CN106638122A - Macromolecular antibacterial raw paper material for packaging cartons and preparation method thereof - Google Patents

Macromolecular antibacterial raw paper material for packaging cartons and preparation method thereof Download PDF

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Publication number
CN106638122A
CN106638122A CN201611181040.6A CN201611181040A CN106638122A CN 106638122 A CN106638122 A CN 106638122A CN 201611181040 A CN201611181040 A CN 201611181040A CN 106638122 A CN106638122 A CN 106638122A
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parts
mentioned
stirred
dispersion liquid
added
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CN201611181040.6A
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CN106638122B (en
Inventor
李小卫
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NINGBO YIFULE BIOTECHNOLOGY CO., LTD.
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Ningbo Lan-Star Packing Printing Co Ltd
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/66—Salts, e.g. alums
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/36—Inorganic fibres or flakes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/07—Nitrogen-containing compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/10—Phosphorus-containing compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/11—Halides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/13—Silicon-containing compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14—Carboxylic acids; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/35—Polyalkenes, e.g. polystyrene
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/53—Polyethers; Polyesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10—Packing paper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Paper (AREA)

Abstract

The invention discloses a macromolecular antibacterial raw paper material for packaging cartons and a preparation method thereof. The material is prepared from, by weight, 0.8-2 parts of alkenyl succinic anhydride, 0.5-1 part of hexamethyl phosphoryl triamide, 1-2 parts of sodium fluoroborate, 3-4 parts of palm wax, 0.8-2 parts of alkylolamides, 1-2 parts of sodium benzoate, 0.4-1 part of ammonium molybdate, 0.8-1 part of 2-bromo-4-methylphenol, 2-3 parts of polyacrylamide, 0.3-1 part of fatty acid polyglycol ester, 1.5-2 parts of calcium linoleate, 2.6-3 parts of benzyl triphenyl phosphonium chloride, 17-20 parts of styrene, 0.5-1 part of dodecyl trimethyl ammonium chloride, 2-3 parts of calcium propionate, 90-100 parts of bamboo pulp, 10-14 parts of mineral wool fibers, 30-40 parts of jute pulp, 0.4-1 part of a silane coupling agent kh5600, 3-5 parts of artemisia seed glue and 0.1-0.2 part of ammonium persulfate. High dimensional stability, great antibacterial performance, excellent comprehensive performance and long service life of finished products are realized.

