CN106633158A - Preparation method of superhydrophobic coating with favorable binding force with polyolefins - Google Patents
Preparation method of superhydrophobic coating with favorable binding force with polyolefins Download PDFInfo
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- CN106633158A CN106633158A CN201611099946.3A CN201611099946A CN106633158A CN 106633158 A CN106633158 A CN 106633158A CN 201611099946 A CN201611099946 A CN 201611099946A CN 106633158 A CN106633158 A CN 106633158A
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- polyolefin
- titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
Abstract
The invention relates to a preparation method of a superhydrophobic coating with favorable binding force with polyolefins. The method comprises the following steps: adding 100 parts by mass of dimethylformamide, 0.5-1.5 parts by mass of tridecafluorooctyltrimethoxysilane, 6-10 parts by mass of nano titanium dioxide, 2-6 parts by mass of micron-sized titanium dioxide and 0.2-0.8 part by mass of titanate coupling agent into a beaker, uniformly stirring, carrying out ultrasonic dispersion, and stirring while heating to obtain a superhydrophobic paint; and spraying the superhydrophobic paint onto a polyolefin board by a spray gun, and drying to obtain the superhydrophobic coating. The mixture of the titanate coupling agent and fluorine-containing silane coupling agent is utilized to treat the micron-sized titanium dioxide and nano titanium dioxide; and the superhydrophobic coating, which has the advantages of favorable binding force with the polyolefin surface and scratch resistance, is obtained by spraying.
Description
Technical field
The present invention relates to a kind of and polyolefin has the preparation method of the super-hydrophobic coat of good combination power.
Background technology
Super hydrophobic surface refer to it is extremely difficult by water bedew surface, water its surface contact angle more than 150 °.It is super thin
Water surface material has waterproof, the property such as viscous that is antifouling, can reducing fluid.The general principle for preparing super hydrophobic surface is to imitate
The structure of lotus leaf, the multi-level micro-nano knot for also having nanoscale concaveconvex structure on micron order concaveconvex structure is constructed in material surface
Structure.The method of structure micro-nano structure prepares the method for super hydrophobic surface sol-gel process, etching method, heterogeneous nucleation means, mould
Plate method, electrochemical process, self-assembly method, phase separation method etc..
These methods generally require the technological process of special process equipment or complexity, it is difficult to industrialization, constrain significantly
The practical application of super hydrophobic surface.Polyolefine material is a class widely used material, such as poly- second in daily life and production
Alkene bottle is widely used in articles for washing, carton containing polyethylene coating and is widely used in emulsion paint and each for milk, polyacrylic container
Plant the packaging of the aqueous solution.Because polyolefin surfaces still have certain adhesiveness to these liquid substances in container, as general
When these liquid are poured out, it may appear that be difficult to completely clean situation.If the surface of these polyolefine materials can be modified to
The lower super hydrophobic surface of surface tension, it will help liquid is flowed completely out, it is to avoid wastage of material also can make packing plastic bottle or
Bucket is secondary to be used.So can realize not wasting, repeatedly moving in circles uses, and meets the theory of environmental protection.
Chinese patent CN102675728A disclose one kind construct with Ultrahydrophobic polypropylene/titanidioxide dioxide composite film and
Its preparation method, which is realized modifies the film surface and has ultra-hydrophobicity without the need for any low-surface-energy.But the method
It is harsh to the requirement of the conditions such as temperature, pH value in dope preparing process obtained by preparing, and using complex process so cannot realize big
Technical scale is produced.
Material surface is modified using fluorinated polysiloxane coupling agent, is one kind conventionalization for preparing super hydrophobic surface
Learn reaction principle.But because siloxanes and polyolefin are not likely to produce chemical bonds, therefore merely using flucride siloxane to poly-
The adhesive force of the super-hydrophobic coat obtained by alkene modifying surface is not good enough, and the scratch resistance of coating and hydrophobic persistence are not
Reach.The class of titanate coupling agent one can produce the auxiliary agent of good combination with polyolefin, but surpass there is not yet using it for polyolefin
The report of hydrophobic coating.
For problem above, the present invention is using flucride siloxane and titanate coupling agent mixed processing micron order and nanoscale
Titanium dioxide, a kind of super-hydrophobic coat is prepared for using the method for spraying in polyolefin surfaces.The new method letter that the present invention is provided
Single to be efficiently easy to operation, while coating scratch-resistant, persistence is strong.
The content of the invention
The technical problem to be solved in the present invention is：Based on the problems referred to above, the present invention provides a kind of and polyolefin good knot
The preparation method of super-hydrophobic coat with joint efforts.
