), Bemisia tabaci (Bemisia tabaci Gennadius), leafhopper (Empoasca
Spp.), popcorn wing plant hopper (Peregrinus maidis), com planthopper (Peregrinus maidisAshmead), corn leaf aphids (Rhopalosiphum
Maidis), corn Rhopalosiphum spp (Rhopalosiphum maidis Fitch), taeniae planthopper (Sogatodes orizicola Muir)；
Orthoptera pest, such as Australian calamity locust (this Kui of Chortoicetes terminifer, fork-tail Zhong (Scudderia furcata), zonocerus variegatus (Zonozerus
Variegatus), Asiatic migrotory locust (Locusta migratoria), African mole cricket (Gryllotalpa africana), guiding principle wing spinelet Zhong (Microcentrum
Retinerve), shrub locust (Zonocerus spp.), blackspot arna Zhong (Anabrus simplex), the black locust (Melanoplus of red foot
Femurrubrum), acheta domestica (Acheta domesticus Linnaeus), residential house Chinese mugwort Xi (Acheta domestica), mole cricket (Scapteriscus
Vicinus Scudder), America desert locust (Schistocerca
Americana), America grasshopper (Schistocerca americana Drury), Morocco's halberd line locust (Dociostaurus maroccanus), the black locust (Melanoplus of Mexico
Mexicanus), South America mole cricket (Scapteriscus borellii Giglio-Tos), the black locust that migrates (Melanoplus sanguinipes), migrate locust (Locusta
MigratoriaLinnaeus grasshopper (Melanoplus), is migrated
SanguinipesFabricius, desert locust (Schistocerca
Gregaria Forskal), stone dwells black locust (Melanoplus
Spretus), the black locust of double cut (Melanoplus bivittatus), the red locust of striped (Nomadacris septemfasciata), front yard disease stove Zhong (Tachycines
Asynamorus), Italian locust (Calliptamus italicus), brown migratory locusts (Locustana pardalina)；
Coleopteran pest, such as acanthoscelides obtectus (Acanthoscelides obtectus), broad bean weevil (Bruchus rufimanus), pale neck are as (Hylobius
Pales), Otiorhynchus spp (Otiorrhynchus ovatus), red flour beetle (Tribolium castaneum), great Li gill cockchafers (Melolontha
Hippocastani), the light sufficient flea beetle (Phyllotreta nemorum) of soybean, big lesser grain borer (Prostephanus truncatus), rice water weevil (Lissorhoptrusoryzophilus
Kuschel), rice water weevil (Lissorhoptrus oryzophilus), paddy weevil (Sitophilus granarius Linnaeus), anoplophora glabripennis (Anoplophora glabripennis), black angle scotellaris (Oulema
Melanopus), Phyllotreta striolata (Phyllotreta striolata), leaf of pear tree are as (Phyllobius pyri), colorado potato bug (Leptinotarsa
Decemlineata Say), mango leaf-cutting is as (Deporaus
Marginatus), boll weevil (Anthonomus grandis Boheman), boll weevil (Anthonomus grandis), mexican bean ladybird (Epilachna
Varivestis), beet tortoise beetle (Cassida vittata), beet shin flea beetle (Chaetocnema tibialis), beet are as (Bothynoderes
Punctiventris), Atomaria linearis (Atomaria linearis), striped root nodule weevil (Sitona lineatus), pea weevil (Bruchus
Pisorum), May beetle (Melolontha melolontha), linear cylinder longicorn (Oberea Linearis), rusty grain beetle (Cryptolestes
Ferrugineus), lasioderma serricorne (Lasioderma serricorne), tobacco flea beetle (Epitrix hirtipennis), tobacco scotellaris (Lema
Bilineata), blister beetle tortoise is as (Ceutorhynchus napi), corn root leaf A (Diabroticavirgifera virgifera LeConte), corn click beetle (Melanotus communis), sitophilus zea-mais (Sitophilus
Zeamais), confused flour beetle (Tribolium confusum), annual bluegrass weevil (Listronotus maculicollis Dietz), alfalfa leaf are as (Hypera postica), the purple suede melolonthid (Maladera
CastaneaArrow), vertical pit cutting pin small moth (Blastophagus piniperda)；
Hymenoptera insect, such as Argentine ant (Iridomyrmex humilis), Argentine ant (Linepithema humile), smelly ant (Tapinoma
Sessile), kitchen ant (Monomorium pharaonis), black fiery ant (Solenopsis richtery), red fire ant (Solenopsis
Invicta), red ant (Pogonomyrmex barbatus), wasp (Polistes rubiginosa), yellow side wasp (Vespa
Crabro), Ji wasp (Dolichovespula maculata), act abdomen ant category (Crematogaster), the fiery ant (Solenopsis in south
Xyloni), leaf cutting ant (Atta cephalotes), Solenopsis geminata (Solenopsis geminata), velvet ant (Dasymutilla
Occidcntalis), small black ant (Monomorium minimum), Athaliarosae (Athalia rosae)；