Description

A kind of Packaging Box antibacterial body paper material of macromolecule and preparation method thereof
Technical field
The present invention relates to Packaging Box field of material technology, more particularly to a kind of Packaging Box antibacterial body paper material of macromolecule Material and preparation method thereof.
Background technology
In recent years, with the continuous improvement of people's living standard, the use range of Packaging Box is also increasingly wider, not only wraps Traditional household items are included, also including various aquatic products, fresh, chemical drugss etc., it is more preferable that this requires that Packaging Box has The materials such as protective value, the employing velveteen that traditional Packaging Box has, paper pulp fiber length is longer made by these, and fiber is very curved Song, poor dimensional stability, and with very strong water absorption, the environment for running into humidity is easy for damage, meanwhile, paper material conduct One of common used material, is the field closely related with people's life, and in people's life Packaging Box is all likely to be exposed everywhere.Cause This, in order to prevent Packaging Box use during noxious bacteria propagation caused by various diseases, protect human body health, Health is ground, Packaging Box of the research and development with anti-microbial property is also necessary, therefore we are accomplished by constantly raising The combination property of Packaging Box, meets its use in each packaging field, improves the use environment of safety and environmental protection.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of Packaging Box antibacterial body paper of macromolecule Material and preparation method thereof.
The present invention is achieved by the following technical solutions.
A kind of Packaging Box antibacterial body paper material of macromolecule, it is by made by the raw material of following weight parts：
Alkenyl succinic anhydride 0.8-2, HMPA 0.5-1, Sodium fluoroborate 1-2, palm wax 3-4, alkylolamideses 0.8-2, sodium benzoate 1-2, ammonium molybdate 0.4-1,2- bromo-4-methylphenol 0.8-1, polyacrylamide 2-3, fatty acid polyglycol second two Alcohol ester 0.3-1, linoleic acid calcium soap 1.5-2, benzyl triphenyl phosphonium chloride phosphine 2.6-3, styrene 17-20, trimethyl chlorine Change ammonium 0.5-1, calcium propionate 2-3, bamboo pulp 90-100, mineral wool fiber 10-14, jute pulp 30-40, silane coupler kh560 0.4-1, Artemisia glue 3-5, Ammonium persulfate. 0.1-0.2.
A kind of described Packaging Box preparation method of the antibacterial body paper material of macromolecule, comprises the following steps：
（1）Above-mentioned alkenyl succinic anhydride is added in the deionized water of its weight 27-30 times, is stirred, rising high-temperature is 50-60 DEG C, insulated and stirred 3-5 minute, obtain anhydride aqueous solution；
（2）By above-mentioned sodium benzoate, ammonium molybdate, calcium propionate mixing, in being added to the deionized water of compound weight 30-40 times, Stir, add abovementioned alkyl alkylolamides, stir, obtain antibacterial dispersion liquid；
（3）Above-mentioned 2- bromo-4-methylphenols are added in the dehydrated alcohol of its weight 67-70 times, are stirred, rise high-temperature For 60-65 DEG C, above-mentioned benzyl triphenyl phosphonium chloride phosphine, palm wax, linoleic acid calcium soap, insulated and stirred 20-30 minute, in addition are added Fatty acid polyethylene glycol ester is stated, is stirred to room temperature, obtain anti-corrosion alcohol dispersion liquid；
（4）Above-mentioned Dodecyl trimethyl ammonium chloride is added in jute pulp, is stirred, add above-mentioned hexamethyl phosphinylidyne three Amine, stirs, and obtains jute pulp dispersion liquid；
（5）Above-mentioned styrene is added in anti-corrosion alcohol dispersion liquid, is stirred, be passed through nitrogen, add above-mentioned anhydride aqueous solution, It is 70-74 DEG C to rise high-temperature, adds above-mentioned Ammonium persulfate., insulation reaction 3-4 hour, add above-mentioned jute pulp dispersion liquid, antibacterial point Dispersion liquid, ultrasonic agitation 4-7 minute, adds above-mentioned artemisia glue, stirs, and obtains graft polymers mucus；
（6）Above-mentioned mineral wool fiber is added in its weight 10-12 times, 70-75% ethanol solution, adds above-mentioned grafting to gather Compound mucus, silane coupler kh560, it is 51-60 DEG C to rise high-temperature, and insulated and stirred 1-2 hour obtains silanol dispersion liquid；
（7）Above-mentioned silanol dispersion liquid is mixed with remaining each raw material, is stirred, in being added to beater, beating, in 60- 20-30 minutes are incubated at 70 DEG C, Jing is discongested, defibrination, add water to solid content for 4-6%, manufactured paper with pulp molding by paper machine, dehydration is dried It is dry, obtain body paper material.
It is an advantage of the invention that：