The present invention solves a technical scheme being adopted of its technical problem：It is a kind of to have good combination power with polyolefin
The preparation method of super-hydrophobic coat, comprises the following steps：
(1) based on quality component, 100 parts of dimethylformamide, ten trifluoro octyl group trimethoxy silanes are added in beaker
0.5～1.5 part, 6～10 parts of Nano titanium dioxide, 2～6 parts of micro-scale titanium dioxide, 0.2～0.8 part of titanate coupling agent,
Stir, ultrasonic disperse half an hour, 80～100 DEG C of heating stirrings one hour obtain super hydrophobic coating；
(2) by super hydrophobic coating spray gun spraying in polyolefin panels, 20～50 DEG C of dryings 5～12 hours are surpassed
Hydrophobic coating.
Further, the particle diameter of Nano titanium dioxide is 10～50 nanometers, the particle diameter of micro-scale titanium dioxide is 0.2～
0.4 micron.
Further, titanate coupling agent be the isophthaloyl titanate esters of isopropyl three, isopropyl three (stearyl) titanate esters,
Isopropyl three (dioctyl pyrophosphoryl base) titanate esters.
Further, the material of polyolefin panels is polypropylene, polyethylene, ethene and octene copolymer.
The invention has the beneficial effects as follows：By being used in mixed way to micron two for titanate coupling agent and fluorine containing silane coupling agent
Titanium oxide and nano titanium oxide are processed, and obtain having good combination power and scratch resistance with polyolefin surfaces by the method for spraying
The super hydrophobic coating of wiping.
Description of the drawings
Below in conjunction with the accompanying drawings the present invention is further described.
Fig. 1 is the water contact angle photo on the super-hydrophobic polyolefin coating surface that embodiment 1 is obtained；
Fig. 2 is the water contact angle photo on the super-hydrophobic polyolefin coating surface that embodiment 2 is obtained；
Fig. 3 is the water contact angle photo on the super-hydrophobic polyolefin coating surface that embodiment 3 is obtained.
Specific embodiment
Presently in connection with specific embodiment, the invention will be further described, and following examples are intended to illustrate rather than
Limitation of the invention further.
Embodiment 1
(1) based on quality component, 100 parts of dimethylformamide, ten trifluoro octyl group trimethoxy silanes are added in beaker
0.5 part, 6 parts of Nano titanium dioxide, 2 parts of micro-scale titanium dioxide, 0.2 part of three isophthaloyl titanate esters of isopropyl stir
Afterwards, ultrasonic disperse half an hour, then in 80 DEG C of heating stirrings, one hour, obtain super hydrophobic coating.
(2) by super hydrophobic coating spray gun spraying on polypropylene board, it is dried 12 hours at 20 DEG C, obtains super-hydrophobic
Coating.
Comparative example 1
According to the same operating process of embodiment 1, but the isophthaloyl titanate esters of isopropyl three are added without, it is right to obtain coating
Ratio 1.
Embodiment 2
(1) based on quality component, 100 parts of dimethylformamide, ten trifluoro octyl group trimethoxy silanes 1 are added in beaker
Part, 8 parts of Nano titanium dioxide, 4 parts of micro-scale titanium dioxide, 0.5 part of isopropyl three (stearyl) titanate esters stir
Afterwards, ultrasonic disperse half an hour, then in 90 DEG C of heating stirrings, one hour, obtain super hydrophobic coating.
(2) by super hydrophobic coating spray gun spraying on polyethylene board, it is dried 8 hours at 35 DEG C, obtains super-hydrophobic
Coating.
Comparative example 2
According to the same operating process of embodiment 2, but isopropyl three (stearyl) titanate esters are added without, obtain coating
For comparative example 2.
Embodiment 3
(1) based on quality component, 100 parts of dimethylformamide, ten trifluoro octyl group trimethoxy silanes are added in beaker
1.5 parts, 10 parts of Nano titanium dioxide, 6 parts of micro-scale titanium dioxide, isopropyl three (dioctyl pyrophosphoryl base) titanate esters 0.8
Part, after stirring, ultrasonic disperse half an hour, then in 100 DEG C of heating stirrings, one hour, obtain super hydrophobic coating.
(2) by super hydrophobic coating spray gun spraying on ethene and octene copolymer (POE) sheet material, 5 are dried at 50 DEG C
Hour, obtain super-hydrophobic coat.
Comparative example 3
According to the same operating process of embodiment 3, but isopropyl three (dioctyl pyrophosphoryl base) titanate esters are added without, are obtained
It is comparative example 3 to coating.