Blattaria insect, such as Groton bug (Blattella germanica), oriental cockroach (Blatta orientalis), Pennsylvania wood Lian (Parcoblatta
Pennsylvanica), American cockroach (Periplaneta americana), Australian cockroach (Periplaneta australasiae), periplaneta brunnea (Periplaneta
Brunnea), smoke Perilpaneta americana (Periplaneta fuliginosa), the green blattaria of sugarcane (Pycnoscelus surinamensis) and long hair blattaria (Supella
longipalpa)；
Thysanoptera, such as cigarette brown thrip (Frankliniella fusca), Frankliniella occidentalis (Frankliniella occidentalis), greenhouse thrips (Heliothrips haemorrhaidalis), Rhipiphorothrips cruentatus, the hard thrips (Scirtothrips of tangerine
Citri), Scirothrips dorsalis (Scirtothrips dorsalis), yellow chest thrips (Thrips hawaiiensis), beans golden thistle horse (Thrips
Nigropilosus), east thrips (Thrips orientalis)；
Acarid, such as ornithonyssus bacoti (Ornithonyssus bacoti), castor bean tick (Ixodes ricinus), adobe tick (Argas
Persicus), Polyphagotarsonemus latus Banks (Polyphagotarsonemus latus), star tick long (Amblyomma americanum), Acarus siro (Acarus
Siro), Di Shi watts of mite (Varroa destructor), ilex Oligonychus (Oligonychus ilicus), Eotetranychus carpini (Eotetranychus
Carpini), Dermanyssus gallinae (Dermanyssus gallinae), itch mite (Sarcoptes scabiei), coffee unguiculus mite (Oligonychus
Coffee), priet mite (Brevipalpus obovatus), sheep scabies disease (Psoroptes ovis), cotton spider mites (Tetranychus
Telarius), ox tick (Boophilus annulatus), thorn apple rust mite (Aculus schlechtendali), panonychus ulmi (Panonychus
Ulmi), apple tetranychus (Panonychusulmi), torrid zone flower tick (Amblyomma variegatum), Pacific Ocean tetranychid (Tetranychus
Pacificus), ixodes pacificus (Ixodes pacificus), Tetranychus cinnabarinus (Tetranychus cinnabarinus), purplish red short hairs mite (Brevipalpus
Phoenicis), brown reclusion spider (Loxosceles reclusa).
Anoplura (Anoplura, Phthiraptera), such as Damalinia (
Damalinia spp.), Haematopinus (Haematopinus
Spp.), Linognathus (Linognathus spp.), Pediculus (Pediculus spp.), Trichodectes (Trichodectes
spp. )。
Isopoda（Isopoda）, for example, Cape jasmine beach louse（Oniscus asellus）, pillworm（Armadilliudium vulgare）, ball pillworm（Porcellio
scaber）.
Times sufficient mesh (Diplopoda), for example,
Blaniulus guttulatus 。
Lip foot mesh (Chi lopoda), for example, ground Scolopendra (
Geophilus carpophagusScutigera spp.) 。
Comprehensive mesh (Symphyla), for example, kahikatea worm (
Scutigerella immaculata)。
Thysanoptera (Thysanura), for example, silverfish (
Lepisma saccharina )。
Collembola (Collembola), for example, arms Onychiurus arcticus (
Onychiurus armatus)。
Dermaptera (Dermaptera), for example, European earwig (Forficula
auricularia) 。
Isoptera (lsoptera), for example, Reticulitermes kind (Reticulitermes
spp. )。
Nematoda（(Nematoda)）Representative biology have the nematode that nematode, stem eelworm and leaf nematode are formed selected from root-knot nematode, cyst.It is preferred that the soybean cyst nematode Heterodera glycines of following nematode（Heterodera）, globodera rostochiensis（golbodera
rostochiensis）, Meloidogyne incognita（meloidogyne incognita）Deng, lance line mesh（dorylaimida）In have, minute hand Turbatrix（longidorus
sp.）Deng.
Pesticidal combination of the invention is applied to preventing and treating Lepidoptera, coleoptera, Diptera, Thysanoptera and Hemipteran pest.
Pesticidal combination of the invention is particularly well-suited to preventing and treating Lepidoptera, Thysanoptera and Hemipteran pest.
Preferably, the Pesticidal combination is used to prevent and treat fleahopper silk worm, aphid, aleyrodid, plant hopper, scale insect, thrips, rice leaf roller, yellow rice borer, pachydiplosis oryzae, base of a fruit moth, red spider, prodenia litura, cabbage caterpillar, diamondback moth, beet armyworm, powder mosquito diamond-back moth, anthonomus grandis, striped flea-beetle, smaller green leaf hopper, root maggot, mythimna separata, nematode, wireworm, cutworm.
Present invention also offers a kind of method prevented or control harmful organism, Pesticidal combination of the invention is acted on into target useful plant, object noxious livings or its environment, the propagating materials of target useful plant.