The present invention adopt styrene for monomer, and Ammonium persulfate. is initiator, and calcium propionate, sodium benzoate etc. are antibacterial auxiliary agent, is gathering The polymer mucus with high-efficiency antimicrobial performance is obtained during conjunction, has then been surface-treated by silane coupler, carried The high compatibility between polymer mucus and fibrous raw material, improves the dimensional stability of product, and the finished product of the present invention has very Dimensional stability well and bacteriostasis property, combination property is superior, long perfomance life.
Specific embodiment
The following is embodiments of the invention one.
A kind of Packaging Box antibacterial body paper material of macromolecule, it is by made by the raw material of following weight parts：
Alkenyl succinic anhydride 0.8, HMPA 0.5, Sodium fluoroborate 1, palm wax 3, alkylolamideses 0.8, benzoic acid Sodium 1, ammonium molybdate 0.4,2- bromo-4-methylphenols 0.8, polyacrylamide 2, fatty acid polyethylene glycol ester 0.3, linoleic acid calcium soap 1.5th, benzyl triphenyl phosphonium chloride phosphine 2.6, styrene 17, Dodecyl trimethyl ammonium chloride 0.5, calcium propionate 2, bamboo pulp 90, mineral wool Fiber 10, jute pulp 30, silane coupler kh560 0.4, artemisia glue 3, Ammonium persulfate. 0.1.
The following is embodiments of the invention two.
A kind of Packaging Box antibacterial body paper material of macromolecule, it is by made by the raw material of following weight parts：
Alkenyl succinic anhydride 1.5, HMPA 0.7, Sodium fluoroborate 1.5, palm wax 3.5, alkylolamideses 1.5, benzene Sodium formate 1.4, ammonium molybdate 0.6,2- bromo-4-methylphenols 0.9, polyacrylamide 2.4, fatty acid polyethylene glycol ester 0.7, sub- oil Sour calcium soap 1.6, benzyl triphenyl phosphonium chloride phosphine 2.8, styrene 19, Dodecyl trimethyl ammonium chloride 0.7, calcium propionate 2.5, bamboo pulp 95th, mineral wool fiber 12, jute pulp 34, silane coupler kh560 0.8, artemisia glue 4, Ammonium persulfate. 0.1.
The following is embodiments of the invention three.
A kind of Packaging Box antibacterial body paper material of macromolecule, it is by made by the raw material of following weight parts：
Alkenyl succinic anhydride 2, HMPA 1, Sodium fluoroborate 2, palm wax 4, alkylolamideses 2, sodium benzoate 2, molybdenum Sour ammonium 1,2- bromo-4-methylphenols 1, polyacrylamide 3, fatty acid polyethylene glycol ester 1, linoleic acid calcium soap 2, benzyltriphenyl phosphonium chlorine Change phosphine 3, styrene 20, Dodecyl trimethyl ammonium chloride 1, calcium propionate 3, bamboo pulp 100, mineral wool fiber 14, jute pulp 40, silane idol Connection agent kh560 1, artemisia glue 5, Ammonium persulfate. 0.2.
A kind of described Packaging Box preparation method of the antibacterial body paper material of macromolecule, comprises the following steps：
（1）Above-mentioned alkenyl succinic anhydride is added in the deionized water of 27 times of its weight, is stirred, it is 50 to rise high-temperature DEG C, insulated and stirred 3 minutes obtains anhydride aqueous solution；
（2）By above-mentioned sodium benzoate, ammonium molybdate, calcium propionate mixing, in being added to the deionized water of 30 times of compound weight, stirring Uniformly, abovementioned alkyl alkylolamides is added, is stirred, obtain antibacterial dispersion liquid；
（3）Above-mentioned 2 bromomethyl phenol is added in the dehydrated alcohol of 67 times of its weight, is stirred, it is 60 DEG C to rise high-temperature, Above-mentioned benzyl triphenyl phosphonium chloride phosphine, palm wax, linoleic acid calcium soap, insulated and stirred 20 minutes is added to add above-mentioned fatty acid polyglycol second Diol ester, stirs to room temperature, obtains anti-corrosion alcohol dispersion liquid；
（4）Above-mentioned Dodecyl trimethyl ammonium chloride is added in jute pulp, is stirred, add above-mentioned hexamethyl phosphinylidyne three Amine, stirs, and obtains jute pulp dispersion liquid；
（5）Above-mentioned styrene is added in anti-corrosion alcohol dispersion liquid, is stirred, be passed through nitrogen, add above-mentioned anhydride aqueous solution, It is 70 DEG C to rise high-temperature, adds above-mentioned Ammonium persulfate., insulation reaction 3 hours to add above-mentioned jute pulp dispersion liquid, antibacterial dispersion liquid, Ultrasonic agitation 4 minutes, adds above-mentioned artemisia glue, stirs, and obtains graft polymers mucus；
（6）Above-mentioned mineral wool fiber is added in 10 times of its weight, 70% ethanol solution, adds above-mentioned graft polymers to stick Liquid, silane coupler kh560, it is 51 DEG C to rise high-temperature, and insulated and stirred 1 hour obtains silanol dispersion liquid；
（7）Above-mentioned silanol dispersion liquid is mixed with remaining each raw material, is stirred, in being added to beater, beating, at 60 DEG C Lower insulation 20 minutes, Jing is discongested, defibrination, adds water to solid content for 4%, is manufactured paper with pulp molding by paper machine, and dehydration, drying obtains body paper material Material.