The water contact angle of model is determined using contact angle instrument.Cut out and No. 80 sand of coating widths identical on model
Paper, places 200 grams of counterweights one on sand paper, sand paper is come and gone on the paint film after pulling 10 times, with ear washing bulb by coating surface
Cast blows clean, and contact angle is determined again.
Embodiment 1-3 is determined using contact angle instrument, the water contact angle of comparative example 1-3 model, test result see the table below.
Table has the dependence test result of the material of the super-hydrophobic coat of good combination power with polyolefin
| Comparative example and embodiment | Contact angle | With the contact angle after counterweight heavy burden friction |
| Embodiment 1 | 156° | 151° |
| Comparative example 1 | 144° | 140° |
| Embodiment 2 | >150 ° and freely slide | 156° |
| Comparative example 2 | 132° | 124° |
| Embodiment 3 | 153° | 152° |
| Comparative example 3 | 142° | 134° |
The water contact angle of polyolefin surfaces of addition titanate coupling agent is found by the measurement data contrast of contact angle more
Greatly, illustrate that its ultra-hydrophobicity is more preferable.And pass through the discovery of sand paper heavy burden friction test Data Comparison, after adding titanate coupling agent
Super-hydrophobic paint film after friction test, water contact angle decline degree it is very low, remain above 150 °, maintain ultra-hydrophobicity,
Illustrate that it is more preferable with polyolefin surfaces adhesion.
With the above-mentioned desirable embodiment according to the present invention as enlightenment, by above-mentioned description, relevant staff is complete
Entirely various change and modification can be carried out in the range of without departing from this invention technological thought.The technology of this invention
Property scope is not limited to the content on specification, it is necessary to its technical scope is determined according to right.
Claims (4)
1. a kind of and polyolefin has the preparation method of the super-hydrophobic coat of good combination power, it is characterized in that：Comprise the following steps：
(1) based on quality component, add in beaker 100 parts of dimethylformamide, ten trifluoro octyl group trimethoxy silanes 0.5～
1.5 parts, 6～10 parts of Nano titanium dioxide, 2～6 parts of micro-scale titanium dioxide, 0.2～0.8 part of titanate coupling agent, stirring
Uniformly, ultrasonic disperse half an hour, 80～100 DEG C of heating stirrings one hour obtain super hydrophobic coating；
(2) by super hydrophobic coating spray gun spraying in polyolefin panels, 20～50 DEG C of dryings 5～12 hours obtain super-hydrophobic
Coating.
2. according to claim 1 a kind of and polyolefin has the preparation method of the super-hydrophobic coat of good combination power, and it is special
Levying is：The particle diameter of described Nano titanium dioxide is 10～50 nanometers, and the particle diameter of micro-scale titanium dioxide is 0.2～0.4 micro-
Rice.
3. according to claim 1 a kind of and polyolefin has the preparation method of the super-hydrophobic coat of good combination power, and it is special
Levying is：Described titanate coupling agent is the isophthaloyl titanate esters of isopropyl three, isopropyl three (stearyl) titanate esters, isopropyl
Three (dioctyl pyrophosphoryl base) titanate esters.
4. according to claim 1 a kind of and polyolefin has the preparation method of the super-hydrophobic coat of good combination power, and it is special
Levying is：The material of described polyolefin panels is polypropylene, polyethylene, ethene and octene copolymer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611099946.3A CN106633158A (en) | 2016-12-05 | 2016-12-05 | Preparation method of superhydrophobic coating with favorable binding force with polyolefins |
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| CN201611099946.3A CN106633158A (en) | 2016-12-05 | 2016-12-05 | Preparation method of superhydrophobic coating with favorable binding force with polyolefins |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107090197A (en) * | 2017-05-19 | 2017-08-25 | 东南大学 | A kind of super-amphiphobic coating with formaldehyde degradation by photocatalytic oxidation process function and its preparation method and application |
| CN108948889A (en) * | 2017-05-18 | 2018-12-07 | 通用汽车环球科技运作有限责任公司 | Textured automatically cleaning membranous system and the method for being used to form the membranous system |
| CN109317111A (en) * | 2018-11-05 | 2019-02-12 | 浙江海洋大学 | A kind of preparation method for the floatability type foamed absorbent carrying nano-photocatalyst |