Applicable useful plant includes Pesticidal combination of the invention：
Crops：Corn, paddy rice, wheat, barley, rye, oat, sorghum, cotton, soybean, red bean, Kidney bean, peanut, buckwheat, beet, rape, sunflower, sugarcane, tobacco etc.；
Vegetables：Solanum vegetables (eggplant, tomato, red green pepper, Chinese prickly ash, potato etc.), cucurbitaceae vegetable (cucumber, pumpkin, cucurbita pepo, watermelon, wax gourd, pumpkin etc.), brassicaceous vegetable (japanese radish, ternip, horseradish, root-mustard, Chinese cabbage, wild cabbage, leaf mustard, broccoli, cauliflower etc.), Aster section vegetables (burdock, garland chrysanthemum, jerusalem artichoke, romaine lettuce etc.), liliaceous vegetable（Shallot, onion, garlic, and asparagus）, ammiaceous vegetables（Carrot, caraway, celery, Indian Epimeredi Herb etc.）, goosefoot vegetable (spinach, Swiss chard etc.), Peppermint section vegetables（Perilla frutescens, peppermint, sweet basil etc.）, strawberry, sweet potato, dioscorea japonica and glycan etc.；
Flowers：Rose, China pink, chrysanthemum, tulip, rough gentian, orchid etc.；
Foliage plant；
Turfgrass；
Fruit tree：Pomaceous fruits fruit（Apple, European pear, Japanese pear, pawpaw, Wen Quinces etc.）, stone fruit (peach, plum, nectarine, Japanese Lee, cherry, apricot, plum etc.), citrus fruit（Satsuma orange, orange, lemon, come lemon, grape fruit etc.）, nut fruits (chestnut, English walnut, fibert, almond, American pistachios, cashew nut, macadamia etc.), berries (blueberry, the red certain kind of berries, blackberry, blueberry, mountain is mould etc.), grape, persimmon, olive, plum, banana, coffee, nipa palm and coconut etc.；
Trees beyond fruit tree：Tea tree, mulberry tree, flowering tree, shade tree（Chinese scholartree, birch, Fructus Corni, eucalyptus, ginkgo, lilac, maple, robur, willow, cercis, sweetgum, plane tree, Chinese juniper tree, pine tree, dragon spruce and taxus chinensis in northeast）Deng.
The implication of plant herein is interpreted as all plants and plant population.Plant is can be by conventional breeding and method for optimizing or can be by biotechnology and genetic engineering method or the plant that can be obtained by the combination of these methods.The plant includes genetically modified plants, also including that can be weighed (plant by plant breeder
Breeders'rights) protection or the plant variety not being protected by it.The implication of plant parts is interpreted as the whole parts and organ above and below the ground of the plant, such as branch, leaf, Hua Hegen, and the example that can be mentioned that is leaf, pin, leaf, stem, dry, flower, fructification, fruit and seed, Yi Jigen, stem tuber and rhizome.The plant parts also include harvested material and asexual with generative propagation thing, such as transplant, stem tuber, rhizome, sprout and seed.
Pesticidal combination of the invention has systemic action, therefore composition of the invention is also suitable for protecting propagating materials such as seed, fruit, stem tuber or the kernel or plant cutting of plant not to be encroached on by harmful organism particularly insect, acarid, nematode.Therefore composition of the invention can be used for protect plants shootses in case foliar pest and for seed and root treatment in case soil pests.
Therefore, Pesticidal combination of the invention is suitable to Seed Treatment to protect seed in case insect pest, particularly soil-borne insects insect, and the plant roots that produce of protection and branch are in case soil pests and foliar pest.
Most of infringement to crop plants caused by insect just there occurs early in seed after memory period and seed are sown into soil and during plant germination or after germination.This stage is particularly critical, because just especially sensitive in the root and seedling of growing plant, even small infringement may also lead to the death of whole plant.Therefore, it is of specific interest that seed and germination plant are protected by using suitable composition.The germination plant and effective plant suppressed after being germinateed from soil or after emerging are also what be can be mentioned that.Young plant can carry out whole or Local treatment to be protected by dipping before transplantation.
Therefore; the invention further relates to one kind protection seed with pest control, particularly soil pests, and protection rice shoot root and branch are with pest control; the particularly method of soil and foliar pest, methods described was included in before sowing and/or seed is contacted with Pesticidal combination of the invention after vernalization.Method the present invention be more particularly directed to protect plant roots and branch.Protection plants shootses specifically preferred according to the invention are in case the method for perforation and sucking property insect.Soil pests are particularly preferably wireworm, cutworm, corn root leaf A.
Term " plant propagation material " is interpreted as referring to all plant parts for having a fertility, such as seed, and vegetable matter such as cuttage bar or stem tuber（Such as potato）.Therefore, plant part used herein includes plant propagation material.It is mentioned that such as seed（In the narrow sense）, root, fruit, stem tuber, bulb, rhizome and plant part.
Plant part and the plant organ for then growing are any parts of the plant produced by plant propagation material such as seed.Plant part, plant organ and plant can also be benefited from protects plant from plant disease by the way that composition is applied into plant propagation material.Certain plants part and some plant organs for then growing can also regard plant propagation material as, and its own can be applied with composition（Or treatment）；Certain plants part and certain plants Organoprotective plant are applied to from insect pest of the plant by by composition so as to the plant, other plant parts and the other plant organs that are produced by the plant part through processing and the plant organ through processing can also be benefited from.
The treatment of plant and plant part is directly carried out or carried out by acting on its environment, habitat or storage areas with conventional treatment method with the present composition, the conventional treatment method for example impregnates, is poured, spraying, atomizing, broadcast sowing, dust, mist formation, broadcast sowing, foam, coating, being coated with, the mode such as drip irrigation is applied to the blade of plant（Foliage applying）, the frequency and consumption of administration can be adjusted, adapt it to by the degree of the harmful organism infestation.
In order to process plant propagation material particularly seed, also stem tuber or grain can be in succession impregnated by with the liquid preparation of each active component, or be coated by with the wet or dry preparation for having combined, so as to active component is administered on seed（Coating）.
Composition of the invention is applied to seed with itself or suitable formulation.It is preferred that, seed is processed at steady state, so that treatment does not cause any infringement.Treatment to seed generally can be between harvesting and sowing any time carry out.It has to be noticed that the amount selection for being applied to the amount and/or other additives of the present composition of seed is not interfere with the germination of seed or will not damage gained plant generally during Seed Treatment.Seed Treatment is applied in before plant seeding and before plant emergence.