Claims (2)

1. a kind of Packaging Box antibacterial body paper material of macromolecule, it is characterised in that it is made up of the raw material of following weight parts 's：
Alkenyl succinic anhydride 0.8-2, HMPA 0.5-1, Sodium fluoroborate 1-2, palm wax 3-4, alkylolamideses 0.8-2, sodium benzoate 1-2, ammonium molybdate 0.4-1,2- bromo-4-methylphenol 0.8-1, polyacrylamide 2-3, fatty acid polyglycol second two Alcohol ester 0.3-1, linoleic acid calcium soap 1.5-2, benzyl triphenyl phosphonium chloride phosphine 2.6-3, styrene 17-20, trimethyl chlorine Change ammonium 0.5-1, calcium propionate 2-3, bamboo pulp 90-100, mineral wool fiber 10-14, jute pulp 30-40, silane coupler kh560 0.4-1, Artemisia glue 3-5, Ammonium persulfate. 0.1-0.2.
2. a kind of Packaging Box as claimed in claim 1 preparation method of the antibacterial body paper material of macromolecule, it is characterised in that Comprise the following steps：
（1）Above-mentioned alkenyl succinic anhydride is added in the deionized water of its weight 27-30 times, is stirred, rising high-temperature is 50-60 DEG C, insulated and stirred 3-5 minute, obtain anhydride aqueous solution；
（2）By above-mentioned sodium benzoate, ammonium molybdate, calcium propionate mixing, in being added to the deionized water of compound weight 30-40 times, Stir, add abovementioned alkyl alkylolamides, stir, obtain antibacterial dispersion liquid；
（3）Above-mentioned 2- bromo-4-methylphenols are added in the dehydrated alcohol of its weight 67-70 times, are stirred, rise high-temperature For 60-65 DEG C, above-mentioned benzyl triphenyl phosphonium chloride phosphine, palm wax, linoleic acid calcium soap, insulated and stirred 20-30 minute, in addition are added Fatty acid polyethylene glycol ester is stated, is stirred to room temperature, obtain anti-corrosion alcohol dispersion liquid；
（4）Above-mentioned Dodecyl trimethyl ammonium chloride is added in jute pulp, is stirred, add above-mentioned hexamethyl phosphinylidyne three Amine, stirs, and obtains jute pulp dispersion liquid；
（5）Above-mentioned styrene is added in anti-corrosion alcohol dispersion liquid, is stirred, be passed through nitrogen, add above-mentioned anhydride aqueous solution, It is 70-74 DEG C to rise high-temperature, adds above-mentioned Ammonium persulfate., insulation reaction 3-4 hour, add above-mentioned jute pulp dispersion liquid, antibacterial point Dispersion liquid, ultrasonic agitation 4-7 minute, adds above-mentioned artemisia glue, stirs, and obtains graft polymers mucus；
（6）Above-mentioned mineral wool fiber is added in its weight 10-12 times, 70-75% ethanol solution, adds above-mentioned grafting to gather Compound mucus, silane coupler kh560, it is 51-60 DEG C to rise high-temperature, and insulated and stirred 1-2 hour obtains silanol dispersion liquid；
（7）Above-mentioned silanol dispersion liquid is mixed with remaining each raw material, is stirred, in being added to beater, beating, in 60- 20-30 minutes are incubated at 70 DEG C, Jing is discongested, defibrination, add water to solid content for 4-6%, manufactured paper with pulp molding by paper machine, dehydration is dried It is dry, obtain body paper material.
CN201611181040.6A 2016-12-20 2016-12-20 A kind of antibacterial body paper material of Packaging Box macromolecule and preparation method thereof Active CN106638122B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108193548A (en) * 2018-02-02 2018-06-22 朱子涵 A kind of antibacterial yellowing-resistant paper making pulp

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002173900A (en) * 2000-09-29 2002-06-21 Kohjin Co Ltd Sterilized paper
CN1910170A (en) * 2004-01-21 2007-02-07 巴斯福股份公司 Aqueous polymer dispersions containing alkenyl succinic acid anhydrides, methods for the production thereof, and use of the same
CN105568771A (en) * 2015-12-24 2016-05-11 浙江华川实业集团有限公司 Strong antibacterial ability medical packaging raw paper and preparation method thereof
CN105885682A (en) * 2016-07-04 2016-08-24 铜陵方正塑业科技有限公司 Flame-retardant film coating and preparation method thereof
CN106189817A (en) * 2016-07-12 2016-12-07 天长市银狐漆业有限公司 A kind of antibacterial anticorrosive paint of steel alloy and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002173900A (en) * 2000-09-29 2002-06-21 Kohjin Co Ltd Sterilized paper
CN1910170A (en) * 2004-01-21 2007-02-07 巴斯福股份公司 Aqueous polymer dispersions containing alkenyl succinic acid anhydrides, methods for the production thereof, and use of the same
CN105568771A (en) * 2015-12-24 2016-05-11 浙江华川实业集团有限公司 Strong antibacterial ability medical packaging raw paper and preparation method thereof
CN105885682A (en) * 2016-07-04 2016-08-24 铜陵方正塑业科技有限公司 Flame-retardant film coating and preparation method thereof
CN106189817A (en) * 2016-07-12 2016-12-07 天长市银狐漆业有限公司 A kind of antibacterial anticorrosive paint of steel alloy and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108193548A (en) * 2018-02-02 2018-06-22 朱子涵 A kind of antibacterial yellowing-resistant paper making pulp

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