| CN109438749A (en) * | 2018-10-09 | 2019-03-08 | 河南骏化发展股份有限公司 | A kind of hydrophobicity melamine formaldehyde resin foam plastics and preparation method thereof |
| CN110408066A (en) * | 2019-08-07 | 2019-11-05 | 千年舟新材科技集团有限公司 | Environment protection damp-proof high abrasion finishing material and its preparation method and application |
| US11059035B2 (en) | 2017-05-18 | 2021-07-13 | GM Global Technology Operations LLC | Self-cleaning film system and method of forming same |
| US11179711B2 (en) | 2017-05-18 | 2021-11-23 | GM Global Technology Operations LLC | Self-cleaning film system and method of forming same |
| CN114957763A (en) * | 2022-07-08 | 2022-08-30 | 江苏三乔智能科技有限公司 | Super-hydrophobic wear-resistant polypropylene coating and preparation method thereof |
| US11448872B2 (en) | 2017-05-31 | 2022-09-20 | GM Global Technology Operations LLC | Light-enhanced self-cleaning film system and method of forming same |
| CN116376431A (en) * | 2023-03-28 | 2023-07-04 | 暨南大学 | Self-repairing super-hydrophobic protective packaging composite coating based on two-dimensional molybdenum sulfide and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104046217A (en) * | 2013-03-12 | 2014-09-17 | 无锡市顺业科技有限公司 | Preparation method of high strength superhydrophobic coating |
| CN104549966A (en) * | 2015-01-06 | 2015-04-29 | 东华大学 | Method for preparing super-hydrophobic self-lighting coating |
| CN105585928A (en) * | 2015-05-19 | 2016-05-18 | 北京易净星科技有限公司 | Super-hydrophobic paint and preparation and application methods thereof |
-
2016
- 2016-12-05 CN CN201611099946.3A patent/CN106633158A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104046217A (en) * | 2013-03-12 | 2014-09-17 | 无锡市顺业科技有限公司 | Preparation method of high strength superhydrophobic coating |
| CN104549966A (en) * | 2015-01-06 | 2015-04-29 | 东华大学 | Method for preparing super-hydrophobic self-lighting coating |
| CN105585928A (en) * | 2015-05-19 | 2016-05-18 | 北京易净星科技有限公司 | Super-hydrophobic paint and preparation and application methods thereof |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11179711B2 (en) | 2017-05-18 | 2021-11-23 | GM Global Technology Operations LLC | Self-cleaning film system and method of forming same |
| CN108948889A (en) * | 2017-05-18 | 2018-12-07 | 通用汽车环球科技运作有限责任公司 | Textured automatically cleaning membranous system and the method for being used to form the membranous system |
| US10754067B2 (en) | 2017-05-18 | 2020-08-25 | GM Global Technology Operations LLC | Textured self-cleaning film system and method of forming same |
| US11067721B2 (en) | 2017-05-18 | 2021-07-20 | GM Global Technology Operations LLC | Textured self-cleaning film system and method of forming same |
| US11059035B2 (en) | 2017-05-18 | 2021-07-13 | GM Global Technology Operations LLC | Self-cleaning film system and method of forming same |
| CN107090197B (en) * | 2017-05-19 | 2019-04-30 | 东南大学 | A kind of super-amphiphobic coating and its preparation method and application with formaldehyde degradation by photocatalytic oxidation process function |
| CN107090197A (en) * | 2017-05-19 | 2017-08-25 | 东南大学 | A kind of super-amphiphobic coating with formaldehyde degradation by photocatalytic oxidation process function and its preparation method and application |
| US11448872B2 (en) | 2017-05-31 | 2022-09-20 | GM Global Technology Operations LLC | Light-enhanced self-cleaning film system and method of forming same |
| CN109438749A (en) * | 2018-10-09 | 2019-03-08 | 河南骏化发展股份有限公司 | A kind of hydrophobicity melamine formaldehyde resin foam plastics and preparation method thereof |
| CN109317111A (en) * | 2018-11-05 | 2019-02-12 | 浙江海洋大学 | A kind of preparation method for the floatability type foamed absorbent carrying nano-photocatalyst |
| CN109317111B (en) * | 2018-11-05 | 2021-12-17 | 浙江海洋大学 | Preparation method of floatable foaming adsorbent loaded with nano photocatalyst |
| CN110408066A (en) * | 2019-08-07 | 2019-11-05 | 千年舟新材科技集团有限公司 | Environment protection damp-proof high abrasion finishing material and its preparation method and application |
| CN114957763A (en) * | 2022-07-08 | 2022-08-30 | 江苏三乔智能科技有限公司 | Super-hydrophobic wear-resistant polypropylene coating and preparation method thereof |
| CN114957763B (en) * | 2022-07-08 | 2023-04-14 | 江苏三乔智能科技有限公司 | Super-hydrophobic wear-resistant polypropylene coating and preparation method thereof |
| CN116376431A (en) * | 2023-03-28 | 2023-07-04 | 暨南大学 | Self-repairing super-hydrophobic protective packaging composite coating based on two-dimensional molybdenum sulfide and preparation method and application thereof |
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Application publication date: 20170510 |