Composition of the invention is particularly advantageous for the seed for the treatment of plant propagation material, particularly paddy rice, rape, cotton, wheat, barley, soybean, corn, peanut.
A kind of method for protecting seed, it includes making seed prior to seeding and/or is contacted with the Pesticidal combination of the invention of cooperative effective quantity after vernalization.
A kind of seed for applying Pesticidal combination of the invention treatment.
The present composition can be applied to environment, habitat or the storage areas of plant growth.The environment of plant growth, habitat are the supporters for referring to make crops take root, grow, for example：Soil, water etc., specific raw material can use such as sand, float stone, vermiculite, diatomite, agar-agar, gelling material, polymer substance, asbestos, wood chip, bark etc..It is preferred that soil.
To the method in soil using medicament, for example liquid preparation is diluted in water or not diluted the medium method in the rice seedling bed of root or seedling for being directly applied to plant, the method that granule is disseminated in the rice seedling bed of the root of plant or seedling is had the method that pulvis, water dispersible granules etc. are sprayed in soil and are integrally mixed with soil prior to seeding, in being sprayed on implantation hole, seed furrow after pulvis, water-dispersible grain dilution agent before sowing or before serike body, in method sowed etc..
The present invention also provides a kind of cover crop in case the method for pest infestation, including jointly or separately applies reactive compound sulfoxaflor and ethiprole or apply sulfoxaflor and ethiprole successively and separate, sequentially or simultaneously apply sulfoxaflor, ethiprole.In the case of separate administration, order does not influence generally on the result of prophylactico-therapeutic measures.
On the other hand, treatment of the invention can also produce following super additive effect：Improve plant growth, improve to the tolerance of high temperature or low temperature, improve tolerance to arid or to water or soil salt content, improve Flowering quality, make harvesting is easier, it is ripe to accelerate, improves harvesting yield, improve harvested products quality and/or improve its nutritive value, improve the bin stability and/or its processing characteristics of harvested products.
It is common and favourable that Pesticidal combination of the invention is generally applied with following dosage：
- for leaf portion treatment：0.1-10000g/ha, preferably 10-1000g/ha, more preferably 20-300g/ha；For impregnating or instiling and apply, the dosage can also even be reduced, particularly when inert base such as asbestos or pearl rock is applied；
- for Seed Treatment：2-1000g/100kg seeds, preferably 3-700g/100kg seeds；
- for soil treatment：0.1-1000g/ha, preferably 1-500g/ha.
Above-mentioned dosage is only general exemplary dose, and those skilled in the art can adjust rate of application according to actual conditions and needs especially in accordance with the property and insect pest situation of pending plant or crop during actual administration.
Pesticidal combination of the invention applies also for resisting parazoon.
Purposes of the Pesticidal combination of the invention in the veterinary drug of confrontation parazoon.
Therefore, the purpose of the present invention also provide preventing and treating animal in and animal on parasite new method.It is a further object to provide the agricultural chemicals safer for animal.It is a further object to provide can the animal-use drug that uses of the dosage lower than existing agricultural chemicals.
Pesticidal combination of the invention is suitable to the internal and external parasite in confrontation animal and on animal.
Pesticidal combination of the invention is preferred for preventing and treating and prevents animal not affected including warm-blooded animal and fish and infect.Be preferred for preventing and treating and prevent domestic animal such as dog or cat in invasion and attack and infect.Pesticidal combination of the invention is suitable to interior suction and/or non-interior suction prevents and treats internal and/or vermin.Pesticidal combination of the invention is particularly well-suited to preventing and treating from Diptera, Siphonaptera and tick purpose insect.It is preferred for resisting mosquito and fly.
The present invention also provides a kind for the treatment of, preventing and treating and protects animal in case parasitic infestation and the method for infecting, and it includes the present composition of parasitical active amount or composition oral comprising it, part or parenteral or is applied to animal.
Pesticidal combination of the invention is also applied for preventing and treating the animal pest of closing space, particularly insect, spider and acarid, the closing space such as house, factory floor, office, cabin etc..They can be used to prevent and treat these insects in domestic insecticide products, their kinds to sensitive and resistance and active to all of stage of development.These insects include:
Scorpionida, for example, clamp scorpion (Buthus occitanus).
Acarina, such as adobe tick, stick up edge sharp-edged tick, Bryobia, Dermanyssus gallinae, family and eat sweet mite, tampan tick, brown dog tick, trombiculid (Trombicula
Alfreddugesi), Neutrombicula autumnalis, dermatophagoides pteronyssinus, dust mite
Araneida, such as cockle spider section, Yuan Zhu sections
Opiliones, for example, intend scorpion class (Pseudoscorpiones chelifer)
,Pseudoscorpiones cheiridium, Opiliones phalangium。
Isopoda, such as damp worm, pillworm.
Times sufficient mesh, for example, have a zebra land, mountain cricket Eimeria.
Lip foot mesh, such as Scolopendra.
Silverfish mesh, such as comb silverfish category, Lepisma saccarina, Lepismodes inquilinus.
Blattaria, such as oriental cockroach, Groton bug, Blatella (Blattella asahinai), leucophaea maderae, angle abdomen Lian category, wood Lian category, Australian cockroach, American cockroach, Periplanetabrunnea, Peroplaneta fluligginosa, long hair blattaria.
Saltatoria, such as family Shuai.
Dermaptera, such as European earwig.
Isoptera, such as kalotermitid category, Reticulitermes.
Worm mesh, such as Lepinatus category, powder breathe heavily Eimeria
Coleoptera, such as Anthrenus, the moth-eaten category of fur, khapra beetle category, head lesser grain borer long, hidden instep cuckoo Eimeria, Ptinus, lesser grain borer, grain weevil, rice weevil, sitophilus zea-mais, Stegobium paniceum.
Diptera, such as Aedes aegypti, aedes albopictus, Aedes taeniorhynchus, Anopheles, calliphora erythrocephala, great number sarcophagid, Culex quinquefasciatus, northern house, Culex tarsalis, stay fly category, Fannia canicularis, housefly, Bai Ling category, sarcophagid (Sarcophaga carnaria), Simulium, male servant chela fly, daddy-longlegs (Tipula paludosa).
Lepidoptera, such as lesser wax-moth, galleria mellonella waxmoth, India Gu phycitid, rain moth, bag rain moth, Tineolabisselliella.
Siphonaptera, such as dog comb head lices, Ctenocephalides felis felis, humanlice, chigo, Xanthopsyllacheopis.
Hymenoptera, for example, blazon hunchbacked ant, bright hair ant, black wool ant, Lasius umbratus, MonomoriumMayr, Paravespula category, Pavement Ant.
Anoplura, such as head louse, body louse, crab louse.
Heteroptera, such as cimex hemipterus, bed bug, phodnius prolixus are invaded and harassed vertebra and hunt stinkbug.
Pesticidal combination of the invention can be used as aerosol, the evaporator that is driven without pressure spray product such as pump spraying and atomizer spray, automatic mist formation system, aerosol producer, foam, gel, the evaporator product of evaporating plate being made with cellulose or polymer, liquid evaporator, gel and film evaporator, propeller, do not consume energy or passive type vapo(u)rization system, catch moth paper, catch moth bag and insect-catching glue, agent or pulvis are drawn as, in the bait formulation of sprinkling or bait formulation position.
The present invention by both compound benefit have it is following some：
A, the activity of the Pesticidal combination exceed active sum when described two reactive compounds are each applied；This makes it possible to optimize the amount of reactive compound used；
B, both use with, solve the problems, such as lasting period and quick-acting, so as to reduce times for spraying, reduce cost of labor；
C, the generation for having delayed resistance：After both present invention compounding, both mechanisms of action and the mode of action are entirely different, there is good killing action after combination to low age and instar larvae high, and action site increases, and is conducive to overcoming and delaying the generation of pest resistance to insecticide.
Specific embodiment
The present invention is further described with reference to specific embodiment, but does not limit the invention to these specific embodiments.One skilled in the art would recognize that present invention encompasses all alternatives, improvement project and the equivalents that are potentially included in Claims scope.
Unless otherwise defined, ratio of the present invention is weight ratio, and content of the present invention is weight content.
Example of formulations
The ethiprole water dispersible granules of 1 4% sulfoxaflor of embodiment+32%
Weigh sulfoxaflor 4%, ethiprole 32%, APES formaldehyde condensation product 8%, calcium sulfate 5%, Arabic gum 4%, kaolin complements to 100%.Above-mentioned each component is mixed, is granulated, water dispersible granules are obtained.
The ethiprole water dispersible granules of 2 16% sulfoxaflor of embodiment+6%
Weigh sulfoxaflor 16%, ethiprole 6%, to methoxyl group fatty acyl anilinesulfonic acid 6%, AEO 5%, calcium sulfate 4%, xanthans 5%, bentonite complements to 100%.Above-mentioned each component is mixed, is granulated, water dispersible granules are obtained.
The ethiprole wettable powder of 3 45% sulfoxaflor of embodiment+5%
Weigh sulfoxaflor 45%, ethiprole 5%, dodecyl trimethyl ammonium salt 12%, triphenoethyl benzene phenol polyethenoxy ether 10%, attapulgite complements to 100%.Each component is mixed, ground, crushing is obtained wettable powder.
The ethiprole wettable powder of 4 2.5% sulfoxaflor of embodiment+37.5%
Weigh sulfoxaflor 2.5%, ethiprole 37.5%, polyoxyethylene lanolin alcohol 9%, polyoxyethylene lauryl ether carboxylic acid sodium 11%, diatomite complements to 100%.Each component is mixed, ground, crushing is obtained wettable powder.
The ethiprole suspending agent of 5 27% sulfoxaflor of embodiment+3%
Weigh sulfoxaflor 27%, ethiprole 3%, polyoxyethylene glyceryl mono fatty acid ester 12%, oleoyl methyl sodium taurocholate 6%, sodium alginate 5%, ethylene glycol 5%, phosphoric acid isobutyl ester 2%, water complements to 100%.Active ingredient and various auxiliary agents are mixed with water, after being sanded through high speed shear dispersion, sand mill, high dispersive, the suspension system of stabilization is formed, suspending agent is obtained.
The ethiprole suspending agent of 6 8% sulfoxaflor of embodiment+16%
Weigh sulfoxaflor 8%, ethiprole 16%, two polyoxyethylene lauryl ether ammonium phosphate 7%, dioctyl sodium sulphosuccinate 7%, sodium alginate 4%, propane diols 4%, phosphoric acid isobutyl ester 2%, water complements to 100%.Active ingredient and various auxiliary agents are mixed with water, after being sanded through high speed shear dispersion, sand mill, high dispersive, the suspension system of stabilization is formed, suspending agent is obtained.
The ethiprole microemulsion of 7 5% sulfoxaflor of embodiment+5%
Sulfoxaflor 5% is weighed, ethiprole 5%, acetone 12%, isopropanol 4%, lauryl sodium sulfate 20%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 4%, aluminium-magnesium silicate 5%, silicone 3%, glycerine 5%, butyl glycidyl ether 2%, water complements to 100%.Active ingredient solvent, cosolvent dissolving are prepared into oil phase, other each components are added to the water to stir are prepared into water phase, oil phase is then added into water phase while stirring, stirred, microemulsion is obtained.
The ethiprole microemulsion of 8 15% sulfoxaflor of embodiment+5%
Sulfoxaflor 15% is weighed, ethiprole 5%, acetone 20%, isopropanol 6%, neopelex 24%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, sodium carboxymethylcellulose 4%, butylphosphoric acid ester 3%, glycerine 5%, butyl glycidyl ether 4%, water complements to 100%.Active ingredient solvent, cosolvent dissolving are prepared into oil phase, other each components are added to the water to stir are prepared into water phase, oil phase is then added into water phase while stirring, stirred, microemulsion is obtained.
The ethiprole aqueous emulsion of 9 9% sulfoxaflor of embodiment+11%
Weigh sulfoxaflor 9%, ethiprole 11%, dimethylformamide 18%, Polyoxyethylene fatty acid amides fatty acid ester 9%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, aluminium-magnesium silicate 4%, butylphosphoric acid ester 2%, glycerine 5%, water complements to 100%.The dissolving of active ingredient solvent is prepared into oil phase, other each components are added to the water to stir are prepared into water phase, oil phase is then added into water phase while stirring, stirred, aqueous emulsion is obtained.
The ethiprole aqueous emulsion of 10 10% sulfoxaflor of embodiment+15%
Weigh sulfoxaflor 10%, ethiprole 15%, dimethylformamide 23%, styryl phenyl APEO 11%, p-hydroxyphenyl sodium lignin sulfonate 8%, sodium carboxymethylcellulose 4%, silicone 4%, glycerine 4%, triphenyl phosphite 2%, water complements to 100%.The dissolving of active ingredient solvent is prepared into oil phase, other each components are added to the water to stir are prepared into water phase, oil phase is then added into water phase while stirring, stirred, aqueous emulsion is obtained.
The ethiprole suspending agent of 11 14% sulfoxaflor of embodiment+16%
Weigh sulfoxaflor 14%, ethiprole 16%, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 9%, lauryl sodium sulfate 7%, Arabic gum 4%, propane diols 4%, silicone 3%, water complements to 100%.Active ingredient and various auxiliary agents are mixed with water, after being sanded through high speed shear dispersion, sand mill, high dispersive, the suspension system of stabilization is formed, suspending agent is obtained.
The ethiprole suspending agent of 12 2% sulfoxaflor of embodiment+3%
Weigh sulfoxaflor 2%, ethiprole 3%, polyoxyethylene glyceryl mono fatty acid ester 13%, dioctyl sodium sulphosuccinate 6%, Arabic gum 5%, propane diols 5%, silicone 2%, water complements to 100%.Active ingredient and various auxiliary agents are mixed with water, after being sanded through high speed shear dispersion, sand mill, high dispersive, the suspension system of stabilization is formed, suspending agent is obtained.
The ethiprole aqueous emulsion of 13 8% sulfoxaflor of embodiment+8%
Weigh sulfoxaflor 8%, ethiprole 8%, dimethylformamide 15%, neopelex 7%, polyoxyethylene alkyl amine 7%, sodium carboxymethylcellulose 3%, butylphosphoric acid ester 1%, propane diols 5%, water complements to 100%.The dissolving of active ingredient solvent is prepared into oil phase, other each components are added to the water to stir are prepared into water phase, oil phase is then added into water phase while stirring, stirred, aqueous emulsion is obtained.
The ethiprole aqueous emulsion of 14 10% sulfoxaflor of embodiment+10%
Weigh sulfoxaflor 10%, ethiprole 10%, dimethylformamide 22%, neopelex 10%, polyoxyethylene alkyl amine 11%, sodium carboxymethylcellulose 5%, silicone 4%, propane diols 5%, triphenyl phosphite 2%, water complements to 100%.The dissolving of active ingredient solvent is prepared into oil phase, other each components are added to the water to stir are prepared into water phase, oil phase is then added into water phase while stirring, stirred, aqueous emulsion is obtained.
The ethiprole microemulsion of 15 5% sulfoxaflor of embodiment+5%
Sulfoxaflor 5% is weighed, ethiprole 5%, dichloromethane 15%, isopropanol 3%, calcium dodecyl benzene sulfonate 18%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, sodium carboxymethylcellulose 4%, silicone 4%, propane diols 4%, butyl glycidyl ether 2%, water complements to 100%.Active ingredient solvent, cosolvent dissolving are prepared into oil phase, other each components are added to the water to stir are prepared into water phase, oil phase is then added into water phase while stirring, stirred, microemulsion is obtained.
The ethiprole microemulsion of 16 5% sulfoxaflor of embodiment+15%
Sulfoxaflor 5% is weighed, ethiprole 15%, dichloromethane 24%, isopropanol 6%, calcium dodecyl benzene sulfonate 19%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 10%, polyvinyl alcohol 5%, butylphosphoric acid ester 2%, propane diols 5%, butyl glycidyl ether 4%, water complements to 100%.Active ingredient solvent, cosolvent dissolving are prepared into oil phase, other each components are added to the water to stir are prepared into water phase, oil phase is then added into water phase while stirring, stirred, microemulsion is obtained.
The ethiprole water dispersible granules of 17 0.5% sulfoxaflor of embodiment+24.5%
Weigh sulfoxaflor 0.5%, ethiprole 24.5%, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 9%, oleoyl methyl sodium taurocholate 10%, sodium carboxymethyl starch 5%, xanthans 5%, kaolin complements to 100%.Above-mentioned each component is mixed, is granulated, water dispersible granules are obtained.
The ethiprole water dispersible granules of 18 50% sulfoxaflor of embodiment+10%
Weigh sulfoxaflor 50%, ethiprole 10%, aliphatic alcohol polyoxyvinethene phosphate 5%, N- sodium lauroyl glutamates 9%, sodium carboxymethyl starch 3%, xanthans 4%, attapulgite complements to 100%.Above-mentioned each component is mixed, is granulated, water dispersible granules are obtained.
The ethiprole wettable powder of 19 30% sulfoxaflor of embodiment+50%
Weigh sulfoxaflor 30%, ethiprole 50%, polyoxyethylene alkylaryl ether 4%, trisiloxanes APEO 8%, attapulgite complements to 100%.Each component is mixed, ground, crushing is obtained wettable powder.
The ethiprole wettable powder of 20 40% sulfoxaflor of embodiment+50%
Weigh sulfoxaflor 40%, ethiprole 50%, polyoxyethylene lanolin alcohol 3%, trisiloxanes APEO 2%, diatomite complements to 100%.Each component is mixed, ground, crushing is obtained wettable powder.
Above-described embodiment proportioning is weight per distribution ratio.
Indoor biological is tested
1
, to black peach aphid
(Myzuspersicae
Sulzer)
Indoor biological test
Subjects：Black peach aphid (Myzuspersicae Sulzer), chooses healthy growth, nymph of the same size for raw test.
Test method with reference to " leaf dipping method " and《Farm-chemical indoor determination test rule NY/T 1154.7-2006》The part of insecticide the 7th " synergy of mixture is determined ", determines the indoor biological activity of the compounding to test worm of sulfoxaflor, ethiprole and the two different proportion.
Will each proportioning medicament acetone solution described in following table, and with 0.1% Tween 80 solution into series concentration.Then, ready peach blade is impregnated into 30s in liquid, taking-up is dried, is placed in the culture dish of diameter 10cm, often process 4 repetitions, and set without medicament（Containing solvent and emulsifying agent）Treatment do blank.Then, 15 test worms are accessed per ware, temperature is placed in for 25 DEG C ± 1 DEG C, relative humidity 60-80%, periodicity of illumination are L:D=(16:8) test worm is raised under the conditions of, inspection result after 48h calculates the death rate, and calculate the LC of each treatment50, the then co-toxicity coefficient with co-toxicity coefficient method calculation composition under each ratio.
Co-toxicity coefficient computational methods are as follows：
=
If co-toxicity coefficient is more than 120, show there is synergistic effect；If being less than 80, antagonism is shown to be；If between 80~120, being shown to be summation action.
The sulfoxaflor of table 1 is with Firponil compounded to black peach aphid Toxicity Determination result
Toxicity Determination result shows that sulfoxaflor is with ethiprole 100:1-1:In 100 proportion, the co-toxicity coefficient to test worm is all higher than 120, shows synergistic effect.
, to the test of the indoor biological of cotton plant bug silk worm
Subjects：Cotton plant bug silk worm, chooses healthy growth, adult of the same size for raw test.
Test method with reference to " leaf dipping method " and《Farm-chemical indoor determination test rule NY/T 1154.7-2006》The part of insecticide the 7th " synergy of mixture is determined ", determines the indoor biological activity of the compounding to test worm of sulfoxaflor, ethiprole and the two different proportion.
Will each proportioning medicament acetone solution described in following table, and with 0.1% Tween 80 solution into series concentration.Then, ready cotton leaf is impregnated into 30s in liquid, taking-up is dried, and is placed in dactylethrae, often processes 4 repetitions, and set without medicament（Containing solvent and emulsifying agent）Treatment do blank.Then, 20 test worms are accessed per ware, temperature is placed in for 25 DEG C ± 1 DEG C, relative humidity 60-80%, periodicity of illumination are L:D=(16:8) test worm is raised under the conditions of, inspection result after 48h calculates the death rate, and calculate the LC of each treatment50, the then co-toxicity coefficient with foregoing co-toxicity coefficient method calculation composition under each ratio.
The sulfoxaflor of table 2 is with Firponil compounded to cotton plant bug silk worm Toxicity Determination result
Toxicity Determination result shows that sulfoxaflor is with ethiprole 100:1-1:In 100 proportion, the co-toxicity coefficient to test worm is all higher than 120, shows synergistic effect.
To the Toxicity Determination result of diamondback moth
Subjects：Diamondback moth, chooses healthy growth, the larva in 1-2 ages of the same size for raw test.
Test method with reference to " leaf dipping method " and《Farm-chemical indoor determination test rule NY/T 1154.7-2006》The part of insecticide the 7th " synergy of mixture is determined ", determines the indoor biological activity of the compounding to test worm of sulfoxaflor, ethiprole and the two different proportion.
Will each proportioning medicament acetone solution described in following table, and with 0.1% Tween 80 solution into series concentration.Then, ready cotton leaf is impregnated into 30s in liquid, taking-up is dried, and is placed in dactylethrae, often processes 4 repetitions, and set without medicament（Containing solvent and emulsifying agent）Treatment do blank.Then, 20 test worms are accessed per ware, temperature is placed in for 25 DEG C ± 1 DEG C, relative humidity 60-80%, periodicity of illumination are L:D=(16:8) test worm is raised under the conditions of, inspection result after 48h calculates the death rate, and calculate the LC of each treatment50, the then co-toxicity coefficient with foregoing co-toxicity coefficient method calculation composition under each ratio.
The sulfoxaflor of table 3 is with Firponil compounded to diamondback moth Toxicity Determination result
Toxicity Determination result shows that sulfoxaflor is with ethiprole 100:1-1:In 100 proportion, the co-toxicity coefficient to test worm is all higher than 120, shows synergistic effect.
Claims (16)
1. a kind of Pesticidal combination, it is characterised in that：Active component is made up of sulfoxaflor and ethiprole, and sulfoxaflor and ethiprole weight proportion are 1:100-100:1.
2. Pesticidal combination according to claim 1, it is characterised in that：The sulfoxaflor and ethiprole weight proportion are 1:50-50:1.
3. Pesticidal combination according to claim 1, it is characterised in that：The sulfoxaflor and ethiprole weight proportion are 1:25-25:1.
4. Pesticidal combination according to claim 1, it is characterised in that：The sulfoxaflor and ethiprole weight proportion are 1:10-10:1.
5. Pesticidal combination according to claim 1, it is characterised in that：The sulfoxaflor and ethiprole weight proportion are 1:5-5:1.
6. Pesticidal combination according to claim 1, it is characterised in that：Also include filler and/or surfactant.
7. Pesticidal combination according to claim 1, it is characterised in that：The formulation of the composition is that suspending agent, seed coat agent, wettable powder, water dispersible granules, microcapsule suspending agent, coated granule, granule, water-soluble granule, water solube powder, aqua missible oil, microemulsion, aqueous emulsion, effervescent tablet, Seed Treatment dispersible granula.
8. Pesticidal combination according to claim 1, it is characterised in that：The content of the sulfoxaflor and ethiprole accounts for the 5%-90% of composition, more preferably preferably 10%-80%, 20%-60%.
9. Pesticidal combination according to claim 1, it is characterised in that：The content of the sulfoxaflor and ethiprole accounts for the 10%-80% of composition.
10. Pesticidal combination according to claim 1, it is characterised in that：The content of the sulfoxaflor and ethiprole accounts for the 20%-60% of composition.
11. Pesticidal combinations according to claim 1 are used to prevent or control the purposes of harmful organism.
12. Pesticidal combinations according to claim 1 are used to preventing or control insect, the purposes of acarid or nematode.
13. Pesticidal combinations according to claim 1 are used to prevent and treat fleahopper silk worm, aphid, aleyrodid, plant hopper, scale insect, thrips, rice leaf roller, yellow rice borer, pachydiplosis oryzae, base of a fruit moth, red spider, prodenia litura, cabbage caterpillar, diamondback moth, beet armyworm, powder mosquito diamond-back moth, anthonomus grandis, striped flea-beetle, smaller green leaf hopper, root maggot, mythimna separata, nematode, wireworm, cutworm.
A kind of 14. methods prevented or control harmful organism, it is characterised in that：The Pesticidal combination of claim 1 is acted on into target useful plant, object noxious livings or its environment, the propagating materials of target useful plant.
A kind of 15. protection seeds are in case soil insect and protection seedling root and branch are in case the method for soil and foliar insect, it is characterised in that：It is included in before sowing and/or seed is contacted with the Pesticidal combination described in claim 1 after vernalization.
16. Pesticidal combinations according to claim 1 are used to resist the purposes in the veterinary drug of parazoon.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102017978A (en) * | 2011-01-07 | 2011-04-20 | 陕西上格之路生物科学有限公司 | Pesticidal composition containing Sulfoxaflor and butene-fipronil |
| CN102271512A (en) * | 2008-12-29 | 2011-12-07 | 拜耳作物科学公司 | Treatment of transgenic crops with mixtures of fiproles and chloronicotinyls |
| CN103755487A (en) * | 2013-12-31 | 2014-04-30 | 灵川县金田农资经营部 | Biogas slurry compound insecticide for preventing and treating aphid |
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2015
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102271512A (en) * | 2008-12-29 | 2011-12-07 | 拜耳作物科学公司 | Treatment of transgenic crops with mixtures of fiproles and chloronicotinyls |
| CN102017978A (en) * | 2011-01-07 | 2011-04-20 | 陕西上格之路生物科学有限公司 | Pesticidal composition containing Sulfoxaflor and butene-fipronil |
| CN103755487A (en) * | 2013-12-31 | 2014-04-30 | 灵川县金田农资经营部 | Biogas slurry compound insecticide for preventing and treating aphid |
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| 陈世军主编: "《抗感染药物兽医临床应用》", 25 December 2014 * |
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